EP4045621B1 - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- EP4045621B1 EP4045621B1 EP20785504.0A EP20785504A EP4045621B1 EP 4045621 B1 EP4045621 B1 EP 4045621B1 EP 20785504 A EP20785504 A EP 20785504A EP 4045621 B1 EP4045621 B1 EP 4045621B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fatty acid
- composition
- oxidase
- enzyme
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 93
- 239000003599 detergent Substances 0.000 title description 11
- 102000004190 Enzymes Human genes 0.000 claims description 65
- 108090000790 Enzymes Proteins 0.000 claims description 65
- 229940088598 enzyme Drugs 0.000 claims description 65
- 239000007844 bleaching agent Substances 0.000 claims description 39
- 101710128063 Carbohydrate oxidase Proteins 0.000 claims description 37
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 24
- 239000000194 fatty acid Substances 0.000 claims description 24
- 229930195729 fatty acid Natural products 0.000 claims description 24
- 239000003054 catalyst Substances 0.000 claims description 20
- -1 fatty acid esters Chemical class 0.000 claims description 20
- 239000002736 nonionic surfactant Substances 0.000 claims description 19
- 239000000758 substrate Substances 0.000 claims description 19
- 235000019420 glucose oxidase Nutrition 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 108010015776 Glucose oxidase Proteins 0.000 claims description 14
- 239000004366 Glucose oxidase Substances 0.000 claims description 14
- 229940116332 glucose oxidase Drugs 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 13
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 108090000854 Oxidoreductases Proteins 0.000 claims description 11
- 102000004316 Oxidoreductases Human genes 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 244000269722 Thea sinensis Species 0.000 claims description 10
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 235000013616 tea Nutrition 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 150000001720 carbohydrates Chemical class 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 108010025188 Alcohol oxidase Proteins 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- 108010015133 Galactose oxidase Proteins 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 108010018734 hexose oxidase Proteins 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000000499 gel Substances 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 101000904208 Aspergillus niger Glucose oxidase Proteins 0.000 claims 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims 1
- 235000009569 green tea Nutrition 0.000 claims 1
- 238000004851 dishwashing Methods 0.000 description 14
- 239000012190 activator Substances 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 7
- 229910016884 MnIII Inorganic materials 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 6
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 6
- 229910016887 MnIV Inorganic materials 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 229960001031 glucose Drugs 0.000 description 6
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 150000005323 carbonate salts Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- MMIPFLVOWGHZQD-UHFFFAOYSA-N manganese(3+) Chemical compound [Mn+3] MMIPFLVOWGHZQD-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 150000004965 peroxy acids Chemical class 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
- WQZGKKKJIJFFOK-SVZMEOIVSA-N (+)-Galactose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-SVZMEOIVSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 241000894007 species Species 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- GQYKSISLCPUNJT-BDVNFPICSA-N (2r,3r,4r,5r)-2,3,5,6-tetrahydroxy-4-methoxyhexanal Chemical compound OC[C@@H](O)[C@@H](OC)[C@H](O)[C@@H](O)C=O GQYKSISLCPUNJT-BDVNFPICSA-N 0.000 description 1
- VCAHKPHDYWWNNK-IPNSULNXSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3r,4s,5r)-3,4,5,6-tetrahydroxyhexanal Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)CC=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O VCAHKPHDYWWNNK-IPNSULNXSA-N 0.000 description 1
- FRJOXJBNQDZEBI-ZLUOBGJFSA-N (2r,3s,5s)-2,3,5,6-tetrahydroxyhexanal Chemical compound OC[C@@H](O)C[C@H](O)[C@@H](O)C=O FRJOXJBNQDZEBI-ZLUOBGJFSA-N 0.000 description 1
- KDSPLKNONIUZSZ-NGJCXOISSA-N (2r,4s,5r)-2,4,5,6-tetrahydroxyhexanal Chemical compound OC[C@@H](O)[C@@H](O)C[C@@H](O)C=O KDSPLKNONIUZSZ-NGJCXOISSA-N 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- UYXFOIMFLBVYDL-UHFFFAOYSA-N 1,2,4,7-tetramethyl-1,4,7-triazonane Chemical compound CC1CN(C)CCN(C)CCN1C UYXFOIMFLBVYDL-UHFFFAOYSA-N 0.000 description 1
- LRPVVAOGGZFVFO-UHFFFAOYSA-N 1,5,9-trimethyl-1,5,9-triazacyclododecane Chemical compound CN1CCCN(C)CCCN(C)CCC1 LRPVVAOGGZFVFO-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical class OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
- NZCIWANIJJJEML-UHFFFAOYSA-N 2-methyl-1,4,7-triazonane Chemical compound CC1CNCCNCCN1 NZCIWANIJJJEML-UHFFFAOYSA-N 0.000 description 1
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 description 1
- WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 description 1
- WQZGKKKJIJFFOK-IVMDWMLBSA-N D-allopyranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-IVMDWMLBSA-N 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- PNNNRSAQSRJVSB-JGWLITMVSA-N D-quinovose Chemical compound C[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-JGWLITMVSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical class OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- GZCGUPFRVQAUEE-FSIIMWSLSA-N aldehydo-D-gulose Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-FSIIMWSLSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PQMKYFCFSA-N alpha-D-mannose Chemical compound OC[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-PQMKYFCFSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-QZABAPFNSA-N beta-D-allose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-QZABAPFNSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 235000013949 black currant juice Nutrition 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- GZCGUPFRVQAUEE-ARQDHWQXSA-N d-altrose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-ARQDHWQXSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 150000003278 haem Chemical class 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 125000003703 phosphorus containing inorganic group Chemical group 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the present invention is in the field of machine dishwashing compositions. More particularly, it relates to machine dishwashing compositions comprising carbohydrate oxidase enzymes and a surfactant system. The invention also relates to a method of washing kitchenware in a machine dishwasher with a machine dishwashing composition comprising carbohydrate oxidase enzymes and a process for making said composition.
- Machine dishwashing compositions comprising bleaching enzymes have been described in the prior art.
- WO1999/002640 discloses cleaning compositions comprising oxidoreductase (non-haem haloperoxidase) with an ⁇ / ⁇ -hydrolase fold and a catalytic triad consisting of the amino acid residues serine, histidine and aspartic acid.
- Example 19 discloses a dishwasher composition comprising 0.002 wt.% haloperoxidase, 1.2 wt.% non-ionic surfactant, pH 8.
- Known enzyme dishwasher compositions suffer from poor stain removing power, particularly in the absence of percarbonate and/or perborate.
- WO94/23637 A1 discloses granular machine dishwashing compositions that comprise 1.5 wt.% non-ionic surfactant, 10 wt.% glucose and 250 units/gram glucose oxidase enzyme, which form an enzymatic source of hydrogen peroxide, having a pH of 10.7.
- the compositions decolorise blackcurrant juice stains and require bleach catalyst. Notorious hard to remove stains include tea stains, which require substantial bleaching power to remove.
- dishwasher compositions that are free of metal bleach catalysts and are capable of being free of bleach precursors (e.g. percarbonate and/or perborate) and more preferably have reduced amounts of, preferably being free of, bleach activators yet provide (tea)-stain removing power.
- the inventors have developed a machine dishwasher composition that has excellent (tea)stain removing powder, in particular in the absence of percarbonate and/or perborate, and in some conditions even show very good tea stain bleaching when free from bleach activator and bleach catalyst.
- the present invention relates to a machine dishwasher composition according to claim 1.
- the carbohydrate oxidase enzyme substrate b) is suitable to be acted upon by the carbohydrate oxidase enzyme a) being used in the composition according to the invention. This for the system to generate adequate amounts of H 2 O 2 . It was surprisingly found that a machine dish wash composition according to the invention is capable of effectively removing tea stains without the presence of bleach precursor, bleach activator and bleach catalyst at high temperatures. This is the more surprising since at such high temperature (and alkaline) conditions one may not expect the enzyme system to be able to effectively generate sufficient H 2 O 2 . Typical optimal enzyme conditions are at low temperatures and or neutral to slightly acidic pH levels.
- the optimal conditions for the used enzyme in the examples were a temperature of 35-40 degrees Celsius and a pH of 5.2. Yet in conditions of a pH of 10.5 with a temperature of 80 degrees Celsius it effectively generated H 2 O 2 from the available glucose and provide excellent tea-stain removal.
- a machine dish wash composition according to the invention is capable of effectively removing tea stain without the presence of bleach precursor and/or bleach activator at low-medium temperatures while using relatively small amounts of active enzyme and bleach catalyst.
- the ability to employ relatively small amounts of active enzyme to provide good tea-stain removal is highly beneficial from a stability point of view, costs point of view as well as from a product stability point.
- the invention also relates to a unit dose comprising a composition defined herein, wherein the unit dose is a gel, powder, liquid or combination thereof.
- the invention in a third aspect, relates to a method of cleaning kitchenware comprising the steps of contacting the composition a defined herein with kitchenware in the presence of water, preferably at a temperature in the range of 30 to 90 °C.
- the invention relates to a use of a composition according to claim 13.
- the invention relates to a process of preparing compositions according to any of the preceding claims comprising the step of combining a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system.
- carbohydrate oxidase enzyme as used herein preferably refers to an enzyme of class E.C.1.1.3 and E.C.1.1.3.4, but is otherwise use in a general sense of an enzymes capable of generating peroxide using a carbohydrate substrate.
- the enzyme selected from the group of carbohydrate oxidases is capable of generating a hydrogen peroxide.
- the carbohydrate oxidase enzyme is selected from the group consisting of alcohol oxidase, glucose oxidase, galactose oxidase, sorbose oxidase, hexose oxidase, aldose oxidase and mixtures thereof, more preferably glucose oxidase.
- Suitable oxidase enzymes are those classified under enzyme classification E.C.1.1.3., namely those acting on the CH-OH group of donors with oxygen as acceptor.
- the oxidase enzyme oxidases are selected from those under enzyme commission number E.C.1.1.3.4.
- the carbohydrate oxidase enzyme is glucose oxidase, for example a glucose oxidase as available from Sigma Aldrich (UK) Catalog Number G7141 ( CAS RN 9001-37-0 ), Roche (GOD), Sorachim (GLO-202A), Sekisui (HPS300 or Maxapal ® GO4 (DSM The Netherlands).
- the glucose oxidase has at least 70%, preferably at least 80%, more preferably at least 90% amino acid sequence homology to the glucose oxidase with accession number P13006 (Uniprot).
- the enzyme of the invention has its optimum temperature condition in a temperature range of from 25 to 55, more preferably from 30 to 45 and even more preferably of from 35 to 40 degrees Celsius.
- the enzyme of the invention has its optimal pH condition in the range of from 4.5 to 8.0, more preferably of from 4.6 to 7.0 even more preferably of from 4.8 to 6.0 and still even more preferably of from 5.0 to 5.5.
- the amount of carbohydrate oxidase enzyme will depend on its specific activity, but preferably the machine dishwash composition of the invention comprises from 10 to 5000, preferably from 60 to 2000, more preferably from 100 to 1500 and even more preferably from 200 to 1000 units of carbohydrate oxidase enzyme per 18g of the composition.
- a unit of enzyme activity is defined as the quantity required to convert 1 ⁇ mol of its substrate per minute under standard conditions.
- the range of 200 to 1000 units of carbohydrate oxidase enzyme was found to be optimal in view of providing good tea-stain cleaning and minimizing the amounts of ingredients actives used. In fact, it was interestingly observed that very high levels of carbohydrate oxidase enzyme did not per se lead to better tea stain removal.
- the machine dishwashing composition preferably comprises 0.01 to 0.4 wt.% active carbohydrate oxidase enzyme. More preferably the machine dishwashing composition comprises 0.02 to 0.3 wt.% of active carbohydrate oxidase enzyme, even more preferably 0.04 to 0.2 wt.%, and still even more preferably of from 0.045 to 0.08 wt. % of active carbohydrate oxidase enzyme.
- the later range was likewise found to provide an optimal balance between good tea stain cleaning and minimizing the amounts of detergent actives required.
- the amount of active enzyme can generally be equated to the amount of pure enzyme.
- the carbohydrate oxidase enzyme substrate is selected from the group consisting of allose, altrose, glucose, mannose, gulose, idose, galactose, talos, sorbose and mixtures thereof, preferably the carbohydrate oxidase enzyme substrate is selected from the group consisting of D-(+)-Allose, D-(+)-Altrose, D-(+)-Glucose, D-(+)-Mannose, D-(-)-Gulose, D-(+)-ldose, D-(+)-Galactose, D-(+)-Talose and mixtures thereof.
- the carbohydrate oxidase enzyme substrate is selected from the group consisting of glucose, galactose, sorbose and mixtures thereof.
- the carbohydrate oxidase enzyme substrate is selected from the group consisting of The D-glucose 2-deoxy-D-glucose, 4-O-methyl-D-glucose, 6-deoxy-D-glucose, 4-deoxy-D-glucose, 3-deoxy-D-glucose, 3-O-methyl-D-glucose and mixtures thereof.
- composition of the invention preferably comprises from 2 to 35 wt. %, more preferably from 5 to 33 wt. %, even more preferably from 10 to 30 wt.% and still more preferably from 11 to 25 wt.% of the carbohydrate substrate.
- Such levels of carbohydrate substrate were found to be more optimal for the removal of tea-stains especially at low-medium temperatures.
- the surfactant system comprises non-ionic surfactant.
- the composition comprises anionic surfactants, cationic surfactants and amphoteric/zwitterionic surfactants and mixtures thereof.
- non-ionic and or anioninc surfactants of the Surfactant System may be chosen from the surfactants described in " Surface Active Agents' Vol. 1, by Schwartz & Perry, Interscience 1949 , Vol. 2 by Schwartz, Perry & Berch, InterScience 1958 , in the current edition of " McCutcheon's Emulsifiers and Detergents' published by Manufacturing Confectioners Company or in " Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Veriag, 1981 .
- Suitable non-ionic detergent compounds which may be used include, in particular, the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
- Specific non-ionic detergent compounds are C-C alkyl phenol ethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic Cs-Cs primary or Secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
- the machine dishwashing composition comprises a non-ionic surfactant system selected from a C10-20 fatty acid, an alkoxylated fatty alcohol, an alkoxylated fatty acid, alkylphenol alkoxylates, alkoxylated amines, alkoxylated fatty acid amides, terminally blocked alkoxylates, fatty acid esters of glycerol, fatty acid esters of sorbitol, fatty acid esters of sucrose, alkyl polyglucosides, amine-oxides, sulphoxides, phosphine oxides, more preferably selected from a C10-20 fatty acid, an ethoxylated fatty alcohol, an ethoxylated fatty acid, alkylphenol ethoxylates, ethoxylated amines, ethoxylated fatty acid amides, terminally blocked ethoxylates, fatty acid esters of glycerol, fatty acid esters
- the machine dishwashing composition comprises from 0.1 to 15 wt.% non-ionic surfactant, preferably 1.0 to 12.0 wt.% non-ionic surfactant, more preferably 2.0 to 8 wt.% non-ionic surfactant, most preferably 2.5 to 5 wt.% non-ionic surfactant.
- the machine dishwashing composition comprises at most 5.0 wt. %, more preferably at most 4.0 wt. %, even more preferably at most 3.0 wt. %, still even more preferably at most 2.0 wt. % and still even more preferably at most 1.0 wt. % of anionic surfactant.
- the machine dishwashing composition preferably comprises 10 to 50 wt.% carbonate salts, preferably selected from Na 2 CO 3 , K 2 CO 3 , CaCO 3 or a combination of both, preferably 15 to 40 wt.% carbonate salts selected from Na 2 CO 3 and CaCO 3 or a combination of both, most preferably 20 to 30 wt. % carbonate, selected from Na 2 CO 3 , CaCO 3 or a combination of both.
- the carbonate salt is Na 2 CO 3 .
- builder refers to a material that is capable of removing calcium and/or magnesium ion from aqueous solution by ion exchange, complexation, sequestration and/or precipitation.
- the builder or sequestrant material is preferably fully soluble in water so as to eliminate the possibility of unwanted and unsightly residues on substrates. For that reason alkali metal aluminosilicates are not favoured.
- Typical examples of phosphorus containing inorganic builders, when present, include the water-soluble salts, especially alkali metal pyrophosphates, orthophosphates and polyphosphates.
- inorganic phosphate builders include sodium and potassium tripolyphosphates, pyrophosphates and hexametaphosphates.
- suitable non-phosphorus water-soluble detergency builders when present, include carbonate, citrate, zeolite, silicate and aminopolycarboxylic compounds, such as glutamate diacetic acid (GLDA), methylglycine diacetic acid (MGDA), and Trisodium Citrate.
- non-phosphorus water-soluble detergency builders may include inorganic builders as alkali metal carbonate, bicarbonates, sesquicarbonates, borates, silicates, metasilicates, and crystalline and amorphous aluminosilicates, and organic builders as polycarboxylate polymers, such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates, monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono- di and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates and hydroxyethyliminodiacetates.
- inorganic builders as alkali metal carbonate, bicarbonates, sesquicarbonates, borates, silicates, metasilicates, and crystalline and amorphous aluminosilicates
- organic builders as polycarboxylate polymers, such as polyacrylates, acrylic/maleic copo
- bleach activator refers to compounds employed in cleaning compositions to activate the bleaching agent, or bleach component, especially at lower temperatures.
- bleach activators suitable for use in the cleaning compositions of this invention include one or more activators such as peroxyacid bleach precursors.
- Peroxyacid bleach precursors are well known in the art. As non-limiting examples can be named tetraacetyl ethylene diamine (TAED), sodium nonanoyloxybenzene sulphonate (SNOBS), sodium benzoyloxybenzene sulphonate (SBOBS) and the cationic peroxyacid precursor (SPCC).
- the detergent composition of the invention may comprise from 0.01 to 15 wt. % of bleach activator, more preferably from 0.2 to 10 wt. % and even more preferably from 1.0 to 6 wt. %, but more preferably comprises no bleach activator.
- Bleach catalysts function by oxidizing typically via peroxide or a peracid to form a bleaching species. They require the presence of an oxidizable soil so that they can be reduced back to the starting bleach activator state.
- Bleach catalysts can be one or more of:
- Bleach catalyst can be part of a bleach catalyst granule comprising less than 5 wt. % of active bleach catalyst. The use of such granules improves the accurate dosing of the bleach catalyst.
- the detergent composition is preferably a powder, a tablet, an aqueous or non-aqueous liquid, a loose flowing powder, a paste, a capsule or a gel.
- the composition is in the form a gel, a capsule or a tablet, more preferably a capsule.
- the carbohydrate oxidase enzyme used in the present invention can usefully be added to the detergent composition in any suitable form, i.e. the form of a granular composition, a liquid or a slurry of the enzyme, or with carrier material.
- adding the enzyme to a liquid detergent product is in the form of a slurry containing 0.5 to 50% by weight of the enzyme in an ethoxylated alcohol nonionic surfactant, such as described in EP-A-450702 (Unilever ).
- the machine dishwashing composition in a preferred embodiment in which the machine dishwashing composition is a solid or flowing powder, the machine dishwashing composition preferably has a water content of less than 5 wt.%.
- the machine dishwashing composition is tablet with a water content of less than 5 wt.%.
- a 1 wt. % solution of the detergent composition in deionised water has a pH in the range of 8.5 - 11.0, more preferably 9.0 - 10.75 and most preferably 9.5 - 10.5.
- the pH being measured at 25 °C, in otherwise standard conditions.
- the composition may be in the form of a unit dose, wherein the unit dose is a gel, powder, liquid or combination thereof.
- a preferred machine dishwash composition comprises:
- the machine dish wash compositions of the invention preferably comprise no bleach precursor, although the presence of such does not negatively affect the tea-stain cleaning.
- a method of cleaning kitchenware comprising the steps of contacting a detergent composition as defined herein with kitchenware in the presence of water.
- the method is carried out at a temperature in the range of 30 to 90 °C, more preferably 40 to 85 °C, even more preferably 50 to 80 °C.
- a high temperature wash conditions is defined as using a temperature of above 65 degrees Celsius; low-medium temperature wash conditions as a temperature of at most 65 degrees Celsius.
- the stain remover is active at a temperature in the range of 40 to 90 °C, more preferably 40 to 85 °C, even more preferably 50 to 80 °C.
- compositions as described herein comprising the step of combining a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system.
- compositions 1-3, 6, 7 and A are not according to the claims and are for illustrative purposes.
- compositions (1-5 and comparative A) were prepared, as shown in Table 1: Table 1 1 2 3 4 5 A Sodium percarbonate (wt.%) - - - - - - - Glucose Oxidase (wt.% active enzyme) 1 2 0.005 0.005 0.05 0.1 0.05 - Glucose (wt.%) 18.9 18.9 18.9 18.9 18.9 - Macrocyclic manganese bleach catalyst (MnCat) (wt.%) 0.02 0.02 0.02 - - 0.02 Tetraacetyl ethylene diamine (TAED) (wt.%) - - - 10.7 10.7 Sodium Carbonate (wt.%) - 24.99 24.99 24.99 24.99 24.99 24.99 24.99 24.99 Methylglycine diacetic acid (MGDA) (wt.%) 26.41 26.41 26.41 26.41 26.41 26.41 Non-lonic surfactant (wt.%) 3.00 3.00 3.00 3.00 3.00 3.00
- compositions 6 to 8 were prepared, as shown in Table 2: 6 7 8 Sodium percarbonate (wt.%) - - - Glucose Oxidase (wt.% active enzyme) 1 0.05 0.05 0.05 Glucose (wt.%) 12.8 6.4 12.8 Macrocyclic manganese bleach catalyst (MnCat) (wt.%) 0.02 0.02 - Tetraacetyl ethylene diamine (TAED) (wt.%) - - - Sodium Carbonate (wt.%) - 24.99 24.99 Methylglycine diacetic acid (MGDA) (wt.%) 26.41 26.41 26.41 Non-lonic surfactant (wt.%) 3.00 3.00 3.00 3.00 3.00 3.00
- Stained tiles (DM-14 Dark Tea on Melamine; Supplier: Center For Test materials B.V.) were placed in a 5L solution made from dosing 18g according to formulations listed in Table 1 in water. Each solution was placed in a beaker under agitation and temperature controlled for 20min. The temperate was as indicated in Table 3.
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Description
- The present invention is in the field of machine dishwashing compositions. More particularly, it relates to machine dishwashing compositions comprising carbohydrate oxidase enzymes and a surfactant system. The invention also relates to a method of washing kitchenware in a machine dishwasher with a machine dishwashing composition comprising carbohydrate oxidase enzymes and a process for making said composition.
- Machine dishwashing compositions comprising bleaching enzymes have been described in the prior art.
-
WO1999/002640 discloses cleaning compositions comprising oxidoreductase (non-haem haloperoxidase) with an α/β-hydrolase fold and a catalytic triad consisting of the amino acid residues serine, histidine and aspartic acid. Example 19 discloses a dishwasher composition comprising 0.002 wt.% haloperoxidase, 1.2 wt.% non-ionic surfactant, pH 8. Known enzyme dishwasher compositions suffer from poor stain removing power, particularly in the absence of percarbonate and/or perborate.WO94/23637 A1 - The inventors have developed a machine dishwasher composition that has excellent (tea)stain removing powder, in particular in the absence of percarbonate and/or perborate, and in some conditions even show very good tea stain bleaching when free from bleach activator and bleach catalyst.
- Accordingly, the present invention relates to a machine dishwasher composition according to claim 1.
- It will be appreciated that the carbohydrate oxidase enzyme substrate b) is suitable to be acted upon by the carbohydrate oxidase enzyme a) being used in the composition according to the invention. This for the system to generate adequate amounts of H2O2. It was surprisingly found that a machine dish wash composition according to the invention is capable of effectively removing tea stains without the presence of bleach precursor, bleach activator and bleach catalyst at high temperatures. This is the more surprising since at such high temperature (and alkaline) conditions one may not expect the enzyme system to be able to effectively generate sufficient H2O2. Typical optimal enzyme conditions are at low temperatures and or neutral to slightly acidic pH levels. In fact, the optimal conditions for the used enzyme in the examples were a temperature of 35-40 degrees Celsius and a pH of 5.2. Yet in conditions of a pH of 10.5 with a temperature of 80 degrees Celsius it effectively generated H2O2 from the available glucose and provide excellent tea-stain removal.
- It was further surprisingly found that a machine dish wash composition according to the invention is capable of effectively removing tea stain without the presence of bleach precursor and/or bleach activator at low-medium temperatures while using relatively small amounts of active enzyme and bleach catalyst. The ability to employ relatively small amounts of active enzyme to provide good tea-stain removal is highly beneficial from a stability point of view, costs point of view as well as from a product stability point.
- In a second aspect, the invention also relates to a unit dose comprising a composition defined herein, wherein the unit dose is a gel, powder, liquid or combination thereof.
- In a third aspect, the invention relates to a method of cleaning kitchenware comprising the steps of contacting the composition a defined herein with kitchenware in the presence of water, preferably at a temperature in the range of 30 to 90 °C.
- In a fourth aspect, the invention relates to a use of a composition according to claim 13.
- In a fifth aspect, the invention relates to a process of preparing compositions according to any of the preceding claims comprising the step of combining a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system.
- The term "carbohydrate oxidase enzyme" as used herein preferably refers to an enzyme of class E.C.1.1.3 and E.C.1.1.3.4, but is otherwise use in a general sense of an enzymes capable of generating peroxide using a carbohydrate substrate.
- The word 'comprising' as used herein is intended to mean 'including' but not necessarily 'consisting of' or 'composed of'. In other words, the listed steps or options need not be exhaustive.
- Unless specified otherwise, numerical ranges expressed in the format 'from x to y' or `x-y' are understood to include x and y. When for a specific feature multiple preferred ranges are described in the format 'from x to y' or 'x-y', it is understood that all ranges combining the different endpoints are also contemplated. For the purpose of the invention ambient temperature is defined as a temperature of about 20°C. Unless indicated otherwise, weight percentages (wt.%) are based on the total weight of the composition.
- The enzyme, selected from the group of carbohydrate oxidases is capable of generating a hydrogen peroxide. Preferably, the carbohydrate oxidase enzyme is selected from the group consisting of alcohol oxidase, glucose oxidase, galactose oxidase, sorbose oxidase, hexose oxidase, aldose oxidase and mixtures thereof, more preferably glucose oxidase. Suitable oxidase enzymes are those classified under enzyme classification E.C.1.1.3., namely those acting on the CH-OH group of donors with oxygen as acceptor. Preferably, the oxidase enzyme oxidases are selected from those under enzyme commission number E.C.1.1.3.4.
- In a preferable embodiment the carbohydrate oxidase enzyme is glucose oxidase, for example a glucose oxidase as available from Sigma Aldrich (UK) Catalog Number G7141 (CAS RN 9001-37-0), Roche (GOD), Sorachim (GLO-202A), Sekisui (HPS300 or Maxapal®GO4 (DSM The Netherlands). Preferably, the glucose oxidase has at least 70%, preferably at least 80%, more preferably at least 90% amino acid sequence homology to the glucose oxidase with accession number P13006 (Uniprot).
- Preferably the enzyme of the invention has its optimum temperature condition in a temperature range of from 25 to 55, more preferably from 30 to 45 and even more preferably of from 35 to 40 degrees Celsius. Advantageously the enzyme of the invention has its optimal pH condition in the range of from 4.5 to 8.0, more preferably of from 4.6 to 7.0 even more preferably of from 4.8 to 6.0 and still even more preferably of from 5.0 to 5.5. Surprisingly, it was found that an enzyme capable of generating peroxide and having temperature and pH optimums in these ranges was able to provide good tea-stain bleaching in MDW wash conditions, even in very alkaline conditions at high temperatures. Such conditions are quite far removed from the general enzyme optimal conditions, yet good carbohydrate oxidase-based tea-stain bleaching was observed.
- The amount of carbohydrate oxidase enzyme will depend on its specific activity, but preferably the machine dishwash composition of the invention comprises from 10 to 5000, preferably from 60 to 2000, more preferably from 100 to 1500 and even more preferably from 200 to 1000 units of carbohydrate oxidase enzyme per 18g of the composition. A unit of enzyme activity is defined as the quantity required to convert 1 µmol of its substrate per minute under standard conditions. The range of 200 to 1000 units of carbohydrate oxidase enzyme was found to be optimal in view of providing good tea-stain cleaning and minimizing the amounts of ingredients actives used. In fact, it was interestingly observed that very high levels of carbohydrate oxidase enzyme did not per se lead to better tea stain removal.
- The machine dishwashing composition preferably comprises 0.01 to 0.4 wt.% active carbohydrate oxidase enzyme. More preferably the machine dishwashing composition comprises 0.02 to 0.3 wt.% of active carbohydrate oxidase enzyme, even more preferably 0.04 to 0.2 wt.%, and still even more preferably of from 0.045 to 0.08 wt. % of active carbohydrate oxidase enzyme. The later range was likewise found to provide an optimal balance between good tea stain cleaning and minimizing the amounts of detergent actives required. The amount of active enzyme can generally be equated to the amount of pure enzyme.
- Preferably, the carbohydrate oxidase enzyme substrate is selected from the group consisting of allose, altrose, glucose, mannose, gulose, idose, galactose, talos, sorbose and mixtures thereof, preferably the carbohydrate oxidase enzyme substrate is selected from the group consisting of D-(+)-Allose, D-(+)-Altrose, D-(+)-Glucose, D-(+)-Mannose, D-(-)-Gulose, D-(+)-ldose, D-(+)-Galactose, D-(+)-Talose and mixtures thereof. More preferably the carbohydrate oxidase enzyme substrate is selected from the group consisting of glucose, galactose, sorbose and mixtures thereof. In certain preferred embodiments, the carbohydrate oxidase enzyme substrate is selected from the group consisting of The D-glucose 2-deoxy-D-glucose, 4-O-methyl-D-glucose, 6-deoxy-D-glucose, 4-deoxy-D-glucose, 3-deoxy-D-glucose, 3-O-methyl-D-glucose and mixtures thereof.
- The composition of the invention preferably comprises from 2 to 35 wt. %, more preferably from 5 to 33 wt. %, even more preferably from 10 to 30 wt.% and still more preferably from 11 to 25 wt.% of the carbohydrate substrate. Such levels of carbohydrate substrate were found to be more optimal for the removal of tea-stains especially at low-medium temperatures.
- The surfactant system comprises non-ionic surfactant. Preferably the composition comprises anionic surfactants, cationic surfactants and amphoteric/zwitterionic surfactants and mixtures thereof.
- In general, the non-ionic and or anioninc surfactants of the Surfactant System may be chosen from the surfactants described in "Surface Active Agents' Vol. 1, by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, InterScience 1958, in the current edition of "McCutcheon's Emulsifiers and Detergents' published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Veriag, 1981. Suitable non-ionic detergent compounds which may be used include, in particular, the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide. Specific non-ionic detergent compounds are C-C alkyl phenol ethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic Cs-Cs primary or Secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
- In a preferred embodiment, the machine dishwashing composition comprises a non-ionic surfactant system selected from a C10-20 fatty acid, an alkoxylated fatty alcohol, an alkoxylated fatty acid, alkylphenol alkoxylates, alkoxylated amines, alkoxylated fatty acid amides, terminally blocked alkoxylates, fatty acid esters of glycerol, fatty acid esters of sorbitol, fatty acid esters of sucrose, alkyl polyglucosides, amine-oxides, sulphoxides, phosphine oxides, more preferably selected from a C10-20 fatty acid, an ethoxylated fatty alcohol, an ethoxylated fatty acid, alkylphenol ethoxylates, ethoxylated amines, ethoxylated fatty acid amides, terminally blocked ethoxylates, fatty acid esters of glycerol, fatty acid esters of sorbitol, fatty acid esters of sucrose, alkyl polyglucosides, amine-oxides, sulphoxides, phosphine oxides.
- Preferably, the machine dishwashing composition comprises from 0.1 to 15 wt.% non-ionic surfactant, preferably 1.0 to 12.0 wt.% non-ionic surfactant, more preferably 2.0 to 8 wt.% non-ionic surfactant, most preferably 2.5 to 5 wt.% non-ionic surfactant.
- Preferably, the machine dishwashing composition comprises at most 5.0 wt. %, more preferably at most 4.0 wt. %, even more preferably at most 3.0 wt. %, still even more preferably at most 2.0 wt. % and still even more preferably at most 1.0 wt. % of anionic surfactant.
- The machine dishwashing composition preferably comprises 10 to 50 wt.% carbonate salts, preferably selected from Na2CO3, K2CO3, CaCO3 or a combination of both, preferably 15 to 40 wt.% carbonate salts selected from Na2CO3 and CaCO3 or a combination of both, most preferably 20 to 30 wt. % carbonate, selected from Na2CO3, CaCO3 or a combination of both. In a preferable embodiment, the carbonate salt is Na2CO3.
- The term "builder" as used herein refers to a material that is capable of removing calcium and/or magnesium ion from aqueous solution by ion exchange, complexation, sequestration and/or precipitation. The builder or sequestrant material is preferably fully soluble in water so as to eliminate the possibility of unwanted and unsightly residues on substrates. For that reason alkali metal aluminosilicates are not favoured. Typical examples of phosphorus containing inorganic builders, when present, include the water-soluble salts, especially alkali metal pyrophosphates, orthophosphates and polyphosphates. Specific examples of inorganic phosphate builders include sodium and potassium tripolyphosphates, pyrophosphates and hexametaphosphates. Examples of suitable non-phosphorus water-soluble detergency builders, when present, include carbonate, citrate, zeolite, silicate and aminopolycarboxylic compounds, such as glutamate diacetic acid (GLDA), methylglycine diacetic acid (MGDA), and Trisodium Citrate. Other non-phosphorus water-soluble detergency builders may include inorganic builders as alkali metal carbonate, bicarbonates, sesquicarbonates, borates, silicates, metasilicates, and crystalline and amorphous aluminosilicates, and organic builders as polycarboxylate polymers, such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates, monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono- di and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates and hydroxyethyliminodiacetates.
- The term "bleach activator" as used herein refers to compounds employed in cleaning compositions to activate the bleaching agent, or bleach component, especially at lower temperatures. Examples of bleach activators suitable for use in the cleaning compositions of this invention include one or more activators such as peroxyacid bleach precursors. Peroxyacid bleach precursors are well known in the art. As non-limiting examples can be named tetraacetyl ethylene diamine (TAED), sodium nonanoyloxybenzene sulphonate (SNOBS), sodium benzoyloxybenzene sulphonate (SBOBS) and the cationic peroxyacid precursor (SPCC). These and other related compounds are described in fuller detail by Grime and Clauss in-Chemistry & Industry (Oct. 15, 1990) 647 653. The detergent composition of the invention may comprise from 0.01 to 15 wt. % of bleach activator, more preferably from 0.2 to 10 wt. % and even more preferably from 1.0 to 6 wt. %, but more preferably comprises no bleach activator.
- Bleach catalysts function by oxidizing typically via peroxide or a peracid to form a bleaching species. They require the presence of an oxidizable soil so that they can be reduced back to the starting bleach activator state.
- Bleach catalyst can be a manganese complex of formula (A):
[LnMnmXp]zYq
,wherein Mn is manganese, which can be in the II, III, IV or V oxidation state or mixtures thereof; n and m are independent integers from 1-4; X represents a co-ordination or bridging species; p is an integer from 0-12; Y is a counter-ion, the type of which is dependent on the charge z of the complex which can be positive, zero or negative; q = z/[charge Y]; and L is a ligand being a macrocyclic organic molecule of the general formula: - Such bleach catalysts are described in
EP0458397A2 . - Bleach catalysts can be one or more of:
- [MnIII 2 (µ-O)1(µ-OAc)2(TACN)2] (ClO4)2;
- [MnIIIMnIV (µ-O)2(µ-OAc)1 (TACN)2] (BPh4)2;
- [MnIV 4 (µ-O)6 (TACN)4] (ClO4)4;
- [MnIII 2 (µ-O), (µ-OAc)2 (Me-TACN)2] (ClO4)2 ;
- [MnIIIMnIV (µ-O)1 (µ-OAc)2 (Me-TACN)2] (PF6)2;
- [MnIV 2 (µ-O)3 (Me/Me-TACN)2] (PF6)2 ;
- [MnIIImnIV(µ-O)2(µ-OAc)1 (Me-TACN)2] (BPh4)2;
- [MnIV 2(µ-O)3(Me-TACN)2] (PF6)2;
- [MnIII 2(µ-O)1(u-OAc)2(Me-TACN)2] (ClO4)2; and
- [MnIIIMnIV 4(µ-O)1(µ-OAc)2(Me-TACN)2] (ClO4)3.
- Bleach catalyst can be part of a bleach catalyst granule comprising less than 5 wt. % of active bleach catalyst. The use of such granules improves the accurate dosing of the bleach catalyst.
- The detergent composition is preferably a powder, a tablet, an aqueous or non-aqueous liquid, a loose flowing powder, a paste, a capsule or a gel. Preferably, the composition is in the form a gel, a capsule or a tablet, more preferably a capsule.
- The carbohydrate oxidase enzyme used in the present invention can usefully be added to the detergent composition in any suitable form, i.e. the form of a granular composition, a liquid or a slurry of the enzyme, or with carrier material. For example, adding the enzyme to a liquid detergent product is in the form of a slurry containing 0.5 to 50% by weight of the enzyme in an ethoxylated alcohol nonionic surfactant, such as described in
EP-A-450702 (Unilever - In a preferred embodiment in which the machine dishwashing composition is a solid or flowing powder, the machine dishwashing composition preferably has a water content of less than 5 wt.%. An even more preferred embodiment is that in which the machine dishwashing composition is tablet with a water content of less than 5 wt.%.
- Preferably a 1 wt. % solution of the detergent composition in deionised water has a pH in the range of 8.5 - 11.0, more preferably 9.0 - 10.75 and most preferably 9.5 - 10.5. The pH being measured at 25 °C, in otherwise standard conditions.
- The composition may be in the form of a unit dose, wherein the unit dose is a gel, powder, liquid or combination thereof.
- Given the above, a preferred machine dishwash composition according to the invention comprises:
- a) from 0.02 to 0.3 wt. % of active carbohydrate oxidase enzyme, preferably selected from the group consisting of alcohol oxidase, glucose oxidase, galactose oxidase, sorbose oxidase, hexose oxidase, aldose oxidase, and mixtures thereof, more preferably glucose oxidase;
- b) from 10 to 30 wt. % of the carbohydrate oxidase enzyme substrate and
- c) a surfactant system comprising non-ionic surfactant,
- Given the above an even more preferred machine dishwash composition according to the invention for use at a wash temperature above 65 degrees Celsius comprises:
- a) from 0.04 to 0.2 wt. % of active carbohydrate oxidase enzyme, preferably selected from the group consisting of alcohol oxidase, glucose oxidase, galactose oxidase, sorbose oxidase, hexose oxidase, aldose oxidase, and mixtures thereof, more preferably glucose oxidase;
- b) from 10 to 25 wt. % of the carbohydrate oxidase enzyme substrate and
- c) a surfactant system comprising non-ionic surfactant,
- The machine dish wash compositions of the invention preferably comprise no bleach precursor, although the presence of such does not negatively affect the tea-stain cleaning.
- In a second aspect, there is provided a method of cleaning kitchenware comprising the steps of contacting a detergent composition as defined herein with kitchenware in the presence of water. Preferably, the method is carried out at a temperature in the range of 30 to 90 °C, more preferably 40 to 85 °C, even more preferably 50 to 80 °C. A high temperature wash conditions is defined as using a temperature of above 65 degrees Celsius; low-medium temperature wash conditions as a temperature of at most 65 degrees Celsius.
- The ingredients and amounts of the ingredients described herein apply mutatis mutandis to the second aspect.
- The ingredients and amounts of the ingredients described herein apply mutatis mutandis to the third aspect.
- Preferably the stain remover is active at a temperature in the range of 40 to 90 °C, more preferably 40 to 85 °C, even more preferably 50 to 80 °C.
- In a fourth aspect, there is provided a process of preparing compositions as described herein comprising the step of combining a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system.
- In fifth aspect there is provided a process of preparing a unit dose according to any of the preceding claims comprising the step of:
- i. providing a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system to provide a mixture,
- ii. forming the mixture of step (i) into a unit dose.
- The ingredients and amounts of the ingredients described herein apply mutatis mutandis to the fourth and fifth aspects.
- Compositions 1-3, 6, 7 and A are not according to the claims and are for illustrative purposes.
- The following compositions (1-5 and comparative A) were prepared, as shown in Table 1:
Table 1 1 2 3 4 5 A Sodium percarbonate (wt.%) - - - - - - Glucose Oxidase (wt.% active enzyme)1 20.005 0.005 0.05 0.1 0.05 - Glucose (wt.%) 18.9 18.9 18.9 18.9 18.9 - Macrocyclic manganese bleach catalyst (MnCat) (wt.%) 0.02 0.02 0.02 - - 0.02 Tetraacetyl ethylene diamine (TAED) (wt.%) - - - 10.7 10.7 Sodium Carbonate (wt.%) - 24.99 24.99 24.99 24.99 24.99 Methylglycine diacetic acid (MGDA) (wt.%) 26.41 26.41 26.41 26.41 26.41 26.41 Non-lonic surfactant (wt.%) 3.00 3.00 3.00 3.00 3.00 3.00 Minor Ingredients (wt.%) Up to balance Up to balance Up to balance Up to balance Up to balance Up to balance 1Maxapal® GO4 (DSM, The Netherlands)
20.005 wt. % of active glucose oxidase enzyme equates to ~ 72 enzyme units per 18g of composition. - The following compositions 6 to 8 were prepared, as shown in Table 2:
6 7 8 Sodium percarbonate (wt.%) - - - Glucose Oxidase (wt.% active enzyme)1 0.05 0.05 0.05 Glucose (wt.%) 12.8 6.4 12.8 Macrocyclic manganese bleach catalyst (MnCat) (wt.%) 0.02 0.02 - Tetraacetyl ethylene diamine (TAED) (wt.%) - - - Sodium Carbonate (wt.%) - 24.99 24.99 Methylglycine diacetic acid (MGDA) (wt.%) 26.41 26.41 26.41 Non-lonic surfactant (wt.%) 3.00 3.00 3.00 - Stained tiles (DM-14 Dark Tea on Melamine; Supplier: Center For Test materials B.V.) were placed in a 5L solution made from dosing 18g according to formulations listed in Table 1 in water. Each solution was placed in a beaker under agitation and temperature controlled for 20min. The temperate was as indicated in Table 3. Scale: (-) poor to (+++) best) stain removing power:
Table 3 Wash temperature and length Stain removing power Comparative A 50 °C 20 minutes - Comparative B (Finish Tablet) 50 °C 20 minutes + 1 50 °C 20 minutes + 2 50 °C 20 minutes ++ 3 50 °C 20 minutes +++ 4 50 °C 20 minutes +++ 5 50 °C 20 minutes +++ 6 50 °C 20 minutes ++ 7 50 °C 20 minutes + 8 80 °C 20 minutes +++
Claims (15)
- A machine dishwasher composition comprising:a) from 0.002 to 0.5 wt. % of active carbohydrate oxidase enzyme, preferably selected from the group consisting of alcohol oxidase, glucose oxidase, galactose oxidase, sorbose oxidase, hexose oxidase, aldose oxidase, and mixtures thereof, more preferably glucose oxidase;b) from 1 to 40 wt. % of the carbohydrate oxidase enzyme substrate andc) a surfactant system comprising non-ionic surfactant,wherein the pH of a 1 wt. % solution of the composition in deionized water is in the range of from 8.5 to 11.5, as measured at 25 degrees Celsius and in otherwise standard conditions,wherein the composition is free of metal bleach catalyst.
- The composition according to claim 1, wherein the composition comprises 0.01 to 0.4 wt.% active carbohydrate oxidase enzyme, preferably 0.02 to 0.3 wt.% carbohydrate oxidase enzyme, more preferably 0.04 to 0.2 wt.% and even more preferably from 0.045 to 0.08 wt. % of active carbohydrate oxidase enzyme.
- The composition according to claims 1 or 2, wherein the carbohydrate oxidase enzyme is an Aspergillus niger glucose oxidase.
- The composition according to claim 3, wherein the carbohydrate oxidase enzyme substrate is glucose.
- The composition according to any of the preceding claims, comprising from 2 to 35 wt. %, preferably from 5 to 33 wt. % more preferably from 10 to 30 wt.% carbohydrate source and even more preferably from 11 to 25 wt.% of the carbohydrate source.
- The composition according to claims any of the preceding claims, wherein the surfactant system comprises 1.0 to 15.0 wt.% non-ionic surfactant, more preferably 2.0 to 10 wt.%, most preferably 2.5 to 5 wt.%.
- The composition according to claims any of the preceding claims, wherein the composition comprises a non-ionic surfactant system selected from a C10-20 fatty acid, an alkoxylated fatty alcohol, an alkoxylated fatty acid, alkylphenol alkoxylates, alkoxylated amines, alkoxylated fatty acid amides, terminally blocked alkoxylates, fatty acid esters of glycerol, fatty acid esters of sorbitol, fatty acid esters of sucrose, alkyl polyglucosides, amine-oxides, sulphoxides, phosphine oxides, more preferably selected from a C10-20 fatty acid, an ethoxylated fatty alcohol, an ethoxylated fatty acid, alkylphenol ethoxylates, ethoxylated amines, ethoxylated fatty acid amides, terminally blocked ethoxylates, fatty acid esters of glycerol, fatty acid esters of sorbitol, fatty acid esters of sucrose, alkyl polyglucosides, amine-oxides, sulphoxides, phosphine oxides.
- The composition according to any of the preceding claims, composition comprises 10 to 50 wt.% of water soluble alkali metal carbonate, preferably the water soluble alkali metal carbonate is selected from Na2CO3, K2CO3 and CaCO3 and combinations thereof.
- The composition according to any of the preceding claims, wherein a 1 wt. % solution of the composition in deionised water has pH in the range of 8.5 - 11.0 preferably 9.0 - 10.75 and more preferably 9.5 - 10.5, as measured at 25 degrees Celsius.
- The composition according to any of the preceding claims, wherein the composition is in the form of a gel, a powder, an aqueous or non-aqueous liquid.
- Unit dose comprising a composition according to any of the preceding claims, wherein the unit dose is a gel, powder, liquid or combination thereof.
- Method of cleaning kitchenware comprising the steps of contacting the composition according to any of claims 1-10 or unit dose according to claim 11 with kitchenware in the presence of water, preferably at a temperature in the range of 30 to 90 °C.
- Use of a composition according to any of claims 1-10 or unit dose according to claim 11 as tea stain remover, preferably as a sustainable/bio-based/green tea stain remover, wherein more preferably the stain remover is active at a temperature in the range of 30 to 90 °C, more preferably 40 to 90 °C and even more preferably 50-80 °C.
- A process of preparing compositions according to any of the claims 1-10, comprising the step of combining a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system.
- A process of preparing a unit dose according to claim 11:i. providing a carbohydrate oxidase enzyme, substrate for said enzyme and a non-ionic surfactant system to provide a mixture,ii. forming the mixture of step (i) into a unit dose.
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PCT/EP2020/077701 WO2021073901A1 (en) | 2019-10-15 | 2020-10-02 | Detergent composition |
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EP0450702A3 (en) | 1990-04-06 | 1993-06-02 | Unilever N.V. | Process for preparing liquid enzymatic detergent compositions |
EP0458397B1 (en) | 1990-05-21 | 1997-03-26 | Unilever N.V. | Bleach activation |
WO1994023637A1 (en) * | 1993-04-09 | 1994-10-27 | The Procter & Gamble Company | Machine dishwashing method employing a metallo catalyst and enzymatic source of hydrogen peroxide |
WO1999002640A1 (en) | 1997-07-09 | 1999-01-21 | The Procter & Gamble Company | Cleaning compositions comprising an oxidoreductase |
DE102010039814A1 (en) * | 2010-08-26 | 2012-03-01 | Henkel Ag & Co. Kgaa | Enzyme-containing machine dishwashing detergent |
EA201691672A1 (en) * | 2014-02-20 | 2017-02-28 | Юнилевер Н.В. | COMPOSITION FOR DISHWASHING MACHINE |
-
2020
- 2020-10-02 ES ES20785504T patent/ES2968816T3/en active Active
- 2020-10-02 WO PCT/EP2020/077701 patent/WO2021073901A1/en unknown
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