DE1958046C3 - Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung - Google Patents

Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung

Info

Publication number
DE1958046C3
DE1958046C3 DE1958046A DE1958046A DE1958046C3 DE 1958046 C3 DE1958046 C3 DE 1958046C3 DE 1958046 A DE1958046 A DE 1958046A DE 1958046 A DE1958046 A DE 1958046A DE 1958046 C3 DE1958046 C3 DE 1958046C3
Authority
DE
Germany
Prior art keywords
titanium
halide
magnesium chloride
polymerization
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1958046A
Other languages
German (de)
English (en)
Other versions
DE1958046A1 (de
DE1958046B2 (de
Inventor
Ermanno Ferrara Susa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montecatini Edison SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montecatini Edison SpA filed Critical Montecatini Edison SpA
Publication of DE1958046A1 publication Critical patent/DE1958046A1/de
Publication of DE1958046B2 publication Critical patent/DE1958046B2/de
Application granted granted Critical
Publication of DE1958046C3 publication Critical patent/DE1958046C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/906—Comminution of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE1958046A 1968-11-21 1969-11-19 Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung Expired DE1958046C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2400868 1968-11-21

Publications (3)

Publication Number Publication Date
DE1958046A1 DE1958046A1 (de) 1970-06-25
DE1958046B2 DE1958046B2 (de) 1973-01-25
DE1958046C3 true DE1958046C3 (de) 1982-02-04

Family

ID=11211449

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1958046A Expired DE1958046C3 (de) 1968-11-21 1969-11-19 Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung

Country Status (17)

Country Link
US (1) US4495338A (cg-RX-API-DMAC10.html)
AT (1) AT292299B (cg-RX-API-DMAC10.html)
BE (1) BE742003A (cg-RX-API-DMAC10.html)
BR (1) BR6914363D0 (cg-RX-API-DMAC10.html)
CS (1) CS150994B2 (cg-RX-API-DMAC10.html)
DE (1) DE1958046C3 (cg-RX-API-DMAC10.html)
DK (1) DK133012C (cg-RX-API-DMAC10.html)
ES (1) ES373699A1 (cg-RX-API-DMAC10.html)
FR (1) FR2023789A1 (cg-RX-API-DMAC10.html)
GB (1) GB1292853A (cg-RX-API-DMAC10.html)
IL (1) IL33378A (cg-RX-API-DMAC10.html)
NL (1) NL162661B (cg-RX-API-DMAC10.html)
PL (1) PL77395B1 (cg-RX-API-DMAC10.html)
RO (1) RO75486A (cg-RX-API-DMAC10.html)
SE (1) SE363977B (cg-RX-API-DMAC10.html)
SU (1) SU403194A3 (cg-RX-API-DMAC10.html)
YU (1) YU34622B (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4336360A (en) 1971-06-25 1982-06-22 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha-olefins

Families Citing this family (243)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA707173B (en) * 1969-10-24 1971-09-29 Mitsui Petrochemical Ind Process for the polymerization of olefins and catalyst therefor
NL163522B (nl) * 1970-07-20 1980-04-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de polymerisatie van alkenen-1.
NL163523C (nl) * 1970-07-31 1983-11-16 Montedison Spa Werkwijze om een polymerisatiekatalysator te bereiden.
NL7113778A (cg-RX-API-DMAC10.html) * 1970-10-13 1972-04-17
JPS5210916B1 (cg-RX-API-DMAC10.html) * 1971-07-22 1977-03-26
US3907759A (en) * 1972-10-06 1975-09-23 Nissan Chemical Ind Ltd Catalyst for polymerization of olefins and process for polymerization of olefins with use of said catalyst
GB1489599A (en) * 1973-10-09 1977-10-19 Nippon Oil Co Ltd Process for preparing polyolefins and catalyst and catalyst component therefor
US4614727A (en) * 1975-01-23 1986-09-30 Montecatini Edison S.P.A. Polymerization catalyst
JPS5242584A (en) 1975-10-02 1977-04-02 Nippon Oil Co Ltd Process for producing polyolefine
NL7613855A (nl) * 1975-12-18 1977-06-21 Sumitomo Chemical Co Werkwijze voor het polymeriseren van olefinen.
ES456321A1 (es) * 1976-02-25 1978-01-16 Charbonnages Ste Chimique Procedimiento mejorado de polimerizacion ionica del etileno bajo alta presion.
IT1062072B (it) * 1976-06-03 1983-06-25 Montedison Spa Catalizzatori per la polimerizzazione di etilene
US4507450A (en) * 1976-08-18 1985-03-26 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
US4242479A (en) * 1976-12-23 1980-12-30 Showa Yuka Kabushiki Kaisha Process for producing an improved ethylenic polymer
US4383938A (en) 1977-02-11 1983-05-17 Exxon Research And Engineering Co. Catalyst system for olefinic polymerization
US4391738A (en) * 1977-04-25 1983-07-05 Exxon Research And Engineering Co. Catalyst for olefinic polymerization
FR2400040A2 (fr) * 1977-08-09 1979-03-09 Charbonnages Ste Chimique Procede controle de polymerisation ionique de l'ethylene sous haute pression
FR2424760A1 (fr) * 1978-05-05 1979-11-30 Charbonnages Ste Chimique Catalyseurs comprenant du magnesium et un metal de transition
DE2830039A1 (de) * 1978-07-07 1980-01-17 Hoechst Ag Verfahren zur herstellung eines mischkatalysators
IT1100285B (it) * 1978-11-21 1985-09-28 Euteco Spa Catalizzatori con supporti misti per la cmo- e co-polimezzazione di alfa-olefine
US4366298A (en) * 1979-07-05 1982-12-28 Wacker-Chemie Gmbh Process and heavy metal catalyst for the polymerization of α-olefins, particularly polyethylene
JPS5610506A (en) 1979-07-09 1981-02-03 Mitsui Petrochem Ind Ltd Production of ethylene polymer composition
IT1141068B (it) * 1979-09-26 1986-10-01 Nippon Oil Co Ltd Procedimento per la preparazione di poliolefine
EP0072128B1 (en) * 1981-08-07 1986-03-19 Imperial Chemical Industries Plc Spraying solid
JPS58125706A (ja) * 1982-01-22 1983-07-26 Mitsubishi Petrochem Co Ltd エチレンの重合法
US4415712A (en) * 1982-03-01 1983-11-15 The Dow Chemical Company Polymerizing olefins with catalysts containing the reaction product of a transition metal compound and a boron compound
IT1178466B (it) 1984-03-20 1987-09-09 Montedison Spa Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti
DE3504808A1 (de) * 1985-02-13 1986-08-14 Studiengesellschaft Kohle mbH, 4330 Mülheim Verfahren zur herstellung von polyolefinen, polydienen und deren copolymerisaten
JPS62267305A (ja) * 1986-05-15 1987-11-20 Sumitomo Chem Co Ltd オレフイン重合体の製造法
US4767735A (en) * 1987-02-02 1988-08-30 Cosden Technology, Inc. Catalyst pretreatment process
US4812432A (en) * 1987-03-31 1989-03-14 Union Carbide Corporation Ethylene polymerization catalyst
US4810761A (en) * 1987-03-31 1989-03-07 Union Carbide Corporation Ethylene polymerization catalyst
US5034365A (en) * 1990-05-09 1991-07-23 Quantum Chemical Corporation Silica supported polymerization catalyst
US5143883A (en) * 1987-09-21 1992-09-01 Quantum Chemical Corporation Modified silica based catalyst
US5098969A (en) * 1987-09-21 1992-03-24 Quantum Chemical Corporation Propylene polymerization using modified silica based catalyst
US5145821A (en) * 1990-05-09 1992-09-08 Quantum Chemical Corporation Silica supported polymerization catalyst system
FI83330C (fi) * 1988-06-03 1991-06-25 Neste Oy Foerfarande foer aktivering av en polymerisationskatalysatorbaerare och en medelst foerfarandet erhaollen katalysatorkomponent.
JP2717723B2 (ja) * 1989-07-17 1998-02-25 日本石油株式会社 ポリオレフィンの製造方法
JP2566829B2 (ja) * 1989-08-03 1996-12-25 日本石油株式会社 ポリオレフィンの製造方法
CA2029639C (en) * 1989-11-13 2002-06-18 Akira Sano Process for preparing polyolefins
JP2678947B2 (ja) * 1990-03-02 1997-11-19 日本石油株式会社 ポリオレフィンの製造方法
US5037789A (en) * 1990-03-23 1991-08-06 Quantum Chemical Corporation Non-supported catalyst
US5232998A (en) * 1990-05-09 1993-08-03 Quantum Chemical Corporation Olefin polymerization using silica supported catalyst
JP2814310B2 (ja) * 1990-12-27 1998-10-22 日本石油株式会社 ポリオレフィンの製造方法
JP2984945B2 (ja) 1991-02-22 1999-11-29 日石三菱株式会社 ポリオレフィンの製造方法
JP2984947B2 (ja) * 1991-04-02 1999-11-29 日石三菱株式会社 ポリオレフィンの製造方法
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1252129B (it) * 1991-11-22 1995-06-05 Himont Inc Componenti a catalizzatori sferici per la polimerizzazione di olefine
IT1262933B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1256648B (it) 1992-12-11 1995-12-12 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US5424263A (en) * 1993-04-23 1995-06-13 Quantum Chemical Corporation Supported polymerization catalyst
IT1264679B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori per la (co)polimerizzazione di etilene
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
IT1274469B (it) * 1995-05-11 1997-07-17 Spherilene Spa Composizioni poliolefiniche vulcanizzabili dinamicamente
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
IT1292108B1 (it) 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1292109B1 (it) 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1292107B1 (it) * 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
WO1999011677A1 (en) 1997-09-03 1999-03-11 Montell Technology Company B.V. Components and catalysts for the polymerization of olefins
JP3406488B2 (ja) * 1997-09-05 2003-05-12 東京エレクトロン株式会社 真空処理装置
BR9904849B1 (pt) 1998-03-05 2009-01-13 homopolÍmero ou copolÍmero de poli(buteno-1), artigos manufaturados, tubos, e processo para a preparaÇço de homopolÍmeros ou copolÍmeros de poli(buteno-1).
ES2198098T3 (es) 1998-03-09 2004-01-16 Basell Poliolefine Italia S.P.A. Procedimiento multietapas para la polimerizacion de olefinas.
ES2232127T3 (es) 1998-03-23 2005-05-16 Basell Poliolefine Italia S.P.A. Componentes cataliticos prepolimerizados para la polimerizacion de olefinas.
KR100530978B1 (ko) 1998-05-06 2005-11-24 바셀 테크놀로지 캄파니 비이브이 올레핀 중합용 촉매 성분
CN1146585C (zh) 1998-11-04 2004-04-21 蒙特尔技术有限公司 用于烯烃聚合的催化剂组分和催化剂
WO2000053646A1 (en) 1999-03-09 2000-09-14 Basell Technology Company B.V. Multi-stage process for the (co)polymerization of olefins
DE60029399T2 (de) 1999-03-15 2007-07-19 Basell Poliolefine Italia S.R.L. Komponente und katalysator für die polymerisation von olefinen
HUP0103083A3 (en) * 1999-04-15 2003-01-28 Basell Technology Co Bv Components and catalysts for the polymerization of olefins
HUP0202584A3 (en) 1999-09-10 2003-10-28 Basell Technology Co Bv Catalyst for the polymerization of olefins
US6436864B1 (en) 1999-10-06 2002-08-20 Sri International Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
AU2849701A (en) 2000-02-02 2001-08-14 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
AU5620301A (en) 2000-03-22 2001-10-03 Basell Technology Company B.V. Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof
ES2330192T3 (es) 2000-05-12 2009-12-07 Basell Poliolefine Italia S.R.L. Componentes catalizadores pre-polimerizados, para la polimerizacion de olefinas.
CN1119354C (zh) 2000-05-19 2003-08-27 中国石油化工集团公司 一种氯化镁－醇载体及其制备的烯烃聚合催化剂组分
AU781278B2 (en) 2000-10-13 2005-05-12 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefins
JP2002173504A (ja) 2000-11-29 2002-06-21 Basell Technology Co Bv オレフィン重合用触媒およびオレフィン重合方法
EP1368392A1 (en) * 2001-03-15 2003-12-10 Basell Poliolefine Italia S.p.A. Process for the (co)polymerization of ethylene
ATE434629T1 (de) * 2001-06-26 2009-07-15 Basell Poliolefine Srl Verfahren zur herstellung von katalysator- komponenten für die olefinpolymerisation
US7365137B2 (en) * 2001-07-17 2008-04-29 Basell Polyolefine Gmbh Multistep process for the (co) polymerization of olefins
US7015170B2 (en) * 2001-09-13 2006-03-21 Basell Poliolefine Italia S.R.L. Components and catalysts for the polymerization of olefins
MY136330A (en) * 2001-12-12 2008-09-30 Basell Poliolefine Spa Process for the polymerization of olefins
RU2315063C2 (ru) * 2002-05-29 2008-01-20 Базелль Полиолефин Италия С.П.А. (co)полимеры бутена-1, трубы, полученные из них, и способ получения (со)полимеров бутена-1
CN100354356C (zh) * 2002-06-26 2007-12-12 巴塞尔聚烯烃意大利有限公司 抗冲击聚烯烃组合物
EP1517954B1 (en) * 2002-06-26 2014-05-28 Basell Poliolefine Italia S.r.l. Impact-resistant polyolefin compositions
US7005487B2 (en) * 2002-07-02 2006-02-28 Basell Poliolefine Italia S.R.L. Catalyst system for the polymerization of olefins
CA2492939A1 (en) * 2002-08-01 2004-02-12 Basell Poliolefine Italia S.P.A. Highly stereoregular polypropylene with improved properties
CA2506650A1 (en) * 2002-11-28 2004-06-10 Basell Poliolefine Italia S.P.A. Butene-1 copolymers and process for their preparation
WO2004055065A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefins
US20080132661A1 (en) * 2003-03-06 2008-06-05 Basell Polyolefine Gmbh Catalyst System for the Polymerization of Olefins
TW200427763A (en) * 2003-04-03 2004-12-16 Basell Poliolefine Spa Impact resistant polyolefin compositions
KR101167538B1 (ko) * 2003-05-29 2012-07-20 바셀 폴리올레핀 이탈리아 에스.알.엘 촉매 성분의 제조 방법 및 그로부터 수득된 성분들
EP1518866A1 (en) * 2003-09-29 2005-03-30 Basell Poliolefine Italia S.P.A. Process for the preparation of porous ethylene polymers
CN1871266B (zh) * 2003-10-28 2012-05-09 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的组分和催化剂
ATE520737T1 (de) * 2003-11-06 2011-09-15 Basell Poliolefine Srl Polypropylenzusammensetzung
CA2549891C (en) * 2003-12-19 2012-01-31 Basell Polyolefine Gmbh Process for the (co)polymerization of ethylene
WO2005097841A1 (en) 2004-04-02 2005-10-20 Basell Poliolefine Italia S.R.L. Components and catalysts for the polymerization of olefins
WO2005113672A1 (en) * 2004-05-21 2005-12-01 Basell Poliolefine Italia S.R.L. Impact resistant polyolefin compositions
CN100431813C (zh) * 2004-05-31 2008-11-12 丽水市吉丽斯纺织材料有限公司 一种纳米浆料的组合物及其制备方法
PL1753813T3 (pl) * 2004-06-08 2008-03-31 Basell Poliolefine Italia Srl Kompozycja poliolefinowa mająca wysokie zrównoważenie sztywności, udarności i wydłużenia przy zerwaniu oraz niskiego skurczu termicznego
CN100519592C (zh) * 2004-06-16 2009-07-29 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分和催化剂
JP2008510056A (ja) * 2004-08-18 2008-04-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ チーグラー−ナッタプロピレンポリマー組成物からの延伸ブロー成形容器
EP1778782B1 (en) * 2004-08-18 2009-02-25 Basell Poliolefine Italia S.r.l. Process for producing clear polypropylene based stretch blow molded containers with improved infrared heat-up rates
WO2006037705A1 (en) * 2004-10-04 2006-04-13 Basell Poliolefine Italia S.R.L. Elastomeric polyolefin compositions
PL1805231T3 (pl) * 2004-10-18 2010-08-31 Basell Poliolefine Italia Srl (Ko)polimery butenu-1 o niskiej izotaktyczności
KR101216434B1 (ko) * 2004-10-21 2012-12-28 바젤 폴리올레핀 게엠베하 1-부텐 중합체 및 그 제조 방법
EP1827673B1 (en) * 2004-12-20 2012-02-01 Basell Poliolefine Italia S.r.l. Process and apparatus for the polymerization of propylene
JP5231808B2 (ja) * 2004-12-21 2013-07-10 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン組成物およびその通気性フィルム
US7795352B2 (en) * 2004-12-23 2010-09-14 Basell Poliolefine Italia S.R.L. Polyolefinic compositions having good whitening resistance
US7410412B2 (en) 2005-01-21 2008-08-12 Black & Decker Inc. Belt sander
US7235005B2 (en) 2005-03-24 2007-06-26 Black & Decker Inc. Belt sander
US7837537B2 (en) 2005-03-24 2010-11-23 Black & Decker Inc. Belt sander
EP1883677B1 (en) 2005-05-27 2009-12-02 Basell Poliolefine Italia S.r.l. Polyolefinic compositions having good whitening resistance
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
ATE430168T1 (de) * 2005-11-15 2009-05-15 Basell Poliolefine Srl Propylen-ethylen-copolymere und herstellungsverfahren dafür
US20090156391A1 (en) * 2005-12-06 2009-06-18 Basell Poliolefine Italia S.R.L. Catalyst Components for the Polymerization of Olefins
US20070213204A1 (en) * 2006-03-10 2007-09-13 Novolen Technology Holdings C.V. Ziegler-Natta catalyst with in situ-generated donor
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
ATE556096T1 (de) * 2006-08-08 2012-05-15 Basell Poliolefine Srl Buten-1-copolymere
JP5595733B2 (ja) * 2006-11-23 2014-09-24 サンアロマー株式会社 ポリオレフィン組成物
ATE482982T1 (de) * 2007-04-27 2010-10-15 Basell Poliolefine Srl Buten-1-terpolymere und herstellungsverfahren dafür
CN101323650B (zh) * 2007-06-13 2010-11-03 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备方法和应用
EP2167570A1 (en) 2007-06-29 2010-03-31 Basell Poliolefine Italia S.R.L. An irradiated polyolefin composition comprising a non - phenolic stabilizer
JP2011506718A (ja) * 2007-12-20 2011-03-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 改良された特性を有する高立体規則性ポリプロピレン
EP2225324B1 (en) * 2007-12-24 2016-12-14 Basell Poliolefine Italia S.r.l. Polyolefin fibres
CN101910208B (zh) * 2007-12-28 2012-09-19 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分
EP2247424B1 (en) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefin compositions
EP2315786A1 (en) * 2008-08-20 2011-05-04 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
WO2010026091A1 (en) * 2008-09-04 2010-03-11 Basell Poliolefine Italia S.R.L. Process for the gas-phase polymerization of olefins
US20110152480A1 (en) * 2008-09-08 2011-06-23 Basell Poliolefine Italia S.R.L. Catalysts for Polymerizing Olefins and Method Thereof
RU2493175C2 (ru) 2008-09-26 2013-09-20 Базелль Полиолефин Италия С.Р.Л. Каталитические компоненты для полимеризации олефинов
EP2194070B1 (en) 2008-12-03 2012-08-22 Süd-Chemie IP GmbH & Co. KG Electron donor composition for a solid catalyst, solid catalyst composition used in the polymerisation of alpha-olefins, and process for the production of a polymer consisting of alpha-olefin units using the solid catalyst composition
KR20110110260A (ko) * 2008-12-29 2011-10-06 다우 글로벌 테크놀로지스 엘엘씨 인-기재 공여체를 갖는 촉매 조성물
US7935740B2 (en) 2008-12-30 2011-05-03 Basell Poliolefine Italia S.R.L. Process for producing high melt strength polypropylene
EP2419461A1 (en) 2009-04-16 2012-02-22 Basell Poliolefine Italia S.R.L. Process for the preparation of polymer of 1-butene
CN107043491A (zh) 2009-06-19 2017-08-15 巴塞尔聚烯烃意大利有限责任公司 制备抗冲击性丙烯聚合物组合物的方法
CN102459453B (zh) 2009-06-26 2013-07-31 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
JP5607155B2 (ja) 2009-07-14 2014-10-15 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ １−ブテンポリマーの製造法
CN102575074B (zh) 2009-07-31 2013-11-20 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102471550B (zh) 2009-07-31 2014-03-12 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102666680B (zh) 2009-09-24 2015-06-24 巴塞尔聚烯烃意大利有限责任公司 热封聚烯烃膜
WO2011039314A1 (en) 2009-09-29 2011-04-07 Basell Poliolefine Italia Srl Heat-sealable polyolefin films
US20110082268A1 (en) 2009-10-02 2011-04-07 Sandor Nagy Indazole-modified ziegler-natta catalyst system
US20110082270A1 (en) * 2009-10-02 2011-04-07 Sandor Nagy Pyridazine-modified ziegler-natta catalyst system
US7871952B1 (en) 2009-10-02 2011-01-18 Equistar Chemicals, Lp 2-hydroxypyridine N-oxide-modified ziegler-natta catalyst system
US8017708B2 (en) 2009-10-02 2011-09-13 Equistar Chemicals, Lp Nitroso-modified Ziegler-Natta catalyst system
US9068029B2 (en) 2009-11-19 2015-06-30 Basell Poliolefine Italia S.R.L. Process for the preparation of impact resistant propylene polymer compositions
CN102666713B (zh) 2009-12-23 2014-11-26 巴塞尔聚烯烃意大利有限责任公司 用于注塑排水系统的聚烯烃组合物
ES2470146T3 (es) 2010-03-04 2014-06-23 Basell Poliolefine Italia S.R.L. Componentes de catalizador para la polimerizaci�n de olefinas
US8835578B2 (en) 2010-03-04 2014-09-16 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
BR112012033011B1 (pt) 2010-06-24 2020-05-26 Basell Poliolefine Italia S.R.L. Sistema catalisador e processo para polimerizar olefinas utilizando tal sistema
US20130131293A1 (en) 2010-08-05 2013-05-23 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
WO2012017040A1 (en) 2010-08-05 2012-02-09 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
RU2579371C2 (ru) 2010-08-24 2016-04-10 Базелль Полиолефин Италия С.Р.Л. Компоненты катализатора для полимеризации олефинов
US10138310B2 (en) 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
US20120053305A1 (en) 2010-08-24 2012-03-01 Equistar Chemicals, Lp Preparation of LLDPE having controlled xylene solubles or hexane extractables
CN103119071B (zh) 2010-09-28 2016-07-06 巴塞尔聚烯烃股份有限公司 聚乙烯挤出制品
BR112013008076B1 (pt) 2010-10-14 2020-06-09 Basell Poliolefine Italia Srl elemento para o interior automotivo e uso de uma composição de polipropileno
BR112013008900A2 (pt) 2010-10-19 2016-06-28 Basell Poliolefine Srl "sistema da catalisação para a polimerização de olefinas"
WO2012052389A1 (en) 2010-10-19 2012-04-26 Basell Poliolefine Italia S.R.L. Process for the preparation of high purity propylene polymers
BR112013008507A2 (pt) 2010-10-19 2017-10-31 Basell Poliolefine Italia Srl processo para a polimerização de olefinas
US9284475B2 (en) 2010-10-21 2016-03-15 Basell Poliolefine Italia S.R.L. Pressure sensitive adhesive with butene-1 copolymers
WO2012076447A1 (en) 2010-12-07 2012-06-14 Basell Poliolefine Italia S.R.L. Polyolefin based corrugated boards
EP2463413B1 (en) 2010-12-07 2014-01-29 Basell Poliolefine Italia S.r.l. Polyolefin fibres
US20130316213A1 (en) 2011-01-18 2013-11-28 Baseell Poliolefine Italia S.r.l. Polyolefin composition
ES2624923T3 (es) 2011-04-12 2017-07-18 Basell Poliolefine Italia S.R.L. Componentes catalizadores para la polimerización de olefinas
CN102746426A (zh) 2011-04-22 2012-10-24 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备和应用
EP2718335B1 (en) 2011-06-09 2020-01-22 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
KR101855066B1 (ko) 2011-06-24 2018-06-25 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
CN103635495B (zh) 2011-07-01 2016-06-22 巴塞尔聚烯烃意大利有限责任公司 聚丙烯膜和片材
US9000097B2 (en) 2011-07-07 2015-04-07 Basell Poliolefine Italia S.R.L. Polypropylene composition
US10221261B2 (en) 2011-09-23 2019-03-05 Basell Poliolefine Italia S.R.L. Process for the preparation of high purity propylene polymers
EP2583983A1 (en) 2011-10-19 2013-04-24 Basell Poliolefine Italia S.r.l. Catalyst component for the polymerization of olefins
EP2583985A1 (en) 2011-10-19 2013-04-24 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2583999A1 (en) 2011-10-20 2013-04-24 Basell Poliolefine Italia S.r.l. Polyolefin compositions
EP2594593A1 (en) 2011-11-17 2013-05-22 Basell Poliolefine Italia S.r.l. Process for the preparation of heterophasic propylene polymer compositions
EP2607384A1 (en) 2011-12-21 2013-06-26 Basell Poliolefine Italia S.r.l. Catalyst system for the polymerization of olefins
EP2607387A1 (en) 2011-12-23 2013-06-26 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
EP2607386A1 (en) 2011-12-23 2013-06-26 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
EP2636687A1 (en) 2012-03-07 2013-09-11 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2666792A1 (en) 2012-05-23 2013-11-27 Basell Poliolefine Italia S.r.l. Catalyst component for the polymerization of olefins
EP2671894A1 (en) 2012-06-08 2013-12-11 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of butene-1
EP2682505A1 (en) 2012-07-06 2014-01-08 Basell Poliolefine Italia S.r.l. Polypropylene fiber
EP2712875A1 (en) 2012-09-28 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2722348A1 (en) 2012-10-16 2014-04-23 Basell Poliolefine Italia S.r.l. Process for the preparation of propylene random copolymers
EP2738213A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
EP2738212A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
KR102008590B1 (ko) 2012-10-22 2019-08-07 바젤 폴리올레핀 게엠베하 우수한 기계적 성질을 가진 폴리에틸렌 조성물
EP2738211A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
BR112015008932B1 (pt) 2012-10-22 2021-03-30 Basell Polyolefine Gmbh Composição de polietileno, artigos manufaturados compreendendo a mesma e processo para sua preparação
JP6062056B2 (ja) 2012-10-22 2017-01-18 バーゼル・ポリオレフィン・ゲーエムベーハー 高いスウェル比を有するポリエチレン組成物
EP2743073A1 (en) 2012-12-12 2014-06-18 Basell Poliolefine Italia S.r.l. Propylene-based terpolymers
EP2754678A1 (en) 2013-01-14 2014-07-16 Basell Poliolefine Italia S.r.l. Process for the preparation of ethylene polymers
EP2757114A1 (en) 2013-01-18 2014-07-23 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2961779B1 (en) 2013-02-27 2019-05-08 Basell Polyolefine GmbH Polyethylene processes and compositions thereof
WO2014139811A2 (en) 2013-03-15 2014-09-18 Basell Poliolefine Italia S.R.L. Process for the preparation of propylene terpolymers and terpolymers obtained thereby
EP2792692A1 (en) 2013-04-17 2014-10-22 Basell Poliolefine Italia S.r.l. Nucleated propylene-based polyolefin compositions
EP2803678A1 (en) 2013-05-14 2014-11-19 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2803679A1 (en) 2013-05-17 2014-11-19 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2816062A1 (en) 2013-06-18 2014-12-24 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
EP2818508A1 (en) 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition having high impact and stress cracking resistance
EP2818509A1 (en) 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition for blow molding having high stress cracking resistance
EP2829557A1 (en) 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Sterilisable article made of propylene copolymer
EP2829397A1 (en) 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Heat sealable polyolefin films and sheets
WO2015059117A1 (en) 2013-10-24 2015-04-30 Basell Poliolefine Italia S.R.L. Process for the preparation of porous propylene polymers
EP3161066B1 (en) 2014-06-24 2020-11-18 Basell Polyolefine GmbH Polyethylene composition for injection moulding
CN107406541B (zh) 2015-03-10 2020-03-31 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂组分
WO2016142377A1 (en) 2015-03-12 2016-09-15 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
RU2661873C1 (ru) 2015-04-01 2018-07-20 Базелл Полиолефин Италия С.Р.Л. Компоненты катализатора для полимеризации олефинов
EP3298048B1 (en) 2015-05-19 2019-07-03 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CN107849317B (zh) 2015-06-26 2020-05-05 巴塞尔聚烯烃股份有限公司 具有高机械性能和可加工性的聚乙烯组合物
EP3313932B1 (en) 2015-06-26 2021-11-17 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties and processability
JP6554563B2 (ja) 2015-06-26 2019-07-31 バーゼル・ポリオレフィン・ゲーエムベーハー フィルム用ポリエチレン組成物
EP3331926B1 (en) 2015-08-04 2023-05-31 Basell Poliolefine Italia S.r.l. Prepolymerized catalyst components for the polymerization of olefins
ES2978633T3 (es) 2016-11-17 2024-09-17 Basell Polyolefine Gmbh Composición de polietileno que presenta una elevada relación de hinchamiento
CN109890852B (zh) 2016-11-18 2020-10-20 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂组分
CN109963881B (zh) 2016-11-24 2021-08-17 巴塞尔聚烯烃股份有限公司 具有高膨胀比和高抗冲击性的用于吹塑的聚乙烯组合物
CN109963879B (zh) 2016-11-24 2021-06-11 巴塞尔聚烯烃股份有限公司 具有高抗应力开裂性的用于吹塑的聚乙烯组合物
MX2019005749A (es) 2016-11-24 2019-08-12 Basell Polyolefine Gmbh Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta.
WO2019231986A1 (en) * 2018-06-01 2019-12-05 Dow Global Technologies Llc Ziegler-natta catalyst with an electron donor compound for increasing polymer molecular weight
JP2021527753A (ja) 2018-09-20 2021-10-14 バーゼル・ポリオレフィン・ゲーエムベーハー フィルム用ポリエチレン組成物
MY209414A (en) 2018-10-19 2025-07-08 Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp Catalyst component and catalyst for olefin polymerization, and application thereof
WO2020120227A1 (en) 2018-12-14 2020-06-18 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
ES2980461T3 (es) 2019-07-03 2024-10-01 Basell Poliolefine Italia Srl Componentes catalíticos para la polimerización de olefinas
EP4069754A1 (en) 2019-12-04 2022-10-12 Basell Poliolefine Italia S.r.l. Catalysts for the polymerization of olefins
CN115698166B (zh) 2020-06-30 2023-09-05 巴塞尔聚烯烃意大利有限公司 聚丙烯组合物
CN116194520B (zh) 2020-07-31 2025-05-13 巴塞尔聚烯烃意大利有限公司 具有短结晶时间的丁烯-1聚合物组合物
CN116209686B (zh) 2020-10-19 2024-01-26 巴塞尔聚烯烃意大利有限公司 聚丙烯组合物
US20240034870A1 (en) 2020-12-16 2024-02-01 Basell Poliolefine Italia S.R.L. Flexible butene-1 copolymer for pipes
JP7749024B2 (ja) 2021-04-06 2025-10-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用予備重合触媒成分
US20240209125A1 (en) 2021-04-16 2024-06-27 Basell Poliolefine Italia S.R.L. Prepolymerized catalyst components for the polymerization of olefins
EP4367170A1 (en) 2021-07-09 2024-05-15 Basell Poliolefine Italia S.r.l. Use of random propylene ethylene copolymers for biaxially oriented films
CN117642435A (zh) 2021-07-23 2024-03-01 巴塞尔聚烯烃股份有限公司 具有高溶胀比、抗冲击性和拉伸模量的用于吹塑的聚乙烯组合物
WO2023046535A1 (en) 2021-09-27 2023-03-30 Basell Poliolefine Italia S.R.L. Propylene polymer composition
EP4413054B1 (en) 2021-10-06 2025-11-26 Basell Poliolefine Italia S.r.l. Polypropylene composition
CN118284659A (zh) 2021-12-21 2024-07-02 巴塞尔聚烯烃意大利有限公司 制备具有提高的结晶温度的聚丁烯组合物的工艺
KR20250073335A (ko) 2022-09-27 2025-05-27 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
CN120712294A (zh) 2023-03-17 2025-09-26 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂组分
CN121127504A (zh) 2023-05-15 2025-12-12 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂组分
US20250043049A1 (en) 2023-08-01 2025-02-06 Basell Polyolefine Gmbh Polyethylene processes and compositions thereof
WO2025056419A1 (en) 2023-09-12 2025-03-20 Basell Poliolefine Italia S.R.L. Polypropylene composition

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA703847A (en) * 1965-02-16 Union Carbide Corporation Titanium catalyst and use for producing linear polyolefins of high molecular weight
IT557942A (cg-RX-API-DMAC10.html) * 1922-08-26
US3058963A (en) * 1955-04-07 1962-10-16 Hercules Powder Co Ltd Process for polymerizing olefins
BE552550A (cg-RX-API-DMAC10.html) * 1955-11-15
US2981725A (en) * 1955-11-16 1961-04-25 Shell Oil Co Process for polymerizing olefins
BE580006A (cg-RX-API-DMAC10.html) * 1958-06-27
BE584091A (cg-RX-API-DMAC10.html) * 1958-10-30
NL253870A (cg-RX-API-DMAC10.html) * 1959-07-15 1900-01-01
US3482935A (en) * 1959-11-02 1969-12-09 Monsanto Co Delta titanium trichloride
FR1291788A (fr) * 1960-03-21 1962-04-27 Shell Int Research Procédé de préparation de nouveaux catalyseurs de polymérisation
US3238146A (en) * 1960-03-21 1966-03-01 Shell Oil Co Catalysts and their preparation
US3130003A (en) * 1960-04-01 1964-04-21 Exxon Research Engineering Co Cocrystallized catalyst preparation process
NL269851A (cg-RX-API-DMAC10.html) * 1960-10-03
US3400110A (en) * 1963-08-01 1968-09-03 Solvay Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal
NL130788C (cg-RX-API-DMAC10.html) * 1963-12-23
NL135604C (cg-RX-API-DMAC10.html) * 1965-06-25
NL270655A (cg-RX-API-DMAC10.html) * 1966-03-23
FR1516800A (fr) * 1966-10-21 1968-03-15 Solvay Procédé de polymérisation et copolymérisation d'oléfines.
NL137364C (cg-RX-API-DMAC10.html) * 1968-03-22
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4336360A (en) 1971-06-25 1982-06-22 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha-olefins

Also Published As

Publication number Publication date
BE742003A (cg-RX-API-DMAC10.html) 1970-05-20
GB1292853A (en) 1972-10-18
DE1958046A1 (de) 1970-06-25
AT292299B (de) 1971-08-25
IL33378A0 (en) 1970-01-29
DE1958046B2 (de) 1973-01-25
FR2023789A1 (cg-RX-API-DMAC10.html) 1970-08-21
DK133012C (da) 1976-08-09
CS150994B2 (cg-RX-API-DMAC10.html) 1973-09-17
DK133012B (da) 1976-03-08
IL33378A (en) 1973-06-29
YU34622B (en) 1979-12-31
SU403194A3 (cg-RX-API-DMAC10.html) 1973-10-19
ES373699A1 (es) 1972-02-01
BR6914363D0 (pt) 1973-01-04
US4495338A (en) 1985-01-22
RO75486A (ro) 1980-11-30
SE363977B (cg-RX-API-DMAC10.html) 1974-02-11
YU289669A (en) 1979-07-10
NL162661B (nl) 1980-01-15
PL77395B1 (cg-RX-API-DMAC10.html) 1975-04-30
NL6917308A (cg-RX-API-DMAC10.html) 1970-05-25

Similar Documents

Publication Publication Date Title
DE1958046C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung
DE1958488C3 (de) Polymerisationskatalysatoren, ihre Herstellung und Verwendung
DE2135884C2 (de) Verfahren zur Polymerisation von Äthylen oder dessen Gemischen mit α-Olefinen und/oder Diolefinen
DE2660216C2 (de) Feste Katalysatorkomponente zur Polymerisation von α-Olefinen
DE2137872C2 (de) Verfahren zur Polymerisation von Äthylen oder dessen Gemischen mit α-Olefinen und/oder Diolefinen
DE2735672C2 (cg-RX-API-DMAC10.html)
DE2153520C2 (de) Verfahren zur Polymerisation von α-Olefinen mit 3-6 Kohlenstoffatomen zu überwiegend isotaktischen Polymeren
DE2029992C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren
DE2150437C3 (de) Verfahren zur Herstellung von Copolymerisaten aus Äthylen und Propylen
DE2013730C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung
DE3117588C2 (cg-RX-API-DMAC10.html)
DE69408649T2 (de) Katalysator für die Herstellung von Elastomeren Ethylenpropylen Copolymeren
DE2533511A1 (de) Verfahren zur herstellung von festem titantrichlorid und dessen verwendung als katalysator zur polymerisation von alpha-olefinen
DE2225690A1 (de) Verfahren zur Polymerisation von Propylen
DE2030753C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren
DE2630619A1 (de) Verfahren zur herstellung einer katalysatorkomponente zur polymerisation von alpha-olefinen
DE2037603C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung
DE2000585C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung
DE2263124C2 (de) Verfahren zur Herstellung von Ziegler-Natta-Katalysatoren die zur Polymerisation von Äthylen oder Propylen sowie zur Copolymerisation von Äthylen mit Propylen oder 1-Buten geeignet sind
DE2125107C2 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung zur Polymerisation von Äthylen
DE1442528C3 (de) Katalysator zum Polymerisieren von alpha-Olefinen und Verfahren zu seiner Herstellung
DE2218363C3 (de) Verfahren zur Polymerisation von a-Olefinen
DE2832440C2 (cg-RX-API-DMAC10.html)
DE2013008C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren
DE2033468C3 (de) Verfahren zur Herstellung von Polymerisationskatalysatoren

Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)