KR950008526A - 3가 인의 사이클릭 화합물 - Google Patents

3가 인의 사이클릭 화합물 Download PDF

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KR950008526A
KR950008526A KR1019940023934A KR19940023934A KR950008526A KR 950008526 A KR950008526 A KR 950008526A KR 1019940023934 A KR1019940023934 A KR 1019940023934A KR 19940023934 A KR19940023934 A KR 19940023934A KR 950008526 A KR950008526 A KR 950008526A
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compound
different
same
radical
hydrogen
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KR1019940023934A
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KR100350814B1 (ko
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바르만 헬무트
랍페 페터
아. 헤르만 볼프강
알바네제 구이도
마네츠베르거 라이너
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페터스,라이헬트
훽스트 아크티엔게젤샤프트
라이헬트
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
    • B01J31/2476—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/14—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the side-chain of aromatic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

본 발명은 신규 사이클릭 인(Ⅲ)화합물 및 이의 제조방법에 대해 기술하고 있다. 인 화합물은 두 자리 리간드로서 작용하여 금속, 특히 주기율표의 8족 금속과 함께 착화합물을 형성하며, 이 착화합물은 촉매 시스템의 성분으로서 사용될 수 있다.

Description

3가 인의 사이클릭 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 일반식(Ⅰ)의 화합물.
    상기식에서, 라디칼은 포화되거나, 단일 또는 다중 불포화되고, 5원 또는 6원 환이며, R1및 R2은 동일하거나 상이하며, 수소, 탄소수 1내지 5의 알킬, 아르알킬 또는 알콕시 라디칼이거나, 할로겐 원자 또는 어닐링된 (annelated)벤젠 환 또는 나프탈렌 환이고, R3및 R4는 동일하거나 상이하고, 수소 또는 메틸 라디칼이며, m 및 n은 동일하거나 상이하며, 0 또는 1이고, s 및 t는 동일하거나 상이하고, 4 또는 5이며, p, q 및 r은 동일하거나 상이하며, 0, 1, 2 또는 3이고, Ar은 탄소수 6 내지 18의 치환되거나 치환되지 않은 방향족 라디칼이다.
  2. 제1항에 있어서, 라디칼 R3및 R4가 H인 화합물.
  3. 제1항 또는 제2항에 있어서, 라디칼 R1및 R2가 수소 또는 메틸 라디칼인 화합물.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, Ar이 페닐렌, 나프틸렌, 1, 1'-비페닐렌 또는 1, 1'-비나프틸렌 라디칼인 화합물.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, s 및 t가 4인 화합물.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, p 및 r이 동일하거나 상이하고 1인 화합물.
  7. 제1항 내지 제6항 중의 어느 한 항에 있어서, q가 O 또는 1인 화합물.
  8. 2, 2'-비스 (3, 4-디메틸포스폴메틸렌)-1, 1'-비페닐인 화합물.
  9. 2, 2'-비스 (3, 4-디메틸포스폴메틸렌)-1, 1'-비나프틸인 화합물.
  10. 일반식(Ⅱ)의 화합물을 알칼리 금속과 반응시킨 다음, 생성물을 일반식(Ⅲ)의 화합물과 반응시킴을 포함하는, 제1항 내지 제9항 중의 어느 한 항에서 청구한 화합물의 제조방법.
    상기식에서 R1, R2, R3,R4, m, n, p, q, r s, t x 및 Ar은 제1항에서 정의한 바와 같고, Hal은 할로겐, 특히 Cl 또는 Br이다.
  11. 제10항에 있어서, 사용되는 알칼리 금속이 나트륨/칼륨 알로이(alloy)인 제조방법.
  12. 제1항 내지 제9항 중의 어느 한 항에서 청구한 화합물의 균일 가용성 촉매 시스템의 성분으로서의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940023934A 1993-09-30 1994-09-23 3가인의사이클릭화합물,이의제조방법및이를포함하는균질가용성촉매시스템 KR100350814B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE?P4333307.9? 1993-09-30
DE4333307A DE4333307A1 (de) 1993-09-30 1993-09-30 Cyclische Verbindungen des dreiwertigen Phosphors
DEWPP4333307.9GH 1993-09-30

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KR950008526A true KR950008526A (ko) 1995-04-19
KR100350814B1 KR100350814B1 (ko) 2002-10-31

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EP (1) EP0646588B1 (ko)
JP (1) JP2644976B2 (ko)
KR (1) KR100350814B1 (ko)
CN (1) CN1106816A (ko)
AT (1) ATE189225T1 (ko)
AU (1) AU7430394A (ko)
BR (1) BR9403827A (ko)
CA (1) CA2132673A1 (ko)
DE (2) DE4333307A1 (ko)
ES (1) ES2143515T3 (ko)
PL (1) PL305159A1 (ko)
TW (1) TW283149B (ko)
ZA (1) ZA947456B (ko)

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DE19621967A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Hydroformylierung und dafür geeignete Katalysatoren die Phosphorverbindungen als Liganden enthalten
DE19702025A1 (de) * 1997-01-23 1998-07-30 Studiengesellschaft Kohle Mbh Verwendung perfluoralkylsubstituierter Phosphorverbindungen als Liganden für die homogene Katalyse in überkritischem Kohlendioxid
US7012162B2 (en) * 2000-06-26 2006-03-14 Basf Aktiengesellschaft Phosphacyclohexanes and the use thereof in the hydroformylation of olefins
WO2002000580A1 (de) * 2000-06-26 2002-01-03 Basf Aktiengesellschaft Alkoholgemische mit 13 und 15 kohlenstoffatomen und deren verwendung in der herstellung von oberflächenaktiven substanzen
DE10106348A1 (de) * 2001-02-09 2002-08-14 Basf Ag Als Katalysator oder zur Herstellung eines Katalysatorsystems geeignete Verbindung
US6794553B2 (en) * 2001-11-09 2004-09-21 Shell Oil Company Process for the telomerization of a conjugated diene, catalyst and bidentate ligand useful therein
DE102008044783B4 (de) 2008-08-28 2012-05-16 Oxea Gmbh Verfahren zur Gewinnung von aliphatischen C3- bis C10- Aldehyden aus Hochsiedern durch thermische Behandlung
DE102009004655B4 (de) 2009-01-15 2013-02-14 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
DE102009016651B4 (de) 2009-04-07 2011-11-17 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
CN106083551A (zh) * 2016-06-30 2016-11-09 成都欣华源科技有限责任公司 一种丙烯氢甲酰化制备丁醛的方法

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CA1300164C (en) * 1986-06-13 1992-05-05 Thomas James Devon Chelate ligands for low pressure hydroformylation catalyst and process employing same
US5202493A (en) * 1991-04-26 1993-04-13 E. I. Du Pont De Nemours And Company Chiral tridentate bis(phospholane) ligands
US5171892A (en) * 1991-07-02 1992-12-15 E. I. Du Pont De Nemours And Company Chiral phospholanes via chiral 1,4-diol cyclic sulfates
ATE165361T1 (de) * 1992-01-31 1998-05-15 Hoffmann La Roche Diphosphinliganden
US5332846A (en) * 1993-06-01 1994-07-26 Eastman Kodak Company Hydroformylation process using novel phosphine-rhodium catalyst system

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EP0646588B1 (de) 2000-01-26
JPH07173183A (ja) 1995-07-11
AU7430394A (en) 1995-04-13
CA2132673A1 (en) 1995-03-31
DE59409100D1 (de) 2000-03-02
EP0646588A1 (de) 1995-04-05
ZA947456B (en) 1995-05-15
BR9403827A (pt) 1995-05-30
TW283149B (ko) 1996-08-11
DE4333307A1 (de) 1995-04-06
ES2143515T3 (es) 2000-05-16
KR100350814B1 (ko) 2002-10-31
JP2644976B2 (ja) 1997-08-25
CN1106816A (zh) 1995-08-16
PL305159A1 (en) 1995-04-03
ATE189225T1 (de) 2000-02-15

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