Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
  • B05D5/10—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an adhesive surface
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
  • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
  • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
  • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
  • B32B3/263—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
  • B32B7/04—Interconnection of layers
  • B32B7/06—Interconnection of layers permitting easy separation
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
  • B32B7/04—Interconnection of layers
  • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2250/00—Layers arrangement
  • B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2307/00—Properties of the layers or laminate
  • B32B2307/40—Properties of the layers or laminate having particular optical properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2307/00—Properties of the layers or laminate
  • B32B2307/70—Other properties
  • B32B2307/748—Releasability
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2405/00—Adhesive articles, e.g. adhesive tapes
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2551/00—Optical elements
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/14—Layer or component removable to expose adhesive
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/14—Layer or component removable to expose adhesive
  • Y10T428/1476—Release layer
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/21—Circular sheet or circular blank
  • Y10T428/219—Edge structure
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/2419—Fold at edge
  • Y10T428/24198—Channel-shaped edge component [e.g., binding, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24777—Edge feature
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Definitions

• the present invention relates to an adhesive optical film in which an adhesive layer is laminated on one or both sides of an optical film. Furthermore, at least one layer selected from a release film, an optical layer, an optical film and an adhesive layer is laminated on the adhesive optical film.
• Adhesive optical film and liquid crystal display (LCD), electroluminescent display (ELD), and plasma device using these adhesive optical films are Adhesive optical film and liquid crystal display (LCD), electroluminescent display (ELD), and plasma device using these adhesive optical films
• the present invention relates to an image display device such as a play panel (PDP) and a field emission display (FED: Fie1dEmissionDisplay).
• PDP play panel
• FED field emission display
• a polarizing plate is attached to the outermost surface of the liquid crystal panel.
• various optical elements are used to improve display quality.
• a retardation plate for preventing coloring, a viewing angle widening film for improving the viewing angle, and a brightness enhancement film for increasing the contrast are used.
• Such films are collectively called optical films.
• the adhesive has the advantages of being able to instantly fix the optical film and not requiring a drying step to fix the optical film.
• the adhesive is pre-coated on one or both sides of the optical film as an adhesive layer. Is provided. That is, an adhesive optical film is generally used for attaching an optical film to a liquid crystal panel or the like.
• the pressure-sensitive adhesive optical film is used, for example, during transportation or handling, When transporting on the processing process line, a defect due to the side of the adhesive layer that is exposed to the outside, specifically, the end of the optical film In some cases, the adhesive may drop off as if it were chipped (hereinafter referred to as glue chipping), and the dropped adhesive may contaminate the surface of the optical film (hereinafter referred to as glue stain). . If glue breakage occurs, it will not be possible to adhere securely, but that force will become an air layer and the refractive index and vibration direction of light will be different from those of other parts, resulting in poor display. In addition, similar display defects occur with glue stains.
• Patent Document 1 a method of attaching powder to the end of the adhesive layer (see, for example, Patent Document 1), non-adhesive spray coating to the end of the adhesive layer.
• Patent Document 2 A method of forming a film (for example, see Patent Document 2) or a method of forming the side of an adhesive optical film into a repeating structure of irregularities (for example, see Patent Document 3) has been used.
• these methods involved contamination by foreign substances such as powders and spray coatings, and required complicated processes. Therefore, simpler methods were required.
• Patent Document 1 Japanese Patent Application Laid-Open No. 2000-201 27
• Patent Document 2 Japanese Patent Application Laid-Open No. 2000-2508 627
• Patent Document 3 Japanese Patent Application Laid-Open No. 2000-01-033 623
• the present invention relates to a pressure-sensitive adhesive optical film in which a pressure-sensitive adhesive layer is laminated on one side or both sides of the optical film, wherein the pressure-sensitive adhesive optical film is less likely to cause glue chipping and contamination during transportation, handling, or on a manufacturing or processing process line.
• the purpose is to provide more easily. It is still another object of the present invention to provide a method for producing the pressure-sensitive adhesive optical film and an image display device using the pressure-sensitive adhesive optical film.
• an adhesive optical film in which an adhesive layer is provided on at least one surface of an optical film, that is, at least one surface of the optical film, a portion where the adhesive layer is inside the edge of the optical film.
• An adhesive optical film having: In other words, the optical film and at least one surface of the optical film
• the pressure-sensitive adhesive optical film including the laminated pressure-sensitive adhesive layer at least a part of the edge of the pressure-sensitive adhesive layer is located inside the edge of the optical film.
• the edge of the pressure-sensitive adhesive layer located inside the edge of the optical film is referred to as “inner edge”.
• At least one layer selected from a release film, an optical layer, an optical film, and an adhesive layer can be further laminated on the adhesive optical film.
• the adhesive optical film of the present invention can be applied to image display devices such as LCD, ELD, and FED.
• the present invention by pressing the pressure-sensitive adhesive layer formed on the optical film from both sides, the side of the adhesive layer is cut or cut while the pressure-sensitive adhesive layer is protruded from the end of the side surface of the film.
• a method for producing a pressure-sensitive adhesive optical film that releases a pressurized state to a pressure-sensitive adhesive layer after cutting is provided.
• the pressure-sensitive adhesive layer of the pressure-sensitive adhesive optical film in which the pressure-sensitive adhesive layer is laminated on one or both surfaces of the optical film, is located inside the edge of the optical film, so that it is easier than before. It is possible to obtain an adhesive-type optical film that is not easily contaminated (glue stains) due to the sticking out of the adhesive at the end during transportation, handling, or on the production and processing process lines.
• FIGS. 1A and 1B are cross-sectional views of the pressure-sensitive adhesive optical film of the present invention
• FIGS. 2A to 2D are cross-sectional views showing examples of the shape of a pressure-sensitive adhesive layer in the pressure-sensitive adhesive optical film of the present invention.
• 3A and 3B are cross-sectional views showing examples of the shape of the pressure-sensitive adhesive layer in the pressure-sensitive adhesive optical film having two or more pressure-sensitive adhesive layers of the present invention
• FIG. 4A is an example of an image display device manufactured using the adhesive optical film of FIGS. 1A and 2A, and FIG. 4B is manufactured using the adhesive optical film of FIG. 3A. 19 is an example of an image display device.
• 1 is an optical film
• 2 is an adhesive layer
• 3 is a release film, any one of an optical layer, an optical film, and an adhesive layer
• 4 is an adhesive optical film.
• the pressure-sensitive adhesive optical film according to the present invention is manufactured by forming a pressure-sensitive adhesive layer on one side or both sides of the optical film. It can also be used as an adhesive optical film in which a film or an optical layer is laminated. Further, it is not preferable to leave or transport the pressure-sensitive adhesive layer in a state where it is exposed and in contact with the air interface, and it is preferable to provide a pressure-sensitive adhesive optical film provided with a release film layer for the purpose of protection until use. I like it.
• FIGS. 1A and 1B show a basic example of an adhesive optical film.
• the pressure-sensitive adhesive optical film 4 is manufactured by laminating the pressure-sensitive adhesive layer 2 on one side or both sides of the optical film 1, that is, at least one side of the optical film. As shown in FIGS. 3A and 3B, two or more adhesive pressure-sensitive optical films 4 may be laminated. Further, a layer 3 selected from a release film, an optical layer, an optical film and an adhesive layer may be laminated. Examples of the optical film include a film supported by a support such as a film among optical elements used for forming an image display device.
• a polarizing plate for example, a polarizing plate, a polarization conversion element, a reflecting plate or a semi-transmitting plate, a retardation plate (including a wavelength plate ( ⁇ plate) such as 12 ⁇ 14), a viewing angle compensation film, a brightness enhancement film, and a protective film Film.
• an optical element used for forming an image display device which is formed directly on the optical film or via an adhesive layer or an adhesive layer, is used.
• various alignment liquid crystal layers having characteristics of controlling viewing angle compensation and birefringence characteristics, and various types of layers such as an easy adhesion treatment layer, a hard coat layer, an anti-reflection layer, an anti-stating layer, a diffusion layer, and an anti-glare layer.
• a surface treatment layer e.g., a surface treatment layer.
• an appropriate thin layer such as a synthetic resin film such as polyethylene, polypropylene, or polyethylene terephthalate, a rubber sheet, paper, cloth, a nonwoven fabric, a net, a foam sheet, a metal foil, or a laminate thereof is used. be able to. Also, on the surface of the release film, in order to enhance the releasability from the adhesive layer, It is preferable that a treatment such as a silicone treatment, a long-chain alkyl treatment, a fluorine treatment or the like be performed as necessary.
• a treatment such as a silicone treatment, a long-chain alkyl treatment, a fluorine treatment or the like be performed as necessary.
• the pressure-sensitive adhesive composition for forming the pressure-sensitive adhesive layer of the pressure-sensitive adhesive optical film of the present invention is not particularly limited as long as it does not adversely affect the required optical properties. , Acrylacrylic oligomers and silane coupling agents, and photopolymerization initiators added to acrylic polymers
• the acryl-based polymer can be obtained by copolymerizing a monomer having a functional group that reacts with a polyfunctional compound with alkyl (meth) acrylate as a main monomer. Further, a carboxyl group can be introduced into the acrylic polymer.
• the acrylic polymer has a weight average molecular weight of 400,000 or more, and preferably 100,000 to 200,000.
• (meth) acrylate refers to acrylate and z or metatarylate, and has the same meaning as (meth) in the present invention.
• the average number of carbon atoms in the alkyl group of the alkyl (meth) acrylate that constitutes the main skeleton of the acrylic polymer is about 1 to 12.
• the specific example of the alkyl (meth) acrylate is methyl (meth). Examples include acrylate, ethyl (meth) atalylate, butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, and isootatyl (meth) acrylate. These can be used alone or in combination.
• Examples of the monomer unit having a functional group that reacts with the polyfunctional compound copolymerized with the acryl-based polymer include a monomer having a carboxyl group, a hydroxyl group, an epoxy group, or the like.
• Examples of the monomer having a carboxyl group include acrylic acid, methacrylic acid, fumaric acid, maleic acid, and itaconic acid.
• Examples of the monomer having a hydroxyl group include 2-hydroxyhexyl (meth) acrylate, hydroxybutyl (meth) acrylate, hydroxyhexyl (meth) acrylate, and N-methylol (meth) acrylamide.
• Examples of monomers having an epoxy group include glycidyl (meth) acrylate. Can be Among them, in the present invention, it is particularly preferable to use a monomer having a carboxyl group.
• a monomer unit 1 having an N element can be introduced into the acryl-based polymer.
• the N element-containing monomer include (meth) acrylamide, N, N-dimethyl (meth) acrylamide, N, N-getyl (meth) acrylamide,
• Atariloyl morpholine (meth) acetonitrile, bulpyrrolidone, N-cyclohexylmaleimide, itaconimid, N, N-dimethylaminoethyl (meth) acrylamide and the like.
• acryl-based polymer butyl acetate, styrene and the like can be used as long as the performance of the adhesive is not impaired. These monomers can be used alone or in combination of two or more.
• the proportion of the monomer unit in the acryl-based polymer is not particularly limited, but is about 0.1 to 12 parts by weight, more preferably 0.1 to 12 parts by weight, per 100 parts by weight of the alkyl (meth) acrylate. It is preferable to use 5 to 10 parts by weight in terms of durability.
• the acrylic polymer can be produced by various known methods.
• a radical polymerization method such as a barta polymerization method, a solution polymerization method, or a suspension polymerization method, or a photopolymerization method using UV light or the like can be appropriately selected.
• the radical polymerization initiator various known azo-based and peroxide-based initiators can be used.
• the reaction temperature is usually about 50 to 85 ° C., and the reaction time is about 1 to 10 hours.
• a solution polymerization method is preferable, and a polar solvent such as ethyl acetate or toluene is generally used as a solvent for the acryl-based polymer.
• the solution concentration is usually about 20 to 80% by weight.
• a method of producing the acryl-based polymer by UV polymerization using a photopolymerization initiator composed of benzophenone or the like is also preferably used.
• an acryl polymer having a weight average molecular weight of 400,000 or more is used as the acrylic polymer, and a weight average molecular weight of 800 to 50,000, more preferably 100, 000 having good compatibility with the acryl polymer. It is also possible to use from 100 to 10,000 acrylate oligomers.
• the amount of the acrylol oligomer used is 1 to 300 parts by weight, preferably 10 to 250 parts by weight, more preferably 20 to 200 parts by weight, based on 100 parts by weight of the acrylyl-based polymer. Parts by weight are more preferred. If the amount of the acrylic oligomer is less than 1 part by weight, good reworkability cannot be obtained because the adhesive strength is too strong.
• the amount of the acrylic oligomer is more than 70 parts by weight, failure under high temperature and high humidity conditions ( (Foaming, peeling).
• the glass transition temperature of the acrylic oligomer is between 15 ° C. and 100 ° C., preferably between 15 ° C. and 170 ° C. If the weight-average molecular weight is less than 800, the adhesive properties change due to contamination of the glass substrate surface to be adhered and bleeding of low molecular weight components, which is not preferable. On the other hand, if the glass transition temperature is higher than 15 ° C or the weight average molecular weight is higher than 50,000, the adhesive strength is strong and good reworkability cannot be obtained.
• the molecular weight distribution of the acrylic oligomer is preferably from 1 to 2, more preferably from 1 to 1.7. If the molecular weight distribution is larger than 2, the adhesive property changes due to contamination on the surface of the glass substrate as an adherend and the bridging of low molecular weight components, which is not preferable.
• the acryl oligomer one having a main skeleton of the same alkyl (meth) acrylate monomer unit as the above-mentioned acrylic polymer can be used, and one obtained by copolymerizing the same copolymer monomer can also be used.
• the acrylic oligomer can be produced by various known methods, for example, a method of producing by a living radical polymerization using a specific polymerization activator and a radical polymerization initiator. By using this method, an acrylyl oligomer having a narrow molecular weight distribution can be easily produced in the absence of a solvent or in the presence of a small amount of a solvent without causing problems such as control of the heat of polymerization.
• a transition metal and its ligand are used as the radical polymerization initiator.
• Transition metals include Cu, Ru, Fe, Rh, V, and Ni, and halides (chlorides, bromides, and the like) of these metals are usually used.
• the ligand coordinates the transition metal to form a complex, and a biviridine derivative, a mercaptan derivative, a trifluorate derivative or the like is preferably used.
• the Cu + 1 -biviridine complex is most preferable in terms of polymerization stability and polymerization rate.
• radical polymerization initiator examples include ester compounds containing a halogen at the a-position.
• a styrene derivative is preferable, and a 2-bromo (or chloro) propionic acid derivative and a chloride (or bromide) 1-phenyl derivative are particularly preferably used.
• the radical polymerization initiator is preferably used in a proportion of usually about 0.01 to 5 mol% with respect to the polymerization component.
• the transition metal is used in an amount of usually about 0.01 to 1 mol, based on 1 mol of the radical polymerization initiator, in the form of a halide.
• the ligand is usually used in a proportion of about 1 to 3 mol per 1 mol of the above transition metal (in the form of a halide or the like).
• Such living radical polymerization can proceed in the absence of a solvent, or may proceed in the presence of a solvent such as butyl acetate, toluene, and xylene.
• a solvent such as butyl acetate, toluene, and xylene.
• the polymerization conditions include a polymerization temperature of about 50 to 130 ° C. and a polymerization time of about 1 to 24 hours from the viewpoint of polymerization rate and deactivation of the catalyst.
• the acrylic oligomer thus formed is a polymer comprising a homopolymer, a random copolymer, or a block copolymer and having a narrow molecular weight distribution (weight average molecular weight Z number average molecular weight).
• the random copolymer can be formed by sequentially subjecting two or more monomers to living radical polymerization.
• the number average molecular weight is a value used in terms of polystyrene by GPC (gel permeation chromatography).
• the photopolymerization initiator various types can be used without particular limitation.
• Irgacure (Irgacure) 907, 184, 651, and 369 manufactured by Ciba Chemical Corporation can be exemplified.
• the amount of the photopolymerization initiator to be added is preferably about 0.5 to 30 parts by weight based on 100 parts by weight of the polymerization component.
• a polyfunctional compound can be used for the pressure-sensitive adhesive composition.
• the polyfunctional compound include an organic crosslinking agent and a polyfunctional metal chelate.
• the organic crosslinking agent include an epoxy crosslinking agent, an isocyanate crosslinking agent, and an imine crosslinking agent.
• Multifunctional metal chelates are those in which a polyvalent metal is covalently or coordinated with an organic compound.
• the polyvalent metal atoms include Al, Cr, Zr, Co, Cu, Fe, Ni, V, Zn, In, Ca, Mg, Mn, Y, Ce, Sr, Ba, Mo, La, SN, Ti and the like.
• the atom in the organic compound which forms a covalent bond or a coordinate bond includes an oxygen atom and the like, and the organic compound includes an alkyl ester, an alcohol compound, a carboxylic acid compound, an ether compound, a ketone compound and the like.
• the organic compound includes an isocyanate-based crosslinking agent.
• the isocyanate-based crosslinking agent used in the pressure-sensitive adhesive composition a compound having two or more isocyanate groups in one molecule can be used without particular limitation.
• Nate and the like can be used.
• Commercially available trade names of these isocyanates include those manufactured by Nippon Polyurethane Industry Co., Ltd .: Coronate L, Coronate HL, Coronate 2030, Coronate 2 031, Millionate MR, Millionate MTL, Takeda Pharmaceutical Co., Ltd .: Takenate D—102, Takenate D—11 ON, Takenate D—200, Takenate D—202, Sumitomo Bayer Made by Urethane Co .: Death module L, Death module IL, Death module N, Death module HL, etc. Further, these can be used alone or in combination of two or more.
• the mixing ratio of the acryl-based polymer and the isocyanate-based cross-linking agent is not particularly limited, but is preferably about 0.05 to 6 parts by weight, and preferably about 0.05 to 6 parts by weight of the isocyanate-based cross-linking agent with respect to 100 parts by weight of the acrylic polymer (solid content). 0.1 to 3 parts by weight.
• the pressure-sensitive adhesive composition may include, if necessary, a filler, a pigment, a coloring agent, a filler comprising a tackifier, a plasticizer, glass fibers, glass beads, metal powder, and other inorganic powders.
• a filler a pigment, a coloring agent, a filler comprising a tackifier, a plasticizer, glass fibers, glass beads, metal powder, and other inorganic powders.
• An agent, an antioxidant, an ultraviolet absorber, a silane coupling agent, and the like, and various additives can be appropriately used without departing from the object of the present invention.
• a pressure-sensitive adhesive layer containing fine particles and exhibiting light diffusing properties may be used. In the present invention, it is preferable to add a silane coupling agent for the purpose of adjusting the adhesive strength.
• silane coupling agent examples include burtriethoxysilane, burtris (] 3-methoxetoxy) silane, ⁇ -methacryloxypropyltrimethoxysilane, burtriacetoxysilane, ⁇ -glycidoxypropyltrimethoxysilane, and ⁇ -glycol.
• silane, ⁇ - ⁇ (aminoethyl) - ⁇ -aminopropyl trimethoxysilane, and the like One of these can be used alone, or two or more can be used in combination.
• the amount of the silane coupling agent to be added in the present invention must be usually 0.01 to 5.0 parts by weight to 100 parts by weight of the acrylic polymer (solid content). It is preferred to add 0.0 parts by weight.
• the method for forming the pressure-sensitive adhesive layer is not particularly limited. For example, a method in which a pressure-sensitive adhesive composition (solution) is applied to one or both sides of an optical film and dried, or a method in which the pressure-sensitive adhesive composition is applied on a release film Apply, dry, and irradiate UV A method of forming an adhesive layer, attaching the adhesive film to one side or both sides of the optical film via the adhesive layer, and peeling off the release film to transfer the adhesive film. At this time, the pressure-sensitive adhesive composition applied on the optical film or the release film may be irradiated with an appropriate amount of UV beforehand, if necessary.
• the drying temperature of the pressure-sensitive adhesive layer is appropriately adjusted depending on the type of the pressure-sensitive adhesive composition, but is generally preferably 70 to 150 ° C.
• the drying time is preferably about 1 to 5 minutes.
• the thickness (film thickness after drying) of the pressure-sensitive adhesive layer is not particularly limited, but is preferably 5 to 50 / im. If the thickness is less than 5 ⁇ , it tends to peel off, and problems with durability tend to occur. Further, a pressure-sensitive adhesive layer having a thickness of more than 50; zm has an excessively high adhesive strength, and is therefore not preferable when used for an optical film designed in consideration of removability. However, when the polymerization method by UV irradiation is used, the pressure-sensitive adhesive layer can be formed with a thickness of about 10 ⁇ m
• the shock-absorbing property is improved, so that when the pressure-sensitive adhesive layer is bonded to another optical film, panel, or the like, the impact caused by the vibration or the like is reduced. Has been found to increase the effect of preventing damage.
• the edge of the pressure-sensitive adhesive layer exists inside the edge of the optical film laminated on the pressure-sensitive adhesive layer (inner edge).
• the cross-sectional shape of the pressure-sensitive adhesive layer at this time is, for example, generally the cross-sectional shape shown in FIG. 1A.
• a part of the cross section of the pressure-sensitive adhesive layer 2 extends to near the edge of the optical film 1 or the layer 3, that is, a shape extending outward. Can also be taken.
• the portion extending outward that is, the portion where the pressure-sensitive adhesive layer 2 and the optical film 1 or the layer 3 are in contact with each other is near the edge of the optical film 1 or the layer 3 unless it protrudes from the edge. There may be. That is, the portion extending outward may be located at least 0 / m inside the edge of the optical film 1. Furthermore, the portion having the shape extending outward is preferably used at a position located about 5 to 50 ⁇ inward from the edge of the optical film 1, because the adhesive is less likely to be chipped.
• a concave end face 5 having a concave cross section is formed.
• Slope-shaped end faces 6, 7 having a cross-sectional shape of a slope are formed.
• a shape consisting of Fig. 1A, Fig. 2A or Fig. 2C (the cross section of the pressure-sensitive adhesive layer extends outward from the layer 3 side toward the optical film 1 side at the inclined end face 7) It is preferable to form a pressure-sensitive adhesive layer in order to reduce the likelihood of chipping. Further, as shown in FIGS. 3A and 3B, even when the pressure-sensitive adhesive optical film has two or more pressure-sensitive adhesive layers, each of the pressure-sensitive adhesive films is located inside the edge of the optical film in the pressure-sensitive adhesive layer. The presence or absence and shape of a certain part can be determined as appropriate.
• the part where the adhesive layer is inside the edge of the optical film is effective if it is formed on at least a part of the edge of the optical film, but the part where the adhesive layer is inside the edge of the optical film is effective.
• the effect is higher as the ratio of is larger for all edges.
• the shape of the optical film it is preferably formed to be at least 1/2 of the total perimeter, and more preferably at least 3/4 of the total perimeter. In particular, it is particularly preferable to be formed on all the edges.
• the cross-sectional shape of the part where the pressure-sensitive adhesive layer is inside the edge of the optical film may be different at each edge as shown in FIG. 2D. In the pressure-sensitive adhesive optical film of FIG. 2D, in addition to the concave end face 5, a convex end face 8 having a convex cross section is formed.
• a pressure-sensitive adhesive layer is formed on the inside of the punched optical film by a predetermined amount from the edge of the optical film.
• a method of designing so that the adhesive layer is applied or a method of removing only the adhesive layer after applying or transferring the adhesive layer (half cut).
• the optical film or the release film sandwiching the adhesive layer may have different sizes.
• a pressure-sensitive adhesive layer may be formed on the entire surface of a release film or an optical film having a smaller area than the optical film on which the pressure-sensitive adhesive layer needs to be formed, and may be bonded to the optical film. At this time, if a release film with a small area is used, the release film is peeled off and then bonded to another optical film via this adhesive layer to obtain the configuration shown in Fig. 1A. It can be. Edge of the adhesive layer edge located inside the edge of the optical film and edge of the optical film For example, when the adhesive layer is formed on a liquid crystal panel with a narrow frame, which has become widespread in recent years, if the distance is too long, it may cause display problems, and the distance is too short.
• This distance is generally 10 ⁇ ! It is sufficient if it is in the range of 300 m to 300 m, more preferably in the range of 20 m to 250 Aim, and particularly preferably in the range of 50 / m to 150 Atm.
• an adhesive optical film in which an optical film is laminated on both sides of an adhesive layer, pressure is applied from both sides of the adhesive optical film with the adhesive layer sandwiched between them (a case where one side is fixed and pressure is applied only from the other side).
• the adhesive layer is protruded from the end of the optical film, and the pressure-sensitive adhesive layer is cut from the edge of the optical film after cutting or cutting the protruded adhesive layer, thereby releasing the pressure-sensitive adhesive layer from the optical film edge.
• a suitable pressure-sensitive adhesive when such a method is used, a pressure-sensitive adhesive that is easily restored to its original shape by release of a force is preferable, and thus a more elastic pressure-sensitive adhesive is suitably used.
• the storage elastic modulus at 25 ° C. determined by dynamic viscoelasticity is preferably 1.0 ⁇ 10 4 to 1.0 ⁇ 10 7 Pa, and 1 . and more preferably 0 X 1 0 4 ⁇ 1. OX 1 0 6 P a.
• the loss elastic modulus at 25 ° C determined by dynamic viscoelasticity is preferably from 1.0 X 10 2 to 1.0 X 10 7 Pa, and 1. ⁇ ⁇ 1 0 3 to 1. more preferably 0 X 1 0 5 P a.
• a viscoelasticity measurement device (ARES: manufactured by Rheometrics Scientific F. Ltd.) was used to measure at a temperature in the range of 50 ° C to 150 ° C. The value at 25 ° C was used.
• a method of retracting the pressure-sensitive adhesive layer inward a method of pulling the pressure-sensitive adhesive layer from one side or both sides of the pressure-sensitive adhesive optical film to the outside in the thickness direction of the pressure-sensitive adhesive layer is also possible.
• an adhesive that is preferably plastically deformed by force is preferable, and a more viscous adhesive is preferably used.
• a method for adjusting the distance from the edge of the portion inside the edge of the optical film to the inside is as follows.
• the method of forming the pressure-sensitive adhesive layer having a shape as shown in FIG. 2C includes a method of half-cutting the pressure-sensitive adhesive layer, and a method of pressing the pressure-sensitive adhesive optical film as described above to cut the pressure-sensitive adhesive layer.
• a diagonal shaving method to release the pressurized state to the shape shown in Fig. 2C
• a method of laminating a release film or an optical film can be used. Further, such a shape may be formed even when the interfacial properties of two films sandwiching the pressure-sensitive adhesive layer are significantly different.
• the optical film and the pressure-sensitive adhesive layer in the present invention are treated with an ultraviolet absorber such as, for example, a salicylate ester compound, a benzophenol compound, a benzotriazole compound, a cyanoatalylate compound, and a nickel complex compound. It may have ultraviolet absorption ability by such a method.
• an ultraviolet absorber such as, for example, a salicylate ester compound, a benzophenol compound, a benzotriazole compound, a cyanoatalylate compound, and a nickel complex compound. It may have ultraviolet absorption ability by such a method.
• optical film those used for forming an image display device are used, and the type thereof is not particularly limited. Examples thereof include a polarizing plate, a retardation plate, an elliptically polarizing plate, a viewing angle compensation film, and a brightness enhancement film. No.
• a polarizing plate having a transparent protective film on one or both sides of a polarizer used for a liquid crystal display device is generally used.
• the polarizer is not particularly limited, and various types can be used.
• dichroic substances such as iodine and dichroic dyes can be used for hydrophilic polymer films such as polyvinyl alcohol-based films, partially formalized polyvinyl alcohol-based films, and ethylene-vinyl acetate copolymer-based partially saponified films.
• polyaxially oriented films such as dehydration products of polyvinyl alcohol and dehydrochlorination products of polyvinyl chloride.
• Polyvinyl alcohol-based film and A polarizer made of a dichroic substance such as silicon is preferable.
• the thickness of these polarizers is not particularly limited, but is generally about 5 to 80 / zm.
• a polarizer obtained by dyeing a polyvinyl alcohol-based film with iodine and uniaxially stretching is created by, for example, dyeing polyvinyl alcohol by immersing it in an aqueous solution of iodine and stretching it 3 to 7 times its original length. be able to. If necessary, it may contain boric acid, zinc sulfate, zinc chloride or the like, and can be immersed in an aqueous solution of potassium iodide or the like. Further, if necessary, the polyvinyl alcohol-based film may be immersed in water and washed with water before dyeing.
• Stretching may be performed after dyeing with iodine, may be performed while dyeing, or may be dyed with iodine after stretching.
• the film can be stretched in an aqueous solution of boric acid boride or the like or in a water bath.
• polyester-based polymers such as polyethylene terephthalate and polyethylene naphthalate; cenorellose-based polymers such as diacetylinocellulose and triacetyl cellulose; acryl-based polymers such as polymethinolemethacrylate; polystyrene and acrylonitrile styrene copolymer (AS Styrene-based polymers such as resin) and polycarbonate-based polymers.
• polyethylene, polypropylene, polyolefin having a cyclo- or norbornene structure polyolefin-based polymer such as ethylene-propylene copolymer, bichloride-based polymer, amide-based polymer such as nylon or directional group-based polymer, and imid-based polymer , Snorefon-based polymer, polyethers-snolefone-based polymer, polyether / polyethylene ketone-based polymer, polyphenylene sulfide-based polymer, bier alcohol-based polymer, bi-lidene chloride-based polymer, vinyl butyral-based polymer, arylate-based polymer , Polyoxymethylene polymer, epoxy polymer, Examples of the polymer which forms the transparent protective film include a blend of the polymer and the like.
• the transparent protective film can be formed as a cured layer of a thermosetting resin or an ultraviolet curable resin such as an acryl-based, urethane-based, acrylic urethane-based, epoxy-based, or silicone-based resin. Of these, those having a hydroxyl group that is reactive with the isocyanate crosslinking agent are preferred, and cellulosic polymers are particularly preferred.
• the thickness of the transparent protective film is not particularly limited, but is generally at most 500 / im, preferably from 1 to 300 ⁇ m. Particularly, the thickness is preferably 5 to 200 ⁇ m. Further, as the transparent protective film, a polymer film described in Japanese Patent Application Laid-Open No.
• a film of a resin composition containing an alternating copolymer composed of isobutene and N-methylmaleimide and an acrylonitrile-styrene copolymer is exemplified.
• a film made of a mixed extruded product of a resin composition or the like can be used.
• the thickness of the transparent protective film is not particularly limited, but is generally 500 ⁇ m or less, preferably 1 to 300 ⁇ m. In particular, the thickness is more preferably 5 to 200 ⁇ m. In addition, it is preferable that the surface of the protective film is saponified with an alkali or the like in view of polarization characteristics and durability.
• a transparent protective film having a retardation value in the film thickness direction of 190 to +75 nm represented by the following formula is preferably used.
• the retardation value (Rth) in the thickness direction is more preferably from 180 to +60 nm, and particularly preferably from 170 to +45 nm.
• the surface of the transparent protective film on which the polarizer is not adhered (the surface on which the coating layer is not provided) has been subjected to a hard coat layer, an antireflection treatment, a treatment for preventing stinging, and a treatment for diffusion or antiglare. There may be.
• the hard coat treatment is performed for the purpose of preventing the polarizing plate surface from being scratched.
• a cured film made of an appropriate acryl-based or silicone-based UV-curable resin with excellent hardness and sliding properties is used as a transparent protective film. It can be formed by a method of adding it to the surface of the device.
• the anti-reflection treatment is performed for the purpose of preventing the reflection of external light on the polarizing plate surface, and can be achieved by forming an anti-reflection film or the like according to the related art. Further, the anti-stating treatment is performed for the purpose of preventing adhesion to an adjacent layer.
• the anti-glare treatment is performed for the purpose of preventing external light from being reflected on the surface of the polarizing plate and obstructing the permeation of the light transmitted through the polarizing plate.
• a sand blast method or an embossing method is used.
• the transparent protective film can be formed by giving a fine uneven structure to the surface of the transparent protective film by an appropriate method such as a surface roughening method by a method or a method of blending transparent fine particles.
• the fine particles to be included in the formation of the surface fine unevenness include a silica force having an average particle diameter of 0.5 to 50 ⁇ m, alumina, titania, zirconia, tin oxide, indium oxide, cadmium oxide, and antimony oxide.
• Transparent fine particles such as inorganic fine particles which may be conductive and organic fine particles comprising a crosslinked or uncrosslinked polymer or the like are used.
• the amount of the fine particles used is generally about 2 to 50 parts by weight, and 5 to 25 parts by weight, based on 100 parts by weight of the transparent resin forming the fine surface uneven structure. Parts are preferred.
• the anti-glare layer may also serve as a diffusion layer (viewing angle expanding function, etc.) for expanding the viewing angle by diffusing light transmitted through the polarizing plate.
• the anti-reflection layer, anti-sticking layer, diffusion layer, anti-glare layer and the like can be provided on the transparent protective film itself, or can be separately provided as an optical layer separately from the transparent protective film.
• the bonding treatment between the polarizer and the transparent protective film is not particularly limited.
• an adhesive made of BULL polymer, or a BURU alcohol-based material such as boric acid or borax, Daltar aldehyde ⁇ melamine, oxalic acid, etc.
• Water-soluble polymer frame It can be performed via an adhesive or the like made of at least a bridging agent.
• This adhesive layer can be formed as a layer for applying and drying an aqueous solution. When the aqueous solution is prepared, other additives and a catalyst such as an acid can be blended as necessary.
• the optical film of the present invention can be used by laminating another optical layer in practical use.
• the optical layer is not particularly limited.
• it is used for forming a liquid crystal display device such as a reflection plate, a semi-transmission plate, a retardation plate (including a wavelength plate such as 1Z2 and 1Z4), and a viewing angle compensation film.
• a liquid crystal display device such as a reflection plate, a semi-transmission plate, a retardation plate (including a wavelength plate such as 1Z2 and 1Z4), and a viewing angle compensation film.
• One or more optical layers that may be used can be used.
• a reflective polarizing plate or a transflective polarizing plate in which a reflecting plate or a transflective reflecting plate is further laminated on a polarizing plate; an elliptically polarizing plate or a circular polarizing plate in which a retardation plate is further laminated on a polarizing plate;
• a wide viewing angle polarizing plate in which a viewing angle compensation film is roughly laminated on a plate, or a polarizing plate in which a brightness enhancement film is further laminated on a polarizing plate is preferable.
• the reflective polarizing plate is a polarizing plate provided with a reflective layer, and is used to form a liquid crystal display device or the like that reflects and reflects incident light from the viewing side (display side). It has the advantage that the built-in light source such as a light can be omitted, and the liquid crystal display device can be made thinner.
• the reflective polarizing plate can be formed by an appropriate method such as a method in which a reflective layer made of metal or the like is provided on one surface of the polarizing plate via a transparent protective layer or the like, if necessary.
• a specific example of a reflective polarizing plate is one in which a reflective layer is formed by attaching a foil made of a reflective metal such as aluminum to one side of a matte-treated transparent protective film and depositing a vapor-deposited film as necessary.
• a transparent protective film in which fine particles are contained to form a fine surface unevenness structure, and a reflective layer having a fine unevenness structure is formed thereon.
• the reflective layer having the above-described fine uneven structure has an advantage that the incident light is diffused by irregular reflection to prevent a directional glare and to suppress uneven brightness.
• the transparent protective film containing fine particles has an advantage that the incident light and its reflected light are diffused when transmitted through the film, and the unevenness in brightness can be further suppressed.
• the formation of the reflective layer having a fine uneven structure reflecting the fine uneven structure on the surface of the transparent protective film is performed by, for example, a vacuum deposition method, an ion plating method, a sputtering method, or the like.
• An appropriate method such as a vapor deposition method or a plating method can be used, for example, by directly attaching a metal to the surface of the transparent protective layer.
• the reflection plate can be used as a reflection sheet or the like in which a reflection layer is provided on an appropriate film according to the transparent film, instead of the method of directly applying the reflection plate to the transparent protective film of the polarizing plate.
• the reflective layer is usually made of a metal
• the use of the reflective layer covered with a transparent protective film and a polarizing plate is important in preventing the decline in reflectance due to oxidation and maintaining the initial reflectance over a long period of time. It is preferable because it avoids separately providing a protective layer.
• the transflective polarizing plate can be obtained by forming a transflective reflective layer such as a half mirror that reflects and transmits light on the reflective layer.
• the transflective polarizing plate is usually provided on the back side of the liquid crystal cell.
• a liquid crystal display device When a liquid crystal display device is used in a relatively bright atmosphere, an image is displayed by reflecting incident light from the viewing side (display side). In a relatively dark atmosphere, it is possible to form a liquid crystal display device of a type for displaying an image by using a built-in light source such as a backlight built in a back side of a transflective polarizing plate.
• a transflective polarizing plate can save energy for using a light source such as a backlight in a bright atmosphere, and is useful for forming a liquid crystal display device that can be used with a built-in light source even in a relatively bright atmosphere.
• An elliptically polarizing plate or a circularly polarizing plate in which a retardation plate is further laminated on a polarizing plate will be described.
• a so-called 1Z4 wavelength plate (also referred to as a ⁇ / 4 plate) is used as a retardation plate that converts linearly polarized light into circularly polarized light or converts circularly polarized light into linearly polarized light.
• a 1Z2 wavelength plate (also referred to as an LZ2 plate) is usually used to change the polarization direction of linearly polarized light.
• the elliptically polarizing plate compensates (prevents) the coloring (blue or yellow) caused by the birefringence of the liquid crystal layer of the super twisted nematic (STN) type liquid crystal display device, and is effective in the case of black-and-white display without coloring. Used.
• the control of the three-dimensional refractive index compensates (prevents) coloring that occurs when the screen of the liquid crystal display device is viewed from an oblique direction. Is preferred.
• the circularly polarizing plate is effectively used, for example, when adjusting the color tone of an image of a reflection type liquid crystal display device for displaying an image in color, and also has an antireflection function.
• the retardation plate examples include a birefringent film obtained by uniaxially or biaxially stretching a polymer material, a liquid crystal polymer alignment film, and a film in which a liquid crystal polymer alignment layer is supported by a film.
• the stretching treatment can be performed, for example, by a roll stretching method, a long gap stretching method, a tenter stretching method, a tubular stretching method, or the like.
• the stretching magnification is generally about 1.1 to 3 times.
• the thickness of the retardation plate is not particularly limited, but is generally 10 to 200 ⁇ , preferably 20 to 100 / ⁇ .
• polymer material examples include polybutyl alcohol, polybutyral, polymethinolebininoleether, polyhydroxyxenotinoleacrylate, hydroxyxine chinoresenorelose, hydroxypropinoresenololose, methinoresenololose, Polycarbonate, Polyarylate, Polysulfone, Polyethylene terephthalate, Polyethylene naphthalate, Polyethenoresnorefone, Polyphenylene sulfide, Polyphenylene oxide, Polyallyl sulfone, Polybutyl alcohol, Polyamide, Polyimide, Polyolefin, Polyolefins having a norbornene structure, polychlorinated vinyl chloride, cellulosic polymers, or binary, ternary copolymers, graft copolymers, or blends of these Throw. These polymer materials become oriented materials (stretched films) by stretching or the like.
• liquid crystal polymer examples include various main chain and side chain types in which a conjugated linear atomic group (mesogen) imparting liquid crystal orientation is introduced into the main chain or side chain of the polymer.
• main chain type liquid crystal polymer examples include a structure in which a mesogen group is bonded to a spacer portion that imparts flexibility, such as a nematic-aligned polyester-based liquid crystal polymer, a discotic polymer, and a cholesteric polymer. And so on.
• the side-chain type liquid crystalline polymer include polysiloxane, polyatalylate, polymetharylate or polymalonate as a main chain skeleton, and nematic alignment through a spacer portion composed of a conjugated atomic group as a side chain. Grantability And those having a mesogen moiety composed of a para-substituted cyclic compound unit.
• These liquid crystal polymers are, for example, those obtained by rubbing the surface of a thin film such as polyimide or polyvinyl alcohol formed on a glass plate, or those obtained by obliquely depositing silicon oxide. This is done by developing a polymer solution and heat-treating it.
• the retardation plate may have an appropriate retardation according to the purpose of use, such as, for example, various wavelength plates or those for the purpose of compensating for a viewing angle or the like due to birefringence of a liquid crystal layer. It may be one in which optical characteristics such as retardation are controlled by laminating retardation plates.
• the above-mentioned elliptically polarizing plate or reflection type elliptically polarizing plate is obtained by laminating a polarizing plate or a reflection type polarizing plate and a retardation plate in an appropriate combination.
• Such an elliptically polarizing plate or the like can also be formed by sequentially and separately laminating a (reflection type) polarizing plate and a retardation plate in the process of manufacturing a liquid crystal display device so as to form a combination.
• an optical film such as an elliptically polarizing plate is excellent in quality stability, laminating workability, and the like, and has an advantage that the manufacturing efficiency of a liquid crystal display device or the like can be improved.
• the viewing angle compensation film is a film for widening the viewing angle so that an image can be seen relatively clearly even when the screen of the liquid crystal display device is viewed not obliquely but perpendicularly to the screen.
• a viewing angle compensating retardation plate include, for example, a retardation plate, an alignment film such as a liquid crystal polymer, and a transparent substrate on which an alignment layer such as a liquid crystal polymer is supported.
• a common retardation plate uses a birefringent polymer film uniaxially stretched in the plane direction, whereas a retardation plate used as a viewing angle compensation film has a biaxially stretched biaxially oriented polymer film.
• Bidirectionally stretched film such as polymer film with refraction, birefringent polymer that is uniaxially stretched in the plane direction and also stretched in the thickness direction, and has birefringence with controlled refractive index in the thickness direction
• the obliquely oriented film include a film obtained by bonding a heat shrink film to a polymer film and subjecting the polymer film to a stretching treatment and / or a shrinking treatment under the action of the shrinkage force caused by heating, or a film obtained by obliquely orienting a liquid crystal polymer.
• the raw material polymer for the retardation plate is the polymer described for the retardation plate
• the same material as that described above can be used, and an appropriate material can be used for the purpose of preventing coloring or the like due to a change in the viewing angle based on the phase difference due to the liquid crystal cell, expanding the viewing angle for good visibility, and the like.
• an optically anisotropic layer composed of a liquid crystal polymer alignment layer particularly an optically anisotropic layer composed of a discotic liquid crystal polymer inclined alignment layer, is supported by a triacetyl cellulose film.
• a compensating retardation plate can be preferably used.
• a polarizing plate in which a polarizing plate and a brightness enhancement film are bonded together is usually used by being provided on the back side of a liquid crystal cell.
• the brightness enhancement film reflects linearly polarized light of a predetermined polarization axis or circularly polarized light of a predetermined direction when natural light enters due to reflection from the back side of a backlight of a liquid crystal display device, etc., and exhibits the property of transmitting other light.
• the polarizing plate, in which the brightness enhancement film is laminated with the polarizing plate receives light from a light source such as a backlight to obtain transmitted light in a predetermined polarization state, and does not transmit light other than the predetermined polarization state.
• the light reflected on the surface of the brightness enhancement film is further inverted through a reflection layer or the like provided on the rear side thereof and re-entered on the brightness enhancement film, and a part or all of the light is transmitted as light of a predetermined polarization state.
• a reflection layer or the like provided on the rear side thereof and re-entered on the brightness enhancement film, and a part or all of the light is transmitted as light of a predetermined polarization state.
• the brightness enhancement film reflects light having a polarization direction that can be absorbed by the polarizer, but does not allow the light to enter the polarizer, but reflects it once, and then reverses it through a reflective layer, etc., provided behind it. And re-enter the brightness enhancement film, and transmit only polarized light whose polarization direction is such that the direction of polarization of the reflected and inverted light between them can pass through the polarization ⁇ . Since the light is supplied to the display, light from the backlight or the like can be efficiently used for displaying an image on the liquid crystal display device, and the screen can be brightened.
• a diffusion plate may be provided between the brightness enhancement film and the above-mentioned reflection layer or the like.
• the light in the polarization state reflected by the brightness enhancement film goes to the reflection layer and the like, but the diffuser provided uniformly diffuses the passing light, and at the same time, eliminates the polarization state and changes to a non-polarization state. That is, it returns to the original natural light state.
• the light in the non-polarized state that is, in the natural light state, repeatedly travels toward the reflection layer and the like, is reflected through the reflection layer and the like, passes through the diffusion plate again, and reenters the brightness enhancement film.
• the brightness enhancement film has a property of transmitting linearly polarized light having a predetermined polarization axis and reflecting other light, such as a multilayer thin film of a dielectric or a multilayer laminate of thin films having different refractive index anisotropies.
• a multilayer thin film of a dielectric or a multilayer laminate of thin films having different refractive index anisotropies As shown in the figure, such as an alignment film of cholesteric liquid crystal polymer or a film with its alignment liquid crystal layer supported on a film substrate, it reflects either left-handed or right-handed circularly polarized light and transmits other light. Any suitable one such as one can be used.
• a brightness enhancement film of a type that transmits linearly polarized light having a predetermined polarization axis the transmitted light is incident on the polarization plate as it is, thereby suppressing absorption loss by the polarization plate. It can be transmitted efficiently.
• a brightness enhancement film that transmits circularly polarized light such as a cholesteric liquid crystal layer, can be directly incident on a polarizer.However, in order to suppress absorption loss, the circularly polarized light is linearly polarized through a retardation plate. It is preferable that the light is incident on a polarizing plate. By using a 1/4 wavelength plate as the retardation plate, circularly polarized light can be converted to linearly polarized light.
• a retardation plate that functions as a 1Z 4 wavelength plate in a wide wavelength range such as the visible light region is, for example, a retardation layer that functions as a 1/4 wavelength plate for monochromatic light with a wavelength of 550 nm and other retardation layers.
• a phase difference layer exhibiting characteristics, for example, a phase difference layer functioning as a 1 Z 2 wavelength plate is superimposed. It can be obtained by such a method. Therefore, the retardation plate disposed between the polarizing plate and the brightness enhancement film may be composed of one or more retardation layers.
• the cholesteric liquid crystal layer also reflects circularly polarized light over a wide wavelength range, such as the visible light region, by combining two or three or more layers with different reflection wavelengths. Can be obtained, and based on that, transmission circularly polarized light in a wide wavelength range can be obtained.
• the polarizing plate may be formed by laminating a polarizing plate and two or three or more optical layers as in the above-mentioned polarized light separating type polarizing plate. Therefore, a reflective elliptically polarizing plate or a transflective elliptically polarizing plate obtained by combining the above-mentioned reflective polarizing plate, semi-transmissive polarizing plate and retardation plate may be used.
• An optical film in which the optical layer is laminated on a polarizing plate can also be formed by a method in which the optical film is laminated separately in the manufacturing process of a liquid crystal display device or the like. It has the advantage of being superior in stability and assembly work, and can improve the manufacturing process of liquid crystal display devices and the like.
• an appropriate bonding means such as a pressure-sensitive adhesive layer can be used.
• the adhesive optical film of the present invention can be used for images such as a liquid crystal display (LCD), an electroluminescence display (ELD), a plasma display panel (PDP), and a field emission display (FED). It can be preferably used for forming a display device.
• FIG. 4A shows an example in which the liquid crystal display device is formed by bonding the adhesive optical films of FIGS. 1A and 2A to both sides of the liquid crystal cell 9.
• FIG. 4B shows an example in which the adhesive optical film shown in FIG. 3A is attached to one surface of a luminous body (organic electroluminescence luminous body) 10 described later, thereby forming an electronic luminescence display device.
• a luminous body organic electroluminescence luminous body
• the pressure-sensitive adhesive optical film of the present invention can be preferably used for forming various devices such as a liquid crystal display device.
• the formation of the liquid crystal display device can be performed according to a conventional method.
• liquid crystal display devices generally consist of a liquid crystal cell and an adhesive optical film, and It is formed by incorporating a drive circuit by appropriately setting all the components such as the illumination system and the like, but is not particularly limited in the present invention except that the polarizing plate or the optical film according to the present invention is used. It can be according to the conventional.
• the liquid crystal cell any type such as TN type, STN type, and ⁇ type can be used.
• Appropriate liquid crystal display devices such as a liquid crystal display device in which an adhesive optical film is arranged on one or both sides of a liquid crystal cell, and a lighting system using a backlight or a reflector can be formed.
• the polarizing plate or the optical film according to the present invention can be installed on one side or both sides of the liquid crystal cell.
• polarizing plates or optical films are provided on both sides, they may be the same or different.
• appropriate parts such as a diffusion plate, an antiglare layer, an antireflection film, a protective plate, a prism array, a lens array sheet, a light diffusion plate, and a backlight are placed at appropriate positions. Layers or two or more layers can be arranged.
• organic electroluminescence device organic EL display device
• a transparent electrode, an organic luminescent layer, and a metal electrode are sequentially laminated on a transparent substrate to form a luminous body (organic electroluminescent luminous body).
• the organic light emitting layer is a laminate of various organic thin films, for example, a laminate of a hole injection layer made of a triphenylamine derivative or the like and a light emitting layer made of a fluorescent organic solid such as anthracene, or A structure having various combinations, such as a laminate of such a light emitting layer and an electron injection layer made of a perylene derivative, or a laminate of a hole injection layer, a light emitting layer, and an electron injection layer. It has been known.
• holes and electrons are injected into an organic light emitting layer by applying a voltage to a transparent electrode and a metal electrode, and the energy generated by the recombination of these holes and electrons is converted into a fluorescent substance.
• the mechanism of recombination on the way is similar to that of a general diode, and as can be expected from this, the current and the emission intensity show strong nonlinearity accompanying rectification with respect to the applied voltage.
• Both electrodes must be transparent, and usually a transparent electrode formed of a transparent conductor such as indium tin oxide (ITO) is used as the anode.
• ITO indium tin oxide
• metal electrodes such as Mg-Ag and A1-Li. .
• the organic light emitting layer is formed of an extremely thin film having a thickness of about 10 nm. Therefore, the organic light emitting layer transmits light almost completely, similarly to the transparent electrode. As a result, when light is incident from the surface of the transparent substrate during non-light emission, the light transmitted through the transparent electrode and the organic light emitting layer and reflected by the metal electrode returns to the transparent substrate surface again, and is viewed from the outside. However, the display surface of the organic EL display device looks like a mirror surface.
• an organic EL display device including an organic electroluminescent luminous element having a transparent electrode on the front side of an organic luminescent layer that emits light by applying a voltage and a metal electrode on the back side of the organic luminescent layer
• the transparent electrode A polarizing plate can be provided on the surface side, and a retardation film can be provided between the transparent electrode and the polarizing plate.
• the retardation film and the polarizing plate have a function of polarizing light incident from the outside and reflected by the metal electrode, there is an effect that the mirror surface of the metal electrode is not visually recognized by the polarization action.
• the retardation film is composed of a 1/4 wavelength plate and the angle between the polarization directions of the polarizing plate and the retardation film is adjusted to ⁇ Z4, the mirror surface of the metal electrode can be completely shielded. .
• linearly polarized light components of the external light incident on the organic EL display device are transmitted by the polarizing plate.
• This linearly polarized light is generally converted to elliptically polarized light by the retardation film.
• the retardation film is a quarter-wave plate and the angle between the polarization directions of the polarizing plate and the retardation film is ⁇ or 4
• circularly polarized light is generated.
• This circularly polarized light passes through the transparent substrate, the transparent electrode, and the organic thin film, is reflected by the metal electrode, passes through the organic thin film, the transparent electrode, and the transparent substrate again, and becomes linearly polarized light by the retardation film. Since this linearly polarized light is orthogonal to the polarization direction of the polarizing plate, it cannot pass through the polarizing plate. As a result, the mirror surface of the metal electrode can be completely shielded.
• in the pressure-sensitive adhesive optical film By forming a portion of the pressure-sensitive adhesive layer that is inside the edge of the optical film, the problem of chipping or remaining adhesive is solved. Examples>
• a separable flask equipped with a thermometer, stirrer, reflux condenser and nitrogen gas inlet was charged with 97 parts of butyl acrylate, 3 parts of acrylic acid, 0.2 parts of azobisisobutyronitrile and 0.2 part of ethyl acetate as solids.
• the flask was heated to 60 ° C. and reacted for 7 hours to obtain an acrylic polymer having a weight average molecular weight (Mw) of 110,000.
• a polybutyl alcohol film with a thickness of 80 ⁇ is stretched 5 times in an aqueous iodine solution, and then dried.
• a triacetyl cellulose film is adhered to both sides of the film with an adhesive to obtain a polarizing plate. Punched out with a Thomson blade.
• the adhesive solution prepared above was dried on a polyethylene terephthalate-based release film having a thickness of 35 m, and dried on the inside of 300 / im from each side of the 11-inch size polarizing plate.
• Example 1 Preparation of pressure-sensitive adhesive optical film
• the pressure-sensitive adhesive solution prepared above was placed on a polarizing plate punched out with a Thomson blade to a size of 11 inches, and a polyethylene terephthalate-based release film having a thickness of 3 Apply on the entire surface of the 11-inch size so that the thickness after drying is 25; xm, and dry at 100 ° C for 4 minutes to obtain the adhesive layer (loss elastic modulus: 8.0 ⁇ 10 4 Pa ( (25 ° C)) to form a pressure-sensitive adhesive polarizing plate with a release film with pressure-sensitive adhesive formed thereon.
• Example 1 Preparation of pressure-sensitive adhesive optical film
• the above-mentioned pressure-sensitive adhesive solution was placed on a polyethylene plate having a thickness of 38 ⁇ on a polarizing plate punched into a 11-inch size with a Thompson blade.
• the thickness after drying was 1 1 inch entirely so that the 40 m, 1 00 ° dried adhesive layer 4 minutes at C (loss bullet resistance index: 1. 1 X 10 3 Pa ( 25 ° C ))
• Example 3 a norbornene-based film (ARTON: JSR Co., Ltd.) was prepared in the same manner as in Example 3 except that a retardation plate prepared by uniaxially stretching 1.5 times in the MD direction was used, and the pressure-sensitive adhesive layer was inside the edge of the optical film.
• An adhesive-type retardation plate was formed in which the portion at was located at a distance of 150 ⁇ from the edge of the optical film (the longest portion).
• Example 3 drying was performed at 150 ° C. for 30 minutes using a hot air dryer to remove the remaining monomers, and then laminated with the polarizing plate in the same manner as in Example 3, and the pressure-sensitive adhesive layer was removed from the edge of the optical film.
• An adhesive type polarizing plate was obtained in which the inner portion was formed at a distance of 150 / m (longest portion) from the edge of the optical film. At this time, the loss elastic modulus of the pressure-sensitive adhesive layer was 2.1 ⁇ 10 4 Pa.
• Example 1 preparation of the pressure-sensitive adhesive composition
• the portion of the pressure-sensitive adhesive layer inside the edge of the optical film is formed at a distance of 150 / zm (longest portion) from the edge of the optical film.
• an adhesive type polarizing plate was obtained.
• Example 1 preparation of the pressure-sensitive adhesive composition
• the part of the pressure-sensitive adhesive layer inside the edge of the optical film was formed at a distance of 150 ⁇ from the edge of the optical film (the longest part). A polarizing plate was obtained.
• Example 1 preparation of the pressure-sensitive adhesive composition
• the portion of the pressure-sensitive adhesive layer inside the edge of the optical film was a distance of 150 ⁇ from the edge of the optical film. (Longest part) was obtained.
• the portion of the pressure-sensitive adhesive layer located inside the edge of the optical film has a distance of 100 / X m from the edge of the optical film ( (Longest part) was obtained.
• Example 1 Preparation of pressure-sensitive adhesive optical film
• the pressure-sensitive adhesive solution prepared as described above was placed on a polarizing plate punched out with a Thomson blade to a size of 11 inches, and a polyethylene terephthalate system having a thickness of 35 zm was separated. It is applied on a mold film so that the thickness after drying becomes 25 / im so as to cover the entire surface of the 11-inch size, and after sticking to the above polarizing plate, it is dried at 100 ° C for 4 minutes. ⁇ An adhesive layer was formed to obtain an adhesive polarizing plate.
• the adhesive type optical film with the adhesive layer inside the edge of the optical film has no adhesive feeling at the edge (side) of the film, and at the same time, the adhesive is chipped. Absent.
• an adhesive optical film in which an adhesive layer is laminated on one or both sides of an optical film, an adhesive which is less likely to cause glue chipping and glue stain during transportation, handling or on a production or processing line.
• a mold optical film is provided.

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• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Optics & Photonics (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Liquid Crystal (AREA)
• Adhesive Tapes (AREA)
• Polarising Elements (AREA)
• Laminated Bodies (AREA)
• Electroluminescent Light Sources (AREA)
• Devices For Indicating Variable Information By Combining Individual Elements (AREA)

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• 2003
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