KR910019678A - 표백제 활성화 방법 - Google Patents

표백제 활성화 방법 Download PDF

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Publication number
KR910019678A
KR910019678A KR1019910008224A KR910008224A KR910019678A KR 910019678 A KR910019678 A KR 910019678A KR 1019910008224 A KR1019910008224 A KR 1019910008224A KR 910008224 A KR910008224 A KR 910008224A KR 910019678 A KR910019678 A KR 910019678A
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South Korea
Prior art keywords
catalyst
bleaching
hydrogen peroxide
peroxy
bleach
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KR1019910008224A
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English (en)
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KR950001046B1 (ko
Inventor
루이스 에프. 파브레 토마스
하게 로날드
반 데어 헬름-라데마커 카린
히포리테스 코에크 진
마르텐스 루돌프요한
스와토프 톤
로버트 피.반 블리트 마르텐
Original Assignee
에이치.드 로이
유니레버 엔 브이
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Priority claimed from GB909011338A external-priority patent/GB9011338D0/en
Priority claimed from GB909027415A external-priority patent/GB9027415D0/en
Application filed by 에이치.드 로이, 유니레버 엔 브이 filed Critical 에이치.드 로이
Publication of KR910019678A publication Critical patent/KR910019678A/ko
Application granted granted Critical
Publication of KR950001046B1 publication Critical patent/KR950001046B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

표백제 활성화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (28)

  1. 다음과 같은 일반식을 가지는 망간-기본 배위 착화합물로 구성되는 표백 및 산화 촉매.
    〔LnMnmXp 2Yq〕 (A)
    (이 식에서 Mn은 산화수가 VI인 망간이고 n 및 m은 각각 2-8 사이의 정수이며 X는 배위성 또는 가교성 종을 나타낸다. P는 0-32 사이의 정수이고 Y는 착화합물의 전하수 z(z는 양수, 영 또는 음수이다.)에 종속되는 카운터 이온이다. q=z/〔Y전하수〕이고 L은 N,P,O 또는 S로 부터 선택되는 다수의 이종원자를 함유하는 유기분자인 리간드로서 반강자성으로 결합되어 있는 Mn(IV)-중심(들)에 모든 도는 일부의 이종원자 및/또는 탄소원자에 이하여 배위되어 있다).
  2. 제1항에 있어서, 반강자성 결합의 정도(J)가 200㎝-1이상인 촉매.
  3. 제2항에 있어서, 반강자성 결합의 정도가 400㎝-1이상인 촉매.
  4. 제1항에 있어서, P가 3-6사이의 정수인 촉매.
  5. 제4항에 있어서, P는 3,n은 2,m은 2인 촉매.
  6. 제5항에 있어서, 다음과 같은 일반식을 가지는 촉매.
    (이 식에서 X는 H2O,OH-,O2 2-,O2-,HO- 2,SH-,S2-,＞ SO,VH2-,RCOO-,NR3[R은 H, 알킬 또는 아릴(치환 또는 비치환)임],Cl-,N3 -,SCN-,N3-또는 그 혼합물로 부터 선택되는 배위성/가교성 종이다).
  7. 제6항에 있어서, L이 Mn(IV)-중심에 3개의 이종원자에 의해 배위되어 있는 다치상의 리간드인 촉매.
  8. 제7항에 있어서, L이 Mn(IV)-중심의 각각 하나에 3개의 질소원자에 의해 배위되어 있는 다치상의 리간드인 촉매.
  9. 제6항에 있어서, X가 O2-인 촉매.
  10. 제9항에 있어서, 다음과 같은 일반식을 가지는 촉매.
    〔L′N3)MnIVM-O)3MnIV(N3L′)〕ZYq
    (이 식에서 L′N3및 N3L′는 3개 이상의 질소원자를 함유하는 리간드를 나타낸다.)
  11. 제9항에 있어서, 다음과 같은 구조식을 가지는 촉매.
  12. 제9항에 있어서, 다음과 같은 구조식을 가지는 촉매.
  13. 페록시 화합물 존재하에, 제1항 기재의 반강자성으로 결합된 Mn(IV)-중심을 가지는 Mn(IV)-기본 배위 착화합물로 변화되는 망간-기본 배위 착화합물인 표백 전구체.
  14. 페록시 화합물을 포함하는 표백제를 사용하는 표백 또는 세정방법으로서, 상기 표백제는 제1항 기재의 촉매적인 양의 촉매 또는 제13항 기재의 촉매 전구체에 의해 활성화되는 것을 특징으로 하는 표백 또는 세정방법.
  15. 제14항에 있어서, 촉매 또는 전구체가 표백용액중 0.001ppm-100ppm Mn의 수준으로 사용되는 표백 또는 세정방법.
  16. 제15항에 있어서, 망간의 양이 0.01-20ppm인 표백 또는 세정방법.
  17. 제14항에 있어서, 표백제가 과산화수소, 과산화수소-방출 화합물, 과산화수소-발생계, 페록시산 및 그염, 페록시산 표백제 전구체 및 이들의 혼합물 중에서 선택되는 표백 또는 세정방법.
  18. 제17항에 있어서, 촉매가 [MnⅣ2(μ-0)3(Me-TACN2](PF6)2인 표백 또는 세정방법.
  19. 제17항에 있어서, 촉매가[MnⅣ2(μ-0)3(Me/Me-TACN2](PF6)2인 표백 또는 세정방법.
  20. 페록시 화합물과 제1항 기재의 촉매 또는 제13항 기재의 촉매 전구체를 함유하는 표백 조성물.
  21. 제20항에 있어서, 2-30중량%의 상기 페록시화합물과 0.0005-1.0중량%의 Mn의함량에 해당하는 상기 촉매 또는 촉매전구체를 함유하는 표백조성물.
  22. 제21항에 있어서, Mn함량이 0.001-0.5중량%인 표백조성물.
  23. 제20항에 있어서, 페록시 화합물이 과산화수소, 과산화수소-방출 화합물, 과산화수소-발생계, 페록시산 및 그 염, 페록시산 전구체 및 이들의 혼합물 중에서 선택되는 표백 조성물.
  24. 제23항에 있어서, 50중량%이하의 계면활성 화합물을 또한 함유하는 표백조성물.
  25. 제24항에 있어서, 5-80중량%의 세척력 빌더를 또한 함유하는 표백조성물.
  26. 제23항에 있어서, 프로테아제, 셀룰라제, 리파제, 아밀라제, 옥시다제 및 이들의 혼합물로 부터 선택되는 효소를 또한 함유하는 표백 조성물.
  27. 제20항에 있어서, 촉매가 [MnⅣ2(μ-0)3(Me-TACN2](PF6)2인 표백 조성물.
  28. 제20항에 있어서, 촉매가 [MnⅣ2(μ-0)3(Me/Me-TACN2](PF6)2인 표백 조상물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910008224A 1990-05-21 1991-05-22 표백제 활성화 방법 KR950001046B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB909011338A GB9011338D0 (en) 1990-05-21 1990-05-21 Bleach activation
GB9027415.0 1990-12-18
GB9011338.2 1990-12-18
GB90274150 1990-12-18
GB909027415A GB9027415D0 (en) 1990-12-18 1990-12-18 Bleach activation

Publications (2)

Publication Number Publication Date
KR910019678A true KR910019678A (ko) 1991-12-19
KR950001046B1 KR950001046B1 (ko) 1995-02-08

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KR1019910008223A KR950001045B1 (ko) 1990-05-21 1991-05-22 표백제 활성화 방법

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US (2) US5246621A (ko)
EP (2) EP0458398B1 (ko)
JP (2) JP2613707B2 (ko)
KR (2) KR950001046B1 (ko)
AU (2) AU622362B2 (ko)
BR (2) BR9102085A (ko)
CA (2) CA2042738C (ko)
DE (2) DE69125309T2 (ko)
ES (2) ES2100925T3 (ko)
IN (2) IN173875B (ko)
MY (2) MY106557A (ko)
NO (2) NO911942L (ko)

Families Citing this family (433)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9108136D0 (en) * 1991-04-17 1991-06-05 Unilever Plc Concentrated detergent powder compositions
EP0522817A1 (en) * 1991-07-11 1993-01-13 Unilever Plc Process for preparing manganese complexes
GB9118242D0 (en) * 1991-08-23 1991-10-09 Unilever Plc Machine dishwashing composition
DE69129150T2 (de) * 1991-10-14 1998-10-08 Procter & Gamble Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung
GB9124581D0 (en) * 1991-11-20 1992-01-08 Unilever Plc Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions
US5153161A (en) * 1991-11-26 1992-10-06 Lever Brothers Company, Division Of Conopco, Inc. Synthesis of manganese oxidation catalyst
EP0544490A1 (en) * 1991-11-26 1993-06-02 Unilever Plc Detergent bleach compositions
US5194416A (en) * 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
GB9127060D0 (en) * 1991-12-20 1992-02-19 Unilever Plc Bleach activation
CA2085642A1 (en) * 1991-12-20 1993-06-21 Ronald Hage Bleach activation
US5256779A (en) * 1992-06-18 1993-10-26 Lever Brothers Company, Division Of Conopco, Inc. Synthesis of manganese oxidation catalyst
FR2692499B1 (fr) * 1992-06-22 1994-08-26 Atochem Elf Sa Procédé de délignification et de blanchiment d'une matière lignocellulosique.
US5280117A (en) * 1992-09-09 1994-01-18 Lever Brothers Company, A Division Of Conopco, Inc. Process for the preparation of manganese bleach catalyst
GB9222129D0 (en) * 1992-10-21 1992-12-02 Unilever Plc Detergent composition
US5480575A (en) * 1992-12-03 1996-01-02 Lever Brothers, Division Of Conopco, Inc. Adjuncts dissolved in molecular solid solutions
US5288746A (en) * 1992-12-21 1994-02-22 The Procter & Gamble Company Liquid laundry detergents containing stabilized glucose/glucose oxidase as H2 O2 generation system
AU6000594A (en) * 1993-02-22 1994-09-14 Unilever Plc Machine dishwashing composition
GB9305626D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Bleach and detergent compositions
GB9305598D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Bleach catalyst composition
GB9305599D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Detergent compositions
US5329024A (en) * 1993-03-30 1994-07-12 National Starch And Chemical Investment Holding Corporation Epoxidation of olefins via certain manganese complexes
GB9308047D0 (en) * 1993-04-19 1993-06-02 Unilever Plc Particulate detergent,bleaching or cleaning compositions containing aluminosilicates
EP0622447A1 (en) * 1993-04-26 1994-11-02 The Procter & Gamble Company Enzymatic detergent compositions inhibiting dye transfer
ES2121174T3 (es) * 1993-06-19 1998-11-16 Ciba Geigy Ag Inhibicion de la reabsorcion de colorantes migrantes en el licor de lavado.
US5672295A (en) * 1993-07-26 1997-09-30 Lever Brothers Company, Division Of Conopco, Inc. Amido peroxycarboxylic acids for bleaching
US5413733A (en) * 1993-07-26 1995-05-09 Lever Brothers Company, Division Of Conopco, Inc. Amidooxy peroxycarboxylic acids and sulfonimine complex catalysts
US5429769A (en) * 1993-07-26 1995-07-04 Lever Brothers Company, Division Of Conopco, Inc. Peroxycarboxylic acids and manganese complex catalysts
GB9318295D0 (en) * 1993-09-03 1993-10-20 Unilever Plc Bleach catalyst composition
AU7506694A (en) * 1993-09-03 1995-03-22 Unilever Plc Bleach catalyst composition
US5601750A (en) * 1993-09-17 1997-02-11 Lever Brothers Company, Division Of Conopco, Inc. Enzymatic bleach composition
GB9322530D0 (en) * 1993-11-02 1993-12-22 Unilever Plc Process for the production of a detergent composition
WO1995027774A1 (en) * 1994-04-07 1995-10-19 The Procter & Gamble Company Bleach compositions comprising metal-containing bleach catalysts and antioxidants
US5686014A (en) * 1994-04-07 1997-11-11 The Procter & Gamble Company Bleach compositions comprising manganese-containing bleach catalysts
US5965505A (en) * 1994-04-13 1999-10-12 The Procter & Gamble Company Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system
EP0682105A3 (en) * 1994-04-13 1997-11-05 The Procter & Gamble Company Bleaching compositions
JPH09512298A (ja) * 1994-04-22 1997-12-09 ザ、プロクター、エンド、ギャンブル、カンパニー アミラーゼを含有する粒状洗剤組成物
AU2524495A (en) * 1994-05-09 1995-11-29 Unilever Plc Bleach catalyst composition
DE4416438A1 (de) * 1994-05-10 1995-11-16 Basf Ag Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren
GB9410677D0 (en) 1994-05-27 1994-07-13 Unilever Plc Detergent compositions
US5560748A (en) * 1994-06-10 1996-10-01 The Procter & Gamble Company Detergent compositions comprising large pore size redox catalysts
WO1995034628A1 (en) * 1994-06-13 1995-12-21 Unilever N.V. Bleach activation
GB2294268A (en) * 1994-07-07 1996-04-24 Procter & Gamble Bleaching composition for dishwasher use
ES2132687T3 (es) * 1994-07-04 1999-08-16 Unilever Nv Procedimiento y composicion de lavado.
DE69533149T2 (de) * 1994-07-21 2005-08-25 Ciba Specialty Chemicals Holding Inc. Bleichmittelzusammensetzung für Gewebe
WO1996006154A1 (en) * 1994-08-19 1996-02-29 Unilever N.V. Detergent bleach composition
WO1996006155A1 (en) * 1994-08-24 1996-02-29 The Procter & Gamble Company Bleach compositions comprising metal-containing bleach catalysts and ammonium salts
GB9417354D0 (en) * 1994-08-26 1994-10-19 Unilever Plc Detergent particles and process for their production
GB9417356D0 (en) * 1994-08-26 1994-10-19 Unilever Plc Detergent particles and process for their production
US5578136A (en) 1994-08-31 1996-11-26 The Procter & Gamble Company Automatic dishwashing compositions comprising quaternary substituted bleach activators
DE4439039A1 (de) * 1994-11-02 1996-05-09 Hoechst Ag Granulierte Bleichaktivatoren und ihre Herstellung
GB2294706A (en) * 1994-11-05 1996-05-08 Procter & Gamble Bleaching composition
WO1996014380A1 (en) * 1994-11-05 1996-05-17 The Procter & Gamble Company Detergents containing a peroxide source, a bleach precursor and a hydrogen peroxide scavenger
US5720897A (en) * 1995-01-25 1998-02-24 University Of Florida Transition metal bleach activators for bleaching agents and detergent-bleach compositions
JPH10513214A (ja) * 1995-02-02 1998-12-15 ザ、プロクター、エンド、ギャンブル、カンパニー コバルトキレート化触媒を含む自動皿洗い組成物
US5968881A (en) * 1995-02-02 1999-10-19 The Procter & Gamble Company Phosphate built automatic dishwashing compositions comprising catalysts
JPH10513215A (ja) * 1995-02-02 1998-12-15 ザ、プロクター、エンド、ギャンブル、カンパニー コバルト▲ｉｉｉ▼触媒を含む自動皿洗い組成物
GB2297978A (en) 1995-02-15 1996-08-21 Procter & Gamble Detergent compositions containing amylase
US5556787A (en) * 1995-06-07 1996-09-17 Hach Company Manganese III method for chemical oxygen demand analysis
US5597936A (en) * 1995-06-16 1997-01-28 The Procter & Gamble Company Method for manufacturing cobalt catalysts
ATE203563T1 (de) * 1995-06-16 2001-08-15 Procter & Gamble Bleichmittelzusammensetzungen, die kobaltkatalysatoren enthalten
EP0832176B1 (en) * 1995-06-16 2001-07-11 The Procter & Gamble Company Automatic dishwashing compositions comprising cobalt catalysts
US5581005A (en) * 1995-06-16 1996-12-03 The Procter & Gamble Company Method for manufacturing cobalt catalysts
DE19523891C1 (de) * 1995-06-30 1996-11-21 Hoechst Ag Chirale Mangan-triazanonankomplexe und Verfahren zu ihrer Herstellung
EP0752466A1 (en) 1995-07-05 1997-01-08 The Procter & Gamble Company Nonaqueous detergent compositions comprising effervescent systems
US5559261A (en) * 1995-07-27 1996-09-24 The Procter & Gamble Company Method for manufacturing cobalt catalysts
DE19529905A1 (de) * 1995-08-15 1997-02-20 Henkel Kgaa Aktivatorkomplexe für Persauerstoffverbindungen
DE19529904A1 (de) * 1995-08-15 1997-02-20 Henkel Kgaa Reinigungsmittel mit Aktivatorkomplexen für Persauerstoffverbindungen
DE19535082A1 (de) 1995-09-21 1997-03-27 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Wasch- und Reinigungsmittel
US5703034A (en) * 1995-10-30 1997-12-30 The Procter & Gamble Company Bleach catalyst particles
EP0778342A1 (en) 1995-12-06 1997-06-11 The Procter & Gamble Company Detergent compositions
DE19545729A1 (de) 1995-12-08 1997-06-12 Henkel Kgaa Bleich- und Waschmittel mit enzymatischem Bleichsystem
DE19600161C1 (de) 1996-01-04 1997-04-17 Hoechst Ag Bis- und Tris-(mu-oxo)-di-Mangan-Komplexsalze und deren Verwendung
DE19600159A1 (de) 1996-01-04 1997-07-10 Hoechst Ag Bleichmittelsysteme enthaltend Bis- und Tris-(mu-oxo)-di-Mangan-Komplexsalze
DE19600160C1 (de) * 1996-01-04 1997-05-28 Hoechst Ag Verfahren zur Oxidation von Vinylverbindungen in Gegenwart von Bis- und Tris-(mu-oxo)-di-Mangan-Komplexsalzen als Katalysator
GB2309976A (en) * 1996-02-08 1997-08-13 Procter & Gamble Bleach catalyst particles for inclusion in detergents
US6093343A (en) * 1996-02-08 2000-07-25 The Procter & Gamble Company Detergent particles comprising metal-containing bleach catalysts
DE19605688A1 (de) * 1996-02-16 1997-08-21 Henkel Kgaa Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen
DE19606343A1 (de) 1996-02-21 1997-08-28 Hoechst Ag Bleichmittel
GB9604022D0 (en) * 1996-02-26 1996-04-24 Unilever Plc Anionic detergent particles
GB9604000D0 (en) * 1996-02-26 1996-04-24 Unilever Plc Production of anionic detergent particles
GB2311078A (en) * 1996-03-16 1997-09-17 Procter & Gamble Bleaching composition containing cellulolytic enzyme
DE69731078T2 (de) * 1996-03-19 2005-10-06 The Procter & Gamble Company, Cincinnati Herstellngsverfahren von maschinengeschirrspülreinigern enthaltend blumiges parfüm und builder
DE19613103A1 (de) * 1996-04-01 1997-10-02 Henkel Kgaa Übergangsmetallkomplex-haltige Systeme als Aktivatoren für Persauerstoffverbindungen
WO1997036986A1 (de) * 1996-04-01 1997-10-09 Henkel Kommanditgesellschaft Auf Aktien Reinigungsmittel mit oligoamminaktivatorkomplexen für persauerstoffverbindungen
DE19620411A1 (de) 1996-04-01 1997-10-02 Henkel Kgaa Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen
US6066612A (en) 1996-05-03 2000-05-23 The Procter & Gamble Company Detergent compositions comprising polyamine polymers with improved soil dispersancy
DE19620241A1 (de) * 1996-05-20 1997-11-27 Patt R Prof Dr Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators
BR9709798A (pt) * 1996-06-19 1999-08-10 Unilever Nv Catalisador de alvejamento e oxidacão sistema de oxidacão catalítica e composicão de alvejamento
US5876625A (en) * 1996-07-22 1999-03-02 Carnegie Mellon University Metal ligand containing bleaching compositions
US6136223A (en) 1996-07-22 2000-10-24 Carnegie Mellon University Metal ligand containing bleaching compositions
DE19636035A1 (de) 1996-09-05 1998-03-12 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Wasch- und Reinigungsmittel
GB9620093D0 (en) * 1996-09-26 1996-11-13 Unilever Plc Photofading inhibitor derivatives and their use in fabric treatment compositions
DE19649375A1 (de) 1996-11-29 1998-06-04 Henkel Kgaa Acetonitril-Derivate als Bleichaktivatoren in Reinigungsmitteln
EP0849354A1 (en) 1996-12-20 1998-06-24 Unilever Plc Softening compositions
DE19703364A1 (de) 1997-01-30 1998-08-06 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Wasch- und Reinigungsmittel
US6387862B2 (en) 1997-03-07 2002-05-14 The Procter & Gamble Company Bleach compositions
EP0977828B1 (en) 1997-03-07 2005-05-11 The Procter & Gamble Company Bleach compositions
US20030017941A1 (en) 1997-03-07 2003-01-23 The Procter & Gamble Company Catalysts and methods for catalytic oxidation
DE19709411A1 (de) 1997-03-07 1998-09-10 Henkel Kgaa Waschmittelformkörper
US6218351B1 (en) 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
AU731577B2 (en) 1997-03-07 2001-04-05 Procter & Gamble Company, The Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
DE19758811B4 (de) 1997-03-11 2008-12-18 Henkel Ag & Co. Kgaa Waschmittelpressling
DE19710254A1 (de) * 1997-03-13 1998-09-17 Henkel Kgaa Wasch- oder reinigungsaktive Formkörper für den Gebrauch im Haushalt
DE19714122A1 (de) * 1997-04-05 1998-10-08 Clariant Gmbh Bleichaktive Metall-Komplexe
DE19719397A1 (de) * 1997-05-07 1998-11-12 Clariant Gmbh Bleichaktive Metall-Komplexe
DE19721886A1 (de) * 1997-05-26 1998-12-03 Henkel Kgaa Bleichsystem
GB9711831D0 (en) * 1997-06-06 1997-08-06 Unilever Plc Cleaning compositions
GB9711829D0 (en) 1997-06-06 1997-08-06 Unilever Plc Detergent compositions
DE19726141A1 (de) * 1997-06-19 1999-01-28 Daum Gmbh Neurotrokar
DE19728021A1 (de) * 1997-07-01 1999-01-07 Clariant Gmbh Metall-Komplexe als Bleichaktivatoren
DE19732750A1 (de) 1997-07-30 1999-02-04 Henkel Kgaa Glucanasehaltiges Reinigungsmittel für harte Oberflächen
DE19732751A1 (de) 1997-07-30 1999-02-04 Henkel Kgaa Neue Beta-Glucanase aus Bacillus
DE19732749A1 (de) 1997-07-30 1999-02-04 Henkel Kgaa Glucanasehaltiges Waschmittel
DE19738273A1 (de) * 1997-09-02 1999-03-04 Clariant Gmbh Cyclische Polyaminsalze
US6066610A (en) * 1997-09-19 2000-05-23 S. C. Johnson & Son, Inc. Low pH amphoteric fabric cleaning solution
CA2248476A1 (en) * 1997-10-01 1999-04-01 Unilever Plc Bleach activation
AR015977A1 (es) 1997-10-23 2001-05-30 Genencor Int Variantes de proteasa multiplemente substituida con carga neta alterada para su empleo en detergentes
CN1280610A (zh) 1997-11-14 2001-01-17 美国博拉克有限公司 漂白催化剂
CA2310457A1 (en) 1997-11-21 1999-06-03 Laura Anne Oakes Product applicator
GB9725614D0 (en) 1997-12-03 1998-02-04 United States Borax Inc Bleaching compositions
US6410500B1 (en) 1997-12-30 2002-06-25 Henkel Kommanditgesellschaft Auf Aktien Moulded body dishwasher detergents with soil release polymers
US6992056B1 (en) 1997-12-30 2006-01-31 Henkel Kgaa Process for preparing detergent tablets having two or more regions
DE19758262A1 (de) 1997-12-31 1999-07-08 Henkel Kgaa Alkylaminotriazolhaltige, granulare Komponente für den Einsatz in Maschinengeschirrspülmitteln (MGSM) und Verfahren zu dessen Herstellung
DE19819187A1 (de) 1998-04-30 1999-11-11 Henkel Kgaa Festes maschinelles Geschirrspülmittel mit Phosphat und kristallinen schichtförmigen Silikaten
KR100516489B1 (ko) * 1998-06-05 2005-12-28 주식회사 엘지생활건강 과산화물 표백제를 활성시키는 비피리딘 망간 착화합물
US6121181A (en) * 1998-08-07 2000-09-19 Equistar Chemicals, L.P. Cyclic oligomeric oxo- and imido- metal complexes as olefin polymerization catalysts
DE19850100A1 (de) 1998-10-29 2000-05-04 Henkel Kgaa Polymer-Granulate durch Wirbelschichtgranulation
DE69817832T2 (de) * 1998-11-10 2004-10-07 Unilever Nv Bleich- und Oxidationskatalysator
DE69825166T2 (de) * 1998-11-10 2004-11-25 Unilever N.V. Wasch- und Bleichzusammensetzungen
US6667288B2 (en) * 1998-11-13 2003-12-23 Procter & Gamble Company Bleach compositions
AU2151200A (en) * 1998-11-16 2000-06-05 Procter & Gamble Company, The Cleaning product which uses sonic or ultrasonic waves
BR0008014A (pt) 1999-02-05 2001-11-20 Unilever Nv Processo para lavagem de artigos em uma máquinapara lavagem mecânica, usos de ácido cìtrico desal de bicarbonato, e de um agente quelante, e,conjunto de peças para uso em uma máquinaautomática para lavagem de pratos
DE19908051A1 (de) 1999-02-25 2000-08-31 Henkel Kgaa Verfahren zur Herstellung compoundierter Acetonitril-Derivate
US6653270B2 (en) * 1999-03-02 2003-11-25 Procter & Gamble Company Stabilized bleach compositions
DE19914811A1 (de) 1999-03-31 2000-10-05 Henkel Kgaa Enzym- und bleichaktivatorhaltige Wasch- und Reinigungsmittel
AU759577B2 (en) * 1999-07-14 2003-04-17 Diversey, Inc. A detergent composition and laundry washing method
US6660711B1 (en) 1999-07-16 2003-12-09 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines and mid-chain branched surfactants
WO2001016270A1 (en) * 1999-09-01 2001-03-08 Unilever Plc Composition and method for bleaching a substrate
DE19943254A1 (de) 1999-09-10 2001-03-15 Clariant Gmbh Bleichaktive Metallkomplexe
DE19944218A1 (de) 1999-09-15 2001-03-29 Cognis Deutschland Gmbh Waschmitteltabletten
WO2001021499A1 (en) 1999-09-22 2001-03-29 The Procter & Gamble Company A hand-held liquid container
US6686327B1 (en) 1999-10-09 2004-02-03 Cognis Deutschland Gmbh & Co. Kg Shaped bodies with improved solubility in water
US6610752B1 (en) 1999-10-09 2003-08-26 Cognis Deutschland Gmbh Defoamer granules and processes for producing the same
JP2003514101A (ja) 1999-11-09 2003-04-15 ザ、プロクター、エンド、ギャンブル、カンパニー 疎水変性ポリアミンを含むランドリー洗剤組成物
US6812198B2 (en) * 1999-11-09 2004-11-02 The Procter & Gamble Company Laundry detergent compositions comprising hydrophobically modified polyamines
DE19953792A1 (de) 1999-11-09 2001-05-17 Cognis Deutschland Gmbh Waschmitteltabletten
US6696401B1 (en) * 1999-11-09 2004-02-24 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines
DE19956802A1 (de) 1999-11-25 2001-06-13 Cognis Deutschland Gmbh Waschmitteltabletten
DE19956803A1 (de) 1999-11-25 2001-06-13 Cognis Deutschland Gmbh Tensidgranulate mit verbesserter Auflösegeschwindigkeit
GB9930422D0 (en) 1999-12-22 2000-02-16 Unilever Plc Bleach catalysts
DE19962886A1 (de) 1999-12-24 2001-07-05 Cognis Deutschland Gmbh Tensidgranulate mit verbesserter Auflösegeschwindigkeit
DE19962883A1 (de) 1999-12-24 2001-07-12 Cognis Deutschland Gmbh Waschmitteltabletten
DE10003124A1 (de) 2000-01-26 2001-08-09 Cognis Deutschland Gmbh Verfahren zur Herstellung von Tensidgranulaten
KR20010081172A (ko) * 2000-02-10 2001-08-29 성재갑 과산화물 표백제를 활성화시키는 전이 금속 착화합물을포함하는 표백 세제 조성물
AU2001256155A1 (en) 2000-02-29 2001-09-12 Unilever Plc Composition and method for bleaching a substrate
GB0004962D0 (en) * 2000-03-01 2000-04-19 Univ Cardiff Macrocyclic ligands and complexes thereof
DE10019344A1 (de) 2000-04-18 2001-11-08 Cognis Deutschland Gmbh Wasch- und Reinigungsmittel
DE10019405A1 (de) 2000-04-19 2001-10-25 Cognis Deutschland Gmbh Verfahren zur Herstellung von Waschmittelgranulaten
DE10019878A1 (de) 2000-04-20 2001-10-25 Clariant Gmbh Bleichaktive Dendrimer-Liganden und deren Metall-Komplexe
DE10019877A1 (de) 2000-04-20 2001-10-25 Clariant Gmbh Wasch- und Reinigungsmittel enthaltend bleichaktive Dendrimer-Liganden und deren Metall-Komplexe
US6602836B2 (en) 2000-05-11 2003-08-05 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Machine dishwashing compositions containing cationic bleaching agents and water-soluble polymers incorporating cationic groups
GB0013643D0 (en) 2000-05-31 2000-07-26 Unilever Plc Targeted moieties for use in bleach catalysts
DE10031620A1 (de) 2000-06-29 2002-01-10 Cognis Deutschland Gmbh Flüssigwaschmittel
DE10044471A1 (de) 2000-09-08 2002-03-21 Cognis Deutschland Gmbh Waschmittel
DE10044472A1 (de) 2000-09-08 2002-03-21 Cognis Deutschland Gmbh Waschmittel
DE10046251A1 (de) 2000-09-19 2002-03-28 Cognis Deutschland Gmbh Wasch- und Reinigungsmittel auf Basis von Alkyl- und/oder Alkenyloligoglycosiden und Fettalkoholen
DE60134760D1 (de) 2000-10-27 2008-08-21 Procter & Gamble Stabilisierte flüssige zusammensetzungen
DE10058645A1 (de) 2000-11-25 2002-05-29 Clariant Gmbh Verwendung von cyclischen Zuckerketonen als Katalysatoren für Persauerstoffverbindungen
US20030050211A1 (en) * 2000-12-14 2003-03-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Enzymatic detergent compositions
GB0030877D0 (en) 2000-12-18 2001-01-31 Unilever Plc Enhancement of air bleaching catalysts
GB0031823D0 (en) 2000-12-29 2001-02-14 Unilever Plc Detergent compositions
GB0031827D0 (en) 2000-12-29 2001-02-14 Unilever Plc Detergent compositions
DE10102248A1 (de) 2001-01-19 2002-07-25 Clariant Gmbh Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren
GB0103871D0 (en) 2001-02-16 2001-04-04 Unilever Plc Bleaching composition of enhanced stability and a process for making such a composition
WO2003086336A1 (fr) * 2001-03-02 2003-10-23 Kao Corporation Composition de colorant capillaire
JP4532762B2 (ja) 2001-03-02 2010-08-25 花王株式会社 染毛剤組成物
GB0106285D0 (en) 2001-03-14 2001-05-02 Unilever Plc Air bleaching catalysts with moderating agent
WO2002072746A1 (en) 2001-03-14 2002-09-19 Unilever Plc Bleaching catalysts with unsaturated surfactant and antioxidants
US6475977B1 (en) 2001-03-16 2002-11-05 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Water soluble sachet with a dishwasher composition
US6492312B1 (en) 2001-03-16 2002-12-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Water soluble sachet with a dishwashing enhancing particle
WO2002088063A1 (en) * 2001-04-27 2002-11-07 Lonza Ag Process for the production of ketones
DE10134364A1 (de) 2001-07-14 2003-01-23 Clariant Gmbh Verfahren zur Herstellung von Bleichaktivator-Granulaten
DE10136805A1 (de) 2001-07-25 2003-02-13 Clariant Gmbh Verfahren zur Herstellung von Bleichaktivator-Granulaten
GB0118749D0 (en) * 2001-08-01 2001-09-26 Procter & Gamble Water treatment compositions
GB0127036D0 (en) 2001-11-09 2002-01-02 Unilever Plc Polymers for laundry applications
DE10161766A1 (de) * 2001-12-15 2003-06-26 Clariant Gmbh Bleichaktivator-Co-Granulate
DE10163331A1 (de) 2001-12-21 2003-07-10 Henkel Kgaa Trägerfixierte Bleichkatalysatorkomplexverbindungen geeignet als Katalysatoren für Persauerstoffverbindungen
DE10163856A1 (de) 2001-12-22 2003-07-10 Cognis Deutschland Gmbh Hydroxymischether und Polymere in Form von festen Mitteln als Vorcompound für Wasch-, Spül- und Reinigungsmittel
ATE444120T1 (de) 2002-01-15 2009-10-15 Lonza Ag Mangan(iv)-komplexsalze und ihre verwendung als oxidationskatalysatoren
AU2003205725A1 (en) * 2002-02-28 2003-09-09 Unilever N.V. Bleach catalyst enhancement
KR100979849B1 (ko) * 2002-11-19 2010-09-02 애경산업(주) 거대고리 망간 착화합물을 함유한 표백제 및 표백세제조성물
BR0316878B1 (pt) 2002-12-23 2012-08-21 polìmeros hidrofobicamente modificados, produto de limpeza, formulação de processo têxtil, auxiliares de tingimento ou impressão e/ou agentes de acabamento, e método para processamento têxtil.
BRPI0407114B1 (pt) 2003-02-03 2018-09-11 Unilever Nv composição para lavagem de roupa
DE10304131A1 (de) 2003-02-03 2004-08-05 Clariant Gmbh Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren
US7066871B1 (en) 2003-06-05 2006-06-27 Bescorp, Inc. Folder with set feeder and telescoping stacker
DE10334046A1 (de) * 2003-07-25 2005-02-10 Clariant Gmbh Verfahren zur Herstellung von granulierten Acyloxybenzolsulfonaten oder Acyloxybenzolcarbonsäuren und deren Salze
GB0324245D0 (en) * 2003-10-16 2003-11-19 Reckitt Benckiser Nv Coated bleach particle
DE102004003710A1 (de) * 2004-01-24 2005-08-11 Clariant Gmbh Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln
DE102004012915A1 (de) * 2004-03-17 2005-10-13 Clariant Gmbh Feste Zubereitungen enthaltend einen sensitiven Wirkstoff
US7704940B2 (en) 2004-04-09 2010-04-27 The Sun Products Corporation Granulate for use in a cleaning product and process for its manufacture
KR100647976B1 (ko) * 2004-05-03 2006-11-23 애경산업(주) 표백촉매로서 거대고리 망간 착화합물 및 이를 함유한표백제 및 표백세제 조성물
GB2416539A (en) 2004-07-24 2006-02-01 Reckitt Benckiser Liquid cleaning composition, catalyst therefor and methods of cleaning
EP1642960B1 (en) 2004-10-01 2007-10-31 Unilever N.V. Detergent compositions in tablet form
EP1669438B1 (en) 2004-12-08 2007-10-17 Unilever N.V. Detergent tablet
DE602005014328D1 (de) 2005-01-04 2009-06-18 Unilever Nv Wasch- und Reinigungsmittelformkörper
DE602006002151D1 (de) 2005-03-23 2008-09-25 Unilever Nv Körperförmige Wasch- oder Reinigungsmittelzusammensetzungen
EP1705240A1 (en) 2005-03-23 2006-09-27 Unilever N.V. Detergent tablets
US20090205143A1 (en) * 2005-05-27 2009-08-20 Ronald Hage Process of bleaching
EP1746151A1 (en) 2005-07-20 2007-01-24 Unilever N.V. Detergent tablet compositions
EP1746152A1 (en) 2005-07-20 2007-01-24 Unilever N.V. Detergent compositions
WO2007025244A2 (en) 2005-08-25 2007-03-01 Houle Philip R Treatment systems for delivery of sensitizer solutions
ES2323554T3 (es) 2005-10-12 2009-07-20 Unilever N.V. Blanqueado de sustratos.
GB0524659D0 (en) 2005-12-02 2006-01-11 Unilever Plc Improvements relating to fabric treatment compositions
US20070138674A1 (en) 2005-12-15 2007-06-21 Theodore James Anastasiou Encapsulated active material with reduced formaldehyde potential
EP1832648A1 (en) 2006-03-08 2007-09-12 Unilever Plc Laundry detergent composition and process
EP1840198A1 (en) * 2006-03-30 2007-10-03 Unilever Plc Bleaching composition
DE102007039651A1 (de) 2006-11-27 2009-02-26 Henkel Ag & Co. Kgaa Bleichkatalysatorgranulat
ES2394847T3 (es) * 2007-01-16 2013-02-06 Catexel Limited Blanqueo de sustratos
US20080177089A1 (en) 2007-01-19 2008-07-24 Eugene Steven Sadlowski Novel whitening agents for cellulosic substrates
DE102008000029A1 (de) 2008-01-10 2009-07-16 Lanxess Deutschland Gmbh Geschirrreinigungsmittel
DE102007003885A1 (de) 2007-01-19 2008-07-24 Lanxess Deutschland Gmbh Geschirrreinigungsmittel
US7928040B2 (en) 2007-01-23 2011-04-19 Halliburton Energy Services, Inc. Compositions and methods for breaking a viscosity increasing polymer at very low temperature used in downhole well applications
US7923417B2 (en) 2007-01-23 2011-04-12 Halliburton Energy Services, Inc. Compositions and methods for breaking a viscosity increasing polymer at very low temperature used in downhole well applications
DE102007006630A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006628A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006629A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007017657A1 (de) 2007-04-12 2008-10-16 Henkel Ag & Co. Kgaa Tris/heterocyclyl)-Metallkomplexe als Bleichkatalysatoren
US8558051B2 (en) * 2007-07-18 2013-10-15 The Procter & Gamble Company Disposable absorbent article having odor control system
US8262804B2 (en) 2007-10-12 2012-09-11 Basf Se Dishwasher detergent formulations comprising a mixture of hydrophobically modified polycarboxylates and hydrophilically modified polycarboxylates
US8198503B2 (en) * 2007-11-19 2012-06-12 The Procter & Gamble Company Disposable absorbent articles comprising odor controlling materials
DE102007059970A1 (de) 2007-12-11 2009-09-10 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007059968A1 (de) 2007-12-11 2009-06-18 Henkel Ag & Co. Kgaa Reinigungsmittel
JP5401034B2 (ja) 2007-12-19 2014-01-29 ライオン株式会社 漂白助剤、および該漂白助剤を含有する漂白助剤粒子
US20090325841A1 (en) * 2008-02-11 2009-12-31 Ecolab Inc. Use of activator complexes to enhance lower temperature cleaning in alkaline peroxide cleaning systems
EP2103735A1 (en) * 2008-03-18 2009-09-23 Unilever PLC Catalytic bleaching of substrates
MX2010010961A (es) 2008-04-09 2010-11-05 Basf Se Uso de compuestos complejos de hidracida de metal como catalizadores de oxidacion.
DE102008045297A1 (de) 2008-09-02 2010-03-04 Friedrich-Alexander-Universität Erlangen-Nürnberg Textilschonendes Waschmittel
DE102008024800A1 (de) 2008-05-23 2009-11-26 Henkel Ag & Co. Kgaa Textilschonendes Waschmittel
GB0813460D0 (en) 2008-07-23 2008-08-27 Reckitt Benckiser Nv Container
EP2149569A1 (en) 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Process for the manufacture of a 1,2-Epoxide
EP2149570A1 (en) 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex
EP2228429A1 (en) 2009-03-13 2010-09-15 Unilever PLC Shading dye and catalyst combination
GB0904700D0 (en) 2009-03-19 2009-04-29 Unilever Plc Improvements relating to benefit agent delivery
DE102009017722A1 (de) 2009-04-11 2010-10-14 Clariant International Limited Bleichmittelgranulate mit Aktivcoating
DE102009017724A1 (de) 2009-04-11 2010-10-14 Clariant International Limited Bleichmittelgranulate
WO2010131231A2 (en) * 2009-05-14 2010-11-18 Ecolab Usa Inc. Peroxygen catalyst-containing fabric and use for in situ generation of alkalinity
EP2273006A1 (en) 2009-06-17 2011-01-12 Unilever PLC Bleaching of substrates
WO2011005730A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company A catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte
EP2451919A1 (en) 2009-07-09 2012-05-16 The Procter & Gamble Company Method of laundering fabric using a liquid laundry detergent composition
EP2451914A1 (en) 2009-07-09 2012-05-16 The Procter & Gamble Company A catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte
WO2011005623A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company Laundry detergent composition comprising low level of bleach
WO2011005910A1 (en) * 2009-07-09 2011-01-13 The Procter & Gamble Company Method of laundering fabric using a compacted laundry detergent composition
HUE029942T2 (en) 2009-08-13 2017-04-28 Procter & Gamble Method for washing low temperature fabrics
ES2533072T3 (es) 2009-09-18 2015-04-07 Weylchem Switzerland Ag Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano
EP2343288A1 (en) 2009-11-27 2011-07-13 Momentive Specialty Chemicals Research Belgium S.A. Process for the manufacture of propylene oxide
DE102009057222A1 (de) 2009-12-05 2011-06-09 Clariant International Ltd. Bleichkatalysator-Compounds, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102009057220A1 (de) 2009-12-05 2011-06-09 Clariant International Ltd. Nicht hygroskopische Übergangsmetallkomplexe, Verfahren zu ihrer Herstellung und ihre Verwendung
ES2423580T5 (es) 2009-12-10 2021-06-17 Procter & Gamble Método y uso de una composición para lavado de vajillas
EP2333041B1 (en) 2009-12-10 2013-05-15 The Procter & Gamble Company Method and use of a dishwasher composition
ES2399311T5 (es) 2009-12-10 2020-06-19 Procter & Gamble Composición detergente
EP2343336A1 (en) 2010-01-06 2011-07-13 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Curing liquids
US8933131B2 (en) 2010-01-12 2015-01-13 The Procter & Gamble Company Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
EP2354130A1 (en) 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium Manufacture of an epoxyethyl carboxylate or glycidyl carboxylate
EP2354129A1 (en) 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium S.A. Epoxidation process
EP2354131A1 (en) 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium Process for the manufacture of a 1,2-epoxide and a device for carrying out said process
EP2357180A1 (en) 2010-02-02 2011-08-17 Momentive Specialty Chemicals Research Belgium S.A. Manufacture of epoxyethyl ethers or glycidyl ethers
ES2401126T3 (es) 2010-02-25 2013-04-17 The Procter & Gamble Company Composición detergente
ES2586570T3 (es) 2010-03-03 2016-10-17 Catexel Limited Preparación de catalizadores de blanqueado
ES2565192T3 (es) 2010-04-23 2016-04-01 The Procter & Gamble Company Método para perfumar
EP2380478A1 (en) 2010-04-23 2011-10-26 The Procter & Gamble Company Automatic dishwashing product
ES2533368T3 (es) 2010-04-23 2015-04-09 The Procter & Gamble Company Producto para lavavajillas
EP2395147A1 (en) 2010-05-10 2011-12-14 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Freeness of paper products
US8262744B2 (en) 2010-05-18 2012-09-11 Milliken & Company Optical brighteners and compositions comprising the same
WO2011146602A2 (en) 2010-05-18 2011-11-24 Milliken & Company Optical brighteners and compositions comprising the same
US8476216B2 (en) 2010-05-28 2013-07-02 Milliken & Company Colored speckles having delayed release properties
WO2012000846A1 (en) 2010-06-28 2012-01-05 Basf Se Metal free bleaching composition
JP5759544B2 (ja) 2010-07-02 2015-08-05 ザ プロクター アンド ギャンブルカンパニー 活性剤を送達する方法
CN102971126B (zh) 2010-07-02 2016-03-23 宝洁公司 由非织造纤维网制备膜的方法
RU2541275C2 (ru) 2010-07-02 2015-02-10 Дзе Проктер Энд Гэмбл Компани Филаменты, содержащие неароматизированный активный агент, нетканые полотна и способы их получения
CN103025929B (zh) 2010-07-02 2015-11-25 宝洁公司 包含活性剂的长丝、非织造纤维网和制备它们的方法
JP5788503B2 (ja) 2010-07-02 2015-09-30 ザ プロクター アンド ギャンブルカンパニー ウェブ材料及びその製造方法
GB201011905D0 (en) 2010-07-15 2010-09-01 Unilever Plc Benefit delivery particle,process for preparing said particle,compositions comprising said particles and a method for treating substrates
MX2013000592A (es) 2010-07-15 2013-03-05 Procter & Gamble Una composicion para el cuidado personal que comprende un compuesto ramificado cerca de la terminal.
WO2012009660A2 (en) 2010-07-15 2012-01-19 The Procter & Gamble Company Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof
EP2441820A1 (en) 2010-10-14 2012-04-18 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Laundry detergent particles
US8715368B2 (en) 2010-11-12 2014-05-06 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
DE102011010818A1 (de) 2011-02-10 2012-08-16 Clariant International Ltd. Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln
CN103380107B (zh) 2011-02-17 2015-06-10 宝洁公司 生物基直链烷基苯基磺酸盐
RU2013136500A (ru) 2011-02-17 2015-03-27 Дзе Проктер Энд Гэмбл Компани Композиции, содержащие смеси с10-с13-алкилфенилсульфонатов
WO2012116023A1 (en) 2011-02-25 2012-08-30 Milliken & Company Capsules and compositions comprising the same
GB201106409D0 (en) 2011-04-15 2011-06-01 Revolymer Ltd Novel composite
GB201106391D0 (en) 2011-04-15 2011-06-01 Reckitt & Colman Overseas Novel composite
GB201106408D0 (en) 2011-04-15 2011-06-01 Revolymer Ltd Novel composite
DE102011118037A1 (de) * 2011-06-16 2012-12-20 Henkel Ag & Co. Kgaa Geschirrspülmittel mit Bleichkatalysator und Protease
EP2537836A1 (en) 2011-06-22 2012-12-26 Momentive Specialty Chemicals Research Belgium S.A. Apparatus and methods to preserve catalyst activity in an epoxidation process
WO2013002786A1 (en) 2011-06-29 2013-01-03 Solae Baked food compositions comprising soy whey proteins that have been isolated from processing streams
BR112014005435B1 (pt) * 2011-09-08 2019-11-12 Catexel Ltd método de preparação de um pó e pó
AR088756A1 (es) 2011-09-20 2014-07-02 Procter & Gamble Composiciones detergentes que comprenden relaciones de mezcla especificas de surfactantes a base de isoprenoides
EP2758505A1 (en) 2011-09-20 2014-07-30 The Procter and Gamble Company Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants
WO2013043855A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company High suds detergent compositions comprising isoprenoid-based surfactants
AR088758A1 (es) 2011-09-20 2014-07-02 Procter & Gamble Composiciones detergentes de facil enjuague que comprenden surfactantes basados en isoprenoides
JP2014526603A (ja) 2011-09-20 2014-10-06 ザ プロクター アンド ギャンブル カンパニー 高度に分枝したイソプレノイド系及び他の界面活性剤を含む主要な界面活性剤系を含む洗剤
US9371504B2 (en) 2011-10-25 2016-06-21 Basf Se Use of acrylate copolymers as soil antiredeposition agents and soil release agents in laundry processes
RU2014120925A (ru) 2011-10-25 2015-12-10 Басф Се Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки
EP2791309B1 (en) 2011-12-16 2018-02-07 Unilever Plc. Improvements relating to fabric treatment compositions
EA026023B9 (ru) 2011-12-22 2017-04-28 Юнилевер Н.В. Композиция моющего средства, содержащая глутамин-n,n-диацетат, воду и отбеливатель
CN106968050B (zh) 2012-01-04 2019-08-27 宝洁公司 具有多个区域的含活性物质纤维结构
EP2800831B1 (en) 2012-01-04 2020-12-16 The Procter and Gamble Company Fibrous structures comprising particles and methods for making same
CN106906573B (zh) 2012-01-04 2019-08-27 宝洁公司 具有不同密度的多个区域的含活性物质纤维结构
PL2662436T3 (pl) 2012-05-11 2018-02-28 The Procter And Gamble Company Kompozycja detergentu
JP6250640B2 (ja) 2012-05-11 2017-12-20 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ エトキシル化ポリエチレンイミン及びそれを使用する方法
US9068147B2 (en) 2012-05-11 2015-06-30 Basf Se Quaternized polyethylenimines with a high quaternization degree
US8754027B2 (en) 2012-05-11 2014-06-17 Basf Se Quaternized polyethulenimines with a high ethoxylation degree
JP2015530424A (ja) 2012-07-26 2015-10-15 ザ プロクター アンド ギャンブルカンパニー 酵素を有する低ｐＨ液体洗浄組成物
DE102012015826A1 (de) 2012-08-09 2014-02-13 Clariant International Ltd. Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen
ES2677702T3 (es) 2012-08-24 2018-08-06 The Procter & Gamble Company Método de lavado de vajillas
EP2700704B1 (en) 2012-08-24 2018-05-09 The Procter and Gamble Company Dishwashing method
CN104781383B (zh) 2012-11-19 2018-06-01 荷兰联合利华有限公司 涉及包封的有益剂的改进
CA2895328A1 (en) 2012-12-20 2014-06-26 The Procter & Gamble Company Detergent composition with silicate coated bleach
EP2746381A1 (en) 2012-12-21 2014-06-25 The Procter & Gamble Company Cleaning pack
DE102013004428A1 (de) 2013-03-15 2014-09-18 Clariant International Ltd. Verfahren zum Waschen und Reinigen von Textilien
AU2014243274B2 (en) 2013-03-27 2017-10-12 Henkel Ag & Co. Kgaa Block copolymers as soil release agents in laundry processes
HUE043499T2 (hu) 2013-03-28 2019-09-30 Procter & Gamble Poliéteramin-tartalmú tiszítószerek
PL3008159T3 (pl) 2013-06-12 2017-06-30 Unilever N.V. Nadająca się do wylewania detergentowa kompozycja zawierająca zawieszone cząstki
DE102013010549A1 (de) 2013-06-15 2014-12-18 Clariant International Ltd. Bleichmittel-Co-Granulate
DE102013010150A1 (de) 2013-06-15 2014-12-18 Clariant International Ltd. Bleichkatalysatorgranulate
BR112015031941A2 (pt) 2013-06-20 2020-01-14 Chemsenti Ltd método, composição, e formulação de branqueamento
EP3024918B1 (en) * 2013-07-24 2019-07-03 Arkema, Inc. Manganese carboxylates for peroxygen activation
AU2014307707B2 (en) * 2013-08-16 2018-08-02 Chemsenti Limited Composition
EP2857487A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857485A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857486A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
JP6254693B2 (ja) * 2013-10-24 2017-12-27 エコラボ ユーエスエー インコーポレイティド 表面から汚れを除去する組成物及び方法
DE102013019269A1 (de) 2013-11-15 2015-06-03 Weylchem Switzerland Ag Geschirrspülmittel sowie dessen Verwendung
KR20160105790A (ko) 2013-11-27 2016-09-07 바스프 에스이 세탁 방법에서 오염물 방출제로서의 랜덤 공중합체
JP6431087B2 (ja) 2013-12-09 2018-11-28 ザ プロクター アンド ギャンブル カンパニー 活性剤を含み、図形が印刷された繊維構造体
EP3107987B1 (en) 2014-02-20 2018-10-03 Unilever N.V. Machine dishwash composition
EP2915873A1 (en) 2014-03-06 2015-09-09 The Procter and Gamble Company Dishwashing composition
EP2915872A1 (en) 2014-03-06 2015-09-09 The Procter and Gamble Company Dishwashing composition
JP6275864B2 (ja) 2014-03-27 2018-02-07 ザ プロクター アンド ギャンブル カンパニー ポリエーテルアミンを含有する洗浄組成物
US20150275143A1 (en) 2014-03-27 2015-10-01 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
JP6466468B2 (ja) 2014-03-27 2019-02-06 ザ プロクター アンド ギャンブル カンパニー 印刷された水溶性パウチ
EP2940116B1 (en) 2014-04-30 2018-10-17 The Procter and Gamble Company Detergent
WO2015187757A1 (en) 2014-06-06 2015-12-10 The Procter & Gamble Company Detergent composition comprising polyalkyleneimine polymers
EP2955219B1 (en) 2014-06-12 2020-03-25 The Procter and Gamble Company Water soluble pouch comprising an embossed area
US9624119B2 (en) 2014-06-13 2017-04-18 Ecolab Usa Inc. Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations
US10196592B2 (en) 2014-06-13 2019-02-05 Ecolab Usa Inc. Enhanced catalyst stability for alkaline detergent formulations
DK2966161T3 (en) 2014-07-08 2019-02-25 Dalli Werke Gmbh & Co Kg ENZYME BLENDIC CATALYST CATEGRANULATE SUITABLE FOR DETERGENT COMPOSITIONS
ES2690335T3 (es) 2014-11-26 2018-11-20 The Procter & Gamble Company Bolsa limpiadora
EP3026103B1 (en) 2014-11-26 2018-07-25 The Procter and Gamble Company Cleaning pouch
ES2855023T3 (es) 2014-11-26 2021-09-23 Procter & Gamble Bolsa limpiadora
EP3026102B1 (en) 2014-11-26 2018-12-26 The Procter and Gamble Company Cleaning pouch
ES2668504T3 (es) 2014-12-22 2018-05-18 The Procter & Gamble Company Proceso para reciclar bolsas de detergente
EP3050954A1 (en) 2015-02-02 2016-08-03 The Procter and Gamble Company New use of sulfonated polymers
EP3050955B2 (en) 2015-02-02 2023-11-08 The Procter & Gamble Company Detergent pack
EP3050948B1 (en) 2015-02-02 2018-09-19 The Procter and Gamble Company New use of complexing agent
EP3050947A1 (en) 2015-02-02 2016-08-03 The Procter and Gamble Company Detergent pack
EP3050950B1 (en) 2015-02-02 2018-09-19 The Procter and Gamble Company New use of sulfonated polymers
PL3050953T3 (pl) 2015-02-02 2019-07-31 The Procter And Gamble Company Kompozycja detergentu
ES2661440T5 (es) 2015-02-05 2021-09-23 Dalli Werke Gmbh & Co Kg Composición de limpieza que comprende un catalizador de blanqueo y carboximetilcelulosa
EP3075832B1 (en) 2015-03-30 2021-04-14 Dalli-Werke GmbH & Co. KG Manganese-amino acid compounds in cleaning compositions
US10280386B2 (en) 2015-04-03 2019-05-07 Ecolab Usa Inc. Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid
US9783766B2 (en) 2015-04-03 2017-10-10 Ecolab Usa Inc. Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid
WO2016177439A1 (en) 2015-05-07 2016-11-10 Novozymes A/S Manganese bleach catalyst / enzyme granules for use in dishwash detergents
AR104939A1 (es) 2015-06-10 2017-08-23 Chemsenti Ltd Método oxidativo para generar dióxido de cloro
AR104940A1 (es) 2015-06-10 2017-08-23 Chemsenti Ltd Método para generar dióxido de cloro
US9777250B2 (en) 2015-10-13 2017-10-03 Milliken & Company Whitening agents for cellulosic substrates
US9745544B2 (en) 2015-10-13 2017-08-29 The Procter & Gamble Company Whitening agents for cellulosic substrates
US9976035B2 (en) 2015-10-13 2018-05-22 Milliken & Company Whitening agents for cellulosic substrates
US10155868B2 (en) 2015-10-13 2018-12-18 Milliken & Company Whitening agents for cellulosic substrates
US9902923B2 (en) 2015-10-13 2018-02-27 The Procter & Gamble Company Polyglycerol dye whitening agents for cellulosic substrates
US10597614B2 (en) 2015-10-13 2020-03-24 The Procter & Gamble Company Whitening agents for cellulosic substrates
DE102015016402A1 (de) 2015-12-18 2017-06-22 Weylchem Wiesbaden Gmbh Feinteilige Bleichkatalysatoren, Verfahren zu deren Herstellung und deren Verwendung
US10308900B2 (en) 2015-12-22 2019-06-04 Milliken & Company Occult particles for use in granular laundry care compositions
DK3190168T3 (da) 2016-01-06 2019-07-15 Dalli Werke Gmbh & Co Kg Belagt blegemiddelkatalysator
AR107753A1 (es) 2016-03-02 2018-05-30 Unilever Nv Suspensión de detergente que se puede verter que comprende una fase fluida coloreada y partículas suspendidas
EP3423558B1 (en) 2016-03-02 2019-06-26 Unilever N.V. Detergent composition in the form of a suspension
WO2017148985A1 (en) 2016-03-02 2017-09-08 Unilever N.V. Pourable detergent composition
PT3426756T (pt) 2016-03-11 2019-10-18 Unilever Nv Suspensão detergente derramável compreendendo grânulos catalisadores de branqueamento
WO2017160935A1 (en) * 2016-03-16 2017-09-21 Ecolab Usa Inc. Low capital bleaching of chemical pulp
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition
EP3312265A1 (en) 2016-10-18 2018-04-25 The Procter and Gamble Company Detergent composition
US20180119070A1 (en) 2016-11-01 2018-05-03 The Procter & Gamble Company Leuco colorants as bluing agents in laundry care compositions, packaging, kits and methods thereof
WO2018085300A1 (en) 2016-11-01 2018-05-11 The Procter & Gamble Company Methods of using leuco colorants as bluing agents in laundry care compositions
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
DE112018000558T5 (de) 2017-01-27 2019-10-10 The Procter & Gamble Company Wirkstoff enthaltende Gegenstände, die für den Verbraucher annehmbare gebräuchliche Gegenstandseigenschaften aufweisen
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
WO2018141237A1 (en) * 2017-02-03 2018-08-09 Rhodia Operations Bleach or detergent composition
CN110603312B (zh) 2017-05-04 2021-10-15 联合利华知识产权控股有限公司 洗涤剂组合物
EP3622049B1 (en) 2017-05-12 2023-08-16 Unilever Global IP Limited Phosphate-free automatic dishwashing detergent composition
WO2018206811A1 (en) 2017-05-12 2018-11-15 Unilever N.V. Automatic dishwashing detergent composition
DE102017004742A1 (de) 2017-05-17 2018-11-22 Weylchem Wiesbaden Gmbh Beschichtete Granulate, deren Verwendung und Wasch- und Reinigungsmittel enthaltend diese
WO2019113926A1 (en) 2017-12-15 2019-06-20 Rhodia Operations Composition containing lanthanide metal complex
WO2019162139A1 (en) 2018-02-23 2019-08-29 Unilever N.V. Unit dose detergent product with a glossy solid part
CA3094073A1 (en) 2018-03-19 2019-09-26 Ecolab Usa Inc. Liquid detergent compositions containing bleach catalyst
EP4349951A3 (en) 2018-06-15 2024-06-19 Ecolab USA Inc. Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid
US11732218B2 (en) 2018-10-18 2023-08-22 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11518963B2 (en) 2018-10-18 2022-12-06 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US20200123472A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
US11299591B2 (en) 2018-10-18 2022-04-12 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US20200123475A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
US11466122B2 (en) 2018-10-18 2022-10-11 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US20200123319A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
US20200190433A1 (en) 2018-12-14 2020-06-18 The Procter & Gamble Company Foaming Fibrous Structures Comprising Particles and Methods for Making Same
EP3754003A1 (en) 2019-06-21 2020-12-23 Dalli-Werke GmbH & Co. KG Detergent package unit with a handle
US11485934B2 (en) 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same
EP4017953B1 (en) 2019-08-21 2023-04-12 Unilever IP Holdings B.V. Detergent solid composition
ES2931031T3 (es) 2019-09-20 2022-12-23 Henkel Ag & Co Kgaa Eliminación no enzimática de suciedades proteicas
WO2021073901A1 (en) 2019-10-15 2021-04-22 Unilever Ip Holdings B.V. Detergent composition
US20210148044A1 (en) 2019-11-15 2021-05-20 The Procter & Gamble Company Graphic-Containing Soluble Articles and Methods for Making Same
CN115151629A (zh) 2020-02-28 2022-10-04 联合利华知识产权控股有限公司 餐具洗涤剂产品
US20230106979A1 (en) 2020-02-28 2023-04-06 Conopco Inc., D/B/A Unilever Dishwash detergent product
BR112022014223A2 (pt) 2020-03-02 2022-09-13 Milliken & Co Composição compreendendo agente de matização
US11718814B2 (en) 2020-03-02 2023-08-08 Milliken & Company Composition comprising hueing agent
US20210269747A1 (en) 2020-03-02 2021-09-02 Milliken & Company Composition Comprising Hueing Agent
US11351106B2 (en) 2020-09-14 2022-06-07 Milliken & Company Oxidative hair cream composition containing thiophene azo colorant
US11344492B2 (en) 2020-09-14 2022-05-31 Milliken & Company Oxidative hair cream composition containing polymeric colorant
US20220079862A1 (en) 2020-09-14 2022-03-17 Milliken & Company Hair care composition containing polymeric colorant
EP3967742A1 (en) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same
EP4008765A1 (en) 2020-12-07 2022-06-08 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same
CN116745398A (zh) 2021-01-29 2023-09-12 联合利华知识产权控股有限公司 专业机器餐具洗涤洗涤液
WO2022197295A1 (en) 2021-03-17 2022-09-22 Milliken & Company Polymeric colorants with reduced staining
WO2022200053A1 (en) 2021-03-26 2022-09-29 Unilever Ip Holdings B.V. Product for machine dishwashing in the form of a capsule with multiple compartments
WO2022219105A1 (en) 2021-04-15 2022-10-20 Unilever Ip Holdings B.V. Machine dishwash detergent
JP2024518106A (ja) 2021-05-28 2024-04-24 ザ プロクター アンド ギャンブル カンパニー 界面活性剤を含む天然ポリマー系繊維要素及びその作製方法
EP4347766A1 (en) 2021-06-03 2024-04-10 Unilever IP Holdings B.V. Machine dishwash detergent
CN117413042A (zh) 2021-06-03 2024-01-16 联合利华知识产权控股有限公司 机器餐具洗涤剂
WO2023031328A1 (en) 2021-09-01 2023-03-09 Unilever Ip Holdings B.V. Bleach catalysts, bleach systems and cleaning compositions
WO2023030882A1 (en) 2021-09-01 2023-03-09 Unilever Ip Holdings B.V. Machine dishwash detergent
WO2023030951A1 (en) 2021-09-01 2023-03-09 Unilever Ip Holdings B.V. Bleach catalysts, bleach systems and cleaning compositions
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
EP4296343A1 (en) 2022-06-24 2023-12-27 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and manganese(ii) acetate, manufacturing thereof, and bleaching and cleaning agent comprising same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1551775A (en) * 1975-05-05 1979-08-30 Gen Electric Process for producting diorganopolysioxane oils
US4728455A (en) * 1986-03-07 1988-03-01 Lever Brothers Company Detergent bleach compositions, bleaching agents and bleach activators
GB8720863D0 (en) * 1987-09-04 1987-10-14 Unilever Plc Metalloporphyrins
ES2008833A6 (es) * 1988-10-25 1989-08-01 Camp Jabones Composiciones blanqueantes para materias textiles yno celulosicas con alta efectividad a bajas temperaturas, y procedimiento de blanqueo con las mismas.
US5021187A (en) * 1989-04-04 1991-06-04 Lever Brothers Company, Division Of Conopco, Inc. Copper diamine complexes and their use as bleach activating catalysts
GB8908416D0 (en) * 1989-04-13 1989-06-01 Unilever Plc Bleach activation
GB9003741D0 (en) * 1990-02-19 1990-04-18 Unilever Plc Bleach activation

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DE69125310D1 (de) 1997-04-30
KR950001045B1 (ko) 1995-02-08
EP0458398A2 (en) 1991-11-27
ES2100925T3 (es) 1997-07-01
NO911942L (no) 1991-11-22
BR9102086A (pt) 1991-12-24
JPH06269676A (ja) 1994-09-27
MY106557A (en) 1995-06-30
IN173875B (ko) 1994-07-30
EP0458397A2 (en) 1991-11-27
EP0458398A3 (en) 1992-01-15

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