JP2001522903A5 - - Google Patents

Info

Publication number

JP2001522903A5

JP2001522903A5 JP2000520485A JP2000520485A JP2001522903A5 JP 2001522903 A5 JP2001522903 A5 JP 2001522903A5 JP 2000520485 A JP2000520485 A JP 2000520485A JP 2000520485 A JP2000520485 A JP 2000520485A JP 2001522903 A5 JP2001522903 A5 JP 2001522903A5

Authority

JP

Japan

Prior art keywords

catalyst

reactor

polymerization

propylene

compound

Prior art date

1998-11-09

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

Links

• Espacenet
• Global Dossier
• Discuss

• 239000003054 catalyst Substances 0.000 description 80
• 238000000034 method Methods 0.000 description 62
• -1 vinyl compound Chemical group 0.000 description 55
• 238000006116 polymerization reaction Methods 0.000 description 51
• 229920000642 polymer Polymers 0.000 description 38
• 229920002554 vinyl polymer Polymers 0.000 description 34
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 31
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 31
• 239000007789 gas Substances 0.000 description 22
• 239000000203 mixture Substances 0.000 description 22
• 229920001155 polypropylene Polymers 0.000 description 22
• 239000000047 product Substances 0.000 description 20
• 239000004743 Polypropylene Substances 0.000 description 15
• 229920001577 copolymer Polymers 0.000 description 15
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 14
• 239000005977 Ethylene Substances 0.000 description 14
• 238000012986 modification Methods 0.000 description 13
• 230000004048 modification Effects 0.000 description 13
• 230000008569 process Effects 0.000 description 13
• 239000000843 powder Substances 0.000 description 12
• 239000000654 additive Substances 0.000 description 11
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
• 238000002425 crystallisation Methods 0.000 description 10
• 230000008025 crystallization Effects 0.000 description 10
• 229920001971 elastomer Polymers 0.000 description 10
• 239000000806 elastomer Substances 0.000 description 10
• 239000000049 pigment Substances 0.000 description 10
• 239000000454 talc Substances 0.000 description 10
• 229910052623 talc Inorganic materials 0.000 description 10
• 239000011345 viscous material Substances 0.000 description 10
• 150000001875 compounds Chemical class 0.000 description 9
• 238000004519 manufacturing process Methods 0.000 description 9
• 239000003921 oil Substances 0.000 description 9
• 239000012429 reaction media Substances 0.000 description 9
• 239000002667 nucleating agent Substances 0.000 description 8
• 239000002002 slurry Substances 0.000 description 8
• 239000007787 solid Substances 0.000 description 8
• 150000003609 titanium compounds Chemical class 0.000 description 7
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
• 239000012190 activator Substances 0.000 description 6
• 239000001257 hydrogen Substances 0.000 description 6
• 229910052739 hydrogen Inorganic materials 0.000 description 6
• 239000000178 monomer Substances 0.000 description 6
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
• 230000006911 nucleation Effects 0.000 description 6
• 238000010899 nucleation Methods 0.000 description 6
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
• TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
• 230000000996 additive effect Effects 0.000 description 5
• 229910052782 aluminium Inorganic materials 0.000 description 5
• 239000007795 chemical reaction product Substances 0.000 description 5
• 239000003426 co-catalyst Substances 0.000 description 5
• JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical group C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 5
• LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 5
• 239000000945 filler Substances 0.000 description 5
• 238000002844 melting Methods 0.000 description 5
• 230000008018 melting Effects 0.000 description 5
• 239000012968 metallocene catalyst Substances 0.000 description 5
• 238000002156 mixing Methods 0.000 description 5
• 229910052757 nitrogen Inorganic materials 0.000 description 5
• 150000003623 transition metal compounds Chemical class 0.000 description 5
• 239000008096 xylene Substances 0.000 description 5
• OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
• ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
• 125000004429 atom Chemical group 0.000 description 4
• 125000004432 carbon atom Chemical group C* 0.000 description 4
• 238000007334 copolymerization reaction Methods 0.000 description 4
• 238000009826 distribution Methods 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
• 229910052732 germanium Inorganic materials 0.000 description 4
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
• NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
• 239000002245 particle Substances 0.000 description 4
• 229910052698 phosphorus Inorganic materials 0.000 description 4
• 239000011574 phosphorus Substances 0.000 description 4
• 230000000379 polymerizing effect Effects 0.000 description 4
• 239000012744 reinforcing agent Substances 0.000 description 4
• 239000010703 silicon Substances 0.000 description 4
• 229910052710 silicon Inorganic materials 0.000 description 4
• 239000010936 titanium Substances 0.000 description 4
• 229910052719 titanium Inorganic materials 0.000 description 4
• 229910052723 transition metal Inorganic materials 0.000 description 4
• 150000003624 transition metals Chemical class 0.000 description 4
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
• 239000002253 acid Substances 0.000 description 3
• 125000001931 aliphatic group Chemical group 0.000 description 3
• 239000003963 antioxidant agent Substances 0.000 description 3
• 125000003118 aryl group Chemical group 0.000 description 3
• 239000006229 carbon black Substances 0.000 description 3
• 238000006243 chemical reaction Methods 0.000 description 3
• 239000003086 colorant Substances 0.000 description 3
• 150000002148 esters Chemical class 0.000 description 3
• 239000012530 fluid Substances 0.000 description 3
• 239000004519 grease Substances 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• 239000007788 liquid Substances 0.000 description 3
• 229910052749 magnesium Inorganic materials 0.000 description 3
• 239000011777 magnesium Substances 0.000 description 3
• 229910001507 metal halide Inorganic materials 0.000 description 3
• 150000005309 metal halides Chemical class 0.000 description 3
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
• 230000003647 oxidation Effects 0.000 description 3
• 238000007254 oxidation reaction Methods 0.000 description 3
• 239000011148 porous material Substances 0.000 description 3
• 150000003658 tungsten compounds Chemical class 0.000 description 3
• JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
• 229920000049 Carbon (fiber) Polymers 0.000 description 2
• 229920003043 Cellulose fiber Polymers 0.000 description 2
• 239000004698 Polyethylene Substances 0.000 description 2
• 229910000831 Steel Inorganic materials 0.000 description 2
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
• 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
• NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 description 2
• 150000001339 alkali metal compounds Chemical class 0.000 description 2
• 150000001341 alkaline earth metal compounds Chemical class 0.000 description 2
• 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
• 230000008901 benefit Effects 0.000 description 2
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
• 230000002902 bimodal effect Effects 0.000 description 2
• 238000000071 blow moulding Methods 0.000 description 2
• 229910052799 carbon Inorganic materials 0.000 description 2
• 239000004917 carbon fiber Substances 0.000 description 2
• 230000003197 catalytic effect Effects 0.000 description 2
• 150000001845 chromium compounds Chemical class 0.000 description 2
• 150000001869 cobalt compounds Chemical class 0.000 description 2
• 238000000748 compression moulding Methods 0.000 description 2
• 230000008602 contraction Effects 0.000 description 2
• 238000001816 cooling Methods 0.000 description 2
• NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 2
• VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 2
• OANIYCQMEVXZCJ-UHFFFAOYSA-N ditert-butyl(dimethoxy)silane Chemical compound CO[Si](OC)(C(C)(C)C)C(C)(C)C OANIYCQMEVXZCJ-UHFFFAOYSA-N 0.000 description 2
• BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
• 239000000835 fiber Substances 0.000 description 2
• 238000001914 filtration Methods 0.000 description 2
• 239000003063 flame retardant Substances 0.000 description 2
• 238000005187 foaming Methods 0.000 description 2
• 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
• 239000003365 glass fiber Substances 0.000 description 2
• 239000012760 heat stabilizer Substances 0.000 description 2
• 125000005842 heteroatom Chemical group 0.000 description 2
• 238000005470 impregnation Methods 0.000 description 2
• 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
• 238000001746 injection moulding Methods 0.000 description 2
• 239000001282 iso-butane Substances 0.000 description 2
• 239000004611 light stabiliser Substances 0.000 description 2
• 239000000314 lubricant Substances 0.000 description 2
• 229910001629 magnesium chloride Inorganic materials 0.000 description 2
• 238000005259 measurement Methods 0.000 description 2
• 239000010445 mica Substances 0.000 description 2
• 229910052618 mica group Inorganic materials 0.000 description 2
• 125000001624 naphthyl group Chemical group 0.000 description 2
• 150000002816 nickel compounds Chemical class 0.000 description 2
• 239000008188 pellet Substances 0.000 description 2
• 238000005453 pelletization Methods 0.000 description 2
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
• 229920013639 polyalphaolefin Polymers 0.000 description 2
• 229920001748 polybutylene Polymers 0.000 description 2
• 229920000573 polyethylene Polymers 0.000 description 2
• 229920000098 polyolefin Polymers 0.000 description 2
• 239000001294 propane Substances 0.000 description 2
• 229920001384 propylene homopolymer Polymers 0.000 description 2
• 150000002909 rare earth metal compounds Chemical class 0.000 description 2
• 239000000376 reactant Substances 0.000 description 2
• 239000011541 reaction mixture Substances 0.000 description 2
• 230000035484 reaction time Effects 0.000 description 2
• 239000000377 silicon dioxide Substances 0.000 description 2
• 239000000243 solution Substances 0.000 description 2
• 239000002904 solvent Substances 0.000 description 2
• 239000010959 steel Substances 0.000 description 2
• 238000003856 thermoforming Methods 0.000 description 2
• XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
• 150000003682 vanadium compounds Chemical class 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• 239000010456 wollastonite Substances 0.000 description 2
• 229910052882 wollastonite Inorganic materials 0.000 description 2
• 229910052726 zirconium Inorganic materials 0.000 description 2
• 150000003755 zirconium compounds Chemical class 0.000 description 2
• VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 2
• SQISRICUGQKXLV-UHFFFAOYSA-N 1-ethenyl-2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1(O)C=C SQISRICUGQKXLV-UHFFFAOYSA-N 0.000 description 1
• FXSUTKNIHXGZFF-UHFFFAOYSA-N 1-ethenyl-2-methylcyclohexane Chemical compound CC1CCCCC1C=C FXSUTKNIHXGZFF-UHFFFAOYSA-N 0.000 description 1
• LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
• YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
• OEGQMCQKZSQYBV-UHFFFAOYSA-N 2-nonan-4-yloxycarbonylbenzoic acid Chemical compound CCCCCC(CCC)OC(=O)C1=CC=CC=C1C(O)=O OEGQMCQKZSQYBV-UHFFFAOYSA-N 0.000 description 1
• OLGHJTHQWQKJQQ-UHFFFAOYSA-N 3-ethylhex-1-ene Chemical compound CCCC(CC)C=C OLGHJTHQWQKJQQ-UHFFFAOYSA-N 0.000 description 1
• YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
• UNUVUYPEOAILGM-UHFFFAOYSA-N 4-ethenylbicyclo[2.2.1]heptane Chemical compound C1CC2CCC1(C=C)C2 UNUVUYPEOAILGM-UHFFFAOYSA-N 0.000 description 1
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
• MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
• ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
• 239000002879 Lewis base Substances 0.000 description 1
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
• 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 1
• NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
• BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
• 230000003213 activating effect Effects 0.000 description 1
• 239000002671 adjuvant Substances 0.000 description 1
• 150000001336 alkenes Chemical class 0.000 description 1
• 125000003545 alkoxy group Chemical group 0.000 description 1
• 125000005234 alkyl aluminium group Chemical group 0.000 description 1
• AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
• 150000001412 amines Chemical class 0.000 description 1
• 238000004458 analytical method Methods 0.000 description 1
• 230000003078 antioxidant effect Effects 0.000 description 1
• 239000002216 antistatic agent Substances 0.000 description 1
• IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
• 238000010923 batch production Methods 0.000 description 1
• BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
• 239000001055 blue pigment Substances 0.000 description 1
• 229910000019 calcium carbonate Inorganic materials 0.000 description 1
• 239000012159 carrier gas Substances 0.000 description 1
• 239000007810 chemical reaction solvent Substances 0.000 description 1
• 229910052804 chromium Inorganic materials 0.000 description 1
• 239000011651 chromium Substances 0.000 description 1
• 239000008395 clarifying agent Substances 0.000 description 1
• 238000013329 compounding Methods 0.000 description 1
• 238000010924 continuous production Methods 0.000 description 1
• XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
• 125000004122 cyclic group Chemical group 0.000 description 1
• SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
• 238000010908 decantation Methods 0.000 description 1
• 238000004925 denaturation Methods 0.000 description 1
• 230000036425 denaturation Effects 0.000 description 1
• 238000013461 design Methods 0.000 description 1
• YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
• 238000000113 differential scanning calorimetry Methods 0.000 description 1
• DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
• DISZQMPRUTYNJL-UHFFFAOYSA-N ditetradecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCC DISZQMPRUTYNJL-UHFFFAOYSA-N 0.000 description 1
• YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
• QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 229920001198 elastomeric copolymer Polymers 0.000 description 1
• 150000002170 ethers Chemical class 0.000 description 1
• 229920001038 ethylene copolymer Polymers 0.000 description 1
• 235000012438 extruded product Nutrition 0.000 description 1
• 238000001125 extrusion Methods 0.000 description 1
• 230000004927 fusion Effects 0.000 description 1
• 238000010574 gas phase reaction Methods 0.000 description 1
• 239000001056 green pigment Substances 0.000 description 1
• 229910052735 hafnium Inorganic materials 0.000 description 1
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
• 150000004820 halides Chemical class 0.000 description 1
• 229910052736 halogen Inorganic materials 0.000 description 1
• 150000002367 halogens Chemical class 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 125000000623 heterocyclic group Chemical group 0.000 description 1
• 229920001519 homopolymer Polymers 0.000 description 1
• 229930195733 hydrocarbon Natural products 0.000 description 1
• 150000002430 hydrocarbons Chemical class 0.000 description 1
• 150000002431 hydrogen Chemical class 0.000 description 1
• 239000012535 impurity Substances 0.000 description 1
• 150000002484 inorganic compounds Chemical class 0.000 description 1
• 229910010272 inorganic material Inorganic materials 0.000 description 1
• PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
• 150000007527 lewis bases Chemical class 0.000 description 1
• 229910044991 metal oxide Inorganic materials 0.000 description 1
• 150000004706 metal oxides Chemical class 0.000 description 1
• 230000000116 mitigating effect Effects 0.000 description 1
• 239000003607 modifier Substances 0.000 description 1
• 229910052750 molybdenum Inorganic materials 0.000 description 1
• 239000011733 molybdenum Substances 0.000 description 1
• 238000000465 moulding Methods 0.000 description 1
• 229920003052 natural elastomer Polymers 0.000 description 1
• 229920001194 natural rubber Polymers 0.000 description 1
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
• 239000001053 orange pigment Substances 0.000 description 1
• 150000002894 organic compounds Chemical class 0.000 description 1
• 239000013110 organic ligand Substances 0.000 description 1
• 150000002902 organometallic compounds Chemical class 0.000 description 1
• 125000002524 organometallic group Chemical group 0.000 description 1
• YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
• 229920005631 polypropylene heterophasic copolymer Polymers 0.000 description 1
• 230000001376 precipitating effect Effects 0.000 description 1
• 238000002360 preparation method Methods 0.000 description 1
• 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
• 238000010926 purge Methods 0.000 description 1
• FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
• 239000002516 radical scavenger Substances 0.000 description 1
• 230000009467 reduction Effects 0.000 description 1
• 229920006395 saturated elastomer Polymers 0.000 description 1
• 238000013341 scale-up Methods 0.000 description 1
• 230000035945 sensitivity Effects 0.000 description 1
• 238000000926 separation method Methods 0.000 description 1
• 238000007873 sieving Methods 0.000 description 1
• 229910000077 silane Inorganic materials 0.000 description 1
• 230000007928 solubilization Effects 0.000 description 1
• 238000005063 solubilization Methods 0.000 description 1
• 239000003381 stabilizer Substances 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 238000010998 test method Methods 0.000 description 1
• 238000012360 testing method Methods 0.000 description 1
• 239000004408 titanium dioxide Substances 0.000 description 1
• YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
• 238000005809 transesterification reaction Methods 0.000 description 1
• 238000012546 transfer Methods 0.000 description 1
• 238000006276 transfer reaction Methods 0.000 description 1
• VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
• JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
• RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
• 235000013799 ultramarine blue Nutrition 0.000 description 1
• GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
• 229910052720 vanadium Inorganic materials 0.000 description 1
• 238000005406 washing Methods 0.000 description 1
• 239000001052 yellow pigment Substances 0.000 description 1