ATE200680T1 - Elastomere und verfahren zu ihrer herstellung - Google Patents

Elastomere und verfahren zu ihrer herstellung

Info

Publication number
ATE200680T1
ATE200680T1 AT97934156T AT97934156T ATE200680T1 AT E200680 T1 ATE200680 T1 AT E200680T1 AT 97934156 T AT97934156 T AT 97934156T AT 97934156 T AT97934156 T AT 97934156T AT E200680 T1 ATE200680 T1 AT E200680T1
Authority
AT
Austria
Prior art keywords
solvent
recovery operation
solvent recovery
olefin
anhydrous
Prior art date
Application number
AT97934156T
Other languages
English (en)
Inventor
Brian W S Kolthammer
Robert S Cardwell
Deepak Parikh
Morris S Edmondson
Stanley W Smith
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE200680T1 publication Critical patent/ATE200680T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT97934156T 1996-07-12 1997-07-09 Elastomere und verfahren zu ihrer herstellung ATE200680T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/679,538 US6545088B1 (en) 1991-12-30 1996-07-12 Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
PCT/US1997/012294 WO1998002471A1 (en) 1996-07-12 1997-07-09 Elastomers and process for their manufacture

Publications (1)

Publication Number Publication Date
ATE200680T1 true ATE200680T1 (de) 2001-05-15

Family

ID=24727319

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97934156T ATE200680T1 (de) 1996-07-12 1997-07-09 Elastomere und verfahren zu ihrer herstellung

Country Status (19)

Country Link
US (1) US6545088B1 (de)
EP (1) EP0910593B1 (de)
JP (1) JP2000514857A (de)
KR (1) KR100496101B1 (de)
CN (1) CN1098289C (de)
AT (1) ATE200680T1 (de)
AU (1) AU718342B2 (de)
BR (1) BR9710347A (de)
CA (1) CA2256668C (de)
CZ (1) CZ9499A3 (de)
DE (1) DE69704617T2 (de)
ES (1) ES2156001T3 (de)
HU (1) HUP9904354A3 (de)
NO (1) NO990095L (de)
NZ (1) NZ332880A (de)
PL (1) PL331038A1 (de)
TR (1) TR199900050T2 (de)
TW (1) TW341576B (de)
WO (1) WO1998002471A1 (de)

Families Citing this family (182)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69929678T2 (de) * 1998-03-04 2006-09-21 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur erhöhung des dienumsatzes in epdm-polymerisationen
CN1292014A (zh) 1998-03-04 2001-04-18 埃克森化学专利公司 聚烯烃聚合物分散体产品及其制备方法
US6319998B1 (en) * 1998-03-04 2001-11-20 Exxon Mobil Chemical Patents Inc. Method for making polymer blends by using series reactors
KR100623106B1 (ko) * 1998-11-02 2006-09-13 다우 글로벌 테크놀로지스 인크. 전단시닝 에틸렌／α―올레핀 인터폴리머 및 그의 제조 방법
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
JP4566305B2 (ja) * 1999-08-31 2010-10-20 日本ポリプロ株式会社 メタロセン化合物由来成分を含有する溶剤の精製方法
EP2267045B1 (de) * 2000-01-26 2015-07-15 Mitsui Chemicals, Inc. Olefinpolymer mit sehr niedriger Polydispersität und Verfahren zu seiner Herstellung
EP1339756B1 (de) 2000-10-25 2006-08-23 Exxonmobil Chemical Patents Inc. Verfahren und vorrichtung zur kontinuierlichen lösungspolymerisation
AU2002219882A1 (en) 2000-12-04 2002-06-18 Exxonmobil Chemical Patents Inc Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions
CA2430222A1 (en) 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Olefin polymerization process to produce branched polymer compositions
SG120869A1 (en) * 2001-05-31 2006-04-26 Mitsui Chemicals Inc Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition
US7022766B2 (en) 2001-05-31 2006-04-04 Mitsui Chemicals, Inc. Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition
ATE407972T1 (de) 2001-12-12 2008-09-15 Exxonmobil Chem Patents Inc Für elastomere membranen geeignete zusammensetzungen
DE60331815D1 (de) 2002-02-08 2010-05-06 Exxonmobil Chem Patents Inc Multimodale ethylen-, alpha-olefin- und dien-polymere, verfahren zu ihrer herstellung und vorrichtungen, die derartige zusammensetzungen enthalten
AU2003249337A1 (en) 2002-06-19 2004-01-06 Exxonmobil Chemical Patents, Inc. Ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene and polymers made using such processes
CN101724110B (zh) 2002-10-15 2013-03-27 埃克森美孚化学专利公司 用于烯烃聚合的多催化剂体系和由其生产的聚合物
US20050176890A1 (en) * 2003-01-23 2005-08-11 Sadahiko Matsuura Process for producing ethylene /alpha-olefin/unconjugated polyene copolymer, and ethylene/alpha-olefin/unconjugated polyene copolymer
JP4928944B2 (ja) * 2003-06-10 2012-05-09 ダウ グローバル テクノロジーズ エルエルシー エチレンポリマーブレンドから製造されたフィルム層
EP1905807B1 (de) 2003-08-19 2010-01-20 Dow Global Technologies Inc. Interpolymere zur Verwendung für Schmelzklebstoffe und Verfahren zu ihrer Herstellung
US7084319B2 (en) 2003-12-05 2006-08-01 Exxonmobil Chemical Patents Inc. Catalyst fluidization in oxygenate to olefin reaction systems
WO2005090425A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
US7951882B2 (en) 2004-03-17 2011-05-31 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
TW200536870A (en) 2004-03-17 2005-11-16 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
GB0420396D0 (en) 2004-09-14 2004-10-13 Bp Chem Int Ltd Polyolefins
ATE517944T1 (de) * 2004-10-13 2011-08-15 Exxonmobil Chem Patents Inc Elastomere reaktorblendzusammensetzungen
KR100586922B1 (ko) 2004-11-18 2006-06-08 금호폴리켐 주식회사 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법
ATE502093T1 (de) * 2004-12-21 2011-04-15 Dow Global Technologies Inc Klebstoffzusammensetzung auf polypropylenbasis
EP1674490A1 (de) * 2004-12-23 2006-06-28 Borealis Technology Oy Copolymer
WO2006083515A1 (en) * 2005-01-31 2006-08-10 Exxonmobil Chemical Patents Inc. Polymer blends and pellets and methods of producing same
EP2894176B1 (de) * 2005-03-17 2022-06-01 Dow Global Technologies LLC Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
JP2008533276A (ja) 2005-03-17 2008-08-21 ダウ グローバル テクノロジーズ インコーポレイティド タクチック／アタクチックマルチブロックコポリマー形成用の可逆的移動剤を含む触媒組成物
ZA200707880B (en) 2005-03-17 2009-09-30 Dow Global Technologies Inc Filled polymer compositions made from interpolymers of ethylene/alpha-olefins and uses thereof
WO2006138052A1 (en) 2005-06-13 2006-12-28 Exxonmobil Chemical Patents Inc. Thermoplastic blend compositions
BR122017016853B1 (pt) * 2005-09-15 2018-05-15 Dow Global Technologies Inc. Processo para a polimerização de um ou mais monômeros polimerizáveis por adição
EP1940896B1 (de) 2005-09-15 2014-10-22 Dow Global Technologies LLC Katalytische olefinblockcopolymere mit hilfe eines polymerisierbaren shuttling-mittels
DK1999168T3 (da) * 2006-03-30 2012-02-20 Total Petrochemicals Res Feluy Fremgangsmåde til fremstilling af ethylenpolymerer ved anvendelse af en række serieforbundne reaktorer
US7744746B2 (en) 2006-03-31 2010-06-29 Exxonmobil Research And Engineering Company FCC catalyst stripper configuration
CN101395250B (zh) 2006-03-31 2013-06-05 埃克森美孚化学专利公司 气-固反应器中的产物回收
CN114805690A (zh) 2006-06-15 2022-07-29 陶氏环球技术有限责任公司 官能化烯烃共聚体、组合物和由其制成的制品及其制法
US8785531B2 (en) * 2006-07-06 2014-07-22 Dow Global Technologies Llc Dispersions of olefin block copolymers
WO2008033343A2 (en) 2006-09-11 2008-03-20 Dow Global Technologies Inc. Polyolefin dispersion technology used for resin coated sand
US8476326B2 (en) * 2006-09-22 2013-07-02 Dow Global Technologies Llc Fibrillated polyolefin foam
NZ578429A (en) * 2007-01-17 2011-12-22 Dow Agrosciences Llc Delivery of ethylene blocking and/or promoting agents
KR20100063004A (ko) 2007-07-16 2010-06-10 다우 글로벌 테크놀로지스 인크. 관능화 중합체, 이로부터 제조된 물품, 및 그 제조방법
CA2598957C (en) 2007-08-27 2014-07-15 Nova Chemicals Corporation Process for high temperature solution polymerization
US8431096B2 (en) 2007-08-27 2013-04-30 Nova Chemicals (International) S.A Process for high temperature solution polymerization
CA2598960C (en) 2007-08-27 2015-04-07 Nova Chemicals Corporation High temperature process for solution polymerization
BRPI0816027B1 (pt) * 2007-09-24 2019-05-28 Dow Global Technologies Inc. Superfície de gramado sintético
EP2543763A3 (de) 2007-09-28 2013-10-30 Dow Global Technologies LLC Faserstruktur impregniert mit Dispersion aus Olefin mit höherer Kristallinität
WO2009055275A2 (en) * 2007-10-25 2009-04-30 Dow Global Technologies Inc. Polyolefin dispersion technology used for porous substrates
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
BRPI0819478B1 (pt) * 2007-12-28 2019-04-24 Dow Global Technologies Inc. Espuma reticulada, método para formar uma espuma reticulada, tufo artificial e sapato
FR2934599B1 (fr) * 2008-07-29 2012-12-21 Arkema France Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations
DE102008039218A1 (de) 2008-08-22 2010-02-25 Woco Industrietechnik Gmbh Vulkanisierbare Kautschukmischungen sowie Elastomerformteile, erhältlich aus diesen Kautschukmischungen
EP2328938B1 (de) * 2008-09-23 2015-04-01 Dow Global Technologies LLC Radikalisch funktionalisiertes polymer auf olefinbasis mit verringerter molekulargewichtsänderung und verfahren
US8969481B2 (en) 2008-12-18 2015-03-03 Exxonmobil Chemical Patent Inc. Peroxide cured TPV
MX2011010291A (es) 2009-03-31 2011-10-11 Dow Global Technologies Llc Pelicula elaborada a partir de interpolimero de etileno heterogeneo/alfa-olefina.
US20100311927A1 (en) 2009-06-05 2010-12-09 Dow Global Technologies Inc. Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene
US8722817B2 (en) * 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
CN102481770B (zh) 2009-07-01 2016-12-21 陶氏环球技术有限责任公司 乙烯类聚合物及其用途
US8389086B2 (en) 2009-07-01 2013-03-05 Dow Global Technologies Llc Composition for stretch hood, method of producing the same, and articles made therefrom
KR101262305B1 (ko) 2009-07-01 2013-05-08 주식회사 엘지화학 전이금속 촉매를 이용한 탄성 중합체의 제조방법
US8629214B2 (en) 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
EP2448979B1 (de) 2009-07-01 2013-05-01 Dow Global Technologies LLC Ethylenpolymer und seine verwendung
US8829115B2 (en) 2009-07-01 2014-09-09 Dow Global Technologies Llc Ethylene-based polymer composition
US8173232B2 (en) * 2009-07-01 2012-05-08 Dow Global Technologies Llc Stretch hood films
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
KR101741857B1 (ko) 2009-07-15 2017-05-30 다우 글로벌 테크놀로지스 엘엘씨 중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품
WO2011016991A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Dual- or multi-headed chain shuttling agents and their use for the preparation of block copolymers
SG179054A1 (en) 2009-09-14 2012-04-27 Dow Global Technologies Llc Polymers comprising units derived from ethylene and polyalkene
WO2011032172A1 (en) 2009-09-14 2011-03-17 Dow Global Technologies Inc. Polymers comprising units derived from ethylene and siloxane
JP5766702B2 (ja) 2009-09-14 2015-08-19 ダウ グローバル テクノロジーズ エルエルシー エチレン及びポリ（アルコキシド）由来の単位を含むポリマー
US9546446B2 (en) 2009-10-23 2017-01-17 Toyo Boseki Kabushiki Kaisha Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove
CN101734996B (zh) * 2009-12-29 2012-12-19 岳阳昌德化工实业有限公司 一种对含4-乙烯基环己烯的废液回收和利用方法
US20110172354A1 (en) * 2010-01-04 2011-07-14 Dow Global Technologies Inc. Ethylene-based polymer compositions for use in fiber applications
US8653196B2 (en) 2010-01-11 2014-02-18 Dow Global Technologies, Llc Method for preparing polyethylene with high melt strength
CN105348417B (zh) 2010-01-14 2019-03-01 埃克森美孚化学专利公司 连续溶液聚合的方法和设备
MX2012008189A (es) 2010-01-14 2013-02-27 List Holding Ag Desvolatilizador al vacio.
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
US8372924B2 (en) 2010-01-14 2013-02-12 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
US20130206224A1 (en) 2010-06-04 2013-08-15 Dow Global Technologies Llc Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Adhesive Property Enhancing Graft Polymer
BR112012030650A2 (pt) 2010-06-04 2016-08-16 Dow Global Technologies Llc módulo de dispositivo eletrônico compreendendo película de copolímero de poliolefina homogêneo e silano enxertado
MX355375B (es) 2010-06-14 2018-04-17 Dow Global Tech Llc Star Composiciones de polímero a base de etileno para utilizarse como un componente de combinación en aplicaciones de película de contracción.
EP2585292A1 (de) 2010-06-24 2013-05-01 Dow Global Technologies LLC Elektronisches gerätemodul mit einem heterogenen polyolefincopolymer und einem optionalen silan
EP2591060B1 (de) 2010-07-09 2016-12-21 Luna Innovations Incorporated Beschichtungssystem zur formung sehr langlebiger umgebungsgehärteter und wasserabweisender beschichtungen auf substraten
US8907034B2 (en) 2010-09-30 2014-12-09 Dow Global Technologies Llc Comb architecture olefin block copolymers
ES2530861T3 (es) 2010-10-29 2015-03-06 Dow Global Technologies Llc Polímeros basados en etileno y procedimientos para los mismos
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
US8877880B2 (en) 2010-11-17 2014-11-04 Exxonmobil Chemical Patents Inc. Method for controlling polyolefin properties
KR101869997B1 (ko) 2010-12-03 2018-06-22 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-기재 중합체 조성물의 제조 방법
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
WO2012082393A1 (en) 2010-12-17 2012-06-21 Dow Global Technologies Llc Ethylene-based polymers and processess to make the same
BR112013016788B1 (pt) 2010-12-30 2021-02-02 Dow Global Technologies Llc composição granulada e composição reticulada
WO2013003541A1 (en) 2011-06-30 2013-01-03 Dow Global Technologies Llc Multilayered polyolefin-based films having a layer comprising a crystalline block copolymer composite or a block copolymer composite resin
CN103781806B (zh) 2011-07-05 2017-06-23 陶氏环球技术有限责任公司 基于乙烯的聚合物和制备它的方法
MX352266B (es) * 2011-09-14 2017-11-16 Materia Inc Mejora de las cubiertas de celdas electrolíticas que comprende una composición de resina polimerizada con un catalizador de metátesis de olefina del grupo 8.
US9969907B2 (en) 2011-09-30 2018-05-15 Dow Global Technologies Llc Controlled peel laminate adhesive films
JP6189325B2 (ja) 2011-12-20 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法
BR112014015135A2 (pt) 2011-12-22 2017-06-13 Dow Global Technologies Llc polímero baseado em etileno, composição, artigo e processo para preparar o polímero baseado em etileno
US8552117B1 (en) 2012-06-13 2013-10-08 Teknor Apex Company Sealing elements and sealing element compositions
US10370524B2 (en) 2012-06-29 2019-08-06 Dow Global Technologies Llc Ethylene/alpha-olefin/nonconjugated polyene based compositions for thermoplastic vulcanizates
WO2014028211A1 (en) * 2012-08-16 2014-02-20 Exxonmobil Chemical Patents Inc. Long chain branched epdm compositions and processes for production thereof
US8796408B2 (en) * 2012-08-31 2014-08-05 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers
WO2014051675A1 (en) 2012-09-28 2014-04-03 Dow Global Technologies Llc Ethylene-based polymers and processes to make the same
KR102037561B1 (ko) 2012-09-28 2019-10-28 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-기재 중합체 및 그의 제조 방법
KR101391692B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
CN104812783B (zh) 2012-11-30 2021-07-16 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯基组合物
JP6408481B2 (ja) 2012-11-30 2018-10-17 ダウ グローバル テクノロジーズ エルエルシー エチレン／αオレフィン／非共役ポリエン系組成物およびそれから形成される発泡体
EP2938685B1 (de) 2012-12-28 2019-01-30 Dow Global Technologies LLC Ethylenbasierte polymere und verfahren zur herstellung davon
KR20140144076A (ko) 2013-06-10 2014-12-18 주식회사 엘지화학 3원계 탄성 공중합체의 제조 방법
EP2883891A4 (de) 2013-06-28 2016-06-01 Lg Chemical Ltd Ternäres elastomeres copolymer mit einem dien und verfahren zur herstellung davon
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
KR101585206B1 (ko) 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
US9428600B2 (en) 2013-06-28 2016-08-30 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
KR102284307B1 (ko) 2013-12-26 2021-08-04 다우 글로벌 테크놀로지스 엘엘씨 비대칭 폴리엔을 이용하여 에틸렌계 중합체의 제조를 위한 반응기 안정성을 개선하는 방법
SG11201605091RA (en) 2013-12-26 2016-07-28 Dow Global Technologies Llc Processes to form ethylene-based polymers using asymmetrical polyenes
US9944733B2 (en) 2013-12-26 2018-04-17 Dow Global Technologies Llc Ethylene-based polymers formed using asymmetrical polyenes
KR101791810B1 (ko) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌 프로필렌 공중합체의 제조 방법
KR101655392B1 (ko) 2014-04-21 2016-09-07 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101660480B1 (ko) 2014-04-25 2016-09-27 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
CN106463556B (zh) 2014-06-24 2020-04-21 陶氏环球技术有限责任公司 包含有机粘土的光伏模块
ES2743478T3 (es) 2014-06-24 2020-02-19 Dow Global Technologies Llc Lámina posterior fotovoltaica de poliolefina que comprende una capa de polipropileno estabilizado
US20170152377A1 (en) 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
MX2016017045A (es) 2014-06-27 2017-05-12 Dow Global Technologies Llc Polimeros a base de etileno que comprenden unidades derivadas de monoxido de carbono y un agente de modificacion de reologia.
EP3160730A1 (de) 2014-06-30 2017-05-03 Dow Global Technologies LLC Gebänderte mehrschichtfolie
MX2017006887A (es) 2014-12-01 2017-09-01 Dow Global Technologies Llc Composiciones poliméricas, películas contraíbles, y métodos de fabricación de las mismas.
WO2016105454A1 (en) 2014-12-23 2016-06-30 Dow Global Technologies Llc Ethylene-based interpolymers and composition comprising the same
CN107108792B (zh) 2014-12-29 2021-07-16 陶氏环球技术有限责任公司 用于形成含有油的乙烯类聚合物的方法
JP6752794B2 (ja) 2014-12-29 2020-09-09 ダウ グローバル テクノロジーズ エルエルシー エチレン／アルファ−オレフィンインターポリマーを形成する方法
SG11201705241QA (en) 2014-12-30 2017-07-28 Dow Global Technologies Llc Process to control output and quality of ethylene-based polymer formed by high pressure free radical polymerization
US10450394B2 (en) 2015-03-31 2019-10-22 Dow Global Technologies Llc Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching
WO2016176821A1 (en) * 2015-05-05 2016-11-10 Dow Global Technologies Llc Functionalized, halogenated olefin-based adhesive, articles containing and process for using thereof
FR3037586A1 (fr) 2015-06-17 2016-12-23 Michelin & Cie Procede de polymerisation continu d'elastomere dienique
WO2016204949A1 (en) 2015-06-17 2016-12-22 Dow Global Technologies Llc Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent
ES2772829T3 (es) 2015-06-22 2020-07-08 Dow Global Technologies Llc Proceso para obtener polímeros basados en etileno usando iniciadores de radicales libres carbono-carbono
KR102575869B1 (ko) 2015-06-24 2023-09-08 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융-강도를 갖는 에틸렌계 폴리머를 제조하는 방법
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
WO2017040089A1 (en) 2015-09-02 2017-03-09 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
JP6804519B6 (ja) 2015-09-02 2021-01-20 ダウ グローバル テクノロジーズ エルエルシー 可撓性架橋ケーブル絶縁体、及び可撓性架橋ケーブル絶縁体を作製するための方法
WO2017048448A1 (en) 2015-09-14 2017-03-23 Exxonmobil Chemical Patents Inc. Process for making branched epdm and epdm therefrom
CA3003170C (en) 2015-10-29 2023-09-12 Dow Global Technologies Llc Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
EP3168237A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Radikalische hochdruckpolymerisierung zur herstellung von ethylenbasierten polymeren
EP3168238A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Mittels hochdruckradikalpolymerisation hergestellte ethylenbasierte polymere
EP3168239A1 (de) 2015-11-10 2017-05-17 Dow Global Technologies LLC Hochdruckfreie radikalpolymerisation
EP3397665B2 (de) 2015-12-29 2023-11-08 Dow Global Technologies LLC Hochgepropfte polymere auf ethylenbasis, hochgepropfte polymerzusammensetzungen auf ethylenbasis und verfahren zur formung davon
JP6997713B2 (ja) 2016-02-23 2022-02-04 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびこれを製造する方法
JP2019515063A (ja) 2016-04-29 2019-06-06 ダウ グローバル テクノロジーズ エルエルシー エチレン一酸化炭素コポリマーを含む組成物
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
CN107474194B (zh) * 2016-06-08 2022-03-18 中国石油化工股份有限公司 一种高分子聚合物材料的制造方法
US11981802B2 (en) 2016-06-30 2024-05-14 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
JP7090562B2 (ja) 2016-06-30 2022-06-24 ダウ グローバル テクノロジーズ エルエルシー エチレン／α－オレフィン／ポリエンインターポリマーおよびそれを含有する組成物
JP7123044B2 (ja) 2016-12-16 2022-08-22 ダウ グローバル テクノロジーズ エルエルシー エチレン／α－オレフィンインターポリマー組成物
ES2893526T3 (es) 2017-02-28 2022-02-09 Dow Global Technologies Llc Polímeros basados en etileno con buena aptitud de procesado para uso en películas multicapa
KR102551637B1 (ko) 2017-06-02 2023-07-06 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체 및 이의 제조
US11345797B2 (en) 2017-08-24 2022-05-31 Dow Global Technologies Llc Ethylene/C5-C10 alpha-olefin/ polyene interpolymers
ES2965047T3 (es) 2017-10-31 2024-04-10 Dow Global Technologies Llc Interpolímeros de etileno/co y procesos para fabricar los mismos
EP3480220A1 (de) * 2017-11-06 2019-05-08 Borealis AG Kombinierte sequentielle parallele reaktorkonfiguration
KR101918484B1 (ko) 2017-11-15 2019-01-31 금호폴리켐 주식회사 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법
US11041034B2 (en) 2018-02-09 2021-06-22 Exxonmobil Chemical Patents Inc. Ethylene-a-olefin-diene elastomers and methods of making them
US11753521B2 (en) 2018-02-14 2023-09-12 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved continuous high temperature resistance
US11970602B2 (en) 2018-02-14 2024-04-30 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
US11623982B2 (en) 2018-02-14 2023-04-11 Dow Global Technologies Llc Ethylene/alpha olefin interpolymer compositions with improved continuous high temperature resistance
WO2019205081A1 (en) 2018-04-27 2019-10-31 Dow Global Technologies Llc Phosphate enhanced, heat resistant ethylene/alpha-olefin interpolymer compositions
JP7419269B2 (ja) 2018-06-15 2024-01-22 ダウ グローバル テクノロジーズ エルエルシー 高分子量高密度画分を有する二峰性エチレン系ポリマーを含むインフレーションフィルム
JP7406513B2 (ja) 2018-06-15 2023-12-27 ダウ グローバル テクノロジーズ エルエルシー 高分子量高密度画分を有するバイモーダルエチレン系ポリマーの生成プロセス
US11873393B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
BR112020025383A2 (pt) 2018-06-15 2021-03-09 Dow Global Technologies Llc Filme fundido, e, estrutura de filme fundido em camadas
US11891463B2 (en) 2018-06-28 2024-02-06 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and thermal stability
WO2020140058A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
EP3902871A4 (de) 2018-12-28 2022-09-21 Dow Global Technologies LLC Härtbare zusammensetzungen mit ungesättigten polyolefinen
JP2022516119A (ja) 2018-12-28 2022-02-24 ダウ グローバル テクノロジーズ エルエルシー テレケリックポリオレフィンを含む硬化性組成物
WO2020140067A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
JP2022534898A (ja) 2019-05-31 2022-08-04 ダウ グローバル テクノロジーズ エルエルシー 加工性を向上させた低密度ポリエチレン
EP4034578A1 (de) 2019-09-24 2022-08-03 Dow Global Technologies LLC Polymerzusammensetzungen für extrudierte profile
EP4034597A1 (de) 2019-09-24 2022-08-03 Dow Global Technologies LLC Ethylen/alpha-olefin/polyenzusammensetzungen
BR112022019446A2 (pt) 2020-04-06 2022-12-13 Dow Global Technologies Llc Homopolímero de polietileno de baixa densidade, filme, e, filme fundido soprado ou termoformado
MX2023004316A (es) 2020-10-14 2023-05-04 Dow Global Technologies Llc Composiciones de polietileno aptas para su uso en peliculas estirables fundidas.
WO2024157121A1 (en) 2023-01-26 2024-08-02 Nova Chemicals (International) S.A. Devolatilization of polyolefin polymers

Family Cites Families (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US4200722A (en) 1971-09-24 1980-04-29 Stamicarbon, B.V. Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack
US4184027A (en) 1971-10-26 1980-01-15 Monsanto Company Recycle control system for continuous polymerization
US4102761A (en) 1974-01-03 1978-07-25 The Firestone Tire & Rubber Company Radiation cure of synthetic rubbers
JPS5111882A (en) 1974-07-20 1976-01-30 Sumitomo Chemical Co Mihannotanryotaio jokyosuruhoho
FR2297713A1 (fr) 1975-01-17 1976-08-13 Telecommunications Sa Procede d'introduction
FR2322883A1 (fr) 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
JPS52141888A (en) 1976-05-21 1977-11-26 Nippon I P Rubber Kk Ethyleneepropylene copolymers rubber
US4075287A (en) 1976-10-27 1978-02-21 Phillips Petroleum Company Separation process
DE2735355A1 (de) 1977-08-05 1979-02-15 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des aethylens
US4182810A (en) 1978-04-21 1980-01-08 Phillips Petroleum Company Prevention of fouling in polymerization reactors
JPS5948046B2 (ja) 1978-08-17 1984-11-24 三井化学株式会社 エチレン共重合ゴム
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
JPS587402A (ja) 1981-07-07 1983-01-17 Mitsui Petrochem Ind Ltd 重合方法
US4792595A (en) 1983-06-15 1988-12-20 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4722971A (en) 1985-08-02 1988-02-02 Exxon Chemical Patents Inc. Easy processing ethylene propylene elastomers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5084534A (en) 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
EP0275925B1 (de) 1987-01-19 1995-04-05 Sumitomo Chemical Company, Limited Elastische Copolymere aus Äthylen, Propylen und einem nichtconjugiertem Dien und Verwendung davon
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5264405A (en) 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US4804794A (en) 1987-07-13 1989-02-14 Exxon Chemical Patents Inc. Viscosity modifier polymers
JP2573613B2 (ja) 1987-08-14 1997-01-22 三菱化学株式会社 エチレンの重合法
US5147949A (en) 1988-03-29 1992-09-15 Exxon Chemical Patents Inc. Polymerization process using a silica gel supported metallocene-alumoxane catalyst
US5231106A (en) 1988-05-18 1993-07-27 Novo Nordisk A/S Azacyclic carboxylic acid derivatives and their preparation and use
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
CA1327673C (en) 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA2034759C (en) 1988-08-01 2003-06-03 Won R. Song Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives
US5229022A (en) 1988-08-01 1993-07-20 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920)
HUT54722A (en) * 1988-09-30 1991-03-28 Exxon Chemical Patents Inc Linear ethylene interpolymer mixtures
US5017665A (en) 1989-07-25 1991-05-21 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin and 1,4-diolefin copolymerization
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2807502B2 (ja) 1989-10-05 1998-10-08 三井化学株式会社 エチレン―プロピレン―ジエン系ゴム、エラストマー組成物およびその加硫ゴム
FR2654108B1 (fr) 1989-11-08 1993-08-20 Norsolor Sa Nouveaux caoutchoucs polyolefiniques et leur procede de preparation.
US5519091A (en) 1990-02-13 1996-05-21 Mitsui Petrochemical Industries, Ltd. Method for the preparation of ethylene polymer compositions
US5149318A (en) 1990-03-14 1992-09-22 Minnesota Mining And Manufacturing Company Quick-changeover blood handling apparatus
MY107639A (en) 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
CA2060019A1 (en) 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
JP2894858B2 (ja) 1991-04-05 1999-05-24 三井化学株式会社 エチレン・α−オレフィン・ジエン系ゴムおよびその用途
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
GB9125934D0 (en) 1991-12-05 1992-02-05 Exxon Chemical Patents Inc Process for polymerising olefinic feeds under pressure
KR100253826B1 (ko) 1991-12-30 2000-04-15 그레이스 스티븐 에스. 에틸렌 공중합체의 중합방법
ES2111656T3 (es) 1992-01-06 1998-03-16 Dow Chemical Co Composicion de catalizador mejorada.
EP0552945B1 (de) 1992-01-23 1997-05-07 Mitsui Petrochemical Industries, Ltd. Verfahren zur Herstellung eines Polyolefins
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
BE1005795A3 (fr) * 1992-05-13 1994-02-01 Solvay Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine.
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
WO1993025590A1 (en) 1992-06-15 1993-12-23 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
DE69317566T2 (de) 1992-06-18 1998-09-24 Montell Technology Co. B.V., Hoofddorp Verfahren zur herstellung eines ethylenischen copolymerisats
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
CA2103380C (en) * 1992-11-19 2002-07-02 Mitsui Chemicals, Inc. Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
JP2986547B2 (ja) 1993-01-29 1999-12-06 ザ・ダウ・ケミカル・カンパニー エチレン共重合
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
WO1995000526A1 (en) 1993-06-24 1995-01-05 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
WO1995016716A1 (en) 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
ES2117829T3 (es) 1994-02-17 1998-08-16 Union Carbide Chem Plastic Composicion de catalizador de metaloceno cargada y secada por pulverizacion, utilizada en la fabricacion de poliolefinas.
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
DE4432798A1 (de) 1994-09-15 1996-03-21 Basf Ag Hochflexible Propylen-Ethylen-Copolymerisate
US5677382A (en) 1994-12-19 1997-10-14 Japan Synthetic Rubber Co., Ltd. Ethylene-α-olefin-non-conjugated diene copolymer rubber composition
TW383314B (en) 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
EP0743066A3 (de) 1995-05-16 1998-09-30 Mitsui Pharmaceuticals, Inc. Wundheilmittel

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EP0910593A1 (de) 1999-04-28
BR9710347A (pt) 1999-08-17
DE69704617D1 (de) 2001-05-23
US6545088B1 (en) 2003-04-08
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TW341576B (en) 1998-10-01
HUP9904354A2 (hu) 2000-04-28
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CA2256668A1 (en) 1998-01-22
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EP0910593B1 (de) 2001-04-18
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NO990095D0 (no) 1999-01-11

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