JP2002524872A5 - - Google Patents
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- JP2002524872A5 JP2002524872A5 JP2000569428A JP2000569428A JP2002524872A5 JP 2002524872 A5 JP2002524872 A5 JP 2002524872A5 JP 2000569428 A JP2000569428 A JP 2000569428A JP 2000569428 A JP2000569428 A JP 2000569428A JP 2002524872 A5 JP2002524872 A5 JP 2002524872A5
- Authority
- JP
- Japan
- Prior art keywords
- platinum
- ruthenium
- electrode
- barrier layer
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 34
- 229910052697 platinum Inorganic materials 0.000 description 13
- 239000003990 capacitor Substances 0.000 description 10
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- 239000005092 Ruthenium Substances 0.000 description 7
- 229910052707 ruthenium Inorganic materials 0.000 description 7
- 229910000929 Ru alloy Inorganic materials 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 210000000352 storage cell Anatomy 0.000 description 4
- 238000000151 deposition Methods 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- IVHJCRXBQPGLOV-UHFFFAOYSA-N azanylidynetungsten Chemical compound [W]#N IVHJCRXBQPGLOV-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cells Anatomy 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- TWXTWZIUMCFMSG-UHFFFAOYSA-N nitride(3-) Chemical compound [N-3] TWXTWZIUMCFMSG-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
Description
【特許請求の範囲】
【請求項1】
反応容器中に表面を有する基材アセンブリを提供すること、及び
前記表面の少なくとも一部に、反応容器中でルテニウムを含む先駆物質、白金を含む先駆物質、及び酸素を含む成分を用いる化学気相堆積によって、白金(x):ルテニウム合金(xは約0.60〜約0.995)でできているバリアー層を堆積させること、
を含む、集積回路の製造で使用する方法。
【請求項2】
基材アセンブリの一部上に第1の電極を形成すること、
前記第1の電極の少なくとも一部上に高誘電率材料を提供すること、及び
前記高誘電率材料上に第2の電極を形成すること、
を更に含み、前記第1と第2の電極のうちの少なくとも一方が、白金(x):ルテニウム合金でできたバリアー層を含む、請求項1に記載の方法。
【請求項3】
前記第1の電極が、白金(x):ルテニウム合金でできたバリアー層を含む、請求項2に記載の方法。
【請求項4】
前記第1の電極が、白金(x):ルテニウム合金でできたバリアー層と1又は複数の追加の導電性層を含む、請求項3に記載の方法。
【請求項5】
前記xが0.90〜0.98である、請求項1〜4のいずれかに記載の方法。
【請求項6】
前記xが0.95である、請求項1〜4のいずれかに記載の方法。
【請求項7】
キャパシター構造体であって、
前記基材アセンブリ表面上に作られた第1の電極、
前記第1の電極の少なくとも1部上の誘電体材料、及び
前記誘電体材料上の第2の電極、
を含み、前記第1と第2の電極の少なくとも一方が、請求項1〜6のいずれか一項でできたバリアー層を含む、構造体。
【請求項8】
少なくとも前記第1の電極が、白金(x):ルテニウム合金でできている前記バリアー層と1又は複数の追加の導電性層を含む、請求項7に記載の構造体。
【請求項9】
少なくとも1つの能動素子を有する基材アセンブリ、及び
前記少なくとも1つの能動素子に関して作られた相互接続、
を含み、前記相互接続が、請求項1〜6のいずれか一項でできたバリアー層を含む、集積回路構造体。
【請求項1】
反応容器中に表面を有する基材アセンブリを提供すること、及び
前記表面の少なくとも一部に、反応容器中でルテニウムを含む先駆物質、白金を含む先駆物質、及び酸素を含む成分を用いる化学気相堆積によって、白金(x):ルテニウム合金(xは約0.60〜約0.995)でできているバリアー層を堆積させること、
を含む、集積回路の製造で使用する方法。
【請求項2】
基材アセンブリの一部上に第1の電極を形成すること、
前記第1の電極の少なくとも一部上に高誘電率材料を提供すること、及び
前記高誘電率材料上に第2の電極を形成すること、
を更に含み、前記第1と第2の電極のうちの少なくとも一方が、白金(x):ルテニウム合金でできたバリアー層を含む、請求項1に記載の方法。
【請求項3】
前記第1の電極が、白金(x):ルテニウム合金でできたバリアー層を含む、請求項2に記載の方法。
【請求項4】
前記第1の電極が、白金(x):ルテニウム合金でできたバリアー層と1又は複数の追加の導電性層を含む、請求項3に記載の方法。
【請求項5】
前記xが0.90〜0.98である、請求項1〜4のいずれかに記載の方法。
【請求項6】
前記xが0.95である、請求項1〜4のいずれかに記載の方法。
【請求項7】
キャパシター構造体であって、
前記基材アセンブリ表面上に作られた第1の電極、
前記第1の電極の少なくとも1部上の誘電体材料、及び
前記誘電体材料上の第2の電極、
を含み、前記第1と第2の電極の少なくとも一方が、請求項1〜6のいずれか一項でできたバリアー層を含む、構造体。
【請求項8】
少なくとも前記第1の電極が、白金(x):ルテニウム合金でできている前記バリアー層と1又は複数の追加の導電性層を含む、請求項7に記載の構造体。
【請求項9】
少なくとも1つの能動素子を有する基材アセンブリ、及び
前記少なくとも1つの能動素子に関して作られた相互接続、
を含み、前記相互接続が、請求項1〜6のいずれか一項でできたバリアー層を含む、集積回路構造体。
本発明のキャパシターを含む蓄積セルの製造で使用するもう1つの方法を説明する。この方法は、少なくとも1つの能動素子を有する基材アセンブリを提供すること、及び前記少なくとも1つの能動素子に関してキャパシターを製造することを含む。前記キャパシターは、白金(x):ルテニウム(1−x)合金のバリアー層を含む少なくとも1つの電極を有する。
本発明のメモリーセル構造体は、少なくとも1つの能動素子を有する基材アセンブリ;及び前記少なくとも1つの能動素子に関して形成されたキャパシターを含む。ここで前記キャパシターは、白金(x):ルテニウム(1−x)合金でできたバリアー層を含む少なくとも1つの電極を有する。
もう1つの集積回路構造体は、少なくとも1つの能動素子を有する基材アセンブリと、この少なくとも1つの能動素子に関して作られた相互接続を含む。ここでこの相互接続は、白金(x):ルテニウム(1−x)合金でできたバリアー層を有する。
更に例えば、白金:ルテニウム合金バリアー層14を、メモリーデバイスのような半導体デバイスに使用する蓄積セルキャパシターの製造で使用することができる。ここで更に説明するように、白金:ルテニウム合金バリアー層14は、キャパシターの電極を作る積層体で、又はそのような蓄積セルキャパシターの電極において単独で使用することができる。CMOSデバイス、メモリーデバイス等のような様々なデバイスのための様々な半導体
プロセス及び構造体が、本発明のバリアー層のバリアー特性で利益を受け、また本発明はここで説明される態様に制限されないことを、当業者は理解する。
プロセス及び構造体が、本発明のバリアー層のバリアー特性で利益を受け、また本発明はここで説明される態様に制限されないことを、当業者は理解する。
図4で示すように、開口184を作る表面185,186上に底部電極構造体を堆積させる前に、開口184を形成することによって、従来の処理技術でデバイス構造体100を作る。そして白金:ルテニウム合金底部電極を開口184内につくる。このように、及びFazan等の米国特許第5,392,189号明細書で示されているように、デバイス構造体100は、電界酸化物(field oxide)領域105及び活性領域、すなわち電界酸化物に覆われていない基材107の領域を含む。ワードライン121及び能動素子、すなわち電界効果トランジスタ(FET)122は、電界酸化物領域105に関して作られる。適当なソース/ドレイン領域125,130をシリコン基材107に作る。酸化物材料140の絶縁層は、FET122及びワードライン121の領域上に作る。ポリシリコンプラグ165を作って、基材107と基材上に作られる貯蔵セルキャパシターとの間の電気的接触を提供する。ポリシリコンプラグ165上に様々な層、例えば層167及び175を作る。そのような層は例えば、窒素化チタン、窒素化タングステン、又はバリアーとして機能する任意の他の金属窒素化物でよく、これは上述のような1又は複数の白金:ルテニウム合金バリアー層を含むこともできる。その後で、もう1つの絶縁層183を作って、開口184を与えるようにする。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/146,866 | 1998-09-03 | ||
US09/146,866 US6323081B1 (en) | 1998-09-03 | 1998-09-03 | Diffusion barrier layers and methods of forming same |
PCT/US1999/020053 WO2000014778A1 (en) | 1998-09-03 | 1999-08-31 | Diffusion barrier layers and methods of forming same |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012003619A Division JP5490829B2 (ja) | 1998-09-03 | 2012-01-11 | 拡散バリアー層及びその製造方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2002524872A JP2002524872A (ja) | 2002-08-06 |
JP2002524872A5 true JP2002524872A5 (ja) | 2006-10-05 |
JP5328065B2 JP5328065B2 (ja) | 2013-10-30 |
Family
ID=22519319
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000569428A Expired - Fee Related JP5328065B2 (ja) | 1998-09-03 | 1999-08-31 | 拡散バリアー層及びその製造方法 |
JP2012003619A Expired - Fee Related JP5490829B2 (ja) | 1998-09-03 | 2012-01-11 | 拡散バリアー層及びその製造方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012003619A Expired - Fee Related JP5490829B2 (ja) | 1998-09-03 | 2012-01-11 | 拡散バリアー層及びその製造方法 |
Country Status (5)
Country | Link |
---|---|
US (2) | US6323081B1 (ja) |
JP (2) | JP5328065B2 (ja) |
KR (1) | KR100441190B1 (ja) |
AU (1) | AU5799699A (ja) |
WO (1) | WO2000014778A1 (ja) |
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1998
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1999
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- 1999-08-31 WO PCT/US1999/020053 patent/WO2000014778A1/en active IP Right Grant
- 1999-08-31 AU AU57996/99A patent/AU5799699A/en not_active Abandoned
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2001
- 2001-08-29 US US09/942,200 patent/US20020008270A1/en not_active Abandoned
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2012
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