JPH08509197A - 合成層状物質mcm−56とその合成と使用 - Google Patents
合成層状物質mcm−56とその合成と使用Info
- Publication number
- JPH08509197A JPH08509197A JP6518465A JP51846594A JPH08509197A JP H08509197 A JPH08509197 A JP H08509197A JP 6518465 A JP6518465 A JP 6518465A JP 51846594 A JP51846594 A JP 51846594A JP H08509197 A JPH08509197 A JP H08509197A
- Authority
- JP
- Japan
- Prior art keywords
- mcm
- calcined
- ray diffraction
- materials
- synthetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Materials For Medical Uses (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Press Drives And Press Lines (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Saccharide Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.モル関係式 X2O3:(n)YO2 ここでnは約35より小さく、Xは3価の元素であり、Yは4価の元素であ る、で示される組成をもち、さらに1,3,5−トリメチルベンゼンの吸着容量 が焼成した合成物質のg当たり少なくとも約35μlであり、焼成した合成物質 のg当たりの2,2−ジメチルブタン15mgの初期吸着時間(アプテーク)が約 20秒より短く且つ焼成した合成物質のX線回折パターンが12.4±0.2、 9.9±0.3、6.9±0.1、6.2±0.1、3.55±0.07及び3 .42±0.07オングストロームにd−間隔最大値をもつことを特徴とする合 成層状物質。 2.Xがアルミニウム、ホウ素、鉄及びガリウムから選ばれ、Yがケイ素および ゲルマニウムから選ばれる請求項1の合成物質。 3.XがアルミニウムをもちYがケイ素をもつ請求項1の合成物質。 4.nが5から25未満である請求項1の物質。 5.nが10〜20である請求項4の物質。 6.合成した状態の無水物基準でYO2のnモル当たりの酸化物のモルで表して 式 (0−2)M2O:(1−2)R:X2O3:(n)YO2 ここでMはアルカリ又はアルカリ土類金属でありRは有機基である、で示さ れる組成を持つ請求項1の物質 7.該Rがシクロアルキルアミン、アザシクロアルカン、ジアザシクロアルカン 及びそれらの混合物からなる群から選ばれると共に上記においてアルキルが5〜 8個の炭素原子をもつ請求項6の物質。 8.有機化合物を含有する供給原料を請求項1の合成層状物質の活性形をもつ触 媒と接触させることを特徴とする有機化合物含有供給原料の転換生成物への転換 方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/051,952 US5362697A (en) | 1993-04-26 | 1993-04-26 | Synthetic layered MCM-56, its synthesis and use |
US051,952 | 1993-04-26 | ||
PCT/US1994/004284 WO1994025539A1 (en) | 1993-04-26 | 1994-04-19 | Synthetic layered material, mcm-56, its synthesis and use |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08509197A true JPH08509197A (ja) | 1996-10-01 |
JP3718222B2 JP3718222B2 (ja) | 2005-11-24 |
Family
ID=21974430
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51846594A Expired - Lifetime JP3718222B2 (ja) | 1993-04-26 | 1994-04-19 | 合成層状物質mcm−56とその合成と使用 |
Country Status (20)
Country | Link |
---|---|
US (4) | US5362697A (ja) |
EP (1) | EP0696308B1 (ja) |
JP (1) | JP3718222B2 (ja) |
KR (1) | KR100301080B1 (ja) |
CN (1) | CN1041216C (ja) |
AT (1) | ATE174616T1 (ja) |
AU (1) | AU678235B2 (ja) |
BR (1) | BR9406361A (ja) |
CA (1) | CA2161414C (ja) |
CZ (1) | CZ277495A3 (ja) |
DE (1) | DE69415313T2 (ja) |
DK (1) | DK0696308T3 (ja) |
ES (1) | ES2126106T3 (ja) |
HU (1) | HU217019B (ja) |
PL (1) | PL175647B1 (ja) |
RO (1) | RO115361B1 (ja) |
RU (1) | RU2140962C1 (ja) |
TW (1) | TW311889B (ja) |
WO (1) | WO1994025539A1 (ja) |
ZA (1) | ZA942733B (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002535227A (ja) * | 1999-01-21 | 2002-10-22 | モービル・オイル・コーポレイション | 合成多孔質結晶mcm−68、その合成及び使用 |
JP2009526790A (ja) * | 2006-02-14 | 2009-07-23 | エクソンモービル・ケミカル・パテンツ・インク | sec−ブチルベンゼンの製造方法 |
JP2009544568A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物(emm−10)とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
JP2009544567A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | Mcm−22族モレキュラーシーブ組成物、その合成法及び炭化水素変換におけるその使用法 |
JP2009544569A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | 新規なモレキュラーシーブ組成物、この製造方法、及びこの使用方法 |
JP2009544566A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物(emm−10−p)とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
JP2014531390A (ja) * | 2011-09-16 | 2014-11-27 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 改善されたmcm−56製造 |
JP2016536240A (ja) * | 2013-09-24 | 2016-11-24 | 中国石油化工股▲ふん▼有限公司 | モレキュラーシーブ、その製造及びその使用 |
JP2018528849A (ja) * | 2015-07-09 | 2018-10-04 | ユミコア アクチェンゲゼルシャフト ウント コンパニー コマンディートゲゼルシャフト | Nh3−scr活性、アンモニア酸化活性ならびに揮発性バナジウムおよびタングステン化合物のための吸着能を有する三元触媒 |
JP2021066626A (ja) * | 2019-10-21 | 2021-04-30 | 東ソー株式会社 | ゼオライト製造用アルミノシリケート |
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ES2105982B1 (es) * | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | Zeolita itq-1 |
US5779882A (en) * | 1996-07-22 | 1998-07-14 | Mobil Oil Corporation | Modified MCM-56, its preparation and use |
CA2269554C (en) * | 1996-10-02 | 2006-11-21 | The Dow Chemical Company | A zeolite-based ethylbenzene process adaptable to an aluminum chloride-based ethylbenzene plant |
DE19649944A1 (de) * | 1996-12-03 | 1998-06-04 | Basf Ag | Verfahren zur Herstellung von Aminen aus Olefinen an Zeolithen des Typs MCM-49 oder MCM-56 |
DE19649946A1 (de) * | 1996-12-03 | 1998-06-04 | Basf Ag | Verfahren zur Herstellung von Aminen aus Olefinen an Bor-MCM-22 oder ERB-1 Zeolithen |
US6919491B1 (en) | 1997-05-08 | 2005-07-19 | Exxonmobil Oil Corporation | Process for preparing short chain alkyl aromatic compounds |
US6063976A (en) * | 1997-08-18 | 2000-05-16 | Exxon Chemical Patent Inc. | Process to alkylate an aromatic with a dilute stream comprising propylene and ethylene |
JPH11116799A (ja) * | 1997-09-30 | 1999-04-27 | E I Du Pont De Nemours & Co | 溶着用ポリアミド組成物 |
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US6143261A (en) * | 1997-12-15 | 2000-11-07 | Exxon Research And Engineering Company | Catalytic reduction of nitrogen oxide emissions with MCM-49 and MCM-56 |
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- 1994-04-19 WO PCT/US1994/004284 patent/WO1994025539A1/en not_active Application Discontinuation
- 1994-04-19 KR KR1019950704692A patent/KR100301080B1/ko not_active IP Right Cessation
- 1994-04-19 CN CN94192390A patent/CN1041216C/zh not_active Expired - Lifetime
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- 1994-04-19 JP JP51846594A patent/JP3718222B2/ja not_active Expired - Lifetime
- 1994-04-19 CZ CZ952774A patent/CZ277495A3/cs unknown
- 1994-04-19 RU RU95122121A patent/RU2140962C1/ru active
- 1994-04-19 PL PL94311293A patent/PL175647B1/pl unknown
- 1994-04-19 EP EP94913426A patent/EP0696308B1/en not_active Expired - Lifetime
- 1994-04-19 HU HU9503056A patent/HU217019B/hu not_active IP Right Cessation
- 1994-04-19 DK DK94913426T patent/DK0696308T3/da active
- 1994-04-19 DE DE69415313T patent/DE69415313T2/de not_active Expired - Lifetime
- 1994-04-19 AU AU65596/94A patent/AU678235B2/en not_active Expired
- 1994-04-19 ES ES94913426T patent/ES2126106T3/es not_active Expired - Lifetime
- 1994-04-20 ZA ZA942733A patent/ZA942733B/xx unknown
- 1994-05-05 TW TW083104092A patent/TW311889B/zh not_active IP Right Cessation
- 1994-05-26 US US08/249,609 patent/US5453554A/en not_active Expired - Lifetime
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Cited By (11)
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JP2002535227A (ja) * | 1999-01-21 | 2002-10-22 | モービル・オイル・コーポレイション | 合成多孔質結晶mcm−68、その合成及び使用 |
JP4689046B2 (ja) * | 1999-01-21 | 2011-05-25 | エクソンモービル オイル コーポレイション | 合成多孔質結晶mcm−68、その合成及び使用 |
JP2009526790A (ja) * | 2006-02-14 | 2009-07-23 | エクソンモービル・ケミカル・パテンツ・インク | sec−ブチルベンゼンの製造方法 |
JP2009544568A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物(emm−10)とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
JP2009544567A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | Mcm−22族モレキュラーシーブ組成物、その合成法及び炭化水素変換におけるその使用法 |
JP2009544569A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | 新規なモレキュラーシーブ組成物、この製造方法、及びこの使用方法 |
JP2009544566A (ja) * | 2006-07-28 | 2009-12-17 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物(emm−10−p)とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
JP2014531390A (ja) * | 2011-09-16 | 2014-11-27 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 改善されたmcm−56製造 |
JP2016536240A (ja) * | 2013-09-24 | 2016-11-24 | 中国石油化工股▲ふん▼有限公司 | モレキュラーシーブ、その製造及びその使用 |
JP2018528849A (ja) * | 2015-07-09 | 2018-10-04 | ユミコア アクチェンゲゼルシャフト ウント コンパニー コマンディートゲゼルシャフト | Nh3−scr活性、アンモニア酸化活性ならびに揮発性バナジウムおよびタングステン化合物のための吸着能を有する三元触媒 |
JP2021066626A (ja) * | 2019-10-21 | 2021-04-30 | 東ソー株式会社 | ゼオライト製造用アルミノシリケート |
Also Published As
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CN1041216C (zh) | 1998-12-16 |
RO115361B1 (ro) | 2000-01-28 |
PL175647B1 (pl) | 1999-01-29 |
DE69415313D1 (de) | 1999-01-28 |
KR960701973A (ko) | 1996-03-28 |
US5362697A (en) | 1994-11-08 |
US5557024A (en) | 1996-09-17 |
KR100301080B1 (ko) | 2001-11-22 |
US5453554A (en) | 1995-09-26 |
US5536894A (en) | 1996-07-16 |
AU6559694A (en) | 1994-11-21 |
CA2161414C (en) | 2005-03-01 |
AU678235B2 (en) | 1997-05-22 |
CA2161414A1 (en) | 1994-11-10 |
CN1124973A (zh) | 1996-06-19 |
TW311889B (ja) | 1997-08-01 |
JP3718222B2 (ja) | 2005-11-24 |
BR9406361A (pt) | 1996-02-27 |
PL311293A1 (en) | 1996-02-05 |
DE69415313T2 (de) | 1999-04-29 |
ATE174616T1 (de) | 1999-01-15 |
HU9503056D0 (en) | 1995-12-28 |
EP0696308A1 (en) | 1996-02-14 |
DK0696308T3 (da) | 1999-08-23 |
HUT73318A (en) | 1996-07-29 |
ES2126106T3 (es) | 1999-03-16 |
HU217019B (hu) | 1999-11-29 |
WO1994025539A1 (en) | 1994-11-10 |
CZ277495A3 (en) | 1996-10-16 |
ZA942733B (en) | 1995-10-20 |
RU2140962C1 (ru) | 1999-11-10 |
EP0696308A4 (ja) | 1996-03-27 |
EP0696308B1 (en) | 1998-12-16 |
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