WO2014079171A1 - Procédé et appareil de préparation de biodiesel composé micro-émulsionné riche en oxygène - Google Patents
Procédé et appareil de préparation de biodiesel composé micro-émulsionné riche en oxygène Download PDFInfo
- Publication number
- WO2014079171A1 WO2014079171A1 PCT/CN2013/071230 CN2013071230W WO2014079171A1 WO 2014079171 A1 WO2014079171 A1 WO 2014079171A1 CN 2013071230 W CN2013071230 W CN 2013071230W WO 2014079171 A1 WO2014079171 A1 WO 2014079171A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- biodiesel
- oxygen
- emulsified
- water
- casing
- Prior art date
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- 239000001301 oxygen Substances 0.000 title claims abstract description 57
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 57
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000003225 biodiesel Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000003756 stirring Methods 0.000 claims abstract description 27
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 10
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 239000003093 cationic surfactant Substances 0.000 claims description 6
- 239000002283 diesel fuel Substances 0.000 claims description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 3
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 3
- 230000032798 delamination Effects 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000009692 water atomization Methods 0.000 claims description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 2
- 229960000800 cetrimonium bromide Drugs 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 238000005352 clarification Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 abstract 3
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 8
- 239000000446 fuel Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000010806 kitchen waste Substances 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- QOHUADYMMOUSQA-UHFFFAOYSA-N [Br-].Br[NH+](Br)Br Chemical compound [Br-].Br[NH+](Br)Br QOHUADYMMOUSQA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/48—Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Definitions
- the invention discloses an apparatus and a method for producing an oxygen-enriched micro-emulsified mixed biodiesel, and more particularly relates to a method for converting a hybrid oil produced in a kitchen waste treatment process into biodiesel, and further preparing an oxygen-enriched micro-emulsified mixture. Method and device for producing biodiesel.
- hybrid oil is inevitably produced. It is a mixture of vegetable oil and animal oil.
- esterification reaction which can also be called pure biodiesel.
- the characteristic is close to petrochemical diesel. It is a kind of typical renewable energy.
- a method of mixing with petrochemical diesel to produce mixed biodiesel or micro-emulsified diesel is used as a boiler.
- Fuel and vehicle fuels, mixed biodiesel and micro-emulsified bio-mixed diesel have found in the current application experience that they can reduce the emission of harmful substances such as smoke, CO and HC, but also because of the low hydrocarbon-to-carbon ratio of oxygen.
- Insufficient fuel production efficiency is poor, carbon deposits on engine cylinder inlets, exhaust valves, combustion chambers, intake pipes, and oxygen sensors cause fuel consumption, exhaustion, and powerlessness, although people use
- the amount of air used to meet the oxygen content of the engine but 78% of the air is nitrogen that cannot be ignited, while only 20% is flammable. Oxygen is not enough to change the combustion environment, but it will increase NOx emissions.
- the invention provides a novel oxygen-enriched micro-emulsified mixed biodiesel production method and device, which further emulsifies pure biodiesel extracted from the kitchen waste to form an oxygen-enriched micro-emulsified mixed biodiesel, which not only improves the combustion quality, but also improves the combustion quality. Moreover, it can expand its application range and also play a significant environmental protection effect.
- an apparatus for manufacturing an oxygen-enriched micro-emulsified mixed biodiesel the device comprises a casing, a vertical agitator is arranged in the casing, the power source drives the vertical agitator to rotate, and the vertical agitator
- the lower part of the vertical shaft of the vertical mixer is equipped with turbine or disc curved blade pulp.
- the top of the casing is provided with more than one inlet.
- Each feeding port is connected with a quantitative feeding device through a pipe.
- the lower part of the casing is provided with a finished product discharging port, and the upper part of the casing is connected with an oxygen-enriched water supply pipe, and the oxygen-enriched water is supplied by the O3 gas generator through the gas source.
- the oxygen-enriched water in the oxygen-rich water storage tank is converted from O3 to oxygen-enriched water with high dissolved oxygen. More than one oxygen-enriched water spray nozzle is installed in the upper portion of the housing.
- a method for preparing an emulsified biodiesel using the above oxygen-enriched micro-emulsified mixed biodiesel production device comprising the following steps:
- the pure biodiesel is input into the above emulsified biodiesel device, the stirring system is started, 30% of the national standard diesel oil is added, and the mixture is stirred for 5 minutes;
- hydrophilic agent is added in an amount of 2-3% of the total weight of the pure biodiesel and the petrochemical diesel, and is stirred for 1 min to 15 min;
- the upper part of the casing is cylindrical and the lower part is semicircular.
- More than one liquid guide vane is mounted around the cylindrical inner wall of the housing.
- a support frame for a rotating shaft supporting a vertical agitator is mounted on the bottom of the housing.
- the power source includes a motor and a shifting device, the shifting device is fixedly mounted on the top of the housing, the motor is disposed above the shifting device, and the motor drives the vertical agitator to rotate through the shifting device.
- the oxygen-enriched water is converted by an ozone generator through a gas and liquid intensive mixer and then into an oxygen-rich water storage tank.
- the hydrophilic agent is a composite active agent selected from a cationic surfactant and a nonionic surfactant, and the ratio is 50% of a cationic surfactant and 50% of a non-cationic surfactant.
- the surfactant is triethanolamine or hexahydroaniline or cetrimonium bromide and aqueous ammonia.
- the water is added in an amount of 10% to 20% by weight based on the total weight.
- the acid value of the octadecyl-cis-9-enoic acid set amount is 200 or more.
- the invention has the beneficial effects that the biodiesel refined in the kitchen waste can be further emulsified by the invention to generate oxygen-enriched micro-emulsified biodiesel, which not only improves the combustion environment, but also expands the application range thereof.
- Figure 1 is a schematic view of the structure of the present invention.
- This embodiment is a preferred embodiment of the present invention, and other principles and basic structures are the same as or similar to those of the present embodiment, and are all within the scope of the present invention.
- the apparatus for manufacturing emulsified biodiesel in the present invention is mainly a casing 1.
- the upper part of the casing 1 has a straight cylindrical shape
- the lower part is a semicircular body
- the casing 1 is internally provided with a vertical agitator 2
- the power source drives the vertical agitator 2 to rotate.
- the power source includes the motor 3 and the shifting device 4, the shifting device 4 is fixedly mounted on the top of the casing 1, the motor 3 is disposed above the shifting device 4, and the motor 3 passes through the shifting device. 4 drives the vertical mixer 2 to rotate.
- a support frame 20 for the rotating shaft is provided in the semicircular body at the bottom of the casing 1 for supporting the rotating shaft of the vertical agitator 2.
- the vertical agitator 2 is equipped with a plurality of straight agitating pulps 5 at a suitable position on the central axis of the vertical agitator 2, and may be replaced by paddle-type vane paddles, and a turbine or disc curved blade is installed at a lower portion of the central axis of the vertical agitator 2
- the slurry 6, the cylindrical inner wall of the casing 1 is provided with a plurality of liquid guiding vanes 10, and the top of the casing 1 is provided with a plurality of feeding ports 8, each of which is connected with a dosing device 9 through a pipe.
- each of the quantitative feeding devices 9 is used for automatic feeding of various additives, and the top of the casing 1 is further provided with an oxygen-enriched water inlet pipe 13 and penetrates into the casing 1 to connect the oxygen-enriched water atomizing nozzle 7
- the inlet pipe 13 is connected to the high-pressure pump 14, and the ozone generator 18 outputs O3 gas into the strong water-gas mixer 16 and mixed with water, and then passes through the pipeline 17 to enter the oxygen-enriched water reserve tank 15, the water outlet of the oxygen-enriched water reserve tank 15. It is connected to the high pressure pump 14.
- the upper part of the casing 1 is provided with an oil inlet 10, one end of which is threaded inside the casing, and the other end is connected to the oil pump, and the lower part of the casing 1 is also provided with a finished discharge port 12, and the obtained emulsified biodiesel is discharged from the discharge port 12 The output is then sent to the oil storage through the pipeline and the pump.
- the oxygen-enriched micro-emulsified biodiesel produced in the present invention acts on various heat source fuels.
- the method for preparing the emulsified biodiesel in the present invention that is, the operation method of the above device in the present invention is as follows: the present invention is mainly directed to further processing of biodiesel produced by a production process from oil and fat, and oxygen-enriched microemulsification of biodiesel. Refined diesel technology.
- the method for preparing the emulsified biodiesel in the present invention comprises the following steps:
- the hydrophilic agent is a composite active agent combined with a cationic surfactant and a nonionic surfactant.
- the two types of surfactants are triethanolamine, hexahydroaniline or west. Tribromoammonium bromide and ammonia water, the ratio is 50% of cationic surfactant and 50% of nonionic surfactant.
- the hydrophilic agent is used to degrade the rigidity of the mask, increase the fluidity, reduce the bending energy required for the formation of microemulsion, and is easy to form.
- the milking solution is stirred for 1 min to 15 min after the hydrophilic agent is added;
- butanol can be used as a co-surfactant, and continue to do not indirectly stir the mixture for 15min, when stirring, the vertical stirrer 2 for 100 rev / min - Stirring at 130 rpm;
- isopentane is mixed with the liquids of the above (1) to (3), and then stirred for 5 minutes.
- the amount of oxygen-enriched water varies from 1% to 20% of the total weight of the product depending on the product, in this embodiment,
- the ozone generator supplies O3, the gas flow rate of ozone is 250ml/min, and is mixed with the water body in the powerful water and gas mixer, and then input into the oxygen-rich water storage tank to be naturally decomposed into oxygen enriched in water, and the natural decomposition time is 30 min, so that the water is in the water.
- the dissolved oxygen content reaches 27-35%, forming oxygen-enriched water.
- the oxygen-enriched water is added in an amount of 10%-20% of the total weight.
- the mixture is stirred for 15 minutes, and the rotation speed is adjusted to 170 rpm. ——200 rpm, and then add the 18-carbon-cis-9-enoic acid with an acid value of 200 or more as an emulsifier in the formulation.
- octadecyl-cis-9-enoic acid The amount of addition is 70% - 90% of the weight of the oxygen-enriched water added, under the continuous stirring of the stirring equipment until clear and transparent, at this time, the speed of the stirrer is adjusted to 280 - 340 rev / min, generally required Continuous stirring for 40-60min, wait for a certain period of time to observe that the emulsified oil is clean and transparent without delamination. .
- micro-emulsified biodiesel refining process has been completed, and the product can be degraded under the temperature of 85 ° C and the storage period of 240 days, containing 20% of oxygen-enriched water and more than 30% of the national standard III.
- the micro-emulsified diesel fuel produced by petrochemical diesel can be used as a heat source fuel, and the micro-emulsified diesel oil containing less than 10% of oxygen-rich water and containing more than 80% of the national standard III petrochemical diesel can be used as a diesel fuel for cleaning vehicles.
- the biodiesel extracted from the kitchen waste can be further refined by the invention to produce oxygen-enriched micro-emulsified biodiesel, which can expand the application range.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Fats And Perfumes (AREA)
- Drying Of Solid Materials (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treating Waste Gases (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Treatment Of Sludge (AREA)
- Catalysts (AREA)
- Combined Means For Separation Of Solids (AREA)
- Crushing And Pulverization Processes (AREA)
Abstract
La présente invention concerne un procédé et un appareil permettant de préparer un biodiesel composé micro-émulsionné riche en oxygène. L'appareil comprend un boîtier. Un agitateur vertical est disposé à l'intérieur du boîtier. Une source d'énergie entraîne l'agitateur vertical en rotation. Des pales agitatrices plates de type pale ou des pales à ailerons sont disposées sur un arbre central de l'agitateur vertical. Une turbine ou une pale à aileron en disque circulaire est dispose sur la partie inférieure de l'arbre central de l'agitateur vertical. Au moins un orifice d'entrée de matériaux est disposé sur la partie supérieure du boîtier. Chaque orifice d'entrée de matériaux est raccordé à un appareil d'alimentation en matériau nominal. Un orifice de sortie de produit est disposé au niveau de la partie inférieure du boîtier. Une ouverture d'alimentation en eau riche en oxygène est dispose au niveau de la partie supérieure du boîtier. Le procédé comprend les étapes consistant à : (1) introduire le biodiesel brut dans l'appareil pour biodiesel émulsionné, activer un système d'agitation, ajouter du diesel de norme nationale III, puis mélanger pendant 5 minutes; (2) ajouter un agent hydrophile, agiter pendant 1 minute à 15 minutes; (3) ajouter du butanol et de l'isopentane, en continuant l'agitation non indirecte du fluide composé pendant 15 minutes; et (4) ajouter de l'eau riche en oxygène, puis agiter pendant 15 minutes, laisser reposer pendant un certain temps, et récupérer le produit lorsque le diesel émulsionné est devenu clair, transparent et non stratifié.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN201210481274 | 2012-11-23 | ||
CN201210481274.8 | 2012-11-23 |
Publications (1)
Publication Number | Publication Date |
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WO2014079171A1 true WO2014079171A1 (fr) | 2014-05-30 |
Family
ID=48098723
Family Applications (10)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2013/071204 WO2014079165A1 (fr) | 2012-11-23 | 2013-01-31 | Système de criblage conjugué de déchets alimentaires |
PCT/CN2013/071235 WO2014079172A1 (fr) | 2012-11-23 | 2013-01-31 | Système de traitement de gaz d'échappement |
PCT/CN2013/071230 WO2014079171A1 (fr) | 2012-11-23 | 2013-01-31 | Procédé et appareil de préparation de biodiesel composé micro-émulsionné riche en oxygène |
PCT/CN2013/071210 WO2014079167A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil pour l'oxygénation, la désodorisation, la désactivation et la réduction de sel par rinçage de déchets alimentaires |
PCT/CN2013/071217 WO2014079168A1 (fr) | 2012-11-23 | 2013-01-31 | Procédé et appareil pour fermentation biochimique |
PCT/CN2013/071237 WO2014079173A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil de désodorisation et de stérilisation de l'air à ions négatifs par photocatalyseur à plasma |
PCT/CN2013/071209 WO2014079166A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil d'assèchement vertical |
PCT/CN2013/071225 WO2014079169A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil de séchage à étages multiples et à déchargement automatique |
PCT/CN2013/071228 WO2014079170A1 (fr) | 2012-11-23 | 2013-01-31 | Procédé et système de production de biodiesel sans distillation |
PCT/CN2013/000146 WO2014079135A1 (fr) | 2012-11-23 | 2013-02-16 | Appareil intégré pour traitement complet de déchets alimentaires et procédé de fabrication de produit |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2013/071204 WO2014079165A1 (fr) | 2012-11-23 | 2013-01-31 | Système de criblage conjugué de déchets alimentaires |
PCT/CN2013/071235 WO2014079172A1 (fr) | 2012-11-23 | 2013-01-31 | Système de traitement de gaz d'échappement |
Family Applications After (7)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2013/071210 WO2014079167A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil pour l'oxygénation, la désodorisation, la désactivation et la réduction de sel par rinçage de déchets alimentaires |
PCT/CN2013/071217 WO2014079168A1 (fr) | 2012-11-23 | 2013-01-31 | Procédé et appareil pour fermentation biochimique |
PCT/CN2013/071237 WO2014079173A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil de désodorisation et de stérilisation de l'air à ions négatifs par photocatalyseur à plasma |
PCT/CN2013/071209 WO2014079166A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil d'assèchement vertical |
PCT/CN2013/071225 WO2014079169A1 (fr) | 2012-11-23 | 2013-01-31 | Appareil de séchage à étages multiples et à déchargement automatique |
PCT/CN2013/071228 WO2014079170A1 (fr) | 2012-11-23 | 2013-01-31 | Procédé et système de production de biodiesel sans distillation |
PCT/CN2013/000146 WO2014079135A1 (fr) | 2012-11-23 | 2013-02-16 | Appareil intégré pour traitement complet de déchets alimentaires et procédé de fabrication de produit |
Country Status (6)
Country | Link |
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KR (1) | KR20150105299A (fr) |
CN (17) | CN203323492U (fr) |
HK (9) | HK1180636A1 (fr) |
RU (1) | RU2015123832A (fr) |
SG (1) | SG11201503980RA (fr) |
WO (10) | WO2014079165A1 (fr) |
Families Citing this family (128)
Publication number | Priority date | Publication date | Assignee | Title |
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CN203323492U (zh) * | 2012-11-23 | 2013-12-04 | 华南再生资源(中山)有限公司 | 自动卸料多级干燥装置 |
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CN1146482A (zh) * | 1995-09-29 | 1997-04-02 | 上海赢得实业总公司 | 微乳化生物合成柴油 |
JP2007145974A (ja) * | 2005-11-28 | 2007-06-14 | Matsuo Kogyosho:Kk | 廃食用油精製装置 |
CN201044896Y (zh) * | 2007-05-22 | 2008-04-09 | 宁波大学 | 一种油柜式全自动柴油动态乳化装置 |
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