CN103140511B - 弹性的湿气可渗透的薄膜、其制备和其用途 - Google Patents
弹性的湿气可渗透的薄膜、其制备和其用途 Download PDFInfo
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- CN103140511B CN103140511B CN201180047105.7A CN201180047105A CN103140511B CN 103140511 B CN103140511 B CN 103140511B CN 201180047105 A CN201180047105 A CN 201180047105A CN 103140511 B CN103140511 B CN 103140511B
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- Prior art keywords
- block
- block copolymer
- polymer
- thin film
- sulfonation
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- 239000010409 thin film Substances 0.000 title claims abstract description 110
- 238000002360 preparation method Methods 0.000 title description 13
- 229920001400 block copolymer Polymers 0.000 claims abstract description 135
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 113
- 238000000576 coating method Methods 0.000 claims abstract description 86
- 239000011248 coating agent Substances 0.000 claims abstract description 84
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000010408 film Substances 0.000 claims abstract description 53
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims abstract description 33
- 238000007306 functionalization reaction Methods 0.000 claims abstract description 30
- 125000000524 functional group Chemical group 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims description 233
- 239000000203 mixture Substances 0.000 claims description 125
- -1 sulphonic acid ester Chemical class 0.000 claims description 107
- 239000006185 dispersion Substances 0.000 claims description 77
- 239000000178 monomer Substances 0.000 claims description 75
- 229920006132 styrene block copolymer Polymers 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 53
- 238000006116 polymerization reaction Methods 0.000 claims description 50
- 150000001993 dienes Chemical class 0.000 claims description 39
- 239000007791 liquid phase Substances 0.000 claims description 37
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- 239000005977 Ethylene Substances 0.000 claims description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 23
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 20
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 20
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 9
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
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- 238000009941 weaving Methods 0.000 claims description 4
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 28
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- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 15
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 15
- 238000004448 titration Methods 0.000 description 15
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- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 14
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
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- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 8
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2535/00—Medical equipment, e.g. bandage, prostheses, catheter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2139—Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US12/893,145 US9394414B2 (en) | 2010-09-29 | 2010-09-29 | Elastic, moisture-vapor permeable films, their preparation and their use |
US12/893,145 | 2010-09-29 | ||
PCT/US2011/052113 WO2012050740A1 (en) | 2010-09-29 | 2011-09-19 | Elastic, moisture-vapor permeable films, their preparation and their use |
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CN103140511A CN103140511A (zh) | 2013-06-05 |
CN103140511B true CN103140511B (zh) | 2016-08-24 |
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US (1) | US9394414B2 (pt) |
EP (1) | EP2621966B1 (pt) |
JP (1) | JP6218606B2 (pt) |
KR (1) | KR20130080045A (pt) |
CN (1) | CN103140511B (pt) |
BR (1) | BR112013007136A2 (pt) |
RU (1) | RU2564017C2 (pt) |
TW (1) | TWI591084B (pt) |
WO (1) | WO2012050740A1 (pt) |
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US10988630B2 (en) * | 2014-12-19 | 2021-04-27 | Certainteed Corporation | Coating compositions for building materials and coated building material substrates |
EP3178873A1 (en) * | 2015-12-08 | 2017-06-14 | ETH Zurich | Waterproof and breathable, porous membranes |
TWI558764B (zh) * | 2015-12-23 | 2016-11-21 | 財團法人紡織產業綜合研究所 | 高分子組成物及其製成的高透濕彈性膜和具有封閉孔洞的高分子材料 |
CN106633587B (zh) * | 2016-12-01 | 2018-09-25 | 新疆天利高新石化股份有限公司 | 一种柔软耐磨鞋材专用料及其制备方法 |
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KR102379593B1 (ko) * | 2018-03-30 | 2022-03-29 | 주식회사 엘지화학 | 블록 공중합체 조성물 |
EP3738743A1 (en) * | 2019-05-13 | 2020-11-18 | Henkel AG & Co. KGaA | Radiation curable and printable composition |
CN110681269B (zh) * | 2019-11-20 | 2022-04-22 | 宁波建嵘科技有限公司 | 一种两级涂覆异质同步复合膜制备装置 |
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CN103140511A (zh) | 2013-06-05 |
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TWI591084B (zh) | 2017-07-11 |
US20120077400A1 (en) | 2012-03-29 |
US9394414B2 (en) | 2016-07-19 |
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