TWI641114B - 使用兩個多晶矽沉積步驟來形成三柵極非揮發性快閃記憶體單元對的方法 - Google Patents
使用兩個多晶矽沉積步驟來形成三柵極非揮發性快閃記憶體單元對的方法 Download PDFInfo
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 title claims abstract description 321
- 238000000034 method Methods 0.000 title claims abstract description 64
- 230000008021 deposition Effects 0.000 title claims abstract description 10
- 229920005591 polysilicon Polymers 0.000 title claims description 6
- 239000000758 substrate Substances 0.000 claims abstract description 52
- 238000005137 deposition process Methods 0.000 claims abstract description 18
- 239000004065 semiconductor Substances 0.000 claims abstract description 10
- 125000006850 spacer group Chemical group 0.000 claims description 84
- 150000004767 nitrides Chemical class 0.000 claims description 31
- 239000011810 insulating material Substances 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 18
- 238000005530 etching Methods 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910021419 crystalline silicon Inorganic materials 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 229910021332 silicide Inorganic materials 0.000 claims description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 3
- 238000000151 deposition Methods 0.000 abstract description 8
- 229920002120 photoresistant polymer Polymers 0.000 description 24
- 239000000463 material Substances 0.000 description 22
- 238000002513 implantation Methods 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
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Abstract
本發明提供了一種用於使用兩次多晶矽沉積形成非揮發性記憶體單元對的簡化方法。在第一多晶矽沉積工藝中,在半導體襯底上形成第一多晶矽層,並將所述第一多晶矽層與所述半導體襯底絕緣。在所述第一多晶矽層上形成一對間隔開的絕緣塊。將所述第一多晶矽層的暴露部分移除,同時保持所述第一多晶矽層的各自被設置在所述一對絕緣塊中的一個絕緣塊下方的一對多晶矽塊。在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣塊上方形成第二多晶矽層。在保持第一多晶矽塊(設置在所述第一對絕緣塊之間)、第二多晶矽塊(設置成與一個絕緣塊的外側相鄰)和第三多晶矽塊(設置成與另一絕緣塊的外側相鄰)的同時,將所述第二多晶矽層的部分移除。
Description
相關申請案 本申請案主張於2016年4月20日申請之中國專利申請案第201610247666.6號的權利,該案以引用方式併入本文中。 發明領域
本發明涉及一種具有字線(WL)柵極、浮動柵極和擦除柵極的非揮發性快閃記憶體單元。
發明背景 具有字線(WL)柵極、浮動柵極和擦除柵極的分離閘非揮發性快閃記憶體單元是本領域所熟知的。參見例如美國專利7,315,056,該專利全文以引用方式併入本文。
隨著非揮發性記憶體單元尺寸的減小,製造這樣的記憶體單元在自對準元件和數量減少的工序(例如,掩模步驟、多晶矽沉積步驟等)方面變得更具有挑戰性。因此,本發明的一個目標是隨著記憶體單元尺寸的不斷縮小而簡化製造工藝。
發明概要 一種用於形成一對非揮發性記憶體單元的簡化方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,每一個所述絕緣塊具有面朝彼此的第一側和背對彼此的第二側;在保持所述第一多晶矽層的被設置在所述一對絕緣塊下方以及所述一對絕緣塊之間的部分的同時,將所述第一多晶矽層的部分移除;形成與所述第一側相鄰並且位於所述第一多晶矽層的設置在所述一對絕緣塊之間的部分上方的一對間隔開的絕緣間隔物;將所述第一多晶矽層的設置在所述絕緣間隔物之間的部分移除,同時保持所述第一多晶矽層的各自被設置在所述一對絕緣塊中的一個絕緣塊和所述一對絕緣間隔物中的一個絕緣間隔物下方的一對多晶矽塊;在所述襯底中且在所述一對絕緣塊之間形成源極區域;將所述一對絕緣間隔物移除;形成至少沿著所述一對多晶矽塊中每個多晶矽塊的端部延伸的絕緣材料;在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時(其中所述第一多晶矽塊被設置在所述一對絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述絕緣塊中的一個絕緣塊的所述第二側相鄰,所述第三多晶矽塊被設置成與所述絕緣塊中的另一絕緣塊的所述第二側相鄰),將所述第二多晶矽層的部分移除;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
一種形成一對非揮發性記憶體單元的簡化方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,每一個所述絕緣塊具有面朝彼此的第一側和背對彼此的第二側;在保持所述第一多晶矽層的各自被設置在所述一對絕緣塊中的一個絕緣塊下方的一對多晶矽塊的同時,將所述第一多晶矽層的部分移除;形成與所述第一側和所述第二側相鄰的絕緣間隔物;將與所述第一側相鄰的所述絕緣間隔物移除;在所述襯底中且在所述一對絕緣塊之間形成源極區域;形成至少沿著所述第一側並沿著與所述第二側相鄰的所述絕緣間隔物延伸的絕緣材料層;在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時(其中所述第一多晶矽塊被設置在所述一對絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述絕緣塊中的一個絕緣塊的所述第二側相鄰,所述第三多晶矽塊被設置成與所述絕緣塊中的另一絕緣塊的所述第二側相鄰),將所述第二多晶矽層的部分移除;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
一種形成一對非揮發性記憶體單元的簡化方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,每一個所述絕緣塊具有面朝彼此的第一側和背對彼此的第二側;形成與所述第一側和所述第二側相鄰的絕緣間隔物;減小與所述第一側相鄰的所述絕緣間隔物的寬度;在保持所述第一多晶矽層的各自被設置在所述一對絕緣塊中的一個絕緣塊和與所述一個絕緣塊的所述第一側和所述第二側相鄰的所述絕緣間隔物下方的一對多晶矽塊的同時,將所述第一多晶矽層的部分移除;在所述襯底中且在所述一對絕緣塊之間形成源極區域;將所述絕緣間隔物移除以使所述第一多晶矽層的所述一對多晶矽塊中每個多晶矽塊的端部暴露;形成至少沿著所述第一多晶矽層的所述一對多晶矽塊中每個多晶矽塊的暴露端部延伸的絕緣材料層;在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時(其中所述第一多晶矽塊被設置在所述一對絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述絕緣塊中的一個絕緣塊的所述第二側相鄰,所述第三多晶矽塊被設置成與所述絕緣塊中的另一絕緣塊的所述第二側相鄰),將所述第二多晶矽層的部分移除;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
一種形成一對非揮發性記憶體單元的簡化方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成絕緣塊,所述絕緣塊具有相對的第一側和第二側;在所述第一多晶矽層上且與所述第一側相鄰形成第一絕緣間隔物,並且在所述第一多晶矽層上且與所述第二側相鄰形成第二絕緣間隔物;在保持所述第一多晶矽層的被設置在所述絕緣塊以及所述第一絕緣間隔物和所述第二絕緣間隔物下方的多晶矽塊的同時,將所述第一多晶矽層的部分移除;將所述絕緣塊移除;將所述第一多晶矽層的設置在所述第一絕緣間隔物和所述第二絕緣間隔物之間的部分移除,以形成所述第一多晶矽層的設置在所述第一絕緣間隔物下方的第一多晶矽塊和所述第一多晶矽層的設置在所述第二絕緣間隔物下方的第二多晶矽塊;在所述襯底中且在所述第一絕緣間隔物與所述第二絕緣間隔物之間形成源極區域;形成至少沿著所述第一多晶矽層的所述第一多晶矽塊和所述第二多晶矽塊中每一者的端部延伸的絕緣材料;在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣間隔物上方形成第二多晶矽層;在保持所述第二多晶矽層的第三多晶矽塊、第四多晶矽塊和第五多晶矽塊的同時(其中所述第三多晶矽塊被設置在所述一對絕緣間隔物之間以及所述源極區域上方,所述第四多晶矽塊被設置成與所述第一絕緣間隔物相鄰,所述第五多晶矽塊被設置成與所述第二絕緣間隔物相鄰),將所述第二多晶矽層的部分移除;在所述襯底中並與所述第四多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第五多晶矽塊相鄰形成第二漏極區域。
通過查看說明書、申請專利範圍和附圖,本發明的其他目的和特徵將變得顯而易見。
較佳實施例之詳細說明 本發明是以數量減少的工序(例如,僅兩個多晶矽沉積步驟)來製造記憶體單元對的方法。參見圖1A至圖1I,它們示出記憶體單元對製造工藝中的步驟的橫截面圖(雖然在附圖中僅僅示出單對記憶體單元的形成,但應當理解,這種記憶體單元對的陣列是同時形成的)。該工藝始於在P型單晶矽襯底10上形成二氧化矽(氧化物)層12。氧化物層12可為80至100Å厚。之後,在二氧化矽層12上形成多晶矽(或非晶矽)層14。多晶矽層14可為200至300Å厚。在多晶矽層14上形成另一個絕緣層16(例如,氧化物),並且在氧化物層16上形成又一個絕緣層18(例如,氮化矽(氮化物)),如圖1A所示。氧化物層16可為20至50Å厚,氮化物層18可為約500Å厚。
在該結構上塗布光刻膠材料(未示出),然後執行掩模步驟,使光刻膠材料的所選部分暴露。光刻膠被顯影,使得光刻膠的部分被移除。使用剩下的光刻膠作為掩模,蝕刻該結構。具體地講,對氮化物層18和氧化物層16進行各向異性蝕刻(使用多晶矽層14作為蝕刻終止層),留下成對氮化物塊18,如圖1B所示(在光刻膠被移除後)。氮化物塊18之間的空間在本文中稱為“內區域”,這對氮化物塊外部的空間在本文中稱為“外區域”。再次在該結構上塗布光刻膠材料,並且用掩模和顯影步驟來將光刻膠材料圖案化,以便覆蓋內區域。隨後,使用各向異性多晶矽蝕刻將多晶矽層14的在外區域中的那些部分移除,如圖1C所示(在光刻膠被移除後)。
然後,在該結構的側面上形成氧化物間隔物20。間隔物的形成是本領域熟知的,並且涉及材料在結構的輪廓上方的沉積,繼之進行各向異性蝕刻工藝,由此將該材料從該結構的水平表面移除,而該材料在該結構的垂直取向表面上在很大程度上保持完整(具有圓化的上表面)。所得結構示於圖1D中。接著,使用多晶矽蝕刻將多晶矽層14的在內區域中的暴露部分移除。接著,執行注入工藝(例如,注入和退火),以便在襯底中於內區域中形成源極區域22。所得結構示於圖1E中。
在該結構上形成光刻膠並將光刻膠從內區域移除,然後使用氧化物蝕刻將內區域中的氧化物間隔物20以及源極區域上方的氧化物層12移除。在光刻膠被移除後,接著,將隧道氧化物層24形成在該結構上方(例如,通過高溫氧化物HTO),包括形成在多晶矽層14的在內區域中的暴露部分上方,如圖1F所示。將多晶矽厚層26形成在該結構上方(參見圖1G),繼之進行多晶矽蝕刻(例如,使用氮化物18作為蝕刻終止層的CMP),從而在內區域中留下多晶矽塊26a並且在外區域中留下多晶矽塊26b,如圖1H所示。可使用可選的多晶矽蝕刻來減小多晶矽塊26a和26b的高度(即,使所述多晶矽塊低於氮化矽塊18的頂部)。
在該結構上形成該光刻膠並將光刻膠圖案化以使多晶矽塊26b部分暴露,繼之進行多晶矽蝕刻以將多晶矽塊26b的暴露部分移除(即,限定多晶矽塊26b的外緣)。接著,執行注入以便在襯底中形成與多晶矽塊26b的外緣相鄰的漏極區域30。然後,在多晶矽塊26a和26b的暴露的上表面上形成自對準多晶矽化物28(以改進導電性)。最終結構示於圖1I中,並且包括一對記憶體單元。每一個記憶體單元包括源極區域22、漏極區域30、襯底中介於源極區域與漏極區域之間的溝道區域32、設置在溝道區域32的第一部分上方且與該第一部分絕緣的浮動柵極14、設置在溝道區域32的第二部分上方且與該第二部分絕緣的字線柵極26b、以及設置在源極區域22上方且與該源極區域絕緣的擦除柵極26a。擦除柵極26a具有在側向上與浮動柵極14相鄰的第一部分,以及向上且在浮動柵極14的一部分上方延伸的第二部分。
上述製造方法具有若干優點。首先,使用僅兩次多晶矽沉積就形成了所有三個柵極(浮動柵極14、擦除柵極26a和字線柵極26b)。浮動柵極14具有尖銳的尖端或邊緣14a,該尖端或邊緣面向擦除柵極26a中的凹口27以改進擦除效率。浮動柵極14相對較薄,而浮動柵極14上方的氮化物塊18相對較厚並且充當可靠的硬掩模且用作多晶矽CMP終止層。
參考圖2至圖7,它們示出記憶體單元對製造工藝的替代實施例的橫截面圖(雖然在這些附圖中僅僅示出一個記憶體單元的形成,但應當理解,在源極區域的另一側上同時形成鏡像記憶體單元來作為一對記憶體單元的組成部分,並且這種記憶體單元對的陣列是同時形成的)。
圖2示出圖1A至圖1I的工藝的替代實施例,其中在形成擦除柵極50a前(即,未進行內區域氧化物蝕刻),留下形成在內區域中浮動柵極14上方的間隔物42,以便簡化製造工藝。
圖3A至圖3D示出圖1A至圖1I的工藝的又一個替代實施例,其中該工藝從上述的且示於圖1A中的相同工序開始。然而,與如圖1C所示僅移除多晶矽層14的在外區域中的暴露部分的多晶矽蝕刻不同,使用多晶矽蝕刻將內區域和外區域兩者中的多晶矽層14移除,如圖3A所示。優選地,在氮化物塊18上形成另外的氧化物層60。絕緣間隔物62(例如,由氧化物和氮化物兩者形成的複合物,或僅氧化物)沿著氮化物塊18和多晶矽層14的側面形成,如圖3B所示。在該結構上形成光刻膠64,然後將所述光刻膠從內區域移除。通過氮化物/氧化物蝕刻移除暴露ON或氧化物間隔物62。接著,使用注入工藝形成源極區域66,如圖3C所示。在光刻膠被移除後,在該結構上方形成氧化物層68。接著,執行多晶矽沉積、CMP和多晶矽蝕刻,形成擦除柵極70a和字線柵極70b。接著,使用注入物形成漏極72。最終結構示於圖3D中。對於該實施例,擦除柵極70a與浮動柵極14和氮化物塊18之間的間距僅由氧化物層68決定。
圖4A至圖4D示出圖1A至圖1I的工藝的又一個替代實施例,其中該工藝從上述的且示於圖1A中的相同工序開始。在氮化物塊18的兩側上形成絕緣材料(例如,氧化物)間隔物74。在該結構上形成光刻膠76,然後選擇性地將所述光刻膠從外區域移除。使用多晶矽蝕刻將多晶矽層14的暴露部分移除。使用WLVT注入來對外區域中的襯底進行注入,如圖4A所示。在光刻膠被移除後,在該結構上形成光刻膠78,然後選擇性地將所述光刻膠從內區域移除。執行氧化物濕法蝕刻,以使內區域中的暴露的間隔物74減薄(以便獨立控制擦除柵極和浮動柵極的最終重疊)。接著,執行多晶矽蝕刻將多晶矽層14的在內區域中的暴露部分移除。接著,執行注入工藝形成源極區域80,如圖4B所示。在光刻膠被移除後,執行氧化物蝕刻以移除間隔物74以及氧化物層12的暴露部分。使用熱氧化工藝在多晶矽層14和襯底10的暴露表面上形成氧化物層82,如圖4C所示。使用多晶矽沉積和蝕刻來形成擦除柵極84a和字線柵極84b,並且使用注入形成漏極區域86,如圖4D所示。擦除柵極84a和字線柵極84b兩者具有在側向上與浮動柵極相鄰的第一部分,以及向上並在浮動柵極上方延伸的第二部分,用以提高擦除效率和電容耦合。浮動柵極相對於字線柵極被擦除柵極重疊的量受到獨立控制,並且由氧化物間隔物減薄步驟決定。
圖5A至圖5C示出圖2A至圖1I的工藝的又一個替代實施例,其中該工藝從上述的且示於圖1A中的相同工序開始。然而,在該實施例中,擦除柵極代替氮化物塊18,而非形成在其旁邊。具體地講,在氮化物塊18的兩側上形成絕緣材料(例如,對於可選間隔物88為氧化物-氮化物,對於間隔物90為氧化物)的間隔物88(可選)和間隔物90,如圖5A所示。使用多晶矽蝕刻將多晶矽層14的不受氮化矽塊18和間隔物88和90保護的那些部分移除。隨後,在該結構的兩側上形成絕緣材料(例如,氧化物)的間隔物92,包括在多晶矽層的暴露端上形成這樣的間隔物,如圖5B所示。使用氮化物蝕刻將氮化物塊18移除,從而留下溝槽並使多晶矽層14的在溝槽底部的部分暴露。使用多晶矽蝕刻將多晶矽層14的暴露部分移除。使用注入工藝形成源極區域93。將間隔物88移除或減薄,或者在無可選間隔物88的情況下將間隔物90減薄,並且沿著移除氮化物塊18所留下的溝槽的側壁形成氧化物94。執行多晶矽沉積和蝕刻,以形成擦除柵極96a和字線柵極96b。接著,使用注入工藝形成漏極區域98。所得結構示於圖5C中。
圖6示出圖5A至圖5C的工藝的替代實施例,其中在形成間隔物90前,執行多晶矽斜坡蝕刻以使得多晶矽層14的上表面隨著其延伸遠離氮化物塊18而向下傾斜。這導致每個浮動柵極具有向上的坡面,該坡面終止於面向擦除柵極的凹口的更尖銳的邊緣。
圖7示出圖1至圖6的工藝的另一個替代實施例,其中通過多晶矽蝕刻將形成字線柵極的多晶矽塊移除,並用高K材料(即,介電常數K大於諸如HfO2
、ZrO2
、TiO2
等的氧化物的介電常數)的絕緣層以及金屬材料塊替代。例如,對於圖2的實施例,通過多晶矽蝕刻將多晶矽塊50b移除,並用高K材料的絕緣層56以及金屬材料塊58替代,如圖7所示。通過使字線柵極58由金屬形成,可實現更高的柵極導電率。對於圖1I中的多晶矽塊26b、圖3D中的多晶矽塊70b、圖4D中的多晶矽塊84b和圖5C和圖6中的多晶矽塊96b,同樣也能夠這樣做。
應當理解,本發明不限於上述的和本文中示出的實施例,而是涵蓋落在所附申請專利範圍的範圍內的任何和所有變型形式。舉例來說,本文中對本發明的提及並不意在限制任何請求項或請求項術語的範圍,而是僅涉及可由這些申請專利範圍中的一項或多項請求項涵蓋的一個或多個特徵。上文所述的材料、工藝和數值的例子僅為示例性的,而不應視為限制申請專利範圍。例如,氮化物塊18可替代地由氧化物層或具有氧化物-氮化物-氧化或氧化物-氮化物的複合物層製成。字線柵極26b、50b、70b、84b和96b下方的絕緣體可為二氧化矽或經受NO、N2
O退火或DPN(去耦等離子體氮化)的經氮處理的氧化物,但不限於這些例子。另外,根據申請專利範圍和說明書顯而易見的是,並非所有方法步驟都需要以所示出或所聲稱的精確循序執行,而是需要以允許本發明的記憶體單元的適當形成的任意順序來執行。最後,單個材料層可以被形成為多個這種或類似材料層,反之亦然。
應該指出的是,如本文所用,術語“在…上方”和“在…上”兩者包容地包含“直接在…上”(之間未設置中間材料、元件或空間)和“間接在…上”(之間設置有中間材料、元件或空間)。類似地,術語“相鄰”包括“直接相鄰”(之間沒有設置中間材料、元件或空間)和“間接相鄰”(之間設置有中間材料、元件或空間),“被安裝到”包括“被直接安裝到”(之間沒有設置中間材料、元件或空間)和“被間接安裝到”(之間設置有中間材料、元件或空間),並且“被電連接到”包括“被直接電連接到”(之間沒有將元件電連接在一起的中間材料或元件)和“被間接電連接到”(之間有將元件電連接在一起的中間材料或元件)。例如,“在襯底上方”形成元件可包括在之間沒有中間材料/元件的情況下在襯底上直接形成元件,以及在之間有一個或多個中間材料/元件的情況下在襯底上間接形成元件。
10‧‧‧P型單晶矽襯底
12‧‧‧二氧化矽(氧化物)層;氧化物層
14‧‧‧晶矽(或非晶矽)層;浮動柵極
14a‧‧‧尖端或邊緣
16‧‧‧絕緣層;氧化物層
18‧‧‧絕緣層;氮化物層;氮化物塊
20‧‧‧氧化物間隔物
22、66、80、93‧‧‧源極區域
24‧‧‧隧道氧化物層
26‧‧‧多晶矽厚層
26a‧‧‧多晶矽塊;擦除柵極
26b、70b、84b、96b‧‧‧多晶矽塊;字線柵極
27‧‧‧凹口
28‧‧‧多晶矽化物
30、86、98‧‧‧漏極區域
32‧‧‧溝道區域
42、74、88、90、92‧‧‧間隔物
50a、70a、84a、96a‧‧‧擦除柵極
50b‧‧‧多晶矽塊
56‧‧‧絕緣層
58‧‧‧金屬材料塊;字線柵極
60、68、82‧‧‧氧化物層
62‧‧‧絕緣間隔物;氧化物間隔物
64、76、78‧‧‧光刻膠
72‧‧‧漏極
94‧‧‧氧化物
圖1A至圖1I為示出形成本發明的一對記憶體單元的步驟的橫截面圖。
圖2為用於形成本發明的一對記憶體單元的另一個替代實施例的橫截面圖。
圖3A至圖3D為示出用於形成本發明的一對記憶體單元的另一個替代實施例的步驟的橫截面圖。
圖4A至圖4D為示出用於形成本發明的一對記憶體單元的另一個替代實施例的步驟的橫截面圖。
圖5A至圖5C為示出用於形成本發明的一對記憶體單元的另一個替代實施例的步驟的橫截面圖。
圖6為用於形成本發明的一對記憶體單元的另一個替代實施例的橫截面圖。
圖7為用於形成本發明的一對記憶體單元的另一個替代實施例的橫截面圖。
Claims (28)
- 一種形成一對非揮發性記憶體單元的方法,所述方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,所述一對間隔開的絕緣塊的每一者具有面朝彼此的第一側和背對彼此的第二側;在保持所述第一多晶矽層的被設置在所述一對間隔開的絕緣塊下方以及所述一對間隔開的絕緣塊之間的部分的同時,將所述第一多晶矽層的部分移除;形成與所述第一側相鄰並且在所述第一多晶矽層的設置在所述一對間隔開的絕緣塊之間的部分上方的一對間隔開的絕緣間隔物;將所述第一多晶矽層的設置在所述一對間隔開的絕緣間隔物之間的部分移除,同時保持所述第一多晶矽層的各自被設置在所述一對間隔開的絕緣塊中的一個絕緣塊和所述一對間隔開的絕緣間隔物中的一個絕緣間隔物下方的一對多晶矽塊;在所述襯底中且在所述一對間隔開的絕緣塊之間形成源極區域;將所述一對間隔開的絕緣間隔物移除;形成至少沿著所述一對多晶矽塊中每個多晶矽塊的端部延伸的絕緣材料;在第二多晶矽沉積工藝中,在所述襯底和所述一對間隔開的絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時,將所述第二多晶矽層的部分移除,其中:所述第一多晶矽塊被設置在所述一對間隔開的絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰,並且所述第三多晶矽塊被設置成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
- 如請求項1所述的方法,所述方法還包括:在所述第一多晶矽塊、所述第二多晶矽塊和所述第三多晶矽塊的上表面上形成自對準多晶矽化物。
- 如請求項1所述的方法,其中所述第一多晶矽塊包括在側向上與所述第一多晶矽層的所述一對多晶矽塊相鄰的第一部分,以及向上且在所述第一多晶矽層的所述一對多晶矽塊上方延伸的第二部分。
- 如請求項1所述的方法,所述方法還包括:在用於形成所述一對間隔開的絕緣間隔物的相同的沉積和蝕刻工藝中,形成與所述第二側相鄰的一對第二絕緣間隔物。
- 如請求項1所述的方法,其中所述一對間隔開的絕緣塊由氮化物、氧化物、或包括氮化物和氧化物兩者的層複合物形成。
- 如請求項1所述的方法,其中所述第一絕緣層由氧化物或經氮處理的氧化物形成。
- 如請求項1所述的方法,所述方法還包括:將所述第二多晶矽塊和所述第三多晶矽塊移除;以及形成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰的第一金屬塊;形成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰的第二金屬塊。
- 如請求項7所述的方法,所述方法還包括:在所述第一金屬塊與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側之間形成高K絕緣材料層;以及在所述第二金屬塊與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側之間形成高K絕緣材料層。
- 一種形成一對非揮發性記憶體單元的方法,所述方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,所述一對間隔開的絕緣塊的每一者具有面朝彼此的第一側和背對彼此的第二側;在保持所述第一多晶矽層的各自被設置在所述一對間隔開的絕緣塊中的一個絕緣塊下方的一對多晶矽塊的同時,將所述第一多晶矽層的部分移除;形成與所述第一側和所述第二側相鄰的絕緣間隔物;將與所述第一側相鄰的所述絕緣間隔物移除;在所述襯底中且在所述一對間隔開的絕緣塊之間形成源極區域;形成至少沿著所述第一側並沿著與所述第二側相鄰的所述絕緣間隔物延伸的絕緣材料層;在第二多晶矽沉積工藝中,在所述襯底和所述一對間隔開的絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時,將所述第二多晶矽層的部分移除,其中:所述第一多晶矽塊被設置在所述一對間隔開的絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰,並且所述第三多晶矽塊被設置成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
- 如請求項9所述的方法,其中:所述第一多晶矽塊通過所述絕緣材料層與所述第一多晶矽層的所述一對多晶矽塊絕緣;所述第二多晶矽塊通過所述絕緣材料層和所述絕緣間隔物中的一個絕緣間隔物與所述第一多晶矽層的所述一對多晶矽塊中的一個多晶矽塊絕緣;以及所述第三多晶矽塊通過所述絕緣材料層和所述絕緣間隔物中的一個絕緣間隔物與所述第一多晶矽層的所述一對多晶矽塊中的一個多晶矽塊絕緣。
- 如請求項9所述的方法,其中所述一對間隔開的絕緣塊由氮化物、氧化物、或包括氮化物和氧化物兩者的層複合物形成。
- 如請求項9所述的方法,其中所述第一絕緣層由氧化物或經氮處理的氧化物形成。
- 如請求項9所述的方法,所述方法還包括:將所述第二多晶矽塊和所述第三多晶矽塊移除;以及形成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰的第一金屬塊;形成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰的第二金屬塊。
- 如請求項13所述的方法,所述方法還包括:在所述第一金屬塊與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側之間形成高K絕緣材料層;以及在所述第二金屬塊與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側之間形成高K絕緣材料層。
- 一種形成一對非揮發性記憶體單元的方法,所述方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成一對間隔開的絕緣塊,所述一對間隔開的絕緣塊的每一者具有面朝彼此的第一側和背對彼此的第二側;形成與所述第一側和所述第二側相鄰的絕緣間隔物;減小與所述第一側相鄰的所述絕緣間隔物的寬度;在保持所述第一多晶矽層的各自被設置在所述一對間隔開的絕緣塊中的一個絕緣塊和與所述一個絕緣塊的所述第一側和所述第二側相鄰的所述絕緣間隔物下方的一對多晶矽塊的同時,將所述第一多晶矽層的部分移除;在所述襯底中且在所述一對間隔開的絕緣塊之間形成源極區域;將所述絕緣間隔物移除以使所述第一多晶矽層的所述一對多晶矽塊中每個多晶矽塊的端部暴露;形成至少沿著所述第一多晶矽層的所述一對多晶矽塊中每個多晶矽塊的暴露端部延伸的絕緣材料層;在第二多晶矽沉積工藝中,在所述襯底和所述一對間隔開的絕緣塊上方形成第二多晶矽層;在保持所述第二多晶矽層的第一多晶矽塊、第二多晶矽塊和第三多晶矽塊的同時,將所述第二多晶矽層的部分移除,其中:所述第一多晶矽塊被設置在所述一對間隔開的絕緣塊之間以及所述源極區域上方,所述第二多晶矽塊被設置成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰,並且所述第三多晶矽塊被設置成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰;在所述襯底中並與所述第二多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第三多晶矽塊相鄰形成第二漏極區域。
- 如請求項15所述的方法,其中:所述第一多晶矽塊包括在側向上與所述第一多晶矽層的所述一對多晶矽塊相鄰的第一部分,以及向上且在所述第一多晶矽層的所述一對多晶矽塊上方延伸的第二部分;所述第二多晶矽塊包括在側向上與所述第一多晶矽層的所述一對多晶矽塊中的一個多晶矽塊相鄰的第一部分,以及向上且在所述第一多晶矽層的所述一對多晶矽塊中的所述一個多晶矽塊上方延伸的第二部分;所述第三多晶矽塊包括在側向上與所述第一多晶矽層的所述一對多晶矽塊中的另一多晶矽塊相鄰的第一部分,以及向上且在所述第一多晶矽層的所述一對多晶矽塊中的所述另一多晶矽塊上方延伸的第二部分。
- 如請求項16所述的方法,其中所述第一多晶矽塊與所述第一多晶矽層的所述一對多晶矽塊中任一者之間的垂直重疊量小於所述第二多晶矽塊與所述第一多晶矽層的所述一對多晶矽塊中的所述一個多晶矽塊之間的垂直重疊量,並且小於所述第三多晶矽塊與所述第一多晶矽層的所述一對多晶矽塊中的所述另一多晶矽塊之間的垂直重疊量。
- 如請求項15所述的方法,其中所述一對間隔開的絕緣塊由氮化物、氧化物、或包括氮化物和氧化物兩者的層複合物形成。
- 如請求項15所述的方法,其中所述第一絕緣層由氧化物或經氮處理的氧化物形成。
- 如請求項15所述的方法,所述方法還包括:將所述第二多晶矽塊和所述第三多晶矽塊移除;以及形成與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側相鄰的第一金屬塊;形成與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側相鄰的第二金屬塊。
- 如請求項20所述的方法,所述方法還包括:在所述第一金屬塊與所述一對間隔開的絕緣塊中的一個絕緣塊的所述第二側之間形成高K絕緣材料層;以及在所述第二金屬塊與所述一對間隔開的絕緣塊中的另一絕緣塊的所述第二側之間形成高K絕緣材料層。
- 一種形成一對非揮發性記憶體單元的方法,所述方法包括:在半導體襯底上形成第一絕緣層;在第一多晶矽沉積工藝中,在所述第一絕緣層上形成第一多晶矽層;在所述第一多晶矽層上形成絕緣塊,所述絕緣塊具有相對的第一側和第二側;在所述第一多晶矽層上且與所述第一側相鄰形成第一絕緣間隔物,並且在所述第一多晶矽層上且與所述第二側相鄰形成第二絕緣間隔物;在保持所述第一多晶矽層的被設置在所述絕緣塊以及所述第一絕緣間隔物和所述第二絕緣間隔物下方的多晶矽塊的同時,將所述第一多晶矽層的部分移除;將所述絕緣塊移除;將所述第一多晶矽層的設置在所述第一絕緣間隔物和所述第二絕緣間隔物之間的部分移除,以形成所述第一多晶矽層的設置在所述第一絕緣間隔物下方的第一多晶矽塊和所述第一多晶矽層的設置在所述第二絕緣間隔物下方的第二多晶矽塊;在所述襯底中且在所述第一絕緣間隔物與所述第二絕緣間隔物之間形成源極區域;形成至少沿著所述第一多晶矽層的所述第一多晶矽塊和所述第二多晶矽塊每者的端部延伸的絕緣材料;在第二多晶矽沉積工藝中,在所述襯底和所述一對絕緣間隔物上方形成第二多晶矽層;在保持所述第二多晶矽層的第三多晶矽塊、第四多晶矽塊和第五多晶矽塊的同時,將所述第二多晶矽層的部分移除,其中:所述第三多晶矽塊被設置在所述一對絕緣間隔物之間以及所述源極區域上方,所述第四多晶矽塊被設置成與所述第一絕緣間隔物相鄰,並且所述第五多晶矽塊被設置成與所述第二絕緣間隔物相鄰;在所述襯底中並與所述第四多晶矽塊相鄰形成第一漏極區域;以及在所述襯底中並與所述第五多晶矽塊相鄰形成第二漏極區域。
- 如請求項22所述的方法,其中在所述絕緣塊被移除前,所述方法還包括:對所述第一多晶矽層的上表面執行多晶矽斜坡蝕刻,以使所述上表面隨著所述上表面延伸遠離所述絕緣塊而向下傾斜。
- 如請求項22所述的方法,其中所述第三多晶矽塊包括在側向上與所述第一多晶矽層的所述第一多晶矽塊和所述第二多晶矽塊相鄰的第一部分,以及向上且在所述第一多晶矽層的所述第一多晶矽塊和所述第二多晶矽塊上方延伸的第二部分。
- 如請求項22所述的方法,其中所述絕緣塊由氮化物、氧化物、或包括氮化物和氧化物兩者的層複合物形成。
- 如請求項22所述的方法,其中所述第一絕緣層由氧化物或經氮處理的氧化物形成。
- 如請求項22所述的方法,所述方法還包括:將所述第四多晶矽塊和所述第五多晶矽塊移除;以及形成與所述第一絕緣間隔物相鄰的第一金屬塊;形成與所述第二絕緣間隔物相鄰的第二金屬塊。
- 如請求項27所述的方法,所述方法還包括:在所述第一金屬塊與所述第一絕緣間隔物之間形成高K絕緣材料層;以及在所述第二金屬塊與所述第二絕緣間隔物之間形成高K絕緣材料層。
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- 2017-03-31 KR KR1020187032732A patent/KR102125469B1/ko active IP Right Grant
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CN107305892A (zh) | 2017-10-31 |
US20230238453A1 (en) | 2023-07-27 |
KR102221577B1 (ko) | 2021-02-26 |
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EP3446336A1 (en) | 2019-02-27 |
KR20180134971A (ko) | 2018-12-19 |
KR102237584B1 (ko) | 2021-04-07 |
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US10217850B2 (en) | 2019-02-26 |
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JP2019516245A (ja) | 2019-06-13 |
KR102125469B1 (ko) | 2020-06-23 |
JP6716716B2 (ja) | 2020-07-01 |
KR20200074267A (ko) | 2020-06-24 |
KR20210024211A (ko) | 2021-03-04 |
US11652162B2 (en) | 2023-05-16 |
US20180069104A1 (en) | 2018-03-08 |
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