DK3640208T3 - Molekularsi scm-14, syntesefremgangsmåde dertil og anvendelse deraf - Google Patents

Molekularsi scm-14, syntesefremgangsmåde dertil og anvendelse deraf Download PDF

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DK3640208T3
DK3640208T3 DK17913991.0T DK17913991T DK3640208T3 DK 3640208 T3 DK3640208 T3 DK 3640208T3 DK 17913991 T DK17913991 T DK 17913991T DK 3640208 T3 DK3640208 T3 DK 3640208T3
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sci
molecular
synthesis procedure
synthesis
procedure
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DK17913991.0T
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Weimin Yang
Zhendong Wang
Yi Luo
Hongmin Sun
Bin Zhang
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China Petroleum & Chem Corp
Shanghai Res Inst Petrochemical Tech Sinopec
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    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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DK17913991.0T 2017-06-13 2017-10-31 Molekularsi scm-14, syntesefremgangsmåde dertil og anvendelse deraf DK3640208T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710440330 2017-06-13
PCT/CN2017/108461 WO2018227849A1 (zh) 2017-06-13 2017-10-31 分子筛scm-14、其合成方法及其用途

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DK3640208T3 true DK3640208T3 (da) 2022-04-11

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US (1) US11097256B2 (da)
EP (1) EP3640208B1 (da)
JP (1) JP7045401B2 (da)
KR (1) KR102359047B1 (da)
CN (1) CN109081360B (da)
DK (1) DK3640208T3 (da)
ES (1) ES2910830T3 (da)
PT (1) PT3640208T (da)
SG (1) SG11201912126PA (da)
WO (1) WO2018227849A1 (da)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3640207B1 (en) * 2017-06-13 2022-02-09 China Petroleum & Chemical Corporation Molecular sieve scm-15, synthesis method therefor and use thereof
CN111099612B (zh) * 2018-10-25 2021-11-30 中国石油化工股份有限公司 分子筛scm-23、其合成方法及其用途
CN112206807B (zh) * 2019-07-09 2023-06-06 中国石油化工股份有限公司 基于硅和锗的scm-25分子筛、其制备方法及其用途
CN112520755B (zh) * 2019-09-19 2022-07-12 中国石油化工股份有限公司 Scm-28分子筛及其制备方法和应用
CN112573535B (zh) * 2019-09-29 2022-07-12 中国石油化工股份有限公司 Scm-32分子筛及其制备方法和应用
CN112707883B (zh) * 2019-10-25 2022-07-08 中国石油化工股份有限公司 一种ε-己内酯的制备方法
CN113831271B (zh) * 2020-06-24 2023-10-31 中国石油化工股份有限公司 一种催化环己酮肟气相重排制备己内酰胺的方法
CN114180597B (zh) * 2020-09-14 2023-06-06 中国石油化工股份有限公司 Scm-34分子筛及其制备方法和应用
CN115231584B (zh) * 2021-04-22 2023-10-31 中国石油化工股份有限公司 一种afi分子筛及其制备方法和应用
CN114426293B (zh) * 2020-09-27 2023-09-29 中国石油化工股份有限公司 Scm-35分子筛、其制备方法和应用
CN115368200B (zh) * 2021-05-21 2024-03-26 中国石油化工股份有限公司 一种生物质转化制备对二甲苯的方法
EP4342872A1 (en) 2021-05-21 2024-03-27 China Petroleum & Chemical Corporation Method for preparing p-xylene by biomass conversion
CN115882163A (zh) 2021-09-28 2023-03-31 中国石油化工股份有限公司 一种分子筛改性隔膜及其制备方法和应用
TW202334036A (zh) * 2021-10-20 2023-09-01 大陸商中國石油化工科技開發有限公司 一種scm-38分子篩及其製備方法和用途

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US2882243A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4016245A (en) 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
CA1064890A (en) 1975-06-10 1979-10-23 Mae K. Rubin Crystalline zeolite, synthesis and use thereof
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
DE3117135A1 (de) 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US6162416A (en) 1996-07-12 2000-12-19 Uop Llc Zeolite beta and its use in aromatic alkylation
JP2006313664A (ja) 2005-05-06 2006-11-16 Nissan Motor Co Ltd 燃料電池車両
JP5397798B2 (ja) 2005-11-19 2014-01-22 独立行政法人産業技術総合研究所 層状珪酸塩を前駆体とする新規高シリカナノ多孔体、その設計方法と製造方法
JP5128594B2 (ja) 2006-07-21 2013-01-23 バーラト ペトローリアム コーポレーション リミテッド 微孔質結晶性シリコアルミノ/(メタロ)アルミノリン酸塩分子篩およびその合成方法
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
FR2940266B1 (fr) 2008-12-18 2010-12-31 Inst Francais Du Petrole Solide cristallise im-20 et son procede de preparation
CN104159849B (zh) * 2012-02-21 2017-01-11 埃克森美孚化学专利公司 分子筛材料,其合成及用途
CN104445263B (zh) * 2013-09-24 2016-02-10 中国石油化工股份有限公司 Scm-3分子筛及其制备方法
CN104445247B (zh) * 2013-09-24 2016-06-08 中国石油化工股份有限公司 Scm-4分子筛及其制备方法
CN104445246B (zh) * 2013-09-24 2017-01-04 中国石油化工股份有限公司 Scm-5分子筛及其制备方法
CN105217651B (zh) * 2014-07-03 2017-07-14 中国石油化工股份有限公司 硅铝分子筛scm‑6、其合成方法及其用途
CN105460953B (zh) * 2014-09-09 2017-08-11 中国石油化工股份有限公司 Scm‑8分子筛及其制备方法
US10293330B2 (en) 2015-06-01 2019-05-21 California Institute Of Technology Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same
BR102016026128B1 (pt) * 2015-11-09 2022-10-04 Shanghai Research Institute Of Petrochemical Technology, Sinopec Peneiras moleculares scm-11, processo para a produção das mesmas, seus usos e composição de peneira molecular
BR102016026121B1 (pt) 2015-11-09 2021-09-14 China Petroleum & Chemical Corporation Peneira molecular scm-10, processo para sua produção, composição e uso
ES2650083B1 (es) * 2016-06-16 2018-10-29 Consejo Superior De Investigaciones Científicas (Csic) Material itq-62, su procedimiento de obtención y su uso
EP3640207B1 (en) * 2017-06-13 2022-02-09 China Petroleum & Chemical Corporation Molecular sieve scm-15, synthesis method therefor and use thereof
CN111099612B (zh) * 2018-10-25 2021-11-30 中国石油化工股份有限公司 分子筛scm-23、其合成方法及其用途

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JP7045401B2 (ja) 2022-03-31
WO2018227849A1 (zh) 2018-12-20
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JP2020523272A (ja) 2020-08-06
EP3640208A1 (en) 2020-04-22
US11097256B2 (en) 2021-08-24
CN109081360B (zh) 2020-10-27
KR20200017482A (ko) 2020-02-18
US20200188892A1 (en) 2020-06-18
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PT3640208T (pt) 2022-04-11
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