JP2005531686A - ポリプロピレン/オレフィンエラストマー混合物を含む定方向フィルム - Google Patents
ポリプロピレン/オレフィンエラストマー混合物を含む定方向フィルム Download PDFInfo
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Abstract
Description
本出願は、米国仮特許出願第60/391,983号(2002年6月26日出願)および米国仮特許出願第60/424,883号(2002年11月8日出願)の優先権を主張する。これらの仮特許出願は、本明細書中でそれらの全体が参照として援用される。
本発明は、流れ方向化(machine−direction oriented)単層フィルムまたは多層フィルムの調製の方法、およびこれらを作製する方法に関する。本発明はまた、このような流れ方向化ポリマーフィルムを使用したラベルおよび他の組成物の調製に関する。
ラベルのための表面の層すなわちフェイスストック材料の提供、または、剥離裏地(release liner)すなわち剥離キャリア(release carrier)によって覆われる感圧接着層によって裏打ちされるmm単位の表示の提供によって、ラベルのための感圧接着ストックを製造および配給することは、長い間公知である。この裏地またはキャリアは、輸送および保管の間、接着剤を保護し、そしてラベルが型抜き(die−cut)され、マトリックス(matrix)がフェイスストック材料の層から外された後、独立したラベルがラベル貼りライン上に順々に分配される時点まで、多くの列の独立したラベルの効率的な取り扱いを可能にする。型抜きされてから分配されるまでの時間、裏地すなわちキャリアは、切断されないままであり、そしてその上に保有する独立したラベルの列の保管、運搬および配置のために、丸められても丸められなくてもよい。
本発明は、(A)約5〜約40のメルトフロー速度を有する、少なくとも1のプロピレンホモポリマー、プロピレンコポリマー、またはこれらの2以上の混合物、および(B)1のオレフィンエラストマーから調製され、(A)は(B)と同一ではない、流れ方向化ポリマーフィルムを含む、フィルムに関する。1つの実施形態において、このフィルムは、核形成(nucleate)される。1つの実施形態において、このフィルムは、透明である。別の実施例において、このフィルムは、良好な剛性およびくもりの低い透明度を有する。このフィルムは、ラベルの調製において有用であり、そして単層フィルムまたは多層フィルムとして使用され得る。1つの実施形態において、このフィルムは、印刷可能である。
本発明のフィルムは、(A)少なくとも1のプロピレンホモポリマー、プロピレンコポリマー、またはこれらの2以上の混合物、および(B)少なくとも1のオレフィンエラストマーの組み合わせから得られるが、但し、(A)は(B)と同一ではない。このフィルムは、単層フィルムとして使用されても、多層フィルムの1つ以上の部分として使用されてもよい。1つの実施形態において、このフィルムは透明であり、非常に透明(crystal clear)ですらある。1つの実施形態において、このフィルムは、10%未満のくもりを有する。くもりは、BYK Gardner視程計で測定される。本発明の定方向プロピレンフィルムは、約10%以下の不透明度を有する。
本発明は、プロピレンポリマーから調製されたフィルムに関する。このフィルムは、(A)約5〜約40のメルトフロー速度、もしくは約6〜約32のメルトフロー速度、もしくは約6〜約30のメルトフロー速度、もしくは約8〜約25のメルトフロー速度を有する、少なくとも1のプロピレンホモポリマー、プロピレンコポリマー、またはこれらの2以上の混合物から調製される。メルトフロー速度は、ASTM試験D−1238によって決定する。1つの実施形態において、ポリマー(A)のメルトフロー速度は、約8〜約26、または約10〜約22である。本明細書中および特許請求の範囲中で、範囲および比率の限度は、組み合され得る。
本明細書において記載されるように、フィルム組成物は(B)少なくとも1種類のオレフィンエラストマーを含む。オレフィンエラストマーは、プラストマー(plastomer)と呼ばれている。1つの実施形態において、オレフィンエラストマーは、約1〜約40g/10分、または約3〜約35g/10分、または約5〜約25g/10分のメルトフローインデックスを有する。メルトフローインデックスは、190℃において、ASTM試験 D−1238により決定される。1つの実施形態において、(B)についてのメルトフローインデックスは、約1〜約25g/10分、または約2〜約10g/10分の範囲内である。オレフィンエラストマーは、代表的には、フィルム中のポリマーの約2%〜約55%、または約10%〜約50%、または約15%〜45%の量で存在する。
1つの実施形態において、フィルムは造核剤を含む。造核剤については前述した。造核剤は、本発明の多層フィルムの任意の層または全ての層に取りこまれ得る。上述のように、造核剤は、プロピレンポリマー(A)中に取りこまれ得るか、またはフィルムを作製するために使用される処方物中の別個の成分として取りこまれ得る。造核剤はまた、プロピレンポリマー(A)またはオレフィンポリマーエラストマー(B)に予め組み込まれ得、フィルム処方物の別個の成分として添加され得る。一般的に、本発明のフィルム処方物中に取りこまれる造核剤の総量は、ごく小さく、約500または1000〜約3000または5000ppmの範囲である。造核剤の量は、(A)または(B)に予め組み込まれている状態と別個の成分(C)として存在している状態との間で均等にまたは不均等に分配され得る。
本明細書に記載される場合、上記のフィルムは、単層フィルムとして単独で使用され得るか、または、多層フィルム構造物を作製するために他のフィルムと組み合せて使用され得る。多層構造物において、その構造物全体が、本発明のフィルムにより作製され得る。別の実施形態において、本発明のフィルムは、多層フィルム構造物の少なくとも1つの層を構成する。別の実施形態において、本発明のフィルムは、多層フィルム構造物の少なくとも1つの表面薄層を構成する。
Claims (47)
- (A)約5〜約40のメルトフロー速度を有する、少なくとも1のプロピレンホモポリマー、プロピレンコポリマー、またはこれらの2以上の混合物、および(B)少なくとも1のオレフィンエラストマーを含む、流れ方向化ポリマーフィルム。
- (A)が、約6〜約32のメルトフロー速度を有する、請求項1に記載のフィルム。
- (A)が、プロピレンホモポリマーである、請求項1に記載のフィルム。
- (A)が、プロピレンおよび2〜約12の炭素原子を有するオレフィンから調製されるプロピレンコポリマーである、請求項1に記載のフィルム。
- 前記プロピレンコポリマーが、プロピレンと1以上のエチレン、ブチレン、ヘキセン、ヘプテン、オクテン、ノネンまたはデセンとのコポリマーである、請求項1に記載のフィルム。
- (A)が、プロピレンエチレンコポリマーまたはプロピレンブチレンコポリマーである、請求項1に記載のフィルム。
- (B)が、エチレンホモポリマーもしくはエチレンコポリマー、プロピレンホモポリマーもしくはプロピレンコポリマー、またはこれらの2以上の混合物である、請求項1に記載のフィルム。
- (B)が、エチレン−ブテンコポリマー、エチレン−オクテンコポリマー、エチレン−ヘキセンコポリマー、およびエチレン−ヘキセン−ブテンターポリマー、またはこれらの2以上の混合物である、請求項1に記載のフィルム。
- (B)が、約1〜約40のメルトフロー速度を有する、請求項1に記載のフィルム。
- (A)または(B)が、核形成される、請求項1に記載のフィルム。
- 前記フィルムが透明である、請求項1に記載のフィルム。
- (A)が、メタロセン触媒を用いて調製される、請求項1に記載のフィルム。
- (B)が、メタロセン触媒を用いて調製される、請求項1に記載のフィルム。
- 前記フィルムの全てのポリマーが、炭化水素ポリマーである、請求項1に記載のフィルム。
- (C)少なくとも1の造核剤をさらに含む、請求項1に記載のフィルム。
- 前記フィルムが、約2:1〜約9:1の伸展比率で流れ方向に伸展することにより方向付けられている、請求項1に記載のフィルム。
- (A)約5〜約40のメルトフロー速度を有する、少なくとも1のプロピレンコポリマー、および(B)少なくとも1のオレフィンエラストマーを含む、透明な流れ方向化フィルム。
- 約1〜約7ミルの厚みを有する、請求項17に記載のフィルム。
- (A)または(B)が、核形成される、請求項17に記載のフィルム。
- (A)または(B)が、メタロセン触媒を使用して調製される、請求項17に記載のフィルム。
- (C)少なくとも1の造核剤をさらに含む、請求項17に記載のフィルム。
- 単層フィルムである、請求項17に記載のフィルム。
- (A)が、プロピレンエチレンコポリマーまたはプロピレンブチレンコポリマーである、請求項17に記載のフィルム。
- (B)が、エチレンホモポリマーもしくはエチレンコポリマー、プロピレンホモポリマーもしくはプロピレンコポリマー、またはこれらの2以上の混合物である、請求項17に記載のフィルム。
- (B)が、エチレン−ブテンコポリマー、エチレン−オクテンコポリマー、エチレン−ヘキセンコポリマー、エチレン−プロピレン−ブテンターポリマー、およびエチレン−ヘキセン−ブテンターポリマー、またはこれらの2以上の混合物である、請求項17に記載のフィルム。
- 約50重量%〜約90重量%の(A)約6〜約30のメルトフロー速度を有する、少なくとも1のプロピレン−エチレンコポリマーまたは少なくとも1のプロピレン−ブチレンコポリマー、および約10重量%〜50重量%の(B)少なくとも1のエチレン−ブチレンコポリマーまたは少なくとも1のエチレン−ヘキセンコポリマーを含む、透明な流れ方向化フィルム。
- 上表面および下表面を有する基礎層、および該上表面の上に少なくとも1の表面薄層を含む多層フィルムであって、該表面薄層が、請求項1に記載のフィルムに由来する、多層フィルム。
- 表面薄層が、前記基礎層の前記上表面上および前記下表面上に存在する、請求項27に記載のフィルム。
- 上表面および下表面を有する基礎層、および請求項17に記載のフィルムに由来する少なくとも1の表面薄層を含む多層フィルムであって、該表面薄層が、該上表面の上にある、多層フィルム。
- 表面薄層が、前記基礎層の前記上表面上および前記下表面上に存在する、請求項29に記載のフィルム。
- 上表面および下表面を有する基礎層、および該上表面の上の請求項26に記載のフィルムに由来する少なくとも1の表面薄層を含む、多層フィルム。
- 表面薄層が、コア層の第1表面上および第2表面上に存在する、請求項31に記載のフィルム。
- 型抜き可能な、伸展方向化多層フィルムであって、該フィルムは、以下:
(A)上表面および下表面を有し、約0.940g/cm3以下の密度を有するポリエチレン、プロピレンホモポリマー、プロピレンコポリマー、またはこれらの混合物を含む基礎層、ならびに
(B)(A)約5〜約40のメルトフロー速度を有する、少なくとも1つのプロピレンホモポリマー、プロピレンコポリマー、またはこれらの2以上の混合物、および(B)少なくとも1のオレフィンエラストマーから調製された、第1表面薄層
を含む、フィルム。 - 前記基礎層が、プロピレンホモポリマーまたはプロピレンコポリマーを含む、請求項33に記載の多層フィルム。
- 前記基礎層が、約0.890〜約0.925g/cm3の密度を有するポリエチレンを含む、請求項33に記載の多層フィルム。
- 前記基礎層もしくは前記第1表面薄層、またはその両方が、造核剤をもまた含む、請求項33に記載の多層フィルム。
- 前記基礎層の下表面を覆う第2表面薄層を含む、請求項33に記載の多層フィルム。
- 前記第2表面薄層の組成が、前記第1表面薄層の組成と異なる、請求項37に記載の多層フィルム。
- 接着ラベルにおける使用のためのラベルストックを含む接着剤であって、該接着ラベルは、以下:
(A)請求項1に記載のフィルム、および
(B)上表面および下表面を有する接着層であって、該接着層の該上表面は、基礎層の下表面に接着して結合する、接着層
を、含む、接着剤。 - 前記接着層が、感圧接着層である、請求項56に記載のラベルストック。
- 接着ラベルにおける使用のためのラベルストックを含む接着剤であって、該接着ラベルは、以下:
(A)請求項17に記載のフィルム、および
(B)上表面および下表面を有する接着層であって、該接着層の該上表面は、基礎層の下表面に接着して結合する、接着層
を、含む、接着剤。 - 前記接着層が、感圧接着層である、請求項41に記載のラベルストック。
- 接着ラベルにおける使用のためのラベルストックを含む接着剤であって、該接着ラベルは、以下:
(A)請求項33に記載のフィルム、および
(B)上表面および下表面を有する接着層であって、該接着層の該上表面は、基礎層の下表面に接着して結合する、接着層
を、含む、接着剤。 - 前記接着層が、感圧接着層である、請求項43に記載のラベルストック。
- 請求項39に記載のラベルストックから型抜きされた、感圧接着ラベル。
- 請求項41に記載のラベルストックから型抜きされた、感圧接着ラベル。
- 請求項43に記載のラベルストックから型抜きされた、感圧接着ラベル。
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US42488302P | 2002-11-08 | 2002-11-08 | |
PCT/US2003/020281 WO2004003874A2 (en) | 2002-06-26 | 2003-06-26 | Oriented films comprising polypropylene / olefin elastomer blends |
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EP (1) | EP1376516B1 (ja) |
JP (1) | JP4268940B2 (ja) |
KR (2) | KR101186271B1 (ja) |
CN (1) | CN100560359C (ja) |
AT (1) | ATE396472T1 (ja) |
AU (1) | AU2003247735B2 (ja) |
CA (1) | CA2488551A1 (ja) |
DE (1) | DE60321090D1 (ja) |
ES (1) | ES2305371T3 (ja) |
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JP2003205966A (ja) * | 2002-01-11 | 2003-07-22 | Sumitomo Chem Co Ltd | 収縮包装用フィルムおよびラベル |
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KR101179249B1 (ko) | 2012-02-27 | 2012-09-03 | (주)대명화학 | 낙진방지용 필름 |
CN103289161A (zh) * | 2012-02-27 | 2013-09-11 | (株)大明化学 | 防尘膜 |
JP2017508057A (ja) * | 2014-02-10 | 2017-03-23 | テーザ・ソシエタス・ヨーロピア | 接着テープ |
JP2017213889A (ja) * | 2016-05-31 | 2017-12-07 | 株式会社ユポ・コーポレーション | 樹脂フィルム、及びこれを用いたポスター用印刷基材 |
JP2020510106A (ja) * | 2017-02-24 | 2020-04-02 | テーザ・ソシエタス・ヨーロピア | 接着テープ |
JP7141792B2 (ja) | 2018-01-23 | 2022-09-26 | 三井化学株式会社 | 伸縮性構造体 |
Also Published As
Publication number | Publication date |
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KR101186271B1 (ko) | 2012-09-27 |
EP1376516A1 (en) | 2004-01-02 |
CN1659030A (zh) | 2005-08-24 |
KR101186268B1 (ko) | 2012-09-27 |
DE60321090D1 (de) | 2008-07-03 |
US7217463B2 (en) | 2007-05-15 |
US20040033349A1 (en) | 2004-02-19 |
WO2004003874A2 (en) | 2004-01-08 |
ES2305371T3 (es) | 2008-11-01 |
USRE46911E1 (en) | 2018-06-26 |
AU2003247735B2 (en) | 2010-03-11 |
JP4268940B2 (ja) | 2009-05-27 |
KR20110088562A (ko) | 2011-08-03 |
AU2003247735A1 (en) | 2004-01-19 |
MXPA04012896A (es) | 2005-03-31 |
CA2488551A1 (en) | 2004-01-08 |
KR20050016884A (ko) | 2005-02-21 |
WO2004003874A3 (en) | 2004-03-18 |
ATE396472T1 (de) | 2008-06-15 |
EP1376516B1 (en) | 2008-05-21 |
CN100560359C (zh) | 2009-11-18 |
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