WO2014079172A1 - Système de traitement de gaz d'échappement - Google Patents

Système de traitement de gaz d'échappement Download PDF

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Publication number
WO2014079172A1
WO2014079172A1 PCT/CN2013/071235 CN2013071235W WO2014079172A1 WO 2014079172 A1 WO2014079172 A1 WO 2014079172A1 CN 2013071235 W CN2013071235 W CN 2013071235W WO 2014079172 A1 WO2014079172 A1 WO 2014079172A1
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WO
WIPO (PCT)
Prior art keywords
exhaust gas
water
gas treatment
flue gas
treatment system
Prior art date
Application number
PCT/CN2013/071235
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English (en)
Chinese (zh)
Inventor
许文姬
李国声
李汉声
李振声
Original Assignee
华南再生资源（中山）有限公司
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Publication date
Application filed by 华南再生资源（中山）有限公司 filed Critical 华南再生资源（中山）有限公司
Publication of WO2014079172A1 publication Critical patent/WO2014079172A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/48—Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the invention discloses a tail gas centralized processing device suitable for multiple different pressures and different temperatures, and more particularly relates to an exhaust gas treatment system in the process of comprehensive processing of the kitchen waste resource.
  • the science and technology of waste resource utilization after a long period of application, has proved that if the waste recycling technology is applied in a single application, the consequences will bring greater crisis to the human living environment, especially The serious problem of secondary pollution is difficult to control, so the comprehensive treatment of waste has become the current development trend.
  • the composition of kitchen waste is extremely complicated, including sewage, plastic bags, plastic bottles, waste cloth strips, spoilage organic matter, paper, metal bottles, broken glass, broken ceramic sheets, animal fats, vegetable oils, primary bacteria and other substances. .
  • the kitchen waste resource treatment technology has presented a “hundred flowers” situation in the domestic and foreign methods and processes, but basically it is a simple single item treatment, and there is no international environmental treatment that shifts from simple treatment to comprehensive treatment, utilization and disposal.
  • the trend and direction may cause the inevitable attachments in the kitchen waste to be transferred and randomly filled, causing water and soil pollution, or transfer, not only blocking the city's sewer pipes, but also emitting a foul smell and causing serious secondary pollution.
  • the single treatment process of kitchen waste is feasible from the perspective of resource utilization value.
  • people's livability and protection of the atmospheric environment it may still do more harm than good.
  • some tail gas will be generated, including boiler heat source exhaust gas, drying equipment exhaust gas, biochemical equipment warm tail gas, hot dust tail gas produced by feed, etc. These exhaust gases will pollute the environment.
  • the present invention provides a new exhaust gas treatment system, which adopts a preliminary purification device, a water-solid mixer, The twin-tower rotary sprinkler system, cooling tower and flue gas discharge equipment work together to achieve complete treatment of the kitchen waste.
  • an exhaust gas treatment system the system includes a preliminary purification device, a water-solid mixer, a double-tower rotary spray system and a flue gas discharge device
  • the preliminary purification device includes air
  • the buffer and the primary flue gas treatment pipeline the exhaust gas is introduced into the air buffer, is input into the primary flue gas treatment pipeline through the air buffer, is discharged into the water-solid mixer through the primary flue gas treatment pipeline, and the water-solid mixer outlet It is passed into the double-tower rotary sprinkler system, processed into the flue gas discharge equipment after being treated by the double-tower rotary sprinkler system, and then discharged after being treated by the flue gas discharge equipment.
  • the exhaust gas discharged is basically dust-free, odorless and non-exhaustive. The effect of black smoke and room temperature emissions.
  • the air buffer comprises a cylindrical outer casing, and more than one water curtain ejection opening is arranged on the upper side of the outer casing, and a sewage outlet is arranged at the bottom of the outer casing, and more than one exhaust air inlet is opened in the middle of the outer casing.
  • the buffer tank is further provided with a circulating water tank.
  • the circulating water tank has a pipe connecting the sewage outlet at the bottom of the casing, and the other pipe is connected to the upper part of the casing through the water pump and enters the buffer chamber, and the bottom side of the circulating water tank is equipped with a sewage outlet. , connected to the sedimentation tank through a pipe.
  • An on-line level monitor for detecting the liquid level inside the air buffer is also mounted above the air damper.
  • the primary flue gas treatment pipeline is provided with more than one negative ion-charged ceramic, and each negative ion-charged ceramic rear end is correspondingly equipped with a high-speed water mist zone nozzle.
  • a baffle is mounted on the rear end of each of the high-speed water mist nozzles.
  • the deflector adopts a concave obtuse angle deflector.
  • the negative ion-charged ceramic is mounted on the left, right, and upper sides of the primary flue gas treatment pipe.
  • the system also includes a cooling tower that cools the hot water within the heat exchanger in the flue gas exhaust device.
  • the invention has the beneficial effects that: according to the invention content of the announcement authorized by CN101816874A, the invention can adapt to the different pressures, different temperatures, different components of smoke and heat generated in the various processes of the comprehensive processing of the kitchen waste resource. Flue gas, dust, pumping air, etc. are concentrated to ensure that there is no irritating odor emission, no harmful toxic gas emissions, no odorous gas emissions, no micro-particle emissions, no room temperature discharge.
  • the invention can desulfurize the exhaust gas and reduce the carbon dioxide emission, and can also remove the carbon dust particles contained in the exhaust gas, thereby realizing no pollution and almost no white smoke emission, and effectively changing the exhaust gas exhaust process in the past.
  • the weak acid corrosion pipeline produced causes defects in the pipeline to be easily damaged, and the service life of the system is guaranteed.
  • the present invention is also capable of reducing the temperature of the exhaust gas to substantially the same level as the atmosphere, thereby also ensuring the service life of the system.
  • FIG. 1 is a schematic view of an exhaust gas treatment system of the present invention.
  • FIG. 2 is a schematic view showing the structure of an exhaust gas buffer in the present invention.
  • Figure 3 is a schematic view showing the construction of a primary flue gas treatment pipeline of the present invention.
  • Figure 4 is a schematic view of the flue gas exhaust system and its internal structure in the present invention.
  • Figure 5 is a schematic view showing the construction of a primary flue gas treatment pipeline of the present invention.
  • 1-air buffer, 1A air inlet, 2-water seal interface, 3-sewage outlet, 4-water valve, 5-line liquid level monitor, 6-automatic circulation water pump, 7-primary smoke Gas treatment pipeline, 8-negative ion-charged ceramic, 9-high speed water mist nozzle, 10- concave obtuse deflector, 11-gas, water, solid separator, 12-circulating water tank, 13-double tower rotary spray System, 14-rotating high pressure nozzle, 15-water outlet, 16-winding equipment, 17-water, gas mixing pipeline, 18-flue gas discharge equipment, 19-tank, 20-heat exchanger, 21-gas discharge pipeline , 22 - water outlet, 23 - cooling tower, 24 - sediment pool, 25 - carbon slag filter, 26 - water curtain jet.
  • This embodiment is a preferred embodiment of the present invention, and other principles and basic structures are the same as or similar to those of the present embodiment, and are all within the scope of the present invention.
  • the invention is mainly used for centralized treatment of flue gas, hot flue gas, dust, extraction air and the like generated in various processes of the kitchen waste recycling treatment, ensuring that the air discharge port has no irritating odor emission and no harmful toxic gas. Emissions, no odorous gas emissions, no particulate emissions, no room temperature emissions, etc.
  • the present invention includes an exhaust gas buffer device, an air inlet, a primary gas, a water, a solid separator 11, a primary purification pipe 7, a twin-tower rotary sprinkler system 13, a cooling tower 23, and a flue gas discharge.
  • the exhaust gas buffer 1 is further provided with a plurality of air inlets 2, the air buffer chamber is filled with water body, and the top end surface formed by the water body is the water body interface 2A, and the bottom of the air buffer 1 is the outer shell
  • the sewage outlet 3 is provided for sewage discharge, and the sewage outlet 3 is connected to the inside of the circulating water tank 12 through a pipe section, and the circulating water tank is connected with a water circulation pipe 4, which acts on the water body inside the buffer to ensure the interface position of the water body and The water body cools down.
  • an in-line liquid level monitor 5 is also installed in the air buffer 1 for real-time monitoring of the water body interface height inside the air buffer 1.
  • a circulating water tank 12 is arranged outside the exhaust gas buffer 1, and the sewage outlet 3 is connected to the sediment pool 24 through the pipe section.
  • the upper part of the circulating water tank 12 is connected through the pipe section 4, and the water pipe 4A is arranged on the pipe section, and the outlet pipe section of the circulating water tank 12 and the automatic circulation water supply.
  • the pump 6 is connected, and the water outlet of the automatic circulation water pump 6 is connected to the middle portion of the exhaust gas buffer 1 through the pipe 4 for discharging the circulating water through the water curtain shower nozzle 26 in the exhaust gas buffer and discharging into the exhaust gas buffer 1.
  • the upper side of the exhaust gas buffer 1 is provided with a primary flue gas treatment pipe 7.
  • the upper, the left and the right sides of the primary flue gas treatment pipe 7 are misplaced with a plurality of negative ion-charged ceramics 8, which are negative ions.
  • the charged ceramic does not need to be powered to start, and can naturally release negative ions.
  • each negative ion-charged ceramic 8 is equipped with a high-speed water mist nozzle 9 and an obtuse angle deflector 10, and a high-speed water mist nozzle 9 at the back end of the negative ion-charged ceramic 8
  • the multi-layer water curtain is formed as a negative ion high-speed water mist zone, and the obtuse angle baffle acts on the instantaneous airflow trajectory direction of the high-speed flue gas, so that the moving direction of the dense dust particle does not flow along the gas direction.
  • the primary flue gas treatment pipe 7 is inclined, the front end of the primary flue gas treatment pipe 7 is connected to the air buffer 1, and the gas, water and solid separator 11 is connected to the rear end of the primary flue gas treatment pipe 7, gas, Below the water and solids separator 11, a carbon residue filter 25 is provided for filtering the carbon residue in the sediment in the water-solid separator 11.
  • the water-solid mixer 11 is connected to the twin-tower rotary sprinkler system 13 through a water-gas mixing pipe.
  • the twin-tower rotary sprinkler system 13 comprises two vertical processing towers arranged side by side. After the flue gas first enters one of the processing towers, the gas flows from top to bottom into the lower part of the other tower body. After that, the gas is further operated from bottom to top in the lower part of the tower, and at the same time, the rotating high-pressure nozzle 14 installed around the periphery of the double tower sprays water on the gas, and the gas is smoothly cleaned, and the bottom of each tower is provided with a water outlet 15, And the water outlet 15 flows into the water and gas mixing pipe 17, and the heated hot flue gas has been formed into the water and gas mixing pipe 17 by the air introducing device 16 installed outside the tower.
  • the water and gas mixing pipe 17 is installed in a horizontally inclined manner to connect the air guiding device, and the water and gas mixing pipe 17 is slightly higher at one end and slightly lower at the other end, and is connected by the water outlet of the lower portion of the double tower rotary sprinkler system 13.
  • the discharged water body and the hot gas derived from the draft fan directly enter the water and gas mixing pipe 17, and flow to the slightly lower end and enter the flue gas discharge device 18.
  • the flue gas discharge device 18 includes three parts, the lower part is a tank body 19, and the heat exchanger 20 is connected to the top of the tank body 19.
  • the upper part of the heat exchanger is a gas discharge pipe 21, wherein the lower tank 19 is connected to the water outlet of the water and gas mixing pipe 17, and the wet slag discharge port and the water outlet 22 are provided on one side of the lower tank 19. Further, the circulating water in the heat exchanger 20 is supplied from the cooling tower 23, and the cooling tower 23 sucks the water in the sedimentation tank 24 through the pump and conveys it to the heat exchanger 20 through the pipe, and the hot water in the heat exchanger 20 The gas is cooled. When the hot water enters the heat exchanger 20, the steam is cooled and liquefied into a water body to fall into the lower tank 19, and discharged through the water outlet 22, and the dry gas that cannot be liquefied is discharged from the discharge port.
  • the gas discharge temperature is not higher than 38 °C.
  • the main point of the present invention is to add a preliminary purification device to the front end of the exhaust gas treatment system, and its structural design.
  • the application number is 201010168879.2
  • the publication number is CN101816874A.
  • the structure is substantially the same as in the present invention.
  • the invention can centrally treat the flue gas, the hot flue gas, the dust, the exhaust air and the like generated in the various processes of the kitchen waste resource treatment, and ensure that the air discharge port has no irritating odor emission, no harmful toxic gas discharge, no Odorous gas emissions, no particulate matter emissions, no room temperature emissions, etc.
  • the invention can desulfurize the exhaust gas and reduce the carbon dioxide emission, and can also remove the carbon dust particles contained in the exhaust gas, thereby realizing no pollution and almost no white smoke emission, and effectively changing the exhaust gas exhaust process in the past.
  • the weak acid corrosion pipeline produced causes defects in the pipeline to be easily damaged, and the service life of the system is guaranteed.
  • the present invention is also capable of reducing the temperature of the exhaust gas to substantially the same level as the atmosphere, thereby also ensuring the service life of the system.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Drying Of Solid Materials (AREA)
  • Fats And Perfumes (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Crushing And Pulverization Processes (AREA)
  • Catalysts (AREA)
  • Combined Means For Separation Of Solids (AREA)
  • Treatment Of Sludge (AREA)

Abstract

La présente invention concerne un système de traitement de gaz d'échappement comprenant un appareil tampon de gaz d'échappement (1), un séparateur eau/solides (11), un système arroseur rotatif à tours jumelles (13), un appareil d'évacuation des fumées (18) et un conduit de traitement des fumées primaires (7). A son introduction dans un tampon de gaz d'échappement, un gaz d'échappement est introduit dans le conduit de traitement des fumées primaires (7) par le biais de l'appareil tampon de gaz d'échappement (1), évacué dans le séparateur eau/liquides (11) par le biais du conduit de traitement des fumées primaires (7), introduit dans le système arroseur rotatif à tours jumelles (13) par le biais d'un orifice de sortie du séparateur eau/solides (11), introduit dans l'appareil d'évacuation des fumées (18) après avoir été traité par le système arroseur rotatif à tours jumelles (13), puis évacué après avoir été traité par l'appareil d'évacuation des fumées (18). Après son traitement par le système de traitement de gaz d'échappement, le gaz d'échappement évacué est sensiblement sans poussière, sans odeur, sans fumée et est évacué à température ambiante.
PCT/CN2013/071235 2012-11-23 2013-01-31 Système de traitement de gaz d'échappement WO2014079172A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210481274 2012-11-23
CN201210481274.8 2012-11-23

Publications (1)

Publication Number Publication Date
WO2014079172A1 true WO2014079172A1 (fr) 2014-05-30

Family

ID=48098723

Family Applications (10)

Application Number Title Priority Date Filing Date
PCT/CN2013/071235 WO2014079172A1 (fr) 2012-11-23 2013-01-31 Système de traitement de gaz d'échappement
PCT/CN2013/071217 WO2014079168A1 (fr) 2012-11-23 2013-01-31 Procédé et appareil pour fermentation biochimique
PCT/CN2013/071230 WO2014079171A1 (fr) 2012-11-23 2013-01-31 Procédé et appareil de préparation de biodiesel composé micro-émulsionné riche en oxygène
PCT/CN2013/071237 WO2014079173A1 (fr) 2012-11-23 2013-01-31 Appareil de désodorisation et de stérilisation de l'air à ions négatifs par photocatalyseur à plasma
PCT/CN2013/071210 WO2014079167A1 (fr) 2012-11-23 2013-01-31 Appareil pour l'oxygénation, la désodorisation, la désactivation et la réduction de sel par rinçage de déchets alimentaires
PCT/CN2013/071225 WO2014079169A1 (fr) 2012-11-23 2013-01-31 Appareil de séchage à étages multiples et à déchargement automatique
PCT/CN2013/071204 WO2014079165A1 (fr) 2012-11-23 2013-01-31 Système de criblage conjugué de déchets alimentaires
PCT/CN2013/071209 WO2014079166A1 (fr) 2012-11-23 2013-01-31 Appareil d'assèchement vertical
PCT/CN2013/071228 WO2014079170A1 (fr) 2012-11-23 2013-01-31 Procédé et système de production de biodiesel sans distillation
PCT/CN2013/000146 WO2014079135A1 (fr) 2012-11-23 2013-02-16 Appareil intégré pour traitement complet de déchets alimentaires et procédé de fabrication de produit

Family Applications After (9)

Application Number Title Priority Date Filing Date
PCT/CN2013/071217 WO2014079168A1 (fr) 2012-11-23 2013-01-31 Procédé et appareil pour fermentation biochimique
PCT/CN2013/071230 WO2014079171A1 (fr) 2012-11-23 2013-01-31 Procédé et appareil de préparation de biodiesel composé micro-émulsionné riche en oxygène
PCT/CN2013/071237 WO2014079173A1 (fr) 2012-11-23 2013-01-31 Appareil de désodorisation et de stérilisation de l'air à ions négatifs par photocatalyseur à plasma
PCT/CN2013/071210 WO2014079167A1 (fr) 2012-11-23 2013-01-31 Appareil pour l'oxygénation, la désodorisation, la désactivation et la réduction de sel par rinçage de déchets alimentaires
PCT/CN2013/071225 WO2014079169A1 (fr) 2012-11-23 2013-01-31 Appareil de séchage à étages multiples et à déchargement automatique
PCT/CN2013/071204 WO2014079165A1 (fr) 2012-11-23 2013-01-31 Système de criblage conjugué de déchets alimentaires
PCT/CN2013/071209 WO2014079166A1 (fr) 2012-11-23 2013-01-31 Appareil d'assèchement vertical
PCT/CN2013/071228 WO2014079170A1 (fr) 2012-11-23 2013-01-31 Procédé et système de production de biodiesel sans distillation
PCT/CN2013/000146 WO2014079135A1 (fr) 2012-11-23 2013-02-16 Appareil intégré pour traitement complet de déchets alimentaires et procédé de fabrication de produit

Country Status (6)

Country Link
KR (1) KR20150105299A (fr)
CN (17) CN203128526U (fr)
HK (9) HK1180657A1 (fr)
RU (1) RU2015123832A (fr)
SG (1) SG11201503980RA (fr)
WO (10) WO2014079172A1 (fr)

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