DE69704617D1 - Elastomere und verfahren zu ihrer herstellung - Google Patents

Elastomere und verfahren zu ihrer herstellung

Info

Publication number
DE69704617D1
DE69704617D1 DE69704617T DE69704617T DE69704617D1 DE 69704617 D1 DE69704617 D1 DE 69704617D1 DE 69704617 T DE69704617 T DE 69704617T DE 69704617 T DE69704617 T DE 69704617T DE 69704617 D1 DE69704617 D1 DE 69704617D1
Authority
DE
Germany
Prior art keywords
solvent
recovery operation
solvent recovery
olefin
anhydrous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69704617T
Other languages
English (en)
Other versions
DE69704617T2 (de
Inventor
W Kolthammer
S Cardwell
Deepak Parikh
S Edmondson
W Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of DE69704617D1 publication Critical patent/DE69704617D1/de
Publication of DE69704617T2 publication Critical patent/DE69704617T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
DE69704617T 1996-07-12 1997-07-09 Elastomere und verfahren zu ihrer herstellung Expired - Lifetime DE69704617T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/679,538 US6545088B1 (en) 1991-12-30 1996-07-12 Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
PCT/US1997/012294 WO1998002471A1 (en) 1996-07-12 1997-07-09 Elastomers and process for their manufacture

Publications (2)

Publication Number Publication Date
DE69704617D1 true DE69704617D1 (de) 2001-05-23
DE69704617T2 DE69704617T2 (de) 2001-08-02

Family

ID=24727319

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69704617T Expired - Lifetime DE69704617T2 (de) 1996-07-12 1997-07-09 Elastomere und verfahren zu ihrer herstellung

Country Status (19)

Country Link
US (1) US6545088B1 (de)
EP (1) EP0910593B1 (de)
JP (1) JP2000514857A (de)
KR (1) KR100496101B1 (de)
CN (1) CN1098289C (de)
AT (1) ATE200680T1 (de)
AU (1) AU718342B2 (de)
BR (1) BR9710347A (de)
CA (1) CA2256668C (de)
CZ (1) CZ9499A3 (de)
DE (1) DE69704617T2 (de)
ES (1) ES2156001T3 (de)
HU (1) HUP9904354A3 (de)
NO (1) NO990095L (de)
NZ (1) NZ332880A (de)
PL (1) PL331038A1 (de)
TR (1) TR199900050T2 (de)
TW (1) TW341576B (de)
WO (1) WO1998002471A1 (de)

Families Citing this family (180)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69929678T2 (de) * 1998-03-04 2006-09-21 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur erhöhung des dienumsatzes in epdm-polymerisationen
US6319998B1 (en) * 1998-03-04 2001-11-20 Exxon Mobil Chemical Patents Inc. Method for making polymer blends by using series reactors
CN1292014A (zh) 1998-03-04 2001-04-18 埃克森化学专利公司 聚烯烃聚合物分散体产品及其制备方法
EP1159320B1 (de) * 1998-11-02 2011-01-12 Dow Global Technologies Inc. Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
JP4566305B2 (ja) * 1999-08-31 2010-10-20 日本ポリプロ株式会社 メタロセン化合物由来成分を含有する溶剤の精製方法
KR100937175B1 (ko) 2000-01-26 2010-01-19 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체
ES2271099T3 (es) 2000-10-25 2007-04-16 Exxonmobil Chemical Patents, Inc. Procediminetos y aparatos para polimerizacion en disolucion en continuo.
CA2429678A1 (en) * 2000-12-04 2002-06-13 Exxonmobil Chemical Patents Inc. Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions
MXPA03005626A (es) * 2000-12-20 2004-12-03 Exxonmobil Chem Patents Inc Proceso de polimerizacion de olefinas para producir composiciones polimericas ramificadas.
SG120869A1 (en) * 2001-05-31 2006-04-26 Mitsui Chemicals Inc Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition
US7022766B2 (en) 2001-05-31 2006-04-04 Mitsui Chemicals, Inc. Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition
ATE407972T1 (de) 2001-12-12 2008-09-15 Exxonmobil Chem Patents Inc Für elastomere membranen geeignete zusammensetzungen
JP4819313B2 (ja) 2002-02-08 2011-11-24 エクソンモービル・ケミカル・パテンツ・インク マルチモーダルエチレン、α−オレフィン及びジエンポリマー、当該組成物を生成する方法及び当該組成物を含む装置
AU2003249337A1 (en) 2002-06-19 2004-01-06 Exxonmobil Chemical Patents, Inc. Ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene and polymers made using such processes
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
WO2004065435A1 (ja) * 2003-01-23 2004-08-05 Mitsui Chemicals, Inc. エチレン・α-オレフィン・非共役ポリエン共重合体の製造方法およびエチレン・α-オレフィン・非共役ポリエン共重合体
ES2606780T3 (es) * 2003-06-10 2017-03-27 Dow Global Technologies Llc Capas de película producidas a partir de mezclas poliméricas de etileno
ATE455832T1 (de) * 2003-08-19 2010-02-15 Dow Global Technologies Inc Interpolymere zur verwendung für schmelzklebstoffe und verfahren zu ihrer herstellung
US7084319B2 (en) 2003-12-05 2006-08-01 Exxonmobil Chemical Patents Inc. Catalyst fluidization in oxygenate to olefin reaction systems
SG183749A1 (en) 2004-03-17 2012-09-27 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
AR048104A1 (es) 2004-03-17 2006-03-29 Dow Global Technologies Inc Composicion catalizadora que comprende un agente de enlace para la formacion de copolimeros superiores de olefina en bloques multiples
BRPI0508161B1 (pt) 2004-03-17 2015-11-17 Dow Global Technologies Inc Composição, processo para preparar um homopolímero em multibloco de alto peso molecular e processo para preparar um copolímero em multibloco de alto peso molecular”
GB0420396D0 (en) 2004-09-14 2004-10-13 Bp Chem Int Ltd Polyolefins
US7947786B2 (en) * 2004-10-13 2011-05-24 Exxonmobil Chemical Patents Inc. Elastomeric reactor blend compositions
KR100586922B1 (ko) 2004-11-18 2006-06-08 금호폴리켐 주식회사 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법
TW200630449A (en) 2004-12-21 2006-09-01 Dow Global Technologies Inc Polypropylene-based adhesive compositions
EP1674490A1 (de) * 2004-12-23 2006-06-28 Borealis Technology Oy Copolymer
WO2006083515A1 (en) * 2005-01-31 2006-08-10 Exxonmobil Chemical Patents Inc. Polymer blends and pellets and methods of producing same
ZA200707867B (en) 2005-03-17 2008-12-31 Dow Global Technologies Inc Fibers made from copolymers of ethylene/alpha-olefins
ZA200708785B (en) * 2005-03-17 2009-01-28 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
ZA200708784B (en) 2005-03-17 2009-01-28 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for tactic/atactic multi-block copolymer formation
WO2006138052A1 (en) 2005-06-13 2006-12-28 Exxonmobil Chemical Patents Inc. Thermoplastic blend compositions
AR058448A1 (es) * 2005-09-15 2008-02-06 Dow Global Technologies Inc Control de arquitectura del polimero y distribucoin de peso molecular va el agente de transferencia multi- centrado
SG156614A1 (en) 2005-09-15 2009-11-26 Dow Global Technologies Inc Catalytic olefin block copolymers via polymerizable shuttling agent
KR20130008644A (ko) * 2006-03-30 2013-01-22 토탈 리서치 앤드 테크놀로지 펠루이 소량의 소거제 존재하의 에틸렌 슬러리 중합 방법
US7935857B2 (en) 2006-03-31 2011-05-03 Exxonmobil Chemical Patents Inc. Product recovery in gas-solids reactors
US7744746B2 (en) 2006-03-31 2010-06-29 Exxonmobil Research And Engineering Company FCC catalyst stripper configuration
EP2363420B1 (de) 2006-06-15 2012-12-12 Dow Global Technologies LLC Funktionalisierte Olefin-Interpolymere, daraus hergestellte Zusammensetzungen und Artikel sowie Herstellungsverfahren dafür
US8785531B2 (en) * 2006-07-06 2014-07-22 Dow Global Technologies Llc Dispersions of olefin block copolymers
EP2066744B1 (de) * 2006-09-11 2018-07-11 Dow Global Technologies LLC Für harzbeschichteten sand verwendete polyolefindispersions-technologie
US8476326B2 (en) * 2006-09-22 2013-07-02 Dow Global Technologies Llc Fibrillated polyolefin foam
PT2109641T (pt) * 2007-01-17 2017-05-25 Agrofresh Inc Entrega de agentes de bloqueio e/ou promotores de etileno
KR20100063004A (ko) 2007-07-16 2010-06-10 다우 글로벌 테크놀로지스 인크. 관능화 중합체, 이로부터 제조된 물품, 및 그 제조방법
CA2598957C (en) 2007-08-27 2014-07-15 Nova Chemicals Corporation Process for high temperature solution polymerization
US8431096B2 (en) 2007-08-27 2013-04-30 Nova Chemicals (International) S.A Process for high temperature solution polymerization
CA2598960C (en) 2007-08-27 2015-04-07 Nova Chemicals Corporation High temperature process for solution polymerization
ES2669294T3 (es) * 2007-09-24 2018-05-24 Dow Global Technologies Llc Césped sintético con capa de absorción de impactos
EP2543763A3 (de) * 2007-09-28 2013-10-30 Dow Global Technologies LLC Faserstruktur impregniert mit Dispersion aus Olefin mit höherer Kristallinität
CN102084053A (zh) * 2007-10-25 2011-06-01 陶氏环球技术公司 用于多孔基质的聚烯烃分散技术
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
ATE513003T1 (de) 2007-12-28 2011-07-15 Dow Global Technologies Llc Vernetzter elastomerschaum auf basis von polyethylen mit einem hohen füllstoffanteil zur herstellung von stossdämpfern, schuhen und bodenbelägen
FR2934599B1 (fr) * 2008-07-29 2012-12-21 Arkema France Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations
DE102008039218A1 (de) 2008-08-22 2010-02-25 Woco Industrietechnik Gmbh Vulkanisierbare Kautschukmischungen sowie Elastomerformteile, erhältlich aus diesen Kautschukmischungen
KR20110063681A (ko) * 2008-09-23 2011-06-13 다우 글로벌 테크놀로지스 엘엘씨 감소된 분자량 변화를 갖는 라디칼 관능화된 올레핀-기재 중합체 및 방법
US8969481B2 (en) 2008-12-18 2015-03-03 Exxonmobil Chemical Patent Inc. Peroxide cured TPV
CN102449003B (zh) 2009-03-31 2013-12-11 陶氏环球技术有限责任公司 由非均匀乙烯/α-烯烃互聚物制成的膜
CN102459357B (zh) 2009-06-05 2013-07-31 陶氏环球技术有限责任公司 制备乙烯的长链支化的(lcb)嵌段共聚物或互连共聚物的方法
US8722817B2 (en) * 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
CN102471403A (zh) 2009-07-01 2012-05-23 陶氏环球技术有限责任公司 烯属聚合物和它的用途
EP2448757B1 (de) 2009-07-01 2016-06-29 Dow Global Technologies LLC Ethylenpolymer und seine verwendung
US8389086B2 (en) 2009-07-01 2013-03-05 Dow Global Technologies Llc Composition for stretch hood, method of producing the same, and articles made therefrom
US8629214B2 (en) 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
KR101262305B1 (ko) 2009-07-01 2013-05-08 주식회사 엘지화학 전이금속 촉매를 이용한 탄성 중합체의 제조방법
US8173232B2 (en) * 2009-07-01 2012-05-08 Dow Global Technologies Llc Stretch hood films
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
CN102471551B (zh) 2009-07-15 2013-09-04 陶氏环球技术有限责任公司 聚合物组合物、其制备方法、以及由该组合物制备的制品
CN102498133B (zh) 2009-07-29 2013-10-30 陶氏环球技术有限责任公司 双头基或多头基的链穿梭剂以及它们用于制备嵌段共聚物的用途
JP5745524B2 (ja) 2009-09-14 2015-07-08 ダウ グローバル テクノロジーズ エルエルシー エチレンおよびポリアルケン由来の単位を含むポリマー
US8598276B2 (en) 2009-09-14 2013-12-03 Dow Global Technologies Llc Polymers comprising units derived from ethylene and poly(alkoxide)
CN102695735B (zh) 2009-09-14 2014-11-05 陶氏环球技术有限责任公司 包含源于乙烯和硅氧烷的单元的聚合物
US9546446B2 (en) 2009-10-23 2017-01-17 Toyo Boseki Kabushiki Kaisha Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove
CN101734996B (zh) * 2009-12-29 2012-12-19 岳阳昌德化工实业有限公司 一种对含4-乙烯基环己烯的废液回收和利用方法
US20110172354A1 (en) * 2010-01-04 2011-07-14 Dow Global Technologies Inc. Ethylene-based polymer compositions for use in fiber applications
US8653196B2 (en) 2010-01-11 2014-02-18 Dow Global Technologies, Llc Method for preparing polyethylene with high melt strength
CN105348417B (zh) 2010-01-14 2019-03-01 埃克森美孚化学专利公司 连续溶液聚合的方法和设备
US8425847B2 (en) 2010-01-14 2013-04-23 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
CN102781533B (zh) 2010-01-14 2015-11-25 利斯特股份公司 真空脱挥发分装置
US8562915B2 (en) 2010-01-14 2013-10-22 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
EP2542621B2 (de) 2010-03-02 2024-02-21 Dow Global Technologies LLC Polymerzusammensetzungen auf ethylenbasis
CN102918069A (zh) 2010-06-04 2013-02-06 陶氏环球技术有限公司 包含均质的聚烯烃共聚物和接枝硅烷的膜的电子器件模块
WO2011153540A1 (en) 2010-06-04 2011-12-08 Dow Global Technologies Llc Electronic device module comprising film of homogeneous polyolefin copolymer and adhesive property enhancing graft polymer
JP5975987B2 (ja) 2010-06-14 2016-08-23 ダウ グローバル テクノロジーズ エルエルシー シュリンクフィルム用途においてブレンド成分として使用するためのエチレン系ポリマー組成物
EP2585292A1 (de) 2010-06-24 2013-05-01 Dow Global Technologies LLC Elektronisches gerätemodul mit einem heterogenen polyolefincopolymer und einem optionalen silan
WO2012024005A2 (en) 2010-07-09 2012-02-23 Luna Innovations Incorporated Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates
US8907034B2 (en) 2010-09-30 2014-12-09 Dow Global Technologies Llc Comb architecture olefin block copolymers
CN103282391B (zh) 2010-10-29 2016-12-07 陶氏环球技术有限责任公司 基于乙烯的聚合物及其制备方法
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
US8877880B2 (en) 2010-11-17 2014-11-04 Exxonmobil Chemical Patents Inc. Method for controlling polyolefin properties
US9045628B2 (en) 2010-12-03 2015-06-02 Dow Global Technologies Llc Processes to prepare ethylene-based polymer compositions
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
US8822601B2 (en) 2010-12-17 2014-09-02 Dow Global Technologies Llc Ethylene-based polymers and processes to make the same
KR101871533B1 (ko) 2010-12-30 2018-06-26 다우 글로벌 테크놀로지스 엘엘씨 조성물, 그의 제조 방법, 및 그로부터 제조된 용품
JP5985625B2 (ja) 2011-06-30 2016-09-06 ダウ グローバル テクノロジーズ エルエルシー 結晶性ブロックコポリマー複合体又はブロックコポリマー複合樹脂を含む層を有する多層ポリオレフィンベースのフィルム
ES2659153T3 (es) 2011-07-05 2018-03-14 Dow Global Technologies Llc Polímeros a base de etileno y procesos para obtener los mismos
CN103890237A (zh) * 2011-09-14 2014-06-25 马特里亚公司 含有用第8族烯烃复分解催化剂聚合的树脂组合物的改进电解池盖
KR101999415B1 (ko) 2011-09-30 2019-07-11 다우 글로벌 테크놀로지스 엘엘씨 조절된 박리의 라미네이트 접착 필름
EP2794693B1 (de) 2011-12-20 2020-09-23 Dow Global Technologies LLC Interpolymere aus einem ethylen/alpha-olefin/ nichtkonjugierten polymer und verfahren zu ihrer herstellung
MX360854B (es) 2011-12-22 2018-11-20 Dow Global Technologies Llc Polímeros basados en etileno con una resistencia a la fusión mejorada, y procesos para lo mismo.
US8552117B1 (en) 2012-06-13 2013-10-08 Teknor Apex Company Sealing elements and sealing element compositions
BR112014032673B1 (pt) 2012-06-29 2021-07-06 Dow Global Technologies Llc composição, composição reticulada e artigo
WO2014028211A1 (en) * 2012-08-16 2014-02-20 Exxonmobil Chemical Patents Inc. Long chain branched epdm compositions and processes for production thereof
US8796408B2 (en) 2012-08-31 2014-08-05 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers
ES2702346T3 (es) 2012-09-28 2019-02-28 Dow Global Technologies Llc Polímeros basados en etileno y procedimientos para producir los mismos
BR112015006812B1 (pt) 2012-09-28 2021-03-23 Dow Global Technologies Llc Composição
KR101391692B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
JP6408481B2 (ja) 2012-11-30 2018-10-17 ダウ グローバル テクノロジーズ エルエルシー エチレン/αオレフィン/非共役ポリエン系組成物およびそれから形成される発泡体
CN104812783B (zh) 2012-11-30 2021-07-16 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯基组合物
JP6419718B2 (ja) 2012-12-28 2018-11-07 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびその製造プロセス
KR20140144076A (ko) 2013-06-10 2014-12-18 주식회사 엘지화학 3원계 탄성 공중합체의 제조 방법
JP2015532362A (ja) 2013-06-28 2015-11-09 エルジー・ケム・リミテッド ジエンを含む三元系弾性共重合体およびその製造方法
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585206B1 (ko) 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
CN104797610A (zh) 2013-06-28 2015-07-22 株式会社Lg化学 弹性二烯三元共聚物及其制备方法
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
BR112016013701B1 (pt) 2013-12-26 2022-01-04 Dow Global Technologies Llc Processo para formar polímeros à base de etileno
WO2015100351A1 (en) 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to improve reactor stability for the preparation of ethylene-based polymers using asymmetrical polyenes
WO2015100302A1 (en) 2013-12-26 2015-07-02 Dow Global Technologies Llc Ethylene-based polymers formed using asymmetrical polyenes
US9382361B2 (en) 2014-03-21 2016-07-05 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
KR101655392B1 (ko) 2014-04-21 2016-09-07 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101660480B1 (ko) 2014-04-25 2016-09-27 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
ES2799799T3 (es) 2014-06-24 2020-12-21 Dow Global Technologies Llc Módulos fotovoltaicos que comprenden organoarcilla
JP6628744B2 (ja) 2014-06-24 2020-01-15 ダウ グローバル テクノロジーズ エルエルシー 安定化されたポリプロピレン層を備えるポリオレフィン光起電力裏面シート
US20170152377A1 (en) 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
CN106661156B (zh) 2014-06-27 2021-01-29 陶氏环球技术有限责任公司 包含衍生自一氧化碳和流变改性剂的单元的乙烯基聚合物
EP3160730A1 (de) 2014-06-30 2017-05-03 Dow Global Technologies LLC Gebänderte mehrschichtfolie
ES2768760T3 (es) 2014-12-01 2020-06-23 Dow Global Technologies Llc Composiciones poliméricas, películas retráctiles y métodos de preparación de las mismas
EP3237467B1 (de) 2014-12-23 2024-05-22 Dow Global Technologies LLC Ethylenbasierte interpolymere und zusammensetzung damit
CN107108792B (zh) 2014-12-29 2021-07-16 陶氏环球技术有限责任公司 用于形成含有油的乙烯类聚合物的方法
SG11201705239SA (en) 2014-12-29 2017-07-28 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
SG11201705241QA (en) 2014-12-30 2017-07-28 Dow Global Technologies Llc Process to control output and quality of ethylene-based polymer formed by high pressure free radical polymerization
CN107428878B (zh) 2015-03-31 2020-08-28 陶氏环球技术有限责任公司 用于制备具有低含量长链支化的高分子量乙烯/α-烯烃/非共轭互聚物的方法
WO2016176821A1 (en) 2015-05-05 2016-11-10 Dow Global Technologies Llc Functionalized, halogenated olefin-based adhesive, articles containing and process for using thereof
KR102617008B1 (ko) 2015-06-17 2023-12-26 다우 글로벌 테크놀로지스 엘엘씨 관형 반응기에서 제조되고 그리고 선택적으로 분기제로 변형된 높은 용융 강도의 에틸렌계 폴리머를 사용하여 가교결합된 케이블 절연체를 제조하는 방법
FR3037586A1 (fr) 2015-06-17 2016-12-23 Michelin & Cie Procede de polymerisation continu d'elastomere dienique
JP2018518572A (ja) 2015-06-22 2018-07-12 ダウ グローバル テクノロジーズ エルエルシー 炭素−炭素フリーラジカル開始剤を用いるエチレン系重合体の作製プロセス
KR102575869B1 (ko) 2015-06-24 2023-09-08 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융-강도를 갖는 에틸렌계 폴리머를 제조하는 방법
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
CN108140448B (zh) 2015-09-02 2022-07-01 陶氏环球技术有限责任公司 柔性交联电缆绝缘材料和其制造方法
KR102587539B1 (ko) 2015-09-02 2023-10-12 다우 글로벌 테크놀로지스 엘엘씨 가요성 가교결합된 케이블 절연체 및 가요성 가교결합된 케이블 절연체를 제조하는 방법
US10800865B2 (en) 2015-09-14 2020-10-13 Exxonmobil Chemical Patents Inc. Process for making branched EPDM and the EPDM therefrom
JP6936795B2 (ja) 2015-10-29 2021-09-22 ダウ グローバル テクノロジーズ エルエルシー 可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法
EP3168239A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Hochdruckfreie radikalpolymerisation
EP3168238A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Mittels hochdruckradikalpolymerisation hergestellte ethylenbasierte polymere
EP3168237A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Radikalische hochdruckpolymerisierung zur herstellung von ethylenbasierten polymeren
CN108431060B (zh) 2015-12-29 2021-10-26 陶氏环球技术有限责任公司 高度接枝的基于乙烯的聚合物、高度接枝的基于乙烯的聚合物组合物和其形成方法
BR112018016355B1 (pt) 2016-02-23 2023-03-07 Dow Global Technologies Llc Composição e artigo
WO2017189299A1 (en) 2016-04-29 2017-11-02 Dow Global Technologies Llc Compositions comprising ethylene-carbon monoxide copolymers
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
CN107474194B (zh) * 2016-06-08 2022-03-18 中国石油化工股份有限公司 一种高分子聚合物材料的制造方法
EP3478762A1 (de) 2016-06-30 2019-05-08 Dow Global Technologies, LLC Auf ethylen/alpha-olefin/polyen basierende zusammensetzungen
EP4029886A3 (de) 2016-06-30 2022-09-28 Dow Global Technologies LLC Ethylen-/alpha-olefin-/polyen-interpolymere und zusammensetzungen damit
MX2019006032A (es) 2016-12-16 2019-08-12 Dow Global Technologies Llc Composiciones de interpolimero de etileno/ alfa-olefina.
ES2893526T3 (es) 2017-02-28 2022-02-09 Dow Global Technologies Llc Polímeros basados en etileno con buena aptitud de procesado para uso en películas multicapa
WO2018223045A1 (en) 2017-06-02 2018-12-06 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
JP7381449B2 (ja) 2017-08-24 2023-11-15 ダウ グローバル テクノロジーズ エルエルシー エチレン/c5-c10アルファ-オレフィン/ポリエチレンインターポリマー
ES2965047T3 (es) 2017-10-31 2024-04-10 Dow Global Technologies Llc Interpolímeros de etileno/co y procesos para fabricar los mismos
EP3480220A1 (de) * 2017-11-06 2019-05-08 Borealis AG Kombinierte sequentielle parallele reaktorkonfiguration
KR101918484B1 (ko) 2017-11-15 2019-01-31 금호폴리켐 주식회사 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법
US20190248934A1 (en) 2018-02-09 2019-08-15 Exxonmobil Chemical Patents Inc. Ethylene-a-olefin-diene Elastomers and Methods of Making Them
JP2021517916A (ja) 2018-02-14 2021-07-29 ダウ グローバル テクノロジーズ エルエルシー 長期熱老化性能が向上したエチレン/アルファ−オレフィンインターポリマー組成物
CN111868155B (zh) 2018-02-14 2024-01-02 陶氏环球技术有限责任公司 具有改进的持续耐高温性的乙烯/α-烯烃互聚物组合物
JP7168672B2 (ja) 2018-02-14 2022-11-09 ダウ グローバル テクノロジーズ エルエルシー 改善された連続高温耐性を有するエチレン/アルファ-オレフィンインターポリマー組成物
US11873393B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
BR112020025521A2 (pt) 2018-06-15 2021-03-09 Dow Global Technologies Llc Filme soprado
KR20210021353A (ko) 2018-06-15 2021-02-25 다우 글로벌 테크놀로지스 엘엘씨 고분자량 고밀도 분획을 갖는 바이모달 에틸렌계 중합체의 제조 방법
MX2020013370A (es) 2018-06-15 2021-03-09 Dow Global Technologies Llc Películas fundidas que comprenden polímeros bimodales a base de etileno que tienen fracciones de alta densidad y alto peso molecular.
JP2021529227A (ja) 2018-06-28 2021-10-28 ダウ グローバル テクノロジーズ エルエルシー 改善された溶融強度および熱安定性を有するエチレン系ポリマー
EP3902810A1 (de) 2018-12-28 2021-11-03 Dow Global Technologies LLC Härtbare zusammensetzungen mit telechelen polyolefinen
BR112021012845A2 (pt) 2018-12-28 2021-09-28 Dow Global Technologies Llc Composição curável, e, artigo
WO2020140067A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
CN113454130A (zh) 2018-12-28 2021-09-28 陶氏环球技术有限责任公司 遥爪聚烯烃和用于制备遥爪聚烯烃的方法
BR112021023912A2 (pt) 2019-05-31 2022-01-25 Dow Global Technologies Llc Polietileno de baixa densidade, filme, e, artigo
KR20220066928A (ko) 2019-09-24 2022-05-24 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/알파-올레핀/폴리엔 혼성중합체 조성물
CN114514280A (zh) 2019-09-24 2022-05-17 陶氏环球技术有限责任公司 用于挤出型材的聚合物组合物
KR20220164756A (ko) 2020-04-06 2022-12-13 다우 글로벌 테크놀로지스 엘엘씨 필름 또는 블렌드에서 사용하기 위한 향상된 용융 강도 저밀도 폴리에틸렌
EP4229102A1 (de) 2020-10-14 2023-08-23 Dow Global Technologies LLC Polyethylenzusammensetzungen zur verwendung in gegossenen dehnfolien

Family Cites Families (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US4200722A (en) 1971-09-24 1980-04-29 Stamicarbon, B.V. Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack
US4184027A (en) 1971-10-26 1980-01-15 Monsanto Company Recycle control system for continuous polymerization
US4102761A (en) 1974-01-03 1978-07-25 The Firestone Tire & Rubber Company Radiation cure of synthetic rubbers
JPS5111882A (en) 1974-07-20 1976-01-30 Sumitomo Chemical Co Mihannotanryotaio jokyosuruhoho
FR2297713A1 (fr) 1975-01-17 1976-08-13 Telecommunications Sa Procede d'introduction
FR2322883A1 (fr) 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
JPS52141888A (en) 1976-05-21 1977-11-26 Nippon I P Rubber Kk Ethyleneepropylene copolymers rubber
US4075287A (en) 1976-10-27 1978-02-21 Phillips Petroleum Company Separation process
DE2735355A1 (de) 1977-08-05 1979-02-15 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des aethylens
US4182810A (en) 1978-04-21 1980-01-08 Phillips Petroleum Company Prevention of fouling in polymerization reactors
JPS6030326B2 (ja) 1978-08-17 1985-07-16 三井化学株式会社 エチレン共重合ゴムの製造方法
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
JPS587402A (ja) 1981-07-07 1983-01-17 Mitsui Petrochem Ind Ltd 重合方法
US4792595A (en) 1983-06-15 1988-12-20 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4722971A (en) 1985-08-02 1988-02-02 Exxon Chemical Patents Inc. Easy processing ethylene propylene elastomers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5084534A (en) 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
EP0275925B1 (de) 1987-01-19 1995-04-05 Sumitomo Chemical Company, Limited Elastische Copolymere aus Äthylen, Propylen und einem nichtconjugiertem Dien und Verwendung davon
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5264405A (en) 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US4804794A (en) 1987-07-13 1989-02-14 Exxon Chemical Patents Inc. Viscosity modifier polymers
JP2573613B2 (ja) 1987-08-14 1997-01-22 三菱化学株式会社 エチレンの重合法
US5147949A (en) 1988-03-29 1992-09-15 Exxon Chemical Patents Inc. Polymerization process using a silica gel supported metallocene-alumoxane catalyst
US5231106A (en) 1988-05-18 1993-07-27 Novo Nordisk A/S Azacyclic carboxylic acid derivatives and their preparation and use
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA1327673C (en) 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
CA2034759C (en) 1988-08-01 2003-06-03 Won R. Song Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives
US5229022A (en) 1988-08-01 1993-07-20 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920)
DE68928100T2 (de) * 1988-09-30 1997-11-06 Exxon Chemical Patents Inc Lineare ethylen-copolymermischungen von copolymeren mit engen molekulargewichts- und kompositionsverteilungen
US5017665A (en) 1989-07-25 1991-05-21 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin and 1,4-diolefin copolymerization
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2807502B2 (ja) 1989-10-05 1998-10-08 三井化学株式会社 エチレン―プロピレン―ジエン系ゴム、エラストマー組成物およびその加硫ゴム
FR2654108B1 (fr) 1989-11-08 1993-08-20 Norsolor Sa Nouveaux caoutchoucs polyolefiniques et leur procede de preparation.
US5519091A (en) 1990-02-13 1996-05-21 Mitsui Petrochemical Industries, Ltd. Method for the preparation of ethylene polymer compositions
US5149318A (en) 1990-03-14 1992-09-22 Minnesota Mining And Manufacturing Company Quick-changeover blood handling apparatus
MY107639A (en) 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
CA2060019A1 (en) 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
JP2894858B2 (ja) 1991-04-05 1999-05-24 三井化学株式会社 エチレン・α−オレフィン・ジエン系ゴムおよびその用途
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
GB9125934D0 (en) 1991-12-05 1992-02-05 Exxon Chemical Patents Inc Process for polymerising olefinic feeds under pressure
KR100253826B1 (ko) 1991-12-30 2000-04-15 그레이스 스티븐 에스. 에틸렌 공중합체의 중합방법
ES2111656T3 (es) 1992-01-06 1998-03-16 Dow Chemical Co Composicion de catalizador mejorada.
DE69310390T2 (de) 1992-01-23 1997-10-23 Mitsui Petrochemical Ind Verfahren zur Herstellung eines Polyolefins
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
BE1005795A3 (fr) * 1992-05-13 1994-02-01 Solvay Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine.
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
ES2126653T3 (es) 1992-06-15 1999-04-01 Exxon Chemical Patents Inc Procedimiento de polimerizacion a alta temperatura que emplea catalizadores ionicos para producir poliolefinas.
ATE164169T1 (de) 1992-06-18 1998-04-15 Montell Technology Company Bv Verfahren zur herstellung eines ethylenischen copolymerisats
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5464905A (en) 1992-11-19 1995-11-07 Mitsui Petrochemical Industries, Ltd. Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
WO1994017112A2 (en) 1993-01-29 1994-08-04 The Dow Chemical Company Ethylene interpolymerizations
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
AU681678B2 (en) 1993-06-24 1997-09-04 Dow Chemical Company, The Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
WO1995016716A1 (en) 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
JP2989512B2 (ja) 1994-02-17 1999-12-13 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション ポリオレフィン製造において用いるためのスプレー乾燥され、充填されるメタロセン触媒組成物
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
DE4432798A1 (de) 1994-09-15 1996-03-21 Basf Ag Hochflexible Propylen-Ethylen-Copolymerisate
US5677382A (en) 1994-12-19 1997-10-14 Japan Synthetic Rubber Co., Ltd. Ethylene-α-olefin-non-conjugated diene copolymer rubber composition
TW383314B (en) 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
EP0743066A3 (de) 1995-05-16 1998-09-30 Mitsui Pharmaceuticals, Inc. Wundheilmittel

Also Published As

Publication number Publication date
CA2256668C (en) 2006-08-22
KR100496101B1 (ko) 2005-06-17
HUP9904354A2 (hu) 2000-04-28
TW341576B (en) 1998-10-01
HUP9904354A3 (en) 2000-05-29
NZ332880A (en) 2000-07-28
CN1223670A (zh) 1999-07-21
AU3727997A (en) 1998-02-09
WO1998002471A1 (en) 1998-01-22
EP0910593A1 (de) 1999-04-28
AU718342B2 (en) 2000-04-13
EP0910593B1 (de) 2001-04-18
PL331038A1 (en) 1999-06-21
US6545088B1 (en) 2003-04-08
NO990095L (no) 1999-01-12
DE69704617T2 (de) 2001-08-02
CA2256668A1 (en) 1998-01-22
ES2156001T3 (es) 2001-06-01
ATE200680T1 (de) 2001-05-15
BR9710347A (pt) 1999-08-17
NO990095D0 (no) 1999-01-11
KR20000023740A (ko) 2000-04-25
TR199900050T2 (xx) 1999-03-22
JP2000514857A (ja) 2000-11-07
CZ9499A3 (cs) 1999-03-17
CN1098289C (zh) 2003-01-08

Similar Documents

Publication Publication Date Title
DE69704617D1 (de) Elastomere und verfahren zu ihrer herstellung
ATE288929T1 (de) Verfahren für katalysatorübergänge in olefinpolymerisationen
DE69501526D1 (de) Verfahren zur gasphasenpolymerisation von alpha-olefinen
CA2193882A1 (en) Polymerization catalyst systems, their production and use
BR9506342A (pt) Processo multi-estágios para a (co) polimerização de olefinas
DE69606188T2 (de) Verfahren zur herstellung von propylen homo- oder copolymeren
ATE160793T1 (de) Katalysator für die olefinpolymerisation, verfahren zu seiner herstellung und seine verwendung
ES2079844T3 (es) Proceso en varias etapas para producir polietileno.
MY138311A (en) Process and apparatus for the polymerization of ethylene
FI945873A0 (fi) Menetelmä etyleenisen polymeerin valmistamiseksi
DE69507436T2 (de) Verfahren zur Herstellung einer In-Situ-Polyethylenmischung
MX9605121A (es) Un proceso para preparar la mezcla de polietileno in situ.
DE69408271T2 (de) Katalysatorsystem für die Polymerisation von Alpha-Olefinen und Verfahren zu dieser Polymerisation
DE69634589D1 (de) Katalysatorsystem für die Co-Polymerisation von Alphaolefinen
ATE40389T1 (de) Verfahren zum herstellen von propylen-ethylenpolymerisaten vom typ der sogenannten ''blockcopolymerisate''.
ATE136042T1 (de) Ethylenpolymere und verfahren zur herstellung derselben in der gasphase
ATE154940T1 (de) Verfahren zum entfernen von niedermolekularen, zähen produkten bei der hochdruckpolymerisation des ethylens
ATE154941T1 (de) Verfahren zum entfernen von niedermolekularen, zähen produkten bei der hochdruckpolymerisation des ethylens
JPS5632508A (en) Polymerization of ethylene
KR910002923A (ko) 프로필렌의 블록공중합체의 제조방법
GB1487141A (en) Method of removing scale from polymerization reactors