WO2014079171A1 - Method and apparatus for preparing oxygen-rich micro-emulsified blended biodiesel - Google Patents

Method and apparatus for preparing oxygen-rich micro-emulsified blended biodiesel Download PDF

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WO2014079171A1
WO2014079171A1 PCT/CN2013/071230 CN2013071230W WO2014079171A1 WO 2014079171 A1 WO2014079171 A1 WO 2014079171A1 CN 2013071230 W CN2013071230 W CN 2013071230W WO 2014079171 A1 WO2014079171 A1 WO 2014079171A1
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biodiesel
oxygen
emulsified
water
casing
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PCT/CN2013/071230
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French (fr)
Chinese (zh)
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许文姬
李国声
李汉声
李振声
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华南再生资源（中山）有限公司
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Publication of WO2014079171A1 publication Critical patent/WO2014079171A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/48—Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the invention discloses an apparatus and a method for producing an oxygen-enriched micro-emulsified mixed biodiesel, and more particularly relates to a method for converting a hybrid oil produced in a kitchen waste treatment process into biodiesel, and further preparing an oxygen-enriched micro-emulsified mixture. Method and device for producing biodiesel.
  • hybrid oil is inevitably produced. It is a mixture of vegetable oil and animal oil.
  • esterification reaction which can also be called pure biodiesel.
  • the characteristic is close to petrochemical diesel. It is a kind of typical renewable energy.
  • a method of mixing with petrochemical diesel to produce mixed biodiesel or micro-emulsified diesel is used as a boiler.
  • Fuel and vehicle fuels, mixed biodiesel and micro-emulsified bio-mixed diesel have found in the current application experience that they can reduce the emission of harmful substances such as smoke, CO and HC, but also because of the low hydrocarbon-to-carbon ratio of oxygen.
  • Insufficient fuel production efficiency is poor, carbon deposits on engine cylinder inlets, exhaust valves, combustion chambers, intake pipes, and oxygen sensors cause fuel consumption, exhaustion, and powerlessness, although people use
  • the amount of air used to meet the oxygen content of the engine but 78% of the air is nitrogen that cannot be ignited, while only 20% is flammable. Oxygen is not enough to change the combustion environment, but it will increase NOx emissions.
  • the invention provides a novel oxygen-enriched micro-emulsified mixed biodiesel production method and device, which further emulsifies pure biodiesel extracted from the kitchen waste to form an oxygen-enriched micro-emulsified mixed biodiesel, which not only improves the combustion quality, but also improves the combustion quality. Moreover, it can expand its application range and also play a significant environmental protection effect.
  • an apparatus for manufacturing an oxygen-enriched micro-emulsified mixed biodiesel the device comprises a casing, a vertical agitator is arranged in the casing, the power source drives the vertical agitator to rotate, and the vertical agitator
  • the lower part of the vertical shaft of the vertical mixer is equipped with turbine or disc curved blade pulp.
  • the top of the casing is provided with more than one inlet.
  • Each feeding port is connected with a quantitative feeding device through a pipe.
  • the lower part of the casing is provided with a finished product discharging port, and the upper part of the casing is connected with an oxygen-enriched water supply pipe, and the oxygen-enriched water is supplied by the O3 gas generator through the gas source.
  • the oxygen-enriched water in the oxygen-rich water storage tank is converted from O3 to oxygen-enriched water with high dissolved oxygen. More than one oxygen-enriched water spray nozzle is installed in the upper portion of the housing.
  • a method for preparing an emulsified biodiesel using the above oxygen-enriched micro-emulsified mixed biodiesel production device comprising the following steps:
  • the pure biodiesel is input into the above emulsified biodiesel device, the stirring system is started, 30% of the national standard diesel oil is added, and the mixture is stirred for 5 minutes;
  • hydrophilic agent is added in an amount of 2-3% of the total weight of the pure biodiesel and the petrochemical diesel, and is stirred for 1 min to 15 min;
  • the upper part of the casing is cylindrical and the lower part is semicircular.
  • More than one liquid guide vane is mounted around the cylindrical inner wall of the housing.
  • a support frame for a rotating shaft supporting a vertical agitator is mounted on the bottom of the housing.
  • the power source includes a motor and a shifting device, the shifting device is fixedly mounted on the top of the housing, the motor is disposed above the shifting device, and the motor drives the vertical agitator to rotate through the shifting device.
  • the oxygen-enriched water is converted by an ozone generator through a gas and liquid intensive mixer and then into an oxygen-rich water storage tank.
  • the hydrophilic agent is a composite active agent selected from a cationic surfactant and a nonionic surfactant, and the ratio is 50% of a cationic surfactant and 50% of a non-cationic surfactant.
  • the surfactant is triethanolamine or hexahydroaniline or cetrimonium bromide and aqueous ammonia.
  • the water is added in an amount of 10% to 20% by weight based on the total weight.
  • the acid value of the octadecyl-cis-9-enoic acid set amount is 200 or more.
  • the invention has the beneficial effects that the biodiesel refined in the kitchen waste can be further emulsified by the invention to generate oxygen-enriched micro-emulsified biodiesel, which not only improves the combustion environment, but also expands the application range thereof.
  • Figure 1 is a schematic view of the structure of the present invention.
  • This embodiment is a preferred embodiment of the present invention, and other principles and basic structures are the same as or similar to those of the present embodiment, and are all within the scope of the present invention.
  • the apparatus for manufacturing emulsified biodiesel in the present invention is mainly a casing 1.
  • the upper part of the casing 1 has a straight cylindrical shape
  • the lower part is a semicircular body
  • the casing 1 is internally provided with a vertical agitator 2
  • the power source drives the vertical agitator 2 to rotate.
  • the power source includes the motor 3 and the shifting device 4, the shifting device 4 is fixedly mounted on the top of the casing 1, the motor 3 is disposed above the shifting device 4, and the motor 3 passes through the shifting device. 4 drives the vertical mixer 2 to rotate.
  • a support frame 20 for the rotating shaft is provided in the semicircular body at the bottom of the casing 1 for supporting the rotating shaft of the vertical agitator 2.
  • the vertical agitator 2 is equipped with a plurality of straight agitating pulps 5 at a suitable position on the central axis of the vertical agitator 2, and may be replaced by paddle-type vane paddles, and a turbine or disc curved blade is installed at a lower portion of the central axis of the vertical agitator 2
  • the slurry 6, the cylindrical inner wall of the casing 1 is provided with a plurality of liquid guiding vanes 10, and the top of the casing 1 is provided with a plurality of feeding ports 8, each of which is connected with a dosing device 9 through a pipe.
  • each of the quantitative feeding devices 9 is used for automatic feeding of various additives, and the top of the casing 1 is further provided with an oxygen-enriched water inlet pipe 13 and penetrates into the casing 1 to connect the oxygen-enriched water atomizing nozzle 7
  • the inlet pipe 13 is connected to the high-pressure pump 14, and the ozone generator 18 outputs O3 gas into the strong water-gas mixer 16 and mixed with water, and then passes through the pipeline 17 to enter the oxygen-enriched water reserve tank 15, the water outlet of the oxygen-enriched water reserve tank 15. It is connected to the high pressure pump 14.
  • the upper part of the casing 1 is provided with an oil inlet 10, one end of which is threaded inside the casing, and the other end is connected to the oil pump, and the lower part of the casing 1 is also provided with a finished discharge port 12, and the obtained emulsified biodiesel is discharged from the discharge port 12 The output is then sent to the oil storage through the pipeline and the pump.
  • the oxygen-enriched micro-emulsified biodiesel produced in the present invention acts on various heat source fuels.
  • the method for preparing the emulsified biodiesel in the present invention that is, the operation method of the above device in the present invention is as follows: the present invention is mainly directed to further processing of biodiesel produced by a production process from oil and fat, and oxygen-enriched microemulsification of biodiesel. Refined diesel technology.
  • the method for preparing the emulsified biodiesel in the present invention comprises the following steps:
  • the hydrophilic agent is a composite active agent combined with a cationic surfactant and a nonionic surfactant.
  • the two types of surfactants are triethanolamine, hexahydroaniline or west. Tribromoammonium bromide and ammonia water, the ratio is 50% of cationic surfactant and 50% of nonionic surfactant.
  • the hydrophilic agent is used to degrade the rigidity of the mask, increase the fluidity, reduce the bending energy required for the formation of microemulsion, and is easy to form.
  • the milking solution is stirred for 1 min to 15 min after the hydrophilic agent is added;
  • butanol can be used as a co-surfactant, and continue to do not indirectly stir the mixture for 15min, when stirring, the vertical stirrer 2 for 100 rev / min - Stirring at 130 rpm;
  • isopentane is mixed with the liquids of the above (1) to (3), and then stirred for 5 minutes.
  • the amount of oxygen-enriched water varies from 1% to 20% of the total weight of the product depending on the product, in this embodiment,
  • the ozone generator supplies O3, the gas flow rate of ozone is 250ml/min, and is mixed with the water body in the powerful water and gas mixer, and then input into the oxygen-rich water storage tank to be naturally decomposed into oxygen enriched in water, and the natural decomposition time is 30 min, so that the water is in the water.
  • the dissolved oxygen content reaches 27-35%, forming oxygen-enriched water.
  • the oxygen-enriched water is added in an amount of 10%-20% of the total weight.
  • the mixture is stirred for 15 minutes, and the rotation speed is adjusted to 170 rpm. ——200 rpm, and then add the 18-carbon-cis-9-enoic acid with an acid value of 200 or more as an emulsifier in the formulation.
  • octadecyl-cis-9-enoic acid The amount of addition is 70% - 90% of the weight of the oxygen-enriched water added, under the continuous stirring of the stirring equipment until clear and transparent, at this time, the speed of the stirrer is adjusted to 280 - 340 rev / min, generally required Continuous stirring for 40-60min, wait for a certain period of time to observe that the emulsified oil is clean and transparent without delamination. .
  • micro-emulsified biodiesel refining process has been completed, and the product can be degraded under the temperature of 85 ° C and the storage period of 240 days, containing 20% of oxygen-enriched water and more than 30% of the national standard III.
  • the micro-emulsified diesel fuel produced by petrochemical diesel can be used as a heat source fuel, and the micro-emulsified diesel oil containing less than 10% of oxygen-rich water and containing more than 80% of the national standard III petrochemical diesel can be used as a diesel fuel for cleaning vehicles.
  • the biodiesel extracted from the kitchen waste can be further refined by the invention to produce oxygen-enriched micro-emulsified biodiesel, which can expand the application range.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Drying Of Solid Materials (AREA)
  • Fats And Perfumes (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Treating Waste Gases (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Catalysts (AREA)
  • Combined Means For Separation Of Solids (AREA)
  • Treatment Of Sludge (AREA)
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Abstract

A method and apparatus for preparing an oxygen-rich micro-emulsified blended biodiesel. The apparatus comprises a housing. A vertical agitator is arranged within the housing. A power source drives the vertical agitator into rotation. Paddle-type flat stirring paddles or paddle-type flapped paddles are arranged at a central shaft of the vertical agitator. A turbine or a circular disk flapped paddle is arranged at the lower part of the central shaft of the vertical agitator. One or more material inlets are arranged at the top part of the housing. Each material inlet is connected to a rated material feeder apparatus. A product outlet is arranged at the lower part of the housing. An oxygen-rich water supply opening is arranged at the top part of the housing. The method comprises the following steps: (1) introducing a crude biodiesel into the apparatus for emulsified biodiesel, activating an agitation system, adding National Standard III diesel, then stirring for 5 minutes; (2) adding a hydrophilic agent, stirring for 1 minute to 15 minutes; (3) adding butanol and isopentane, continuing non-indirect stirring of the blended fluid for 15 minutes; and, (4) adding oxygen-rich water, then stirring for 15 minutes, leaving to stand for a certain amount of time, and acquiring the product when the emulsified diesel is observed to have turned clear, transparent, and non-stratified.

Description

富氧微乳化混合生物柴油的制作方法及装置  Method and device for preparing oxygen-enriched micro-emulsified mixed biodiesel 技术领域  Technical field
本发明公开一种富氧微乳化混合生物柴油的生产装置和方法，更具体涉及一种餐厨垃圾处理过程中所产生的杂化油脂转化为生物柴油后，再进一步制成富氧微乳化混合生物柴油的制作方法及装置。 The invention discloses an apparatus and a method for producing an oxygen-enriched micro-emulsified mixed biodiesel, and more particularly relates to a method for converting a hybrid oil produced in a kitchen waste treatment process into biodiesel, and further preparing an oxygen-enriched micro-emulsified mixture. Method and device for producing biodiesel.
背景技术Background technique
餐厨垃圾处理过程中，必然会产生杂化油脂，它是由植物油及动物油脂混合而成，当前众多方法是通过酯化反应制成脂肪酸甲脂燃料，也可称为纯生物柴油，其理化特性接近石化柴油，是一种典型可再生能源，为了使纯生物柴油更加接近矿物柴油的特性，便产生了一种与石化柴油混合的方法制成混合生物柴油或微乳化柴油，用作锅炉的燃料及车用燃料，混合生物柴油及微乳化生物混合柴油在目前的应用经验中发现确实能降低烟尘、CO和HC等有害物质的排放，但是也出现了由于燃油的碳氢比低，氧气助燃不足而导致燃油燃烧效率不佳，发动机气缸进、排气门、燃烧室、进气管、氧传感器上产生积碳现象，使汽车耗油加大，排气不畅且行驶无力，虽然人们采用增加空气用量来满足发动机的氧量，可是空气中的78%是不能助燃的氮气，而只有20%是可以助燃的氧气，不足以改变燃烧环境，反而会增加NOX的排放。In the process of kitchen waste treatment, hybrid oil is inevitably produced. It is a mixture of vegetable oil and animal oil. At present, many methods are made into fatty acid methyl ester fuel by esterification reaction, which can also be called pure biodiesel. The characteristic is close to petrochemical diesel. It is a kind of typical renewable energy. In order to make pure biodiesel closer to the characteristics of mineral diesel, a method of mixing with petrochemical diesel to produce mixed biodiesel or micro-emulsified diesel is used as a boiler. Fuel and vehicle fuels, mixed biodiesel and micro-emulsified bio-mixed diesel have found in the current application experience that they can reduce the emission of harmful substances such as smoke, CO and HC, but also because of the low hydrocarbon-to-carbon ratio of oxygen. Insufficient fuel production efficiency is poor, carbon deposits on engine cylinder inlets, exhaust valves, combustion chambers, intake pipes, and oxygen sensors cause fuel consumption, exhaustion, and powerlessness, although people use The amount of air used to meet the oxygen content of the engine, but 78% of the air is nitrogen that cannot be ignited, while only 20% is flammable. Oxygen is not enough to change the combustion environment, but it will increase NOx emissions.
发明内容Summary of the invention
本发明中提供一种新的富氧微乳化混合生物柴油的制作方法及装置，其将餐厨垃圾中提炼的纯生物柴油进一步乳化，生成富氧微乳化混合生物柴油，不仅提高其燃烧质量，而且可以扩大其应用范围，也确切地起到显著的环保效应。The invention provides a novel oxygen-enriched micro-emulsified mixed biodiesel production method and device, which further emulsifies pure biodiesel extracted from the kitchen waste to form an oxygen-enriched micro-emulsified mixed biodiesel, which not only improves the combustion quality, but also improves the combustion quality. Moreover, it can expand its application range and also play a significant environmental protection effect.
本发明解决其技术问题采用的技术方案是：一种富氧微乳化混合生物柴油的制作装置，该装置包括壳体，壳体内装有垂直搅拌器，动力源带动垂直搅拌器转动，垂直搅拌器的中轴上装有一个以上的浆式平直搅拌器或桨式折叶桨，垂直搅拌器的中轴下部安装有涡轮或圆盘弯叶浆，壳体的顶部设置有一个以上的进料口，每个进料口均通过管道连接有一个定量加料设备，壳体下部设置有成品出料口，壳体上部连接有富氧水供给管道，富氧水由O3气体发生器提供气源，通过三通强力气体混合器后输入富氧水储备箱内由O3转化为溶氧量高的富氧水。壳体内的上部装有一个以上的富氧水喷雾嘴。The technical solution adopted by the invention solves the technical problem is: an apparatus for manufacturing an oxygen-enriched micro-emulsified mixed biodiesel, the device comprises a casing, a vertical agitator is arranged in the casing, the power source drives the vertical agitator to rotate, and the vertical agitator There are more than one slurry flat mixer or paddle folding blade on the middle shaft. The lower part of the vertical shaft of the vertical mixer is equipped with turbine or disc curved blade pulp. The top of the casing is provided with more than one inlet. Each feeding port is connected with a quantitative feeding device through a pipe. The lower part of the casing is provided with a finished product discharging port, and the upper part of the casing is connected with an oxygen-enriched water supply pipe, and the oxygen-enriched water is supplied by the O3 gas generator through the gas source. After the three-way powerful gas mixer, the oxygen-enriched water in the oxygen-rich water storage tank is converted from O3 to oxygen-enriched water with high dissolved oxygen. More than one oxygen-enriched water spray nozzle is installed in the upper portion of the housing.
一种采用上述的富氧微乳化混合生物柴油的制作装置的乳化生物柴油的制作方法，该方法包括下述步骤：A method for preparing an emulsified biodiesel using the above oxygen-enriched micro-emulsified mixed biodiesel production device, the method comprising the following steps:
（1）、将纯生物柴油输入上述的乳化生物柴油装置内，启动搅拌系统，加入30%国III标准柴油后，搅拌5min；(1), the pure biodiesel is input into the above emulsified biodiesel device, the stirring system is started, 30% of the national standard diesel oil is added, and the mixture is stirred for 5 minutes;
（2）加入亲水剂，亲水剂的加入量为纯生物柴油和石化柴油总重量的2-3%，作1min——15min时间的搅拌；(2) adding a hydrophilic agent, the hydrophilic agent is added in an amount of 2-3% of the total weight of the pure biodiesel and the petrochemical diesel, and is stirred for 1 min to 15 min;
（3）、加入丁醇作为中间体，加入量为纯生物柴油和石化柴油总重量的2-4%，继续对混合液作不间接搅拌15min，搅拌时，垂直搅拌器（2）作100转/min——130转/min的转速搅拌；(3) Add butanol as an intermediate, add 2-4% of the total weight of pure biodiesel and petrochemical diesel, continue to indirectly stir the mixture for 15 min, stir, vertical stirrer (2) for 100 rpm /min - stirring at a speed of 130 rpm;
（4）、加入异戊烷作为自燃温度调节剂，加入量为纯生物柴油重量的1.5-2%。(4) Add isopentane as a self-ignition temperature regulator in an amount of 1.5-2% by weight of pure biodiesel.
（5）、加入干净的富氧水，水占产品总重量的1%——20%，再搅拌15min，转速调整为170转/min——200转/min，再加入十八碳—顺—9—烯酸作为乳化剂，十八碳—顺—9—烯酸的加入量为所加入富氧水重量的70%——90%，在搅拌设备的连续搅拌下直至澄清透明为止，此时，搅拌器的转速调整为280——340转/min，一般需要连续搅拌40——60min，待静置一定时间观察乳化油为清洁透明无分层后为成品。(5), add clean oxygen-enriched water, water accounts for 1% - 20% of the total weight of the product, and then stir for 15min, the speed is adjusted to 170 rev / min - 200 rev / min, then add eighteen carbon - cis - 9-enoic acid as emulsifier, the amount of 18-carbon-cis-9-enoic acid added is 70%-90% of the weight of the oxygen-enriched water added, under continuous stirring of the stirring equipment until clear and transparent, at this time The speed of the stirrer is adjusted to 280-340 rev / min. Generally, continuous stirring is required for 40-60 min. After standing for a certain period of time, the emulsified oil is observed to be clean and transparent without delamination.
本发明解决其技术问题采用的技术方案进一步还包括：The technical solution adopted by the present invention to solve the technical problem thereof further includes:
所述的壳体上部为圆筒形，下部呈半圆形。The upper part of the casing is cylindrical and the lower part is semicircular.
所述的壳体的圆筒形内壁四周安装一个以上的液体导流叶板。More than one liquid guide vane is mounted around the cylindrical inner wall of the housing.
所述的壳体底部安装有支撑垂直搅拌器的转轴用的支承架。A support frame for a rotating shaft supporting a vertical agitator is mounted on the bottom of the housing.
所述的动力源包括电机和变速设备，变速设备固定安装在壳体顶部，电机设置在变速设备上方，电机通过变速设备驱动垂直搅拌器转动。The power source includes a motor and a shifting device, the shifting device is fixedly mounted on the top of the housing, the motor is disposed above the shifting device, and the motor drives the vertical agitator to rotate through the shifting device.
所述的富氧水，由臭氧发生器通过气、液强力混合器混合后进入富氧水储备箱后转化而成。The oxygen-enriched water is converted by an ozone generator through a gas and liquid intensive mixer and then into an oxygen-rich water storage tank.
所述的亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂，配比例为阳离子表面活性剂50%，非阳离子表面活性剂50%。The hydrophilic agent is a composite active agent selected from a cationic surfactant and a nonionic surfactant, and the ratio is 50% of a cationic surfactant and 50% of a non-cationic surfactant.
所述的表面活性剂有三乙醇胺或六氢苯胺或西曲溴铵和氨水。The surfactant is triethanolamine or hexahydroaniline or cetrimonium bromide and aqueous ammonia.
所述的水的加入量为总重量的10%——20%。The water is added in an amount of 10% to 20% by weight based on the total weight.
所述的十八碳—顺—9—烯酸设定量的酸值为200以上。The acid value of the octadecyl-cis-9-enoic acid set amount is 200 or more.
本发明的有益效果是：通过本发明可自动的将餐厨垃圾中提炼的生物柴油进一步乳化，生成富氧微乳化生物柴油，不仅改善燃烧环境，而且可以扩大其应用范围。The invention has the beneficial effects that the biodiesel refined in the kitchen waste can be further emulsified by the invention to generate oxygen-enriched micro-emulsified biodiesel, which not only improves the combustion environment, but also expands the application range thereof.
下面将结合附图和具体实施方式对本发明做进一步说明。The invention will be further described with reference to the drawings and specific embodiments.
附图说明DRAWINGS
图1为本发明结构示意图。Figure 1 is a schematic view of the structure of the present invention.
图中，1-壳体，2-垂直搅拌器，3-电机，4-变速设备，5-浆式平直搅拌浆，6-圆盘弯叶浆，7-富氧水雾化喷嘴，8-进料口，9-定量加料设备，10-进油口、11-油泵、12-出料口、13-进水管、14-高压泵、15-富氧水储备箱、16-强力气水混合器、17-管道、18-臭氧发生器、19-导流叶板、20-支承架。In the figure, 1-shell, 2-vertical stirrer, 3-motor, 4-speed shifting equipment, 5-slurry straight mixing slurry, 6-disc curved blade pulp, 7-oxygen water atomizing nozzle, 8 - Feed inlet, 9-quantitative feeding equipment, 10-inlet port, 11-oil pump, 12-discharge port, 13-inlet pipe, 14-high pressure pump, 15-oxygen water reserve tank, 16-strong gas water Mixer, 17-pipe, 18-ozone generator, 19-lead vane, 20-support frame.
具体实施方式detailed description
本实施例为本发明优选实施方式，其他凡其原理和基本结构与本实施例相同或近似的，均在本发明保护范围之内。This embodiment is a preferred embodiment of the present invention, and other principles and basic structures are the same as or similar to those of the present embodiment, and are all within the scope of the present invention.
请参看附图1，本发明中的乳化生物柴油的制作装置主要为壳体1，本实施例中，壳体1上部呈直筒形，下部为半圆体，壳体1内部装有垂直搅拌器2，动力源带动垂直搅拌器2转动，本实施例中，动力源包括电机3和变速设备4，变速设备4固定安装在壳体1顶部，电机3设置在变速设备4上方，电机3通过变速设备4驱动垂直搅拌器2转动。本实施例中，在壳体1底部的半圆体内设有转轴的支承架20，用于支撑垂直搅拌器2的转轴。本实施例中，垂直搅拌器2的中轴适当位置装有若干平直搅拌浆5，也可采用桨式折叶桨替代，同时垂直搅拌器2的中轴下部安装有涡轮或圆盘弯叶浆6，壳体1的圆筒形内壁四周安装若干液体导流叶板10，壳体1的顶部设置有多个进料口8，每个进料口8均通过管道连接有定量加料设备9，本实施例中，各个定量加料设备9用于各种添加剂的自动投料，壳体1的顶部还设有富氧水进水管道13并穿入壳体1内连接富氧水雾化喷嘴7，进水管13连接高压泵14，臭氧发生器18输出O3气体进入强力水气混合器16与水混合后，通过管道17的输送进入富氧水储备箱15，富氧水储备箱15的出水口与高压泵14连接。壳体1上部一侧设有进油口10，其一端由管道穿于壳体内部，另一端连接油泵，同时壳体1下部还设置成品出料口12，所得乳化生物柴油由出料口12输出，再通过管道与泵具输送至油料储存库，本发明中产生的富氧微乳化生物柴油作用于各种热源燃料。Referring to Figure 1, the apparatus for manufacturing emulsified biodiesel in the present invention is mainly a casing 1. In this embodiment, the upper part of the casing 1 has a straight cylindrical shape, the lower part is a semicircular body, and the casing 1 is internally provided with a vertical agitator 2 The power source drives the vertical agitator 2 to rotate. In this embodiment, the power source includes the motor 3 and the shifting device 4, the shifting device 4 is fixedly mounted on the top of the casing 1, the motor 3 is disposed above the shifting device 4, and the motor 3 passes through the shifting device. 4 drives the vertical mixer 2 to rotate. In the present embodiment, a support frame 20 for the rotating shaft is provided in the semicircular body at the bottom of the casing 1 for supporting the rotating shaft of the vertical agitator 2. In the present embodiment, the vertical agitator 2 is equipped with a plurality of straight agitating pulps 5 at a suitable position on the central axis of the vertical agitator 2, and may be replaced by paddle-type vane paddles, and a turbine or disc curved blade is installed at a lower portion of the central axis of the vertical agitator 2 The slurry 6, the cylindrical inner wall of the casing 1 is provided with a plurality of liquid guiding vanes 10, and the top of the casing 1 is provided with a plurality of feeding ports 8, each of which is connected with a dosing device 9 through a pipe. In this embodiment, each of the quantitative feeding devices 9 is used for automatic feeding of various additives, and the top of the casing 1 is further provided with an oxygen-enriched water inlet pipe 13 and penetrates into the casing 1 to connect the oxygen-enriched water atomizing nozzle 7 The inlet pipe 13 is connected to the high-pressure pump 14, and the ozone generator 18 outputs O3 gas into the strong water-gas mixer 16 and mixed with water, and then passes through the pipeline 17 to enter the oxygen-enriched water reserve tank 15, the water outlet of the oxygen-enriched water reserve tank 15. It is connected to the high pressure pump 14. The upper part of the casing 1 is provided with an oil inlet 10, one end of which is threaded inside the casing, and the other end is connected to the oil pump, and the lower part of the casing 1 is also provided with a finished discharge port 12, and the obtained emulsified biodiesel is discharged from the discharge port 12 The output is then sent to the oil storage through the pipeline and the pump. The oxygen-enriched micro-emulsified biodiesel produced in the present invention acts on various heat source fuels.
本发明中的乳化生物柴油的制作方法，即本发明中上述装置的运作方法如下：本发明主要是针对由油脂中通过生产工艺制得的生物柴油进行进一步加工，对生物柴油予以富氧微乳化柴油工艺精制。The method for preparing the emulsified biodiesel in the present invention, that is, the operation method of the above device in the present invention is as follows: the present invention is mainly directed to further processing of biodiesel produced by a production process from oil and fat, and oxygen-enriched microemulsification of biodiesel. Refined diesel technology.
本发明中的乳化生物柴油的制作方法包括下述步骤：The method for preparing the emulsified biodiesel in the present invention comprises the following steps:
（1）、首先对生物柴油进行含水量测定后，将粗生物柴油输入上述的乳化生物柴油装置内，启动搅拌系统，加入30-80%的国III标准柴油后，搅拌5min；(1) First, after measuring the water content of the biodiesel, the crude biodiesel is input into the above emulsified biodiesel device, the stirring system is started, 30-80% of the national III standard diesel oil is added, and the mixture is stirred for 5 minutes;
（2）加入亲水剂，亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂，本实施例中，两类表面活性剂有三乙醇胺、六氢苯胺或西曲溴铵和氨水，配比例为阳离子表面活性剂50%，非离子表面活性剂50%，亲水剂是为了降解面膜的刚性，增加流动性，减少微乳液形成所需要的弯曲能，易于形成乳发液，在加入亲水剂后，稍作1min——15min时间的搅拌；(2) adding a hydrophilic agent, the hydrophilic agent is a composite active agent combined with a cationic surfactant and a nonionic surfactant. In this embodiment, the two types of surfactants are triethanolamine, hexahydroaniline or west. Tribromoammonium bromide and ammonia water, the ratio is 50% of cationic surfactant and 50% of nonionic surfactant. The hydrophilic agent is used to degrade the rigidity of the mask, increase the fluidity, reduce the bending energy required for the formation of microemulsion, and is easy to form. The milking solution is stirred for 1 min to 15 min after the hydrophilic agent is added;
（3）、加入丁醇作为中间体，本实施例中，丁醇可作为助表面活性剂，且继续对混合液作不间接搅拌15min，搅拌时，垂直搅拌器2作100转/min——130转/min的转速搅拌；(3), adding butanol as an intermediate, in this embodiment, butanol can be used as a co-surfactant, and continue to do not indirectly stir the mixture for 15min, when stirring, the vertical stirrer 2 for 100 rev / min - Stirring at 130 rpm;
（4）、加入异戊烷作为自燃温度调节剂，本实施案例中，异戊烷与上述（1）-（3）的液体混合后，再搅拌5min。(4) Adding isopentane as a self-ignition temperature regulator. In the present embodiment, isopentane is mixed with the liquids of the above (1) to (3), and then stirred for 5 minutes.
（5）、分别加入富氧水和十八碳—顺—9—烯酸，富氧水的分量视产品需要，从产品总重量的1%——20%不等，本实施例中，利用臭氧发生器供给O3，臭氧输送的气体流量为250ml/min，并于强力水、气混合器中与水体混合后输入富氧水储备箱自然分解成水中富氧，自然分解时间为30min，使水中溶解氧含量达到27-35%，形成富氧水，通常富氧水的加入量为总重量的10%——20%，当富氧水加入后，再搅拌15min，转速调整为170转/min——200转/min，再加入配方中设定量的酸值为200以上的十八碳—顺—9—烯酸作为乳化剂，本实施例中，十八碳—顺—9—烯酸的加入量为所加入富氧水水重量的70%——90%，在搅拌设备的连续搅拌下直至澄清透明为止，此时，搅拌器的转速调整为280——340转/min，一般需要连续搅拌40——60min，待静置一定时间观察乳化油为清洁透明无分层后为成品。此时已完成整个富氧微乳化生物柴油精制工序，所出产品可以在85℃温度条件下和240天的储存期内不变质的优点，含富氧水20%及含30%以上的国标III石化柴油所制得的微乳化柴油可用于做热源燃料，含富氧水10%以下及含80%以上国标III石化柴油所制得的微乳化柴油可用作清洁车用柴油。(5), respectively, adding oxygen-enriched water and 18-carbon-cis-9-enoic acid, the amount of oxygen-enriched water varies from 1% to 20% of the total weight of the product depending on the product, in this embodiment, The ozone generator supplies O3, the gas flow rate of ozone is 250ml/min, and is mixed with the water body in the powerful water and gas mixer, and then input into the oxygen-rich water storage tank to be naturally decomposed into oxygen enriched in water, and the natural decomposition time is 30 min, so that the water is in the water. The dissolved oxygen content reaches 27-35%, forming oxygen-enriched water. Usually, the oxygen-enriched water is added in an amount of 10%-20% of the total weight. When the oxygen-enriched water is added, the mixture is stirred for 15 minutes, and the rotation speed is adjusted to 170 rpm. ——200 rpm, and then add the 18-carbon-cis-9-enoic acid with an acid value of 200 or more as an emulsifier in the formulation. In this embodiment, octadecyl-cis-9-enoic acid The amount of addition is 70% - 90% of the weight of the oxygen-enriched water added, under the continuous stirring of the stirring equipment until clear and transparent, at this time, the speed of the stirrer is adjusted to 280 - 340 rev / min, generally required Continuous stirring for 40-60min, wait for a certain period of time to observe that the emulsified oil is clean and transparent without delamination. . At this point, the entire oxygen-enriched micro-emulsified biodiesel refining process has been completed, and the product can be degraded under the temperature of 85 ° C and the storage period of 240 days, containing 20% of oxygen-enriched water and more than 30% of the national standard III. The micro-emulsified diesel fuel produced by petrochemical diesel can be used as a heat source fuel, and the micro-emulsified diesel oil containing less than 10% of oxygen-rich water and containing more than 80% of the national standard III petrochemical diesel can be used as a diesel fuel for cleaning vehicles.
通过本发明可将餐厨垃圾中提炼的生物柴油进一步精制，制成富氧微乳化生物柴油，能扩大其应用范围。The biodiesel extracted from the kitchen waste can be further refined by the invention to produce oxygen-enriched micro-emulsified biodiesel, which can expand the application range.

Claims (11)

  1. 一种乳化生物柴油的制作装置，其特征是：所述的装置包括壳体（1），壳体（1）内装有垂直搅拌器（2），动力源带动垂直搅拌器（2）转动，垂直搅拌器（2）的中轴上装有一个以上的浆式平直搅拌浆（5）或桨式折叶桨，垂直搅拌器（2）的中轴下部安装有涡轮或圆盘弯叶浆（6），壳体（1）内的上部装有富氧水雾化喷嘴（7），壳体（1）的顶部设置有一个以上的进料口（8），每个进料口（8）均通过管道连接有一个定量加料设备（9），壳体（1）中上部一侧设有油品进料口（10），并由管道连接于油品输送泵（11），壳体（1）上部装有进水管道（13）并连接高压泵（14），进水管道（13）的水源由富氧水储备箱（15）提供，而富氧水由臭氧发生器（18）输出O3气体，并通过气体输送管道进入强力气水混合器（16）与通过管道（17）进入水体混合后进入富氧水储备箱（15），壳体（1）下部设置有成品出料口（12）。 An apparatus for manufacturing emulsified biodiesel, characterized in that: the device comprises a casing (1), and a vertical agitator (2) is arranged in the casing (1), and the power source drives the vertical agitator (2) to rotate, vertical The middle shaft of the agitator (2) is equipped with more than one slurry type straight mixing slurry (5) or paddle type folding paddle. The lower part of the vertical shaft of the vertical agitator (2) is equipped with a turbine or disc curved blade slurry (6). The upper part of the casing (1) is provided with an oxygen-enriched water atomizing nozzle (7), and the top of the casing (1) is provided with more than one feeding port (8), and each feeding port (8) A dosing device (9) is connected through a pipe, and an oil feed port (10) is arranged on the upper side of the casing (1), and is connected to the oil transfer pump (11) by a pipe, and the casing (1) The upper part is provided with a water inlet pipe (13) and is connected to a high pressure pump (14), the water source of the water inlet pipe (13) is supplied by an oxygen-rich water reserve tank (15), and the oxygen-enriched water is output by the ozone generator (18). And enter the powerful gas-water mixer (16) through the gas transmission pipeline and enter the water body through the pipeline (17) to enter the rich The oxygen water storage tank (15) and the lower part of the casing (1) are provided with a finished product discharge port (12).
  2. 根据权利要求1所述的乳化生物柴油的制作装置，其特征是：所述的壳体（1)上部为圆筒形，下部呈半圆形。The apparatus for manufacturing an emulsified biodiesel according to claim 1, wherein the upper portion of the casing (1) has a cylindrical shape and the lower portion has a semicircular shape.
  3. 根据权利要求2所述的乳化生物柴油的制作装置，其特征是：所述的壳体（1)的圆筒形内壁四周安装一个以上的液体导流叶板（19）。The apparatus for manufacturing an emulsified biodiesel according to claim 2, wherein one or more liquid guiding vanes (19) are installed around the cylindrical inner wall of the casing (1).
  4. 根据权利要求2所述的乳化生物柴油的制作装置，其特征是：所述的壳体（1)底部安装有支撑垂直搅拌器（2）的转轴用的支承架（20）。The apparatus for manufacturing an emulsified biodiesel according to claim 2, characterized in that the bottom of the casing (1) is provided with a support frame (20) for supporting a rotating shaft of the vertical agitator (2).
  5. 根据权利要求1至5中任意一项所述的乳化生物柴油的制作装置，其特征是：所述的动力源包括电机（3）和变速设备（4），变速设备（4）固定安装在壳体（1）顶部，电机（3）设置在变速设备（4）上方，电机（3）通过变速设备（4）驱动垂直搅拌器（2）转动。The apparatus for manufacturing an emulsified biodiesel according to any one of claims 1 to 5, wherein the power source comprises a motor (3) and a shifting device (4), and the shifting device (4) is fixedly mounted to the casing. At the top of the body (1), the motor (3) is placed above the shifting device (4), and the motor (3) drives the vertical agitator (2) to rotate by the shifting device (4).
  6. 一种采用如权利要求1至5所述的乳化生物柴油的制作装置的微乳化生物柴油的制作方法，其特征是：所述的方法包括下述步骤：A method for producing microemulsified biodiesel using the emulsified biodiesel manufacturing apparatus according to any one of claims 1 to 5, wherein the method comprises the following steps:
    （1）、将粗生物柴油输入上述的微乳化生物柴油装置内，启动搅拌系统，加入30-80%国III标准柴油后，搅拌5min；(1), the crude biodiesel is input into the above micro-emulsified biodiesel device, the stirring system is started, 30-80% of the national standard diesel oil is added, and the mixture is stirred for 5 minutes;
    （2）加入亲水剂，加入量为纯生物柴油和国III标准柴油总重量的2-3%，作1min——15min时间的搅拌；(2) adding a hydrophilic agent in an amount of 2-3% of the total weight of the pure biodiesel and the national standard diesel, and stirring for 1 min to 15 min;
    （3）、加入丁醇作为中间体，加入量为纯生物柴油和国III标准柴油总重量的2-4%，继续对混合液作不间接搅拌15min，搅拌时，垂直搅拌器（2）作100转/min——130转/min的转速搅拌；(3) Add butanol as an intermediate, add 2-4% of the total weight of pure biodiesel and National III standard diesel, continue to indirectly stir the mixture for 15 min, stir, vertical stirrer (2) 100 rpm / min - 130 rpm / rpm stirring;
    （4）、加入异戊烷作为自燃温度调节剂，加入量为纯生物柴油总重量的1.5-2%；(4), adding isopentane as a self-ignition temperature regulator, the amount of addition is 1.5-2% of the total weight of pure biodiesel;
    （5）、加入富氧水，水占产品总重量的1%——20%，再搅拌15min，转速调整为170转/min——200转/min，再加入十八碳—顺—9—烯酸作为乳化剂，十八碳—顺—9—烯酸的加入量为所加入干净水重量的70%——90%，在搅拌设备的连续搅拌下直至澄清透明为止，此时，搅拌器的转速调整为280——340转/min，一般需要连续搅拌40——60min，待静置一定时间观察乳化油为清洁透明无分层后为成品。(5), adding oxygen-enriched water, water accounts for 1% - 20% of the total weight of the product, and then stir for 15min, the rotation speed is adjusted to 170 rev / min - 200 rev / min, then add 18 carbon - cis - 9 - The olefinic acid is used as an emulsifier, and the amount of the 18-carbon-cis-9-enoic acid is 70%-90% of the weight of the clean water to be added, and the mixture is continuously stirred until the clarification is transparent. At this time, the agitator The speed is adjusted to 280-340 rev / min, generally requires continuous stirring for 40-60 min. After standing for a certain period of time, observe that the emulsified oil is clean and transparent without delamination.
  7. 根据权利要求6所述的微乳化生物柴油的制作方法，其特征是：所述的亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂，配比例为阳离子表面活性剂50%，非离子表面活性剂50%。The method for preparing a micro-emulsified biodiesel according to claim 6, wherein the hydrophilic agent is a compound active agent in combination with a cationic surfactant and a nonionic surfactant, and the ratio is cation. Surfactant 50%, nonionic surfactant 50%.
  8. 根据权利要求6所述的微乳化生物柴油的制作方法，其特征是：所述的表面活性剂有三乙醇胺或六氢苯胺或西曲溴铵和氨水。The method for preparing microemulsified biodiesel according to claim 6, wherein the surfactant is triethanolamine or hexahydroaniline or cetrimonium bromide and ammonia.
  9. 根据权利要求6所述的微乳化生物柴油的制作方法，其特征是：所述的富氧水的加入量为总重量的10%——20%。The method for preparing microemulsified biodiesel according to claim 6, wherein the oxygen-enriched water is added in an amount of 10% to 20% by weight based on the total weight.
  10. 根据权利要求6所述的微乳化生物柴油的制作方法，其特征是：所述的十八碳—顺—9—烯酸设定量的酸值为200。The method for preparing microemulsified biodiesel according to claim 6, wherein the octadecano-cis-9-enoic acid has a set value of 200.
  11. 根据权利要求6-10中任意一项所述的微乳化生物柴油的制作方法，其特征是：所述的富氧水是由干净水通过脱钙及精滤，并于强力水气混合器中与O3混合合，在富氧水储备箱内转化为溶氧量15%以上的富氧水。The method for preparing micro-emulsified biodiesel according to any one of claims 6 to 10, wherein the oxygen-enriched water is decalcified and finely filtered by clean water, and is mixed in a strong water-gas mixer. It is mixed with O3 and converted into oxygen-enriched water with a dissolved oxygen content of 15% or more in an oxygen-rich water storage tank.
PCT/CN2013/071230 2012-11-23 2013-01-31 Method and apparatus for preparing oxygen-rich micro-emulsified blended biodiesel WO2014079171A1 (en)

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PCT/CN2013/071209 WO2014079166A1 (en) 2012-11-23 2013-01-31 Upright dewatering apparatus
PCT/CN2013/071230 WO2014079171A1 (en) 2012-11-23 2013-01-31 Method and apparatus for preparing oxygen-rich micro-emulsified blended biodiesel
PCT/CN2013/071217 WO2014079168A1 (en) 2012-11-23 2013-01-31 Method and apparatus for biochemical fermentation
PCT/CN2013/071225 WO2014079169A1 (en) 2012-11-23 2013-01-31 Automatic unloading multistage drying apparatus
PCT/CN2013/071235 WO2014079172A1 (en) 2012-11-23 2013-01-31 Exhaust gas treatment system
PCT/CN2013/071237 WO2014079173A1 (en) 2012-11-23 2013-01-31 Plasma photocatalyst negative ion air deodorization and sterilization apparatus
PCT/CN2013/071228 WO2014079170A1 (en) 2012-11-23 2013-01-31 Distillation-free biodiesel production method and system
PCT/CN2013/071210 WO2014079167A1 (en) 2012-11-23 2013-01-31 Apparatus for food waste oxygenation, deodorization, inactivation, salt-reduction by rinsing
PCT/CN2013/071204 WO2014079165A1 (en) 2012-11-23 2013-01-31 Food waste joint screening system
PCT/CN2013/000146 WO2014079135A1 (en) 2012-11-23 2013-02-16 Integrated apparatus for comprehensive treatment of food waste and product manufacturing method

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PCT/CN2013/071217 WO2014079168A1 (en) 2012-11-23 2013-01-31 Method and apparatus for biochemical fermentation
PCT/CN2013/071225 WO2014079169A1 (en) 2012-11-23 2013-01-31 Automatic unloading multistage drying apparatus
PCT/CN2013/071235 WO2014079172A1 (en) 2012-11-23 2013-01-31 Exhaust gas treatment system
PCT/CN2013/071237 WO2014079173A1 (en) 2012-11-23 2013-01-31 Plasma photocatalyst negative ion air deodorization and sterilization apparatus
PCT/CN2013/071228 WO2014079170A1 (en) 2012-11-23 2013-01-31 Distillation-free biodiesel production method and system
PCT/CN2013/071210 WO2014079167A1 (en) 2012-11-23 2013-01-31 Apparatus for food waste oxygenation, deodorization, inactivation, salt-reduction by rinsing
PCT/CN2013/071204 WO2014079165A1 (en) 2012-11-23 2013-01-31 Food waste joint screening system
PCT/CN2013/000146 WO2014079135A1 (en) 2012-11-23 2013-02-16 Integrated apparatus for comprehensive treatment of food waste and product manufacturing method

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