CN103118777B - 纳米线催化剂 - Google Patents
纳米线催化剂 Download PDFInfo
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- CN103118777B CN103118777B CN201180035734.8A CN201180035734A CN103118777B CN 103118777 B CN103118777 B CN 103118777B CN 201180035734 A CN201180035734 A CN 201180035734A CN 103118777 B CN103118777 B CN 103118777B
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- nano wire
- catalyst
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- nano
- oxide
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- 239000002070 nanowire Substances 0.000 title claims abstract description 810
- 239000003054 catalyst Substances 0.000 title claims abstract description 217
- 238000000034 method Methods 0.000 claims abstract description 192
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 170
- 229910052751 metal Inorganic materials 0.000 claims abstract description 161
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 142
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000005977 Ethylene Substances 0.000 claims abstract description 64
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 64
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 64
- 239000000956 alloy Substances 0.000 claims abstract description 47
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 45
- 229910052768 actinide Inorganic materials 0.000 claims abstract description 43
- 150000001255 actinides Chemical class 0.000 claims abstract description 43
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims description 198
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 133
- 239000000203 mixture Substances 0.000 claims description 115
- 230000003197 catalytic effect Effects 0.000 claims description 92
- 230000000694 effects Effects 0.000 claims description 89
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- 239000000395 magnesium oxide Substances 0.000 claims description 69
- 239000000126 substance Substances 0.000 claims description 66
- 229910052760 oxygen Inorganic materials 0.000 claims description 54
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 50
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 44
- 239000013590 bulk material Substances 0.000 claims description 43
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- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 claims description 34
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 2
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- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- 229910000351 vanadium(III) sulfate Inorganic materials 0.000 description 1
- ITAKKORXEUJTBC-UHFFFAOYSA-L vanadium(ii) chloride Chemical compound Cl[V]Cl ITAKKORXEUJTBC-UHFFFAOYSA-L 0.000 description 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- LBVWQMVSUSYKGQ-UHFFFAOYSA-J zirconium(4+) tetranitrite Chemical compound [Zr+4].[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O LBVWQMVSUSYKGQ-UHFFFAOYSA-J 0.000 description 1
Classifications
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Abstract
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AU2016269476A1 (en) | 2016-12-22 |
US10195603B2 (en) | 2019-02-05 |
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US20200070136A1 (en) | 2020-03-05 |
AU2011258422B2 (en) | 2016-09-15 |
BR112012030016B8 (pt) | 2021-05-18 |
IL223215B (en) | 2019-09-26 |
CN106000393A (zh) | 2016-10-12 |
US9718054B2 (en) | 2017-08-01 |
BR112012030016A2 (pt) | 2016-11-01 |
EP2853521A1 (en) | 2015-04-01 |
MX2012013521A (es) | 2013-04-08 |
EP2576046B1 (en) | 2014-11-19 |
AU2011258422A1 (en) | 2013-01-10 |
MY164976A (en) | 2018-02-28 |
WO2011149996A2 (en) | 2011-12-01 |
BR112012030016B1 (pt) | 2020-10-27 |
CN106000393B (zh) | 2019-11-19 |
US20120041246A1 (en) | 2012-02-16 |
CA2800142A1 (en) | 2011-12-01 |
EP2853521B1 (en) | 2018-10-10 |
IL223215A0 (en) | 2013-02-03 |
CA2800142C (en) | 2018-06-05 |
EA027816B1 (ru) | 2017-09-29 |
HK1208858A1 (zh) | 2016-03-18 |
EP2576046A2 (en) | 2013-04-10 |
AU2016269476B2 (en) | 2019-09-19 |
AU2011258422C1 (en) | 2017-03-30 |
CN103118777A (zh) | 2013-05-22 |
US20180117579A1 (en) | 2018-05-03 |
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