ES2126653T3 - Procedimiento de polimerizacion a alta temperatura que emplea catalizadores ionicos para producir poliolefinas. - Google Patents

Procedimiento de polimerizacion a alta temperatura que emplea catalizadores ionicos para producir poliolefinas.

Info

Publication number
ES2126653T3
ES2126653T3 ES93916548T ES93916548T ES2126653T3 ES 2126653 T3 ES2126653 T3 ES 2126653T3 ES 93916548 T ES93916548 T ES 93916548T ES 93916548 T ES93916548 T ES 93916548T ES 2126653 T3 ES2126653 T3 ES 2126653T3
Authority
ES
Spain
Prior art keywords
high temperature
polymerization procedure
ionic
temperature polymerization
ionic catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93916548T
Other languages
English (en)
Inventor
Howard William Turner
Jo Ann Marie Canich
Bernard J Folie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2126653T3 publication Critical patent/ES2126653T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTA INVENCION SE REFIERE A PROCESOS PARA POLIMERIZAR OLEFINAS A ELEVADAS PRESIONES EN UN MEDIO DE POLIMERIZACION A ELEVADA TEMPERATURA UTILIZANDO UN CATALIZADOR DE POLIMERIZACION DE OLEFINA IONICO DERIVADO DE LA REACCION DE UN COMPUESTO DE METAL DE TRANSICION QUE CONTIENEN CICLOPENTADIENILO QUE TIENE UN LIGANDO DE HIDRIDO O ALQUILO HIDROLIZABLE CON UN ACTIVADOR DE INTERCAMBIO DE IONES. EL SISTEMA CATALIZADOR IONICO HA SIDO ENCONTRADO PARA SER ACTUALMENTE ACTIVO A TEMPERATURAS DE 160 (GRADOS) C O MAS, PARA PROPORCIONAR UN PROCESO CAPAZ DE PRODUCIR PRODUCTOS POLIMEROS DE PROPIEDADES QUIMICAS Y FISICAS DESEADAS A ALTA VELOCIDAD DE PRODUCCION.
ES93916548T 1992-06-15 1993-06-15 Procedimiento de polimerizacion a alta temperatura que emplea catalizadores ionicos para producir poliolefinas. Expired - Lifetime ES2126653T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US89863892A 1992-06-15 1992-06-15

Publications (1)

Publication Number Publication Date
ES2126653T3 true ES2126653T3 (es) 1999-04-01

Family

ID=25409791

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93916548T Expired - Lifetime ES2126653T3 (es) 1992-06-15 1993-06-15 Procedimiento de polimerizacion a alta temperatura que emplea catalizadores ionicos para producir poliolefinas.

Country Status (6)

Country Link
EP (1) EP0646140B1 (es)
JP (1) JP3058690B2 (es)
CA (1) CA2117888C (es)
DE (1) DE69322865T2 (es)
ES (1) ES2126653T3 (es)
WO (1) WO1993025590A1 (es)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
EP0891991A3 (en) * 1995-03-01 1999-02-24 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom
US5696213A (en) * 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
EP0868440B1 (de) * 1995-10-14 2001-12-12 Basell Polyolefine GmbH Verfahren zur herstellung von ethylen-copolymerisaten unter hochdruck
US6194341B1 (en) 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US6812184B1 (en) 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
EP0906344B2 (en) * 1996-06-17 2009-02-18 ExxonMobil Chemical Patents Inc. Elevated pressure polymerization processes with late transition metal catalyst systems
DE19719517A1 (de) 1997-05-09 1998-11-12 Basf Ag Katalysatorlösung zur Polymerisation von alpha-Olefinen
DE19737306A1 (de) 1997-08-27 1999-03-04 Basf Ag Katalysatorzubereitung für die (Co)polymerisation von Alk-l-enen
CA2228802C (en) * 1998-02-04 2006-04-25 Stephen John Brown Solution polymerization of ethylene
WO2000001766A1 (en) 1998-07-01 2000-01-13 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2001042315A1 (en) * 1999-12-10 2001-06-14 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6727361B2 (en) 2000-11-07 2004-04-27 Symyx Technologies, Inc. Phosphino substituted pyridine amine ligands
JP5156167B2 (ja) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
WO2004031250A1 (en) 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
AU2003301313A1 (en) 2002-10-17 2004-05-04 Dow Global Technologies Inc. Highly filled polymer compositions
WO2005028584A1 (en) 2003-08-19 2005-03-31 Dow Global Technologies Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
WO2005095475A1 (en) * 2004-03-24 2005-10-13 Exxonmobil Chemical Patents Inc. Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
US7528222B1 (en) 2008-01-15 2009-05-05 Exxonmobil Chemical Patents Inc. Olefin polymerization process
WO2010114028A1 (ja) 2009-03-31 2010-10-07 日本ポリエチレン株式会社 太陽電池封止材用樹脂組成物、太陽電池封止材及びそれを用いた太陽電池モジュール
CN102971863B (zh) * 2010-06-28 2015-04-22 日本聚乙烯株式会社 太阳能电池密封材料及使用其的太阳能电池组件
WO2012036063A1 (ja) 2010-09-14 2012-03-22 日本ポリプロ株式会社 プロピレン系樹脂多層シートおよびそれを用いた加熱処理用包装体
EP2617765B1 (en) 2010-09-17 2014-11-05 Japan Polypropylene Corporation Propylene resin sheet and heat processing packaging body using same
CN108473605B (zh) 2015-12-21 2021-03-26 博里利斯股份公司 用于聚合物的在线共混的方法和装置
EP3394114A1 (en) 2015-12-21 2018-10-31 Borealis AG A process for recovering hydrocarbons in a solution polymerisation process
KR101637234B1 (ko) * 2015-12-28 2016-08-02 주식회사 오프리스 보관 및 휴대가 용이한 신체착용식 의자장치
KR102395595B1 (ko) 2017-06-29 2022-05-09 보레알리스 아게 분리기 내의 폴리머-부족 액체상에서 폴리머의 혼입을 감소시키는 방법
WO2019110316A1 (en) 2017-12-04 2019-06-13 Borealis Ag A method of recovering olefins in a solution polymerisation process
SG11202003064UA (en) 2017-12-04 2020-06-29 Borealis Ag A method of recovering olefins in a solution polymerisation process
SG11202004491VA (en) 2018-01-10 2020-07-29 Borealis Ag Phase-stabilized ethylene alpha olefin copolymerization process
US20220089802A1 (en) 2019-01-28 2022-03-24 Borealis Ag Process for producing a polymer composition
EA202192040A1 (ru) 2019-01-28 2021-11-02 Бореалис Аг Полимерная композиция
WO2020178010A1 (en) 2019-03-04 2020-09-10 Borealis Ag Polymerization process
US20220348702A1 (en) 2019-07-08 2022-11-03 Borealis Ag Polymerization Process
EP4179036A1 (en) 2020-07-13 2023-05-17 Borealis AG Adhesive polyethylene composition
KR20230037609A (ko) 2020-07-13 2023-03-16 보레알리스 아게 접착성 폴리에틸렌 조성물
ES2974059T3 (es) 2020-08-13 2024-06-25 Borealis Ag Conjunto y proceso de cribado de polímero de una corriente de efluente a niveles reducidos de arrastre de polímero
EP3954448A1 (en) 2020-08-13 2022-02-16 Borealis AG Screening assembly and process for screening polymer from an effluent stream at reduced levels of polymer entrainment
EP4000723A1 (en) 2020-11-20 2022-05-25 Borealis AG Device and process for preparing a feed stream for solution polymerization
US20240002552A1 (en) 2020-12-08 2024-01-04 Borealis Ag Polymerization Process and Arrangement
EP4406983A1 (en) 2023-01-24 2024-07-31 Borealis AG Process for preparing an alpha-olefin feed stream and polymerization process using the same
EP4424414A1 (en) 2023-02-28 2024-09-04 Borealis AG Rapid mixing polymerization reactor and process
EP4424413A1 (en) 2023-02-28 2024-09-04 Borealis AG Rapid mixing polymerization process

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0260999A1 (en) * 1986-09-19 1988-03-23 Exxon Chemical Patents Inc. High pressure, high temperature polymerization of ethylene
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers

Also Published As

Publication number Publication date
WO1993025590A1 (en) 1993-12-23
DE69322865T2 (de) 1999-06-17
EP0646140A1 (en) 1995-04-05
CA2117888A1 (en) 1993-12-23
JPH07508545A (ja) 1995-09-21
JP3058690B2 (ja) 2000-07-04
EP0646140B1 (en) 1998-12-30
DE69322865D1 (de) 1999-02-11
CA2117888C (en) 2001-05-15

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