KR910019677A - 표백제 활성화 방법 - Google Patents

표백제 활성화 방법 Download PDF

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Publication number
KR910019677A
KR910019677A KR1019910008223A KR910008223A KR910019677A KR 910019677 A KR910019677 A KR 910019677A KR 1019910008223 A KR1019910008223 A KR 1019910008223A KR 910008223 A KR910008223 A KR 910008223A KR 910019677 A KR910019677 A KR 910019677A
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South Korea
Prior art keywords
catalyst
compound
bleach
alkyl
hydrogen peroxide
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KR1019910008223A
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English (en)
Other versions
KR950001045B1 (ko
Inventor
루이스 에프. 파브레 토마스
하게 로날드
반 데어 헬름-라데마커 카린
히포리테스 코에크 진
마르텐스 루돌프요한
스와토프 톤
로버트 피.반 블리트 마르텐
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에에치.드 로이
유니레버 엔 브이
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Priority claimed from GB909011338A external-priority patent/GB9011338D0/en
Priority claimed from GB909027415A external-priority patent/GB9027415D0/en
Application filed by 에에치.드 로이, 유니레버 엔 브이 filed Critical 에에치.드 로이
Publication of KR910019677A publication Critical patent/KR910019677A/ko
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Publication of KR950001045B1 publication Critical patent/KR950001045B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

표백제 활성화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 다음과 같은 일반식(A)을 가지는 금속 착화합물로 구성되는 표백 및 산화촉매
    〔LNMnMXP〕2Yq(A)
    〔아삭에서 Mn은 산화수가 Ⅱ,Ⅲ,Ⅳ 또는 Ⅴ인 망간, 철, 또는 이들의 혼합물이며 n및 m은 1-4사이의 독립된 정수이고, X는 배위성 또는 가교성 종을 나타내며, P는 -0-12사이의 정수이고 Y는 착화합물의 전하수Z에 종속되는 카운터이온 이며 Z는 양수, 영, 또는 음수이다.
    q=z/〔Y 전하수〕이며 l은 다음과 같은 일반식을 가지는 매크로시클릭 유기분자인 리간드이다.
    (여기서 R1및 R2는 각각 영,H,알킬 또는 아릴(치환 또는 비치환)이고 t및 t´는 각각 2-3 사이의 정수이며, D는 각각 N.NR,PR,O 또는 S(R은 H, 알킬, 아릴(치환 또는 지치혼)임)이 S는 2-5사이의 정수이다.)〕.
  2. 제1항에 있어서, 다음과 같은 일반식 (A)의 망간 화합물를 구성되는 촉매.
    〔LnMnmXP〕2Yq
    〔위 식에서, Mn은 산화수가 Ⅱ,Ⅲ,Ⅳ 또는 V인 망긴이고 X는 크기가 작은 배위성 이온 및/또는 가교성 분자 또는 그 배합물을 나타내며 L은 다음과 같은 일반식을 가지는 매크로시클릭 유기분자이다.
    (여기서 R1및 R2는 각각 영, H, 알킬 또는 아릴 (치환 또는 비치환)이고 D및 D′는 각각 N, NR, PR, O 또는 S(R은 H, 알킬, 또는 아릴(치환 또는 비치환)임)이며, t및 t′는 각각 2-3 사이으이 정수이고 S는 2-4 사이의 정수이다.)〕.
  3. 제2항에 있어서, P가 3-6인 촉매.
  4. 제3항에 있어서, n=m=2인 촉매.
  5. 제4항에 있어서, D및 D′는 각각 NH 또는 NR이고 S는 2이며 R1및 R2는 각각 H또는 알킬인 촉매.
  6. 제5항에 있어서, D및 D′는 NCH3이고 t,t′=2인 촉매.
  7. 제4항에 있어서, D및 D′는 각각 NH 또는 NR이고 S는 2이며 R1및 R2는 각각 H또는 알킬인 촉매.
  8. 제7항에 있어서, D및 D′는 NCH3이고 t.t′=2인 촉매.
  9. 제6항에 있어서, 리간드 L이 1,4,7-트리메틸-1,4,7-트리아자시클로노난인 촉매.
  10. 제8항에 있어서, 리간드 L이 2-메틸-1.4,7-트릭메틸-1,4,7-트리아자시클로노난인 촉매.
  11. 제9항에 있어서,코어 착화합물이 다음으로 부터 선택되는 촉매.
  12. 폐록시화합물을 포함한 표백제를 사용하는 표백 또는 세정 방법으로서,상기 표백제는 제1항 기재의 촉매적인 양의 촉매에의해 활성화되는 것을 특징으로하는 촉매.
  13. 제12항에 있어서,촉매는 망간착화합물로서 수성 표백용액중 0.001ppm-100ppm의 Mn의 수준으로 사용되는 표백 또는 세정방법.
  14. 제13항에 있어서, 망간의 양이 0.01-20ppm인 표백 또는 세정방법.
  15. 제12항에 있어서, 표백제가 과산화수소, 과산화수소-방출화합물, 과산화수소-,발생계, 페록시산 및 그염 페록시산 표백제 전구체, 및 이들의 혼합물중에서 선택되는 표백 또는 세정방법.
  16. 제15항에 있어서,제11항 기재의 촉가 사용되는 표백 또는 세정방법.
  17. 페록시화합물과 제1항 기재의 촉매를 함유하는 표백조성물.
  18. 제17항에 있어서, 2-30중량%의 상기 페록시화합물과 0.0005-0.5중량%의 Mn함량에 해당하는 수준의 상기 촉매를 함유하는 표백조성물.
  19. 제18항에 있어서, Mn함량이 0.001-0.25중량%인 표백조성물.
  20. 제17항에 있어서, 페록시화합물이 과산화수소, 과산화수소-방출화합물, 과산화수소-발생계, 페록시산 및 그 염, 페로깃산 표백제전구체, 및 이들의 혼합물중에서 선택되는 표백조성물.
  21. 제20항에 있어서, 50중량%이하의 계면활성화합물을 또한 함유하는 표백조성물.
  22. 제21항에 있어서, 5-80중량%의 세척빌더를 또한 함유하는 표백조성물.
  23. 제20항에 있어서, 프로테아제, 셀룰라제, 피아제, 아밀라제, 옥시다제 및 이들의 혼합물중에서 선택되는 효소를 또한 함유하는 표백조성물.
  24. 제17항에 있어서, 촉매가 제11항의 촉매인 표백조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910008223A 1990-05-21 1991-05-22 표백제 활성화 방법 KR950001045B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB909011338A GB9011338D0 (en) 1990-05-21 1990-05-21 Bleach activation
GB9011338.2 1990-05-21
GB90274150 1990-12-18
GB909027415A GB9027415D0 (en) 1990-12-18 1990-12-18 Bleach activation
GB9027415.0 1990-12-18

Publications (2)

Publication Number Publication Date
KR910019677A true KR910019677A (ko) 1991-12-19
KR950001045B1 KR950001045B1 (ko) 1995-02-08

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KR1019910008224A KR950001046B1 (ko) 1990-05-21 1991-05-22 표백제 활성화 방법
KR1019910008223A KR950001045B1 (ko) 1990-05-21 1991-05-22 표백제 활성화 방법

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US (2) US5246621A (ko)
EP (2) EP0458397B1 (ko)
JP (2) JP2613707B2 (ko)
KR (2) KR950001046B1 (ko)
AU (2) AU622363B2 (ko)
BR (2) BR9102086A (ko)
CA (2) CA2042738C (ko)
DE (2) DE69125309T2 (ko)
ES (2) ES2100925T3 (ko)
IN (2) IN173875B (ko)
MY (2) MY106557A (ko)
NO (2) NO911943L (ko)

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KR100979849B1 (ko) * 2002-11-19 2010-09-02 애경산업(주) 거대고리 망간 착화합물을 함유한 표백제 및 표백세제조성물

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