WO2014079135A1 - 餐厨垃圾全方位处理的集成化装备及产物制造方法 - Google Patents

餐厨垃圾全方位处理的集成化装备及产物制造方法 Download PDF

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Publication number
WO2014079135A1
WO2014079135A1 PCT/CN2013/000146 CN2013000146W WO2014079135A1 WO 2014079135 A1 WO2014079135 A1 WO 2014079135A1 CN 2013000146 W CN2013000146 W CN 2013000146W WO 2014079135 A1 WO2014079135 A1 WO 2014079135A1
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WO
WIPO (PCT)
Prior art keywords
water
kitchen waste
oil
air
treatment system
Prior art date
Application number
PCT/CN2013/000146
Other languages
English (en)
French (fr)
Inventor
许文姬
李国声
李汉声
李振声
Original Assignee
华南再生资源(中山)有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 华南再生资源(中山)有限公司 filed Critical 华南再生资源(中山)有限公司
Priority to RU2015123832A priority Critical patent/RU2015123832A/ru
Priority to SG11201503980RA priority patent/SG11201503980RA/en
Priority to KR1020157013923A priority patent/KR20150105299A/ko
Publication of WO2014079135A1 publication Critical patent/WO2014079135A1/zh

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/48Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the invention discloses an integrated equipment for omnidirectional treatment of kitchen waste and a product manufacturing method thereof.
  • the invention belongs to the technical field of comprehensive treatment of domestic garbage, and relates to an integrated device and a manufacturing method, a recipe and a process for the waste processing of a kitchen waste, and at the same time Involved in microbiology, biochemistry, equipment manufacturing, optoelectronics, ozone applications, functional plastics, plastic reversal engineering, clean coal, mineral fuel manufacturing, biomass fuel manufacturing, cleaner production, air purification, sewage treatment and many other technical fields.
  • the science and technology of waste resource utilization after a long period of application, has proved that if the waste recycling technology is applied in a single application, the consequences will bring greater crisis to the human living environment, especially The serious problem of secondary pollution is difficult to control, so the comprehensive treatment of waste has become the current development trend.
  • the composition of kitchen waste is extremely complicated, including sewage, plastic bags, plastic bottles, waste cloth strips, spoilage organic matter, paper, metal bottles, broken glass, broken ceramic sheets, animal fats, vegetable oils, primary bacteria and other substances. .
  • the kitchen waste resource treatment technology has presented a “hundred flowers” situation in the domestic and foreign methods and processes, but basically it is a simple single item treatment, and there is no international environmental treatment that shifts from simple treatment to comprehensive treatment, utilization and disposal.
  • the trend and direction may cause the inevitable attachments in the kitchen waste to be transferred and randomly filled, causing water and soil pollution, or transfer, not only blocking the city's sewer pipes, but also emitting a foul smell and causing serious secondary pollution.
  • the single treatment process of kitchen waste is feasible from the perspective of resource utilization value. However, considering the comprehensive protection of the global environment, people's livability and protection of the atmospheric environment, it may still do more harm than good.
  • the present invention provides a large-scale highly integrated kitchen waste comprehensive processing equipment and application mode and production The process and formula are in line with the current international development direction of the residue after the waste resource treatment.
  • a comprehensive kitchen and garbage processing system the system includes a kitchen garbage bag breaking device, a kitchen garbage combined screening device, a wet advanced oxidation deodorizing inactivation cleaning salt reducing device , vertical dewatering device, material crusher and automatic control device, the kitchen waste is put into the kitchen garbage bag breaking device for bag breaking treatment, and then input into the kitchen garbage combined screening device for joint screening, and the filtered oil-water solid mixture is input.
  • the wet-type advanced oxidation and deodorization inactivation cleaning and salt-reducing device is inactivated, and the kitchen waste which has been deactivated and dehydrated by wet advanced oxidation is sent to the dehydration device by the screw conveying pipeline, and dehydrated by the dehydration device.
  • the material is input into the material crusher for pulverization, and the automatic control device controls the operation of other devices.
  • a method for producing a transformant using the above-described kitchen waste comprehensive treatment system comprising the following steps
  • the material after dehydration is pulverized by a material crusher.
  • the cutting device comprises a horizontal cylindrical casing, one end of the casing is a discharge port, and the outer casing is provided with one or more cutters on one end of the discharge port, and the other end of the casing is arranged to slide along the inner cavity of the casing.
  • the piston is connected with a power tool for pushing the piston, and a sipe is arranged on the piston corresponding to each tool position, and a feed port is opened at the middle of the top of the casing.
  • the bottom of the piston is mounted with a pulley, and the bottom of the inner wall of the outer casing is fixedly provided with a concave sliding rail corresponding to the position of the pulley, and the pulley can slide back and forth on the concave sliding rail.
  • a collecting box is arranged at the position of the feeding port, the upper part of the collecting box is funnel-shaped, the lower part is connected with the feeding port on the outer casing through the blanking pipe, and the pneumatic sliding gate valve is arranged on the discharging pipe.
  • a rolling cleat is mounted on the outlet of the casing, and the motor drives the rolling cleat to rotate.
  • the rolling cleat is square or polygonal and is provided with an inner cavity.
  • the rolling clapper plate is provided with more than one compressed air ejection slot on each surface, and the rolling clapper plate is provided with a compressed air air guiding tube and a gas injection nozzle, and the gas injection nozzle is connected to the compressed air air guiding tube, and the jet direction of the gas injection nozzle The same direction as the discharge of the discharge port.
  • the compressed air injection slots are arranged in parallel.
  • the blade of the tool has a 90 degree angle to the cross section of the housing discharge opening or a 30 degree angle to the inner wall of the outer casing.
  • the kitchen and kitchen garbage combined screening system comprises a casing, wherein the casing is provided with a partition plate, and the inside of the casing is divided into an air floating zone and a non-air floating zone through a partition plate, and the partition plate is provided with a material leakage outlet, the gas
  • a feeding port at the floating area a heavy material discharging outlet at the lower part of the air floating area, a valve at the heavy material discharging outlet, one or more air nozzles around the heavy material discharging outlet, and a tumbler on the upper part of the air floating area
  • a material output device in the non-air floating area one end of the material output device is arranged in the casing, the other end is arranged outside the casing, the material output device is provided with auger, the material output device is equipped with a motor and a transmission, and the motor is matched with The transmission drives the auger to rotate.
  • the material leakage outlet is provided with a louver guide groove, the louver guide groove is connected to the pneumatic propulsion rod, the pneumatic device drives the propulsion rod movement, and the propulsion rod controls the opening and closing of the louver guide groove.
  • the roller is provided with two, two rollers are arranged one above the other, and the lower roller is 1/2 The position is set in the liquid level of the air floating zone, and the upper roller is disposed above the liquid level of the air floating zone, and the two rollers are engaged with each other.
  • a rolling motor is mounted on the casing, and the rolling motor simultaneously drives the two rollers to rotate.
  • a transmission is mounted at the material outputter, and the motor drives the auger to rotate through the transmission.
  • a liquid level automatic control device for controlling the liquid level is installed at the air floating area.
  • the casing is provided with a pipe for conveying kitchen waste into the casing, and the pipe is connected to the water inlet pipe.
  • the circulating water inlet of the air floating zone is connected with a hydraulic pressure pump, the water source is provided by the circulating water storage tank, and the water outlet is provided in the middle and lower part of the non-air floating zone, and the water body is input into the circulating water storage tank through the water pump for the gas
  • the circulation of the water in the floating zone and the non-air-floating zone and the strengthening of the water in the air-floating zone are strongly tumbling.
  • the kitchen waste oxidation, deodorization, inactivation, cleaning and salt reduction device comprises more than one reactor and a gas, water and material mixer for ozone-water-material mixing, and the mixer is connected with waterproofing.
  • One-way valve, one end of the waterproof check valve is connected to the gas pipe, and then connected to the ozone generating device.
  • the mixer is also connected with a high-viscosity cam rotor pump outlet.
  • the outlet of the mixer extends into a reactor, and the high-viscosity cam rotor pump
  • the inlet is connected to another reactor, and more than one granular activated carbon reaction sphere is arranged in the reactor, granular activated carbon is arranged in the granular activated carbon reaction sphere, and a material outlet is arranged at the bottom of the reactor.
  • the total volume of the particulate activated carbon accounts for 15% to 98% of the volume of the granular activated carbon reaction sphere.
  • the top of the reactor is provided with an automatic exhaust valve, and an ozone destroyer is connected to the automatic exhaust valve.
  • the bottom of the reactor is provided with a semi-circular head, and the material outlet is arranged on the semi-circular head.
  • the front end of the reactor is provided with a beveled ribbon conveyor, and the reactor at the rear end is provided with a water level height regulating pipe.
  • a solid and liquid separator is connected to the material outlet.
  • the solid-liquid separator comprises a casing and a slanted mesh barrel, wherein the inclined mesh barrel is disposed in the outer casing, and the inclined mesh barrel is rotated by the motor in cooperation with the transmission, and the front end of the inclined mesh barrel is provided with more than one row.
  • the mesh hole and the inclined mesh barrel are provided with a spiral ribbon connected to the inner wall of the mesh barrel, and a water receiver is arranged at the bottom of the shell.
  • the spiral ribbon occupies the entire length of the inclined mesh barrel.
  • the outer casing is provided with a window.
  • the side of the reactor is equipped with a manhole.
  • the vertical dewatering device comprises a casing, a vertical inner leakage tower and a ribbon propulsion rod, the vertical inner leakage tower is arranged inside the outer casing, the spiral propulsion rod is arranged inside the vertical inner leakage tower, and the vertical inner leakage tower side
  • the bottom of the vertical inner leakage tower is provided with a feed inlet
  • the top of the vertical inner leakage tower is provided with a discharge port
  • the bottom of the outer casing is provided with a power source for driving the rotation of the propeller rod
  • the inside of the outer casing corresponds to
  • a water tank is arranged around the bottom of the vertical inner leakage tower, and a water outlet is connected to the water tank.
  • more than one water pipe is arranged around the vertical inner leakage tower, and more than one high pressure water recoil nozzle is connected to each water pipe.
  • the top of the vertical inner leak tower is provided with a shaft fixing plate for mounting a screw push rod.
  • the end of the ribbon on the ribbon push rod is provided with a sealing plate for adjusting the discharge speed.
  • the spacing of the ribbons on the ribbon push rod is gradually narrowed from the lower portion toward the top of the tower.
  • the pitch of the lower end of the ribbon on the ribbon push rod is 25 CM, and the distance between the terminals is 10 CM.
  • the power source includes a motor, a transmission, and a steering conversion device that converts the horizontal axial rotation into a vertical axial rotation.
  • the motor drives the transmission to rotate
  • the transmission drives the steering conversion device to rotate
  • the steering conversion device drives the ribbon push rod to rotate.
  • a stainless steel bearing sleeve is disposed in the outer casing.
  • More than one stainless steel vertical plate is arranged around the outer side of the vertical inner leakage tower, and more than one reinforcing ring sleeve is arranged around the stainless steel vertical plate, and each reinforcing circle is provided with a slope anti-backlash guiding flow.
  • the vertical inner leakage tower is composed of more than one tower body, each tower body is provided with a reinforcing flange at an upper and lower circumferential position, and the connection of adjacent tower bodies is abutment between the upper and lower flanges of the tower body, and Bolted, the upper flange of the joint flange position of each tower body is equipped with a bevel anti-backlash guide.
  • the biochemical fermentation device comprises an anaerobic fermentation tank and a main fermentation device
  • the main fermentation device comprises two sub-fermenters and more than one main fermenter, two sub-fermenters are arranged above the main fermenter, and the secondary fermentation
  • the ribbon agitator, the anaerobic fermentation tank is connected to the main fermenter, and the anaerobic fermentation tank feeds the material into the main fermenter through an automatic unloading system.
  • the double-layer ribbon agitator comprises a shaft body, an inner layer ribbon and an outer ribbon, the inner layer ribbon is disposed inside the outer layer ribbon, and the inner layer ribbon and the outer layer ribbon are spirally belt-shaped, and They are fixedly mounted on the shaft body respectively, and the inner spiral belt and the outer spiral belt have opposite spiral directions, and the double-sided ribbon stirrer is provided with a braided blade around the shaft body.
  • the mixing device is a main shaft in the middle, and more than one stirring blade is fixedly mounted on the central shaft.
  • the material of the anaerobic fermentation tank is provided with an automatically movable material agitator.
  • the automatic unloading multi-stage drying device comprises a pre-drying device and a main drying device, wherein the pre-drying device is installed above the main drying device, and the pre-drying device shell is on both sides, and the outer casing interlayer of the pre-drying device is formed between the two sides.
  • the pre-drying device is provided with an automatic material turning plate, and the central drying device is a horizontal cylindrical body capable of rotating 360 degrees in the reverse direction.
  • the front and rear ends of the main drying device are respectively fixed heads and horizontal cylindrical bodies.
  • the combustion chamber and the burner, the heat generated by the burner passes into the interior of the main drying device, and the exhaust gas of the main drying device is input into the inner cavity of the outer casing through the hot air discharge port, and the material output port of the pre-drying device corresponds to the innermost side of the main drying device.
  • Secondary cylinder setting
  • the bottom of the pre-drying device is provided with a screw auger automatic discharge device, and the screw auger automatic discharge device has a cylindrical shape, and a screw auger is arranged inside.
  • the top of the pre-drying device is provided with a drafting device.
  • the respective sub-cylinders are set together, and the material inlet of the outer sub-cylinder is longer than the material outlet of the inner sub-cylinder.
  • Airflow disturbing fins are fixedly mounted on the outer side walls of the respective sub-cylinders.
  • the horizontal cylindrical body and the guide spirals inside the respective secondary cylinders are opposite in direction.
  • the material selection device comprises a base, a metal rolling screen cylinder, a material carrier, an automatic conveying tool, a chain plate conveyor and a diverter shutter, the metal rolling screen cylinder is mounted on the base, and the material carrier is arranged on the metal rolling Below the screen cylinder, the automatic conveying tool is arranged under the material carrier, the front end of the metal rolling screen cylinder is provided with a mesh hole, the rear end is provided with a spiral belt, and the chain conveyor is arranged below the discharge opening of the metal rolling screen cylinder.
  • the splitter shutter is placed at the end of the chain conveyor.
  • the mesh hole diameter is 4 mm - 6 mm, and the interval between the hole and the hole is 2 mm.
  • the metal rolling screen cylinder is inclined, and the inclination angle is 1 degree - 20 degrees.
  • the diverter shutter is provided with an adjusting device for adjusting the height between the diverter shutter and the chain plate conveyor.
  • a protective cover is mounted on the outer side of the metal rolling screen cylinder.
  • the kitchen garbage combined screening device is provided with a plastic solid output end, and the plastic solid output end of the kitchen garbage combined screening device is connected with a waste plastic reverse engineering device.
  • the waste plastic reverse engineering device mainly swings the main processing device, and the main processing device feeds the material into the pneumatic automatic feeding machine by the conveyor belt, and feeds the material into the cracking catalytic horizontal reaction kettle through the pneumatic automatic feeding machine.
  • the reactor can be rotated 360 degrees and reversely.
  • the reactor is equipped with an automatic random scraping device.
  • the reactor is connected with a vacuum system.
  • the reactor is connected to the oil wax separator through a pipeline.
  • the oil wax separator is connected with a first-stage heavy oil separator through a pipeline, and the first-stage heavy oil separator is connected with a first-stage condenser through a pipeline, and the oil-bearing container is connected to the bottom of the first-stage condenser, after the first-stage condenser
  • the end is connected with a negative pressure device, the back end of the negative pressure device is connected with a vertical water-sealed gas safety conveyor, and the rear end of the vertical water-sealed gas safety conveyor is connected with a secondary gas compressor, a secondary gas compressor and a gas
  • the repository is connected.
  • the bottom of the reaction kettle is provided with a cracking furnace, and the gas outlet pipe of the cracking furnace is connected with the tail gas environmental protection equipment system.
  • the oil carrying container is connected with a carbon removal rinser and a dewaxing glue remover.
  • the system further includes a coarse carbon black processing device connected to the residual slag outlet of the waste plastic reversing engineering device.
  • the crude carbon black processing device comprises a crude carbon black artificial aging processor, the crude carbon black artificial aging processor is connected with the physical aging bed, and the physical aging bed is connected with the material matching device by an automatic conveying tool, and the material matching device
  • the liquid and solid automatic dosing feeding device is connected to the upper part, and the back end of the material matching device is provided with a multi-layer push-pull screw, and the back end of the multi-layer push-pull screw is connected with the low-sulfur high-energy environmentally-friendly clean coal forming machine.
  • the system further includes a distillation-free biodiesel production device, wherein each device separates the oil, water, and solid mixture through oil and water through a pipeline, and then feeds the distillation-free biodiesel production device.
  • the distillation-free biodiesel production system comprises a horizontal spiral belt solid-liquid separation device, an oil-water separation tower, an oil storage container, a grease colloid removal device, a bio-oil normal temperature grease exchange device, a liquid separation device and a filtration device, and a lying device.
  • the outlet of the spiral ribbon solid-liquid separation device is connected to the lower end of the oil-water separation tower through a pipeline, and the oil-water separation tower is provided with a heating pipeline, and the heating pipeline extends from the lower part of the oil-water separation tower to the inside of the oil-water separation tower, and then from the upper part of the oil-water separation tower
  • the output is output to the outside of the oil-water separation tower, and the oil-water separation tower is provided with an oil scraper at the top of the oil-water separation tower.
  • the oil-water separation tower is connected to the oil storage container through the oil-discharging pipeline, and the oil outlet pipeline inlet corresponds to the oil scraper setting, and the oil storage container passes through the pipeline and the grease colloid.
  • the device for removing the device is connected, and the grease colloid removal device is internally provided with a hole impact plate fixedly disposed, and the rotary hydraulic propeller is respectively installed at the corresponding positions on both sides of the impact plate, and the propeller blade of the rotary hydraulic propulsion machine is disposed at
  • the motor is arranged outside the grease gel removal device, the motor drives the propeller blade to rotate, and the grease gel removal device
  • the grease outlet is connected to the bio-oil normal temperature grease exchange device through the pipeline, and more than one ultrasonic generator is arranged in the bio-oil normal temperature grease exchange device, and the bio-oil normal temperature grease exchange device has a feed port at the top, and the bio-oil normal temperature
  • the bottom of the grease exchange device is connected to the liquid separation device through a pipeline, and the bottom of the liquid separation device is connected to the filtration device through an oil pipeline, and the filtration device outputs biodiesel.
  • the horizontal spiral belt solid-liquid separation device comprises a horizontal cylindrical outer casing, a filter mesh is arranged in the outer casing, a conveying screw is fixed inside the filter mesh, and the spiral belt driving motor cooperates with the transmission to drive the filter mesh and the spiral belt.
  • Rotating, horizontal spiral belt solid-liquid separation equipment is provided with an oil and water mixture output pipe at the bottom.
  • the top of the oil-water separation tower is equipped with an infrared water body liquid level locator.
  • the outer periphery of the ultrasonic generator is respectively provided with a sleeve, and an inner threaded jet hole is arranged around the sleeve, and a locking device is fixed on the sleeve, and the ultrasonic generator is installed in the bio-oil normal temperature grease exchange device through the locking device. .
  • the bio-oil normal temperature grease exchange device is provided with a liquid guiding tube, one end of the liquid guiding tube is connected to the upper part of the bio-oil normal temperature grease exchange device, and the other end is connected to the bottom of the bio-oil normal temperature fat exchange device, and the liquid guiding tube is connected Pump.
  • the bottom of the bio-oil normal temperature grease exchange device is provided with a gas pipe, and one end of the gas pipe is connected to the compressed air machine.
  • the system further includes an oil gel removal device, and the special oil pump inputs the bio-fat from the oil storage container into the grease gel removal device and then enters the grease exchange device.
  • the system also includes the manufacture of an emulsified biodiesel device, the bio-fat from the lipid exchange process being exported to an emulsified biodiesel device.
  • the emulsified biodiesel manufacturing device comprises a casing, a vertical agitator is arranged in the casing, the power source drives the vertical agitator to rotate, and the vertical agitator has more than one paddle type straight mixer or paddle folding on the central shaft of the vertical agitator.
  • the blade paddle and the lower part of the vertical shaft of the vertical agitator are equipped with a turbine or disc curved blade slurry, and the top of the casing is provided with more than one feeding port, and each feeding port is connected with a quantitative feeding device through a pipe, the casing
  • the lower part is provided with a finished product discharge port.
  • the upper part of the casing is cylindrical and the lower part is semicircular.
  • More than one liquid guide vane is mounted around the cylindrical inner wall of the housing.
  • a support frame for a rotating shaft supporting a vertical agitator is mounted on the bottom of the housing.
  • the power source includes a motor and a shifting device, the shifting device is fixedly mounted on the top of the housing, the motor is disposed above the shifting device, and the motor drives the vertical agitator to rotate through the shifting device.
  • the system also includes a rapid sewage treatment recycling device, and the sewage generated by each device is connected to the rapid sewage treatment recycling device through a pipeline.
  • the rapid sewage treatment and recycling device comprises a sewage filtration tank, a sewage barrier is arranged in the sewage filtration tank, and an anti-plug recoil is arranged in the debris barrier, and the sewage filtration tank is connected with the hot felt sewage treatment device through the water inlet pipe.
  • the hot felt sewage treatment equipment comprises an inner cavity and a casing, and the top of the casing is provided with a plurality of atomizing spray heads communicating with the inlet pipe, and a burning felt is arranged under the atomizing spray head, and a heat conducting oil pipe is arranged inside the burning felt.
  • the bottom of the hot felt is provided with a micro-solid sedimentation zone, and the bottom of the micro-solid sedimentation zone is provided with a sewage outlet, and an anti-fouling recoil baffle is arranged above the sewage outlet, and a high-temperature cushion for supporting the hot felt is arranged under the hot felt
  • the top of the casing is provided with an automatic suction and exhaust valve, and the casing is located above the hot felt with a hot steam collecting port, and the hot steam collecting port is connected to the heat exchanger through a pipe, and the rear end of the heat exchanger is connected with a collecting pool.
  • the pool is connected to the advanced oxidation system through the pipe section.
  • the advanced oxidation system has two inner and outer cavities, the inner cavity is a gas-water reaction cavity, the outer cavity is a gas-water circulation reaction buffer cavity, and the inner cavity inlet is introduced into the end of the pipe.
  • Activated carbon reaction ball activated carbon reaction ball is filled with granular activated carbon
  • the bottom of the inner cavity is provided with a sewage outlet
  • the sewage outlet is connected with the sewage outlet of the outer casing
  • the anti-backlash plate is also installed on the sewage outlet of the inner cavity
  • the advanced oxidation reactor passes
  • the circulating pipe is connected with a gas-water mixer, the gas-water mixer is a three-way connection, the circulating water is connected at both ends, and one port in the middle is connected with the waterproof one-way valve, and the other port of the waterproof one-way valve is connected to the ozone generator.
  • the gas pipeline, the advanced oxidation system is connected with a transfer tank, and the transfer tank is connected with an activated carbon filter fixed bed, the activated carbon filter fixed bed is connected with a composite filter device, and the composite filter device includes more than one filter tank.
  • Each filter column has a water outlet hole at half of the length of the filter column.
  • the bottom of the filter column is equipped with a filter screen of 80-140 mesh.
  • the top of the filter tank has a water inlet and
  • the pressurized tube and the filter tank are divided into two layers, and each layer of the tank is respectively provided with a filter column tray, and the filter column holder has an orifice matched with the diameter of the filter column, and the filter column is inserted in the filter column holder.
  • the upper side of the upper tank is provided with a water guiding pipe
  • the inlet guiding pipe leads to the upper part of the lower tank
  • the lower side of the upper tank is provided with a water guiding pipe
  • the outlet guiding pipe leads to the lower layer.
  • the lower part of the tank body is respectively provided with an exhaust port on the upper and lower sides of the tank body
  • the water outlet of the filter tank is disposed on one side of the bottom seal head of the composite filter device, and a sediment discharge port is arranged at a center position of the bottom seal head.
  • the surface of the hot felt is provided with a plurality of shallow shallow water channels.
  • the top of the inner chamber is equipped with an automatic exhaust valve and a liquid level control online monitor for monitoring the liquid level.
  • the upper portion of the activated carbon reaction sphere is impervious to water, and the lower part is a mesh outlet.
  • the volume of activated carbon in the activated carbon reaction sphere accounts for 15% to 95% of the volume of the reaction sphere.
  • the system further includes a hybrid charged adsorbent production device for treating the remaining solid sludge, and the sludge generated in each section is input to the hybrid charged adsorbent production device.
  • the system further includes an exhaust gas environmental treatment device that centrally treats the flue gas, hot flue gas, dust, and the like generated in each process.
  • the exhaust gas treatment system comprises a preliminary purification device, a water-solid mixer, a twin-tower rotary spray system and a flue gas discharge device, the preliminary purification device comprising an air buffer and a primary flue gas treatment pipe, and the exhaust gas is introduced into the air.
  • the buffer is input into the primary flue gas treatment pipeline through the air buffer, discharged into the water-solid mixer through the primary flue gas treatment pipeline, and the water-solid mixer outlet is connected into the double-tower rotary sprinkler system.
  • the tower rotary sprinkler system is processed and input into the flue gas discharge equipment, and then discharged through the flue gas discharge equipment.
  • the air buffer comprises a cylindrical outer casing, and more than one water curtain ejection opening is arranged on the upper side of the outer casing, and a sewage outlet is arranged at the bottom of the outer casing.
  • the preliminary purification device further includes a sedimentation tank, and the sewage outlet is connected to the sedimentation tank through the pipe section.
  • a pipe section is connected to the sewage outlet, and the pipe section is connected to the upper part of the sedimentation tank, and the upper part of the sedimentation tank is connected to the air buffer through the pump and the pipe section.
  • An on-line level monitor for detecting the liquid level inside the air buffer is also mounted above the air damper.
  • the primary flue gas treatment pipeline is provided with more than one negative ion-charged ceramic, and each negative ion-charged ceramic rear end is correspondingly equipped with a high-speed water mist zone nozzle.
  • a baffle is mounted on the rear end of each of the high-speed water mist nozzles.
  • the deflector adopts a concave obtuse angle deflector.
  • the negative ion-charged ceramic is mounted on the left, right, and upper sides of the primary flue gas treatment pipe.
  • the exhaust gas treatment system further includes a cooling tower that cools the hot water in the heat exchanger in the flue gas discharge device.
  • the system further comprises a plasma photocatalyst negative ion air deodorizing and sterilizing device for generating air which is treated as air at the male end and air in the production area, and an air inlet of the plasma photocatalyst negative ion air deodorizing and sterilizing device is installed around each kitchen garbage collecting pool.
  • the plasma photocatalyst negative ion air deodorization and sterilizing device comprises an air conveying pipeline, a photocatalytic main processor and an activated carbon air filter, a gas input air conveying pipeline, an negative ion device in the air conveying pipeline, and a gas passing through the air conveying pipeline
  • the photocatalytic main processor is provided with an air passage, and the air passage is equipped with more than one ultraviolet light tube with an emission wavelength of 253 nm - 258 nm, and the rear end of the ultraviolet light tube is fixedly installed with titanium dioxide light
  • the catalytic contact plate is connected to the activated carbon air filter at the end of the air passage, and the gas is output through an activated carbon air filter.
  • An air discharge pipe is connected between the photocatalytic main processor and the activated carbon air filter, and an negative ion device is arranged in the air discharge pipe, and the air passage end is connected with the air discharge pipe, the air discharge pipe and the activated carbon air filter Connected.
  • the negative ion device adopts a negative ion corrugated plate, and the negative ion corrugated plate is stackedly installed.
  • the negative ion corrugated plate is provided with two sections, the front section is horizontally installed, and the rear section is vertical installation.
  • the front end of the air conveying pipe is provided with an air inlet, and an automatic sliding gate valve is installed at the rear end of the air inlet.
  • the back surface of the ultraviolet light pipe is equipped with a light reflecting plate.
  • the air passage in the photocatalytic main processor is Z-shaped.
  • the size and shape of the titanium dioxide photocatalytic contact plate coincides with the cross section of the air passage and can be just blocked in the air passage.
  • the titanium dioxide photocatalytic touch panel is of a honeycomb type.
  • the titanium dioxide photocatalytic touch panel has a thickness of 1 cm - 10 cm and has more than one hole.
  • the pulverized material in the step E is subjected to biochemical treatment by a biochemical treatment device, and then dried by an automatic unloading multi-stage drying device, and then subjected to multi-stage drying and material selection to form a mixed feed.
  • the biochemical treatment includes the following steps:
  • the pre-fermented material is generated by the simultaneous action of the anaerobic fermentation tank and the two auxiliary fermenters;
  • the materials in the two sub-fermenters are sent to the main fermenter through the automatic conveying equipment provided at the bottom of the auxiliary fermenter, and the materials in the anaerobic fermentation tank are also passed through the automatic unloading system. Feeded into the main fermenter for secondary fermentation;
  • the pre-fermented material When the pre-fermented material is formed in the anaerobic fermentation tank, it will account for 50% of the weight of the total fermentation base - 80% of the bean seed stalk and 20% of the total fermentation base weight - 50% of the timber
  • the current season orange stalk of the crop is broken into a powder having a particle diameter of 0.5 mm to 1 mm, and a composite bacterium capable of decomposing the crude fiber is added to biochemically treat the mixture material, and the bacterial strain of the composite bacterium has not less than two One kind of Aspergillus oryzae, the compounding agent is input in an amount of 1% of the mixed solid base, and the chemical components calcium oxide, sodium chloride, sodium hydrogen phosphate and urea are added.
  • the artificially inactivated kitchen waste is added to the auxiliary fermenter as the base material, and the bran and the base material are added in an amount of 1% to 2% by weight of the base material.
  • 1% - 3% of rice bran and 1% of the weight of the base of sugar as a mixture, and add appropriate amount of water to make a paste the temperature is controlled between 20 ° C - 30 ° C range
  • adding 2% - 4% of the bread yeast to the mixture, and fully stirring and strengthening the aeration to enhance the growth of the yeast the fermentation method can adopt the old fermentation method.
  • the solid fermentation is carried out by adding the artificially inactivated, washed and dehydrated kitchen waste to the secondary fermenter, and the green wood mold and the tropical silk are selected.
  • Yeast, white fungus and endophytic yeast consist of a mixture of four bacteria, the weight ratio of four bacteria is 2:2:1:1, the inoculum is 2% of the total weight, and the total weight is added 1%- - 1.5% urea, temperature 25 ° C - 42 ° C, tumbling once per hour by a stirring device, fermentation time 9 hours - 10 hours.
  • the material that has been pre-biochemically processed is input into the main fermenter, and the percentage of the total material weight in the straw fermentation material is 10%-40%, and the baker's yeast fermentation material accounts for 20% of the total material weight percentage.
  • the fermentation material in the second sub-fermenter accounts for 40%-70% of the total material weight.
  • the waste plastic produced in the step B is reversed by the waste plastic reverse engineering device to generate biodiesel.
  • the raw slag crude carbon black artificial aging processor produced by the biodiesel uses aging to grind the material, and then passes through the chemically aged coarse carbon black to enter the physical aging bed, and the crude carbon black is artificially aged.
  • the special automatic conveying tool is used to input the material compatibility equipment.
  • Each of the compatibility aids is added by the liquid and solid automatic quantitative feeding equipment.
  • the material is fully mixed into the low-sulfur high-energy environment-friendly clean coal-forming machine through the multi-layer push-pull screw. After the material is formed, a crude carbon black is obtained.
  • the sewage generated in the steps A to E is treated by the rapid sewage treatment and recycling device, and discharged or reused.
  • the solid sludge treatment produced in the steps A to E is treated by the hybrid charged adsorbent production device to form a hybrid charged adsorbent.
  • the flue gas, the hot flue gas, the dust and the exhaust air generated in the steps A to E are discharged by the environmental treatment device.
  • the treated gas is discharged through a plasma photocatalyst negative ion air deodorizing and sterilizing device.
  • the oil-water mixture produced in the steps A to E is produced by the distillation-free biodiesel production method, and the method comprises the following steps:
  • the bio-fat is sent into the grease colloid removal device by a pump or the like, and then the hydro-pneumatic propulsion machine is started, and the phosphoric acid having a concentration of 85% is added.
  • the ratio of phosphoric acid to bio-fat is not more than 1% of the total amount of grease.
  • the grease is used to remove the liquid from both ends of the device to cause the colloidal grease to remove the liquid inside the device.
  • the impact time is 10 Min——15min, after the end of the phase collision time of the liquid, the diluted brine is added immediately.
  • the weight ratio of water to salt in the dilute brine is between 95:5 and 90:10, and the weight ratio of bio-fat to dilute brine is 90: Between 10 and 80:20;
  • the biological grease mixture is input into the liquid separation device to be statically layered, the upper layer is a mixed liquid of methanol and glycerin, and the lower layer is crude biodiesel;
  • the liquid separation device is set to be opened at the lower liquid discharge port, and the crude biodiesel is transported into the filtering device, and the purified biodiesel is obtained after filtration and the solid catalyst is recovered.
  • the oil-water mixture in the oil-water separation tower is heated to 60° C. to 85° C., after the bio-oil is floated, the oil moisture layer is realized, and the upper layer of bio-oil is scraped by the scraper and passes through the oil pipeline. Feed into the oil storage container.
  • the cosolvent is selected from methyl alcohol, and the cosolvent is added in an amount of 0.5% to 2% by mass of the bio-fat.
  • the co-solvent further comprises butanol added in an amount of 0.5% by mass of the bio-fat.
  • the solid anionic metal base catalyst is characterized by reagent activated carbon and nanoparticles of silicate minerals of aluminum, sodium, iron and lithium as a base nucleus, and then wrapped with silicon, aluminum and lithium mesh skeleton medium. And a hybrid carrier with polarity, and the carrier is immersed in the KNO3 liquid, and treated to become a hybrid charge with polarity, a solid anionic metal base catalyst containing 15% - 25% KNO3 .
  • the biodiesel is made into emulsified biodiesel by a microemulsified biodiesel manufacturing device, and the method comprises the following steps:
  • the crude biodiesel is input into the above micro-emulsified biodiesel device, the stirring system is started, 30%-80% of the national standard diesel oil is added, and the mixture is stirred for 5 minutes;
  • the hydrophilic agent is a composite active agent selected from a cationic surfactant and a nonionic surfactant, and the ratio is 50% of a cationic surfactant and 50% of a non-cationic surfactant.
  • the surfactant is triethanolamine or hexahydroaniline or cetrimonium bromide and aqueous ammonia.
  • the water is added in an amount of 10% to 20% by weight based on the total weight.
  • the octadecano-cis-9-enoic acid set amount has an acid value of 200.
  • the beneficial effects of the invention are as follows: 1.
  • the integrated equipment and method for comprehensively treating the kitchen waste according to the application of the present invention is a comprehensive integration of domestic and foreign kitchen processing industry for the first time with high integration, automation and comprehensiveness.
  • the equipment is compatible with the method of resource-based treatment of the inevitable attachment of kitchen waste, adapts to the trend of the international environmental protection industry, and implements the safe disposal and disposal direction of the residue after the centralized treatment of waste is not transferred and digested.
  • the application of the invention provides kitchen waste and its inevitable attachments - waste plastic bags, drowning sludge and domestic sewage in the plant, industrial sewage and sludge produced in the production process, various large systems in the same equipment The processing method in the device.
  • the application of the present invention provides various high value-added product names, manufacturing methods and uses thereof after the comprehensive recycling of the kitchen waste.
  • the application of the invention provides a comprehensive energy-saving production, safe production, no residue transfer treatment for the kitchen waste treatment industry, no room temperature discharge, no odor emission close to the clean production method and mode without sewage discharge.
  • the products produced by the invention are National III mineral diesel, low sulfur and high calorific value clean environmental protection coal, and gas three strategic energy sources, which can alleviate the pressure of social supply and demand.
  • the high-nutrition microbial protein feed additive produced can effectively fill the gap of the lack of high-protein additives in domestic feed.
  • the invention provides a novel garbage carrier (barrel) production method capable of naturally sterilizing and deodorizing the kitchen garbage carrier (barrel) and providing clean air around the outer periphery of the barrel, which is an application surface extremely A wide range of new environmentally friendly cleaning appliances.
  • FIG. 1 is a schematic flow chart of a core part of a system of the present invention.
  • FIG. 2 is a schematic flow chart of the system of the present invention.
  • FIG. 3 is a schematic view showing the production process of the energy plastic carrying device of the present invention.
  • Figure 4 is a schematic view showing the structure of the collecting device of the present invention.
  • Fig. 5 is a perspective view showing the three-dimensional structure of the kitchen waste bag breaking device of the present invention.
  • Fig. 6 is a schematic view showing the structure of a cut surface of a kitchen waste bag breaking device according to the present invention.
  • Fig. 7 is a schematic cross-sectional structural view of a kitchen waste bag breaking device according to the present invention.
  • FIG. 8 is a schematic structural view of a kitchen garbage combined screening device according to the present invention.
  • FIG. 9 is a schematic cross-sectional structural view of a kitchen waste combined screening device according to the present invention.
  • Figure 10 is a schematic view showing the structure of a wet advanced oxidation, deodorization, inactivation, cleaning and salt reducing device in the present invention.
  • Figure 11 is a schematic view showing the structure of a primary solid separator in the present invention.
  • Figure 12 is a schematic view showing the structure of a vertical dewatering apparatus in the present invention.
  • Figure 13 is a schematic view showing the internal structure of a vertical dewatering apparatus in the present invention.
  • Figure 14 is a schematic view showing the structure of a main biochemical treatment device in the present invention.
  • Figure 15 is a schematic view showing the structure of a main fermentation apparatus in the present invention.
  • Figure 16 is a perspective view showing the structure of the main biochemical treatment device of the present invention.
  • Figure 17 is a schematic view showing the structure of the automatic unloading multi-stage drying device of the present invention.
  • Figure 18 is a schematic cross-sectional view showing the pre-drying apparatus of the present invention.
  • Figure 19 is a schematic view showing the structure of a main drying device in the present invention.
  • Figure 20 is a schematic cross-sectional view showing the main drying apparatus of the present invention.
  • Figure 21 is a schematic view showing the structure of a selection device in the present invention.
  • Figure 22 is a schematic view showing the structure of a mixed feed device of the present invention.
  • Figure 23 is a partial structural view of the waste plastic reversal engineering device of the present invention.
  • Figure 24 is a partial structural view of the waste plastic reversal engineering device of the present invention.
  • Figure 25 is a partial structural view of the waste plastic reversal engineering device of the present invention.
  • Figure 26 is a partial structural view of the waste plastic reversal engineering device of the present invention.
  • Figure 27 is a schematic view showing the structure of a coarse carbon black processing apparatus in the present invention.
  • Figure 28 is a schematic view showing the structure of a water, oil and solid separation device of the present invention.
  • Figure 29 is a schematic view showing the structure of a biodiesel production apparatus of the present invention.
  • Figure 30 is a schematic view showing the structure of a cut surface of a bio-oil normal temperature fat exchange device according to the present invention.
  • Figure 31 is a schematic view showing the structure of the ultrasonic transducer in the present invention.
  • Figure 32 is a schematic view showing the structure of an emulsified biodiesel apparatus of the present invention.
  • Figure 33 is a partial structural view of the rapid sewage treatment and recycling device of the present invention.
  • Figure 34 is a partial structural view of the rapid sewage treatment and recycling device of the present invention.
  • Figure 35 is a partial structural view of the rapid sewage treatment recycling device of the present invention.
  • Figure 36 is a partial structural view of the rapid sewage treatment and recycling device of the present invention.
  • Figure 37 is a partial schematic view showing the structure of a hybrid charged adsorbent production apparatus of the present invention.
  • Figure 38 is a partial schematic view showing the structure of a hybrid charged adsorbent production apparatus of the present invention.
  • Figure 39 is a partial schematic view showing the structure of a hybrid charged adsorbent production apparatus of the present invention.
  • Figure 40 is a schematic illustration of an exhaust gas treatment system of the present invention.
  • Figure 41 is a schematic view showing the double-tower wet gas-solid separator of the present invention and its internal structure.
  • Figure 42 is a schematic view showing the construction of a primary flue gas treatment pipe in the present invention.
  • Figure 43 is a schematic view showing the flue gas discharge system and its internal structure in the present invention.
  • Figure 44 is a schematic view showing the construction of a primary flue gas treatment pipe of the present invention.
  • Figure 45 is a schematic view showing the structure of a plasma photocatalyst negative ion air deodorizing and sterilizing device in the present invention.
  • Figure 46 is a partial structural view showing the gas collection and pretreatment apparatus of the plasma photocatalyst negative ion air deodorizing and sterilizing device of the present invention.
  • This embodiment is a preferred embodiment of the present invention, and other principles and basic structures are the same as or similar to those of the present embodiment, and are all within the scope of the present invention.
  • the present invention is mainly a comprehensive kitchen waste processing system, which includes a kitchen garbage bag breaking device, a kitchen garbage combined screening device, and a wet advanced oxidation deodorizing and inactivation cleaning device.
  • the salt reduction device, the vertical dewatering device, the material crusher and the automatic control device, the kitchen waste is put into the kitchen garbage bag breaking device for bag breaking treatment, and then input into the kitchen garbage combined screening device for joint screening, the filtered oil water
  • the solid mixture is input to the wet advanced oxidation and deodorization inactivation cleaning and salt reducing device for inactivation treatment, and the kitchen waste which has been deactivated by dehumidification and desulfurization by wet advanced oxidation is sent to the dewatering device by the screw conveying pipeline through the dewatering device
  • the dehydrated material is input into the material crusher for pulverization, and the automatic control device controls the operation of other devices.
  • the material input material crusher is further provided with a biochemical treatment device for biochemical treatment, and the biochemically processed materials are input into the pre-drying equipment and the main drying equipment for drying, and then selected by the selected device. After mixing of the mixed feed devices, a feed product is formed.
  • the solid waste input from the kitchen waste combined screening device is processed into the waste plastic reverse engineering device, and then the biodiesel is formed by the distillation-free biodiesel production device and the emulsified biodiesel device, and the residual residue is passed through the crude carbon black treatment device. Processed into coarse carbon black.
  • the sewage generated by the system is input into the rapid sewage treatment and recycling device, the tail gas input tail gas environmental protection treatment device generated by the system and the plasma photocatalyst negative ion air deodorization sterilization device are processed and discharged, and the sludge generated by the system is input into the hybrid charged adsorbent production device. Hybrid charged adsorbent production.
  • the material after dehydration is pulverized by a material crusher.
  • the source of the invention is an energy plastic carrying device A, and the kitchen waste is put into the energy plastic carrying device A, and then the energy plastic carrying device A for the kitchen garbage collected by the kitchen garbage collecting point is collected and transported by the special collecting vehicle B. Go to the production and processing workshop.
  • the production process steps of the energy plastic carrying device used in the present invention are as follows:
  • Aa based on a plastic carrier resin suitable for the manufacture of kitchen waste bins
  • ultra-fine anatase titanium dioxide A3 (in this embodiment, the particle size of titanium dioxide is less than 1 ⁇ m) is stirred by a mixer with A4 as energy
  • the raw material wherein the weight ratio of the nanometer natural energy stone powder and the carbon black in the energy raw material is 50%-85%: 50%-15%, and the ultrafine anatase titanium dioxide accounts for 10% of the total weight of the mixture- —15%
  • the Chinese patent of the applicant application No. 201010154643.3 for the production steps of the energy plastic masterbatch of the present invention, reference may be made to the Chinese patent of the applicant application No. 201010154643.3;
  • energy raw material in the drying equipment A5 is kept at a temperature of 100-120 ° C for 1-2 hours, and the dried energy raw material is added to the material of 2% aminosilane or hard fatty acid magnesium which accounts for the specific gravity of the energy raw material.
  • Dispersant ;
  • the energy raw material to which the dispersing agent has been added is uniformly mixed with the plastic carrier resin and the calcium oxide filler, wherein the weight ratio of the plastic carrier resin to the energy raw material to which the dispersing agent is added is 1:2 to 1:1, the plastic carrier resin and the oxidation Calcium was added in an amount of 20:1.
  • the above-mentioned treated materials are mixed into a professional plastic mixing equipment A6 for mixing, and extruded by the extruder A7 to produce a plastic energy masterbatch.
  • the Af, plastic energy masterbatch is molded by the injection molding machine A7a according to the geometry of the molding die for manufacturing the kitchen waste-receiving device.
  • the kitchen waste-containing device made by the above-mentioned process of the present invention has a long-term release of 5000-12000/cm 3 negative ions regardless of size and shape, and the special structure of natural energy stone powder can make it It emits light with a wavelength of 4-14 microns for a long time. This wavelength of light is suitable for exciting the photons of titanium dioxide in the equipment, so that the garbage-loading equipment can generate photo-reaction process for a long time.
  • the energy consumed is for the equipment. Its own body, in line with the principle of conservation of energy.
  • the energy plastic kitchen garbage container used in the invention can release a large amount of negative ions for a long time, and has long-term photocatalytic ability, and the generated photogenerated electrons and photoholes have strong energy, far higher than the kitchen
  • the strength of the molecular chain of junk organic pollutants can easily decompose organic pollutants into the most primitive state and form a highly effective antibacterial effect.
  • the special collection vehicle B transports the kitchen waste to the production processing workshop, and then puts it into the kitchen garbage breaking bag device.
  • the main body of the kitchen garbage bag breaking device is a cylindrical outer casing D11.
  • the cylindrical outer casing D11 is arranged in a horizontal structure, and the cylindrical outer casing D11 is supported by a support frame (not shown). .
  • the cylindrical outer casing D11 is open at one end, and is the discharge port D18 of the present invention, and the other end is blocked.
  • the plug is internally provided with a piston D13 capable of sliding back and forth along the cylindrical outer casing D11, and the cross section of the piston D13 and the cylinder
  • the cross section of the shaped outer casing D11 coincides.
  • the power tool D12 is mounted on the outer side of the cylindrical outer casing D11.
  • the power tool D12 is a pneumatic power tool or a hydraulic power tool, that is, a cylinder or a hydraulic cylinder.
  • the power tool D12 is connected to the piston D13 through a connecting rod. Through the telescopic movement of the power tool D12, the piston D13 is made to reciprocate linearly in the inner cavity of the horizontal cylindrical casing D11.
  • a plurality of sipe D14 is formed on the periphery of the piston D13.
  • the bottom of the cross section of the sipe D14 is rectangular, and the top is triangular.
  • the number of sipe D14 is suitable for the need of breaking the bag, and can be according to the outer casing D11.
  • the diameter is adjusted, and in this embodiment, eight are used.
  • a plurality of tools D16 are fixedly mounted, the number of the tools D16 is the same as the number of the sipes D14, and the mounting position of the cutter D16 corresponds to the installation of the sipes D14, that is,
  • Each tool D16 corresponds to a sipe D14, and the cross-sectional shape of the tool D16 coincides with the shape of the sipe D14, which can be slightly smaller than the shape of the sipe D14, so that the tool D16 can move freely in the sipe D14, and the cross section of the tool D16 is also
  • the bottom has a rectangular shape and the top blade has a triangular shape.
  • the cutter D16 can adopt two structural forms, and the installation angle of the blade is at an angle of 90 degrees with the cross section of the discharge port of the cylinder D11, or is 30 degrees from the inner wall. .
  • the length of the cutter D16 is about 1/5 of the total length of the cylindrical outer casing D161
  • the length of the piston D13 is about 2/5 of the total length of the cylindrical outer casing D11.
  • the cutter D16 and the piston D13 The length can be set according to actual needs. When the piston D13 retreats to the end point, the space between the piston D13 and the cutter D16 is the empty position EQ.
  • the top position of the cylindrical outer casing D11 in the kitchen waste bag breaking device is provided with a feed port D21, and the feed port D21 is disposed corresponding to the space position D1.
  • the kitchen garbage collection box D19 is fixedly mounted at the feed port D21.
  • the outer casing of the collection box D19 has a funnel type, which is close to the position of the feed port D21 on the cylindrical outer casing D11.
  • a pneumatic slide gate valve 18 is mounted on the blanking pipe D20 for partitioning the odor from the next processing section.
  • a concave guide rail D17 is fixedly mounted on a lower portion of the inner wall of the cylindrical outer casing D11, and one or more pulleys D15 are mounted at a position corresponding to the concave guide rail D17 under the piston D13, and the pulley D15 is matched with the concave guide rail D17. It can guarantee that the piston D13 does not deviate from the center point during the action.
  • a square rolling clapper D22 is arranged at a position corresponding to the discharge port D18 (also referred to as a non-powered driving end of the casing), and the rolling clapper D22 is provided with kinetic energy by the motor D28 in cooperation with the transmission to drive the rotation thereof, and the rolling clapper D22 is laterally
  • the discharge port D18 is mounted on the cylindrical casing D11.
  • a plurality of compressed air injection grooves D23 are formed on each side of the rolling frame D22, and the compressed air injection grooves D23 are strip-shaped, and each compressed air The ejection grooves D23 are arranged in parallel.
  • the inside of the square rolling clapper D22 is a cavity D25.
  • the cavity D25 is internally provided with a compressed air air duct D24 and a gas injection nozzle D26.
  • the compressed air air duct D24 is provided with compressed air and can be sprayed by gas.
  • the nozzle D26 is ejected, the air jet direction of the gas jet nozzle D26 is the same as the discharge direction of the discharge port D18, the gas is ejected 1-2 times per second, and the air ejected from the gas jet nozzle D26 is ejected through the compressed air ejection slot D23.
  • Use a gas jet to blow the plastic bag forward.
  • the piston of the main equipment D13 uses a pneumatic tool as a power source to make a straight-line push-pull action in the horizontal direction.
  • the square rolling clapper D22 provided at the discharge port D18 also starts to roll at the same time.
  • the pneumatic slide gate valve D27 of the discharge pipe D20 of the kitchen garbage collection box D19 is opened, the garbage passes through the discharge pipe D20 from top to bottom, and the feed space position D1 which is presented when the piston D13 of the main device is retracted to the end point.
  • the kitchen waste is passed through the feed port D21 during this time, and at the same time enters the empty space D1 of the inner cavity of the main device.
  • the piston D13 at this moment pushes the kitchen waste to the front by the push rod action of the pneumatic tool, and the piston D13 is pushed forward, at this time.
  • the inner cavity under the mouth D21 is infested by the piston D13, the feed port D21 is closed, and the kitchen waste is pushed by the piston D13 toward the inner cutter D16 of the equipment cylinder casing D11, and is disposed on the outer circumference of the piston D13.
  • the sipe D14 allows the blade to penetrate into the sipe D14, and the plastic bag of the kitchen waste is cut by the blade at this time.
  • the piston D13 is pushed to the position of the rolling shutter D22 of the discharge port D18, and the broken kitchen garbage receiving bag is strong in the rolling clapper D22.
  • the built-in kitchen waste leaks out from the crack of the plastic bag.
  • the multi-stage gravitational compressed air set in the rolling clapper D22 passes through the exit slot D23 which is directed to the clapper surface, and the kitchen waste is further taken off.
  • the bag, and the gravitational gas jet blows the plastic bag forward, avoiding being covered by the falling kitchen waste, and affecting the next sorting work.
  • the splitting device for the kitchen garbage receiving bag in the invention is a production process of converting the kitchen waste into a microbial high-protein feed, and preventing the plastic pieces from being mixed into the feed, and the plastic can be realized by the device.
  • the combination of the bag splitting, the smashing of the board, and the blowing of the bag to ensure that the bag is broken into pieces during the bag breaking process of the kitchen waste, especially to break the bag and not break, the kitchen The garbage is removed from the bag and is not covered by the garbage.
  • the kitchen waste After the bag is broken, the kitchen waste enters the kitchen and garbage combined screening device, and is filtered.
  • the broken kitchen waste is firstly pushed into the magnetic separator as a preliminary screening, and then added to the liquid air flotation sorting device.
  • the utility model mainly relates to hydraulic sorting and salt washing of the kitchen waste.
  • the kitchen garbage combined screening device of the present invention is mainly used for screening the kitchen waste that has been broken, and It is mainly used for hydraulic sorting and salt washing of kitchen waste. Therefore, this part of the invention is called a water float screening device or a liquid air flotation sorting device.
  • the upper part of the casing E11 of the kitchen garbage combined screening device of the present invention has a round barrel shape, and the lower part is composed of an inner hollow cone E18, and the feeding port is arranged at the upper middle part of the casing E11, and the kitchen waste is used by the pipe water flow force. From the exit of the previous section, the air-floating zone E10 inside the casing is pushed from the top to the bottom.
  • the water used for the pipeline is the treated water for the sewage treatment system.
  • the pipeline is equipped with the inlet pipe E20 near the inlet, and the front end of the inlet pipe E20.
  • the hydraulic pressure pump E21 is installed, and the kitchen waste is flushed into the air floating area E10 inside the casing by the action of the hydraulic pressure pump E21.
  • the kitchen garbage combined screening device of the present invention is mainly divided into an air floating zone E10 and a non-air floating zone E32, and a partition plate E25 is disposed inside the casing E11.
  • the partition plate E25 is disposed inside the casing E11.
  • the façade is divided into about 1/3 position, and the inside of the casing is divided into an air floating zone E10 and a non-air floating zone E32, that is, the air floating zone E10 occupies about 2/3 of the inner space of the casing, and the non-air floating zone E32 occupies the interior of the casing.
  • the feed port is connected to the upper side of the air floating zone E10.
  • a rolling jaw E30 (or a tumbler) is installed at a position near the top of the air floating area E10 near the liquid surface.
  • two rolling teeth E30 are provided, and two rolling teeth E30 are installed one above the other. 1/2 of the lower rolling jaws are disposed in the liquid surface, the upper rolling jaws are disposed above the liquid surface, and the two rolling jaws E30 are synchronously driven to rotate by the rolling motor E39.
  • the tooth movement trajectories of the two rolling teeth E30 are passed between the mutual tooth positions, that is, when the two rolling teeth E30 rotate, the tooth positions of the first rolling teeth are set at the second rolling ⁇ .
  • the tooth position of the second rolling tooth is disposed between two adjacent tooth positions of the first rolling tooth, and the group of rolling teeth E30 is used for kitchen waste.
  • the fishing operation and unloading operation when the low-density material in the liquid air-floating process floats on the water surface is mainly used for fishing for light-weight materials such as plastic bags and toothpicks, and the rolling teeth underneath are used to remove plastic bags and toothpicks. Then it is transported away through the rolling jaws above.
  • the bottom of the casing E11 is provided with a residue discharge port E22, and the residue discharge port E22 is provided with a valve E23.
  • the residue discharge port E22 and the valve E23 are mainly arranged corresponding to the air floating zone E10 for weighting the material.
  • the object is removed.
  • more than one air nozzle E24 is disposed around the residue discharge port E22, and air is introduced into the water body for performing a tumbling and tumbling action on the water body and the material in the air floating area E10.
  • a circulating water pipe E40 is also installed between the non-air floating zone E32 and the air floating zone E10, and one end of the circulating water pipe E40 is a water outlet E41 at one end of the non-air floating zone, and one end of the air floating zone E10 is a water filling port, circulating water
  • the pipes are connected through the water storage tank E42 to realize liquid air flotation sorting of the kitchen waste.
  • the partition plate E25 is installed with a semi-floating material leakage outlet E26 at a position 20 cm or more from the bottom, and a louver guide groove E27 having an opening upward at the leakage outlet E26, and the groove direction of each louver guide groove E27 is pneumatically mounted.
  • the push-pull rod E28 and the pneumatic device E38 push the pneumatic push-pull rod E28 up and down to realize the opening and closing of the louver guide groove E27, and the opening angle control, thereby controlling the semi-floating material, that is, the kitchen which is regarded as useful.
  • the garbage enters the non-air floating zone E32.
  • the non-air floating zone E32 is another barrel communicating with the air floating zone E10, and the air floating zone E10 and the non-air floating zone E32 are communicated through the leakage outlet E26 of the flat floating layer material.
  • the water outlet E41 disposed on one side of the non-air floating zone mainly ensures that the horizontal liquid level of the non-air floating zone E32 is lower than the horizontal liquid level of the air floating zone E10, and enters the reservoir through the output water body.
  • the air floating area E10 is replenished, and under the action of the hydraulic pressure pump E21 installed on the water supply pipe, the water body is strongly input into the lower part of the air floating area E10 to strengthen the water body and material tumbling action, and strengthen A useful semi-float enters the non-air-floating zone through the louvered diversion trough E27.
  • the lower part of the non-air floating area E32 is provided with a material output device E33, and one end of the material output device E33 is disposed in the non-air floating area E32, and the other end is exposed outside the casing E11, and is exposed on the outer side of the casing E11.
  • a discharge port E35 There is a discharge port E35, a material auger E33 is internally provided with a screw auger E37, a discharge motor E36 is fixedly mounted on the outer end of the material output device E33, a transmission E34 is mounted corresponding to the discharge motor E36, and a discharge motor E36 is passed through the transmission.
  • the E34 drives the screw auger E37 to rotate, and the material is stirred from the bottom to the top in the non-air floating zone E32, and then discharged from the discharge port E35 to the next section.
  • the upper part of the casing E11 is provided with a liquid level automatic control device E29 for controlling the water level in the air floating area E10 to overflow the waterproof body.
  • the kitchen waste combined screening device of the present invention is disposed at the lower part of the ground or above the ground, and the food waste that has been broken is pushed into the magnetic separator (the magnetic separator removes iron impurities in the kitchen waste by using a magnet)
  • the kitchen waste is pushed into the device by the hydraulic discharge pipe, and the material contains plastic bags, glass bottles, metal sheets, small light wood strips, etc., and the complex kitchen materials are in liquid gas.
  • the plastic bag and the lightweight small-shaped wooden strip are pushed to the water surface with the density lower than other materials by the floating force of the air, they are caught by the roll E30 and sent to another roll E30.
  • the light material conveying trough enters the waste plastic reversal engineering section or the waste plastic collection chamber, and the glass bottles, glass fragments and metal dense materials in the liquid air floating area E10 sink to the bottom of the air floating area E10, and wait Open the heavy material discharge port E22 at an appropriate time and collect it from the automatic valve E23 and deliver it to the workshop to be treated by the automatic conveying tool.
  • the louver guide trough E27 can be opened, so that the flat-floating layer of the high-protein feed can be used to automatically enter the leaking outlet E26 of the louver diversion trough E27 and enter the non-volume.
  • the push-pull rod E28 disposed in the louver guide groove E27 is pneumatically controlled, and the opening and closing movement of the guiding trough body E27 can be automatically performed in the set time during the production process, and the air floating area is acted upon.
  • the useful material in E10 is delivered to the non-air-floating zone E32.
  • the beveled ribbon conveyor E33 starts to start, and while the partial water body is effectively separated, the initially sorted kitchen material is sent to the next station device for further processing. deal with.
  • the kitchen-to-garbage combined screening device of the present invention can utilize the opening and closing action of the air flotation and water float, the rolling and the louver diversion trough, and the water level pressure difference between the air floating zone and the non-air floating zone, Plastics, toothpicks, etc. are removed, and the heavy materials such as glass and metal in the kitchen waste are removed by the deposition process, and finally the useful materials are output for further processing to realize automatic screening of the kitchen waste.
  • the inclined bevel conveyor starts to start, and while the part of the water body is effectively separated, the initially sorted kitchen material is sent to the next station device, that is, wet advanced oxidation, Deodorization, inactivation, cleaning and salt reduction devices.
  • the wet advanced oxidation, deodorization, inactivation, cleaning and salt reducing device in the invention mainly utilizes ozone gas to sterilize and clean the kitchen waste in the water body, and the device is divided into more than one reactor F34, and each reaction
  • the device F34 is connected to each other through a pump and a pipe and circulated to each of the reactors F34.
  • the number of the specific reactors F34 can be set according to actual needs.
  • the reactor F34 has a cylindrical shape and is a stainless steel cavity structure, the lower part of the reactor F34 is a semicircular head F35, the top of the reactor F34 is a semicircular or flat top head F37, and the top of the reactor F34 is sealed.
  • An automatic exhaust valve F53 is installed on the head F37, and an ozone destroyer F39 is connected to the automatic exhaust valve F53. The gas in the reactor F34 can be eliminated into the ozone destroyer F39 through the automatic exhaust valve F53, and passed through the ozone destroyer F39.
  • a beveled ribbon conveyor F36 is connected to the inlet of the reactor F34, and the sorted kitchen waste is sent to the wet advanced oxidation and deodorization, sterilization, and cleaning by the inclined spiral conveyor F36.
  • the beveled ribbon conveyor F36 has a tubular shape, and a conveying screw is disposed inside, and the material is sent to the reactor F34 by the rotation of the conveying screw.
  • More than one granular activated carbon reaction sphere F41 is fixedly mounted on the inner periphery of the inner chamber of the reactor F34, and the position is placed in the upper middle portion of the inner chamber of the reactor F34, and the granular activated carbon reaction sphere F41 is a stainless steel mesh shell, and the particle activity is The carbon is encapsulated inside the stainless steel mesh casing.
  • the total volume of the granular activated carbon accounts for 15% to 98% of the volume of the active carbon reaction sphere F41 sphere, and the combined application of the granular activated carbon reaction sphere and ozone It can accelerate the conversion of ozone into hydroxyl radicals in the liquid state, and achieve the artificial forced inactivation and deodorization speed of bacteria in the water.
  • the top of the inner chamber of the reactor F34 is also equipped with an online liquid level automatic control monitor F40 for monitoring the liquid level in the reactor F34, and the online liquid level automatic control monitor F40 can be realized by a liquid sensor, and The liquid level is adjusted by the water level of the other reactor F34 to control the supply and discharge of the pipe F54.
  • a gas, water, and material mixer F42 for ozone-water-mixing of materials is further installed on the outer casing of the reactor F34.
  • the mixer F42 is a three-way connection, one end of which is connected to the inner cavity of the reactor F34 through the communication pipe F55, and the other end is connected to the outlet F43 of the high-viscosity cam rotor pump F49, and the center end of the mixer F42 is connected with an air inlet.
  • the air inlet is connected to the waterproof check valve F56, and the gas supplied by the ozone generator F44 enters through the air pipe F57 and passes through the waterproof check valve F56, enters the mixer F42 and is strongly mixed with water and material, thereby making the water-
  • the kitchen waste-ozone mixture is transported to another reactor F34 through a high viscosity cam rotor pump F49 disposed in a circulation line at the lower portion of the reactor F34 to form a cycle between the two reactors. , control the mixing of the material for continuous oxidation time.
  • the above structure is the front structure of the wet advanced oxidation, deodorization, inactivation, cleaning and salt reducing device in the present invention, and the wet advanced oxidation, deodorization, inactivation, cleaning and salt reducing device of the present invention further comprises a rear structure
  • the latter part of the advanced oxidation deodorization, sterilization and salt reduction device is a solid and liquid separator.
  • the separator is composed of a tilted mesh barrel F52, and the separator front end is connected.
  • the barrel F52 is provided with a plurality of rows of mesh holes.
  • the mesh diameter is 3-8 mm
  • the outer casing F45 is provided outside the barrel F52.
  • a window F46 is mounted on the side of the outer casing F45 for viewing the inside of the barrel F52.
  • the bottom of the outer casing F45 is provided with a water receiver F47 for receiving the water leaked from the mesh barrel F52, and the entire length of the inclined barrel F52 is provided with a flow guiding screw leading to the discharge port F48, that is, in the inclined mesh shape.
  • the full length of the barrel F52 is equipped with a spiral ribbon, and the material is led by the spiral belt.
  • the rotating power of the inclined mesh barrel F52 is driven by the AC motor and the transmission, which is not shown in the figure.
  • the wet advanced oxidation, deodorization, inactivation, cleaning and salt reduction device is used to put the water and kitchen waste mixture into the reactor F34 through the inclined conveyor F36, and the kitchen waste mixture and the water volume.
  • the ratio is 5:7, which is fluid, and is continuously circulated between the inside and the outside of each reactor by a high-viscosity cam rotor pump F49, and ozone gas and water are added to the water-gas mixer F42.
  • the kitchen garbage material is forcibly mixed.
  • the concentration of ozone in the mixture is 10g/T - 15g/T.
  • the mixture is treated with the reaction time in and out of the reactor as the advanced oxidation reaction.
  • the whole time is 5min - 15min, due to The ozone is reduced in water at any time, and the chain reaction is initiated under the assistance of the activated carbon reaction sphere to accelerate the conversion of ozone into hydroxyl radicals, similar to the advanced oxidation process of O 3 /H 2 O 2 or O 3 /UV.
  • the monoatomic oxygen and hydroxyl OH which produce strong oxidation, artificially inactivate and deodorize the pathogenic bacteria in the kitchen waste and remove the sodium chloride substance.
  • the lower valve of the reaction vessel outlet 15A is opened, and the high-viscosity cam rotor pump is used to input the solid and liquid separator for dehydration.
  • the ozone can be used for oxidizing, deodorizing and desalting the kitchen waste, preventing the unpleasant smell from being emitted, polluting the air, and at the same time, eating the meal.
  • Bacteria, viruses and other microorganisms in the kitchen waste are inactivated to prevent their spread, especially if the kitchen waste needs to be biochemically treated in the next stage, the treatment process is protected from the interference of bacteria.
  • the kitchen waste that has been inactivated, deodorized, desalted, and primary dehydrated by wet advanced oxidation is sent to the dewatering device for dehydration by the screw conveying pipe.
  • the dewatering is performed by a vertical dewatering device, see FIG. 12 and Figure 13 shows that the vertical dewatering device of the present invention mainly comprises a casing G49, a vertical inner leakage tower G50 and a ribbon propulsion rod G51.
  • the outer casing G49 has a vertical cylindrical shape, and the vertical inner leakage tower G50 is provided.
  • a stainless steel bearing sleeve G56 is disposed inside the outer casing G49 adjacent to the inner wall of the outer casing G49.
  • the vertical inner leakage tower G50 is a vertically mounted upper and lower cone (please refer to the attached Figure 13)
  • the vertical internal leakage tower G50 is composed of more than one tower body, each tower body has a truncated cone shape, and each tower body is provided with a reinforcing flange G67 at the upper and lower circumferential positions thereof.
  • the connection of the adjacent towers is abutment between the upper and lower flanges G67 of the tower body, and is fixed by bolts G68, and the plurality of tower bodies are spliced into one whole vertical inner leakage tower G50.
  • each tower The flange of the top of the body is mounted at the flange position Surface anti-kickback diversion eaves G59.
  • a plurality of high pressure water recoil nozzles G53 are arranged around the outer portion of the vertical inner leakage tower G50 in the outer casing G49, and the high pressure water recoil nozzle G53 is mounted on the water pipe G65.
  • the water pipes G65 are provided with more than one, each water pipe G65 is vertically disposed inside the outer casing G49 and distributed around the outside of the vertical inner leakage tower G50.
  • Each water pipe G65 is provided with more than one high pressure water recoil nozzle G53 for cleaning the vertical inner leakage tower G50. Anti-clogging.
  • the ribbon push rod G51 is disposed inside the vertical inner leak tower G50 and conforms to the internal shape of the vertical inner leak tower G50.
  • the middle of the ribbon push rod G51 is a spiral rotating shaft, and the rotating shaft is provided with a propeller screw and a screw.
  • the shaft spacing of the belt is gradually narrowed from the lower 25CM to the top of the tower, and the terminal spacing is 10CM.
  • a motor G54 and a transmission G64 are mounted on the outer side of the outer casing G49.
  • the motor G54 drives the transmission G64 to rotate.
  • the bottom of the casing G49 is equipped with a steering converter G66.
  • the transmission G64 is rotated by the belt to drive the steering device G66, and the steering converter G66 converts the horizontal rotation into a vertical position.
  • the steering converter G66 drives the ribbon push rod G51 to rotate.
  • the steering converter G66 can use a worm gear pair or a helical gear pair.
  • the feed port G62 is disposed on the lower side of the vertical inner leak tower G50, and the discharge port G60 is disposed on the upper side of the vertical inner leak tower G50 to allow the material to run from bottom to top.
  • the top of the vertical inner leakage tower G50 is equipped with a shaft fixing plate G61 for mounting a rotating shaft of the spiral belt, and an adjustable discharge speed is also arranged between the shaft fixing plate G61 and the end of the ribbon on the ribbon pushing rod G51.
  • the sealing plate and the sealing plate can be adjusted up and down, and are controlled by a hydraulic or pneumatic tool 16.
  • the upper and lower adjustment of the sealing plate can adjust the size of the discharging port G60, thereby adjusting the discharging speed.
  • a vertical stainless steel vertical plate G57 is fixed around the vertical inner leakage tower G50, and a stainless steel vertical plate G57 is vertically arranged.
  • a plurality of leakage holes G58 are distributed around the vertical inner leakage tower G50, and the leakage hole G58 is elongated and arranged.
  • the anti-backlash guide G59 is installed on the outer circle of the flange of the vertical inner leakage tower G50 and the reinforcement ring of the stainless steel vertical plate G57.
  • the anti-backlash guide G59 is at a 30 degree angle with the tower body.
  • the anti-backlash guide flow G59 is disposed close to the rounded edge of the upper flange G67 and the reinforcing collar G69 of the tower body of the vertical inner leakage tower G50.
  • the inside of the outer casing G49 is provided with a water receiving groove G55 corresponding to the bottom of the vertical inner leakage tower G50 for receiving water leaking from the vertical inner leakage tower G50, and a water outlet G63 is connected to the bottom of the water receiving tank G55 for discharging water.
  • a door G52 is mounted on the side of the outer casing G49, and the door G52 is a vertical three-door body, that is, the outer casing enclosing the inner leakage tower is a tetrahedron, and the three sides are provided with a door body that can be opened.
  • the vertical dewatering device of the present invention is mainly for dehydrating treatment of kitchen waste which has been inactivated, deodorized, desalted, and primary dehydrated by wet advanced oxidation.
  • the device When working, the device is started, and the motor G54 is matched with the shifting system G64.
  • the source firstly drives the tower-type propeller rod G51 through the shaft to rotate, and then the kitchen waste that has completed the wet advanced oxidation and primary dehydration is sent to the feeding port G62 of the vertical dewatering device via the conveying tool, and the material is carried along with the spiral belt.
  • the direction of movement of the ribbon on the push rod G51 is pushed from bottom to top until the top of the inner leak tower is sealed, the material is pressed under the action of pressure, and is simultaneously discharged by the discharge port G60, and the water body is taken out.
  • the water leakage hole G58 of each tower body leaks out, passes through the anti-backlash guide flow G59 from the top to the bottom to the water tank G55 at the bottom of the inner leak tower, and enters the oil water treatment section through the water outlet pipe connected to the water tank G55, and is The discharged dehydrated material is transported into the material crushing section by the conveying equipment.
  • the water leakage hole G58 is placed by the high pressure water from the top to the bottom of the inner leaking tower. Recoil cleaning.
  • the vertical dewatering device of the invention adopts a vertical inner leakage tower and a spiral propulsion rod structure to dehydrate the kitchen waste, has a simple structure and good dehydration effect, and has a sealing plate which can be adjusted up and down at the exit for adjusting Output speed to control the degree of dehydration.
  • the dehydrated kitchen waste is sent to the material crusher H63 by the pneumatic propulsion device.
  • the crushing device adopts a multi-axis structure design, and the material is broken by the low-speed high-torque shearing structure. This technology is a well-known technology.
  • the kitchen waste is further processed for reuse.
  • the biochemical fermentation device of the present invention is mainly used for biochemical treatment of kitchen waste, and the biochemical fermentation device is mainly used. It comprises a plurality of anaerobic fermentation tanks I65 used in combination with each other and a main fermentation unit I71, which are anaerobic fermentation and aerobic fermentation, respectively.
  • the anaerobic fermentation process is provided with an anaerobic fermentation tank I65, the anaerobic fermentation tank I65 is cylindrical, the top is provided with a sealing cover I66, and the sealing cover I66 is controlled by a pneumatic tool (ie, an automatic flipper I94), this embodiment
  • a pneumatic tool ie, an automatic flipper I94
  • the automatic clamshell I94 is connected to the top of the sealing cover I66 through a connecting rod, and the connecting rod is moved by the cylinder, and the sealing cover I66 is pulled by the connecting rod to realize opening and closing.
  • the bottom of the anaerobic fermentation tank I65 is equipped with an automatic unloading system I67.
  • the automatic unloading system I67 is tubular, with a spiral stirring knife inside.
  • the anaerobic fermentation tank I65 is equipped with an automatically movable material agitator I68, anaerobic.
  • a strain activation tank I69 is arranged on one side of the fermentation tank I65, and a discharge port I95 is arranged on the side of the strain activation tank I69, and the discharge port I95 is connected to the automatic discharge system 4.
  • the anaerobic fermentation section is provided with a plurality of anaerobic fermentation tanks used in combination with each other, one of which is a strain activation pool I69.
  • the main fermentation apparatus is divided into two sub-fermenters I71 and one or more main fermenters.
  • a material hoist I64 is provided, and the material hoist I64 is used for kitchen waste. Lift up and put into one of the sub-fermenters.
  • Two auxiliary fermenters I71 are installed above the main fermenter, and a material conveying pipeline is arranged between the main and the auxiliary fermenters, and the conveying pipeline is an automatic conveying device I74 disposed at the bottom of the auxiliary fermenter I71.
  • the automatic conveying is provided.
  • the device I74 is cylindrical, and a cylindrical stirring shell is provided with a spiral stirring knife.
  • the material is sent to the main fermenter through the automatic conveying device I74, and a pneumatic valve is arranged in the middle of the connecting passage of the auxiliary fermenter I71 and the main fermenter inlet. I85.
  • a stirring device I73 for tumbling action is installed in the auxiliary fermenter I71, and the stirring device I73 is a middle main shaft, and a plurality of stirring blades are fixedly mounted on the central shaft for tumbling the material.
  • an exhaust port I91 is opened in the upper portion of the casing of the sub-fermenter I71, and an air blower I92 is connected to the exhaust port I91 for discharging the gas generated in the sub-fermentor I71.
  • the main fermenter mainly comprises a horizontal shell I75, a support I76, a heat transfer oil transport pipe I77 and a double-layer ribbon stirrer I78.
  • the double-layer ribbon stirrer I78 has a shaft body and an inner layer ribbon.
  • the inner spiral belt is disposed inside the outer spiral ribbon, and the inner spiral ribbon and the outer spiral ribbon are spirally belt-shaped, and are respectively fixedly mounted on the shaft body, the inner layer spiral belt and the outer layer spiral The spiral direction of the belt is opposite.
  • the shaft of the double-layer ribbon stirrer I78 is provided with a raking blade I79.
  • the transmission system in this embodiment includes the motor I80, the transmission I81, the gear I82 and the chain I83, and the gear I82 and the chain I83 are respectively arranged.
  • a plurality of transmissions I81 are provided, and the specific number can be set according to actual needs.
  • the motor I80 directly drives the main transmission, and the main transmission is driven by the transmission shaft.
  • Each of the slave transmissions is provided with a driving gear I82, and a double-sided ribbon agitator I78 is respectively provided with a driven gear on both ends of the shaft body, and two driving gears I82 are respectively connected to the driven gear through the chain I83.
  • a feed port I84 is opened above the main fermentation device, and a pneumatic valve I85 is installed at the feed port I84.
  • An observation window I86 is installed on the upper middle portion of the horizontal casing I75 for viewing the reaction situation in the horizontal casing I75.
  • the upper part of the horizontal casing I75 is also equipped with an air transmission pipe, a pipe I87 and a material sampling port. I88, the air transmission and exhaust pipe I87 is used for introducing air into the horizontal casing I75 or discharging the internal gas of the horizontal casing I75, and the material sampling port I88 is used for sampling the materials in the horizontal casing I75.
  • the upper part of the horizontal casing I75 is provided with an automatic discharge hole I89, and the automatic discharge hole I89 is provided with an automatic valve gate I90 for discharging.
  • an exhaust port (not shown) is also provided in the main fermenter.
  • An automatic temperature control system is also installed in the biochemical device of the present invention.
  • the method for biochemical fermentation by the above biochemical treatment device comprises the following steps:
  • Anaerobic fermentation tank I65 fermentation The solid base material is pulverized and added to the strain for biochemical treatment.
  • the first is to consider the normal crop orange in the surrounding area of the kitchen waste treatment plant.
  • Stalk in this embodiment, take the bean seed crop orange stalk (such as: one or more of soybean, mung bean, red bean and pea) to account for 50%-80% of the weight of the total fermentation base, and take the wood crop (such as: wheat, corn, millet, rice), the current season of orange stalks accounted for 20% -50% of the total weight of the fermentation base, in this example, the weight ratio of the two is 60%: 40%, the above
  • the two kinds of orange stalks are used as a mixture.
  • the reason for using this mixed solid base is that the legume crop orange stalk has high protein content, but the soluble sugar content is low, and the microbial activity is not high at the initial stage of fermentation, while the straw crop stalk is low.
  • the nutritional value of the plant itself is not high, but the soluble sugar content is high.
  • the mixing of the two crops of orange stalks not only improves the quality of the fermentation, but also complements the nutrients of the two types of crop stalks;
  • the diameter is 0.5m M——1mm powder, and adding a composite microbial agent capable of decomposing crude fiber to biochemically treat the above mixture material, and the complex bacteria agent refers to not less than two kinds of bacteria, one of which is Aspergillus oryzae, a composite microbial agent
  • the input amount is 1% of the mixed solid base, and the chemical components calcium oxide, sodium chloride, sodium hydrogen phosphate and urea are added;
  • the main fermentation device I70 is composed of two main fermenters and two sub-fermenters.
  • the main fermentation device I70 is composed of two main fermenters and two sub-fermenters. Pre-fermentation of materials by different strains. Firstly, in one of the sub-fermenters 8, the artificially inactivated kitchen waste is added as a base material, and the bran which accounts for 8%-10% by weight of the base material, 10% by weight of the base material, 15% of rice bran and The white sugar, which accounts for 1% by weight of the base material, is added as a mixture to the crushed base material to form a paste, and then 2-3% of the strain is added.
  • the fermentation method adopts the old fermentation method (the first fermentation strain is bread).
  • Yeast added in an amount of 2% - 3% by weight of the total fermented base, and 1% of the weight of the fermented base, mixed with the broken base and adjusted to a paste, heated to 24 ° C - 25 °C, then add baker's yeast), and use the heat source of other sections of the kitchen waste treatment work, and fully stir and strengthen the aeration to enhance the growth of the yeast.
  • the fermentation time is 12 hours after stopping the stirring and aeration.
  • the old fermentation method After each fermentation is completed, 10% of the total material is stored as the next yeast material at the time of unloading, and the amount of baker's yeast added in each subsequent fermentation can be reduced, and only the bacteria added in the first fermentation are added. 60% of the weight.
  • Another sub-fermenter I71 is a pre-fermenter for the main raw material, and solid-state fermentation is carried out using the kitchen waste which has been artificially inactivated, washed and dehydrated.
  • the strains selected at this stage are composed of Trichoderma viride, Candida tropicalis, White bacillus and Saccharomyces cerevisiae.
  • the weight ratio of the four bacteria is 2:2:1:1.
  • the inoculum ie, the amount of mixed bacteria
  • the temperature is 25 ° C - 30 ° C is better, the highest does not exceed 42 ° C, by
  • the automatic equipment rolls once every hour the fermentation time is 9 hours - 10 hours
  • the ventilation condition is 8min / h (that is, 8 minutes of ventilation per hour)
  • the ventilation is 0.2m 3 / h.
  • the heat source of this pre-fermentation section is provided by the waste heat generated by the heat source of other sections of the kitchen waste treatment work.
  • the pre-biochemically processed material is input into the main fermenter, wherein the treatment in the main fermenter comprises: the straw fermenting material and the material in the pre-biochemical treatment device are input into the main fermenter in the main biochemical device, and the input ratio of the material is: straw 10% - 40% of the total material weight percentage in the fermentation material, the baker's yeast fermentation material accounts for 20% of the total material weight percentage, and the second pre-biochemically treated fermentation material accounts for 40% - 70% of the total material weight percentage.
  • the double-layer ribbon stirrer 14 rotates 360 degrees under the driving of the power source, the rotation speed is 6-9 rpm, and the rotating motion is the round-trip direction.
  • the material is slowly stirred at a low speed.
  • the temperature in the main fermenter starts from the initial temperature of 20 °C, and the temperature is gradually increased to 28 ° C.
  • the air valve 23 is closed, and the temperature is raised to 35 ° C - 38 ° C.
  • the exhaust valve After 3 hours of constant temperature, open the exhaust valve and use the positive pressure in the main biochemical device to discharge the water.
  • open the wind exhaust device I112 when the fermentation material with the water vapor in the exhaust system into the gas-water separator means and an air treatment device for processing environment (not part of the invention).
  • the total secondary fermentation time is 9 hours.
  • the biochemical treatment device adopts the method of combined fermentation of anaerobic fermentation and aerobic fermentation, and the two-step fermentation of the main fermenter and the auxiliary fermenter realizes the effect of automatic biochemical fermentation, the structure is simple and reasonable, and the fermentation effect is good.
  • the automatic unloading multi-stage drying device of the present invention mainly comprises a pre-drying device J93 and a main drying device.
  • the pre-drying device J93 is installed above the main drying device, and the pre-drying device J93 is an accessory device of the main drying device.
  • the pre-drying device J93 is a horizontal sleeve design, and the material automatic flap J94 is provided inside, the implementation
  • the pre-drying device J93 is provided with a spindle in the middle
  • the material automatic flap J94 is a flipper plate fixedly mounted on the spindle, and the spindle can be driven to rotate by a motor disposed outside the pre-drying device J93.
  • the pre-drying equipment J93 is equipped with a screw auger automatic discharge device J95 (or automatic material discharge and discharge device) at the bottom, and the material pre-dried by the pre-drying device J93 is input through the screw auger automatic discharge device J95.
  • the automatic auger J95 of the auger auger has a cylindrical shape, and a screw auger is arranged inside, and the auger is driven by the motor to rotate.
  • the outer casing of the pre-drying device J93 is on both sides, and the inner casing J97 of the pre-drying device is formed between the two sides, and the inner cavity J97 of the outer casing is provided with heat-conducting oil, etc., and the hot exhaust gas of the main drying device is arranged by the pipe. After passing through the heat transfer oil layer of the pre-drying chamber J97, it passes through the outside of the equipment.
  • the heat source in the pre-drying device J93 is derived from the exhaust gas discharge port J96 of the main drying device, and enters the inner cavity J97 of the pre-drying device through the pipe, and heat is transferred by the heat transfer oil carried in the inner cavity of the interlayer, and The tail end of the heat pipe is introduced into the air treatment equipment of the rear end by the air introducing device J98, and the air with smoke, fine dust and moisture is collected and environmentally treated.
  • the main drying device in the present invention is provided with a gas or liquid fuel combustion chamber J99 and a burner J100, and a combustion gas or a liquid fuel is generated in the combustion chamber J99 by the burner J100 to generate hot air, which is introduced into the main drying device by the air guiding hood. Referring to FIG.
  • the middle of the main drying device is a horizontally rotatable cylindrical body J102 which is reversible in a 360 degree direction, and the front and rear ends of the main drying device are respectively fixed heads J101.
  • two or more sub-cylinders rotating in the direction of the main cylinder of the rotating horizontal cylindrical body J102 are provided inside the rotating horizontal cylindrical body J102, and the diameters and lengths of the respective cylinders are different, respectively
  • the outer tube is small, the outer tube is a fixed foundation and layered, and the hot air is used to dry the horizontal cylinder.
  • the cylinder body is provided with a plurality of rotating sleeves.
  • the material to be dried enters the innermost sleeve
  • the material advances. And then falling into the second layer of sleeve, at this time, the advancement direction of the material in the second layer sleeve is opposite to the advancing direction of the innermost sleeve, and the material is made to fall and advance in the multi-layer sleeve. Move until you reach the outermost main drum.
  • the plurality of inner cylinders are all circular in cross section, and a guide spiral ribbon is extended along the inner wall of the inner cylinder, and the spiral directions of the guide spiral ribbons on the adjacent inner cylinders are opposite to each other.
  • the outer side is installed with the airflow disturbing fin J103 in the circumferential direction for disturbing the airflow.
  • the installation angle of the deflector is 20 degrees - 30 degrees, which guides the gas to guide the flow.
  • the innermost cylinder The body moves with the main cylinder, and the kinetic energy of the movement is brought up by the mechanical rotation of the main cylinder.
  • the moving direction of the input material is guided by the guide nut and advances toward the discharge port of the cylinder.
  • the outer side of the outermost cylinder is provided with a sub-transmission wheel J111, the motor J108 drives the main transmission wheel J110 through the transmission J109, the main transmission wheel J110 drives the sub-transmission wheel J111 to rotate, and the auxiliary transmission wheel J111 drives all the cylinders.
  • the overall movement of the body, the guiding ribbons in the layers of the cylinder are set in different directions, and the material is guided by the guiding material.
  • the hot gas stream perturbs and washes the material, and the airflow is accompanied by a turbulent trajectory phenomenon (mixed layer), so that the transport and diffusion mode of the hot gas flow in the cylinder will be the key to drying the material.
  • the discharge port J104 falls into the inlet J105 of the secondary inner cylinder body, and is guided by the guide material ribbon and the heat.
  • the direction of the airflow is reversed and reaches the discharge port of the layer, and then falls into the feed port of the outer sleeve of the layer of the cylinder.
  • the material to be dried is made multiple times with the hot gas flow. After the reverse contact, it finally falls into the main rotating cylinder, that is, the outermost cylinder, and is guided by the guiding screw to the main discharge port J106, and is transported by the automatic conveying tool to the next section, in the automatic unloading
  • the other end of the multi-stage drying device is provided with a hot air discharge port J107, and the hot air discharge port J107 is connected to the outer casing interlayer J97 of the pre-drying device J93.
  • the working method of the automatic unloading multi-stage drying device of the invention is as follows: the protein nutrient feed (that is, the biochemically treated kitchen waste) which has been biochemically fermented is sent to the pre-drying device J93 through the material hoist, and the material is installed.
  • the stirring flap system in the pre-drying device J93 is turned at a speed of 10-18 rotations per second.
  • the inner cavity of the device has been passed through the hot exhaust gas of the main drying device through the interlayer of the pre-drying device J93 to pre-dry the device J93.
  • the temperature of the inner chamber is raised to 80 ° C - 120 ° C.
  • the residence time of the material in the pre-drying device J93 is 1.5 hours - 3 hours, and the hot humid air in the pre-drying device J93 is discharged from the exhaust port by the air-inducing device J98.
  • the material is sent to the innermost cylindrical body of the main drying device by the ribbon auger automatic discharge device disposed at the lower part of the pre-drying device J93, the main drying device inlet and The outlet temperature is 240 ° C - 280 ° C and 80 ° C - 120 ° C, at this time the material is in direct contact with the hot gas, and through the action of the spiral strips in the various layers of the drum, the forward flow is established to establish the heat transfer process, When the material is dried by the inner layer drum, it automatically enters the next layer of the drum, and the heat transfer process is established by the reverse flow method before entering the cylinder of the next layer.
  • each horizontal cylinder is 25-29 rpm.
  • the feed is directly contacted with the hot air flow after so many times of reverse direction.
  • the material is continuously dried and sent to the material selection by automatic conveying tools.
  • the device at this time has become an unselected protein nutrient feed.
  • the automatic unloading multi-stage drying device of the invention uses the secondary heat drying to dry the kitchen waste, and has the function of automatic unloading, the structure is simple, the drying effect is good, energy saving, and environmental protection are saved.
  • the dried protein nutrient feed is selected by the automatic conveying system into the selection device.
  • the material selection device of the present invention performs the final fine screening of the dried protein nutrient feed.
  • the front-end process of fine screening is to biochemically treat the kitchen waste. This section is the debris that has not been caught by screening in the previous process and the large organic matter that has not been completely decomposed in the biochemical process. Isolation from protein nutrient feed.
  • the equipment base K108 is used as the bearing foundation, and the protective cover K109 is installed on the upper part of the base K108 for preventing the material from running out.
  • the production protective cover K109 is provided with the inclined metal rolling screen cylinder K110.
  • the metal rolling The screen diameter ⁇ of the screen cylinder on the screen cylinder K110 is 4 mm - 6 mm, and the interval between the hole and the hole is 2 mm.
  • the inclination angle of the metal rolling screen cylinder K110 is 1 degree - 20 degrees, and The inclination angle is adjusted, and an adjustment bolt is arranged inside to adjust the inclination angle thereof.
  • the inner cavity of the downward end of the metal rolling screen cylinder K110 is provided with a spiral belt K111 along the cylinder wall as a guiding rail, and the weight is guided by the spiral belt K111. After the debris and large debris enter the dump outlet, they fall into the debris receiver K112.
  • a finished carrier K113 is mounted on the base K108 below the metal rolling screen cylinder K110, and a funnel-shaped receiving device is arranged under the metal rolling screen cylinder K110, and the material leaked through the metal rolling screen cylinder K110 The funnel-shaped receiving device falls onto the finished carrier K113.
  • the finished carrier K113 is in the shape of a conveyor belt, and the lower part of the finished carrier K113 is equipped with an automatic conveying tool K114, which is used for conveying the finished product into the warehouse or directly into the feeding preparation workshop of the next section.
  • a secondary selector is installed in the lower portion of the debris acceptor K112, and the debris falling into the debris receiver K112 is secondarily selected.
  • the secondary selector is connected by a chain plate.
  • the conveyor K115 carries the animal material forward, and the size object flapper K116 is installed in the front direction of the chain conveyor K115 near the tail end.
  • the size object flapper K116 is disposed at a position of not less than 5 mm above the chain conveyor K115.
  • the material size can be adjusted to adjust the distance between the object splitter K116 and the chain conveyor K115, and the material can be fed into the finished product conveying system through the gap between the object splitter K116 and the chain conveyor K115. After that, enter the finished carrier.
  • the working process of the material selection device in the invention is as follows: the dried protein nutrition feed (ie the kitchen waste product) of the invention, the input speed is about 30 kg/min - 80 kg / min, the material is rolled by metal
  • the rotation of the screen cylinder K110 advances along the oblique direction of the metal rolling screen cylinder K110, and the material is continuously turned in the metal rolling screen cylinder K110 with the metal rolling screen cylinder K110, and the large object or the heavy object is Rolling up and moving forward in the oblique direction and entering the guiding track of the spiral belt K111, is sent into the heavy debris and the bulk material receiving interface, and the finished product is smashed from the wall hole of the metal rolling screen cylinder K110 into the finished carrier K113 .
  • the material of the large-sized debris receiving device is sent to the chain conveyor belt.
  • the material is conveyed to the separation port of the object splitting gate K116, and the material capable of passing the gap of the object shunting gate K116 is the finished product.
  • the finished product conveying system After being sent to the finished product conveying system, it is sent to the finished product carrier, and the large piece of material or heavy debris is separated by the pneumatic feeder, and then dialed into the debris collection box.
  • the feed product produced by the kitchen waste is screened, and the screening efficiency is fast and the precision is high.
  • automatic processing such as automatic feeding and automatic discharging into the warehouse can be realized.
  • the produced feed can also be mixed by means of a mixed feed device.
  • the mixed feed device used in the present invention consists of a pulverizer, a cylindrical pulse dust collector L117, a spiral mixer L117L, a ring die granulator L118, and a countercurrent flow.
  • the cooler L118L and the rotary grading screening L119 and the automatic weighing and packaging device L120 are composed of six parts.
  • the waste plastic reversal engineering device is a device connected to the next section of the rolling molar E30 of FIG.
  • the waste plastic, waste paper, waste cloth and other debris sorted by the air flotation sorting device are taken out by the rolling caries E30, and enter the centrifugal dewatering equipment of the waste plastic reversal engineering device through the conveying system to carry out basic materials.
  • the main treatment device is taken from the conveyor belt M122 as the starting point, and the material is sent to the pneumatic automatic feeder M123 which can move forward and backward through the rail, and the raw material is sent to the cracking catalytic horizontal reactor M124 (reaction)
  • the structure of the kettle can be found in the Chinese patent publication No. CN102220152A and the publication No. 201660599U.
  • the reactor M124 can be rotated 360 degrees with an automatic random scraping device M125, and the material is added with oxidation in the reactor M124.
  • the synthetic fuel of the bio-oil product obtained from the project, and the combustible gas obtained by reversing the project, the production fuel used is self-sufficient, and the exhaust gas generated by the cracking furnace M126 during the combustion process is output from the gas outlet of the furnace body and is connected by a pipe.
  • Exhaust gas environmental protection equipment system M127 Exhaust gas environmental protection equipment system M127.
  • the material in the reactor M124 is cracked under anaerobic conditions to obtain an oil and gas mixture.
  • the vacuum system M130 is automatically opened, and the check valve of the reactor M124 is followed.
  • M128 is automatically opened, oil and gas first enter the oil wax separator M129.
  • the oil and gas enter the first-stage heavy oil separator M131 along the pipeline under the action of the vacuum equipment of the next stage, and the light oil and gas pass through the safety.
  • the water sealing device enters the first stage condenser M132, the mixed oil enters the oil carrying container M133, and the gas that cannot be liquefied is transferred into the negative pressure device M134 for cis and reverse gas rinsing, and the rinsed gas continues to enter the rear stage vertical water.
  • the sealed gas safety conveyor M135 compresses and dehydrates the combustible gas from the special secondary gas compressor M136, and then delivers it to the first stage gas compressor to compress the gas to 0.5mpa, and the second stage gas compressor compresses the gas to 1mpa, and the flammable gas is transported to the gas storage M137 for use.
  • the mixed oil After the mixed oil enters the oil-bearing container M133 to cool down, the mixed oil is input into the diesel refining equipment through a special oil pump, and the equipment is started from the first-stage chemical decarburization and decontamination synthesizer M138, and then enters the carbon removal rinser M139 and dewaxed.
  • the chemical agent required in the carbon removal rinser M139 and the dewaxing glue remover M140 is set in several chemical containers, and the liquid agent addition zone M141 and the solid agent addition zone M142, all additives
  • the automatic dosing device automatically feeds according to the set process.
  • the refined oil After the refined oil has passed the test, it enters the diesel synthesis equipment M143 to adjust the quality (according to the quality of each refinery, adjusted to the same quality and then shipped out), then enters the fixed bed filtration equipment for smooth and reverse double-layer filtration, followed by Qualified National III standard diesel is obtained and transferred to the warehouse.
  • a non-vaporizable residue that is, a crude carbon black
  • the crude carbon black may be treated by the crude carbon black treatment device for the residue after the anaerobic cracking.
  • the crude carbon black processing device comprises a coarse carbon black artificial aging processor N144, which is a device for aging materials by using ozone, after being chemically aged.
  • the crude carbon black then enters the physical aging bed N145, and the aged carbon bed is steamed under the condition of pressure 2.8mpa-3.2mpa for 25-35 minutes.
  • the above two artificial aging methods are implemented to implement the change.
  • the specific volume of the coarse carbon black forcibly changing the orderly characteristics of the external crystallization of the carbon black particles, helps the embedding and enhances the carbon-hydrogen ratio of the carbon black.
  • the crude carbon black is artificially aged, it is input into the material compatibility equipment N146 by a special automatic conveying tool.
  • the materials are divided into two categories: liquid and solid.
  • the remaining share of the weight of the material is treated crude carbon black.
  • Each of the compatibility aids is added by liquid and solid automatic dosing and feeding equipment N147.
  • the material is fully mixed into the low-sulfur high-energy environment-friendly clean coal by multi-layer push-pull screw N148.
  • Forming machine N149 after the material is formed, the finished product is called a low-sulfur high-energy clean coal.
  • the quality is 0.2-0.5% of total sulfur, the grade of coke slag is grade 1, and the ash is 5.5-7%.
  • the coarse carbon black used in this embodiment refer to the Chinese patent of the publication number: CN102220179A.
  • the collecting device, the kitchen garbage bag breaking device, the kitchen garbage liquid air flotation sorting device, the wet advanced oxidation, the deodorizing, the inactivation, the cleaning and salt reducing device, the primary solid separator and the vertical dewatering device All of them are provided with water outlet pipes, and the oil, water and solid mixture from the various outlet pipes are sent to the distillation-free biodiesel production device for diesel production. Please refer to FIG. 28 to FIG. 31 for the biodiesel in the present invention.
  • the front end of the manufacturing system is provided with an oil-water mixing tank O150.
  • the oil, water and solid mixture generated in each section of the kitchen waste treatment process is transported to the oil-water mixing tank O150 through the water outlet pipe, and the oil-water mixing tank O150 is disposed at the tail end of the water outlet pipe.
  • the horizontal end of the oil-water mixing tank O150 is provided with a horizontal spiral-belt solid-liquid separation device O151 for removing solids of oil, water and solid mixture.
  • the horizontal spiral-belt solid-liquid separation device O151 includes a lying The cylindrical casing has a filter screen inside the casing, and a conveying screw is fixed inside the filter screen, the motor is matched with the transmission to drive the filter screen and the spiral belt rotates, and the horizontal spiral belt solid-liquid separation device O151 is provided with oil and water mixing at the bottom.
  • the oil, water and solid mixture is input into the horizontal spiral belt solid-liquid separation equipment O151 through the pipeline through the pump, and after the liquid-solid separation by the horizontal spiral-belt solid-liquid separation equipment O151, the oil and water mixture is input through the conveying pipeline.
  • the oil-water separation tower O152 is disposed at the rear end of the horizontal spiral belt solid-liquid separation device O151, and the oil-and-water mixture after de-solidification is sent to the oil-water separation tower O152.
  • the oil-water separation tower O152 is a vertical cylinder.
  • the inlet port is disposed at the middle and lower sides of the side, and the oil-water separation tower O152 is internally provided with a heating pipe O153.
  • the heating pipe O153 extends from the lower part of the oil-water separation tower O152 to the inside of the oil-water separation tower O152, and then is output from the upper part of the oil-water separation tower O152.
  • the heat source used in the heating pipe O153 is the waste heat of the heat-conducting oil furnace, which can save energy use.
  • a heat source can also be separately provided.
  • the top of the oil-water separation tower O152 is equipped with an infrared water level locator O154 for positioning the oil-water mixture at the time of oil-water separation, and thereby automatically controlling the amount of oil-water mixture.
  • the oil-water separation tower O152 is provided with an oil scraper O155 (like a wiper to scrape off the oil) and an oil outlet pipe O156 on the side close to the upper portion.
  • the scraper O155 has a strip-shaped plate shape and is separated by oil and water.
  • the motor at the top of the tower O152 is rotated to scrape the oil in the oil-water mixture into the oil sump and output through the oil outlet pipe O156.
  • an electric valve O157 is provided on the oil discharge pipe O156, and the bio-oil is controlled to enter the oil storage container O149 from the oil discharge pipe O156 through the electric valve O157.
  • biodiesel production is carried out by using the grease removed from the kitchen waste.
  • the front end of the biodiesel production device is a grease colloid removal device O158.
  • the grease colloid removal device is used.
  • O158 is a rectangular shape, and the grease gel removal device O158 is fixedly provided with a hole impact plate O159 in the middle, and a hole is formed in the impact plate O159.
  • the two facing positions of the impact plate O159 are respectively installed with a rotary hydraulic propulsion machine O160.
  • the rotary hydraulic propulsion machine O160 includes a propeller blade disposed inside the grease gel removal device O158 and a motor disposed outside the grease gel removal device O158, and the motor drives the propeller blade to rotate.
  • the bio-oil material is input from the oil storage container O149 into the oil gel removal device O158 by a special oil pump to effectively remove the phosphorus ester, sugar, protein and other impurities in the oil, and prevent the glue.
  • the quality covers the fine particles of grease in the latter stage, and the barrier grease contacts the catalyst.
  • the ozone oxidation processor is composed of an ozone generator O174, an anti-liquid recoil valve O175, a powerful gas, a liquid mixer O176, a reactor O177, a circulation pump O178, an oil inlet pipe O179, an oil outlet O180, and a liquid.
  • ozone generator O174 is connected with strong gas and liquid mixer O176 through anti-liquid recoil valve O175, strong gas and liquid mixer O176 through oil inlet pipe O179 and grease colloid
  • the removal equipment O158 is connected, the powerful gas and liquid mixer O176 is connected to the reactor O177 through a pipeline, the circulating pump O178 is connected to the reactor O177, the bottom of the reactor O177 is the oil outlet O180, and the oil outlet O180 is passed through the pipeline and the bio-oil.
  • the normal temperature grease exchange equipment O161 is connected, the liquid level controller O181 is installed in the reactor O177, and the ozone residual gas destroyer O182 is installed on the top of the reactor O177.
  • a theorem feeder O183 is also mounted on top of the reactor O177.
  • the oil and fat can remove impurities, pigments, odors, proteins, and the like from the fat by the ozone oxidation processor.
  • the main body of the biodiesel production device is a bio-oil normal temperature grease exchange device O161.
  • the bio-oil normal temperature grease exchange device O161 is a cylindrical cone-bottom reaction kettle, and the bio-oil normal temperature grease exchange device O161 is equipped with more than one ultrasonic wave.
  • the generator O162 in this embodiment, is provided with four, each of the ultrasonic generators O162 is respectively provided with a sleeve O163, a sleeve O163 is surrounded by an internal threaded jet hole O164, and a sleeve is fixed above the sleeve O163.
  • a pneumatic take-off device O184 is connected above the locking device O165, and acts on the depth of the inlet of the control sleeve O163 and the ultrasonic transducer O162 in the bio-oil normal temperature grease exchange device, and the ultrasonic generator O162 is passed through the card holder O165. It is installed inside the bio-oil normal temperature grease exchange equipment O161.
  • the bio-oil normal temperature grease exchange equipment O161 is equipped with a liquid guiding tube O166, one end of the liquid guiding tube O166 is connected to the upper part of the bio-oil normal temperature grease exchange equipment O161, and the other end is connected to the bottom of the bio-oil normal-temperature fat exchange equipment O161, and the pump O167 is connected at Liquid conduit O166.
  • the top of the bio-oil normal temperature grease exchange equipment O161 is equipped with a top cover O168, the top cover O168 is provided with a feed port O169, and the bio-oil normal temperature grease exchange device O161 is equipped with a window O170.
  • a gas pipe O171 is provided at the bottom of the bio-oil normal temperature grease exchange device O161, and one end of the gas pipe O171 is connected to the compressed air machine.
  • methanol and a co-solvent are added from the feed port O169.
  • the co-solvent should be selected to enhance the mutual solubility of the oil and the methanol, and to be recyclable.
  • the ultrasonic generator O162 is introduced into the bio-oil from the top to the bottom of the bio-oil normal temperature grease exchange device O161 by pneumatic or hydraulic tools, and the compressed air is blown from the bottom of the bio-oil normal temperature grease exchange device O161. , thereby promoting the accelerated co-solubilization of bio-oil and methanol, and inputting the bio-fat mixture to the inner cavity of the casing O163 through the oil pump O167, flowing from top to bottom into the ultrasonic treatment, and the ultrasonic frequency is gradually enhanced from 25KHz to 30KHz, the time is 20 - 60min.
  • the liquid separation device O172 is in the form of a vertical cylinder, and the liquid separation device O172 is provided with a filtering device O173 at the rear end of the liquid oil normal temperature grease exchange device O161, and the mixing after the ultrasonic treatment is completed.
  • the liquid is supplied to the liquid separation device O172, and the obtained crude biodiesel is obtained by the filtration device O173 to obtain biodiesel.
  • the method for producing biodiesel that is, the method for operating the above biodiesel manufacturing system, comprises the following steps:
  • the oil-water mixture is sent to the oil-water separation tower O152 for oil-water separation.
  • the oil-water mixture in the oil-water separation tower O152 is heated to 60 ° C by using the residual heat of the heat-conducting oil furnace - 85 °C, after the biological grease floats to realize the oil moisture layer, the lower layer of water is sent to the sewage treatment system by the conveying pipeline, and the upper layer of the biological grease is scraped out by the scraper O155, and sent into the oil storage container through the oil outlet pipe O156;
  • the bio-fat is sent into the grease colloid removal device O158 by a pump or the like, and then the hydro-pneumatic propulsion machine O160 is started, and the concentration is 85%.
  • the ratio of phosphoric acid, phosphoric acid and bio-oil is not more than 1% of the total amount of grease.
  • the liquid-pulling thrust at both ends of the O158 is removed by the grease colloid removal device, and the liquid inside the O158 is removed.
  • the impact time is established. Within the required time range of the set process conditions, in the present embodiment, the collision time is 10 min - 15 min, and after the end of the liquid impact time, the diluted brine is immediately added, and the weight ratio of water to salt is 95:5. Between 90:10, the weight ratio of bio-oil to dilute brine is between 90:10 and 80:20.
  • the action of electrolyte salt accelerates flocculation and the formed micelles are more stable;
  • the solid catalyst is characterized by the reagent activated carbon and the nanoparticles of the silicate mineral of the cyclic structure of aluminum, sodium, iron, magnesium and lithium.
  • the base nucleus itself can release 12,000/cm 3 or more negative ions as qualified products, and then immerse the base nucleus in a mixed liquid of alkaline silica sol and aluminum sol and lithium hydride, and take it out at a temperature of 650-720 ° C. After constant temperature for one hour, after cooling, it is screened and refined to form a hybrid medium with silicon, aluminum and lithium mesh, and a polar hybrid carrier. The carrier is then immersed in the solution of KNO 3 . After taking out, drying in a drying apparatus at 110 ° C to obtain a basic catalyst carrying 15% - 25% of KNO 3 .
  • the initial frequency of the ultrasonic generator O162 is 25KHZ, the time is 1min, and then gradually increase to 30KHZ, the time is 30min - 40min, the reaction temperature is 25 - 35 °C.
  • the bio-fat mixture is input into the liquid separation device O172, and the upper layer is a mixed liquid of methanol and glycerin, and the lower layer is crude biodiesel;
  • the liquid separation device is set to be opened in the lower liquid discharge port, and the crude biodiesel is transported into the filtering device O173, and the purified biodiesel is obtained after filtration and the solid catalyst is recovered, and can be recycled after being recycled.
  • the biodiesel is then fed into a storage container for further refining, while the methanol and glycerin mixture is used for other purposes.
  • the biodiesel manufacturing system of the invention can automatically separate the solids, moisture and the like contained in the kitchen waste, and then further convert the contained fats and oils into biodiesel for use, the device structure is simple, the process, the energy saving and the production cost are low. .
  • the distillation-free biodiesel production device produces crude biodiesel, and the crude biodiesel is further emulsified by the emulsified biodiesel device to form emulsified biodiesel.
  • the device is mainly a housing P174.
  • the upper portion of the housing P174 has a straight cylindrical shape, and the lower portion is a semicircular body.
  • the housing P174 is internally provided with a vertical agitator P175, and the power source drives the vertical agitator P175 to rotate.
  • the power source includes a motor P176 and a shifting device P177 fixedly mounted on the top of the housing P174, the motor P176 being disposed above the shifting device P177, and the motor P176 driving the vertical agitator P175 to rotate by the shifting device P177.
  • a support frame P180 of a rotating shaft is provided in a semicircle at the bottom of the casing P174 for supporting the rotating shaft of the vertical agitator P175.
  • the vertical shaft of the vertical agitator P175 is equipped with a plurality of slurry type straight mixers P178, and can also be replaced by paddle type leaf blades.
  • the lower part of the central shaft of the vertical mixer P175 is equipped with a turbine or a disk.
  • the curved blade slurry P179 and the cylindrical inner wall of the casing P174 are provided with a plurality of liquid guiding vanes P183 (provided inside the casing P174 to act as a spoiler), and a plurality of inlet ports P181 are arranged at the top of the casing P174.
  • Each of the feed ports P181 is connected to the dosing device P182 through a pipe.
  • each dosing device P182 is used for automatic feeding of various additives.
  • the top of the casing P174 is further provided with an oxygen-enriched water inlet pipe P186 and penetrates into the casing P174 to connect the oxygen-enriched water atomizing nozzle P185, the inlet pipe P186 is connected to the high-pressure pump P187, and the ozone generator P188 outputs the O3 gas to enter the strong water and gas.
  • the mixer P189 is mixed with water, it is sent to the oxygen-enriched water reserve tank P191 through the conveyance of the pipe P190, and the water outlet of the oxygen-enriched water reserve tank P191 is connected to the high-pressure pump P187.
  • the upper part of the casing P174 is provided with an oil inlet port P192, one end of which is threaded inside the casing, and the other end is connected with the oil pump, and the lower part of the casing P174 is also provided with a finished discharge port P184, and the obtained emulsified biodiesel is discharged from the discharge port P184.
  • the output is then sent to the oil storage through the pipeline and the pump.
  • the oxygen-enriched micro-emulsified biodiesel produced in the present invention acts on various heat source fuels.
  • the method for preparing the emulsified biodiesel in the present invention that is, the operation method of the above device in the present invention is as follows: the present invention is mainly directed to further processing of biodiesel produced by a production process from oil and fat, and oxygen-enriched microemulsification of biodiesel. Refined diesel technology.
  • the method for preparing the emulsified biodiesel in the present invention comprises the following steps:
  • the hydrophilic agent is a composite active agent combined with a cationic surfactant and a nonionic surfactant.
  • the two types of surfactants are triethanolamine, hexahydroaniline or west. Tribromoammonium bromide and ammonia water, the ratio is 50% of cationic surfactant and 50% of nonionic surfactant.
  • the hydrophilic agent is used to degrade the rigidity of the mask, increase the fluidity, reduce the bending energy required for the formation of microemulsion, and is easy to form.
  • the milking solution is stirred for 1 min to 15 min after the hydrophilic agent is added;
  • butanol can be used as a co-surfactant, and continue to do not indirectly stir the mixture for 15min, when stirring, the vertical stirrer 2 for 100 rev / min - Stirring at 130 rpm;
  • isopentane as a self-ignition temperature regulator.
  • isopentane is mixed with the above liquids of (1)-(3) and stirred for 5 minutes.
  • the amount of oxygen-enriched water varies from 1% to 20% of the total weight of the product depending on the product, in this embodiment,
  • the ozone generator supplies O 3 , the gas flow rate of ozone transport is 250ml/min, and is mixed with the water body in the powerful water and gas mixer, and then input into the oxygen-rich water storage tank to be naturally decomposed into oxygen enriched in water, and the natural decomposition time is 30 min.
  • the dissolved oxygen content in the water reaches 27-35%, forming oxygen-enriched water.
  • the oxygen-enriched water is added in an amount of 10%-20% of the total weight.
  • the mixture is stirred for 15 minutes, and the rotation speed is adjusted to 170 rpm.
  • octadecyl-cis-9-ene The acid is added in an amount of 70% to 90% by weight of the oxygen-enriched water added, and is continuously condensed until the clarification is transparent under the stirring of the stirring device.
  • the rotation speed of the agitator is adjusted to 280-340 rpm, generally Continuous stirring is required for 40-60 minutes.
  • micro-emulsified diesel fuel produced by petrochemical diesel can be used as a heat source fuel, and the micro-emulsified diesel oil containing less than 10% of oxygen-rich water and containing more than 80% of the national standard III petrochemical diesel can be used as a diesel fuel for cleaning vehicles.
  • the biodiesel extracted from the kitchen waste can be further refined by the invention to produce oxygen-enriched micro-emulsified biodiesel, which can expand the application range.
  • the invention also provides a rapid sewage treatment and recycling device, and the wastewater generated in all the production processes in the invention is concentrated and rapidly processed into qualified industrial water reuse, and is used as the production water for the kitchen garbage resource treatment.
  • the rapid sewage treatment and recycling device firstly allows sewage to enter the sewage filtration tank Q185, and uses the debris in the sewage filtration tank Q185.
  • the gate Q186 is isolated from the impurities in the sewage.
  • the debris block Q186 is also provided with an anti-plug back buffer Q187.
  • the sewage after passing through the fence Q186 is input by the water pump into the hot felt sewage treatment device Q188.
  • the device has a cavity Q189.
  • the casing Q190 the sewage enters the top of the casing through the pressure pump, and the discharge pipe also has a venting port Q191, and the top of the casing is provided with a plurality of atomizing spray heads Q192 communicating with the inlet pipe, and the atomizing spray head Q192
  • a hot and hard felt Q193 ie, two-layer structure, upper layer, lower layer, and two layers of misalignment
  • the hot felt Q193 has multiple shallow shallow grooves on the surface of the Q193 (the shallow ditch Q194 is criss-crossed).
  • the heat source of the hot felt Q193 is heat transfer of the heat transfer oil pipe Q195, the felt surface temperature is controlled between 90 and 200 ° C, and the bottom of the hot felt Q193 is provided with a micro solid.
  • the water body flows between the hot felt Q193 and the high temperature resistant cushion Q199 into the bottom of the inner cavity of the equipment.
  • the top of the casing Q190 is provided with an automatic suction and exhaust valve Q200, and the casing Q190 is located above the hot felt Q193 for hot steam collection.
  • Port Q201, the hot steam collecting port Q201 is connected to the heat exchanger Q202 through a pipe, converts the hot water steam into a water body to the collecting tank Q203 and merges with the discharged water body on the lower side of the casing, and pumps the water body of the collecting tank Q203 from the pool.
  • this system is an ozone-water reactor, which is a sleeve-type structure with two inner and outer cavities, the inner chamber is a gas-water reaction chamber Q205, and the outer chamber is a gas-water circulation reaction buffer chamber Q206.
  • the inner cavity has an inner casing, and the outer cavity has an outer casing.
  • the top of the inner casing is provided with an automatic exhaust valve Q207 and a liquid level control online monitor Q208 for monitoring the liquid level, and the ozone-water reactor inner cavity Inlet inlet tube
  • the end position is equipped with activated carbon reaction ball Q209.
  • the reaction ball Q209 is used to accelerate the conversion of ozone into hydroxyl radicals in water, so as to accelerate the degradation rate of organic matter in the water by ozone.
  • the upper part of the reaction ball Q209 is impervious to water and the lower part is mesh.
  • the ball is filled with granular activated carbon, and the volume of activated carbon contained in the ball accounts for 15% to 95% of the volume of the reaction sphere.
  • the gas-water mixture in the inner chamber is transported to the outer chamber through the inner and outer chamber connecting pipe Q213 of the reactor, and then the water pump Q211 provided outside the advanced oxidation reactor is supplied with the water-in-water mixer to replenish the ozone, and then re-enters the inner chamber to allow the gas.
  • the water mixture was subjected to such a cyclic motion for 2 to 5 minutes.
  • the reaction of the gas-water mixture reaches a set time, it is discharged from the drain port Q212 provided on the bottom side of the inner chamber, and the residual sludge is discharged through the drain port Q212 at the bottom of the reactor, and the drain port is the drain port of the outer casing.
  • the gas water mixer Q215 mentioned above is installed at one position of the circulating pipe in the advanced oxidation reactor, and the mixer is a three-way connection method.
  • the circulating water is connected to both ends, and one port in the middle is connected with the waterproof check valve Q216, and the other interface of the waterproof check valve Q216 is connected to the gas pipeline of the ozone generator, and leads to the gas, water and material mixer Q217
  • the water body enters the transfer tank Q218, and then the water body is sent into the activated carbon filter fixed bed Q219 for treatment, and then enters the composite filtration device Q220.
  • the filtering mode of the device is to carry out the bottom-up reverse direction by pressurization. After filtration, the initially filtered water body is transported into the composite filtering device Q220 through a water pump and a pipeline.
  • the device Q220 is composed of a plurality of sets of filter tanks Q221, and the filter tanks are respectively provided with a plurality of vertical types.
  • the filter column Q222 has a water outlet hole at half of the length of each filter column Q222.
  • the bottom of the filter column Q222 is equipped with a filter screen of 80-140 mesh, the working pressure is 0.5-1mpa, and the top of the filter tank Q221 has a water inlet.
  • the tank body is divided into two layers, a sealing partition plate Q225 is installed between the tank and the tank, and each layer of the tank is respectively provided with a filter column tray Q226, which is opened on the Q226.
  • the diameter of the filter column Q222 is matched, and the number of holes is also the same as the number of the filter column Q222 to be installed.
  • the contact edge of the Q226 pallet and the filter column Q222 are provided with a leakproof seal Q227, the upper tank
  • the upper side is installed with water inlet diversion pipe Q228, the inflow diversion pipe Q228 is connected to the upper part of the lower tank, the lower side of the upper tank is provided with the water diversion pipe Q229, and the outlet diversion pipe Q229 is connected to the lower tank.
  • the lower part is provided with an exhaust port Q230 on the upper and lower sides of the can body.
  • Each filter column Q222 is equipped with two kinds of solid adsorbents, the lower layer is activated carbon Q231, and the upper layer is hybrid charge adsorbent Q232.
  • the joint mode of the two adsorbents is random joint, and the water outlet after water filtration is set in composite filtration.
  • the side of the bottom of the device is Q233, and the center of the bottom head is provided with a sediment discharge port Q234.
  • the water body treated by the composite filter device has reached a level of clear turbidity, no odor, no heavy metal ions, and has been basically
  • the ozone gas and the generated strong oxidant are removed, and the clean water treated by the composite filtering device directly enters the ultraviolet sterilizer Q235 to perform the final step treatment on the water body, and the obtained qualified water body acts on the production water.
  • the operation method of the rapid treatment and reuse device for sewage is as follows: all the sewage in the whole process of the kitchen waste recycling process is concentrated into the sewage collection basin through the discharge pipe, and the debris contained in the sewage is coarsely blocked.
  • the grid is isolated, and the water enters the hot felt sewage treatment equipment.
  • the sewage is sprayed to contact the hot felt body, the water body instantaneously contacts the hot plate in the shallow groove, the microorganisms basically die, and the hot water vapor rises upward and rises.
  • the hot mist water vapor is introduced into the heat exchanger by the hot steam collecting port and returns to the liquid water.
  • the precipitation zone is discharged from the sewage outlet located at the bottom of the microsolid precipitation zone, and the supernatant is discharged from the drainage port at the upper portion of the microsolid precipitation zone, and after being merged with the water body liquefied by the heat exchanger, the advanced oxidation reaction device is input through the pipeline.
  • the water enters the powerful gas-water mixer and is strongly mixed with the ozone gas supplied by the ozone generator, and then enters the ozone-water reactor.
  • the charcoal reaction ball passes through the sewage water net of the reaction ball and enters the gas-water mixed water body circulation system of the reactor, and the water pump continuously circulates the water body in the inner cavity and the outer cavity to act on the advanced oxidation reaction, and the reaction time is 2-5 minutes.
  • the concentration of ozone in the water is 1 - 5g / T.
  • the ozone in the water is activated by activated carbon to initiate a chain reaction in water to accelerate the conversion of ozone into hydroxyl radicals, similar to O 3 /H. 2 O 2 or O 3 /UV advanced oxidation process, the residue of the precipitate layer in the lower part of the reactor is periodically discharged from the sewage outlet.
  • the water body first enters the fixed bed of activated carbon for reverse filtration, and then outputs the pressure control valve to the composite filtration device.
  • the water body first passes through the filtration layer of the hybrid charged absorbent, and the adsorbent is not solid.
  • the polar adsorbent is a base nucleus, and the outer layer is coated with a combination of a silicon-aluminum microporous skeleton and a polar absorbing agent.
  • the adsorbent acts on various inorganic and organic substances hidden in the water.
  • the heavy metal ions in the water body produce larger and faster adsorption.
  • the water body treated by the hybrid charge adsorbent naturally passes through the activated carbon adsorption layer, it is refined, and then enters the ultraviolet sterilizer to perform the final step on the water body.
  • the treatment uses ultraviolet radiation in the sterilizer, the intensity is 2600-3000UW/cm 2 , the wavelength is 235-258nm, and the irradiation time to the water body is 1-4s. When the water body completes the whole process, it enters the cistern container. As production water for the treatment of kitchen waste.
  • the sludge adhered to the kitchen waste is processed by the hybrid charged adsorbent production device.
  • the hybrid charged adsorbent production device can process the pollution of the inevitable attachment of the kitchen waste.
  • the utilization of the sludge in the mud and the plant area is the best choice for the non-transfer treatment of environmentally friendly residues, and it is also the implementation and application of the pollution control method.
  • the production method of the hybrid charged adsorbent is mainly for the cumbersome use of microorganisms in the sludge, and the technical requirements are high, and under a condition of natural dryness, the microbial cells are only metabolically treated in a stagnant state, not Death, and a key problem that can be revived once the moisture is given, and a solid adsorbent is produced by using a microbial individual or a dead microorganism individual living in the sludge as a pore module.
  • the hybrid charged adsorbent production device is forcibly inactivated by manually forcibly inactivating the sludge by the artificial inactivater R236.
  • the treated sludge is sent to the curing equipment R237 through the automatic conveying equipment for curing or semi-curing process.
  • the solidified or semi-solidified sludge is transferred by the automatic conveying equipment.
  • the pellet is fed into the sludge propeller R238, and the sludge is pushed into the anaerobic pyrolysis reactor R239.
  • the sludge propeller is installed on the guide rail. When the feed is fed, the outlet is connected to the reaction tank inlet, and if the feed is completed When the propeller can retreat by itself, the discharge port is separated from the feed port of the reaction kettle, and the inlet of the reaction kettle is sealed and closed.
  • the outer shell of the reaction kettle is a furnace body, the reaction kettle is installed horizontally, and the other end of the same axial direction of the feed inlet is provided with a vapor outlet, and the vapor outlet is controlled by a one-way automatic valve, and the reaction kettle is at a set pressure.
  • the valve is automatically opened, and the vapor enters the water-sealed combustible gas collection and processing device R240.
  • the combustible gas rises into the heat exchanger through the water seal interface, the non-liquefiable gas generated is combustible gas, and the return pipeline is returned to the pyrolysis furnace for use as a gas.
  • the heat source fuel is reused, and the hot flue gas discharged from the cracking furnace is treated by the fuel cracking furnace tail gas processing system R241 together with the hot flue gas generated by the other materials in the kitchen waste recycling process.
  • the sludge crevice moisture that has completed the anaerobic heating has been forced into water vapor and discharged with the combustible gas.
  • the set pyrolysis time is completed, the microbial dead body residue contained in the sludge in the reaction vessel is coked, and the sludge formation rate is consolidated.
  • the discharge port of the reaction vessel is opened, and the reaction kettle is used.
  • the automatic discharge screw belt unloads the sludge, transfers it to the pipeline type spiral belt conveyor and sends it to the aging warehouse R242. It is naturally aged for 12 to 48 hours, and then the naturally aged microporous sludge particles are placed.
  • the acidification time is 12-18 hours, which acts to remove the dead bodies of the coked microorganisms, and at the same time acts to remove the metal impurity ions and causes the pore structure skeleton of the particles to be exposed, so that the hydrogen ions
  • the sludge particles after the acidification process are sent to the hot water rinse tank R244 for rinsing, and after adjusting the pH to 6.5-8, the rinsed granular material is transferred into the hot steam by the conveying device.
  • Bed R245 undergoes a preliminary physical activation with an activation time of 1.5 to 2.5 hours.
  • the physically activated microporous particles are placed in a high temperature anaerobic activation furnace R246 for high temperature activation for 1-4 hours, and the controlled heating rate is 15-30 ° C / min.
  • the exhaust gas of the activation furnace is discharged into the tail gas environmental protection treatment system. .
  • the screened finished product is a non-polar microporous adsorbent, which becomes the base of the hybrid charged adsorbent.
  • the mixed liquid of acidic aluminum and silicon solution is thoroughly mixed with the non-polar microporous adsorbent, and then processed into a high temperature furnace, the temperature is 650 ° C - 700 ° C, the temperature is constant for 1 hour, and the material is taken out and pulverized.
  • the core of the nano-scale micropores and pores is a non-polar adsorbent and the outer layer is loaded with a polar micro-porous sorbent composition of a silicon- or aluminum-mesh skeleton medium-mixed charged adsorbent, which can be used for meals.
  • the treatment of sewage produced In the treatment of kitchen waste resources, the treatment of sewage produced.
  • the hybrid charged adsorbent production device and the manufacturing method thereof are as follows: the sewage generated in the whole process of the kitchen waste resource treatment and the domestic sewage in the plant area are treated and reused in the residual sludge.
  • the sludge is first input into the manual forced inactivation equipment, and the vertical circulating conveyor cassette in the equipment allows the sludge to reverse from the top and bottom.
  • the reaction time is 5-20 min, and the ozone dosage is 12 g/kg.
  • the sludge enters the primary curing equipment from the automatic conveying system.
  • the equipment is composed of horizontal multi-layer ribbons.
  • the steering of the ribbons and ribbons is reversed and smoothed.
  • the action of twisting, tearing and tumbling is strongly sheared, and the additive is added by the dosing device for 20-25 min.
  • the sludge temperature has naturally risen to about 60 ° C, and the sludge is granulated into a large size.
  • the inlet of the reaction kettle is automatically retreated by the guide rail. At this time, the cover of the reaction port of the reaction kettle is sealed and closed, and the inside of the kettle is in an anaerobic operation state.
  • the temperature in the kettle is 30 ° C / min, the final temperature is 220 ° C, and the temperature is kept constant for 1 hour.
  • the sludge is heated in the kettle. During the solution, water vapor and flammable gas will be generated.
  • the one-way valve at the rear end of the reactor is automatically opened, and the vapor and flammable gas mixture is pressed into the water-sealed safety equipment and allowed to contain water.
  • the gas enters the heat exchanger, and the non-liquefiable gas generated at this time is flammable gas, and is returned to the pyrolysis furnace through the pipeline as a supplementary raw material for the heat source.
  • the automatic discharge screw provided in the kettle is discharged from the discharge port on the side of the kettle, and sent to the aging warehouse by the conveying equipment, which is naturally aged for 12-48 hours, and then will be naturally aged.
  • the sludge is placed in the acidification equipment, and the sludge is statically immersed for 12 hours in a concentration of 20% sulfuric acid solution, which acts to remove the dead body residue of the coking microorganism and remove the metal impurity ions, so that the hydrogen ion replaces the additive. Calcium ion.
  • the sludge has exposed the pore structure skeleton of the particles, and the acidified sludge particles are put into a hot water rinser at 80 ° C for rinsing and pH adjustment, and then enter the hot steam bed for physical activation, and the hot steam flow rate is 250 mL/min.
  • the activation time is 1.5 hours, and the physically activated sludge particles are input into the high temperature resistance furnace, the heating rate is controlled to be 20 ° C / min, the activation temperature of the isolated air is 650 ° C - 700 ° C, and the constant temperature activation time is 1 hour - 1.5 hour.
  • a non-polar adsorbent has been prepared as a base nucleus of the hybrid charge adsorbent. Further, the prepared non-polar adsorbent is further processed into particles of a certain size, and then uniformly mixed with the acidic aluminum solution and the silicon solution. When mixed, the weight ratio of the non-polar adsorbent, the acidic aluminum solution and the silicon solution is mixed. 20:20:10, the mixture is placed in a high temperature furnace, the treatment temperature is 680 ° C -720 ° C, constant temperature for 1 hour, after the temperature is reduced, the hybrid charge adsorbent is prepared.
  • the exhaust gas, the hot flue gas, the dust, the exhaust air, and the like generated in each process of the kitchen waste recycling treatment are collectively processed by the exhaust gas environmental protection processing device to ensure that the air discharge port has no irritating odor discharge, No harmful toxic gas emissions, no odorous gas emissions, no micro-particle emissions, no room temperature emissions.
  • the exhaust gas environmental protection device of the present invention mainly comprises an exhaust gas buffer device, an air inlet, a primary purification pipeline, a primary gas, water, and a solid.
  • the starting point of the whole system is the exhaust gas buffer S247
  • the outer exhaust buffer S247 has a cylindrical shape and the bottom is Conical
  • exhaust gas buffer S247 is provided with a plurality of air inlets S272 inside the casing
  • the air buffer chamber is filled with water body
  • the top end surface formed by the water body is the water body interface S248,
  • the bottom of the exhaust gas buffer S247 is equipped with the sewage outlet S249.
  • the sewage outlet S249 is connected to the inside of the circulating water tank S258 through the pipe section
  • the circulating water tank is connected with the water circulation pipe 4, which acts on the water body inside the buffer to ensure the interface position of the water body and the water body to cool down.
  • an in-line liquid level monitor S251 is also installed in the exhaust gas buffer S247 for real-time monitoring of the water body interface height inside the exhaust gas buffer S247.
  • a circulating water tank S258 is arranged outside the exhaust gas buffer S247, and the circulating water tank S258 is connected to the sediment pool S270 through the pipe section.
  • the sewage outlet S249 side in the exhaust gas buffer S247 communicates with the upper part of the circulating water tank S258 through the pipe section S275, and the water pipe is arranged on the pipe section.
  • the upper part of the circulating water tank S258 is connected to the automatic circulating water pump S252 through the pipe section, and the automatic circulating water pump S252 water outlet is connected to the middle of the exhaust gas buffer S247, and the circulating water is discharged through the water curtain spraying nozzle 26 in the exhaust gas buffer.
  • the upper side of the exhaust gas buffer S247 is provided with a primary flue gas treatment pipe S253.
  • the upper, the left and the right sides of the primary flue gas treatment pipe S253 are misplaced with a plurality of negative ion-charged ceramics S254, the negative ions.
  • the charged ceramic does not need to be powered to start, and can naturally release negative ions.
  • a high-speed water mist nozzle S255 and a concave obtuse angle deflector S256 are installed, and the high-speed water mist nozzle S255 is behind the negative ion-charged ceramic S254.
  • the multi-layer water curtain is formed at the end, which is a high-pressure water mist area of negative ions, and the obtuse angle baffle acts on the instantaneous airflow path direction of the high-speed flue gas, so that the moving direction of the dense dust particle does not flow along the gas direction.
  • the primary flue gas treatment pipeline S253 is inclined, the front end of the primary flue gas treatment pipeline S253 is connected to the exhaust gas buffer S247, and the primary gas, water and solid separator S257 is connected to the rear end of the primary flue gas treatment pipeline S253.
  • a carbon slag filter S271 is disposed under the gas, water, and solid separator S257 for filtering the carbon residue in the sediment in the primary gas, water, and solid separator S257.
  • the primary gas, water, and solid separator S257 is connected to the twin-tower rotary sprinkler system S259 through a water-gas mixing conduit.
  • the water body is sent to the next-stage water-gas mixing pipe, but the gas is introduced into the twin-tower rotary sprinkler system S259 by the draft fan device.
  • the double-tower rotary sprinkler system S259 includes two vertical processing towers arranged side by side. After the flue gas first enters one of the processing towers, the gas flows from top to bottom into the lower part of the other tower body.
  • the gas is further operated from bottom to top in the lower part of the tower, and at the same time, the rotating high-pressure nozzle S260 installed around the periphery of the double tower sprays water on the gas, and the gas is smoothly cleaned, and the bottom of the double tower is provided with a water outlet S261.
  • the water outlet S261 flows into the water and gas mixing pipe, and the cleaned hot flue gas has been formed into the water and gas mixing pipe S263 by the air introducing device S262 installed outside the tower.
  • the water The gas mixing pipe S263 is installed in a horizontally inclined manner to connect the air guiding device.
  • the water and gas mixing pipe S263 has a slightly higher end and the other end is slightly lower, and the water body discharged from the water outlet of the lower part of the double tower rotary sprinkler system S259
  • the hot gas derived from the induced draft fan directly enters the water and gas mixing pipe S263 to the slightly lower end and enters the flue gas discharging device S264.
  • the flue gas discharge device S264 includes three parts, the lower part is a tank S265, and the top of the tank S265 is connected to a heat exchanger S266, and the upper part of the heat exchanger is a gas.
  • the discharge pipe S267 wherein the lower tank S265 is connected to the water outlet of the water and gas mixing pipe S263, and the wet slag discharge port and the water outlet S268 are provided on one side of the lower tank S265.
  • the circulating water in the heat exchanger S266 is supplied from the cooling tower S269, and the cooling tower S269 sucks the water in the sedimentation tank S270 through the pump and delivers it to the heat exchanger S266 through the pipeline, and the hot water in the heat exchanger S266 After the gas is cooled, when the hot water enters the heat exchanger S266, the steam is cooled and liquefied into a water body to fall, enters the lower tank S265, and is discharged through the water outlet S268, and the dry gas that cannot be liquefied is discharged from the discharge port.
  • the gas discharge temperature is not higher than 38 °C.
  • the exhaust gas environmental protection treatment device of the present invention mainly comprises an exhaust gas buffer device added to the front end of the exhaust gas treatment system, and the structural design thereof.
  • the structure of other parts of the exhaust gas environmental protection treatment device of the present invention can be referred to the prior Chinese patent application for application. No. 201010168879.2, the publication number is CN101816874A, and the structure of the patent is substantially the same as the exhaust gas environmental protection treatment device in the present invention.
  • the exhaust gas environmental protection treatment device of the present invention can centrally treat the flue gas, hot flue gas, dust, and exhaust air generated in each process of the kitchen waste resource treatment, and ensure that the air discharge port has no irritating odor discharge, and no Harmful and toxic gas emissions, no odorous gas emissions, no micro-particle emissions, no room temperature emissions.
  • the exhaust gas environmental protection treatment device of the present invention can desulfurize the exhaust gas and reduce the carbon dioxide emission, and can also remove the carbon dust particles contained in the exhaust gas, thereby achieving no pollution and almost no white smoke emission, effectively changing the conventional gas furnace.
  • the weak acid corrosion generated by the tail exhaust gas discharge process causes the pipeline to be easily damaged, which guarantees the service life of the system.
  • the exhaust gas environmental protection treatment device of the invention can also reduce the temperature of the exhaust gas to substantially the same emission as the atmosphere, thereby also ensuring the service life of the system.
  • the odor generated in the whole process is also processed by the plasma photocatalyst negative ion air deodorizing and sterilizing device, and the plasma photocatalyst negative ion air deodorizing and sterilizing device is applied to the odor overflowing in the processing of each kitchen waste and the entire workshop.
  • the air is collected and collected to continuously and efficiently remove harmful microorganisms, kill bacteria and viruses, and degrade the odor in the air.
  • the air inlet T270 of the plasma photocatalyst negative ion air deodorizing and sterilizing device of the present invention is installed around each kitchen garbage collecting pool to ensure the prevention of the spread of pollutants and the possibility of overflowing odors.
  • the production section and the upper part of the production workshop are equipped with an automatic slide gate valve T271 at the rear end of each air inlet T270.
  • the automatic slide gate valve T271 is controlled to open and close by a pneumatic device or an electric device.
  • the automatic slide gate valve T271 is used to prevent air treatment. When the equipment is faulty and the machine is shut down for maintenance, it is ensured that the pollution source does not spread.
  • the rear end of the automatic slide gate valve T271 is connected to the air conveying pipe T272, and the negative ion corrugated plate T273 is provided in the air conveying pipe T272 (in this embodiment, the plastic used for the energy plastic carrying device is used.
  • the raw material is coated on both sides of the steel plate, and then formed into a corrugated shape by pressing and bending.
  • the front end of the air conveying pipe T272 is installed at a distance of 30 cm - 80 cm from the entrance end, and a plurality of stacked stacks of 15,000 pieces/cm 3 are installed.
  • An anion corrugated sheet T273 (designed according to the pipe and air volume), where the negative ion corrugated sheet T273 is horizontally mounted
  • the vertical negative ion corrugated plate is installed vertically at the rear end of the horizontally mounted negative ion corrugated plate.
  • a horizontal negative ion corrugated plate is combined with a vertical negative ion corrugated plate, and when implemented, You can set multiple segments according to actual needs.
  • each segment of the negative ion corrugated plate comprises more than one piece, and the spacing between the plates and the plate is 10 mm.
  • the end of the air conveying pipe T272 is connected with a photocatalytic main processor T274. After the air is processed through the negative ion zone, the air is guided by the induced draft fan installed in the photocatalytic main processor T274 to the tail end of the air supply duct, and then enters. Photocatalytic main processor T274.
  • the photocatalytic main processor T274 is provided with an air passage, the air passage is a Z-shaped air passage, the Z-shaped air passage is a Z-shaped guide plate T275, and the Z-shaped guide plate T275 is a mirror aluminum alloy plate.
  • the light emitted by the ultraviolet light pipe T276 light source is reflected in the Z-shaped air channel, and the Z-shaped air channel is provided with a plurality of ultraviolet light pipes T276 (horizontal mounting) with an emission wavelength of 253 nm - 258 nm, each ultraviolet light
  • the back surface of the light pipe T276 is equipped with a smooth reflecting plate T277 for reflecting the light source emitted from the ultraviolet light pipe T276 into the air passage to maximize its function.
  • a honeycomb-shaped titanium dioxide photocatalytic contact plate T278 is installed at a distance of 10 cm to 20 cm behind the ultraviolet light pipe T276.
  • the size and shape of the photocatalytic contact plate T278 are the same as the Z-shaped air passage cross-section, and can be just blocked.
  • the photocatalytic contact plate T278 has a thickness of 1 cm - 10 cm, and a plurality of holes are formed in the upper portion, and a plurality of plasma generators T283 are installed at a corner position of the Z-shaped air channel of the photocatalytic main processor T274, and the plasma is installed.
  • the discharge power of the generator is 2.5WH/m 3
  • the tail end of the Z-shaped air passage in the photocatalytic main processor T274 is connected with an air discharge pipe T279, and the tail end inside the air discharge pipe T279 is installed with a negative ion amount that can be released.
  • 15000/cm 3 stacked second negative ion corrugated plate T280, the second negative ion corrugated plate T280 has the same structure as the first negative ion corrugated plate T273, and the air passes through the laminated second negative ion corrugated plate T280 and enters the activated carbon air filter. After the T281 treatment, it is discharged.
  • the activated carbon air filter T281 is provided with activated carbon in the outer casing to carry out the final activated carbon adsorption on the gas.
  • the plasma photocatalyst negative ion air deodorizing and sterilizing device of the present invention operates as follows: when the kitchen waste enters the collecting pool, the air introducing device of the present invention is activated, and the automatic sliding gate valve T271 at the front end of the air collecting pipe around the pool is opened. If the production workshop or other collection pool does not need to handle the air, the automatic slide gate valve T271 at the front end of the air collection pipeline is closed. If the production workshop or other collection pool also needs to handle the air, the front end of the collection pipeline The automatic slide valve is open. Due to the action of the air blower, the air containing bacteria and odor is processed into the negative ion laminated corrugated plate T273 in the pipe through the gate valve T271.
  • the corrugated plate and the corrugated plate is 5 mm—— 10mm
  • the negative ion laminated corrugated plate T273 releases 15000 pieces/cm 3 of negative ions and does not need to be energized. It carries out the first capture and killing of the cells and odors with cations in the passing air, after the first killing and
  • the deodorizing gas enters the plasma processing zone along the air conveying pipeline under the strong action of the air deflector, and then continues Continue to enter the photocatalytic main processor T274, the gas enters the main processor and moves from bottom to top in the zigzag direction.
  • the gas is installed under the ultraviolet light emitted by the ultraviolet light tube T276 of the four walls of the Z-shaped channel, and then enters the honeycomb.
  • Hydroxyl radicals and superoxide ion radicals these capabilities are far higher than the strength of the general organic pollutant molecular chain, so when the air enters the Z-shaped channel, the organic pollutants in the air are decomposed into the most primitive state, especially After several times of repeated photocatalytic treatment of air in the Z-shaped air passage, the bacterial virus in the air has been effectively removed, and the odor in the air is simultaneously degraded, in order to further ensure that the discharged air is fresh and qualified, in the Z-shaped air passage.
  • the plasma generator 13 is installed at the corner position to enhance the degradation and removal of pollutants, and has been subjected to photocatalysis and plasma combined treatment.
  • the plasma photocatalyst negative ion air deodorizing and sterilizing device in the invention can collect and treat the odor overflowing in each section of the kitchen waste treatment process and the air of the entire workshop, and continuously and efficiently remove harmful microorganisms from the collected air. Kill bacteria, viruses, and degrade the odor in the air.
  • the gas discharged at this time is odorless, sterile, free of solid particles, free from toxic and harmful substances, and fresh and clean.
  • the automatic control device in the invention is mainly applied to the automatic intelligent control of the production process of the kitchen waste feeding, screening, cleaning, biochemical treatment, drying and fine screening in the process of the kitchen garbage resource recycling process, and the control system is well-known. technology.
  • This device adopts multiple PLCs in parallel to complete the central control function.
  • Each PLC has its own independent program.
  • Each field electrical unit and operation command collects signals through PLC to RS-422 communication.
  • the method is transmitted to the upper computer to form a complete distributed control system. All electrical control units are divided into several large-scale on-site control units according to the operation requirements of various production equipments on site, and independent program control is established, and the main operation room is established.
  • the integrated equipment and method for all-round processing of kitchen wastes is a set of domestic and foreign kitchen processing industry for the first time with high integration, automation and comprehensive comprehensive equipment, compatible with kitchen waste
  • the method of resource treatment is inevitable, adapting to the trend of the international environmental protection industry, and implementing the safe disposal and disposal direction of the residue after the comprehensive treatment of waste is not transferred and digested, and secondary pollution is not generated.
  • the application of the invention provides kitchen waste and its inevitable attachments - waste plastic bags, drowning sludge and domestic sewage in the plant, industrial sewage and sludge produced in the production process, various large systems in the same equipment The processing method in the device.
  • the application of the present invention provides various high value-added product names, manufacturing methods and uses thereof after the comprehensive recycling of the kitchen waste.
  • the application of the invention provides a comprehensive energy-saving production, safe production, no residue transfer treatment for the kitchen waste treatment industry, no room temperature discharge, no odor emission close to the clean production method and mode without sewage discharge.
  • the products produced by the invention are National III mineral diesel, low sulfur and high calorific value clean environmental protection coal, and gas three strategic energy sources, which can alleviate the pressure of social supply and demand.
  • the high-nutrition microbial protein feed additive produced can effectively fill the gap of the lack of high-protein additives in domestic feed.
  • the invention provides a novel garbage carrier (barrel) production method capable of naturally sterilizing and deodorizing the kitchen garbage carrier (barrel) and providing clean air around the outer periphery of the barrel, which is an application surface extremely A wide range of new environmentally friendly cleaning appliances.
  • the present invention is a complete set of integrated kitchen waste processing equipment, a plurality of special large-scale devices and systems are assembled, each having its own independence and application range, but also having coherence and detour between the devices and the devices. In order to more clearly and completely express the application mode and production process of the complete equipment and its related methods and related formulas, the actual case description.
  • the kitchen waste used is from restaurants, hotels, Chinese restaurants, western restaurants, government canteens, school canteens, etc. in a prefecture-level city in the Pearl River Delta of the People's Republic of China.
  • the production rate of the products in the case and the methods and related formulas used in the production are set according to the dining habits, characteristics and food quality of the humanities in the area.
  • the kitchen wastes referred to in the specific embodiment are clear.
  • the transportation work is carried out by the environmental protection and transportation enterprises designated by the relevant government departments.
  • the whole set of equipment for comprehensive treatment of kitchen and kitchen waste is provided by South China Renewable Resources (Zhongshan) Co., Ltd., and the specific implementation location is at the kitchen waste processing base in the company.
  • the base daily processing capacity is set to 200 tons, and the embodiment, the production process and method, and the related formulations of the integrated equipment for processing 50 tons per day are described as a specific embodiment of the present invention.
  • this collection bucket is a loading tool distributed to the source of each kitchen, and is also a transport tool from the source to the processing plant. It protects the source of the sanitary environment and avoids transit. The possible secondary pollution has a very important key. Therefore, it is necessary to use a kitchen waste bin with a sterilization and deodorization function in the barrel and a negative oxygen ion fresh air around the barrel.
  • the specific manufacturing method is as follows: :
  • the carbon black is subjected to ozone oxidation treatment, and the carbon black particle size is ⁇ 2 um.
  • the ozone oxidation treatment is a conventional oxidation treatment of the carbon black by the ozone oxidation equipment in the prior art, so that the internal surface area of the carbon black is increased by more than 4 times. This promotes the adsorption capacity of carbon black.
  • the treated carbon black is thoroughly mixed with the nanometer tourmaline powder as a base material, wherein the carbon black accounts for 15% of the total weight of the base material, and the nanometer tourmaline powder accounts for 85% of the total weight, in the mixed base material.
  • ultrafine titanium dioxide is added and further mixed as an energy raw material, and the ultrafine titanium oxide is added in an amount of 10% by weight based on the total weight of the base.
  • the mixed energy raw materials are further dried at 100-120 ° C for 1-2 hours (the mixed energy raw materials are completely dried).
  • the energy raw material is added with a dispersing agent, and the dispersing agent adopts a coupling agent related to the basic resin, in particular, a coupling agent which is used to facilitate mixing with the carrier resin, and the dispersing agent is added in an amount of 3% of the energy raw material.
  • a coupling agent which is used to facilitate mixing with the carrier resin
  • the dispersing agent is added in an amount of 3% of the energy raw material.
  • One of the dispersing agents selected in the present embodiment is magnesium stearate.
  • the energy raw material added with the dispersing agent is further added to the plastic carrier resin, and uniformly mixed to form a well-mixed village material.
  • the plastic carrier resin used in the embodiment is PE, and the ratio of the amount of the plastic carrier resin to the energy raw material is 30%: 70%.
  • the mixture described above is input into a special mixing equipment for kneading, and a coupling agent is further added during the kneading process.
  • the coupling agent selected in the embodiment is an aminoalkane coupling agent, and the amount thereof is added.
  • the ratio of the total weight of the energy raw material to the plastic carrier is 2%: 98%, and the mixing temperature is set at the normal temperature of the mixed resin, and the plastic energy is made when the kneaded material passes through the extruder and completes the cooling and pelletizing process. Masterbatch.
  • the further output energy detected plastic masterbatch which measures infrared radiation in the wavelength range of 4-16, the whole firing process was ⁇ 0.86, a concentration of 7000 ions / cm 3 or more, when it is determined masterbatch
  • the energy masterbatch that meets the production standard is mixed with HPPE and ABS plastic rubber particles.
  • the mixing ratio of PE and ABS is determined according to the load weight of the kitchen waste bin, while the energy masterbatch accounts for three.
  • 70% of the mixed plastic resin is finally injection molded by a professional injection molding machine to form a barrel and a lid.
  • the flow rate of the solution and the temperature of the barrel, the mold temperature control, and the injection pressure are all Production technology methods according to industry routines.
  • the prepared kitchen garbage container is assembled and tested to naturally release more than 5,000/cm 3 of negative ion content, and then distributed to each kitchen garbage collection point, thereby ensuring that the kitchen waste is from entering the receiving bucket. Will not smell bad in hours.
  • the environmentally-friendly cleaning and transportation enterprises designated by the government collect and deliver the kitchen waste carried by the above-mentioned carrying barrels to the processing plant area.
  • the collection port is operated by the main control room to open the sluice cover, and the vent gate valve disposed around the upper side of the collection port is opened, and the plasma photocatalyst negative ion air treatment system is activated. .
  • the kitchen waste is sent to the collector by the automatic unloading equipment.
  • the collection device brake cover is automatically closed. Since the air treatment system has been activated, the odor of the garbage is introduced into the treatment device to sterilize and deodorize.
  • the air environment in the plant area is fresh, and at the same time, after the kitchen waste enters the collector, the horizontal automatic gate valve in the lower part of the device is opened, and the garbage naturally falls into the propelled bag breaking device.
  • the kitchen waste enters the discharge pipe after breaking the bag, and uses the water flow force to send the kitchen waste into the liquid air flotation sorting device.
  • the main sorting device of the device is 6m 3 , which is set at the main
  • the semi-floating material discharge louver opening in the middle and lower part of the sorting device is closed, and the water body starts to inject water into the main device bucket through the water pipe system.
  • the water injection amount is based on the set water surface height, and is controlled by the liquid surface automatic positioner.
  • the sub-input kitchen waste is 1/3-1.5/3 of the total cubic volume of the main unit water body. When the water body rises to the set liquid level, the main and auxiliary rolls placed on the upper part of the main unit are shifted by the motor.
  • the box starts to roll, and the compressed air valve located at the lower part of the main device is opened, and the high-pressure air emitted from the plurality of gas nozzles is used to flip the kitchen waste immersed in the water body under the buoyancy of water, and the plastic with lower density at this time
  • the debris such as cloth strips and toothpicks floats to the upper layer of the water body, and is swept upward by the rolling caries, and is captured by the auxiliary caries provided on the upper part of the main roll side and then discharged to the light debris collection bucket.
  • the louver opening in the middle and lower part of the water body is opened, and the kitchen waste of the semi-floating layer is pressed against the louver mouth by the hydraulic pressure difference of the main device water body, and enters the auxiliary device.
  • the circulating water pump is started to deliver water to the buffer water tank and the main device is replenished.
  • This action is to ensure that the liquid level of the main device is higher than the liquid level of the auxiliary device, when the semi-floating layer
  • the valve at the discharge opening of the main device is opened, and the density at the bottom of the device is large or large, such as: metal debris, glass, broken Porcelain pieces, heavy debris and discarded small quantities of raw chicken, duck, fish or large pieces of meat in the kitchen waste are discharged from the residue discharge port and delivered to the set location by automatic conveying tools.
  • the selected kitchen waste is selected into the input crusher, and after the liquid air flotation is sorted, the food waste that is beneficial for the production of protein feed has been basically carried out for the first time. Desalination step and cleaning process.
  • the used kitchen waste that has been sorted is discharged from the discharge port of the auxiliary device in the liquid air flotation sorting device and automatically sent to the first-stage reactor and the second reaction of the wet advanced oxidation device through the conveying tool.
  • the internal cavity of the secondary reactor is 5m 3 , the amount of kitchen waste is 5T, and the fresh water is injected 2T.
  • the input of both is controlled by an automatic quantitative tool and passed through a liquid level controller installed in the kettle. Set the height of the water level in the reactor.
  • the waterproof check valve mainly acts to prevent the water from flowing back into the ozone generator. While the ozone gas enters the gas-water mixer, the high-viscosity cam rotor pump installed between the circulation pipes is started, and the blend of the kitchen waste and the water body is strongly pushed into the water, gas mixer and into the mixer.
  • Ozone gas implements kitchen waste-water-ozone gas mixing, and promotes the dissolution of ozone in the activated water, and then enters the reaction kettle, and another cam rotor pump pumps the kitchen waste in the reaction kettle-water- - the mixture of ozone gas is strongly input into another reaction kettle, and the reaction is repeated as a reaction process, especially in the case where the ozone-containing material is acted upon by the activated carbon fixed reaction ball in the reactor, causing a chain reaction in the mixture to accelerate the ozone Conversion to hydroxyl radicals, similar to the advanced oxidation process of O 3 /H 3 O 3 or O 3 /UV, the above reaction of organic matter, bacteria and microorganisms in kitchen wastes is instantaneously dispersed in water with oxidation of single primary oxygen Very rapid, single primary oxygen O and hydroxyl radical OH can forcibly inactivate pathogens and spores in kitchen waste within 1-2 minutes.
  • the pump port The working pressure is 0.25mpa, the conveying strength is 500kg/min, the reaction time of the mixture in the kettle is 10min, and the ozone concentration in the kitchen waste water is 12g/T.
  • the gas overflow port and ozone are arranged in the upper part of the reactor.
  • the destroyer is always on, and the process of desalting and inactivation of the original bacteria has been completed after the kitchen waste has undergone advanced oxidation. Effectively ensure the quality of inoculation and expansion work in the subsequent protein feed production process, and effectively eliminate the interference of bacteria and remove the salt into the kitchen waste.
  • the kitchen waste processed by the previous step is discharged from the discharge port at the lower part of the reactor and enters the primary solid-liquid separator. After separating most of the water body, the kitchen waste having a water content of about 85% is obtained, and then the snail is obtained.
  • the belt conveyor is gradually fed into the vertical dewatering device, and the adjustable water pressure plate installed on the upper part of the dewatering device is adjusted by the hydraulic device to the closed state, and the middle shaft running through the shaft center of the ribbon is driven by the gearbox with a 3.7KW motor, and Rotating at 580 rpm, the electric ball valve connected to the water outlet of the water separator installed in the lower part of the dehydration tower is automatically opened.
  • the kitchen waste is put into the feeding port at the lower part of the dehydration tower, and the kitchen waste is large.
  • the extrusion action of the small spiral ribbon and the shell and the resistance of the water pressure plate at the top of the tower increase the material conveying resistance.
  • the discharge door provided on the top side of the tower automatically opens. This discharge port is controlled by hydraulic pressure.
  • the kitchen waste is continuously pushed up to the dewatering zone through the concentration zone in the lower part of the dehydration tower, and continuous dewatering and discharging are carried out, and the removed water body flows out from the grid of the tower body shell and is disposed along the grid.
  • the outer baffle of the fixed ring flows into the water receiving device and is discharged through the drain port.
  • the discharge amount of the dehydrated material is 8T/h, and the continuous running time of the dehydration tower is set no more than 8 hours. After the shutdown, it is installed around the dehydration tower.
  • the high pressure water recoil nozzle cleans the water outlet gap of the grid strip.
  • the rated working pressure of the water outlet is 0.35mpa, the water supply intensity is 14L/min, and the cleaning time is 10min.
  • the route connected to the upper process is divided into two processes of different working properties, one of which is: an oil extraction process.
  • the oil-containing water body above the middle of the pool is input into the oil-water separation tower by using a water pump, and the oil-water separation tower is used. It is composed of two towers, and there are pipelines in the middle. The two towers are all cavities. The total volume of the cavity is 60m 3 and the water body is 50m 3 .
  • the heating pipeline inside the tower The hot gas enters the water body through the heat transfer of the pipe wall, and the hot gas source is collected in the hot tail gas of the heat transfer oil boiler for production.
  • the oil in the water body is heated to 80 ° C, the oil in the water body is completely separated from the water, and the upper layer is upward. Floating up and naturally entering the upper part of the inclined partition provided in the upper part of the oil-water separation tower, flowing down the inclined surface of the partition into the oil-bearing bearing area, and then passing the oil through the oil discharge pipe through the scraper plate installed in the bearing area Into the biodiesel production area, the resulting oil is about 180kg.
  • the temperature of 80 ° C most of the bacteria and microorganisms are inactivated in the water body at the lower part of the oil-water separation tower, and are input into the sewage treatment zone through the drain port at the lower part of the tower.
  • the other of the two different working properties described above is the crushing process: when the kitchen waste discharged from the dewatering process is about 45%, and the pneumatic pusher is input into the crusher for crushing, this is a well-known technique. This is no longer stated.
  • the two pre-biochemical fermenters have an internal volume of 10m 3 Entering 7 tons of kitchen waste, another pre-biochemical fermenter with an internal volume of 30m 3 , entering the kitchen waste and the fiber nutrient material input from another straw biochemical fermentation device, the intermixing of kitchen waste and fiber nutrients
  • the ratio is determined by the type of feed that is ultimately produced by the visual symbol. In this embodiment, each accounted for 50%, but the total weight of the two entered the biochemical fermenter was 20 tons.
  • the biochemical treatment of 7 tons of kitchen waste is based on the use of baker's yeast as a strain.
  • the bran is added to the base by 2% by weight of the base material, 2.5% of rice bran, and 1% of brown sugar is mixed and adjusted.
  • the bread yeast is added to the mixture by 3% by weight of the base material, and fully stirred to enhance the aeration to enhance the growth of the yeast.
  • the fermentation time is 12 hour.
  • Another biochemical processor containing 20 tons of mixed-mix kitchen waste was put into the combined compound strains of Trichoderma viride and Candida tropicalis and Pseudomonas and Pseudomonas syringae. Directly fed microorganisms in the Chinese Species Catalogue.
  • the ratio is 2:2:1:1, and the inoculation amount is 3% of the substrate quality.
  • the inoculation method is that the composite strains are added one after another, and 0.5% urea is added, and the biochemical fermentation is continued for 10 hours.
  • the heat source of the fermentation is feed.
  • the waste heat of the dryer is provided, the temperature is set to 32 ° C, the ventilation condition is 8 min / h, the ventilation is 0.2 m 3 / h, and the green wood mold in the strain with the white fungus reduces the crude fiber content of the base material extremely significantly, and Candida tropicalis, white fungus and Trichoderma viride can increase the crude protein and true protein to a significant level, and use the endophytic bacteria as the auxiliary mold, the first expansion of the pre-biochemical fermenter.
  • the implementation of this case is in the Pearl River Delta region of southern China. Therefore, the type of straw selected in this case is selected locally, with local legume straw and grass.
  • the wood crops are mixed with straw, using peanut stalks, broad bean stalks, bean stalks of legume stalks and rice stalks, sugar cane heads and tails, and corn stalks of the current season, such as wheat stalks.
  • the above-mentioned straw combination is based on the high content of straw protein such as legume crops, but the sugar content is low, and the microbial activity is not high at the initial stage of fermentation, and then mixed with the straw straw containing higher soluble sugar content, not only Improve the quality of the fermentation, and make the nutrients of the two types of crop straws complement each other, so as to achieve better feed quality.
  • the ratio of the two types of straw is 60% for legumes and 40% for straws.
  • the crop stalks are properly cleaned, kicked out the rotten, moldy parts and dirt, sand and other debris, and exposed to the surface to remove the surface moisture, inhibit the growth and reproduction of the mold, and smash the straw into 0.5-1 mm by the pulverizer. Powder.
  • the chemical composition of 2 kg of calcium oxide, 0.2 kg of sodium chloride, 3 kg of sodium hydrogen phosphate and 0.5 kg of urea is added, and the weight of the chemical component is required per ton of straw.
  • the chemical component acts on the decomposition of lignin, softens the straw, destroys the crystal structure of the plant cell wall, breaks the physical and chemical state of the close combination of lignin and cellulose, improves the biochemical treatment effect and the palatability of the feed.
  • the above-mentioned activation liquid and chemical components are uniformly stirred to obtain a fermentation liquid.
  • the fermentation broth is sprayed into the material in the biochemical fermentation tank, the ratio of the straw to the fermentation broth is 1:2, and then the materials of several pools are uniformly stirred by the automatic stirring device installed on the side of the biochemical pool for about 10 minutes.
  • the material was compacted after the end of the agitation.
  • the biochemical fermentation tank cover is sealed and closed by a hydraulic automatic system, and the biochemical treatment time is 7-9 days in the next season, and the required temperature is normal temperature.
  • the composite microbial agent biochemically treats the straw, so that the crude fiber is effectively degraded and saccharified, and the rich bacterial protein and physiological active substance are synthesized, and the biological energy contained in the straw is not consumed. Therefore, under normal conditions, no heat phenomenon and gas production phenomenon and swelling phenomenon will occur.
  • the biochemical treatment of the straw the color is bright and golden yellow, the hand feels delicate and soft, the aroma is rich, and the wine is slightly scented.
  • the material of the pre-biochemical treatment will now be stated. After 10 hours of pretreatment, the material is input into the lower two groups of main biochemical devices by a screw conveyor at the bottom of the biochemical device.
  • the volume of the main biochemical chamber of each group is 20 m3.
  • Baker's yeast is a kind of material, and it needs to remain about 10% to enter the main biochemical device, which is used for the next fermentation, because the next fermentation is the old fermentation method.
  • the automatic slide gate valve of the material delivery port installed between the main and auxiliary biochemical devices is closed.
  • the rotation speed is 7 rev / min, for horizontal 360o rotation, the direction of the outer ribbon of the agitator In the forward direction, the direction of movement of the inner layer of the ribbon is reversed.
  • the heat transfer oil is output from the heat transfer oil boiler, and is sent to the two sides of the biochemical device through the heat pump, and the material is heated by the heat transfer of the biochemical case, according to the aerobic or anaerobic conditions and bacteria of various selected strains. The optimum conditions for the breeding conditions to adapt to the temperature conditions.
  • the initial temperature is 20 ° C, gradually increase to 28 ° C, after 4 hours of constant temperature, close the air inlet and outlet, and gradually increase the temperature to 35 ° C -38 ° C, after a constant temperature of 3 hours, this period of biochemical fermentation of oxygen supply
  • the points are between the gap between the source materials and the specific area.
  • the kitchen waste that has undergone biochemical fermentation has been converted into microbial protein feed, and the water content is about 35%.
  • the main biochemical fermenter is opened at the discharge port on the bottom side, the feed is discharged into the feed hoist and is lifted.
  • the machine is sent to the pre-drying device in the drying device.
  • the hot air of the pre-drying device is derived from the exhaust heat of the main drying device, and the hot gas enters the outer casing of the pre-drying device, and the inner cavity is heated by the heat-conducting oil in the inner cavity of the device casing.
  • the inner cavity volume is 16m3, the feed volume is 8 tons per time, and the inner cavity temperature of the device is 100 °C.
  • the middle shaft flap installed in the equipment is rotated by the motor and the transmission, and the rotation speed is 12 rpm. Min, at this time, the feed is rotated by the flap, the material is heated continuously in contact with the hot gas and the wall of the cylinder, and when the feed below the temperature of the cylinder wall of the apparatus continuously contacts the wall of the cylinder, the wall of the cylinder is cooled, but Under the rotation of the flap, the cycle of change is short, the temperature change range is small, the temperature of the wall of the tube can be considered to be constant, and the feed without contact with the wall of the tube is subjected to radiation heat transfer by the heated feed particles, which can also be said to be particles. Surface receiving radiation heat.
  • the main drying device is a horizontal shaftless rotary airflow drying device.
  • the main drying device in the case of the specific embodiment is a four-layer rotating drum structure, and the inner wall of each layer of the rotating drum is provided with a spiral belt connecting the wall of the cylinder, the innermost rotating drum has a pitch of 150 mm, the cylindrical body has a diameter of 700 mm, and the cylinder length is 4000 mm;
  • the next layer of drum has a pitch of 200mm, the cylinder diameter is 1200,mm, and the cylinder length is 4600mm;
  • the next layer of the drum has a pitch of 300mm, the cylinder diameter is 1800mm, and the cylinder length is 4600mm;
  • the outermost drum is the main drum of the drying equipment.
  • the pitch is 450mm, the diameter of the cylinder is 2200mm, and the length of the cylinder is 6000mm.
  • each layer of the drum is based on the outer drum.
  • Several fixed brackets are installed in the circumference of the inner drum, which are fixed one by one.
  • the rotation speed of the drum is 29 rpm, and the upper part of the tail end of the main drying equipment is equipped with an exhaust port.
  • the hot air is led by the air blower.
  • the heat source of the main drying device is generated by the diesel injection burner in the combustion chamber, and the hot air is sent into the drying device by the adjustable reverse fan disposed at the side of the combustion chamber.
  • the feed is started when the inlet temperature is 280 ° C and the outlet temperature is higher than 110 ° C.
  • the feed rate is 20 kg/min, and the gas flow rate is 1.2 m/s.
  • the feed first enters the innermost rotating drum and then advances in contact with the hot air flow in the forward direction of the spiral belt.
  • the feed reaches the end of the rotating drum, it naturally falls into the next layer of the rotating drum and advances with the advancement direction of the spiral belt. After countercurrent contact with the hot air flow, it naturally falls into the next layer.
  • the direction of the drum's forward direction is in contact with the hot air flow in the same way as the innermost drum.
  • the feed finally falls into the main drum and follows the snail. Push the belt forward to the discharge port.
  • the sleeve type horizontal drum is used to extend the forward track of the feed to ensure that the material has sufficient residence time contact with the hot air, and the moisture in the feed is quickly evaporated by the heat energy.
  • the dried feed is gradually fed into the feed selection device through the conveying equipment, and the feed drum is rotated by the inclined drum in the device, and the movement track is continuously rolled forward, and at this time, the large number of the mesh of the drum screen cannot be passed.
  • the article or heavy object is fed into the ribbon guide at the end of the drum and falls into the mixing box with the direction of advancement of the ribbon, while the feed smaller than the mesh of the roller falls through the aperture into the finished carrier. Then, the mixed materials in the mixing box are subjected to secondary screening to select a slightly larger-sized feed, and then crushed and returned to the finished carrier.
  • the calorie consumption energy required for the above biochemical fermentation and feed drying process is about 630 kcal/kg, and the produced product is a high protein nutrient feed with a feed weight of 12.7 tons.
  • the quality of the test product is:
  • Qualified products are golden yellow, brightly colored, slightly scented and toasted
  • High-nutrition feed enters the feed granulation production area. According to the size and adaptability of various aquatic animals, special feeds such as puffed floating materials and semi-floating materials are produced through special equipment. This technique is well known and will not be described here.
  • the extracted fat and water enters the biodiesel production area.
  • the measured oil and fat was 1.6 tons, accounting for 3.2% of the 50 tons of kitchen waste entering.
  • the method for treating this grease is to adopt a distillation-free production method, which has strong adaptability to raw materials, is clean, safe and simple in the production process, and the entire production process is carried out at normal temperature.
  • the crude oil and fat in the oil storage tank are first taken out from the container by the oil pump, and sent to the bio-oil lipid removal impinging stream reactor for the removal of the gel. At this time, the installation is started in the impact reaction.
  • the hydro-pneumatic propulsion machine at both ends of the machine will force the grease to collide with the orifice plate provided in the impactor.
  • 0.8% phosphoric acid is added to the grease in the process, and the continuous phase collides with the orifice plate, and the hole of the orifice plate is used.
  • the oil at both ends is strongly traversed by each other for 15 minutes. This step acts on phospholipids that cannot be hydrated in oils, that is to say, non-hydrated phospholipids, especially the symmetry of its structure, affected by the spatial effects of molecular structure, hydrophilic Poor sex, the reason why it is not easy to absorb water and expand, will seriously affect the difficulty and quality of bio-oil processing into biodiesel.
  • the strong mixing and scouring of phosphoric acid in oil and fat destroys the micro-metal complex of non-hydrated phospholipids, thereby transforming into Hydrated phospholipids.
  • add 10% diluted brine to the oil the input amount is 120kg, and continue to force the oil to collide with each other by means of the rotary pulp at both ends, stop after 20min, and let stand for layering, due to The action of the electrolyte promotes the flocculation of the impurities in the oil in the hydrated phospholipids, and reduces the oil content of the formed colloidal mass.
  • the gum in the bio-fat is detached, and the colloid in the oil is effectively prevented from covering the grease particles in the next fatning step, thereby ensuring contact between the grease and the catalyst.
  • the colloidal grease is separated from the grease impactor, and then input into the fat exchange reaction vessel.
  • the volume of the reaction chamber is 3 m3.
  • the radial impeller installed at the bottom is started. At medium speed, the grease is quickly tumbling, and the feed port is opened.
  • 80 kg of methanol and 3.2 kg of methyl ethyl ketone and 1 kg of t-butanol are added.
  • methyl ethyl ketone and t-butanol are co-solvents, and the co-solvent contains a lipophilic group compatible with the oil.
  • a polar group capable of binding to methanol wherein an oxygen atom contained in the molecule forms a hydrogen bond with methanol, promoting mutual solubility of the oil and the methanol, forming a homogeneous system, and effectively accelerating the alcoholysis exchange reaction with the catalyst.
  • the base nucleus is then impregnated with a mixed liquid of an alkali silica sol and an aluminum sol and lithium hydride, and then taken out at a temperature of 650 ° C to 720 ° C for one hour. After cooling, it is ground into 50-80 mesh particles, and made into a non-polar adsorbent-based core, which is wrapped with silicon, aluminum-lithium mesh skeleton medium and polar hybrid catalyst.
  • the catalyst was immersed in an aqueous KNO 3 solution, taken out, and dried at 110 ° C to obtain a KNO 3 solid alkali metal catalyst having a KNO 3 loading of 25%. This solid catalyst was added in an amount of 24 kg.
  • the contact surface between the molecules of the reaction medium is increased, and the reaction is pushed in the positive direction.
  • the reaction is installed in the kettle and immersed in the grease.
  • the ultrasonic probe is turned on, the number of probes is four, the initial frequency is 25KHz, and gradually increases to 30KHz after 1min.
  • the flow of grease is generated by hundreds of millions.
  • the cavitation nucleus of the tiny bubble vibrates under the action of the sound field, and when the sound pressure reaches a certain value, collapse cavitation occurs.
  • the 1.53 tons of biodiesel produced still has tiny water.
  • the above-mentioned biodiesel is used to produce micro-emulsified diesel without dehydration. .
  • the water content of the biodiesel was measured, and the water content in the oil was measured to be 4.6 kg.
  • the biodiesel is input into the special device of micro-emulsified oil by the oil pump, and the stirring system in the starting device is set to rotate at 128 rpm.
  • the composite ion surfactant is added as a hydrophilic agent, and the other is a cationic surface.
  • the active agent is a nonionic surfactant
  • the above two types of surfactants include triethanolamine, hexahydroaniline and aqueous ammonia and intermediate butanol, the percentage of which is a combination of a cationic hydrophilic surfactant and a nonionic surface.
  • the active agents each accounted for 50% and the amount used was 2.5% of the biodiesel moisture content.
  • 300 kg of mineral diesel oil is added to biodiesel, and the water content in the total weight of biodiesel and mineral diesel is adjusted to 10%, that is, the amount of water to be added is 180 kg.
  • the agitator The speed was changed to 200 rpm.
  • Waste plastic processing (waste plastic reversal project):
  • the waste plastic is derived from the waste plastics selected by the liquid air flotation screening device described in the sixth step of the present embodiment, and is sent to the waste plastic processing area through the conveyor belt - the waste plastic reverse engineering production area
  • a total of 280kg of waste plastics were selected from 50T kitchen waste, including plastic bags, plastic bottles, bottle caps, plastic lunch boxes, as well as toothpicks, wooden chopsticks, cloth strips, etc., special equipment for plastic reversal engineering.
  • the minimum feed amount is 2.5 tons, so the waste plastics screened in this case is only 280kg, which can not meet the production requirements of the equipment. Only other waste plastics can be added into 4.5 tons.
  • the operation is as follows:
  • the waste plastic used does not need to be cleaned, does not need to be screened, does not need to be dried, and is directly fed into the pneumatic automatic feeder through the sealed conveyor belt through the trough, and the waste plastic is continuously used by the reciprocating push-pull action of the automatic feeder. It is sent to the cracking reactor for cracking catalysis.
  • the cracking reactor is a horizontal reactor.
  • the tank is equipped with a fin-type shaftless random scraping device.
  • the shell of the reactor is a cracking furnace body.
  • the heat source conditions of the cracking furnace are The micro-emulsified biodiesel at the 13th point in the case is self-fueled.
  • the reactor starts to heat up, the lifting speed is 100 ° C / h, and the waste plastic is continuously fed into the reaction.
  • the total feeding time of the kettle was 40 min. Thereafter, the set amount of calcium oxide is immediately added, and the calcium oxide reacts with the water in the waste plastic to instantly increase the temperature of the material in the kettle to prevent coke formation, and also convert the chlorine-containing material into calcium chloride and effectively Adjusting the pH value of the reactants, adding 5 minutes after the calcium oxide addition process, adding zinc, aluminum-based metal solid catalyst and non-metal catalyst, the catalyst is added in an amount of 62 kg, wherein the aluminum-based metal solid catalyst acts on the gas, waiting for all After all the additives were added to the reaction vessel, the feed port of the reaction vessel was closed tightly, and the reaction in the autoclave was in an anaerobic state.
  • the one-way valve connected to the rear end of the reactor is automatically opened, and the water vapor in the kettle is converted into liquid water from the valve through the first-stage condenser.
  • the drain outlet is directly discharged, and the pH of the water is 6.5.
  • the material in the kettle enters the cracking process.
  • the high-condensation point wax discharged from the reactor sublimation passes through the check valve and enters the wax collector.
  • the oil and gas clamp carries a small amount of tiny carbon particles and continues to pass through the oil and gas separation device, the magnetic ring disposed in the device will trap some of the tiny carbon particles, and the oil and gas will enter the secondary heat exchanger.
  • the easily liquefied oil enters.
  • the oil collector, and the non-liquefiable combustible gas is placed in the gas reverse cleaner by the gravitational force of the negative pressure system of the latter stage, and the negative pressure system is automatically turned on after receiving the gas electronic sensor signal provided in the system.
  • the flammable gas passes the first cleaning, it enters the next-stage weak alkaline water washing system, and quickly passes through the rear-stage safety water sealing device to enter the special gas compressor for primary desorption.
  • the pressure of the combustible gas is increased to 0.5mpa, and then the secondary gas compressor is introduced to increase the pressure of the combustible gas to 1mpa. After the secondary dehydration, the gas is directly sent to the gas storage reservoir for use.
  • the combustible gas is output from the storage tank, after the first stage decompression is 0.4-0.5 mpa, and then the second decompression is 0.1-02 mpa, and is input into the furnace combustion, and the cracking in the case of the specific embodiment
  • the exhaust gas of the furnace combustion chamber is treated by the tail gas environmental protection treatment system.
  • the oil of the oil collector is input into a special oil-water separator, and the water that has been liquefied at the same time as the oil is introduced into the oil collector is removed, and then input into the diesel refining system.
  • the automatic system automatically stops the infusion and opens the gas collector and odor destruction system at the top of the reactor.
  • the stirring device disposed in the reactor is opened, the oil material is in a flow-cutting mode, and the gas agitation system in the lower part of the reactor starts to start, and the oil flow direction rapidly hits the baffle disposed around the inner surface of the synthesizer.
  • the quantitative additive device is added to the oil in batches according to the set additive component, two of which are acidic catalyst and acid white clay, etc., when the additives are all added in order, the reaction time is 30 min.
  • the oil after decarburization and degumming is discharged through the oil output port provided on the bottom side of the reactor, and then enters the second stage dewaxing, neutralization, quality adjustment synthesis system.
  • the stirrer inside the device is started, and the additive is added by the quantitative feeding device, wherein the two materials are alkaline clay and xylene, and the others are liquid additives, after all the additives are added.
  • the neutralized and dewaxed oil is input into the later stage of the system and sampled and tested to determine whether it is necessary to increase the type and composition of the chemical materials, and then the quality adjustment is made. After the quality adjustment, the quality is adjusted.
  • the oil is transferred to a 350-mesh slag separator, and the separated oil enters the temporary reservoir.
  • the oil is output to the metal catalyst fixed bed processor through the temporary oil reservoir for the final refining process, and the oil output from the product discharge port of the fixed bed processor is the refined oil, and the quality thereof conforms to the national III standard diesel oil, and the obtained product is obtained.
  • the National III standard diesel oil is 2.2 tons, which is used to provide the fuel for the garbage collection of the kitchen waste.
  • the crude carbon black solid residue which is finally non-vaporizable and sublimated is left in the reaction vessel. It is a kind of fine particles with a high fixed carbon, but if it is not properly treated on site, it turns. When it is transferred, it will cause damage to land and air, so it is an indispensable item in the case of this specific implementation.
  • the crude carbon black is discharged from the automatic slag outlet of the cracking reactor, and the crude carbon black is sent to a special ozone aging device through a conveying device to artificially age the material, and the external crystallization of the carbon black particles is more orderly, and the particles are The internal order is poor, and the particle specific volume is changed by aging, thereby increasing the oxygen function of the crude carbon black and increasing the hydrocarbon ratio.
  • the coarse carbon black is aged, it is composed of the lower part of the aging device.
  • the discharge port is discharged, then transported into the physical aging treatment equipment, and subjected to hot steam treatment on a fixed bed, under a condition of a vapor pressure of 2.8 mpa for 25 minutes, which effectively increases the embedding of the combustion material of the crude carbon black. Quantity, modify its characteristics that are difficult to ignite.
  • the conveying equipment feeds the material into the coal pulverizer and produces high-energy low-sulfur environmentally friendly coal according to the particle size and shape required by the customer.
  • the product quality is 0.2% of total sulfur, 6.58% of ash, 11% of volatile matter, and grade 1 of coke slag.
  • the base heat is 5300kcal/kg.
  • the sewage and plant domestic sewage generated by the multiple processes referred to in the specific implementation case are after the multiple sewage discharge pipes enter the collecting pool, and the debris floating on the water surface is removed by the rolling grating, and then The pump is pumped into the ribbon dewatering machine to remove small solid debris.
  • the water discharged from the dehydrator is directly sent by the water pump to the top of the electric felt processor through the pipe, and then sprayed out at the mechanical atomizing nozzle.
  • the rated working pressure of the nozzle is 0.35. Mpa, the water supply intensity is 50-80kg/min.
  • the sewage When the fog falls on the hot felt, the sewage is partially converted into water vapor under the heat of the hot felt, partially converted into hot water, and the rising water vapor is converted into liquid state through the condensing device.
  • the water enters the reservoir, and the hot water passes through the shallow ditch of the hot felt into the water discharge port at the bottom of the device and enters the reservoir to be mixed with the liquefied water.
  • the hardness of the treated water is greatly reduced and the microorganisms in the water are artificially inactivated at a high temperature, and the purified metal ions are separated from the water body.
  • the heat source of the hot felt device for treating the sewage is controlled by the heat transfer oil.
  • the silicon intermediate frequency device is heated, and the intermediate frequency power supply circuit adopts six-pulse rectification mode, the incoming line voltage is 380V, the intermediate frequency induction coil generates heat of 500000kcal, and the hot felt diameter is 1.5m.
  • the water treated by the hot felt When the water treated by the hot felt is treated, it enters the reservoir directly, passes through the pump to enter the strong gas, the water mixer mixes with the ozone gas, enters the front end of the advanced oxidation reactor, and enters the advanced stage through the activated carbon reaction ball.
  • the water entering the reactor is first input into the buffer zone of the outer casing, and then enters the strong gas and water mixer again, and is again contacted with the supplemental ozone gas.
  • the reaction time is 5 min
  • the ozone concentration in the water of the reaction process is 5 g / T
  • the water body after the completion of the reaction stays in the reaction kettle for 2 min, in the reaction
  • the ozone air overflowing during the process is inactivated by an ozone destroyer that is sucked into the top of the reactor.
  • the advanced oxidation treated sewage passes through the water outlet provided at the lower side of the reaction kettle, and the water body is input into the composite filtering device by a water pump.
  • the device is composed of a plurality of sets of vertical filter tanks, and the water body enters from the top of the filter tank and is set in the water.
  • the pressure is passed through dozens of filter columns.
  • the filter column has a diameter of 200 mm and a length of 1 m.
  • the upper part of the column is filled with a non-polar adsorbent, and the lower part is filled with a hybrid charge adsorbent.
  • the water body Under the adsorption of the adsorbent, the water body has reached a clear and turbidity, no odor, no heavy metal ions, and basically removes the strong oxidant converted from ozone gas present in the water body due to the advanced reaction.
  • the ozone concentration is only 0.008 mg/L.
  • the water body treated by the composite filtering device is discharged from the drain port provided on the lower side of the device, and then enters the ultraviolet ray sterilizing device, and the ultraviolet radiation intensity is 2600-3000 UW/cm 2 and the wavelength is 235-258 nm, and the irradiation time is 4S, after the water body is sterilized by ultraviolet light, the whole sewage treatment process has been completed. Not only the water quality meets the industrial water reuse standard, but also is used as the production water for the waste disposal of the kitchen waste, and the treatment of the sewage is fast and reliable, and the water consumption per hour is about 5 tons.
  • the dewatered sludge generated in the sewage generated from the production and domestic sewage in the sewage treatment process into the sludge storage tank for 24 hours, using the naturally occurring or dead microorganisms naturally produced in the sludge as the pore former.
  • the hole-forming module when the sludge in the sludge storage device is taken out and put into the ozone processor, the microorganism is artificially forcibly inactivated by using the sludge in the processor from top to bottom.
  • Reverse ozone contact with ozone the time is 2min, the ozone concentration of the ozone processor is 12g/L, and the ozone gas flow rate is 7L/min.
  • the ozone exhaust gas is collected and processed by special equipment.
  • the sludge that has been forcedly inactivated is sent to the primary curing device by the automatic conveying device, which is composed of horizontal overlapping layers of spiral ribbons.
  • the automatic conveying device which is composed of horizontal overlapping layers of spiral ribbons.
  • 10% calcium oxide sludge is uniformly mixed for a mixing time of 25 minutes, and the mixed sludge is solidified or semi-cured to form granules.
  • the granulated sludge is discharged from the bottom of the mixer, and is continuously conveyed to the pneumatic propulsion equipment by the spiral belt conveying device, and the conveying system quickly sends the granulated sludge into the reaction kettle, and the reaction at this time
  • the temperature in the autoclave was 100 ° C, which had jumped over the survival condition zone below 75 ° C of the methanogen.
  • the pneumatic propulsion equipment automatically leaves the reaction tank inlet under the guidance of the guide rail. At this time, the feed port of the reaction kettle is sealed and closed at the same time, and the heating speed of the reaction kettle is closed.
  • the one-way air valve at the end of the reaction kettle is automatically opened, and the gas is passed through the safety water sealing device, and then enters the exhaust gas environmental protection treatment system, when the temperature in the reaction kettle reaches At 160 ° C, the structure of the sludge was destroyed, and the crystal water of the sludge was quickly released, and the water gas was taken out of the tail end of the kettle and discharged into the water sealer through a one-way gas valve.
  • the temperature of the reactor reaches 220 °C, the dead microorganisms are carbonized.
  • the cell matrix sol of the microorganism overflows to the outside of the mud and the cokes shrink, and the sludge particles basically form a multi-phenotype. Microcavities and channels.
  • the temperature in the reactor was kept at a constant temperature and kept at a constant temperature for one hour, but in order to prevent the sludge from entering pyrolysis, the final temperature setting in the autoclave could not be higher than 260 °C.
  • the moisture in the sludge particles in the kettle has basically escaped, and the porosity of the sludge is consolidated.
  • the anaerobic heat-treated sludge After the anaerobic heat-treated sludge is cooled, it is discharged from the automatic discharge port of the reaction vessel, and is sent to the processing warehouse by the automatic conveying tool to perform natural aging, and the aging time is 48 hours. Thereafter, the sludge is sent to the acidification.
  • the reactor is statically immersed in a 20% strength liquid sulfuric acid for 14 hours to remove the coke knots of the dead organisms, and at the same time remove the metal impurity ions in the sludge, and act on the hydrogen ions instead of the solidification of the sludge mass. Calcium ion.
  • the sludge granules substantially completely expose the pore structure skeleton of the granules in this process.
  • the acidified sludge particles are discharged from the discharge port of the reactor and then enter the water bleaching.
  • the water temperature condition of the water bleaching is 80 ° C, and the pH value is adjusted at this time, and the particles which are floated by the water are fed by the conveyor.
  • the hot steam activated room was subjected to a preliminary physical activation stage with a steam flow rate of 250 ml/min and an activation time of 2 hours.
  • the sludge particles in the physical activation process are then subjected to high-temperature pipeline type electric heating furnace for high-temperature activation, and are carried out under the condition of isolated air.
  • the overflowed hot gas is treated by the tail gas environmental protection treatment system, and the heating rate of the activation furnace is 20 ° C / min, and the activation is performed.
  • the temperature is 720 ° C, the activation time is 2 hours.
  • the sludge particles are cooled, and after being output, they are refined to become the core material of the hybrid charge adsorbent, and the pores and pore structures are amorphous structures.
  • the pore size and pore volume and pore form, pore size and length are naturally constant according to the type and quantity of various microorganisms attached to the sludge, and the pores per gram of finished product are between 1 and 150 million.
  • the diameter of the hole is about 0.8-1.2um
  • the length of the hole is about 2-5um
  • the width is about 0.3-0.4um.
  • the acidic aluminum sol and the silica sol are used to prepare a certain dilution, wherein the aluminum sol is 60% and the silica sol is 40%.
  • the nucleus material prepared above is mixed in the two mixed sols, and the weight ratio thereof is 78%: 20 %, then take out the mixture and put it into a high-temperature tubular resistance furnace, and keep it at 650 °C for one hour. After the process is finished, the temperature is removed and refined, and the core is made into a non-polar adsorbent.
  • the outer layer is an aluminum-silicon skeleton.
  • Multi-functional hybrid charged adsorbent material synthesized by medium network polar adsorbent the adsorbent has excellent quality, good mechanical strength, long service life, wide pore size distribution, and organic matter in various inorganic and organic gases and aqueous solutions.
  • heavy metal ions and the like have a large adsorption capacity and a fast adsorption rate, and the finished product made of the sludge is applied to the filter column of the composite filtration device of the sewage treatment system in the case of the specific embodiment, and Applied in odor treated odor destroyers.
  • the exhaust gas conveying system composed of a plurality of pipes, such as dry dust air generated in the middle, enters the water-sealed flue gas buffer chamber with the action of the two-stage air deflector.
  • the flue gas is input from the underwater 150mm, and then jumps from the bottom to the top in the water body. This action causes multiple smokes of different pressures, different wind speeds and air flows to form the same condition after jumping out of the water surface.
  • the flue gas is filled with solid particles of carbon particles and other substances, enters the treatment channel of the negative ion and the water curtain, and rushes to the ceramic high-speed water curtain area which can naturally release the negative ion charge.
  • the concave, obtuse angle deflector installed on the upper, left and right dislocations, the direction of the instantaneous airflow path is changed. At this time, the moving direction of the dense solid dust particles in the flue gas does not flow in the negative ion region.
  • the water vapor washed by the weak alkaline water enters the gas through the exhaust port provided in the upper part of the twin towers.
  • Water transport pipelines, and tiny solid materials enter the gas and water transport pipelines along with the water bodies at the drains of the lower towers.
  • the hot water vapor entering the gas and water transfer pipeline enters the flue gas discharge system in the upper layer of the pipeline, and the water body and the micro-solid matter entering the gas and water transport pipeline are also in the lower layer of the pipeline, and also enter the flue gas discharge system.
  • the discharge system is divided into upper, middle and lower parts.
  • the liquefiable gas continues to rise, and the upper gas discharge port of the system is discharged. At this time, the temperature of the exhaust gas discharged is not higher than 38 ° C, which is a room-free gas discharge, and the emitted gas has no odor and carbon particles, and no black smoke.
  • the harmful substance, and the air is introduced into the corrugated anion zone provided at the front end of the air discharge port and having a negative ion release amount of 15000/cm 3 under the action of a 1500 m 3 /h air inlet provided in the subsequent stage of the photocatalytic zone, and then discharged.
  • the air that is expelled is a clean, odorless air.
  • the central intelligent control operating system of this specific implementation case is a well-known technology.
  • the specific implementation is to set up a central intelligent control room, a central control operation platform, and a large display screen as a human-machine interface on the production line of each field device.
  • the control cabinet is arranged separately from the gas discharge port.
  • the central control room operation platform is used as a full-line monitoring center, and the whole line working condition is observed from the main screen, and the computer configuration screen is synchronized with the real-time operation to monitor the display fluid dynamics and the motor running state, and also according to the changes in the production process. Make timely data adjustments, and also make on-site control in the central control system.
  • one of the links in the system can be started separately, and the unmanned state can be realized in the main production area in the whole kitchen waste recycling process.

Abstract

公开一种餐厨垃圾全方位处理的集成化装备及产物制造方法,该装备由中央智能自动操控系统、空气处理系统、秸秆生化系统、高级氧化人工强制灭活系统、联合筛选除杂系统、复合生化系统、自动干燥系统、联合输送系统、废塑料逆转工程系统、污泥处理系统、污水处理系统、油脂处理系统、热烟气联合处理系统等组成,所产出成品为高营养微生物蛋白饲料、矿物国III柴油、生物柴油、乳化柴油、低硫清洁燃煤、杂化荷电吸附剂、工业回用水等。餐厨垃圾的资源化利用率达95%以上,生产过程基本无废水排放、无污泥转移、无温室排放、无异味排放、无烟尘排放、无残余物转移。

Description

餐厨垃圾全方位处理的集成化装备及产物制造方法 技术领域
本发明公开一种餐厨垃圾全方位处理的集成化装备及产物制造方法,本发明属于生活垃圾处理综合技术领域,涉及餐厨垃圾资源化处理的集成化设备和制造方法及配方和工艺,同时涉及微生物、生物化学、装备制造、光电、臭氧应用、功能塑料、塑料逆转工程、清洁煤炭、矿物质燃料制造、生物质燃料制造、清洁生产、空气净化、污水处理等众多技术领域。
背景技术
废弃物资源化利用的科学技术,经过长时间的应用,已证明了一个道理,就是如果废弃物的资源化处理技术单一应用,其后果将会对人类生存环境带来更大的危机,尤其是产生二次污染的严重问题难以控制,所以废弃物的综合处理已经成为当前发展的趋势。餐厨垃圾的组成极其复杂,其中包含污水、塑料袋、塑料瓶、废布条、腐败性有机物、纸张、金属瓶罐、破碎玻璃、破碎陶瓷片、动物油脂、植物油脂、原生细菌体等物质。目前餐厨垃圾资源化处理技术在国内外的方法和工艺中已呈现“百花齐放”局面,但是基本都是单纯的单项处理,没有走向从单纯的处理转向综合处理、利用与处置的国际性环保处理趋势和方向,可能会造成餐厨垃圾中的必然附着物进行转移及乱填乱放,造成水土污染,或转移,不仅堵塞城市下水管道,散发恶臭气味,造成严重的二次污染。餐厨垃圾的单一处理工艺从资源化利用价值考虑是可行的,但从长期保护地球环境、人民宜居、保护大气环境的综合性角度来考虑,还是可能弊大于利。
发明内容
针对上述提到的现有技术中的餐厨垃圾都是单纯的单相处理,会造成二次污染的缺点,本发明提供一种大型的高度集成化餐厨垃圾综合处理装备和应用方式及生产工艺与配方,是符合国际目前对废弃物资源化处理后的残余物不转移处理的发展方向。
本发明解决其技术问题采用的技术方案是:一种餐厨垃圾全方位综合处理系统,系统包括餐厨垃圾破袋装置、餐厨垃圾联合筛选装置、湿式高级氧化除臭灭活清洗降盐装置、立式脱水装置、物料破碎机和自动控制装置,餐厨垃圾投入餐厨垃圾破袋装置进行破袋处理,然后输入至餐厨垃圾联合筛选装置进行联合筛选,经筛选后的油水固混合物输入至湿式高级氧化除臭灭活清洗降盐装置进行灭活处理,通过湿式高级氧化已灭活除臭除盐初级脱水的餐厨垃圾由螺旋杆输送管道送入脱水装置,经脱水装置脱水后的物料输入物料破碎机进行粉碎,自动控制装置控制其他装置工作。
一种采用上述的餐厨垃圾全方位综合处理系统的转化物制造方法,该方法包括下述步骤
A、将餐厨垃圾收集,并投入餐厨垃圾破袋装置,对其进行破袋处理;
B、将破袋后的餐厨垃圾通过餐厨垃圾联合筛选装置进行联合筛选,从中分理处固体塑料和其它;
C、对于除去固体塑料后的其他餐厨垃圾通过湿式高级氧化除臭灭活清洗降盐装置进行灭活处理;
D、对于灭活后的垃圾通过立式脱水装置进行脱水处理;
E、对于脱水后的物料通过物料破碎机进行粉碎。
本发明解决其技术问题采用的技术方案进一步还包括:
所述的割破装置包括卧式筒状外壳,外壳一端为出料口,外壳于出料口的一端内壁设有固定一个以上的刀具,外壳另一端内设有能够沿着外壳内腔滑动的活塞,并连接有推动活塞运动的动力工具,活塞上对应于每个刀具位置处开设有一个刀槽,外壳顶部中间位置开有进料口。
所述的活塞底部安装有滑轮,外壳内壁底部对应于滑轮位置处固定设有凹形滑轨,滑轮能够在凹形滑轨上来回滑动。
所述的进料口位置处安装有收集箱,收集箱上部呈漏斗形,下部通过下料管道与外壳上的进料口连通,下料管道上设有气动滑板闸阀。
所述的外壳上的出料口位置处安装有滚动拍板,电机带动滚动拍板转动。
所述的滚动拍板呈方形或多边形并设有内腔。
所述的滚动拍板每个面上设有一个以上的压缩空气射出槽,滚动拍板内设有压缩空气导气管和气体喷射嘴,气体喷射嘴连接在压缩空气导气管上,气体喷射嘴的射流方向与出料口的出料方向相同。
所述的压缩空气射出槽平行设置。
所述的刀具的刀锋与外壳出料口横截面呈90度角或与外壳内壁呈30度角。
所述的餐厨垃圾联合筛选系统包括壳体,壳体内设有分隔板,通过分隔板将壳体内部分为气浮区和非气浮区,分隔板上设有物料漏出口,气浮区处设有进料口,气浮区下部设有重物料卸出口,重物料卸出口处设有阀门,重物料卸出口四周设有一个以上的空气喷嘴,气浮区上部设有滚耙,非气浮区内设有物料输出器,物料输出器一端设置在壳体内,另一端设置在壳体外侧,物料输出器内设有搅龙,物料输出器上安装有电机和变速器,电机配合变速器带动搅龙转动。
所述的物料漏出口处设有百叶导槽,百叶导槽连接在气动推进拉杆上,气动装置驱动推进拉杆运动,并由推进拉杆控制百叶导槽的开启与闭合。
所述的滚耙设有两个,两个滚耙一上一下设置,下面的滚耙的1/2 位置处设置在气浮区的液面内,上面的滚耙设置在气浮区的液面上方,两个滚耙相互啮合。
所述的壳体上安装有滚耙电机,滚耙电机同时带动两个滚耙转动。
所述的物料输出器处安装有变速器,电机通过变速器驱动搅龙转动。
所述的气浮区处安装有用于控制液面高度的液面高度自动控制装置。
所述的壳体上设有用于向壳体内输送餐厨垃圾的管道,该管道连接在进水管道上。
所述的气浮区的循环水进水口连接水力加压泵,水源由循环储水箱提供,非气浮区的中下部设有出水口,并通过水泵将水体输入循环储水箱内,用于气浮区与非气浮区水体的循环和加强气浮区内的水体强力翻滚。
所述的餐厨垃圾氧化、除臭、灭活、清洗降盐装置包括一个以上的反应器和用于臭氧——水——物料混合的气、水、物混合器,混合器上连接有防水单向阀,防水单向阀的一端连接输气管后,再连接臭氧发生设备,混合器上还连接有高粘度凸轮转子泵出口,混合器的出口伸入一个反应器内,高粘度凸轮转子泵的入口与另一个反应器连接,反应器内设有一个以上的颗粒活性碳反应球,颗粒活性碳反应球内设有颗粒活性碳,反应器底部设有物料出口。
所述的颗粒活性碳的总体积占颗粒活性碳反应球球体内腔体积的15%——98%。
所述的反应器顶部设有自动排气阀,自动排气阀上连接有臭氧毁灭器。
所述的反应器底部设有半圆封头,物料出口设置在半圆封头上。
所述的反应器中最前端的反应器上设有斜面螺带输送器,而后端的反应器上设有水位高度调节管道。
所述的物料出口处连接有固、液分离器。
所述的固、液分离器包括外壳和倾斜网状桶体,倾斜网状桶体设置在外壳内,倾斜网状桶体由电机配合变速器带动转动,倾斜网状桶体前端设有一排以上的网孔,倾斜网状桶体内设有连接于网状桶体内壁的螺旋状的螺带,外壳底部设有接水器。
所述的螺旋状的螺带占倾斜网状桶体的全长。
所述的外壳上装有视窗。
所述的反应器侧面装有人孔。
所述的立式脱水装置包括外壳、立式内漏塔和螺带推进杆,立式内漏塔设置在外壳内部,螺带推进杆设置在立式内漏塔内部,立式内漏塔侧面开有一个以上的漏水孔,立式内漏塔底部设有进料口,立式内漏塔顶部设有出料口,外壳底部安装有驱动螺带推进杆转动的动力源,外壳内部对应于立式内漏塔底部四周设有接水槽,接水槽上连接有出水口。
所述的外壳内部,立式内漏塔四周设有一条以上的水管,每条水管上连接有一个以上的高压水反冲喷嘴。
所述的立式内漏塔顶部装有安装螺带推进杆的轴心固定板。
所述的螺带推进杆上的螺带尾端装有调节出料速度的封口板。
所述的螺带推进杆上的螺带的间距为由下部渐步往塔顶收窄。
所述的螺带推进杆上的螺带下端的间距为25CM,终端的间距为10CM。
所述的动力源包括电机、变速器和将水平轴向转动转为竖直轴向转动的转向变换装置,电机带动变速器转动,变速器带动转向变换装置转动,转向变换装置带动螺带推进杆转动。
所述的外壳内设有不锈钢支承套。
所述的立式内漏塔外侧四周设有一条以上的不锈钢立板,不锈钢立板的周围装有一根以上的加固圈套,每根加固圆圈上装有斜面防反冲导流檐。
所述的立式内漏塔由一个以上的塔体组成,每个塔体的上下圆周位置装有加强法兰,且相邻塔体的连接均是塔体上下的法兰之间对接,并采用螺栓固定,每个塔体的连接法兰位置上的上层法兰装有斜面防反冲导流檐。
所述的生化发酵装置包括厌氧发酵池和主发酵装置,所述的主发酵装置包括两个副发酵器和一个以上的主发酵器,两个副发酵器设置在主发酵器上方,副发酵器与主发酵器连接处设有进料口,主发酵装置外设有用于将物料输入至副发酵器内的物料提升机,副发酵器内设有搅拌设备,主发酵器内设有双层螺带搅拌器,厌氧发酵池与主发酵器连接,厌氧发酵池通过自动卸料系统将物料投入主发酵器内。
所述的双层螺带搅拌器包括轴体、内层螺带和外侧螺带,内层螺带设置在外层螺带内部,内层螺带和外层螺带均呈螺旋形带状,且分别固定安装在轴体上,内层螺带和外层螺带的螺旋方向相反,双层螺带搅拌器的轴体周边加装铧叶片。
所述的搅拌设备中间为一个主轴,中轴上固定安装有一个以上的搅拌叶片。
所述的厌氧发酵池内上方设有可自动移动的物料搅拌器。
所述的自动卸料多级干燥装置包括预干燥设备和主干燥设备,预干燥设备安装于主干燥设上方,预干燥设备外壳呈两侧,两侧之间形成预干燥设备的外壳夹层内腔,预干燥设备内设有物料自动翻板,主干燥设备中间为能够360度逆顺方向旋转的卧式圆筒形体,主干燥设备前、后两端分别为固定封头,卧式圆筒形体内设有一个以上的与卧式圆筒形体固定安装在一起的副筒体,卧式圆筒形体和各个副筒体内部均设有导料螺带,主干燥设备上设有气体或液态燃料燃烧室和燃烧器,燃烧器产生的热量通入主干燥设备内部,主干燥设备的尾气通过热空气排出口输入至外壳夹层内腔内,预干燥设备的物料输出口对应于主干燥设备最内侧副筒体设置。
所述的预干燥设备底部设有螺带搅龙自动出料器,螺带搅龙自动出料器呈筒状,内部设有螺带搅龙。
所述的预干燥设备顶部设有引风设备。
所述的各个副筒体套装在一起,外侧副筒体的物料入口长于内层副筒体的物料出口。
所述的各个副筒体的外侧壁上固定安装有气流扰动翅。
所述的卧式圆筒形体和各个副筒体内部的导料螺带方向相反。
所述的物料精选装置包括底座、金属滚动筛网筒、物料承载器、自动输送工具、链板输送机和分流闸板,金属滚动筛网筒安装在底座上,物料承载器设置在金属滚动筛网筒下方,自动输送工具设置在物料承载器下方,金属滚动筛网筒前端设有筛网孔,后端设有螺带,链板输送机设置在金属滚动筛网筒出料口下方,分流闸板设置在链板输送机尾端。
所述的筛网孔直径为4mm——6mm,孔与孔这间间隔为2mm。
所述的金属滚动筛网筒倾斜设置,倾斜角度为1度——20度。
所述的分流闸板处设有用于调节分流闸板与链板输送机之间高度的调节装置。
所述的金属滚动筛网筒外侧安装有保护罩。
所述的餐厨垃圾联合筛选装置设有塑料固体输出端,餐厨垃圾联合筛选装置的塑料固体输出端连接有废塑料逆转工程装置。
所述的废塑料逆转工程装置主要摆阔主体处理装置,主体处理装置由输送带将物料送入气压式自动进料机,通过气压式自动进料机将物料送入裂解催化卧式反应釜内,反应釜能够作360度顺、逆旋转,反应釜内带有自动随机刮壁装置,反应釜上连接有后级真空系统,反应釜通过管道与油腊分离器连接,管道上设有单向阀,油腊分离器通过管道连接有第一级重油分离器,第一级重油分离器通过管道连接有第一级冷凝器,第一级冷凝器底部连接有油料承载容器,第一级冷凝器后端连接有负压设备,负压设备后端连接有立式水封式气体安全输送器,立式水封式气体安全输送器后端连接有二级燃气压缩机,二级燃气压缩机与燃气贮存库连接。
所述的反应釜底部设有裂解炉,裂解炉的出气口管道连接尾气环保装备系统。
所述的油料承载容器连接有除碳精漂器和脱腊除胶器。
所述的系统还包括粗炭黑处理装置,粗炭黑处理装置连接在废塑料逆转工程装置的余渣输出口处。
所述的粗炭黑处理装置包括粗炭黑人工陈化处理器,粗炭黑人工陈化处理器与物理陈化床连接,物理陈化床通过自动输送工具与物料配伍设备连接,物料配伍设备上连接有液、固自动定量加料加料设备,物料配伍设备后端设有多层推拉式螺杆,多层推拉式螺杆后端与低硫高能环保清洁燃煤成形机连接。
所述的系统还包括免蒸馏法生物柴油生产装置,各个装置通过管道将油、水、固混合体先经过油水分离,再送入免蒸馏法生物柴油生产装置。
所述的免蒸馏法生物柴油生产系统包括卧式螺带固液分离设备、油水分离塔、储油容器、油脂胶质脱除设备、生物油常温脂交换设备、分液设备和过滤设备,卧式螺带固液分离设备的出口通过管道连接至油水分离塔中下端,油水分离塔内设有加热管道,加热管道从油水分离塔下部伸入至油水分离塔内部,再从油水分离塔中上部输出至油水分离塔外侧,油水分离塔顶部设有刮油器,油水分离塔通过出油管道与储油容器连接,出油管道入口对应于刮油器设置,储油容器通过管道与油脂胶质脱除设备连通,油脂胶质脱除设备内部设有固定设置有孔洞撞击板,撞击板的两侧对应位置分别安装有旋浆式水力推进机,旋浆式水力推进机的螺旋桨扇叶设置在油脂胶质脱除设备内,电机设置在油脂胶质脱除设备外侧,电机驱动螺旋桨扇叶转动,油脂胶质脱除设备下部设有油脂出口,油脂出口通过管道连通至生物油常温脂交换设备内,生物油常温脂交换设备内设有一个以上的超声波发生器,生物油常温脂交换设备顶部开有投料口,生物油常温脂交换设备底部通过管道连通至分液设备,分液设备底部通过输油管道连接至过滤设备,过滤设备输出生物柴油。
所述的卧式螺带固液分离设备包括有一个卧式圆筒形外壳,外壳内设有滤网,滤网内部固定设有输送螺带,螺带驱动电机配合变速器带动滤网及螺带转动,卧式螺带固液分离设备底部设有油、水混合体输出管道。
所述的油水分离塔的顶部装有红外线水体液面定位仪。
所述的超声波发生器外围分别装有套管,套管四周开有内螺纹射流孔,套管上方固定设有卡定器,通过卡定器将超声波发生器安装在生物油常温脂交换设备内部。
所述的生物油常温脂交换设备内装有液体导流管,液体导流管一端连接在生物油常温脂交换设备上部,另一端连接在生物油常温脂交换设备底部,液体导流管上连接有泵具。
所述的生物油常温脂交换设备底部设有鼓气管,鼓气管的一端连接压缩空气机。
所述的系统还包括油脂胶质脱除设备,由专用油泵将生物油脂从储油容器输入油脂胶质脱除设备之后在进入脂交换设备。
所述的系统还包括制造乳化生物柴油装置,经脂交换工艺出来的生物油脂输出至制造乳化生物柴油装置。
所述的乳化生物柴油的制作装置包括壳体,壳体内装有垂直搅拌器,动力源带动垂直搅拌器转动,垂直搅拌器的中轴上装有一个以上的浆式平直搅拌器或桨式折叶桨,垂直搅拌器的中轴下部安装有涡轮或圆盘弯叶浆,壳体的顶部设置有一个以上的进料口,每个进料口均通过管道连接有一个定量加料设备,壳体下部设置有成品出料口。
所述的壳体上部为圆筒形,下部呈半圆形。
所述的壳体的圆筒形内壁四周安装一个以上的液体导流叶板。
所述的壳体底部安装有支撑垂直搅拌器的转轴用的支承架。
所述的动力源包括电机和变速设备,变速设备固定安装在壳体顶部,电机设置在变速设备上方,电机通过变速设备驱动垂直搅拌器转动。
所述的系统中还包括快速污水处理回用装置,各个装置产生的污水通过管道连接至快速污水处理回用装置。
所述的快速污水处理回用装置包括污水过滤池,污水过滤池内设置有杂物拦栅,杂物拦栅内设有防塞反冲器,污水过滤池通过进水管道与灼热毡污水处理设备连接,灼热毡污水处理设备包括内腔和机壳,机壳顶部设有多个与进水管相通的雾化喷射头,雾化喷射头下方设有一个灼热毡,灼热毡内设有导热油管道,灼热毡下方的底部设有微固物沉淀区,微固物沉淀区底部设有排污口,排污口上方设有防污反冲挡板,灼热毡下方装有用于支撑灼热毡的耐高温垫层,机壳的顶部开有自动吸排气阀,机壳位于灼热毡的上方开有热蒸汽收集口,热蒸汽收集口通过管道与热交换器相连,热交换器后端连接有集水池,集水池通过管段与高级氧化系统连接,高级氧化系统具有内外两层空腔,内腔为气水反应腔,外腔为气水循环反应缓冲腔,内腔进水口引入管的端部装有活性碳反应球,活性碳反应球内装有颗粒活性碳,内腔底部设有排污口,排污口与外壳的排污口相连,内腔的排污口上还安装防反冲档板,高级氧化反应器通过循环管道连接有气水混合器,气水混合器为三通接法,两端接通循环水,而中间的一个端口连接防水单向阀,防水单向阀的另一接口连通臭氧发生器的输气管道,高级氧化系统连接有中转水池,与中转水池连接有活性炭过滤固定床,活性炭过滤固定床上连接有复合过滤设备,复合过滤设备包括一个以上的过滤罐, 过滤罐内分别设有一支以上的立式过滤柱,每支过滤柱长度的一半位置处开有出水孔,过滤柱的底部装有80——140目的滤网,过滤罐的顶部有进水口和加压管,过滤罐罐体内分为二层,每层的罐内分别装有过滤柱托板,过滤柱托板上开有与过滤柱直径相配的孔口,过滤柱插装在过滤柱托板内,上层罐体的上部一侧安装进水导流管道,进水导流管道通向下层罐体的上部,上层罐体的下部一侧安装出水导流管道,出水导流管道通向下层罐体的下部,罐体的上、下层一侧分别安装有排气口,过滤罐的出水口设于复合过滤设备底部封头的一侧,底部封头的中心位置设有沉淀物排出口。
所述的灼热毡表面设有多道流水浅沟。
所述的内腔顶部安装有自动排气阀和用于监控液面高度的液面控制在线监控器。
所述的活性碳反应球上部不透水,下部为网状出水口。
所述的活性碳反应球内的颗粒活性碳体积占反应球内腔体积的15%——95%。
所述的系统还包括对剩余固体污泥处理的杂化荷电吸附剂生产装置,各个工段产生的污泥都输入至杂化荷电吸附剂生产装置。
所述的系统还包括对各个工序中所产生的烟气、热烟气、粉尘等集中处理的尾气环保处理装置。
所述的尾气处理系统包括初步净化装置、水固混合器、双塔式旋转喷淋系统和烟气排放设备,所述的初步净化装置包括空气缓冲器和初级烟气处理管道,尾气通入空气缓冲器内,通过空气缓冲器输入到初级烟气处理管道内,经初级烟气处理管道排入至水固混合器内,水固混合器出口通入双塔式旋转喷淋系统内,经双塔式旋转喷淋系统处理后输入至烟气排放设备内,再经烟气排放设备处理后排出。
所述的空气缓冲器包括圆筒形外壳,外壳内上方设有一个以上的水帘喷射口,外壳底部装有排污口。
所述的初步净化装置还包括有沉淀池,排污口通过管段连接至沉淀池内。
所述的排污口旁边连接有管段,管段连接至沉淀池上部,沉淀池上部通过泵具和管段连接至空气缓冲器内。
所述的空气缓冲器内部上方还安装有用于检测空气缓冲器内部液面高度的在线液面监控器。
所述的初级烟气处理管道内设有一个以上的负离子荷电陶瓷,每个负离子荷电陶瓷后端对应安装有一个高速水雾区喷头。
所述的每个高速水雾区喷头后端安装有一个导流板。
所述的导流板采用凹钝角导流板。
所述的负离子荷电陶瓷安装在初级烟气处理管道内的左、右、上三面上。
所述的尾气处理系统还包括冷却塔,冷却塔对烟气排放设备中的热交换器内的热水气进行冷却。
所述的系统还包括对产生有以为公端的空气及生产区空气处理的等离子光触媒负离子空气除臭杀菌装置,等离子光触媒负离子空气除臭杀菌装置的进风口安装于各个餐厨垃圾收集池的四周。
所述的等离子光触媒负离子空气除臭、杀菌装置包括空气输送管道、光催化主处理器和活性碳空气过滤器,气体输入空气输送管道内,空气输送管道内设有负离子装置,气体通过空气输送管道输入至光催化主处理器内,光催化主处理器内设有空气通道,空气通道内安装有一个以上的发光波长为253nm——258nm的紫外线光管,紫外线光管后端固定安装有二氧化钛光催化触板,空气通道尾端与活性碳空气过滤器连通,通过活性碳空气过滤器将气体输出。
所述的光催化主处理器和活性碳空气过滤器之间连接有空气排出管道,空气排出管道内设有负离子装置,空气通道尾端与空气排出管道连通,空气排出管道与活性碳空气过滤器连通。
所述的负离子装置采用负离子波纹板,负离子波纹板呈层叠式安装。
所述的负离子波纹板设有两段,前段为卧式安装,后段为立式安装。
所述的空气输送管道前端设有进风口,进风口的后端安装有自动滑板闸阀。
所述的紫外线光管背面均配装光面反射板。
所述的光催化主处理器内的空气通道呈Z形。
所述的二氧化钛光催化触板的尺寸和形状与空气通道横截面相吻合,可刚好挡在空气通道内。
所述的二氧化钛光催化触板呈蜂窝型。
所述的二氧化钛光催化触板为厚度1cm——10cm,上开有一个以上的孔洞。
所述的步骤E中粉碎后的物料经过生化处理装置进行生化处理,然后经过自动卸料多级干燥装置进行干燥,然后经过多级干燥和物料精选后,形成混合饲料。
所述的生化处理包括下述步骤:
A、通过厌氧发酵池和两个副发酵器同时作用,生成预发酵物料;
B、当预发酵工段完成后,将两个副发酵器内的物料,通过设于副发酵器底部的自动输送设备送进主发酵器,将厌氧发酵池内的物料,通过自动卸料系统也送进主发酵器,进行二次发酵;
C、二次发酵完成后,进行出料。
所述的厌氧发酵池内生成预发酵物料时,将占总发酵基料重量的50%——80%的豆种作物桔秆和占总发酵基料重量的20%——50%的禾木料作物的当季桔秆破碎成粒径为0.5mm——1mm的粉末,并加入能分解粗纤维的复合菌剂对上述混合物料进行生化处理,所述的复合菌剂中菌种不少于两种,其中一种为米曲霉,复合菌剂的投入量为混合固体基料的1%,并加入化学成份氧化钙、氯化钠、磷酸氢钠和尿素。
所述的一个副发酵器内生成预发酵物料时,在副发酵器中加入已经人工灭活的餐厨垃圾为基料,加入占基料重量1%——2%的麸皮、占基料重量1%——3%的米糠和占基料重量1%的白糖作为混合料,并加入适量的水调成糊状,温度控制在20℃——30℃之间范围 ,并向混合料中加入占混合料总重量的2%——4%的面包酵母,并充分搅拌、强化曝气,以增强酵母生长,发酵的方式可采用老酵法。
所述的一个副发酵器内生成预发酵物料时,在副发酵器中加入已经过人工灭活、清洗并已脱水的餐厨垃圾为基料进行固态发酵,选用由绿色木霉、热带假丝酵母菌、白地菌和拟内孢霉酵母菌组成四菌混合菌剂,四菌的重量比例为2:2:1:1,接种量为总重量的2%,同时添加占总重量1%——1.5%的尿素,温度为25℃——42℃,由搅拌设备每小时翻滚一次,发酵时间9小时——10小时。
所述的二次发酵时,将已进行预生化处理的物料输入主发酵器,秸秆发酵物料中总物料重量百分比的10%——40%,面包酵母发酵物料占总物料重量百分比的20%,第二副发酵器内的发酵物料占总物料重量百分比的40%——70%,当三种经预发酵处理后的物料进入主发酵器内后,双层螺带搅拌器作360度旋转,旋转动作为往返方向,对物料作低速缓慢搅拌,主发酵器内的温度从初始的20℃开始起温,起温阶段物料平均温度20℃——28℃,恒温时间为4小时后关闭空气阀I87,同时提温至35℃——38℃,恒温时间3小时后,开启第一级引风装置,作轻质量排风,当上述的二次恒温时间完成后,再次提温至82℃,时间为2小时,并开启二级引风装置作强力排风。
所述的步骤B中产生的废塑料经过废塑料逆转工程装置逆转生成生物柴油。
所述的制造生物柴油产生的余渣粗炭黑人工陈化处理器,利用臭氧对物料进行陈化,通过化学陈化后的粗炭黑再进入物理陈化床,当粗炭黑经过人工陈化后,由专用自动输送工具输入物料配伍设备,每种配伍助剂均由液、固自动定量加料设备添加,通过多层推拉式螺杆将物料充分混合输入低硫高能环保清洁燃煤成形机,待物料成形后得到粗炭黑。
所述的步骤A至步骤E中产生的污水经快速污水处理回用装置处理后,排出或回用。
所述的步骤A至步骤E中产生的固体污泥处理经杂化荷电吸附剂生产装置处理后生成杂化荷电吸附剂。
所述的步骤A至步骤E中产生的烟气、热烟气、粉尘和抽排口空气经环保处理装置处理后排出。
所述的处理后的气体经过等离子光触媒负离子空气除臭杀菌装置处理后排出。
所述的步骤A至步骤E中产生的油水混合物通过免蒸馏法生物柴油生产方法生产生物柴油,该方法包括下述步骤:
(1)、将餐厨垃圾生产过程中所产生的油、水、固混合物通过卧式螺带固液分离设备进行脱固处理,得到油水混合液;
(2)、将油水混合液输送至油水分离塔进行油水分离,将分离后的油脂输入储油容器;
(3)、当需要对生物油脂时行加工处理时,通过输送泵等工具将生物油脂送进油脂胶质脱除设备内后,启动旋浆水力推进机,并加入浓度为85%的磷酸,磷酸与生物油脂的比例为不超过油脂总量的1%,利用油脂胶质脱除设备两端的旋浆推力使油脂胶质脱除设备内部的液体产生相向撞击,撞击时间为10 min——15min,在液体的相向撞击时间结束后,当即加入稀盐水,稀盐水中水、盐的重量比为95:5至90:10之间,生物油脂与稀盐水的重量比例为90:10至80:20之间;
(4)、继续启动旋浆水力推进机,时间为10 min——20min;
(5)、油脂混合体于油脂胶质脱除设备中停留60min——120min;
(6)、将已脱胶质的生物油脂被输进生物油常温脂交换设备;
(7)、当生物油常温脂交换设备内的油脂输入的液面达到生产工艺设定的液面高度时,停止输入,开始启动生物油常温脂交换设备底部的鼓气管,打开投料口,加入固体催化剂和甲醇,固体催化剂用量为生物油脂质量的1.5%——3.5%,甲醇用量为生物油脂质量的3%——8%,在加入甲醇后再加入共溶剂;
(8)、利用搅拌器连续搅拌10 min——15min,再加入固体金属碱催化剂,加入量为生物油脂质量的3%——4.5%;
(9)、当加入所需要的助剂后,关闭投料孔,开启物料循环输送泵,并开启超声波发生器,超声波发生器的初始频率为25KHZ,时间为1min,随后逐步增大到30KHZ,时间为30 min——40min,反应温度为25——35℃。
(10)、当油脂于生物油常温脂交换设备中完成脂交换后,将生物油脂混合物输入分液设备静置分层,上层为甲醇和甘油混合液体,下层为粗制生物柴油;
(11)、首先将分液设备设于下部排液口开启,让粗制生物柴油输送进入过滤设备,过滤后得到精制生物柴油并回收固体催化剂。
所述的油水分离时,油水分离塔内的油水混合液加热至60℃——85℃,待生物油脂上浮后实现油水分层,上层的生物油脂由刮油器刮出,并通过出油管道送入储油容器内。
所述的共溶剂的选择为甲乙醇,共溶剂的加入量是生物油脂质量的0.5%——2%,共溶剂还包括有加入量是生物油脂质量的0.5%的丁醇。
所述的固体阴离子金属碱催化剂的特征是以试剂活性碳和铝、钠、铁、锂的环状结构硅酸盐矿物的纳米颗粒为基核,再外裹硅、铝、锂网状骨架介质,且带极性的杂化荷载体,再净该载体浸渍于KNO3液体中,经处理后而成为带极性的杂化荷电,含15%——25%的KNO3的固体阴离子金属碱催化剂。
所述的生物柴油通过微乳化生物柴油的制作装置制作成乳化生物柴油,该方法包括下述步骤:
(1)、将粗生物柴油输入上述的微乳化生物柴油装置内,启动搅拌系统,加入30%-80%国III标准柴油后,搅拌5min;
(2)加入亲水剂,加入量为纯生物柴油和国III标准柴油总重量的2-3%,作1min——15min时间的搅拌;
(3)、加入丁醇作为中间体,加入量为纯生物柴油和国III标准柴油总重量的2-4%,继续对混合液作不间接搅拌15min,搅拌时,垂直搅拌器(P175)作100转/min——130转/min的转速搅拌;
(4)、加入异戊烷作为自燃温度调节剂,加入量为纯生物柴油总重量的1.5-2%;
(4)、加入富氧水,水占产品总重量的1%——20%,再搅拌15min,转速调整为170转/min——200转/min,再加入十八碳—顺—9—烯酸作为乳化剂,十八碳—顺—9—烯酸的加入量为所加入干净水重量的70%——90%,在搅拌设备的连续搅拌下直至澄清透明为止,此时,搅拌器的转速调整为280——340转/min,一般需要连续搅拌40——60min,待静置一定时间观察乳化油为清洁透明无分层后为成品。
所述的亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂,配比例为阳离子表面活性剂50%,非阳离子表面活性剂50%。
所述的表面活性剂有三乙醇胺或六氢苯胺或西曲溴铵和氨水。
所述的水的加入量为总重量的10%——20%。
所述的十八碳—顺—9—烯酸设定量的酸值为200。
本发明的有益效果是:1、通过本发明申请所述的餐厨垃圾全方位处理的集成化装备和方法是一套国内、外餐厨处理同业首次以高集成化、自动化、全面化的综合装备,兼容对餐厨垃圾必然附着物同时作出资源化处理的方法,适应国际环保产业趋向,实施对废弃物集中综合处理后残余物不转移消化,不产生二次污染的安全处理、处置方向。
2、本发明申请提供了对餐厨垃圾及其必然附着物——废塑料袋,泔水污泥和厂区生活污水,生产过程产出的工业污水及污泥,在同一装备中的各种大型系统设备中的处理方法。
3、本发明申请提供了餐厨垃圾综合性资源化处理后,所制成各种高附加值的产品名称和制造方法及其用途。
4、本发明申请为餐厨垃圾处理行业提供了一种综合性的节能生产、安全生产、无残余物转移处理,无室温排放,无异味排放接近无污水排放的清洁生产方法和模式。
5、本发明所产出的产品为国III矿物柴油,低硫高热值清洁环保煤,燃气三大战略能源,起到减轻社会供需压力。同时所产生的高营养微生物蛋白饲料添加剂,能有效地填补国内饲料高蛋白质添加剂缺失的缺口。
6、本发明提供了一种餐厨垃圾承载器(桶)且能自然杀菌除臭,并于桶体外周边能自然提供清洁空气的新型垃圾承载器(桶)生产方法,是一种应用面极其广阔的新型环保清洁用具。
下面将结合附图和具体实施方式对本发明做进一步说明。
附图说明
图1为本发明系统核心部分流程示意图。
图2为本发明系统流程示意图。
图3为本发明能量塑料承载器具生产流程示意图。
图4为本发明中收集装置结构示意图。
图5为本发明中餐厨垃圾破袋装置立体结构示意图。
图6为本发明中餐厨垃圾破袋装置切面结构示意图。
图7为本发明中餐厨垃圾破袋装置剖面结构示意图。
图8为本发明中餐厨垃圾联合筛选装置结构示意图。
图9为本发明中餐厨垃圾联合筛选装置剖面结构示意图。
图10为本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置结构示意图。
图11为本发明中的初级固体分离器结构示意图。
图12为本发明中的立式脱水装置结构示意图。
图13为本发明中的立式脱水装置内部结构示意图。
图14为本发明中主生化处理装置结构示意图。
图15为本发明中主发酵装置结构示意图。
图16为本发明中主生化处理装置立体结构示意图。
图17为本发明中的自动卸料多级干燥装置结构示意图。
图18为本发明中预干燥设备剖面结构示意图。
图19为本发明中主干燥设备结构示意图。
图20为本发明中主干燥设备剖面结构示意图。
图21为本发明中精选装置结构示意图。
图22为本发明中混合饲料装置结构示意图。
图23为本发明中废塑料逆转工程装置部分结构示意图。
图24为本发明中废塑料逆转工程装置部分结构示意图。
图25为本发明中废塑料逆转工程装置部分结构示意图。
图26为本发明中废塑料逆转工程装置部分结构示意图。
图27为本发明中粗炭黑处理装置结构示意图。
图28为本发明中水、油、固分离装置结构示意图。
图29为本发明中生物柴油生产装置结构示意图。
图30为本发明中生物油常温脂交换设备切面结构示意图。
图31为本发明中超声波换能器切面结构示意图。
图32为本发明中制造乳化生物柴油装置结构示意图。
图33为本发明中快速污水处理回用装置部分结构示意图。
图34为本发明中快速污水处理回用装置部分结构示意图。
图35为本发明中快速污水处理回用装置部分结构示意图。
图36为本发明中快速污水处理回用装置部分结构示意图。
图37为本发明中杂化荷电吸附剂生产装置部分结构示意图。
图38为本发明中杂化荷电吸附剂生产装置部分结构示意图。
图39为本发明中杂化荷电吸附剂生产装置部分结构示意图。
图40为本发明中的尾气处理系统的示意图。
图41为本发明中双塔形湿式气固分离器及其内部构造示意图。
图42为本发明中初级烟气处理管道构造示意图。
图43为本发明中烟气排放系统及其内部构造示意图。
图44为本发明初级烟气处理管道构造示意图。
图45为本发明中的等离子光触媒负离子空气除臭杀菌装置结构示意图。
图46为本发明中的等离子光触媒负离子空气除臭杀菌装置气体收集及前处理装置部分结构示意图。
具体实施方式
本实施例为本发明优选实施方式,其他凡其原理和基本结构与本实施例相同或近似的,均在本发明保护范围之内。
请参看附图1和附图2,本发明主要为一种餐厨垃圾全方位综合处理系统,该系统包括餐厨垃圾破袋装置、餐厨垃圾联合筛选装置、湿式高级氧化除臭灭活清洗降盐装置、立式脱水装置、物料破碎机和自动控制装置,餐厨垃圾投入餐厨垃圾破袋装置进行破袋处理,然后输入至餐厨垃圾联合筛选装置进行联合筛选,经筛选后的油水固混合物输入至湿式高级氧化除臭灭活清洗降盐装置进行灭活处理,通过湿式高级氧化已灭活除臭除盐初级脱水的餐厨垃圾由螺旋杆输送管道送入脱水装置,经脱水装置脱水后的物料输入物料破碎机进行粉碎,自动控制装置控制其他装置工作。本实施例中,物料输入物料破碎机进行粉碎的物料后端还设有生化处理装置,进行生化处理,生化处理过的物料输入预干燥设备和主干燥设备进行干燥然后经过精选装置精选和混合饲料装置的混合后,形成饲料产品。
餐厨垃圾联合筛选装置输出的固体废物输入废塑料逆转工程装置中进行处理,然后经免蒸馏法生物柴油生产装置和制造乳化生物柴油装置后形成生物柴油,产生的余渣经过粗炭黑处理装置处理成粗炭黑。
系统产生的污水输入快速污水处理回用装置,系统产生的尾气输入尾气环保处理装置和等离子光触媒负离子空气除臭杀菌装置进行处理后排出,系统产生的污泥输入杂化荷电吸附剂生产装置进行杂化荷电吸附剂生产。
本发明的主要步骤如下:
A、将餐厨垃圾收集,并投入餐厨垃圾破袋装置,对其进行破袋处理;
B、将破袋后的餐厨垃圾通过餐厨垃圾联合筛选装置进行联合筛选,从中分理处固体塑料和其它;
C、对于除去固体塑料后的其他餐厨垃圾通过湿式高级氧化除臭灭活清洗降盐装置进行灭活处理;
D、对于灭活后的垃圾通过立式脱水装置进行脱水处理;
E、对于脱水后的物料通过物料破碎机进行粉碎。
下面将结合具体结构及其操作步骤对本发明做进一步阐述:
本发明中的源头为能量塑料承载器具A,餐厨垃圾投之于能量塑料承载器具A内,然后通过专用收集车B将餐厨垃圾收集点的盛装餐厨垃圾的能量塑料承载器具A收集输送到生产处理工场。请参看附图3,本发明中采用的能量塑料承载器具的生产工艺步骤如下:
A、餐厨垃圾源头的能量塑料承载器具的制造工艺和方法:
Aa、采用适合于制造餐厨垃圾桶的塑料载体树脂为基础原料;
Ab、采用经过人工物理陈化的碳黑A1与纳米级天然能量石粉A2、超细锐钛型二氧化钛A3(本实施例中,二氧化钛的粒径小于1μm)经混合器搅伴A4搅拌后作为能量原料,其中能量原料中纳米级天然能料石粉和碳黑的混合料重量比例为50%——85%:50%——15%,超细锐钛型二氧化钛占混合料总重量的10%——15% ,本发明的能量塑料母粒的制作步骤可参看,申请人在先申请的申请号为 201010154643.3 的中国专利 ;
Ac、能量原料在干燥设备中A5以100——120℃温度条件下恒温1——2小时,干燥后的能量原料再加入占能量原料比重的2%的氨基硅烷类或硬脂肪酸镁的物料作为分散剂;
Ad、将已加入分散剂的能量原料与塑料载体树脂及氧化钙填充剂混合均匀,其中塑料载体树脂与加入分散剂的能量原料的重量比为1:2~1:1,塑料载体树脂与氧化钙的加入量为20:1。
Ae、将上述处理过的物料进入专业塑料混炼设备A6进行混炼,由挤出机A7挤出切料制造成塑料能量母料。
Af、塑料能量母料通过注塑机A7a根据制造餐厨垃圾承装器具的成型模具的几何形状成型产品。
2、通过本发明中的上述工艺所制成的餐厨垃圾承装器具不论大小和形状均具备能长久释放出5000——12000个/cm3负离子,由于天然能量石粉的特殊结构,造就其能长期发出波长为4——14微米的光线,此光波长正适合激发承装器具中二氧化钛的光子,使垃圾承装器具能长久产生光催反应过程,所需消耗的能量是出于承装器具的自身本体,符合能量守恒原则。
3、本发明中采用的能量塑料餐厨垃圾承装器具能长久地释放大量负离子功能,还具有长期的光催化能力,所产生光生电子和光空穴具有很强能量,远远高出于餐厨垃圾有机污染物分子链的强度,可以轻易地将有机污染物分解成最原始状态,形成高效率的抗菌作用。
B、将餐厨垃圾收集点的垃圾承载器具由专用收集车收集输送到生产处理工场。
C、生产区餐厨垃圾收集装置。
D、餐厨垃圾破袋装置。
请结合参看附图4、附图5、附图6和附图7,本发明中,专用收集车B将餐厨垃圾输送到生产处理工场后,投入到餐厨垃圾破袋装置内,本实施例中,餐厨垃圾破袋装置主体为一个圆筒形外壳D11,本实施例中,圆筒形外壳D11呈卧式结构设置,圆筒形外壳D11采用支撑架支撑(图中未画出)。圆筒形外壳D11一端开口,为本发明的出料口D18,另一端封堵,封堵一端内部设有能够沿着圆筒形外壳D11往返滑动的活塞D13,活塞D13的横截面与圆筒形外壳D11的横截面相吻合。圆筒形外壳D11封堵一端外侧安装有动力工具D12,本实施例中,动力工具D12为气动动力工具或液压动力工具,即气缸或液压缸等,动力工具D12通过连杆连接在活塞D13上,通过动力工具D12的伸缩运动,使活塞D13在卧式圆筒外壳D11内腔做出来回往复的直线运动。本实施例中,在活塞D13上周边开有若干刀槽D14,刀槽D14的横截面底部呈长方形,顶部呈三角形,刀槽D14的数量以可以满足破袋需要为宜,可根据外壳D11的直径作出调整,本实施例中,采用八个。本实施例中,在圆筒形外壳D11的出料口D18一端,固定安装有若干个刀具D16,刀具D16的数量与刀槽D14数量相同,刀具D16的安装位置对应于刀槽D14安装,即每个刀具D16对应一个刀槽D14,刀具D16的横截面形状与刀槽D14形状相吻合,可略小于刀槽D14形状,使刀具D16可在刀槽D14内自由运动,刀具D16的横截面也是底部呈长方形,顶部刀锋呈三角形,本实施例中,刀具D16可采用两种结构形式,其刀锋的安装角度与圆筒D11的出料口横截面呈90度角,或与内壁呈30度角。本实施例中,刀具D16的长度约为圆筒形外壳D161总长度的1/5,活塞D13的长度约为圆筒形外壳D11总长度的2/5,具体实施时,刀具D16和活塞D13的长度可根据实际需要设定。当活塞D13后退至端点时,活塞D13与刀具D16之间的空间为隔空位置EQ。
本发明中,餐厨垃圾破袋装置中的圆筒形外壳D11的顶部中间位置开有进料口D21,进料口D21对应于隔空位置D1设置。本实施例中,在进料口D21处固定安装有餐厨垃圾收集箱D19,本实施例中,收集箱D19外壳呈漏斗型,其接近于圆筒形外壳D11上的进料口D21位置处为下料管道D20,本实施例中,在下料管道D20上安装有气动滑板闸阀18,用于与下一处理工段的气味隔断。本实施例中,在圆筒形外壳D11内壁下部固定安装有凹形导轨D17,活塞D13下方对应于凹形导轨D17位置处安装有一个以上的滑轮D15,滑轮D15与凹形导轨D17相配合,能够保障活塞D13在动作过程中不偏离中心点。
本实施例中,在对应于出料口D18(也称为外壳非动力牵动端)位置处装有正方形滚动拍板D22,滚动拍板D22由电机D28配合变速器提供动能,带动其转动,滚动拍板D22横向于圆筒外壳D11上的出料口D18安装,本实施例中,滚动拍板D22上的每边板面上均开有若干压缩空气射出槽D23,压缩空气射出槽D23呈条形,各个压缩空气射出槽D23平行设置。本实施例中,正方形滚动拍板D22内部为腔体D25,腔体D25内部安装有压缩空气导空管D24和气体喷射嘴D26,压缩空气导空管D24内设有压缩空气,并可通过气体喷射嘴D26喷出,气体喷射嘴D26的空气射流方向与出料口D18出料方向相同,气体的喷射方法为每秒1-2次,气体喷射嘴D26喷出的空气通过压缩空气射出槽D23射出,利用气体射流将塑料袋吹向前方。
本发明中的餐厨垃圾破袋装置在使用时,当餐厨垃圾以散装或从大袋夹杂小袋的塑料袋承装形式投入收集箱D19中,进入餐厨垃圾收集箱D19时,主设备的活塞D13由气动工具作为动力源,作出卧向的直线推拉动作,此时设于出料口D18的四方形滚动拍板D22也同时开始滚动。当餐厨垃圾收集箱D19的下料管道D20的气动滑板闸阀D27打开,垃圾自上而下通过下料管道D20,并利用主设备的活塞D13后退到端点时呈现出的进料隔空位置D1,使餐厨垃圾于此期间穿过进料口D21,且同时进入主体设备的内空腔的隔空位置D1。当散装或袋装的餐厨垃圾进入主体设备的内腔后,此刻的活塞D13通过气动工具的推动杆动作将餐厨垃圾向前方强力推动,由于活塞D13的向前推进移位,此时进料口D21下的内空腔被活塞D13梗塞,进料口D21呈关闭状态,而餐厨垃圾被活塞D13推向设备圆筒外壳D11内圆的刀具D16位置,并利用设于活塞D13外周的刀槽D14,使刀锋穿入刀槽D14内,餐厨垃圾的塑料袋于此时被刀锋割开若干瓣破口。当承装餐厨垃圾的塑料袋被割开若干瓣破口后,被活塞D13顺势推向出料口D18的滚动拍板D22位置,已破口的餐厨垃圾承装袋在滚动拍板D22的强有力拍打动作下,内装的餐厨垃圾从塑料袋裂口处向外漏出,在这同时设于滚动拍板D22内的多段引力压缩空气通过射向拍板面的出射槽D23,射出使餐厨垃圾进一步脱袋,并以此引力气体射流将塑料袋吹向前方,避免被落下的餐厨垃圾覆盖,而影响下一步分选工作的进行。
通过本发明中的餐厨垃圾承装袋分瓣割破装置,是有针对性的餐厨垃圾转化为微生物高蛋白饲料的生产过程,防止塑料碎片混入饲料的必要性,通过本装置可实现塑料袋分瓣割破、拍板打散、气吹脱袋的联合动作,保障在餐厨垃圾的破袋工序中,不产生塑料袋被破成碎片,尤其是做到破袋且不破碎,餐厨垃圾脱袋,且不被垃圾覆盖的显著效果。
经破袋后的餐厨垃圾进入餐厨垃圾联合筛选装置,对其进行筛选,已破袋的餐厨垃圾先被推进磁选器作为初步筛选后,再被加入到液态气浮分选装置,主要作用于对餐厨垃圾进行水力分选及盐分清洗,请参看附图8和附图9,本发明中的餐厨垃圾联合筛选装置主要用于将已破袋的餐厨垃圾进行筛选,其主要用于对餐厨垃圾进行水力分选及盐分清洗,因此本发明中的此部分称为水浮筛选设备,或液态气浮分选装置。
E、餐厨垃圾联合筛选装置:
本发明中的餐厨垃圾联合筛选装置的壳体E11的上部为圆桶形,下部为内空圆锥体E18组成,进料口设于壳体E11的中上部,利用管道水流冲力将餐厨垃圾由上一工段出口由高而下推进壳体内部的气浮区E10中,管道用水为污水处理系统经过处理的回用水,管道靠近进料口处装有进水管道E20,进水管道E20前端装有水力加压泵E21,通过水力加压泵E21的作用,利用水压将餐厨垃圾冲入壳体内部的气浮区E10。
本发明中的餐厨垃圾联合筛选装置主要分为气浮区E10和非气浮区E32,壳体E11内部设有分隔板E25,本实施例中,分隔板E25设置在壳体E11内部立面约1/3位置处,将壳体内部分为气浮区E10和非气浮区E32,即气浮区E10占壳体内部空间的约2/3,非气浮区E32占壳体内部空间的约1/3,进料口连接在气浮区E10上部的一侧。在气浮区E10顶部接近液面的位置处安装有滚动耙齿E30(或称为滚耙),本实施例中,滚动耙齿E30设有两个,两个滚动耙齿E30一上一下安装,下方的滚动耙齿的1/2设置在液面内,上面的滚动耙齿设置在液面上方,两个滚动耙齿E30通过滚耙电机E39同步驱动转动。本实施例中,两个滚动耙齿E30的齿位运动轨迹是于相互的齿位间通过,即当两个滚动耙齿E30转动时,第一滚动耙齿的齿位设置在第二滚动耙齿两个相邻齿位之间,同理,第二滚动耙齿的齿位设置在第一滚动耙齿两个相邻齿位之间,该组滚动耙齿E30是用于将餐厨垃圾在液态气浮过程中的低密度物料浮于水面时的捞取作业及卸料作业,主要用于捞取塑料袋、牙签等密度轻的物料,下方的滚动耙齿将塑料袋、牙签等捞出,然后再经过上方的滚动耙齿运走。壳体E11底部设有残余物出料口E22,残余物出料口E22上设有阀门E23,残余物出料口E22和阀门E23主要对应于气浮区E10设置,用于将物料中的重物卸除。本实施例中残余物出料口E22四周装有一个以上的空气喷嘴E24,向水体内通入空气,用于对气浮区E10内的水体及物料作爆动翻腾动作,本实施例中,还在非气浮区E32与气浮区E10之间装有循环水管道E40,循环水管道E40于非气浮区的一端为出水口E41,而气浮区E10的一端为补水口,循环水管道是通过储水箱E42连接,以实现餐厨垃圾的液态气浮分选。本实施例中,分隔板E25距离底部20cm以上位置安装有半浮物料的漏出口E26,漏出口E26处安装开口向上的百叶导流槽E27,各个百叶导流槽E27的槽向位置安装气动推拉杆E28,气动装置E38推动气动推拉杆E28上下运动,从而实现百叶导流槽E27的打开与闭合,以及张开角度的控制,从而控制半浮层物料,即被视为有用途的餐厨垃圾进入非气浮区E32内。本实施例中,非气浮区E32为与气浮区E10连通的另一个桶体,气浮区E10和非气浮区E32通过平浮层物料的漏出口E26连通。本实施案例中,设于非气浮区一侧的出水口E41,主要是保障非气浮区E32的水平液面位低于气浮区E10的水平液面位,并通过输出的水体进入储水箱E42后,再对气浮区E10进行补水,且在设于补水管道上装置的水力加压泵E21作用下,水体以强力输入气浮区E10的下部,加强水体及物料的翻腾动作,强化有用的半浮物通过百叶导流槽E27进入非气浮区内。本实施例中,非气浮区E32的下部装有物料输出器E33,物料输出器E33一端设在非气浮区E32内,另一端露于壳体E11外侧,露于壳体E11外侧端设有卸料口E35,物料输出器E33内部设有螺旋搅龙E37,物料输出器E33外侧端上固定安装有卸料电机E36,与卸料电机E36对应安装有变速器E34,卸料电机E36通过变速器E34驱动螺旋搅龙E37转动,将物料由非气浮区E32内由下而上搅出,再由卸料口E35输出,至下一工段。本实施例中,壳体E11内上部装有液面高度自动控制装置E29,用于控制气浮区E10内的水位,以防水体溢出。
本发明中的餐厨垃圾联合筛选装置设置在地面下部或地面上方,其将已破袋的餐厨垃圾被推进磁选器(磁选器是利用磁铁将餐厨垃圾中的铁杂质去除)作为初步筛选后,再加入本发明中,餐厨垃圾被水力卸料管推入装置内,物料中含有塑料袋、玻璃瓶、金属片、小形轻质木条等,复杂的餐厨物料在液态气浮区E10内,利用气浮动力,将塑料袋和轻质小形木条等其密度低于其他物料而被水力推向水面时,被滚耙E30捕抓并经另一滚耙E30送向轻质物料输送槽,进入废塑料逆转工程工段或废塑料收集室,而在液态气浮区E10内的玻璃瓶、玻璃碎片及金属等密度大的物料沉至气浮区E10内底部,并待适当时间打开重物质出料口E22自动阀门E23收集并由自动输送工具送达待处理车间。当轻质物料全部浮于水面后,百叶导流槽E27方可打开,让制造高蛋白饲类的平浮层餐厨物质利用水体流向压力自动进入百叶导流槽E27的漏出口E26并进入非气浮区E32内,设于百叶导流槽E27的推拉杆E28由气动控制,在于生产过程中设定的时间内能自动使导流槽体E27内作开启和闭合运动,作用于气浮区E10中有用物料向非气浮区E32输送。当有用的物料进入非气浮区E32内后,斜面螺带输送器E33开始启动,并在有效分离部分水体的同时,将已初步分选的餐厨物料送入下一工段装置内,进行进一步处理。
本发明中的餐厨垃圾联合筛选装置可利用气浮和水浮、滚耙和百叶导流槽的开与合动作及气浮区与非气浮区的水位压差,将餐厨垃圾中的塑料、牙签等去除,在利用沉积工艺将餐厨垃圾中的玻璃、金属等重物去除,最后将有用物料输出进行进一步加工,实现餐厨垃圾自动筛选。
当有用的物料进入非气浮区内后斜面螺带输送器开始启动,并在有效分离部分水体的同时,将已初步分选的餐厨物料送入下一工段装置内,即湿式高级氧化、除臭、灭活、清洗降盐装置。
F、湿式高级氧化、除臭、灭活、清洗降盐装置:
本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置主要是利用臭氧气体在水体中对餐厨垃圾进行杀菌和清洗,该装置分为一个以上的反应器F34,并每个反应器F34通过泵具和管道相互连接且循环于每个反应器F34,具体的反应器F34的数量,可根据实际需要设定。
下面将以一个具体的反应器F34的结构对本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置进行具体说明。请参看附图10,反应器F34呈圆筒形,为不锈钢空腔结构,反应器F34下部为半圆封头F35,反应器F34的顶部为半圆或平顶封头F37,反应器F34的顶部封头F37上安装有自动排气阀F53,自动排气阀F53上连接有臭氧毁灭器F39,反应器F34内的气体可通过自动排气阀F53排除至臭氧毁灭器F39内,通过臭氧毁灭器F39对气体内残余的臭氧进行去除,然后通过气体排出管段F50排出。本实施例中,反应器F34的入口处连接有斜面螺带输送器F36,将已分选的餐厨垃圾废弃物由斜面螺带输送器F36送入湿式高级氧化除臭、灭菌、清洗降盐装置F36f内,斜面螺带输送器F36呈管状,内部设有输送螺带,通过输送螺带的转动将物料送入反应器F34。反应器F34的内腔体内周边固定安装有一个以上的颗粒活性碳反应球F41,其位置装于反应器F34内腔体内的中上部位,颗粒活性碳反应球F41为不锈钢网状外壳,颗粒活性碳被包于不锈钢网状外壳内部,本实施例中,颗粒活性碳的总体积占颗粒活性碳反应球F41球体内腔体积的15%——98%,颗粒活性碳反应球与臭氧的联合应用,能使臭氧在液态中加速转化为羟基自由基的作用,达到提升臭氧对水中细菌的人工强制灭活和除臭速度。本实施例中,反应器F34内腔顶部还装有在线液面自动控制监控器F40,用于监测反应器F34内的液面高度,在线液面自动控制监控器F40可采用液体传感器实现,并通过另一反应器F34的水位高度控制管道F54的给、排,对液面高度进行调整。
本实施例中,在反应器F34的外壳上还安装有用于臭氧——水——物料混合的气、水、物混合器F42。混合器F42为三通接法,其一端通过连通管道F55通向反应器F34的内腔,另一端与高粘度凸轮转子泵F49的出口F43连通,混合器F42的中心端连接有进气口,进气口连接于防水单向阀F56处,臭氧发生器F44提供的气体通过输气管F57进入并通过防水单向阀F56,进入混合器F42内与水、物强力混合,以此使水——餐厨垃圾——臭氧的混合体再通过设于反应器F34下部的循环管道中的高粘度凸轮转子泵F49输送到另一反应器F34,而形成一个循环往复于两个反应器之间的过程,控制物料的混匀连续的氧化时间。
上述结构为本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置的前部结构,本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置还包括有后部结构,高级氧化除臭、灭菌、降盐份装置的后一部分为固、液分离器,请结合参看附图11,本实施例中,分离器由倾斜网状桶体F52构成,分离器前端连接在反应器F34底部的半圆封头F35的出料口15A处,桶体F52上设有多排网孔,本实施例中,网孔直径为3-8mm,桶体F52外设有外壳F45,外壳F45侧面装有视窗F46,用于观看桶体F52内部情况。外壳F45底部设有安装有接水器F47,用于承接网状桶体F52漏下的水,倾斜桶体F52内全长装有导流螺带通向出料口F48,即在倾斜网状桶体F52全长装有螺旋状的螺带,靠螺带将物料导出,倾斜网状桶体F52的转动动力,源于交流电机配合变速器带动,图中未画出。
本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置在使用时,将水和餐厨垃圾混合体通过斜面输送器F36投入反应器F34内,其餐厨垃圾混合体与水体积的比例为5:7,呈流动性,利用高粘度凸轮转子泵F49不间断地循环于各个反应釜内与外之间,并在水——气混合器F42中加入臭氧气体,与水——餐厨垃圾物料强制混合,混合物料中的臭氧浓度为10g/T——15g/T,混合物料利用循环于反应釜内与外的运动时间作为高级氧化反应,全程时间为5min——15min,由于臭氧在水中时刻发生还原反应,并在活性碳反应球的协助反应作用下引发链式反应,加速臭氧转化为羟自由基,类似于O3/H2O2或O3/UV的高级氧化过程,产生强烈氧化作用的单原子氧和羟基OH,对餐厨垃圾中的致病菌进行人工强制灭活和除臭并清除氯化钠物质。当餐厨垃圾经过对细菌实行人工灭活和除臭的工段完成后,打开反应釜出料口15A下部阀门,利用高粘度凸轮转子泵输入固、液分离器内进行脱水。
利用本发明中的湿式高级氧化、除臭、灭活、清洗降盐装置,可采用臭氧对餐厨垃圾进行氧化、除臭,脱盐,防止其散发难闻气味,污染空气,同时,可对餐厨垃圾中的细菌、病毒等微生物进行灭活,防止其散播,尤其是若在下一工段需要对餐厨垃圾进行生化处理时,保障处理过程不受杂菌干扰。
G、立式脱水装置
通过湿式高级氧化已灭活、除臭、除盐、初级脱水的餐厨垃圾由螺旋杆输送管道送入脱水装置进行脱水,本实施例中,脱水采用立式脱水装置,请参看附图12和附图13,本发明中的立式脱水装置主要包括外壳G49、立式内漏塔G50和螺带推进杆G51三部份组成,外壳G49呈立式圆筒状,立式内漏塔G50设置在外壳G49内部,外壳G49内部贴近外壳G49内壁处设有不锈钢支承套G56,本实施例中,立式内漏塔G50为一种立式安装的下大上小之圆锥体(请结合参看附图13),本实施例中,立式内漏塔G50由一个以上的塔体组成,每个塔体均呈圆台形,每个塔体的上下圆周位置上均装有加强法兰G67,相邻塔体的连接均是塔体上下的法兰G67之间对接,并采用螺栓G68固定,将多个塔体拼接成一个整个的立式内漏塔G50,本实施例中,在每层塔体的连接法兰位置上的顶部的法兰位置处装有斜面防反冲导流檐G59。外壳G49内对应于立式内漏塔G50的外部四周装有若干高压水反冲喷嘴G53,高压水反冲喷嘴G53安装在水管G65上,本实施例中,水管G65设置有一条以上,各个水管G65在外壳G49内部竖直设置,且分布在立式内漏塔G50的外部四周,每条水管G65上设有一个以上的高压水反冲喷嘴G53用于对立式内漏塔G50的清洗和防堵塞。螺带推进杆G51设置在立式内漏塔G50内部,且与立式内漏塔G50内部形状相吻合,螺带推进杆G51中间为螺带转动轴,转动轴上安装有推进螺带,螺带的轴间距由下部的25CM渐步往塔顶收窄,终端间距为10CM。外壳G49底部外侧安装有电机G54和变速器G64,电机G54带动变速器G64转动,外壳G49底部安装有转向变换装置G66,变速器G64通过皮带带动转向变换装置G66转动,转向变换装置G66将水平转动转换成竖直方向转动,转向变换装置G66带动螺带推进杆G51转动,本实施例中,转向变换装置G66可采用蜗轮蜗杆副或斜齿轮副。进料口G62设于立式内漏塔G50下部一侧,出料口G60设于立式内漏塔G50上部一侧,使物料由下而上运行。立式内漏塔G50顶部装有安装螺带转动轴的轴心固定板G61,在轴心固定板G61与螺带推进杆G51上的螺带尾端之间还装有可调节出料速度的封口板,封口板可上下调节,且由液压或气动工具16控制,通过封口板的上下调节,可调节出料口G60的大小,从而调节出料速度。立式内漏塔G50四周固定设有多条不锈钢立板G57,不锈钢立板G57竖直设置,立式内漏塔G50四周分布有多个漏水孔G58,漏水孔G58呈长条形,且设置在不锈钢立板G57之间。立式内漏塔G50的塔体对接之法兰及不锈钢立板G57的加固圈套G69外圆圈上装有防反冲导流檐G59,各个防反冲导流檐G59与塔体呈30度角,本实施例中,防反冲导流檐G59紧贴立式内漏塔G50的塔体的上层法兰G67及加固圈套G69的圆边设置。外壳G49内部对应于立式内漏塔G50底部周边装有接水槽G55,用于承接立式内漏塔G50漏下的水,接水槽G55底部连接有出水口G63,用于将水排出。本实施例中,在外壳G49侧面装有门G52,门G52采用立式三开门体,即包裹内漏塔的外壳为四面体,其中三面装有可启合的门体。
本发明中的立式脱水装置主要是针对经过湿式高级氧化已灭活、除臭、除盐、初级脱水的餐厨垃圾进行脱水处理,工作时,装置开动,由电机G54配合变速系统G64为动力源,首先通过轴杆带动塔式螺带推进杆G51转动后,再将已完成湿式高级氧化并初级脱水的餐厨垃圾经由输送工具送入立式脱水装置的进料口G62,物料随螺带推进杆G51上的螺带运动方向由下而上推进,直至内漏塔顶部封板时,物料在受到压力的作用下,进而压榨脱水,并同时由出料口G60卸出,被脱出的水体由每个塔体的漏水孔G58漏出,通过防反冲导流檐G59由上而下流落到内漏塔底部的接水槽G55,通过连接于接水槽G55的出水管道进入油水处理工段,而被卸出的已脱水物料由输送设备进入物料破碎工段,在立式脱水装置运作的间断时间,利用设于由内漏塔四周由上而下的高压水对漏水孔G58进行反冲清洗。
本发明中的立式脱水装置采用立式内漏塔配合螺带推进杆结构对餐厨垃圾进行脱水处理,结构简单、脱水效果好,且出口处设有可上下调节的封口板,用于调节输出速度,控制脱水程度。
H.破碎装置:
将已脱水的餐厨垃圾由气动推进设备送入物料破碎机H63,本实施例中,破碎装置采用多轴结构设计,以低速高扭矩剪切结构实施对物料破碎,此技术为公知技术。
餐厨垃圾经上述初步处理后,再进行进一步的再利用处理。
I.生化发酵装置:
将已被破碎的物料由物料提升机I64输送到主生化处理装置内,请参看附图14和图16,本发明中的生化发酵装置主要用于对餐厨垃圾进行生化处理,生化发酵装置主要包括若干相互联合使用的厌氧发酵池I65和一个主发酵装置I71组成,分别为厌氧发酵与好氧发酵。厌氧发酵工艺中设有厌氧发酵池I65,厌氧发酵池I65呈圆筒状,顶部设有密封盖I66,密封盖I66由气动工具(即自动翻盖器I94)控制开合,本实施例中,自动翻盖器I94通过连杆连接在密封盖I66顶部,通过气缸推动连杆运动,由连杆拉动密封盖I66实现开合。厌氧发酵池I65内底部装有自动卸料系统I67,自动卸料系统I67呈管状,内部设有螺旋搅刀,厌氧发酵池I65内上方设有可自动移动的物料搅拌器I68,厌氧发酵池I65的一侧设置菌种激活池I69,菌种激活池I69侧面设有出料口I95,出料口I95与自动卸料系统4连通。本实施例中,厌氧发酵工段设有若干个相互联合使用的厌氧发酵池,其中一个为菌种激活池I69。
请结合参看附图15,主发酵装置分为两个副发酵器I71和一个以上的主发酵器联合组成,本实施例中,设有物料提升机I64,物料提升机I64用于将餐厨垃圾向上提升,投入其中一个副发酵器内。两个副发酵器I71安装于主发酵器上方,主副发酵器之间的设有物料输送管道,该输送管道是设于副发酵器I71底部的自动输送设备I74,本实施例中,自动输送设备I74为圆筒状,圆筒状外壳内设有螺旋搅刀,经过自动输送设备I74将物料送入主发酵器,同时副发酵器I71出口与主发酵器进口的连接通道中间装有气动阀门I85,本实施例中,在副发酵器I71内装有搓翻动作的搅拌设备I73,搅拌设备I73为中间一个主轴,中轴上固定安装有多个搅拌叶片,用于对物料进行翻搅。本实施例中,在副发酵器I71的壳体上部开设有排气口I91,排气口I91上连接引风机I92,用于将副发酵器I71内产生的气体排出。主发酵器主要有卧式壳体I75、支承I76、导热油输送排管I77和双层螺带搅拌器I78组成,本实施例中,双层螺带搅拌器I78有轴体、内层螺带和外侧螺带组成,内层螺带设置在外层螺带内部,内层螺带和外层螺带均呈螺旋形带状,且分别固定安装在轴体上,内层螺带和外层螺带的螺旋方向相反,双层螺带搅拌器I78的轴体周边加装铧叶片I79,本实施例中的传动系统包括电机I80、变速器I81、齿轮I82和链条I83,齿轮I82和链条I83分别设置在卧式壳体I75外侧的两端,变速器I81设置有多个,具体数量可根据实际需要设定,本实施例中,设有三个,电机I80直接驱动主变速器,主变速器通过传动轴驱动两个从变速器,每个从变速器上装有一个主动齿轮I82,双层螺带搅拌器I78的轴体两端分别安装有一个从动齿轮,两个主动齿轮I82分别通过链条I83连接在从动齿轮上,驱动双层螺带搅拌器I78转动。本实施例中,主发酵装置上方开设有进料口I84,进料口I84处装有气动阀门I85。卧式壳体I75侧面中上部位安装观察窗I86,用于观看卧式壳体I75内的反应情况,卧式壳体I75侧面中上部位还分别安装有空气输、排管I87及物料取样口I88,空气输、排管I87用于向卧式壳体I75内通入空气或将卧式壳体I75内部气体排出,物料取样口I88用于对卧式壳体I75内的物料进行取样。卧式壳体I75下部开设自动出料孔I89,自动出料孔I89处装有自动阀闸I90,用于卸料。本实施例中,在主发酵器也装有排气口(图中未画出)。本发明中的生化装置内还安装有自动温控系统。
通过上述的生化处理装置进行生化发酵的方法,包括如下步骤:
1、首先通过厌氧发酵池I65和两个副发酵器I71同时作用,生成预发酵物料:
1-1、厌氧发酵池I65发酵:将固体基料物质粉碎并加入菌种进行生化处理,本发明中,对于固体基料的选择,首先是考虑餐厨垃圾处理厂周边区域的常态农作物桔秆,本实施例中,取豆种作物桔秆(如:黄豆、绿豆、红豆和豌豆中的一种或几种)占总发酵基料重量的50%——80%,另取禾木料作物(如:小麦、玉米、小米、水稻)的当季桔秆占总发酵基料重量的20%——50%,本实施例中,两者搭配重量比为60%:40%,将上述的两种种类的桔秆搭配作为混合料,选用这种混合固体基料的理由是:豆科作物桔秆蛋白质含量高,但可溶性糖分含量低,在发酵初期微生物活力不高,而禾木料作物秸秆本身营养价值不高,但可溶性糖分含量高,将此两个科类作物桔秆混合,不仅可提高发酵质量,而且可使这两类作物桔秆的营养物质相互补充;将混合物料破碎成粒径为0.5mm——1mm的粉末,并加入能分解粗纤维的复合菌剂对上述混合物料进行生化处理,所指的复合菌剂中菌种不少于两种,其中一种为米曲霉,复合菌剂的投入量为混合固体基料的1%,并加入化学成份氧化钙、氯化钠、磷酸氢钠和尿素;
1-2、主发酵装置I70由两个主发酵器和两个副发酵器组成,主发酵装置I70由两个主发酵器和两个副发酵器组成,首先两个副发酵器分别由多种不同菌种对物料进行预发酵。首先于其中一个副发酵器8中加入已经人工灭活的餐厨垃圾为基料,加入占基料重量8%——10%的麸皮、占基料重量10%——15%的米糠和占基料重量1%的白糖作为混合料加入到已破碎的基料中调成糊状后,再加入2-3%的菌种,发酵方法采用老法发酵法(首次发酵的菌种为面包酵母,加入量为总发酵基料重量的2%——3%,再发酵基料重量的1%的红糖,与已破碎的基料混合并调成糊状后,加热至24℃——25℃,再加入面包酵母),并利用餐厨垃圾处理工作其他工段的热源所产生,并充分搅拌、强化曝气,以增强酵母生长,在停止搅拌和曝气发静置发酵时间为12小时。本实施例中,所指的老酵法 ,是在每次的发酵完成后,于卸料时,保存总料的10%作为下次发酵母料,以后的每次发酵的面包酵母加入量可减少,只需加入首次发酵所加入的菌种重量的60%。
1-3、另一个副发酵器I71为主原料预发酵器,采用已经过人工灭活、清洗并已脱水的餐厨垃圾为基料进行固态发酵。该阶段选用的菌种是由绿色木霉、热带假丝酵母菌、白地菌和扣囊拟内孢霉酵母菌组成四菌混合菌剂,四菌的重量比例为2:2:1:1,接种量(即混合菌剂的投入量)为总重量的2%,同时添加占总重量1%——1.5%的尿素,温度为25℃——30℃为佳,最高不超过42℃,由自动设备每小时翻滚一次,发酵时间9小时——10小时,通风条件为8min/h(即每小时通风8分钟),通风量为0.2m3/h。此预发酵工段的热源由餐厨垃圾处理工作其他工段的热源产生的余热提供。本实施例中,菌种中的绿色木霉配合白地菌对餐厨垃圾中的粗纤维含量的降低起着极显著的作用,而热带假丝酵母、白地菌、绿色木霉对粗蛋白质和真蛋白质的提高作用达到明显水平,拟内孢霉酵母菌作为辅助霉。
2、物料接种,即当预发酵工段完成后,将两个副发酵器的物料,通过设于发酵器底部的自动输送设备10送进主生化装置进行二次发酵。
将已进行预生化处理的物料输入主发酵器,其中主发酵器中的处理包括:秸秆发酵物料和预生化处理装置内的物料输入主生化装置中的主发酵器,物料的输入比例为:秸秆发酵物料中总物料重量百分比的10%——40%,面包酵母发酵物料占总物料重量百分比的20%,第二预生化处理的发酵物料占总物料重量百分比的40%——70%,当三种经预发酵处理后的物料进入主发酵器内后,双层螺带搅拌器14在动力源的驱动下作360度旋转,转速为6-9转/min,旋转动作为往返方向,对物料作低速缓慢搅拌,主发酵器内的温度从初始的20℃开始起温,逐步将温度提升为28℃,恒温时间为4小时后关闭空气阀23,同时提温至35℃——38℃,恒温时间3小时后,开启排气阀,利用主生化器内的正压,将水份排出,当上述的二次恒温时间完成后,再次提温至82℃,时间为2小时,当全部完成整个二次发酵工序后,开启引风装置I112排风,此时发酵物料中的水气将随排风系统进入气水分离装置和空气环保处理装置进行处理(不是本发明的部分)。整个二次发酵时间共计9小时,此工作时间将会快速完成从微生物繁殖和生长高峰期以及休眠或死亡的全过程。此发酵工艺需要的供氧量相对较小,其氧分来源于脱水物料之间的空隙和比面积之间,且能耗较小、时间较短,有效地避免了微生物利用其中的碳骨架作为能源,而同时脱氢产生的刺激性氨味影响饲类的经济价值的问题;
3、出料。
本发明中通过生化处理装置采用厌氧发酵和好氧发酵联合发酵的方法,并通过主发酵器和副发酵器两步发酵,实现自动生化发酵的效果,结构简单、合理,发酵效果好。
J、自动卸料多级干燥装置
经发酵后的物料由自动卸料多级干燥装置进行干燥,请参看附图17和附图18,本发明中的自动卸料多级干燥装置主要包括一个预干燥设备J93和一个主干燥设备,预干燥设备J93安装于主干燥设上方,预干燥设备J93是主干燥设备的附属设备,本实施例中,预干燥设备J93为卧式套筒设计,内部设有物料自动翻板J94,本实施例中,预干燥设备J93中间设有主轴,物料自动翻板J94为固定安装在主轴的翻动板,主轴可通过设置在预干燥设备J93外侧的电机驱动转动。预干燥设备J93底部安装有螺带搅龙自动出料器J95(或称为物料自动输送出料器),通过螺带搅龙自动出料器J95将经过预干燥设备J93已预干燥的物料输入主干燥设备,本实施例中,螺带搅龙自动出料器J95呈筒状,内部设有螺带搅龙,螺带搅龙通过电机带动转动。本实施例中,预干燥设备J93外壳呈两侧,两侧之间形成预干燥设备的外壳夹层内腔J97,外壳夹层内腔J97内部设置有导热油等,由管道将主干燥设备的热尾气穿过预干燥设备内腔J97的导热油层后,再穿过设备外。本实施例中,预干燥设备J93内的热源来源于主干燥设备的尾气排出口J96,并通过管道进入预干燥设备的外壳夹层内腔J97,利用载于夹层内腔的导热油传热,且通热管道的尾端通过引风设备J98把热尾气余热引入后端的空气处理设备,对带有烟、微尘、水气的空气进行收集和环保处理。本发明中的主干燥设备设有气体或液态燃料燃烧室J99和燃烧器J100,通过燃烧器J100在燃烧室J99内燃烧气体或液态燃料产生热气,热气由空气导流罩导入主干燥设备内部。请结合参看附图19和附图20,本实施例中,主干燥设备中间为可360度可逆顺方向的旋转卧式圆筒形体J102,主干燥设备前、后两端分别为固定封头J101,形成住干燥设备的主体。本实施例中,在旋转卧式圆筒形体J102的内部套装有两个以上的随旋转卧式圆筒形体J102主筒体方向旋转的副筒体,各筒体的直径和长度不同,分别是外大内小,以外筒为固定基础并分层套装,热风干燥卧式筒体,筒体内装有若干个旋转套筒,当需干燥的物料进入最内一层套筒后,物料向前推进,再落入第二层套筒,此时,物料在第二层套筒内的前进方向与最内层套筒的前进方向相反,物料在多层套筒内作出上述的连接落下与前进的动作,直至进入最外层的主转筒。本实施例中,多个内筒的截面均为圆形,并在其内部沿筒壁伸延安装有导料螺带,相邻的内筒上的导料螺带的螺旋方向相反,各个筒体外侧沿圆周方向安装气流扰动翅J103,用于对气流进行扰动,导流板的安装角度为20度——30度,对气体起到引导导流作用,当主筒体旋转时,最内层筒体随主筒体运动,运动的动能由设于主筒体外部的机械转动所带起,同时被输入的物料运动方向由导料螺带引导,并往该层筒体的出料口方向前进,本实施例中,最外层筒体外侧设有副传动轮J111,电机J108通过变速器J109驱动主传动轮J110转动,主传动轮J110带动副传动轮J111转动,副传动轮J111带动所有的筒体整体运动,各层筒体内的导料螺带设置方向不同,通过导料螺带引导物料运动。在此过程中热气流对物料进行扰动和冲刷,气流并于此出现朦胧的运动轨迹现象(混合层),这样热气流于筒体内的输送和扩散模式将是对物料干燥的关键所在。当最内层物料在导料螺带的引导下走向该筒体的出料口J104,由出料口J104落入次内层筒体的进口J105,并在导料螺带的导向下与热气流方向作逆向前进且到达该层的出料口,再落入此一层筒体的外层套筒的进料口,就如上述的方法,需干燥的物料于此与热气流作多次的顺逆向接触后,最后落入主旋转筒体,即最外层的筒体,并被导料螺带导向主出料口J106,由自动输送工具输送至下一工段,在自动卸料的多级干燥装置的另一端封头上部设有热空气排出口J107,热空气排出口J107连接在预干燥设备J93的外壳夹层内腔J97上。
本发明中的自动卸料多级干燥装置的工作方式如下:将已生化发酵完成的蛋白营养饲料(即经过生化处理过的餐厨垃圾)通过物料提升机送入预干燥设备J93,物料被安装于预干燥设备J93内的搅拌翻板系统以每秒10——18转的速度翻动,此时设备的内腔已被主干燥设备的热尾气通过预干燥设备J93的夹层将预干燥设备J93的内腔的温度提升到80℃——120℃。物料在预干燥设备J93内停留时间为1.5小时——3小时,并利用引风设备J98把预干燥设备J93内的热湿空气从排气口排出。当物料在预热设备内已满足停留时间后,由设于预干燥设备J93下部的螺带搅龙自动出料器将物料送入主干燥装置的最内层圆筒体,主干燥装置入口和出口温度分别为240℃——280℃和80℃——120℃,此时物料与热气直接接触,并通过各层滚筒内的螺带导流的作用下,实施顺向流动建立传热过程,当物料通过内层滚筒干燥后自动进入下一层滚筒,并采用逆向流式建立传热过程后再进入下一层的筒体。每层卧式圆筒体的转速为25——29转/min,饲料经过如此多次的顺逆向与热气流直接接触,源源不断地来完成物料干燥,并由自动输送工具送至物料精选装置,此时的物料已成为未经精选的蛋白质营养饲料。
本发明中的自动卸料多级干燥装置采用二级热干燥对餐厨垃圾进行干燥,且具有自动卸料功能,其结构简单,干燥效果好,并且节约能源,绿色环保。
K、精选装置
经过干燥后的蛋白营养饲料通过自动输送系统进入精选装置进行精选,请结合参看附图21,本发明中的物料精选装置是对经过干燥后的蛋白营养饲料进行最后的精筛选,在餐厨垃圾处理过程中,精筛选的前端工序是对餐厨垃圾进行生化处理,此工段是将前段工序通过筛选而未捕抓到的杂物和在生化过程中未能完全分解的大件有机物从蛋白质营养饲料中分离。本发明中,由设备底座K108为承载基础,底座K108上部安装生产保护罩K109,用于防止物料跑出,生产保护罩K109内装有倾斜的金属滚动筛网筒K110,本实施例中,金属滚动筛网筒K110上的筛网筒孔径Φ为4mm——6mm,孔与孔这间间隔为2mm,本实施例中,金属滚动筛网筒K110的倾斜角度为1度——20度,并可对倾斜角度进行调整,内部设有调整螺栓,对其倾角进行调整,金属滚动筛网筒K110向下的一端的内腔沿筒壁设有螺带K111,作为引导轨道,通过螺带K111引导重杂杂物及大件杂物进入杂物卸出口后,再落入杂物承接器K112。本实施例中,在金属滚动筛网筒K110下方的底座K108上安装有成品承载器K113,金属滚动筛网筒K110下方设有漏斗形承接装置,经金属滚动筛网筒K110漏下的物料经漏斗形承接装置落入成品承载器K113上。本实施例中,成品承载器K113呈输送带状,成品承载器K113下部安装有自动输送工具K114,其用于将成品输送入库或直接进入下一工段的饲类配制车间。本实施例中,在杂物承接器K112下部安装二次精选器,对落入杂物承接器K112内的杂物进行二次精选,本实施例中,二次精选器由链板输送机K115带动物料向前推进,在链板输送机K115的前方向于接近尾端外安装大小物件分流闸板K116,此大小物件分流闸板K116设于链板输送机K115上方不小于5mm位置处,可视所需通过的物料大小调整物件分流闸板K116与链板输送机K115间的隔距,能够通过物件分流闸板K116与链板输送机K115间的隙距的物料输入成品输送系统后,再进入成品承载器。当大件物料被挡于分流闸板K116前端时,由安装于分流闸板K116上方的气动拨料器K117的拨板以向下180度的动作将滞留于分流闸板K116前的大件物料拨进杂件收集箱。
本发明中的物料精选装置在使用时的工作流程如下:将干燥后的蛋白营养饲料(即餐厨垃圾产物)本发明,输入速度约为30kg/min——80kg/min,物料由金属滚动筛网筒K110的转动并随金属滚动筛网筒K110的倾斜方向前进,物料在金属滚动筛网筒K110内随金属滚动筛网筒K110运动转迹不间断翻动,大件物件或重质物件被滚起朝倾斜方向不断前进并进入螺带K111引导轨道,被送入重杂物及大件物料承接口,而成品即从金属滚动筛网筒K110的壁孔中堕下,进入成品承载器K113。当通过螺带K111引导轨道送入杂物承接器K112的物料中还存在着若干的成品未得到彻底分离,为了更有效的收集成品,将大件杂物承接器的物料送入链板输送带,输送至物件分流闸板K116分离口,能通过物件分流闸板K116隙距的物质为成品。送入成品输送系统后,再送入成品承载器,而大件物料或重质杂物被气动拨料器分离后,拨进入杂物收集箱。
本发明中的通过筛网筒和分流闸板的配合,对餐厨垃圾生产的饲料产品进行筛选,筛选效率快,精度高。而且可实现自动进料、自动卸料入库等全自动处理。
L、混合饲料装置
生产的饲料还可以通过混合饲料装置进行混合,请参看附图22,本发明中采用的混合饲料装置由粉碎机,圆筒脉冲除尘器L117,螺旋混合器L117L,环模制粒机L118,逆流冷却器L118L及回旋分级筛选L119和自动称量包装器L120等六大部份组成。
M、废塑料逆转工程装置:
餐厨垃圾中存在不可避免的废弃塑料,如:塑料瓶、塑料饭盒、塑料袋、塑料瓶盖等废弃塑料,其总重量约占餐厨垃圾经初级去水后重量的1.2%,这些废弃塑料部分是已多次的再生品,已无再生的经济价值,同时垃圾废弃塑料隐藏着各种有害细菌,在餐厨垃圾处理工程中,必须着实处理,避免污染物的转移造成严重的二次污染。请结合参看附图23、附图24、附图25和附图26,本实施例中,废塑料逆转工程装置是连接于附图8中滚动耙齿E30的下一工段的装置,当于液态气浮分选装置所分选出的废塑料、废纸、废布条等杂物由滚动耙齿E30捞出,并经输送系统进入废塑料逆转工程装置的离心脱水设备,对物料进行基本的脱水后,进入主体处理装置,主体处理装置由输送带M122为起点,将物料送入能通过路轨作前后移动的气压式自动进料机M123,将原料送入裂解催化卧式反应釜M124(反应釜的结构可参看公开号为CN102220152A和公开号为201660599U的中国专利)内,该反应釜M124可作360度顺逆旋转,并带有自动随机刮壁装置M125,物料在反应釜M124内加入氧化砷和氧化铝作为联合催化剂,及氧化钙为固氯剂的作用下,实施绝氧裂解反应,所使用的热源可采用此工段逆转工程的液态产品与餐厨垃圾处理工程所得的生物油产品之合成燃料,以及逆转工程所得的可燃气体,所用的生产燃料自供自给,而裂解炉M126在燃烧过程中所产生的尾气,由炉体的出气口输出,且由管道连接尾气环保装备系统M127。反应釜M124内的物料在绝氧条件下进行裂解,得到油气混合物,在反应釜M124内达到设定压力范围内的条件下,后级真空系统M130自动打开,随之反应釜M124的单向阀M128自动开启,油、气首先进入油腊分离器M129,当油腊被分离后,油、气在下一级的真空设备作用下沿管道进入第一级重油分离器M131,而轻质油气通过安全水封设备进入第一级冷凝器M132,混合油进入油料承载容器M133,不能被液化的气体再转入负压设备M134内进行顺、逆向气体漂洗,经过漂洗的气体继续进入后级立式水封式气体安全输送器M135,并将可燃气体由专用二级燃气压缩机M136压缩脱水后,输送到第一级燃气压缩机将燃气压缩到0.5mpa,第二级燃气压缩机再将燃气压缩到1mpa,并将可燃气体输送燃气贮存库M137待用。混合油进入油料承载容器M133降温后,通过专用输油泵将混合油输入柴油精炼装备,该装备由第一级化学脱碳除杂合成器M138为起点,再进入除碳精漂器M139和脱腊除胶器M140进行化学处理,除碳精漂器M139和脱腊除胶器M140中所需化学剂设于若干个化工容器中,并分液态剂添加区M141和固态剂添加区M142,所有添加剂均由自动定量设备按照设定的工序作自动加料。经过精处理后的油料通过检测后,进入柴油合成设备M143调整质量(根据每次炼油的质量不同,调整到同样质量后出厂)后,进入固定床过滤设备作顺、逆向双层过滤,随之得到合格的国III标准柴油并转移入库。废塑料裂解过程中,会产生不可气化的余渣,即粗炭黑,可利用粗炭黑处理装置对绝氧裂解后的残余物粗炭黑处理。
N、粗炭黑处理装置:
请参看附图27,本实施例中,粗炭黑处理装置包括粗炭黑人工陈化处理器N144,该处理器是一种利用臭氧对物料进行陈化的设备,当通过化学陈化后的粗炭黑再进入物理陈化床N145,该陈化床将粗炭黑在压强2.8mpa——3.2mpa的条件下进行蒸汽处理25——35min,上述两种人工陈化手段是起到实施改变粗炭黑的粒子比容,强制改变碳黑粒子外部结晶比较有序的特征,有助于助剂嵌入及提高碳黑的碳氢比。当粗炭黑经过人工陈化后,由专用自动输送工具输入物料配伍设备N146,物料的配伍物分为液态和固态两大类,分别有基础原煤、多价金属催化剂、六次甲基四胺点燃剂、二茂铁消烟剂、黏结剂和固氯剂等,其中基础原煤占总物料重量的32%——45%,其他助剂合共占总物料重量的6%——15%,总物料重量的剩余份额为经过处理的粗碳黑,每种配伍助剂均由液、固自动定量加料加料设备N147添加,通过多层推拉式螺杆N148将物料充分混合输入低硫高能环保清洁燃煤成形机N149,待物料成形后得到成品,该成品称为一种低硫高能清洁燃煤,品质为全硫0.2——0.5%,焦渣物征为1级,灰分5.5——7%,挥发分8——11%,发热量4300——5300大卡,本实施例中采用的粗炭黑的应用可参看公开号为:CN102220179A的中国专利。
O、免蒸馏法生物柴油生产装置:
本发明中,在收集装置、餐厨垃圾破袋装置、餐厨垃圾液态气浮分选装置、湿式高级氧化、除臭、灭活、清洗降盐装置、初级固体分离器和立式脱水装置处都设有出水管道,各处出水管道六出的油、水、固混合体送入免蒸馏法生物柴油生产装置,进行柴油生产,请参看附图28至附图31,本发明中的生物柴油制造系统前端设有油水混合池O150,餐厨垃圾处理过程中各个工段产生的油、水、固体混合物通过出水管道输送至油水混合池O150内,油水混合池O150设置在出水管道尾端。油水混合池O150后端设有一个卧式螺带固液分离设备O151,用于将油、水、固体混合物的固体脱出,本实施例中,卧式螺带固液分离设备O151包括有一个卧式圆筒形外壳,外壳内设有滤网,滤网内部固定设有输送螺带,电机配合变速器带动滤网及螺带转动,卧式螺带固液分离设备O151底部设有油、水混合体输送管道。油、水、固混合体由泵具通过管道输入卧式螺带固液分离设备O151内,经卧式螺带固液分离设备O151进行液固分离后,油、水混合体通过输送管道输入下一处理装置,固体排出。卧式螺带固液分离设备O151后端设有油水分离塔O152,经过脱固体后的油、水混合体被输送到油水分离塔O152,本实施例中,油水分离塔O152呈立式圆筒形,其进料口设置在侧面中下部,油水分离塔O152内部设有加热管道O153,加热管道O153从油水分离塔O152下部伸入至油水分离塔O152内部,再从油水分离塔O152中上部输出至油水分离塔O152外侧,本实施例中,加热管道O153所采用的热源为导热油炉的余热,可节约能源的使用,具体实施时,也可以单独设置有热源。油水分离塔O152的顶部装有红外线水体液面定位仪O154,用于油水分离时的油水混合体高度的定位,并以此来自动控制油水混合液的进入量。油水分离塔O152接近上部的一侧装有刮油器O155(类似雨刷,将油刮走)和出油管道O156,本实施例中,刮油器O155呈条形板状,由设置在油水分离塔O152顶部的电机带动转动,将油水混合体中的油刮入油槽中,并通过出油管道O156输出。本实施例中,在出油管道O156上设有电动阀O157,通过电动阀O157控制生物油料从出油管道O156进入储油容器O149。
请结合参看附图28,本发明中,利用餐厨垃圾中脱出的油脂进行生物柴油的生产,生物柴油生产装置前端为油脂胶质脱除设备O158,本实施例中,油脂胶质脱除设备O158为长方形,油脂胶质脱除设备O158中间固定设置有孔洞撞击板O159,撞击板O159上开有孔洞,撞击板O159的两面对开位置分别安装有旋浆式水力推进机O160,本实施例中,旋浆式水力推进机O160包括有设置在油脂胶质脱除设备O158内部的螺旋桨扇叶和设置在油脂胶质脱除设备O158外侧的电机,电机带动螺旋桨扇叶转动。当需要生产生物柴油时,由专用油泵将生物油料从储油容器O149中输入至油脂胶质脱除设备O158内,进行有效地脱除油脂中的磷酯、糖、蛋白质及其它杂质,防止胶质在后一工段中遮盖油脂细小粒子,而障碍油脂与催化剂的接触。本实施例中,臭氧氧化处理器是由臭氧发生器O174,防液体反冲阀O175,强力气、液混合器O176,反应器O177,循环泵O178,进油管道O179,出油口O180,液面控制器O181和臭氧余气毁器O182组成,臭氧发生器O174通过防液体反冲阀O175与强力气、液混合器O176连接,强力气、液混合器O176通过进油管道O179与油脂胶质脱除设备O158连接,强力气、液混合器O176通过管道与反应器O177连接,反应器O177上连接有循环泵O178,反应器O177底部为出油口O180,出油口O180通过管道与生物油常温脂交换设备O161连接,反应器O177内安装有液面控制器O181,反应器O177顶部安装有臭氧余气毁器O182。反应器O177顶部还安装有定理加料器O183。通过臭氧氧化处理器可以对油脂进行除去脂中杂质、色素、臭味、蛋白质等。生物柴油生产装置主体为生物油常温脂交换设备O161,本实施例中,生物油常温脂交换设备O161为一圆筒形锥底反应釜,生物油常温脂交换设备O161内部装有一支以上的超声波发生器O162,本实施例中,设有四个,每个超声波发生器O162外围分别装有套管O163,套管O163四周开有内螺纹射流孔O164,套管O163上方固定设有卡定器O165,卡定器O165上方连接有气动起降器O184,作用于控制套管O163与超声波换能器O162在生物油常温脂交换设备内的入液深度,通过卡定器O165将超声波发生器O162安装在生物油常温脂交换设备O161内部。生物油常温脂交换设备O161内装有液体导流管O166,液体导流管O166一端连接在生物油常温脂交换设备O161上部,另一端连接在生物油常温脂交换设备O161底部,泵具O167连接在液体导流管O166上。生物油常温脂交换设备O161顶部装有顶盖O168,顶盖O168上设有投料口O169,生物油常温脂交换设备O161侧面装有视窗O170。本实施例中,在生物油常温脂交换设备O161底部设有鼓气管O171,鼓气管O171的一端连接压缩空气机。当生物油脂输入生物油常温脂交换设备O161后,再从投料口O169加入甲醇和共溶剂,本实施例中,共溶剂宜选择可增强油脂与甲醇的互溶性的液态剂,并加入可再生利用的固体催化剂后,超声波发生器O162通过气动或液压工具由生物油常温脂交换设备O161顶盖处从上而下进入生物油中,同时,压缩空气从生物油常温脂交换设备O161底部开始鼓气,从而促进生物油与甲醇加速共溶,并通过油泵O167将生物油脂混合体输入到套管O163的内腔上方,由上而下流动进入超声处理,超声波频率由25KHz逐步增强到30KHz,时间为20——60min。生物油常温脂交换设备O161后端连接有分液设备O172,本实施例中,分液设备O172呈立式筒状,分液设备O172后端设有过滤设备O173,经超声波处理完毕后的混合液体输入分液设备O172,所取得的粗生物柴油通过过滤设备O173而取得生物柴油。
本发明中,生物柴油的制造方法,即上述生物柴油制造系统的运作方法包括下述步骤:
(1)、将餐厨垃圾生产过程中所产生的油、水、固混合物进行脱固处理,得到油水混合液;
(2)、将油水混合液输送至油水分离塔O152,进行油水分离,本实施例中,油水分离时,利用导热油炉余热将油水分离塔O152内的油水混合液加热至60℃——85℃,待生物油脂上浮后实现油水分层,下层的水体由输送管道送至污水处理系统,上层的生物油脂由刮油器O155刮出,并通过出油管道O156送入储油容器内;
(3)、当需要对生物油脂时行加工处理时,通过输送泵等工具将生物油脂送进油脂胶质脱除设备O158内后,启动旋浆水力推进机O160,并加如浓度为85%磷酸,磷酸与生物油脂的比例为不超过油脂总量的1%,利用油脂胶质脱除设备O158两端的旋浆推力使油脂胶质脱除设备O158内部的液体产生相向撞击,撞击时间建立在设定的工艺条件的所需时间范围内,本实施例中,对撞时间为10min——15min,在液体的相向撞击时间结束后,当即加入稀盐水,水、盐的重量比为95:5至90:10之间,生物油脂与稀盐水的重量比例为90:10至80:20之间,利用电解质盐的作用,使絮凝加快,形成的胶团更加稳定;
(4)、继续启动旋浆水力推进机O160,时间为10min——20min;
(5)、当上述脱胶工序完成,油脂混合体于设备中停留60min——120min;
(6)、将带有胶团的水体排出另行处理,而已脱胶质的生物油脂被输进生物油常温脂交换设备O161;
(7)、当生物油常温脂交换设备O161内的油脂输入的液面达到生产工艺设定的液面高度时(通常为超过超声波转换器),停止输入,开始启动生物油常温脂交换设备O161底部的鼓气管O171,使液面迅速强力翻滚浮动,此时,打开投料口O169,加入固体催化剂和甲醇,催化剂用量为生物油脂质量的1.5%——3.5%,甲醇用量为生物油脂质量的3%——8%,在加入甲醇后再加入共溶剂,加强生物油脂和甲醇的促溶性能,形成均相体系,共溶剂的选择为甲乙醇的任意比例的混合物,共溶剂的加入量是生物油脂质量的0.5%——2%,本实施例中,共溶剂还包括有加入量是生物油脂质量的0.5%的丁醇;
(8)、其后利用搅拌器连续搅拌10min——15min,再加入固体金属碱催化剂(本实施例中采用的为华南再生资源(中山)有限公司生产的型号为华南713#的催化剂),加入量为生物油脂质量的3%——4.5%,该固体催化剂的特征是以试剂活性碳及铝、钠、铁、镁和锂的环状结构硅酸盐矿物的纳米颗粒为基核,首先测得基核自身能释放出12000个/cm3以上负离子为合格品,然后将基核浸渍在碱性硅溶胶与铝溶胶及氢化锂的混合液体中,取出后于650-720℃的温度条件下,恒温一小时,降温后经过筛选细化,制成一种外裹硅、铝、锂网状骨架介质,且带极性的杂化荷电载体,再将此载体浸渍于KNO3的溶液中,取出后于110℃烘干设备中干燥制得载有15%——25%的KNO3的碱性催化剂。
(9)、当加入所需要的助剂后,关闭投料孔O169,开启物料循环输送泵,并开启超声波发生器O162,超声波发生器O162的初始频率为25KHZ,时间为1min,随后逐步增大到30KHZ,时间为30min——40min,反应温度为25——35℃。
(10)、当油脂于生物油常温脂交换设备O161中完成脂交换后,将生物油脂混合物输入分液设备O172静置分层,上层为甲醇和甘油混合液体,下层为粗制生物柴油;
(11)、首先将分液设备设于下部排液口开启,让粗制生物柴油输送进入过滤设备O173,过滤后得到精制生物柴油并回收固体催化剂,待再生后可循环再用。而生物柴油被输入进储存容器内待进一步精制,而甲醇和甘油混合液另作他用。
本发明中的生物柴油制造系统可自动将餐厨垃圾中所包含的固体、水分等进行分离,然后进一步将所含油脂转换成生物柴油使用,设备结构简单,处理过程,节约能源、生产成本低。
P、制造乳化生物柴油装置:
本实施例中,免蒸馏法生物柴油生产装置生产的为粗生物柴油,粗生物柴油经乳化生物柴油装置进行进一步乳化生成乳化生物柴油,请参看附图32,本发明中的乳化生物柴油的制作装置主要为壳体P174,本实施例中,壳体P174上部呈直筒形,下部为半圆体,壳体P174内部装有垂直搅拌器P175,动力源带动垂直搅拌器P175转动,本实施例中,动力源包括电机P176和变速设备P177,变速设备P177固定安装在壳体P174顶部,电机P176设置在变速设备P177上方,电机P176通过变速设备P177驱动垂直搅拌器P175转动。本实施例中,在壳体P174底部的半圆体内设有转轴的支承架P180,用于支撑垂直搅拌器P175的转轴。本实施例中,垂直搅拌器P175的中轴适当位置装有若干浆式平直搅拌器P178,也可采用桨式折叶桨替代,同时垂直搅拌器P175的中轴下部安装有涡轮或圆盘弯叶浆P179,壳体P174的圆筒形内壁四周安装若干液体导流叶板P183(设置在壳体P174内部,起到扰流作用),壳体P174的顶部设置有多个进料口P181,每个进料口P181均通过管道连接有定量加料设备P182,本实施例中,各个定量加料设备P182用于各种添加剂的自动投料。壳体P174的顶部还设有富氧水进水管道P186并穿入壳体P174内连接富氧水雾化喷嘴P185,进水管P186连接高压泵P187,臭氧发生器P188输出O3气体进入强力水气混合器P189与水混合后,通过管道P190的输送进入富氧水储备箱P191,富氧水储备箱P191的出水口与高压泵P187连接。壳体P174上部一侧设有进油口P192,其一端由管道穿于壳体内部,另一端连接油泵,同时壳体P174下部还设置成品出料口P184,所得乳化生物柴油由出料口P184输出,再通过管道与泵具输送至油料储存库,本发明中产生的富氧微乳化生物柴油作用于各种热源燃料。
本发明中的乳化生物柴油的制作方法,即本发明中上述装置的运作方法如下:本发明主要是针对由油脂中通过生产工艺制得的生物柴油进行进一步加工,对生物柴油予以富氧微乳化柴油工艺精制。
本发明中的乳化生物柴油的制作方法包括下述步骤:
(1)、首先对生物柴油进行含水量测定后,将粗生物柴油输入上述的乳化生物柴油装置内,启动搅拌系统,加入30-80%的国III标准柴油后,搅拌5min;
(2)加入亲水剂,亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂,本实施例中,两类表面活性剂有三乙醇胺、六氢苯胺或西曲溴铵和氨水,配比例为阳离子表面活性剂50%,非离子表面活性剂50%,亲水剂是为了降解面膜的刚性,增加流动性,减少微乳液形成所需要的弯曲能,易于形成乳发液,在加入亲水剂后,稍作1min——15min时间的搅拌;
(3)、加入丁醇作为中间体,本实施例中,丁醇可作为助表面活性剂,且继续对混合液作不间接搅拌15min,搅拌时,垂直搅拌器2作100转/min——130转/min的转速搅拌;
(4)、加入异戊烷作为自燃温度调节剂,本实施案例中,异戊烷与上述(1)-(3)的液体混合后,再搅拌5min
(5)、分别加入富氧水和十八碳—顺—9—烯酸,富氧水的分量视产品需要,从产品总重量的1%——20%不等,本实施例中,利用臭氧发生器供给O3,臭氧输送的气体流量为250ml/min,并于强力水、气混合器中与水体混合后输入富氧水储备箱自然分解成水中富氧,自然分解时间为30min,使水中溶解氧含量达到27-35%,形成富氧水,通常富氧水的加入量为总重量的10%——20%,当富氧水加入后,再搅拌15min,转速调整为170转/min——200转/min,再加入配方中设定量的酸值为200以上的十八碳—顺—9—烯酸作为乳化剂,本实施例中,十八碳—顺—9—烯酸的加入量为所加入富氧水水重量的70%——90%,在搅拌设备的连续搅拌下直至澄清透明为止,此时,搅拌器的转速调整为280——340转/min,一般需要连续搅拌40——60min,待静置一定时间观察乳化油为清洁透明无分层后为成品。此时已完成整个富氧微乳化生物柴油精制工序,所出产品可以在85℃温度条件下和240天的储存期内不变质的优点,含富氧水20%及含30%以上的国标III石化柴油所制得的微乳化柴油可用于做热源燃料,含富氧水10%以下及含80%以上国标III石化柴油所制得的微乳化柴油可用作清洁车用柴油。
通过本发明可将餐厨垃圾中提炼的生物柴油进一步精制,制成富氧微乳化生物柴油,能扩大其应用范围。
Q、快速污水处理回用装置:
本发明中还设有快速污水处理回用装置,对本发明中的所有生产过程中产生的废水进行集中快速处理成合格的工业回用水,作为餐厨垃圾资源化处理的生产用水。请结合参看附图33、附图34、附图35和附图36,本实施例中,快速污水处理回用装置首先让污水进入污水过滤池Q185,利用设置污水过滤池Q185内的杂物拦栅Q186对污水中的杂物隔离,此杂物拦栅Q186内还设有防塞反冲器Q187,通过栏栅Q186后的的污水由水泵输入灼热毡污水处理设备Q188,此设备具有内腔Q189和机壳Q190,污水经过压力泵进入机壳顶部,输水管上还开有放空管口Q191,机壳顶部设有多个与进水管相通的雾化喷射头Q192,在雾化喷射头Q192下方设有一个上下错位的灼热毡Q193(即两层结构,上面一层,下面一层,两层错位设置),灼热毡Q193表面有多道流水浅沟Q194(流水浅沟Q194为纵横交错设置,以减缓水流下的速度,防止生成水垢),灼热毡Q193的发热源为导热油管道Q195传热,毡面温度控制在90——200℃之间,灼热毡Q193下方的底部设有微固物沉淀区Q196及位于微固物沉淀区Q196底部的排污口Q197,排污口Q197上方设有防污反冲挡板Q198,灼热毡Q193下方装有用于支撑灼热毡Q193的耐高温垫层Q199,未能雾化的水体于灼热毡Q193与耐高温垫层Q199之间为水道流入设备内腔的底部,机壳Q190的顶部开有自动吸排气阀Q200,机壳Q190位于灼热毡Q193的上方开有热蒸汽收集口Q201,热蒸汽收集口Q201通过管道与热交换器Q202相连,将热水蒸汽转为水体流向集水池Q203并与由机壳下部侧的排出水体汇合,将集水池Q203的水体从池中泵入高级氧化系统Q204,此系统为一种臭氧——水反应器,为套筒式结构,具有内外两层空腔,内腔为气水反应腔Q205,外腔为气水循环反应缓冲腔Q206,内腔具有内壳体,外腔具有外壳体,内壳体的顶部安装有自动排气阀Q207和用于监控液面高度的液面控制在线监控器Q208,臭氧——水反应器内腔的进水口引入管的端位装有活性碳反应球Q209,此反应球Q209用于加速臭氧于水中转化为羟基自由基,达到提升臭氧对水中有机物更快的降解速度,该反应球Q209上部不透水,下部为网状出水口Q210,球内装有颗粒活性碳,所装的颗粒活性碳体积占反应球内腔体积的15%——95%。内腔的气水混合液通过反应器的内外腔连接管道Q213输到外腔,再由设于高级氧化反应器外的水泵Q211输进气水混合器补充臭氧后,重新进入内腔,让气水混合液在2——5min时间内作如此循环运动。当气水混合液的反应达到设定时间后,由设于内腔底部侧的排水口Q212排出,而残余的污泥通过反应器底部的排污口Q212排出,此排污口是与外壳的排污口Q212相连,在内腔的排污口上还安装防反冲档板Q214,在高级氧化反应器内循环管道的其中一个位置上装有上述所指的气水混合器Q215,此混合器为三通接法,两端接通循环水,而中间的一个端口连接防水单向阀Q216,防水单向阀Q216的另一接口连通臭氧发生器的输气管道,而通向气、水、物强力混合器Q217,经过高级气化处理的水体进入中转水池Q218,再由水泵将水体输进活性炭过滤固定床Q219处理后,进入复合过滤设备Q220,该设备的过滤方式是通过加压实行由下而上的逆向过滤,经初步过滤后的水体再通过水泵和管道输送进入复合过滤设备Q220,该设备Q220由多组过滤罐Q221组成,过滤罐内分别设有多支立式过滤柱Q222,每支过滤柱Q222长度的一半位置处开有出水孔,过滤柱Q222的底部装有80——140目的滤网,工作压力为0.5——1mpa,过滤罐Q221的顶部有进水口Q223和加压管Q224,罐体内分为二层,在罐与罐之间位置安装密封分隔板Q225,每层的罐内分别装有过滤柱托板Q226,该托板Q226上开有与过滤柱Q222直径相配的孔口,其孔数也与所需安装的过滤柱Q222支数相同,Q226托板的孔口边缘与过滤柱Q222的接触位加装防漏密封垫Q227,上层罐体的上部一侧安装进水导流管道Q228,进水导流管道Q228通向下层罐体的上部,上层罐体的下部一侧安装出水导流管道Q229,出水导流管道Q229通向下层罐体的下部,且罐体的上、下层一侧分别安装有排气口Q230。每支过滤柱Q222内装有两种固体吸附剂,下层为活性碳Q231,上层为杂化荷电吸附剂Q232,两种吸附剂的接合方式为随机接合,水体过滤后的出水口设于复合过滤设备底部封头的一侧Q233,底部封头的中心位置设有沉淀物排出口Q234,通过复合过滤设备处理后的水体已达到清彻无混浊、无异味、无重金属离子存在的程度,同时基本已经将臭氧气体及所产生的强氧化剂除去,由复合过滤设备处理后的清水直接进入紫外线杀菌器Q235对水体进行最后一步的处理,而所获得的合格水体作用于生产用水。本实施例中,污水快速处理回用装置的运作方法如下:在餐厨垃圾资源化处理全过程中的所有污水通过排放管道集中进入污水集水池,污水中的所含带的杂物被粗拦栅隔离,而水体进入灼热毡污水处理设备,当污水被喷下接触灼热毡体时,水体在浅沟内瞬间接触高温板的灼热,微生物基本死亡,并产生热水蒸汽向上雾升,上升的热雾水汽被热蒸汽收集口导入热交换器后回复液态水,部份没有形成热水蒸汽的带微颗粒物和微生物尸体的水,经过灼热毡表面的流水浅沟进入该装置底部的微固物沉淀区并从位于微固物沉淀区底部的排污口排出,而清液由微固物沉淀区上部的排水口排出,与被热交换器液化的水体汇合后,通过管道输入高级氧化反应设备,首先水液进入强力气水混合器与由臭氧发生器提供的臭氧气体强力混合后,进入臭氧——水反应器内的活性炭反应球,再经过反应球的下水网进入反应器的气水混合水体循环系统,并由水泵不断把水体循环于内腔与外腔作用于高级氧化反应,反应时间为2——5min,水中臭氧浓度为1——5g/T,在整段的往复循环反应中,使水中臭氧于活性炭的作用下,在水中引发链式反应,加速臭氧转化为羟基自由基,类似于O3/H2O2或O3/UV的高级氧化过程,在反应器下部沉淀层的残余物由排污口定期排出。在反应过程中,有部分臭氧气体会溢出,并进入反应器设于顶部的排气通管,再而进入臭氧毁灭器及气体过滤器,对排出的含臭氧气体进行灭活和过滤,防止臭氧和二氧化碳对大气的污染。经过高级氧化过程的水体首先进入活性炭固定床进行逆向过滤后,再通过加压控制阀输出至复合过滤设备,水体首先通过杂化荷电吸咐剂的过滤层,该吸附剂每个固体以非极性吸附剂为基核,外层包裹以硅铝微孔骨架具极性的组合吸咐剂,当水体在经过杂化荷电吸附层时,吸附剂对各种藏于水中的无机和有机物及其水体中的重金属离子产生较大和较快的吸附,当通过杂化荷电吸附剂处理的水体自然透过活性碳吸附层,进行精处理后,再进入紫外线杀菌器,对水体进行最后一步的处理,杀菌器中采用紫外线辐射,强度为2600——3000UW/cm2,波长为235——258nm,对水体的照射时间为1——4s,当水体完成全部过程的处理后进入储水池容器,作为餐厨垃圾资源化处理的生产用水。
R、杂化荷电吸附剂生产装置:
本发明中,对餐厨垃圾中所附着的污泥通过杂化荷电吸附剂生产装置进行处理,本实施例中,杂化荷电吸附剂生产装置可以处理餐厨垃圾的必然附着物中产污泥和厂区内生活污泥的资源化利用,且是一种对环保处理残余物非转移处理的最佳选择,也是一种以污治污方法的实施与应用。此杂化荷电吸附剂的生产方法,主要是针对存活于污泥中的微生物择向利用工序繁琐,技术性要求高及其在一段自然干燥的条件下,微生物细胞只是新陈代谢处理于停滞状态,并非死亡,而在一旦给潮气后又可复活的关键问题,而作出利用污泥中存活的微生物个体或死体微生物个体作为孔洞模块,制造固体吸附剂。请结合参看附图37、附图38和附图39,本实施例中,杂化荷电吸附剂生产装置首先由人工灭活器R236对污泥进行人工强制灭活后,将已强制灭活处理的污泥通过自动输送设备,将污泥送入固化设备R237进行固化或半固化工序,待污泥于固化设备内与添加剂反应完毕后,由自动输送设备将已固化或半固化的污泥颗粒输进污泥推进器R238,将污泥推入绝氧热解反应釜R239,此污泥推进器是安装于导轨上,当进料时其出口连接反应釜进料口,若进料完毕时,推进器能自行后退,此时出料口与反应釜进料口脱离,反应釜进料口密封关闭。反应釜的外壳为炉体,反应釜采用卧式安装,与进料口同轴向的另一端开有气化物出口,其气化物出口由单向自动阀控制,反应釜在设定压力时,阀门自动打开,汽化物进入水封式可燃气体收集处理装置R240,当可燃气通过水封界面上升进入热交换器,所产生的不可液化气体为可燃气,并回输管道返回热解炉用作热源燃料再利用,裂解炉所排出的热烟气与餐厨垃圾资源化处理其他设备所产生的热烟气共同由燃料裂解炉尾气处理系统R241处理。已完成绝氧热化的污泥缝隙水份已迫出成为水蒸汽,并随可燃气体排出。待在设定的热解时间完成后,于反应釜内的污泥中含有的微生物死体残物被焦化,污泥成孔率巩固,此时开启反应釜的出料口,并利用反应釜内的自动排料螺带将污泥卸出,转入管道式螺带输送机送入陈化库房R242,实行自然陈化12——48小时,再将经过自然陈化的微孔污泥颗粒投放在酸化设备R243中,酸化时间为12——18小时,以此作用于对已焦化的微生物死体实施脱除,同时作用于除去金属杂质离子,并致使暴露出颗粒的孔穴结构骨架,使氢离子替代添加固化剂中的钙离子,通过酸化工序后的污泥颗粒被送入热水漂洗池R244漂洗,并调整PH值至6.5——8后,由输送设备将已漂洗的颗粒物料进入热蒸汽床R245进行初步的物理活化,活化时间为1.5——2.5小时。将经过物理活化的微孔颗粒放入高温绝氧活化炉R246进行高温活化1——4小时,控制加温速率为15——30℃/min,活化炉的尾气排往尾气环保处理系统中处理。在高温活化工序完成并将微孔颗取出并自然降温后,经筛选过后的成品为非极性微孔吸附剂,成为杂化荷电吸附剂的基核。此时采用酸性铝、硅溶液混合液体与非极性微孔吸附剂充分混合后,再进入高温炉处理,温度为650℃——700℃,恒温1小时,取出物料后经过粉碎加工,制成纳米级微孔和孔道的内核为非极性吸附剂而外层加载带极性的硅、铝网状骨架介质的超微孔洞吸附剂的合成体——杂化荷电吸附剂,可用于餐厨垃圾资源化处理中,对所产污水的治理物。本实施例中,杂化荷电吸附剂生产装置及其制造方法如下:将在餐厨垃圾资源处理整个过程中所产生的污水和厂区中的生活污水于处理回用中所产生的残余污泥进行集中处理,在集中处理的污泥内自然存活的多种微生物和微生物死体,此微生物的个体数量数以亿计。为了很好地利用微生物个体及其复杂的菌体结构作为成孔剂,首先将污泥输入人工强制灭活设备,于设备内的立式循环输送卡带让污泥自上而下与臭氧实施逆向循环接触,反应时间为5-20min,臭氧投放量为12g/kg。当人工强制灭活工序完成后,污泥由自动输送系统进入初级固化设备中,此设备是由卧式多层螺带组成,螺带与螺带的转向为一逆一顺,对污泥实行掀、撕、翻滚的动作进行强力剪切,并由定量加料器加入添加剂混合20-25min,此时污泥温度已自然升温约为60℃左右,污泥成大小颗粒状体,由卸料口放出,并由输送器不断送入污泥推进器,且由推进器不断地将污泥送入热解反应釜,当所送入的污泥达到设定的数量时,停止送料,污泥推进器通过导轨自动后退离开反应釜的进料口。此时反应釜进料口的封盖被密封关闭,釜内呈绝氧运行状态,釜内提温速度在30℃/min,终温为220℃,保持恒温1小时,污泥于釜内热解期间,将会产生水汽和可燃气体,当釜内达到设定的压力时,反应釜后端的单向阀门自动打开,水汽和可燃气混合气化物被压进水封式安全设备,并让含水气体进入热交换器,此时产生的不可液化的气体为可燃气,并通过管道回输热解炉,作为热源的补充原料应用。釜内的污泥降温后,由釜内设置的自动排料螺带,从釜侧面的排料口排出,由输送设备送入陈化库,自然陈化12-48小时,再将已自然陈化的污泥投放于酸化设备中,采用浓度为20%硫酸液对污泥静态浸泡12小时,作用于对把焦化的微生物死体残物实施脱除,并除去金属杂质离子,使氢离子替代添加剂中的钙离子。污泥此时已暴露颗粒的孔穴结构骨架,经酸化处理后的污泥颗粒投入80℃的热水漂洗器漂洗并调整PH值,再进入热蒸汽床进行物理活化,热蒸汽流量为250mL/min,活化时间为1.5小时,将已物理活化的污泥颗粒输入高温电阻炉中,控制加热速率为20℃/min,隔绝空气的活化温度为650℃-700℃,恒温活化时间为1小时-1.5小时。当物料从高温活化炉取出时,即非极性吸附剂已制成,作为杂化荷电吸附剂的基核。进一步将已制成的非极性吸附剂再加工为一定大小的颗粒后,与酸性铝溶液和硅溶液混合均匀,混合时,非极性吸附剂、酸性铝溶液和硅溶液混合的重量比例为20:20:10,再将混合物料放入高温炉中处理,处理温度为680℃-720℃,恒温1小时,待降温后杂化荷电吸附剂制成。
S、尾气环保处理装置:
本发明中,还通过尾气环保处理装置对餐厨垃圾资源化处理的各个工序中所产生的烟气、热烟气、粉尘、抽排口空气等集中处理,确保空气排放口无刺激气味排放、无有害有毒气体排放、无恶臭气体排放、无微颗粒物排放、无室温排放等。请结合参看附图40、附图41、附图42、图43和图44,本发明中的尾气环保处理装置主要包括有尾气缓冲装置、进气口、初级净化管道、初级气、水、固分离器S257、双塔式旋转喷淋系统S259、冷却塔S269和烟气排放设备S264,本实施例中,整套系统的起点为尾气缓冲器S247,尾气缓冲器S247外壳呈圆筒状,底部为圆锥形,尾气缓冲器S247外壳内上方设有多个进气口S272,空气缓冲室内装有水体,且水体形成的顶部端面为水体界面S248,尾气缓冲器S247外壳底部装有排污口S249,用于污水排出,排污口S249通过管段连通至循环水箱S258内部,循环水箱连接有水体循环管道4,作用于对缓冲器内部的水体补充,确保水体设定的界面位置和水体降温。本实施例中,尾气缓冲器S247内还安装在线液面监控器S251,用于实时监控尾气缓冲器S247内部的水体界面高度。尾气缓冲器S247外侧设有循环水箱S258,循环水箱S258通过管段连通至沉渣池S270内,尾气缓冲器S247内的排污口S249一侧与循环水箱S258上部通过管段S275连通,管段上设有水阀S250,循环水箱S258上部通过管段与自动循环补水泵S252连接,自动循环补水泵S252出水口连接至尾气缓冲器S247内的中部,循环水通过尾气缓冲器内的水帘喷淋嘴26后排入尾气缓冲器S247内。尾气缓冲器S247上部侧面装有初级烟气处理管道S253,本实施例中,初级烟气处理管道S253内的上、左、右三个面上错位装有若干个负离子荷电陶瓷S254,该负离子荷电陶瓷无须电源启动、能自然释放负离子,在每个负离子荷电陶瓷S254后面装有高速水雾区喷头S255和凹钝角导流板S256,高速水雾区喷头S255在负离子荷电陶瓷S254后端形成多层水帘,为负离子高速水雾区,而钝角导流板作用于对高速烟气产生瞬间气流轨迹方向改变,使密度大的尘粒运动方向不随气体方向流动。本实施例中,初级烟气处理管道S253倾斜设置,初级烟气处理管道S253前端连接在尾气缓冲器S247上,初级烟气处理管道S253后端连接有初级气、水、固分离器S257,初级气、水、固分离器S257下方设有碳渣过滤器S271,用于滤除初级气、水、固分离器S257中沉淀物里面的碳渣。初级气、水、固分离器S257通过水气混合管道连接至双塔式旋转喷淋系统S259内。当烟气进入尾气缓冲器S247内时,直接通过管道通入至水封界面S248下方10cm——15cm处,并由于进气口的正压作用,烟气再跃出水封界面S248后进入初级烟气处理管道S253内。当热气流夹带着碳微粒或其他固态微粒高速撞向负离子高速水雾区时,在凹钝角导流板S256的作用下产生瞬间气流轨迹方向改变,尤其是利用负电离子与碳尘所带的阳离子中和以及高速水雾喷淋的冷水扰动,且尘粒具有密度大的特征,并不随气体方向流动,而是进入初级气、水、固分离器S257,再将带有碳微粒和其它固体微粒的水体送入下一级的水气混合管道,但气体由引风机设备被导入双塔式旋转喷淋系统S259。本实施例中,双塔式旋转喷淋系统S259包括两个并排设置的立式处理塔,烟气首先进入其中一个处理塔后,气体的走向为从上至下进入到另一个塔体的下部后,气体再于此塔下部从下至上的运行,同时设于双塔内围绕周边安装的旋转高压喷嘴S260对气体喷水,对气体进行顺逆清洗,双塔底部均设有出水口S261,并由此出水口S261流入水、气混合管道,而经过清洗的热烟气已形成热水气由安装于塔外的引风设备S262引入水、气混合管道S263中,本实施例中,水、气混合管道S263以卧式微倾斜安装,连接引风设备,水、气混合管道S263一端稍高,而另一端稍低,由双塔式旋转喷淋系统S259下部的出水口所排出的水体和由引风机导出的热气直接进入水、气混合管道S263流向稍低的一端并进入烟气排放设备S264内。请结合参看附图3,本实施例中,烟气排放设备S264包括三部分,下部为罐体S265,与罐体S265顶部相连接的为热交换器S266,设于热交换器上部的为气体排放管道S267,其中下部罐体S265与水、气混合管道S263的出水口相连接,下罐体S265的一侧设置湿渣排出口及出水口S268。另外,热交换器S266中的循环水由冷却塔S269提供,冷却塔S269通过泵具吸取沉渣池S270内的水,并通过管道输送至热交换器S266内,对热交换器S266内的热水气进行冷却,当热水气进入热交换器S266后,蒸汽被冷却液化为水体落下,进入下部罐体S265,并经出水口S268排出,不能液化的干洁气体由排放口排出,这时的气体排出温度不高于38℃。
本发明中的尾气环保处理装置主要点在于在尾气处理系统前端加入了尾气缓冲装置,及其结构设计,本发明中的尾气环保处理装置的其他部分的结构可参看申请的在先中国专利,申请号为201010168879.2,公开号为CN101816874A,其专利的结构与本发明中的尾气环保处理装置大体相同。
本发明中的尾气环保处理装置能够对餐厨垃圾资源化处理的各个工序中所产生的烟气、热烟气、粉尘、抽排口空气等集中处理,确保空气排放口无刺激气味排放、无有害有毒气体排放、无恶臭气体排放、无微颗粒物排放、无室温排放等。通过本发明中的尾气环保处理装置能够对尾气进行脱硫、减轻二氧化碳排放的同时,还能将尾气中含有的碳尘粒进行清除,实现无污染几乎无白烟排放,有效的改变了以往燃气炉尾因尾气排放过程中所产生的弱酸腐蚀管道引起管道容易破损的缺陷,保障系统的使用寿命。本发明中的尾气环保处理装置还能够将尾气的温度降低到与大气基本相同排放,从而同样保障了系统的使用寿命。
T、等离子光触媒负离子空气除臭杀菌装置:
本发明中,还通过等离子光触媒负离子空气除臭杀菌装置对整个处理过程中产生的异味进行处理,等离子光触媒负离子空气除臭杀菌装置应用于将各个餐厨垃圾处理中所溢出的异味以及整个工场的空气作集中收集处理,对所收集的空气进行持续高效地灭除有害微生物,杀灭细菌,病毒,降解空气中的异味。请参看附图45和附图46,本发明中的等离子光触媒负离子空气除臭杀菌装置的进风口T270安装于各个餐厨垃圾收集池的四周,确保防止污染体扩散,以及各个有可能溢出异味的生产工段和生产车间的上部两侧,每个进风口T270的后端均安装有自动滑板闸阀T271,自动滑板闸阀T271通过气动装置或电动装置控制开合,自动滑板闸阀T271用于防止因空气处理设备故障而停机维修时,得以保证污染源不扩散,自动滑板闸阀T271后端连接空气输送管道T272,在空气输送管道T272内设有负离子波纹板T273(本实施例中,采用能量塑料承载器具所用塑料原料涂覆在钢板两侧,再压弯呈波纹状形成),本实施例中,空气输送管道T272内前端距离进入端30cm——80cm处安装有多组释放15000个/cm3的层叠式第一负离子波纹板T273(按照管道和出风量设计),此处的负离子波纹板T273呈卧式安装,在卧式安装的负离子波纹板后端设有立式安装的层叠式负离子波纹板,本实施例中,以一段卧式负离子波纹板配合一段立式负离子波纹板构成,具体实施时,还可以根据实际需要分别设置多段。本实施例中,每一段负离子波纹板包括一片以上,板与板之间的间距为10mm。空气输送管道T272尾端连接有光催化主处理器T274,当空气通过负离子区处理后,由安装于光催化主处理器T274内的引风机引导空气向空气送风管道的尾端后,再进入光催化主处理器T274内。本实施例中,光催化主处理器T274内设有空气通道,空气通道呈Z形的空气通道,Z形的空气通道内部为Z形导向板T275,Z形导向板T275均为镜面铝合金板,用于将紫外线光管T276光源发出的光反射于Z形的空气通道中,Z形的空气通道内装有若干支发光波长为253nm——258nm的紫外线光管T276(横向安装),每个紫外线光管T276背面均配装光面反射板T277,用于将紫外线光管T276发出的光源反射至空气通道内,最大程度发挥其作用。本实施例中,在距离紫外线光管T276后方10cm——20cm处安装蜂窝形的二氧化钛光催化触板T278,光催化触板T278的尺寸和形状与Z形的空气通道横截面一致,可刚好挡在Z形的空气通道内,光催化触板T278为厚度1cm——10cm,上开有若干孔洞,光催化主处理器T274的Z形空气通道的转角位置安装若干个等离子发生器T283,该等离子发生器的放电功率为2.5WH/m3,光催化主处理器T274内的Z形的空气通道尾端连接有空气排出管道T279,空气排出管道T279内部的尾端安装有能释放的负离子量为15000个/cm3的层叠式第二负离子波纹板T280,第二负离子波纹板T280结构与第一负离子波纹板T273结构相同,空气通过此层叠式第二负离子波纹板T280后进入活性碳空气过滤器T281处理后排出,本实施例中,活性碳空气过滤器T281为在外壳内设置有活性碳,对气体进行最后的活性碳吸附。
本发明中的等离子光触媒负离子空气除臭杀菌装置的运作方法如下:当餐厨垃圾进入收集池时,本发明中的引风器启动,打开池边四周的空气收集管道前端的自动滑板闸阀T271,如果生产车间或其它收集池尚无需对空气进行处理时,其空气收集管道前端的自动滑板闸阀T271均呈关闭状态,若生产车间或其他收集池也需要对空气进行处理时,其收集管道前端的自动滑阀均是呈打开状态,由于引风器的作用,含有细菌和异味的空气通过闸阀T271进入管道内的负离子层叠式波纹板T273内处理,波纹板与波纹板的隔距为5mm——10mm,负离子层叠式波纹板T273所释放的负离子量为15000个/cm3且无须通电产生,对通过的空气中带有阳离子的菌体和异味实施首次捕捉灭杀后沉降,经过首次灭杀和除臭的气体于引风器的强力作用下,沿空气输送管道进入等离子处理区后,再继续进入光催化主处理器T274,气体进入主处理器后作由下至上的Z形方向运动,气体被装于Z形通道四壁的紫外线光管T276所发出的紫外线全面照射下,再进入蜂窝状的二氧化钛光催化板T278的通道,由于二氧化钛催化板T278吸收光能后产生生光电子和生光空穴并产生很强能量,与空气中表面吸附的水份和氧气反应生成氧化性很活泼的羟基自由基和超氧离子自由基,这些能力远远高出于一般有机污染物分子链的强度,因此当空气进入Z形通道后,空气中带有的有机污染物分解成最原始状态,尤其是空气于Z形空气通道中经过若干次的重复光催化处理,空气中的细菌病毒已被有效除去,空气中的异味同时降解,为了进一步确保排出的空气清新合格,在Z形空气通道中的转角位置安装等离子发生器13,加强污染物降解和去除,并将已经过光催化和等离子联合处理的空气自动进入设于装置尾端的负离子层叠形波纹板T280进行再一次的负离子处理后,再通过活性碳空气处理器对空气中残留杂质进行吸附后排出。此时所排出的气体无味,无菌,无固体微粒,无有毒有害物且清新干净。
本发明中的等离子光触媒负离子空气除臭杀菌装置可以对餐厨垃圾处理过程中各个工段所溢出的异味以及整个工场的空气作集中收集处理,对所收集的空气进行持续高效地灭除有害微生物,杀灭细菌,病毒,降解空气中的异味此时所排出的气体无味,无菌,无固体微粒,无有毒有害物且清新干净。
U、自动控制装置:
本发明中的自动控制装置主要应用于餐厨垃圾资源化处理过程中对餐厨垃圾进料、筛选、清洗、生化处理、干燥、精筛选的生产工序进行自动智能控制,此控制系统为公知的技术。此装置是采用多台PLC并联方式完成中央控制功能,每台PLC各自有独立的程式,多台PLC之间内部自动通讯,各现场电器单元和操作指令均通过PLC采集信号,以RS-422通讯方式传到上位机,组成完整的集散控制系统,所有电器控制单元均按照现场各个生产设备装置动作需要,分为若干个现场控制大单元,并进行独立程序化控制,并建立主操作室,实现对现场各控制柜的全部监控,在中央控制室控制所有电器的开停,并且显示器上显示所有运行状态和故障报警,所有程式在主站CPU中进行逻辑控制,完成对工艺设备按照预先设计好的逻辑与要求自动运作。
本发明具有如下的好处:
1、通过本发明申请所述的餐厨垃圾全方位处理的集成化装备和方法是一套国内、外餐厨处理同业首次以高集成化、自动化、全面化的综合装备,兼容对餐厨垃圾必然附着物同时作出资源化处理的方法,适应国际环保产业趋向,实施对废弃物集中综合处理后残余物不转移消化,不产生二次污染的安全处理、处置方向。
2、本发明申请提供了对餐厨垃圾及其必然附着物——废塑料袋,泔水污泥和厂区生活污水,生产过程产出的工业污水及污泥,在同一装备中的各种大型系统设备中的处理方法。
3、本发明申请提供了餐厨垃圾综合性资源化处理后,所制成各种高附加值的产品名称和制造方法及其用途。
4、本发明申请为餐厨垃圾处理行业提供了一种综合性的节能生产、安全生产、无残余物转移处理,无室温排放,无异味排放接近无污水排放的清洁生产方法和模式。
5、本发明所产出的产品为国III矿物柴油,低硫高热值清洁环保煤,燃气三大战略能源,起到减轻社会供需压力。同时所产生的高营养微生物蛋白饲料添加剂,能有效地填补国内饲料高蛋白质添加剂缺失的缺口。
6、本发明提供了一种餐厨垃圾承载器(桶)且能自然杀菌除臭,并于桶体外周边能自然提供清洁空气的新型垃圾承载器(桶)生产方法,是一种应用面极其广阔的新型环保清洁用具。
下面以具体的实施案例说明本发明申请所述的餐厨垃圾全方位处理的集成化装备的细节应用方式和产品的制造方法。该具体实施方式与案例应当理解成实施方式中所说明以及其过程是为了让公众更好的理解本发明的技术内容,而不是对本发明的技术内容的限制,在不违反本发明内容精神实质的基础上,所做的改进都是在本发明申请所要求保护的范围之内。
实施方式与案例:
由于本发明是一整套集成化餐厨垃圾处理装备,其中集合有多种专用大型装置和系统,均有各自的独立性和应用范围,但也具备装置与装置之间的连贯性及迂回应用性,为了更加清楚完整地表达整套装备的应用方式和生产工序及其方法与相关配方,以实际案例说明。
本实施方式与案例在广东保密试验,其所采用的餐厨垃圾来源于中华人民共和国广东省珠江三角洲内的某地级城市中的酒楼、酒店、中餐厅、西餐厅、政府食堂、学校食堂等,案例中的产品产成率和生产中所采用的方法和相关配方,是按照该地区人文的餐饮习惯、特点及其厨余质素而设定,本具体实施方式所指的餐厨垃圾清运工作是由政府相关部门指定的环保清运企业负责,餐厨垃圾综合处理的整套装备由华南再生资源(中山)有限公司提供,具体实施地点于该公司内的厨余资源化处理基地,该基地日处理能力设为200吨,现以基中一组日处理50吨的集成化装备的实施方式和生产工序及方法和相关配方,作为表述本发明的具体实施方式。
1、首先从餐厨垃圾的收集桶述起,此收集桶是分发给各个餐厨源头的承装工具,也是从源头至处理厂的运输途中的转运工具,对保护源头卫生环境和避免转运途中可能出现的二次污染具有相当重要的关健,因此需采用具有桶内具杀菌除臭功能,而桶外周围可释放负氧离子清新空气的餐厨垃圾桶,其具体制造方法按如下步骤实施:
首先将炭黑进行臭氧氧化处理,其炭黑粒度≤2um,臭氧氧化处理是采用现有技术中的臭氧氧化设备对炭黑进行常规的氧化处理,使炭黑的内表面积增加4倍以上,以此来促进炭黑的吸附能力。
进一步将处理过的炭黑与纳米级电气石粉剂充分混合作为基料,其中炭黑占基料总重量的15%,纳米级电气石粉剂占总重量的85%,在混合后的基料中再加入超细二氧化钛,并再充分混合作为能量原料,超细二氧化钛的加入量为基料总重量的10%。
再进一步将混合的能量原料在100——120℃条件下干燥1——2个小时(混合的能量原料完全干燥即可)。
再进一步在干燥后的能量原料加分散剂,分散剂采用与基本树脂相关的偶联剂,特别是采用以利于和载体树脂混合的偶联剂,分散剂的加入量为能量原料的3%,本实施方式选用的其中一款分散剂为硬脂酸镁。
再进一步将加入分散剂后的能量原料再加入塑料载体树脂中,并混合均匀,形成充分混合的村料,本实施方式采用的塑料载体树脂为PE,塑料载体树脂的加入量与能量原料的比例为30%:70%。
再进一步将上述所述的混合物输入专用混炼设备中进行混炼,在此混炼过程中再加入偶联剂,本实施方式中选用的偶联剂为氨基烷类偶联剂,其加入量与能量原料和塑料载体总重量比例是2%:98%,混炼的温度是以混合树脂的常规温度设定,当混炼物通过挤出机并完成冷却和切粒工序后制成塑料能量母粒。
再进一步将所产出的能量塑料母粒进行检测,其测定范围是红外线辐射波长为4——16,法向全发射率为≥0.86,负离子浓度为7000个/cm3以上,当确定母料的质量符合要求后,再将检测符合生产标准的能量母粒与HPPE和ABS塑料胶粒混合,其中PE与ABS的混合比例要视符餐厨垃圾桶的承载重量配置,而能量母粒占三种混合塑料树脂的70%,最后利用专业注塑机注塑成型,制成桶体和桶盖,对于注塑中对混合树脂的溶体流动速度及料筒温度的控制和模具温度控制、以及注射压力等均按行业常规生产技术方法。
进一步将制成的餐厨垃圾承装桶组装并检测能自然释放出5000个/cm3以上负离子含量后,发放给各个餐厨垃圾收集点,以此保证餐厨垃圾从进入承装桶起12个小时内不会变臭。
2、由政府指定的环保清运企业到各餐厨垃圾产生地将上述承载桶所承载的餐厨垃圾收集并送达处理厂区。
3、当餐厨垃圾送达厂区指定的漏斗型收集口时,收集口由主控制室操作打开闸盖,并开启设于收集口上侧四周的抽风口闸阀,同时启动等离子光触媒负离子空气处理系统。此时餐厨垃圾被自动卸料设备送入收集器,当餐厨垃圾输卸完毕后,收集装置闸盖自动关闭,由于空气处理系统已启动,垃圾的异味被导入处理装置杀菌除臭,保证厂区空气环境清新,同时于餐厨垃圾进入收集器后,装置内下部的横向自动闸阀打开,垃圾自然落入推进式破袋设备。
再进一步
4、当餐厨垃圾从上面落入破袋设备管道,管道前端液压系统的活塞向前推进,将散装餐厨垃圾及其袋装餐厨垃圾推向装有若干固定刀具的管套,活塞推进时其周边的凹腔位穿过固定刀具的啮合,将垃圾袋剖开若干破口,且随散装的餐厨垃圾一起同时推向下一工序。破袋设备的活塞是随管道方向作推拉的往复运动,当活塞被拉回起始点时,餐厨垃圾从上落入,当活塞被向前推动时,餐厨垃圾被破袋且被推入下一工序,液压油泵最小压力为3mpa,处理量为20——30m3/h,当餐厨垃圾全部通过破袋设备后,设于连接破袋设备进料口上部的横向自动闸门关闭。
再进一步
5、餐厨垃圾经过破袋后进入卸料管道,并利用水流冲力,将餐厨垃圾送入液态气浮分选装置,此装置的主分选装置内腔为6m3,这时设于主分选装置一侧中下部的半浮沉料卸料百叶口关闭,水体通过输水管系统开始向主装置桶注水,注水量以设定的水面高度为准,且由液面自动定位器控制,每次投入的餐厨垃圾是主装置水体总立方量的1/3——1.5/3,当水体升至设定的液面高度后,设于主装置上部的主、副滚耙由电机通过变速箱带动开始滚动,同时设于主装置下部的压缩空气阀门打开,利用若干个气体喷嘴射出的高压空气,将浸于水体的餐厨垃圾在水的浮力作用下翻动,此时密度较小的塑料、布条、牙签等杂物浮向水体的上层,被滚耙的耙齿捕捞向上转动,并由设于主滚耙侧上部的副耙齿捕捉后卸向轻质杂物收集桶。当餐厨垃圾从水体中翻滚开始5min后,设于水体中下部的百叶口开启,借助主装置水体的液压力差,将半浮层的餐厨垃圾压向百叶口,并进入副装置,当副装置的水位到达设定的高度时,启动循环水泵将水输送到缓冲水箱并对主装置进行补水,此举作用于保证主装置的液面保证高于副装置的液面,当半浮层的餐厨垃圾基本或全部进入副装置后,设于主装置的残余物出料口阀门开启,并将沉于装置底部的密度较大或大件物伯,如:金属杂物,玻璃,碎瓷件,重质杂物及餐厨垃圾中的已废弃的小量原只鸡、鸭、鱼或大件肉类从残余物出料口卸出,并由自动输送工具送达设定地点后再稍作人工分选,将有作用的餐厨垃圾选出输入破碎机,经过液态气浮分选,所得到的有利用于生产蛋白饲料的餐厨余物,已基本进行第一次的初级脱盐步骤和清洗过程。
再进一步
6、将已经分选出的有利用的餐厨垃圾从液态气浮分选装置中的副装置出料口排出并通过输送工具自动送入湿式高级氧化装置的第一级反应器及第二反应器,该二级反应器内腔各为5m3,餐厨垃圾加入量为5T,再注入清水2T,两者的投入均由自动定量工具控制,并通过设于釜内的液面控制器,设定反应器的水位的高度。当餐厨垃圾进入一、二级反应器后,进料口关闭,呈密封状态,与两个反应器相连的循环输送管道阀门打开,此时由臭氧发生器提供的臭氧气体通过防水单向阀进入气水混合器,该防水单向阀主要作用于防止水体回流而进入臭氧发生器。在臭氧气体进入气水混合器的同时,安装于循环管道之间的高粘度凸轮转子泵启动,餐厨垃圾与水体的共混物被强力推入水、气混合器并与进入该混合器的臭氧气体实施餐厨垃圾——水——臭氧气体混合,并促进臭氧溶附于激化水中,并随后进入反应釜内,并由另一凸轮转子泵将反应釜内的餐厨垃圾——水——臭氧气体的混合物强力输入另一反应釜,于如此返复循环动作作为反应过程,尤其在含臭氧的物料在反应器内的活性炭固定反应球作用下,于混合物中引发链式反应,加速臭氧转化为羟基自由基,类似于O3/H3O3或O3/UV的高级氧化过程,在具有氧化作用的单原氧瞬时分散在水中与餐厨垃圾有机物质、细菌和微生物发生以上反应十分迅速,单原氧O和羟基自由基OH在1——2min内可以对餐厨垃圾中的病原菌及芽孢等强行灭活,本具体实施方式中泵口额定工作压力为0.25mpa,输送强度500kg/min,釜内混合物反应时间为10min,餐厨垃圾水中的臭氧浓度为12g/T,在整个反应过程中,设于反应器上部的气体溢出口和臭氧毁灭器始终处于开启状态,当餐厨垃圾经过高级氧化过程后已完成脱盐,原生菌体灭活等工序。有效地保证往后的蛋白饲料生产工序中的接种和扩种工作质量,并有效排除杂菌干扰和清除透入餐厨垃圾中的盐份。
再进一步
7、经过上一步骤处理的餐厨垃圾由反应器下部的卸料口排出并进入初级固液分离器,将大部分水体分离后,得到含水量约为85%的餐厨垃圾,再由螺带输送工具渐步送入立式脱水装置,安装于脱水装置上部的可调压水板由液压器调整至闭口状态,贯穿于螺带轴心的中轴由3.7KW电机配合变速箱驱动,并以580转/min的转速旋转,安装于脱水塔下部的承水器出水口所连接的电动球阀自动打开,此时餐厨垃圾被投入于脱水塔下部的进料口,餐厨垃圾随下大上小的螺带与筒壳的挤压作用以及塔顶压水板的阻档,物料输送阻力变大,当压力达到设定的压强时,设于塔顶一侧的出料门自动打开,此出料口由液压控制。此时餐厨垃圾不间断地通过脱水塔下部的浓缩区向上推进至脱水区,实行连续性脱水和出料,而被脱除的水体从塔体筒壳的栅条流出并顺着设于栅条固定圈外侧导流片流入承水器,并通过排水口排出,脱水物料的排出量为8T/h,脱水塔的连续运转时间设定不超过8小时,在停机后利用安装于脱水塔周边高压水反冲喷嘴对栅条的出水缝隙进行清洗,出水喷头额定工作压力为0.35mpa,供水强度为14L/min,清洗时间为10min。
当完成上述的工序后,连接于上工序的路线分为两个不同工作性质的工序,其中一个工序是:提油工序。
将本具体实施方式中所指的3、4、5、6点工序中产生的含油水体集中收集于地沉池后,利用水泵将池中中部以上的含油水体输入油水分离塔,该油水分离塔分两个塔体组成,且中部有管道相通,两个塔体均为空腔,空腔总容积60m3,承载水体50m3,当含油水体被输进油水分离塔后,塔内的加热管道的热气透过管壁的热传递而进入水体中,其热气源采集于生产用的导热油锅炉热尾气,当含油水体被加热至80℃时,水体中的油脂与水充分脱离,并向上层浮起,且自然进入设于油水分离塔上部的斜面隔板上部后,顺着隔板向下倾斜面流入浮油承载区,再通过安装于承载区的刮油板将油料通过卸油管道送入生物柴油生产区,所得油脂约为180kg。而处于油水分离塔下部的水体在80℃的温度下,大部分的细菌和微生物被灭活,并通过塔下部的排水口输入污水处理区。
以上所述的两个不同工作性质的装置中之另一工序是破碎工序:当从脱水工序输出的餐厨垃圾约45%,并由气动推板输入破碎机进行破碎,此为公知技术,在此不再阐述。
当破碎机输出餐厨垃圾后,再进一步:
8、将已破碎的餐厨垃圾分批卸入物料提升斗,按照设定的分量分别送入两个采用不同菌种的付生化发酵器,该两个预生化发酵器一个内容积为10m3,进入餐厨垃圾7吨,另一个预生化发酵器内容积为30m3,进入餐厨垃圾及于另一个秸秆生化发酵装置所输入的纤维营养物料,餐厨垃圾和纤维营养物类的互配比例是视符最后所生产的饲料种类所需而定,本具体实施方式中是各占50%,但两者进入生化发酵器的总重量为20吨。内载7吨餐厨垃圾的生化处理是选用面包酵母作为菌种,首先利用定量加料器在基料中加入占基料重量2%的麸皮,2.5%的米糠,1%的红糖混合并调成糊状,利用饲料干燥器的余热将混合物加热至25℃后,向混合料中投入占基料重量3%的面包酵母,并充分搅,强化曝气,以增强酵母生长,发酵时间为12小时。另一个内载20吨的混合物料餐厨垃圾的生化处理器中,投入绿色木霉和热带假丝酵母及白地菌和拟内胞霉酵母菌的联合复合菌种,这多种菌种均符合《中国菌种目录》中允许直接饲喂的微生物。其比例为2:2:1:1,接种量为底物质量的3%,接种方式为复合菌种不分先后加入,并加入0.5%的尿素,连续生化发酵10小时,发酵的热源由饲料干燥机余热提供,温度设定为32℃,通风条件为8min/h,通风量为0.2m3/h,菌种中的绿色木霉配合白地菌对基料的粗纤维含量降低极其显著,而热带假丝酵母、白地菌和绿色木霉能对粗蛋白质和真蛋白质的提高作用达到明显水平,利用拟内孢霉酵母菌作为辅助霉,于此预生化发酵器中实行首次扩菌。
再回到上述所指出的纤维营养物料的制作实施方法,本案例的实施处理地域在中国南方的珠三角地区,所以在本案中选用的秸秆种类选择就地取材,以当地的豆科秸秆和禾木科作物秸秆混合,采用花生秆、蚕豆秆、土豆秆的豆科秸秆和稻秆、甘蔗头部和尾部、玉米杆的当季禾木科秸秆,如在冬季生产即采用加入麦秆。上述所指的秸杆搭配是依据豆科作物这类秸秆蛋白质含量高,但糖分含量低,在发酵初期微生物活力不高,再与含可溶性糖分含量较高的禾木科作物秸秆混合,不仅可以提高发酵质量,而且可使这两类作物秸秆的营养物质互相补充,从而取得更好的饲料质量。在本具体实施方式案例中的两类秸秆中的搭配比例为豆科类秸秆60%,禾木科类秸秆40%。作物秸秆进行适当的清洁工作,踢除腐烂、发霉的部分和泥土、砂石等杂物,并予暴晒除去表面水分,抑制霉菌的生长和繁殖,并通过粉碎机将秸秆粉碎成0.5-1毫米的粉末。并投放入若干个生化发酵池,秸秆粉料的投放量为13.2吨,物料由自动输送翻斗车投放。另外还设有菌种激活池一个,选用复合菌种,其中一类为米曲素。由于干菌粉中基本不含培养基成分,本案例采用1%的红糖水溶液作为激活液,复合菌剂的投入量为基料的1%,当复合菌剂投入于激活液中静置1.5小时后,再加入氧化钙2kg,氯化钠0.2kg,磷酸氢钠3kg,尿素0.5kg的化学成分,此化学成分的重量是指每吨秸杆所需。该化学成份是作用于分解木质素、软化秸秆、破坏植物细胞壁的晶区结构、打破木质素与纤维素紧密结合的物理化学状态,改善生化处理效果和饲料的是适口性。将上述的激活液与化学成分搅拌均匀后成为发酵液。将发酵液喷洒于生化发酵池内的物料中,秸秆和发酵液的比例为1:2,随后利用安装于生化池侧的自动搅拌装置对若干个池的物料进行均匀搅拌,时间约为10分钟,并于搅拌结束后将物料压实。当上述工序完成后,由液压自动系统将生化发酵池盖密封关闭,生化处理时间下季为7-9天,要求温度为常温。在整个生化过程中,复合菌剂对秸秆进行生化处理,使粗纤维得到有效降解和糖化,并合成丰富的菌体蛋白质和生理活性物质,且秸秆蕴含的生物能量基本不被消耗。因此,在正常条件下不会发生热的现象和产气现象及胀池现象。秸秆经生化处理后,颜色鲜亮,呈金黄色,手感细腻松软,香味浓郁,略带酒香味。
现在再陈述预生化处理的物料。经过10小时的预处理后,由装置于生化器底部的螺带自动输料机将物料输入下层的两组主生化器,每组主生化器内腔体积为20m3.但是于副生化器中以面包酵母为菌种的物料,需留存约10%不进入主生化器,作用于下次的发酵所用,因为下次的发酵是采用老法发酵法。当已经过预生化发酵的物料完全进入主生化发酵器后,安装于主、副生化器之间的物料输送口自动滑板闸阀关闭。此时,开启设于生化器壳体侧面中部的空气输排管,并启动双层螺带搅拌器,转速为7转/min,作卧式360o旋转,此间的搅拌器外层螺带运动方向为顺向,内层螺带的运动方向为逆向。由导热油锅炉输出导热油,通过热泵输往安装于生化器两侧面,利用生化器壳体传热对物料进行提温,根据所选用的多种不同菌种的好氧或厌氧情况及菌种繁殖生长的适应温度情况,做出最佳工况。首先初始温度为20℃,逐步提温至28℃,恒温4小时后关闭输排气口,且逐步提温至35℃-38℃,恒温时间3小时后,,此段时间生化发酵的供氧分是来源物料之间的空隙和比面积之间,当完成此温段后,开启引风装置作轻量排气,将主发生器内的水气排出生化器外,且再提温至54℃,恒温1.5小时,再提温至80℃,恒温1小时,于此温度有效地避免了微生物利用其中的碳骨架作为能源,而脱氢产生刺激性氨味影响产品的经济价值,并对微生物作基本的灭活,同时对物料实施大量的脱水,从物料含水率55%到生化发酵完成出料时的含水率约为35%。
再进一步
9、经过完成生化发酵的餐厨垃圾已转化为微生物蛋白饲料,含水量约为35%,当打开主生化发酵器设于底部侧的出料口,将饲料卸入饲料提升机,并通过提升机送入干燥装置中的预干燥设备,预干燥设备的热风来源于主干燥设备的尾气余热,热气进入套于预干燥设备的外套壳,利用设备套壳内腔的导热油对内腔提温,内腔体积16m3,每次进料8吨,设备内腔温度为100℃,当饲料进入设备时,安装于设备内的中轴翻板由电机配合变速器提供动力而转动,转速为12转/min,此时,饲料被翻板转动,物料不间断地与热气和筒壁接触而被加热,当低于设备筒壁温度的饲料不断地接触筒壁时,而筒壁会被冷却,但由于翻板的转动下,变化周期较短,温度变化幅度小,筒壁温度基本可以认为不变,没有接触筒壁的饲料会受到受热饲料颗粒的辐射传热,也可以说是粒子表面接受辐射热。当投入于预热干燥设备内的饲料被热燥45min的时间内,水分从饲料内部以气态扩散,透过饲料层面达到表面,然后水气通过饲料表面的气膜而向设备内腔上部扩散,并由气体排放口排出,进入气体处理工序。当饲料完成预干燥工序后,设于预干燥设备下部的滑板闸阀全部打开,饲料被落入连接于滑板闸阀的螺带输送设备,且被送入主干燥设备。该主干燥设备为卧式无轴旋转气流干燥设备。本具体实施方式案例中的主干燥设备为四层转筒结构,每层转筒内壁装有连接筒壁的螺带,最内层转筒螺距为150mm,筒体直径700mm,筒长为4000mm;下一层转筒螺距200mm,筒体直径1200,mm,筒长为4600mm;再下一层转筒螺距300mm,筒体直径1800mm,筒长4600mm;最外层转筒是干燥设备的主转筒,螺距450mm,筒体直径2200mm,筒长6000mm。各层转筒的固定连接均以外转筒为基础,于内转筒圆周内安装若干固定支架,逐个固定,转筒的转速为29转/min,主干燥设备的尾端上部装有排气口,热气由引风器导出。主干燥设备的热源由柴油喷射燃烧器于燃烧室喷烧产生,由设于燃烧室侧部的可调式逆风机,将热空气送进热气导流罩后进入干燥设备。本具体实施方式案例中在设定的入口温度280℃,出口温度高于110℃时才开始进入饲料,进料速度为20kg/min,气流速度为1.2m/s。饲料首先进入最内层的转筒后随螺带的前进方向推进与热气流作顺流接触,当饲料到达转筒尾端后,自然落入下一层转筒后,随螺带的前进方向推进,与热气流作逆流接触后,再自然落入下一层,此层的转筒前进方向与热气流接触的方式与最内层转筒相同,饲料最后落入主转筒后,并随螺带前进方向推向卸料口。在整个干燥过程中,利用套筒式卧式转筒来延伸饲料的前进轨道,确保物料与热空气有充足的停留时间接触,通过热能将饲料中水分快速蒸发。
再进一步
10、将已干燥后的饲料通过输送设备逐步送进饲料精选装置,饲料于该装置内的倾斜滚筒旋转,其运动轨迹不间断滚动向前,此时不能通过滚筒筛网目数的大件物件或重质物件被送入设滚筒尾部的螺带引流器,并随螺带前进方向落入杂料箱,而小于滚筒筛网目数的饲料通过孔眼落入成品承载器。再将杂料箱中的杂料经过二次筛选择取稍大粒度的饲料后,进行破碎并输回成品承载器。
上述的生化发酵及饲料干燥过程所需的热卡耗能约为630大卡/kg,所产出的产品为高蛋白营养饲料,饲料重量为12.7吨,检验产品量质结果为:
水分:7.84
粗蛋白质:28.66(干物质)
粗纤维:15.5(干物质)
钙:6.86
总磷:3.09
食盐:1.11
锌:196mg/kg
粗脂肪:4.79(干物质)
粗灰分:1.17(干物质)
合格产品呈金黄色、色泽鲜亮、稍带酒香味和烤面包香味
再进一步
11、高营养饲料进入饲料造粒生产区,按照各种水产动物的大小和适应口感,通过专用设备产出膨化浮料、半浮沉料等专用饲料。该技术为公知技术,在此不再叙述。
从上述所列具体实施方式案例,只是陈述从餐厨垃圾的收集到进入处理厂区后,进行综合处理中的其中之主物生产工序。
但于上述的处理工序中所筛选和产生的餐厨垃圾必然附着物还需要进行资源化处理,在此下面所述的是对含臭味处理、热烟气处理、污水处理、污泥处理的具体实施方式案例。
现在陈述油脂处理的具体实施方式案例。
12、本具体实施方式案例中上述第7点中的提油工序中,所提取的油脂水进入生物柴油生产区后。测得所得到的油脂为1.6吨,占所进入的餐厨垃圾50吨中的3.2%。对于处理此油脂的方法是采用免蒸馏法的生产方式,此生产工艺对原料的适应力强,生产过程中清洁、安全、简易,整个生产过程于常温下进行。本具体实施方式案例是首先利用油泵将储油罐中的粗生物油脂从容器中抽出,送入生物油脂质脱除撞击流反应器中进行胶质的脱除,此时,启动安装于撞击反应器两端的旋浆水力推进机,将油脂强力撞向设于撞击器中的孔板,在这过程中加入油脂重量0.8%的磷酸于油脂中,连续相向撞击孔板,利用孔板的孔洞使两端的油脂互相强力穿越,时间为15min,此步骤作用于对油脂中不能水化的磷脂,也就是说非水化磷脂,尤其是它结构的对称性,受分子结构的空间效应影响,亲水性差,不易吸水膨胀被去除的原因,将会严重影响生物油脂加工成生物柴油的难度和质量,因此采用磷酸于油脂中的强烈混合冲刷,破坏非水化磷脂的微金属复合物,从而转化成水化磷脂。当完成此步骤后,再加入10%含量的稀释盐水于油脂中,投入量为120kg,且继续借助两端的旋浆推动使油脂相互强力撞击,用时20min后停止,并静置待分层,由于电解质的作用,促使油脂中杂物于水化磷脂絮凝加快,使已形成的胶质团含油减少。通过上述该工序,使生物油脂中的胶质得到脱离,有效避免油中胶质在下一脂化工序中遮盖油脂粒子,保障油脂与催化剂的相接触。
通过脱除磷脂——胶质后的油脂从油脂撞击器分离出来后,输入脂交换反应釜,该反应釜内腔容积为3m3,当油脂进入釜内后,启动装于底部的径向叶轮实施中速转动,迅速使油脂翻滚,并打开投料口,加入甲醇80kg和甲乙酮3.2kg,叔丁醇1kg,其中甲乙酮与叔丁醇为共溶剂,利用共溶剂含有与油脂相容的亲油性基团以及可与甲醇结合的极性基团,其中分子里含有的氧原子于甲醇形成氢键,促进油脂与甲醇的互溶,形成均相体系,有效地加速与催化剂的作用下发生醇解脂交换反应。当甲醇与共溶剂投入油脂中,混合液被叶轮的动力翻滚,混合液进入互溶阶段,时间为15min,在此阶段结束后,再加入固体金属碱催化剂(华南713#),该催化剂以试剂活性碳为基核,然后浸渍碱性硅溶胶与铝溶胶及氢化锂的混合液体中,取出后于650℃-720℃的温度条件下,恒温一小时。降温后研磨成50——80目颗粒状,制成一种以非极性吸附剂为基核,外裹为硅、铝锂网状骨架介质,且带极性的杂化荷电催化剂,再将催化剂浸渍于KNO3水溶液中,取出后于110℃下烘干,制得KNO3负载量为25%的KNO3固体碱金属催化剂。此固体催化剂的加入量为24kg。当全部的添加物料添加完毕后,为了使反应体系尽可能达到均质化,增大反应介质分子间的接触面,推动反应向正方向进行,此时,将安装于釜内且浸于油脂中的超声波探头开启,探头数量为四支,初始频率为25KHz,于1min后逐步增大到30KHz,随着超声波频率的增大,并在超声波的辐射作用下,使油脂流动产生数以亿计的微小气泡的空化核在声场作用下振动,并于声压达到一定值时,产生崩溃空化,在这短时间内在空化泡周围的极小空间产生局部的高温和高压,高温使反应物的活性增加,促使自由基的形成和裂解反应发生,同时高压致使冲击波和微射流产生,导致分子之间产生强烈的碰撞。整个脂交换反应时间为35min,于35℃温度条件下进行,在完成脂换后,将反应釜中的物料输入分漏器内静置分层,取走上层甲醇甘油混合液另作它用,而下层的粗制生物柴油通过压滤机过滤后,得到精制生物柴油,生物柴油产率为95.2%,滤出的催化剂回收再生后循环再用。
进一步
13、所产出的1.53吨生物柴油尚有微小水分存在,为了适应本餐厨垃圾高度集成化资源化处理的能源自供所需,采取将上述的生物柴油在不脱水的条件下制造微乳化柴油。首先对生物柴油的含水量进行测定,测得油中含水量为4.6kg。通过油泵将生物柴油输入微乳化油的专用装置内,启动装置内的搅拌系统,设定转速为128转/min,此时,再加入复合离子表面活性剂作为亲水剂,一种为阳离子表面活性剂,另一种为非离子表面活性剂,上述的两类表面活性剂包含三乙醇胺、六氢苯胺和氨水及中间体丁醇,其组合的百分比为阳离子亲水表面活性剂与非离子表面活性剂各占50%,使用量为生物柴油含水量的2.5%。为了将生物柴油更适应生产用途,于生物柴油中再加入300kg矿物柴油,并将生物柴油和矿物柴油的总重量中的含水量调整为10%,即需要加入水量为180kg,此时,搅拌器转速改为200转/min。连续搅拌15min,于此工序完成后再加入酸值200以上的十八碳-顺-9-烯酸作为乳化剂,加入量为120kg,再调整搅拌器转速为340转/min,时间为60min,经取样静置,观察微乳化油为清洁透明,再通过振动器振动5min后不分层后,再慢速提温至85℃时不分层,经取样测定合格后被视为成品油。该油质可存储1年不分层,总热值为10000大卡以上。
废塑料处理(废塑料逆转工程):
14、废塑料来源于本具体实施方式案例中的第6点工序所述的由液态气浮筛选装置中筛选出的废塑料,通过输送带送入废塑料处理区——废塑料逆转工程生产区,于实施案例中从50T的餐厨垃圾中共筛选得280kg废塑料,其中有塑料袋、塑料瓶、瓶盖、塑料饭盒以及还有牙签、木筷、布条等,由于塑料逆转工程的专用装备最小进料量为2.5吨,因此本案例中所筛选得到的废塑料只有280kg,未能满足设备的生产需求,只能加入其它的废塑料搭配成4.5吨,开始实施操作如下:
所采用的废塑料不须要清洗,不需要筛选,不需要干燥,直接由料槽通过密封式输送带送入气压自动进料机后,利用自动进料机的往复推拉动作,将废塑料连续地送入裂解反应釜进行裂解催化,该裂解反应釜为一卧式反应釜,釜内安装有一个鳍式无轴随机刮壁装置,反应釜的外壳为裂解炉体,裂解炉的热源条件为本具体实施方式案例中第13点的微乳化生物柴油,为自供燃料,当首批废塑料被送入反应釜后,反应釜开始加热,提升速度100℃/h,于废塑料不断地送入反应釜的全程加料时间为40min。此后,立即加入设定量的氧化钙,借助氧化钙与废塑料中的水反应,瞬间提高釜内物料温度,防止釜壁结焦,同时也可以将含氯成份的物料转化成氯化钙并有效地调整反应物的PH值,于加入氧化钙工序后5min,再加入锌、铝类金属固体催化剂及非金属催化剂,催化剂的加入量为62kg,其中铝类金属固体催化剂作用于产气,待所有的添加剂全部加入反应釜后,随之将反应釜的进料口紧密关闭,釜内反应呈绝氧状态。
再进一步
当反应釜内温度不断提高,釜内压力达到设定的条件下,连接反应釜后端的单向阀门自动打开,釜内水蒸汽从阀门通过进入第一级冷凝器后转化为液态水被系统中的排水口直接排出,水的PH值为6.5,随着反应温度提高,釜内物料进入裂解过程,首先从反应釜升华输出的高凝点腊油通过单向阀而进入腊油收集器,而油气夹带着小量微小碳粒继续通过油气分离装置时,被设于装置中的磁环将部份微小碳粒被截留,而油气再进入二级热交换器,此时,易于液化的油料进入油料收集器,而不可液化的可燃气被设于后级的负压系统引力的作用下进入气体逆向清洁器,该负压系统是在接收到设于系统中的气体电子感应器讯号后自动开启的,当可燃气体通过首次清洁后再进入下一级的弱碱水洗系统,并迅速通过后级安全水封装置,进入专用燃气压缩器进行初级脱水,可燃气体压力提升为0.5mpa,然后再进入二次燃气压缩机再将可燃气压力提升为1mpa,进行二次脱水后直接将燃气送入燃气储存库待用,当裂解炉需要燃气作为热源补充燃料时,可燃气体从储存库输出,通过第一级减压为0.4——0.5mpa后,再经第二次减压为0.1——02mpa,并输入炉膛燃烧,本具体实施方式案例中的裂解炉燃烧室的尾气由尾气环保处理系统处理。
再进一步
再回到上述所指的易于液化的油料进入毛油收集器的下一步
将油料收集器的油料输入专用油水分离器,将跟随油料同时液化而进入油料收集器的水份去除后,输入柴油精炼系统。首先进入的是第一级的化学除碳脱腊反应器,当油料达到反应器的液面高度时,自动系统自动停止输液,并开启设于反应器顶部的气体收集器和气味毁灭系统,同时开启设于反应器内的搅拌设备,油料此时呈切流方式运动流型,反应器下部的气体鼓动系统开始启动,油料流动方向迅速撞向设于合成器内立面四周的档板,此时由定量加料装置按设定的添加剂分量,分批加入于油料中,其中的两种为酸性催化剂和酸性白土等,当添加剂全部按顺序加入后,反应时间为30min。在完成第一级的工序后,经过除碳脱胶后的油料通过设于反应器底部一侧的油料输出口排出后,再进入第二级的脱腊、中和、质量调整的合成系统,当油料全部进入合成系统的前级时,启动装置内部的搅拌器,并由定量加料装置加入添加剂,其中二种物料为碱性白土和二甲苯,其余的均为液态添加剂,于添加剂全部加入后,连续搅拌25min,再静置20min后,将已中和及脱腊的油料输入该系统的后级并取样测验,决定是否需要增加化学物料的种类及分量后,再进行质量调整,经过质量调整后的油料被输送到350目的渣液分离机,被分出的油料进入临时储油器。最后通过临时储油器将油料输出到金属催化剂固定床处理器进行最后的精制工序,从固定床处理器的产品排出口所输出的油品为成品油,其质量符合国III标准柴油,所得的国III标准柴油2.2吨,作用于提供餐厨垃圾资源化处理收集车辆的油料使用。
现在再陈述废塑料逆转工程的残余物中的粗碳黑的资源化处理具体实施方式案例:
15、废塑料逆转工程中,于反应釜内留有最后不可气化升华的粗碳黑固体残余物,它是一种微细颗粒,含固定碳极高,但如果不进行现场合理处理,而转向于转移处理时,将会对土地和空气造成破坏,因此是本具体实施方式案例中不可缺少的一项。
首先于裂解反应釜的自动出渣口排出粗碳黑,并通过输送设备将粗碳黑送入专用臭氧陈化器,对物料进行人工陈化,针对炭黑粒子外部结晶比较有序,而粒子内部的序性较差的特点,通过陈化手段改变粒子比容,以此增加粗碳黑的氧功能团,并提高碳氢比,当粗碳黑经过陈化后,由陈化器下部的出料口排出,再输送进入物理陈化处理设备内,于固定床上进行热蒸气处理,在蒸气气压为2.8mpa的条件下进行,时间为25min,此序有效地增加粗炭黑的助燃物料嵌入量,修改其难于点燃的特点。
进一步
当粗碳黑经过化学和物理的人工陈化后,进入物料与添加剂的混合设备后,启动设于混合设备内的多组不同运动方向的螺带,将物料作上而下并从右而左的翻动,此时启动设于混合设备上方的多个自动定量加料器,加添NaOH1%、Fe(C5H5)20.5%、C6H12N40.6%、V2O50.2%,再连续混合15min后,再加入35%原煤及6%的黏合剂,再混合15min便打开设于混合器底部的出料口,借助于螺带的推力,将混合物料排出,并转入螺带输送设备把物料送入形煤机,按照客户要求的颗粒大小和形状产出高能低硫环保煤,产品质量为全硫0.2%,灰分6.58%,挥发分11%,焦渣特征1级,干基发热量5300kcal/kg。
现在再陈述生产环节产出的污水和厂区生活污水处理的具体实施方式案例:
16、于本具体实施案例中所指的由多个工序所产生的污水和厂区生活污水,是通过多条污水排出管道入流集水池后,经过滚栅耙除去浮于水面的杂物,再由水泵抽入螺带脱水机去除小型固体杂物,而此时从脱水机排出的水体直接由水泵通过管道送入电热毡处理器顶部,再于机械雾化嘴喷出,喷头额定工作压力为0.35mpa,供水强度50——80kg/min,雾点落在灼热毡时,污水在灼热毡的热作用下部份转化为水蒸汽,部分转化为热水,上升的水蒸汽经过冷凝装置转为液态水进储水池,而热水即经过灼热毡的流水浅沟进入装置的底部的水体排出口进入储水池,与被液化的水体混合。此时,被处理过的水质硬度大为下降且对水中微生物实施高温人工灭活,同时使纯化的金属离子与水体分离,于上述处理污水的灼热毡设备的热源,是由导热油经过可控硅中频设备进行加热,中频电源电路采用六脉波整流方式,进线电压为380V,中频感应线圈发热量500000kcal,灼热毡直径为1.5m。
进一步
当经过灼热毡的污水处理备处理的水体,直接进入储水池后通过水泵的输送进入强力气、水混合器与臭氧气体混合,再进入高级氧化反应器前端,并通过活性碳反应球后进入高级氧化反应的过程中,此时设于后级的二级水泵开启下,首先将进入反应器的水体输入外壳的缓冲区后,再次进入强力气、水混合器,与补充的臭氧气体再次接触后再进入反应器,不间断地连续进行如此循环的水体运动作为反应过程,反应时间为5min,反应过程的水中臭氧浓度为5g/T,于反应完成后的水体在反应釜内停留2min,在反应过程中所溢的臭氧空气被吸入反应器顶部的臭氧毁灭器灭活处理。
再进一步
经过高级氧化处理的污水通过设于反应釜下部侧面的出水口,由水泵将水体输入复合过滤装置中,该装置由多组立式过滤罐组成,水体由过滤罐的顶部进入并于在设定的压力下通过数十支滤柱,此滤柱直径为200mm,长度为1m,该虑柱内上部装有非极性吸附剂,下部装有杂化荷电吸附剂,于过滤柱内的二种吸附剂的吸附作用下,水体已达到清彻无混浊,无异味,无重金属离子存在的程度,同时基本将由于高级反应中而存在于水体的由臭氧气体转化之强氧化剂去除,此时的水中臭氧浓度只有0.008mg/L。
再进一步
经过复合过滤装置处理后的水体,由设于装置下部侧面的排水口排出,再进入紫外线杀菌装置,采用的紫外线辐射强度为2600——3000UW/cm2,波长为235——258nm,照射时间为4S,水体经过紫外线杀菌后,整个污水处理过程已完成,不但水质符合工业回用水标准,作为餐厨垃圾资源化处理的生产用水,且对污水的处理快速而可靠,每小时生产回用水约为5吨。
现在陈述于污水处理中的污泥处理具体实施方式案例:
17、将生产中产生的污水和厂区生活污水在污水处理过程中产生的脱水污泥置于污泥储存器中24小时,利用在污泥中自然产生的自然生存的或死体微生物作为成孔剂或称为成孔模块,当将污泥储存器中的污泥取出后投放到臭氧处理器中,对微生物进行人工强制灭活,采用的方式为:将污泥于处理器中自上而下与臭氧逆向循环接触,时间为2min,臭氧处理器的臭氧浓度为12g/L,,臭氧气体流速为7L/min,臭氧的溢出尾气由专用设备收集处理。
进一步
将已经过强制灭活的污泥由自动输送设备送入初级固化设备中,该设备以卧式多层重叠的螺带组成,当泥泥被投入到固化设备中后,由自动定量加料器加入污泥重量10%的氧化钙,实行均匀混合,混合时间为25min,经混合的污泥被固化或半固化,成颗粒体。
再进一步
将已成颗粒体的污泥从混合器的底部排出,由螺带输送设备不间断地送达气动推进设备中,并由此输送系统迅速将颗粒体污泥送入反应釜,此时的反应釜内温度为100℃,已跃过甲烷菌的75℃以下的生存条件区。当污泥按设定的重量全部进入反应釜内后,气动推进设备由导轨的引导下自动离开反应釜进料口,此时反应釜的进料口同时被密封关闭,反应釜的提温速度调整为每30min30℃,于釜内压力达到0.6mpa时,反应釜的尾端单向气阀自动开启,并将气体通过安全水封装置后,进入尾气环保处理系统,当反应釜内的温度达到160℃时,污泥的结构被破坏,污泥的结晶水被加快释出,成为水气被引出釜内尾端,并通过单向气阀被排出进入水封器。当反应釜温度达到220℃时,已死亡的微生物出现碳化,至此釜内温度继续提升到240℃时,微生物的细胞基质溶胶向泥体外溢并焦结收缩,污泥颗粒基本形成多表型的微孔穴和孔道。此时,反应釜内温度进入恒温状态,保持恒温一小时,但为了防止污泥进入热解,釜内终温设定不能高于260℃。于恒温期间,釜内的污泥颗粒内水分基本已脱出,污泥的成孔率巩固。
再进一步
经过绝氧热化的污泥降温后从反应釜的自动排料口排出,被自动输送工具送入待加工库实行自然陈化,陈化时间为48小时,此后,再将污泥送入酸化反应器,于20%浓度的液体硫酸中进行静态浸泡14小时,对微生物死亡体的焦结进行清除,并同时除去污泥中的金属杂质离子,以及作用于氢离子替代污泥团固化时添加剂中的钙离子。污泥颗粒于此工序中基本完全暴露颗粒的孔穴结构骨架。
再进一步
将经过酸化后的污泥颗粒,从反应器的出料口排出后进入水漂,水漂的水温条件为80℃,并于此时调整PH值,通过水漂的颗粒物再由输送器送入热蒸气活化房,进行初步的物理活化阶段,蒸汽流量为250ml/min,活化时间2小时。
再进一步
通过物理活化工序的污泥颗粒物,再进入高温管道式电热炉中进行高温活化,在隔绝空气条件下进行,溢出的热气由尾气环保处理系统处理,活化炉的提温速度20℃/min,活化温度为720℃,活化时间为2小时,活化工序完成后,污泥颗粒经过降温,输出后通过细化,成为杂化荷电吸附剂的基核材料,其孔穴和孔道结构为无定形结构,孔径和孔容积及孔洞形式、孔道大小与长短均是以附存于污泥中的各类微生物体的种类形态和数量来自然恒定,每克成品的孔穴约在1——1.5亿之间,孔穴直径约在0.8——1.2um,孔道长约在2——5um,宽约在0.3——0.4um之间。
再进一步
采用酸性铝溶胶和硅溶胶调配至一定的稀释度,其中铝溶胶60%,硅溶胶40%,将上述所制造成的基核材料混合于两种混合溶胶中,其重量比为78%:20%,然后取出混合物放入高温管式电阻炉中,在650℃的条件下,恒温一小时,待工序结束降温后取出进行细化,制造成内核为非极性吸附剂外层为铝硅骨架介质网络极性吸附剂所合成的多功能杂化荷电吸附剂材料,该吸附剂品质优良,机械强度好,使用寿命长,孔径分布很宽,对各种无机和有机气体、水溶液中的有机物及重金属离子等具有较大的吸附容量和较快的吸附速率,该种以污泥制成的成品,于本具体实施方式案例中作用于污水处理系统的复合过滤装置的滤柱中应用,以及在气味处理的气味毁灭器中应用。
现在陈述尾气环保处理系统具体实施方式案例:
18、首先将裂解炉的热源烟气、导热流炉的热源烟气、旋转干燥装置的热源烟气、生化装置的水蒸汽、高温活化炉的灼热气体、蒸汽活化床的热水蒸汽、饲料生产中所产生的干尘空气等由多根管道组成的尾气输送系统,随两级引风器的作用下进入水封式烟气缓冲室。此时,烟气从水下150mm处输入后,再于水体中从下而上跃出,此一动作使多道不同压力、不同风速和空气流量的烟气于跃出水面后,形成同等条件均匀混合烟气。此烟气在后级引风器的作用下,流夹带着碳微粒及其它物质的固体微粒,进入负离子与水幕的处理通道,并高速撞向能自然释放负离子电荷的陶瓷高速水幕区,于上、左、右错位安装的带凹钝角导流板导向下,产生瞬间气流轨迹方向改变,此时,此烟气中密度大的固体尘粒的运动方向在负离子区内下不随气体方向流动,且落于安装于管道下部的水滴混合器中,并随水体进入系统中的水固混合管道,而烟、水蒸汽进入另一缓冲室后,烟、水蒸汽再次被设于缓冲室内的双层水帘冲洗及降温,以此来防止热烟气带着尚存的碳粒子对后级设备引发破坏性的热冲击力。烟气于缓冲室内有效降温后,直接通过连接管道进入双塔形立式气固分离器,烟气受到两个分离器内的回旋喷雾喷嘴所喷出的弱碱性水对烟气作顺逆方向的两次大面积冲洗,以此起到除去还随于烟气中的微小固体物质和对烟气脱硫,经过弱碱性水清洗的水蒸汽由设于双塔上部的排气口进入气、水输送管道,而微小固体物质随水体于双塔下部的排水口进入气、水输送管道。
再进一步
进入气、水输送管道的热水蒸汽在管道内的上层,进入烟气排放系统,而进入气、水输送管道的水体和微固体物质在管道内的下层,同样也进入烟气排放系统,该排放系统分为上、中、下三部分组成,当水体与热水蒸汽进入系统的下部时,水体与微小固体物质直接通过系统底部的出水口进入三级滤池,而热水蒸汽即从下部上升至系统中部,进入设于中部的热交换器内,被液化的水体落入下部的水体排出口,进入三级滤池,而不可液化的气体继续上升,进入系统的上部气体排出口被排出,此时所排出的尾气温度不高于38℃,属无室温气体排放,且排放的气体无异味和碳粒,无黑烟。
现在陈述生产现场的空气集中式空气处理具体实施方式案例(等离子光触媒负离子空气除臭杀菌装置):
19、将生化处理工序前端的各工序和设备与设备的连接口所有可能会产生异味的位置,安装排气管道,同时在生产车间的四侧也安装排气管道,当异味空气通过排气管道后级的引风器,将含异味的空气导入排气管前端的波纹负离子区,该区的负离子含量为15000个/cm3,当含异味的空气从波纹层叠的8mm隔距通过后,再进入等离子处理区,并继续通过排气管直接进入光催化区,在光催化作用下的反应过程中,利用空气中的表面水份和氧气作为氧化剂,空气中的异味已被完全氧化成无毒无害的物质,而空气在设于光催化区后级的1500m3/h的引风器作用下,导入设于空气排出口前端,负离子释放量为15000个/cm3的波纹负离子区后排出,所排出的空气是干净而无异味的空气。
现在陈述中央智能化控制操作具体实施方式案例:
20、本具体实施案例的中央智能化控制操作系统为公知技术,其具体实施是设立一个中央智能控制室,室内有中控操作平台,大型显示屏幕作为人机界面,于各个现场设备的生产线上和气体排放口分别布置控制控制柜。其中央控制室操作平台作全线监控中心,并从主屏幕观察整线工作状况,并通过电脑组态画面与实时操作同步,监察显示流体动态和电机运转状态,也可按照生产过程出现的变化状况作出及时的数据调整,在中央控制系统中还作出现场控制,随时可以单独启动系统中的其中某个环节,在整个餐厨垃圾资源化处理中的主生产区可以实现无人值守状态。

Claims (124)

  1. 一种餐厨垃圾全方位综合处理系统,其特征是:所述的系统包括餐厨垃圾破袋装置、餐厨垃圾联合筛选装置、湿式高级氧化除臭灭活清洗降盐装置、立式脱水装置、物料破碎机和自动控制装置,餐厨垃圾投入餐厨垃圾破袋装置进行破袋处理,然后输入至餐厨垃圾联合筛选装置进行联合筛选,经筛选后的油水固混合物输入至湿式高级氧化除臭灭活清洗降盐装置进行灭活处理,通过湿式高级氧化已灭活除臭除盐初级脱水的餐厨垃圾由螺旋杆输送管道送入脱水装置,经脱水装置脱水后的物料输入物料破碎机进行粉碎,自动控制装置控制其他装置工作。
  2. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的割破装置包括卧式筒状外壳(D11),外壳(D11)一端为出料口(D18),外壳(D11)于出料口(D18)的一端内壁设有固定一个以上的刀具(D12),外壳(D11)另一端内设有能够沿着外壳(D11)内腔滑动的活塞(D13),并连接有推动活塞(D13)运动的动力工具(D12),活塞(D13)上对应于每个刀具(D12)位置处开设有一个刀槽(D14),外壳(D11)顶部中间位置开有进料口(D21)。
  3. 根据权利要求2所述的餐厨垃圾全方位综合处理系统,其特征是:所述的活塞(D13)底部安装有滑轮(D15),外壳(D11)内壁底部对应于滑轮(D15)位置处固定设有凹形滑轨(D17),滑轮(D15)能够在凹形滑轨(D17)上来回滑动。
  4. 根据权利要求2所述的餐厨垃圾全方位综合处理系统,其特征是:所述的进料口(D21)位置处安装有收集箱(D19),收集箱(D19)上部呈漏斗形,下部通过下料管道(D20)与外壳(D11)上的进料口(D21)连通,下料管道(D20)上设有气动滑板闸阀(D27)。
  5. 根据权利要求2或3或4所述的餐厨垃圾全方位综合处理系统,其特征是:所述的外壳(D11)上的出料口(D18)位置处安装有滚动拍板(D22),电机(D28)带动滚动拍板(D22)转动。
  6. 根据权利要求5所述的餐厨垃圾全方位综合处理系统,其特征是:所述的滚动拍板(D22)呈方形或多边形并设有内腔。
  7. 根据权利要求6所述的餐厨垃圾全方位综合处理系统,其特征是:所述的滚动拍板(D22)每个面上设有一个以上的压缩空气射出槽(D23),滚动拍板(D22)内设有压缩空气导气管(D24和气体喷射嘴(D23),气体喷射嘴(D26)连接在压缩空气导气管(D24)上,气体喷射嘴(D26)的射流方向与出料口的出料方向相同。
  8. 根据权利要求7所述的餐厨垃圾全方位综合处理系统,其特征是:所述的压缩空气射出槽(D23)平行设置。
  9. 根据权利要求2或3或4所述的餐厨垃圾全方位综合处理系统,其特征是:所述的刀具(D16)的刀锋与外壳出料口横截面呈90度角或与外壳内壁呈30度角。
  10. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的餐厨垃圾联合筛选系统包括壳体(E11),壳体(E11)内设有分隔板(E25),通过分隔板(E25)将壳体(E11)内部分为气浮区(E10)和非气浮区(E32),分隔板(E25)上设有物料漏出口(E26),气浮区(E10)处设有进料口,气浮区(E10)下部设有重物料卸出口(E22),重物料卸出口(E22)处设有阀门(E23),重物料卸出口(E22)四周设有一个以上的空气喷嘴(E24),气浮区(E10)上部设有滚耙(E30),非气浮区(E32)内设有物料输出器(E33),物料输出器(E33)一端设置在壳体(E11)内,另一端设置在壳体(E11)外侧,物料输出器(E33)内设有搅龙(E37),物料输出器(E33)上安装有电机(E36)和变速器(E34),电机(E33)配合变速器带动搅龙(E37)转动。
  11. 根据权利要求10所述的餐厨垃圾全方位综合处理系统,其特征是:所述的物料漏出口(E26)处设有百叶导槽(E27),百叶导槽(E27)连接在气动推进拉杆(E28)上,气动装置(E38)驱动推进拉杆(E28)运动,并由推进拉杆(E28)控制百叶导槽(E27)的开启与闭合。
  12. 根据权利要求10所述的餐厨垃圾全方位综合处理系统,其特征是:所述的滚耙(E30)设有两个,两个滚耙(E30)一上一下设置,下面的滚耙的1/2设置在气浮区(E10)的液面内,上面的滚耙设置在气浮区(E10)的液面上方,两个滚耙(E30)相互啮合。
  13. 根据权利要求12所述的餐厨垃圾全方位综合处理系统,其特征是:所述的壳体(E11)上安装有滚耙电机(E39),滚耙电机(E39)同时带动两个滚耙(E30)转动。
  14. 根据权利要求10至13中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的物料输出器(E33)处安装有变速器(E34),电机(E36)通过变速器(E34)驱动搅龙(E37)转动。
  15. 根据权利要求10至13中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的气浮区(E10)处安装有用于控制液面高度的液面高度自动控制装置(E29)。
  16. 根据权利要求10至13中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的壳体(E11)上设有用于向壳体(E11)内输送餐厨垃圾的管道,该管道连接在进水管道(E20)上。
  17. 根据权利要求10至13中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的气浮区(E10)的循环水进水口连接水力加压泵(E21),水源由循环储水箱提供,非气浮区(E32)的中下部设有出水口,并通过水泵将水体输入循环储水箱内,用于气浮区(E10)与非气浮区(E32)水体的循环和加强气浮区(E10)内的水体强力翻滚。
  18. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的餐厨垃圾氧化、除臭、灭活、清洗降盐装置包括一个以上的反应器(F34)和用于臭氧——水——物料混合的气、水、物混合器(F42),混合器(F42)上连接有防水单向阀,防水单向阀的一端连接输气管后,再连接臭氧发生设备(F44),混合器(F42)上还连接有高粘度凸轮转子泵(F49)出口,混合器(F42)的出口伸入一个反应器(F34)内,高粘度凸轮转子泵(F49)的入口与另一个反应器(F34)连接,反应器(F34)内设有一个以上的颗粒活性碳反应球(F41),颗粒活性碳反应球(F41)内设有颗粒活性碳,反应器(F34)底部设有物料出口。
  19. 根据权利要求18所述的餐厨垃圾全方位综合处理系统,其特征是:所述的颗粒活性碳的总体积占颗粒活性碳反应球(F41)球体内腔体积的15%——98%。
  20. 根据权利要求18所述的餐厨垃圾全方位综合处理系统,其特征是:所述的反应器(F34)顶部设有自动排气阀(F38),自动排气阀(F38)上连接有臭氧毁灭器(F39)。
  21. 根据权利要求18或19或20所述的餐厨垃圾全方位综合处理系统,其特征是:所述的反应器(F34)底部设有半圆封头(F35),物料出口设置在半圆封头(F35)上。
  22. 根据权利要求18或19或20所述的餐厨垃圾全方位综合处理系统,其特征是:所述的反应器(F34)中最前端的反应器(F34)上设有斜面螺带输送器(F36),而后端的反应器(F34)上设有水位高度调节管道。
  23. 根据权利要求18或19或20所述的餐厨垃圾全方位综合处理系统,其特征是:所述的物料出口处连接有固、液分离器。
  24. 根据权利要求23所述的餐厨垃圾全方位综合处理系统,其特征是:所述的固、液分离器包括外壳(F45)和倾斜网状桶体(F52),倾斜网状桶体(F52)设置在外壳(F45)内,倾斜网状桶体(F52)由电机配合变速器带动转动,倾斜网状桶体(F52)前端设有一排以上的网孔,倾斜网状桶体(F52)内设有连接于网状桶体内壁的螺旋状的螺带,外壳(F45)底部设有接水器(F47)。
  25. 根据权利要求24所述的餐厨垃圾全方位综合处理系统,其特征是:所述的螺旋状的螺带占倾斜网状桶体(F52)的全长。
  26. 根据权利要求24所述的餐厨垃圾全方位综合处理系统,其特征是:所述的外壳(F45)上装有视窗(F46)。
  27. 根据权利要求18或19或20所述的餐厨垃圾全方位综合处理系统,其特征是:所述的反应器(F34)侧面装有人孔。
  28. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的立式脱水装置包括外壳(G49)、立式内漏塔(G50)和螺带推进杆(G51),立式内漏塔(G50)设置在外壳(G49)内部,螺带推进杆(G51)设置在立式内漏塔(G50)内部,立式内漏塔(G50)侧面开有一个以上的漏水孔(G58),立式内漏塔(G50)底部设有进料口(G62),立式内漏塔(G50)顶部设有出料口(G60),外壳(G49)底部安装有驱动螺带推进杆(G51)转动的动力源,外壳(G49)内部对应于立式内漏塔(G50)底部四周设有接水槽(G55),接水槽(G55)上连接有出水口(G63)。
  29. 根据权利要求28所述的餐厨垃圾全方位综合处理系统,其特征是:所述的外壳(G49)内部,立式内漏塔(G50)四周设有一条以上的水管(G65),每条水管(G65)上连接有一个以上的高压水反冲喷嘴(G53)。
  30. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的立式内漏塔(G50)顶部装有安装螺带推进杆(G51)的轴心固定板(G61)。
  31. 根据权利要求30所述的餐厨垃圾全方位综合处理系统,其特征是:所述的螺带推进杆(G51)上的螺带尾端装有调节出料速度的封口板。
  32. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的螺带推进杆(G51)上的螺带的间距为由下部渐步往塔顶收窄。
  33. 根据权利要求32所述的餐厨垃圾全方位综合处理系统,其特征是:所述的螺带推进杆(G51)上的螺带下端的间距为25CM,终端的间距为10CM。
  34. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的动力源包括电机(G54)、变速器(G64)和将水平轴向转动转为竖直轴向转动的转向变换装置(G66),电机(G54)带动变速器(G64)转动,变速器(G64)带动转向变换装置(G66)转动,转向变换装置(G66)带动螺带推进杆(G51)转动。
  35. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的外壳(G49)内设有不锈钢支承套(G56)。
  36. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的立式内漏塔(G49)外侧四周设有一条以上的不锈钢立板(G56),不锈钢立板(G56)的周围装有一根以上的加固圈套,每根加固圆圈上装有斜面防反冲导流檐。
  37. 根据权利要求28或29所述的餐厨垃圾全方位综合处理系统,其特征是:所述的立式内漏塔(G49)由一个以上的塔体组成,每个塔体的上下圆周位置装有加强法兰,且相邻塔体的连接均是塔体上下的法兰之间对接,并采用螺栓固定,每个塔体的连接法兰位置上的上层法兰装有斜面防反冲导流檐。
  38. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的生化发酵装置包括厌氧发酵池(I65)和主发酵装置(I70),所述的主发酵装置(I70)包括两个副发酵器(I71)和一个以上的主发酵器,两个副发酵器(I71)设置在主发酵器上方,副发酵器(I71)与主发酵器连接处设有进料口(I84),主发酵装置外设有用于将物料输入至副发酵器(I71)内的物料提升机(I64),副发酵器(I71)内设有搅拌设备(I73),主发酵器内设有双层螺带搅拌器(I78),厌氧发酵池(I65)与主发酵器连接,厌氧发酵池(I65)通过自动卸料系统(I67)将物料投入主发酵器内。
  39. 根据权利要求38所述的餐厨垃圾全方位综合处理系统,其特征是:所述的双层螺带搅拌器(I78)包括轴体、内层螺带和外侧螺带,内层螺带设置在外层螺带内部,内层螺带和外层螺带均呈螺旋形带状,且分别固定安装在轴体上,内层螺带和外层螺带的螺旋方向相反,双层螺带搅拌器(I78)的轴体周边加装铧叶片(I79)。
  40. 根据权利要求38或39所述的餐厨垃圾全方位综合处理系统,其特征是:所述的搅拌设备(I73)中间为一个主轴,中轴上固定安装有一个以上的搅拌叶片。
  41. 根据权利要求38或39所述的餐厨垃圾全方位综合处理系统,其特征是:所述的厌氧发酵池(I65)内上方设有可自动移动的物料搅拌器(I68)。
  42. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的自动卸料多级干燥装置包括预干燥设备(J93)和主干燥设备,预干燥设备(J93)安装于主干燥设上方,预干燥设备(J93)外壳呈两侧,两侧之间形成预干燥设备的外壳夹层内腔(J97),预干燥设备(J93)内设有物料自动翻板(J94),主干燥设备中间为能够360度逆顺方向旋转的卧式圆筒形体(J102),主干燥设备前、后两端分别为固定封头(J101),卧式圆筒形体(J102)内设有一个以上的与卧式圆筒形体(J102)固定安装在一起的副筒体,卧式圆筒形体(J102)和各个副筒体内部均设有导料螺带,主干燥设备上设有气体或液态燃料燃烧室(J99)和燃烧器(J100),燃烧器(J100)产生的热量通入主干燥设备内部,主干燥设备的尾气通过热空气排出口(J107)输入至外壳夹层内腔(J97)内,预干燥设备(J93)的物料输出口对应于主干燥设备最内侧副筒体设置。
  43. 根据权利要求42所述的餐厨垃圾全方位综合处理系统,其特征是:所述的预干燥设备(J93)底部设有螺带搅龙自动出料器(J95),螺带搅龙自动出料器(J95)呈筒状,内部设有螺带搅龙。
  44. 根据权利要求42所述的餐厨垃圾全方位综合处理系统,其特征是:所述的预干燥设备(J93)顶部设有引风设备(J98)。
  45. 根据权利要求42或43或44所述的餐厨垃圾全方位综合处理系统,其特征是:所述的各个副筒体套装在一起,外侧副筒体的物料入口长于内层副筒体的物料出口。
  46. 根据权利要求42或43或44所述的餐厨垃圾全方位综合处理系统,其特征是:所述的各个副筒体的外侧壁上固定安装有气流扰动翅(J103)。
  47. 根据权利要求42或43或44所述的餐厨垃圾全方位综合处理系统,其特征是:所述的卧式圆筒形体(J102)和各个副筒体内部的导料螺带方向相反。
  48. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的物料精选装置包括底座(K108)、金属滚动筛网筒(K110)、物料承载器(K113)、自动输送工具(K114)、链板输送机(K115)和分流闸板(K116),金属滚动筛网筒(K110)安装在底座(K108)上,物料承载器(K113)设置在金属滚动筛网筒(K110)下方,自动输送工具(K114)设置在物料承载器(K113)下方,金属滚动筛网筒(K110)前端设有筛网孔,后端设有螺带,链板输送机(K115)设置在金属滚动筛网筒(K110)出料口下方,分流闸板(K116)设置在链板输送机(K115)尾端。
  49. 根据权利要求48所述的餐厨垃圾全方位综合处理系统,其特征是:所述的筛网孔直径为4mm——6mm,孔与孔这间间隔为2mm。
  50. 根据权利要求48所述的餐厨垃圾全方位综合处理系统,其特征是:所述的金属滚动筛网筒(K110)倾斜设置,倾斜角度为1度——20度。
  51. 根据权利要求48或49或50所述的餐厨垃圾全方位综合处理系统,其特征是:所述的分流闸板(K116)处设有用于调节分流闸板(K116)与链板输送机(K115)之间高度的调节装置,分流闸的一侧装有气动拨料器。
  52. 根据权利要求48或49或50所述的餐厨垃圾全方位综合处理系统,其特征是:所述的金属滚动筛网筒(K110)外侧安装有保护罩(K109)。
  53. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的餐厨垃圾联合筛选装置设有塑料固体输出端,餐厨垃圾联合筛选装置的塑料固体输出端连接有废塑料逆转工程装置。
  54. 根据权利要求53所述的餐厨垃圾全方位综合处理系统,其特征是:所述的废塑料逆转工程装置主要摆阔主体处理装置,主体处理装置由输送带(M122)将物料送入气压式自动进料机(M123),通过气压式自动进料机(M123)将物料送入裂解催化卧式反应釜(M124)内,反应釜(M124)能够作360度顺、逆旋转,反应釜(M124)内带有自动随机刮壁装置(M125),反应釜(M124)上连接有后级真空系统(M130),反应釜(M124)通过管道与油腊分离器(M129)连接,管道上设有单向阀(M128),油腊分离器(M129)通过管道连接有第一级重油分离器(M131),第一级重油分离器(M131)通过管道连接有第一级冷凝器(M132),第一级冷凝器(M132)底部连接有油料承载容器(M133),第一级冷凝器(M132)后端连接有负压设备(M134),负压设备(M134)后端连接有立式水封式气体安全输送器(M135),立式水封式气体安全输送器(M135)后端连接有二级燃气压缩机(M136),二级燃气压缩机(M136)与燃气贮存库(M137)连接。
  55. 根据权利要求54所述的餐厨垃圾全方位综合处理系统,其特征是:所述的反应釜(M124)底部设有裂解炉(M126),裂解炉(M126)的出气口管道连接尾气环保装备系统(M127)。
  56. 根据权利要求54所述的餐厨垃圾全方位综合处理系统,其特征是:所述的油料承载容器(M133)连接有除碳精漂器(M139)和脱腊除胶器(M140)。
  57. 根据权利要求53所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括粗炭黑处理装置,粗炭黑处理装置连接在废塑料逆转工程装置的余渣输出口处。
  58. 根据权利要求57所述的餐厨垃圾全方位综合处理系统,其特征是:所述的粗炭黑处理装置包括粗炭黑人工陈化处理器(N144),粗炭黑人工陈化处理器(N144)与物理陈化床(N145)连接,物理陈化床(N145)通过自动输送工具与物料配伍设备(N146)连接,物料配伍设备(N146)上连接有液、固自动定量加料加料设备(N147),物料配伍设备(N146)后端设有多层推拉式螺杆(N148),多层推拉式螺杆(N148)后端与低硫高能环保清洁燃煤成形机(N149)连接。
  59. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括免蒸馏法生物柴油生产装置,各个装置通过管道将油、水、固混合体先经过油水分离,再送入免蒸馏法生物柴油生产装置。
  60. 根据权利要求59所述的餐厨垃圾全方位综合处理系统,其特征是:所述的免蒸馏法生物柴油生产系统包括卧式螺带固液分离设备(O151)、油水分离塔(O152)、储油容器(O149)、油脂胶质脱除设备(O158)、生物油常温脂交换设备(O161)、分液设备(O172)和过滤设备(O173),卧式螺带固液分离设备(O151)的出口通过管道连接至油水分离塔(O152)中下端,油水分离塔(O152)内设有加热管道(O153),加热管道(O153)从油水分离塔(O152)下部伸入至油水分离塔(O152)内部,再从油水分离塔(O152)中上部输出至油水分离塔(O152)外侧,油水分离塔(O152)顶部设有刮油器(O155),油水分离塔(O152)通过出油管道(O156)与储油容器(O149)连接,出油管道(O156)入口对应于刮油器(O155)设置,储油容器(O149)通过管道与油脂胶质脱除设备(O158)连通,油脂胶质脱除设备(O158)内部设有固定设置有孔洞撞击板(O159),撞击板(O159)的两侧对应位置分别安装有旋浆式水力推进机(O160),旋浆式水力推进机(O160)的螺旋桨扇叶设置在油脂胶质脱除设备(O158)内,电机设置在油脂胶质脱除设备(O158)外侧,电机驱动螺旋桨扇叶转动,油脂胶质脱除设备(O158)下部设有油脂出口,油脂出口通过管道连通至生物油常温脂交换设备(O161)内,生物油常温脂交换设备(O161)内设有一个以上的超声波发生器(O162),生物油常温脂交换设备(O161)顶部开有投料口(O169),生物油常温脂交换设备(O161)底部通过管道连通至分液设备(O172),分液设备(O172)底部通过输油管道连接至过滤设备(O173),过滤设备(O173)输出生物柴油。
  61. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的卧式螺带固液分离设备(O151)包括有一个卧式圆筒形外壳,外壳内设有滤网,滤网内部固定设有输送螺带,螺带驱动电机配合变速器带动滤网及螺带转动,卧式螺带固液分离设备(O151)底部设有油、水混合体输出管道。
  62. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的油水分离塔(O152)的顶部装有红外线水体液面定位仪(O154)。
  63. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的超声波发生器(O162)外围分别装有套管(O163),套管(O163)四周开有内螺纹射流孔(O164),套管(O163)上方固定设有卡定器(O165),通过卡定器(O165)将超声波发生器(O162)安装在生物油常温脂交换设备(O161)内部。
  64. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的生物油常温脂交换设备(O161)内装有液体导流管(O166),液体导流管(O166)一端连接在生物油常温脂交换设备(O161)上部,另一端连接在生物油常温脂交换设备(O161)底部,液体导流管(O166)上连接有泵具(O167)。
  65. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的生物油常温脂交换设备(O161)底部设有鼓气管(O171),鼓气管(O171)的一端连接压缩空气机。
  66. 根据权利要求60所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括油脂胶质脱除设备,由专用油泵将生物油脂从储油容器输入油脂胶质脱除设备之后在进入脂交换设备。
  67. 根据权利要求66所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括制造乳化生物柴油装置,经脂交换工艺出来的生物油脂输出至制造乳化生物柴油装置。
  68. 根据权利要求67所述的餐厨垃圾全方位综合处理系统,其特征是:所述的乳化生物柴油的制作装置包括壳体(P174),壳体(P174)内装有垂直搅拌器(P175),动力源带动垂直搅拌器(P175)转动,垂直搅拌器(P175)的中轴上装有一个以上的浆式平直搅拌浆(P178)或桨式折叶桨,垂直搅拌器(P175)的中轴下部安装有涡轮或圆盘弯叶浆(P179),壳体(P174)内的上部装有富氧水雾化喷嘴(P185),壳体(P174)的顶部设置有一个以上的进料口(P181),每个进料口(P181)均通过管道连接有一个定量加料设备(P182),壳体(P174)中上部一侧设有油品进料口(P192),并由管道连接于油品输送泵,壳体(P174)上部装有进水管道(P186)并连接高压泵(P187),进水管道(P186)的水源由富氧水储备箱(P191)提供,而富氧水由臭氧发生器(P188)输出O3气体,并通过气体输送管道进入强力气水混合器(P189)与通过管道(P190)进入水体混合后进入富氧水储备箱(P191),壳体(P174)下部设置有成品出料口(P184)。
  69. 根据权利要求68所述的餐厨垃圾全方位综合处理系统,其特征是:所述的壳体(P174)上部为圆筒形,下部呈半圆形。
  70. 根据权利要求69所述的餐厨垃圾全方位综合处理系统,其特征是:所述的壳体(P174)的圆筒形内壁四周安装一个以上的液体导流叶板(P183)。
  71. 根据权利要求69所述的餐厨垃圾全方位综合处理系统,其特征是:所述的壳体(P174)底部安装有支撑垂直搅拌器(P175)的转轴用的支承架(P180)。
  72. 根据权利要求68至71所述的餐厨垃圾全方位综合处理系统,其特征是:所述的动力源包括电机(P176)和变速设备(P177),变速设备(P177)固定安装在壳体(P174)顶部,电机(P176)设置在变速设备(P177)上方,电机(P176)通过变速设备(P177)驱动垂直搅拌器(P175)转动。
  73. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统中还包括快速污水处理回用装置,各个装置产生的污水通过管道连接至快速污水处理回用装置。
  74. 根据权利要求73所述的餐厨垃圾全方位综合处理系统,其特征是:所述的快速污水处理回用装置包括污水过滤池(Q185),污水过滤池(Q185)内设置有杂物拦栅(Q186),杂物拦栅(Q186)内设有防塞反冲器(Q187),污水过滤池(Q185)通过进水管道与灼热毡污水处理设备(Q188)连接,灼热毡污水处理设备(Q188)包括内腔(Q189)和机壳(Q190),机壳(Q190)顶部设有多个与进水管相通的雾化喷射头(Q192),雾化喷射头(Q192)下方设有一个灼热毡(Q193),灼热毡(Q193)内设有导热油管道(Q195),灼热毡(Q193)下方的底部设有微固物沉淀区(Q196),微固物沉淀区(Q196)底部设有排污口(Q197),排污口(Q19)7上方设有防污反冲挡板(Q198),灼热毡(Q193)下方装有用于支撑灼热毡(Q193)的耐高温垫层(Q199),机壳(Q190)的顶部开有自动吸排气阀(Q200),机壳(Q190)位于灼热毡(Q193)的上方开有热蒸汽收集口(Q201),热蒸汽收集口(Q201)通过管道与热交换器(Q202)相连,热交换器(Q202)后端连接有集水池(Q203),集水池(Q203)通过管段与高级氧化系统(Q204)连接,高级氧化系统(Q204)具有内外两层空腔,内腔为气水反应腔(Q205),外腔为气水循环反应缓冲腔(Q206),内腔进水口引入管的端部装有活性碳反应球(Q209),活性碳反应球(Q209)内装有颗粒活性碳,内腔底部设有排污口(Q212),排污口(Q212)与外壳的排污口(Q213)相连,内腔的排污口(Q212)上还安装防反冲档板(Q214),高级氧化反应器通过循环管道连接有气水混合器(Q215),气水混合器(Q215)为三通接法,两端接通循环水,而中间的一个端口连接防水单向阀(Q216),防水单向阀Q216的另一接口连通臭氧发生器的输气管道,高级氧化系统(Q204)连接有中转水池(Q218),与中转水池(Q218)连接有活性炭过滤固定床(Q219),活性炭过滤固定床(Q219)上连接有复合过滤设备(Q220),复合过滤设备(Q220)包括一个以上的过滤罐(Q221), 过滤罐(Q221) 内分别设有一支以上的立式过滤柱(Q222),每支过滤柱(Q222)长度的一半位置处开有出水孔,过滤柱(Q222)的底部装有80——140目的滤网,过滤罐(Q221)的顶部有进水口(Q223)和加压管(Q224),过滤罐(Q221) 罐体内分为二层,每层的罐内分别装有过滤柱托板(Q226),过滤柱托板(Q226)上开有与过滤柱(Q222)直径相配的孔口,过滤柱(Q222)插装在过滤柱托板(Q226)内,上层罐体的上部一侧安装进水导流管道(Q228),进水导流管道(Q228)通向下层罐体的上部,上层罐体的下部一侧安装出水导流管道(Q229),出水导流管道(Q229)通向下层罐体的下部,罐体的上、下层一侧分别安装有排气口(Q230),过滤罐(Q221)的出水口设于复合过滤设备(Q220)底部封头的一侧(Q233),底部封头的中心位置设有沉淀物排出口(Q234)。
  75. 根据权利要求74所述的餐厨垃圾全方位综合处理系统,其特征是:所述的灼热毡(Q193)表面设有多道流水浅沟(Q194)。
  76. 根据权利要求74所述的餐厨垃圾全方位综合处理系统,其特征是:所述的内腔顶部安装有自动排气阀(Q207)和用于监控液面高度的液面控制在线监控器(Q208)。
  77. 根据权利要求74所述的餐厨垃圾全方位综合处理系统,其特征是:所述的活性碳反应球(Q209)上部不透水,下部为网状出水口(Q210)。
  78. 根据权利要求74所述的餐厨垃圾全方位综合处理系统,其特征是:所述的活性碳反应球(Q209)内的颗粒活性碳体积占反应球内腔体积的15%——95%。
  79. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括对剩余固体污泥处理的杂化荷电吸附剂生产装置,各个工段产生的污泥都输入至杂化荷电吸附剂生产装置。
  80. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括对各个工序中所产生的烟气、热烟气、粉尘等集中处理的尾气环保处理装置。
  81. 根据权利要求80所述的餐厨垃圾全方位综合处理系统,其特征是:所述的包括尾气缓冲装置、水固分离器(S257)、双塔式旋转喷淋系统(S259)和烟气排放设备(S264),所述的空气缓冲器(S247)和初级烟气处理管道(S253),尾气通入空气缓冲器(S247)内,通过空气缓冲器(S247)输入到初级烟气处理管道(S253)内,经初级烟气处理管道(S253)排入至水固分离器(S257)内,水固分离器(S257)出口通入双塔式旋转喷淋系统(S259)内,经双塔式旋转喷淋系统(S259)处理后输入至烟气排放设备(S264)内,再经烟气排放设备(S264)处理后排出。
  82. 根据权利要求81所述的餐厨垃圾全方位综合处理系统,其特征是:所述的空气缓冲器(S247)包括圆筒形外壳,外壳内上方设有一个以上的水帘喷射口(S272),外壳底部装有排污口(S249)。
  83. 根据权利要求81所述的餐厨垃圾全方位综合处理系统,其特征是:所述的尾气缓冲装置(S253)外壳周边开有一个以上的尾气进气口。
  84. 根据权利要求82所述的餐厨垃圾全方位综合处理系统,其特征是:所述的尾气缓冲装置还包括有储水箱,排污口(S249)通过管段连接至储水箱内。
  85. 根据权利要求84所述的餐厨垃圾全方位综合处理系统,其特征是:所述的循环水管段通过水阀(S250)连接至储水箱上部,储水箱中、下部通过泵具和管段连接至空气缓冲器(S247)内的水帘喷淋器。
  86. 根据权利要求82或83或84或85所述的餐厨垃圾全方位综合处理系统,其特征是:所述的空气缓冲器(S247)内部上方还安装有用于检测空气缓冲器(S247)内部液面高度的在线液面监控器(S251)。
  87. 根据权利要求81或82或83或84或85所述的餐厨垃圾全方位综合处理系统,其特征是:所述的初级烟气处理管道(S253)内设有一个以上的负离子荷电陶瓷(S254),该陶瓷件无须电源,能自然释放负离子,每个负离子荷电陶瓷(S254)后端对应安装有一个高速水雾区喷头(S255)。
  88. 根据权利要求87所述的餐厨垃圾全方位综合处理系统,其特征是:所述的每个高速水雾区喷头(S255)后端安装有一个导流板(S256)。
  89. 根据权利要求88所述的餐厨垃圾全方位综合处理系统,其特征是:所述的导流板(S256)采用钝角导流板。
  90. 根据权利要求87所述的餐厨垃圾全方位综合处理系统,其特征是:所述的负离子荷电陶瓷(S254)安装在初级烟气处理管道(S253)内的左、右、上三面上。
  91. 根据权利要求81或82或83或84或85所述的餐厨垃圾全方位综合处理系统,其特征是:所述的尾气处理系统还包括冷却塔(S269),冷却塔(S269)对烟气排放设备(S264)中的热交换器(S266)内的热水气进行冷却。
  92. 根据权利要求1所述的餐厨垃圾全方位综合处理系统,其特征是:所述的系统还包括对产生有以为公端的空气及生产区空气处理的等离子光触媒负离子空气除臭杀菌装置,等离子光触媒负离子空气除臭杀菌装置的进风口安装于各个餐厨垃圾收集池的四周。
  93. 根据权利要求92所述的餐厨垃圾全方位综合处理系统,其特征是:所述的等离子光触媒负离子空气除臭、杀菌装置包括空气输送管道(T272)、光催化主处理器(T274)和活性碳空气过滤器(T281),气体输入空气输送管道(T272)内,空气输送管道(T272)内设有负离子装置,气体通过空气输送管道(T272)输入至光催化主处理器(T274)内,光催化主处理器(T274)内设有空气通道,空气通道内安装有一个以上的发光波长为253nm——258nm的紫外线光管(T276),紫外线光管(T276)后端固定安装有二氧化钛光催化触板(T278),空气通道尾端与活性碳空气过滤器(T281)连通,通过活性碳空气过滤器(T281)将气体输出。
  94. 根据权利要求93所述的餐厨垃圾全方位综合处理系统,其特征是:所述的光催化主处理器(T274)和活性碳空气过滤器(T281)之间连接有空气排出管道(T279),空气排出管道(T279)内设有负离子装置,空气通道尾端与空气排出管道(T279)连通,空气排出管道(T279)与活性碳空气过滤器(T281)连通。
  95. 根据权利要求93所述的餐厨垃圾全方位综合处理系统,其特征是:所述的负离子装置采用负离子波纹板(T273),负离子波纹板(T273)呈层叠式安装。
  96. 根据权利要求95所述的餐厨垃圾全方位综合处理系统,其特征是:所述的负离子波纹板(T273)设有两段,前段为卧式安装,后段为立式安装。
  97. 根据权利要求93至96中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的空气输送管道(T272)前端设有进风口(T270),进风口(T270)的后端安装有自动滑板闸阀(T271)。
  98. 根据权利要求93至96中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的紫外线光管(T276)背面均配装光面反射板(T277)。
  99. 根据权利要求93至96中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的光催化主处理器(T274)内的空气通道呈Z形,并于Z形的空气通道转角位置装有等离子发生器。
  100. 根据权利要求93至96中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的二氧化钛光催化触板(T278)的尺寸和形状与空气通道横截面相吻合,可刚好挡在空气通道内。
  101. 根据权利要求93至96中任意一项所述的餐厨垃圾全方位综合处理系统,其特征是:所述的二氧化钛光催化触板(T278)呈蜂窝型。
  102. 根据权利要求101所述的餐厨垃圾全方位综合处理系统,其特征是:所述的二氧化钛光催化触板(T278)为厚度1cm——10cm,上开有一个以上的孔洞。
  103. 一种采用如权利要求1至102中任意一项所述的餐厨垃圾全方位综合处理系统的转化物制造方法,其特征是:所述的方法包括下述步骤
    A、将餐厨垃圾收集,并投入餐厨垃圾破袋装置,对其进行破袋处理;
    B、将破袋后的餐厨垃圾通过餐厨垃圾联合筛选装置进行联合筛选,从中分理处固体塑料和其它;
    C、对于除去固体塑料后的其他餐厨垃圾通过湿式高级氧化除臭灭活清洗降盐装置进行灭活处理;
    D、对于灭活后的垃圾通过立式脱水装置进行脱水处理;
    E、对于脱水后的物料通过物料破碎机进行粉碎。
  104. 根据权利要求103所述的方法,其特征是:所述的步骤E中粉碎后的物料经过生化处理装置进行生化处理,然后经过自动卸料多级干燥装置进行干燥,然后经过多级干燥和物料精选后,形成混合饲料。
  105. 根据权利要求104所述的方法,其特征是:所述的生化处理包括下述步骤:
    A、通过厌氧发酵池(I65)和两个副发酵器(I71)同时作用,生成预发酵物料;
    B、当预发酵工段完成后,将两个副发酵器(I71)内的物料,通过设于副发酵器(I71)底部的自动输送设备(I74)送进主发酵器,将厌氧发酵池(I65)内的物料,通过自动卸料系统(I67)也送进主发酵器,进行二次发酵;
    C、二次发酵完成后,进行出料。
  106. 根据权利要求105所述的方法,其特征是:所述的厌氧发酵池(I65)内生成预发酵物料时,将占总发酵基料重量的50%——80%的豆种作物桔秆和占总发酵基料重量的20%——50%的禾木料作物的当季桔秆破碎成粒径为0.5mm——1mm的粉末,并加入能分解粗纤维的复合菌剂对上述混合物料进行生化处理,所述的复合菌剂中菌种不少于两种,其中一种为米曲霉,复合菌剂的投入量为混合固体基料的1%,并加入化学成份氧化钙、氯化钠、磷酸氢钠和尿素。
  107. 根据权利要求106所述的方法,其特征是:所述的一个副发酵器(I71)内生成预发酵物料时,在副发酵器(I71)中加入已经人工灭活的餐厨垃圾为基料,加入占基料重量1%——2%的麸皮、占基料重量1%——3%的米糠和占基料重量1%的白糖作为混合料,并加入适量的水调成糊状,温度控制在20℃——30℃之间范围 ,并向混合料中加入占混合料总重量的2%——4%的面包酵母,并充分搅拌、强化曝气,以增强酵母生长,发酵的方式可采用老酵法。
  108. 根据权利要求107所述的方法,其特征是:所述的一个副发酵器(I71)内生成预发酵物料时,在副发酵器(I71)中加入已经过人工灭活、清洗并已脱水的餐厨垃圾为基料进行固态发酵,选用由绿色木霉、热带假丝酵母菌、白地菌和拟内孢霉酵母菌组成四菌混合菌剂,四菌的重量比例为2:2:1:1,接种量为总重量的2%,同时添加占总重量1%——1.5%的尿素,温度为25℃——42℃,由搅拌设备(I73)每小时翻滚一次,发酵时间9小时——10小时。
  109. 根据权利要求108所述的方法,其特征是:所述的二次发酵时,将已进行预生化处理的物料输入主发酵器,秸秆发酵物料中总物料重量百分比的10%——40%,面包酵母发酵物料占总物料重量百分比的20%,第二副发酵器(I71)内的发酵物料占总物料重量百分比的40%——70%,当三种经预发酵处理后的物料进入主发酵器内后,双层螺带搅拌器(I78)作360度旋转,旋转动作为往返方向,对物料作低速缓慢搅拌,主发酵器内的温度从初始的20℃开始起温,起温阶段物料平均温度20℃——28℃,恒温时间为4小时后关闭空气阀I87,同时提温至35℃——38℃,恒温时间3小时后,开启第一级引风装置I92,作轻质量排风,当上述的二次恒温时间完成后,再次提温至82℃,时间为2小时,并开启二级引风装置(I92)作强力排风。
  110. 根据权利要求103所述的方法,其特征是:所述的步骤B中产生的废塑料经过废塑料逆转工程装置逆转生成生物柴油。
  111. 根据权利要求110所述的方法,其特征是:所述的制造生物柴油产生的余渣粗炭黑人工陈化处理器,利用臭氧对物料进行陈化,通过化学陈化后的粗炭黑再进入物理陈化床,当粗炭黑经过人工陈化后,由专用自动输送工具输入物料配伍设备,每种配伍助剂均由液、固自动定量加料设备添加,通过多层推拉式螺杆将物料充分混合输入低硫高能环保清洁燃煤成形机,待物料成形后得到粗炭黑。
  112. 根据权利要求103至111中任意一项所述的方法,其特征是:所述的步骤A至步骤E中产生的污水经快速污水处理回用装置处理后,排出或回用。
  113. 根据权利要求103至111中任意一项所述的方法,其特征是:所述的步骤A至步骤E中产生的固体污泥处理经杂化荷电吸附剂生产装置处理后生成杂化荷电吸附剂。
  114. 根据权利要求103至111中任意一项所述的方法,其特征是:所述的步骤A至步骤E中产生的烟气、热烟气、粉尘和抽排口空气经环保处理装置处理后排出。
  115. 根据权利要求114所述的方法,其特征是:所述的处理后的气体经过等离子光触媒负离子空气除臭杀菌装置处理后排出。
  116. 根据权利要求103至111中任意一项所述的方法,其特征是:所述的步骤A至步骤E中产生的油水混合物通过免蒸馏法生物柴油生产方法生产生物柴油,该方法包括下述步骤:
    (1)、将餐厨垃圾生产过程中所产生的油、水、固混合物通过卧式螺带固液分离设备(O151)进行脱固处理,得到油水混合液;
    (2)、将油水混合液输送至油水分离塔(O152)进行油水分离,将分离后的油脂输入储油容器(O149);
    (3)、当需要对生物油脂时行加工处理时,通过输送泵等工具将生物油脂送进油脂胶质脱除设备(O158)内后,启动旋浆水力推进机(O160),并加入磷酸,磷酸与生物油脂的比例为不超过油脂总量的0.8%——1.2%,利用油脂胶质脱除设备(O158)两端的旋浆推力使油脂胶质脱除设备(O158)内部的液体产生相向撞击,撞击时间为10 min——15min,在液体的相向撞击时间结束后,当即加入稀盐水,稀盐水中水、盐的重量比为95:5至90:10之间,生物油脂与稀盐水的重量比例为90:10至80:20之间;
    (4)、继续启动旋浆水力推进机(O160),时间为10 min——20min;
    (5)、油脂混合体于油脂胶质脱除设备(O158)中停留60min——120min;
    (6)、将已脱胶质的生物油脂被输进生物油常温脂交换设备(O161);
    (7)、当生物油常温脂交换设备(O161)内的油脂输入的液面达到生产工艺设定的液面高度时,停止输入,开始启动生物油常温脂交换设备(O161)底部的鼓气管(O171),打开投料口(O169),加入固体催化剂和甲醇,固体催化剂用量为生物油脂质量的1.5%——3.5%,甲醇用量为生物油脂质量的3%——8%,在加入甲醇后再加入共溶剂;
    (8)、利用搅拌器连续搅拌10 min——15min,再加入固体金属碱催化剂,加入量为生物油脂质量的3%——4.5%;
    (9)、当加入所需要的助剂后,关闭投料孔(O169),开启物料循环输送泵,并开启超声波发生器(O162),超声波发生器(O162)的初始频率为25KHZ,时间为1min,随后逐步增大到30KHZ,时间为30 min——40min,反应温度为25——35℃。
    (10)、当油脂于生物油常温脂交换设备(O161)中完成脂交换后,将生物油脂混合物输入分液设备(O172)静置分层,上层为甲醇和甘油混合液体,下层为粗制生物柴油;
    (11)、首先将分液设备设于下部排液口开启,让粗制生物柴油输送进入过滤设备(O173),过滤后得到精制生物柴油并回收固体催化剂。
  117. 根据权利要求116所述的方法,其特征是:所述的油水分离时,油水分离塔(O152)内的油水混合液加热至60℃——85℃,待生物油脂上浮后实现油水分层,上层的生物油脂由刮油器(O155)刮出,并通过出油管道(O156)送入储油容器内。
  118. 根据权利要求116所述的方法,其特征是:所述的共溶剂的选择为甲乙醇的任意比例的混合物,共溶剂的加入量是生物油脂质量的0.5%——2%,共溶剂还包括有加入量是生物油脂质量的0.5%的丁醇。
  119. 根据权利要求116所述的方法,其特征是:所述的固体阴离子金属碱催化剂的特征是以试剂活性碳和铝、钠、铁、锂的环状结构硅酸盐矿物的纳米颗粒为基核,再外裹硅、铝、锂网状骨架介质,且带极性的杂化荷载体,再净该载体浸渍于KNO3液体中,经处理后而成为带极性的杂化荷电,含15%——25%的KNO3的固体阴离子金属碱催化剂。
  120. 根据权利要求116所述的方法,其特征是:所述的生物柴油通过微乳化生物柴油的制作装置制作成乳化生物柴油,该方法包括下述步骤:
    (1)、将粗生物柴油输入上述的微乳化生物柴油装置内,启动搅拌系统,加入30%-80%国III标准柴油后,搅拌5min;
    (2)加入亲水剂,加入量为纯生物柴油和国III标准柴油总重量的2-3%,作1min——15min时间的搅拌;
    (3)、加入丁醇作为中间体,加入量为纯生物柴油和国III标准柴油总重量的2-4%,继续对混合液作不间接搅拌15min,搅拌时,垂直搅拌器(P175)作100转/min——130转/min的转速搅拌;
    (4)、加入异戊烷作为自燃温度调节剂,加入量为纯生物柴油总重量的1.5-2%;
    (4)、加入富氧水,水占产品总重量的1%——20%,再搅拌15min,转速调整为170转/min——200转/min,再加入十八碳—顺—9—烯酸作为乳化剂,十八碳—顺—9—烯酸的加入量为所加入干净水重量的70%——90%,在搅拌设备的连续搅拌下直至澄清透明为止,此时,搅拌器的转速调整为280——340转/min,一般需要连续搅拌40——60min,待静置一定时间观察乳化油为清洁透明无分层后为成品。
  121. 根据权利要求120所述的方法,其特征是:所述的亲水剂选用阳离子表面活性剂及非离子表面活性剂联合的复配物料作为复合活性剂,配比例为阳离子表面活性剂50%,非离子表面活性剂50%。
  122. 根据权利要求120所述的方法,其特征是:所述的表面活性剂有三乙醇胺或六氢苯胺或西曲溴铵和氨水。
  123. 根据权利要求120所述的方法,其特征是:所述的富氧水的加入量为总重量的10%——20%。
  124. 根据权利要求120所述的方法,其特征是:所述的十八碳—顺—9—烯酸设定量的酸值为200。
PCT/CN2013/000146 2012-11-23 2013-02-16 餐厨垃圾全方位处理的集成化装备及产物制造方法 WO2014079135A1 (zh)

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Families Citing this family (118)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014079171A1 (zh) * 2012-11-23 2014-05-30 华南再生资源(中山)有限公司 富氧微乳化混合生物柴油的制作方法及装置
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US10919249B2 (en) 2016-02-19 2021-02-16 Albert Mardikian Apparatus for pressing and dehydrating of waste
EP3417224B1 (en) * 2016-02-19 2021-03-24 Regreen Technologies, Inc. System for processing waste
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US9630888B1 (en) 2016-05-17 2017-04-25 B.A.M.2 Waste Water Consulting, Ptr. Sanitary waste treatment method
US10246380B2 (en) 2016-05-17 2019-04-02 B.A.M.2 Waste Water Consulting, Ptr. Solid waste treatment method
CN106040723A (zh) * 2016-07-19 2016-10-26 苏州鸿本机械制造有限公司 一种厨余垃圾处理机的除臭系统
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WO2018026747A1 (en) 2016-08-05 2018-02-08 Rti International Liquid waste treatment system
WO2018031280A1 (en) * 2016-08-08 2018-02-15 Rti International Solid waste treatment system
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CN106546087B (zh) * 2016-10-31 2019-04-23 程建中 节能环保转筒式烘干机
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CN112923662B (zh) * 2021-03-01 2021-11-16 中国科学院过程工程研究所 一种两段式分离干燥装置及固废分离干燥方法
CN113105996B (zh) * 2021-03-10 2023-07-07 长沙工研院环保有限公司 一种水力气力联动浮选餐厨垃圾厌氧发酵处理系统
CN112759443B (zh) * 2021-03-15 2024-02-02 河北省农业机械化研究所有限公司 一种农业废弃物快速均匀发酵处理装置
CN113004066A (zh) * 2021-03-26 2021-06-22 启迪城市环境服务集团有限公司 一种厨余垃圾快速处理设备及方法
CN113778036B (zh) * 2021-09-27 2022-04-05 广州天幕信息科技有限公司 餐厨垃圾处理智能管理和控制方法及系统
CN113578179B (zh) * 2021-09-30 2021-12-14 广东预防医学健康研究院(有限合伙) 一种药物分析用预混合搅拌装置
CN114314763B (zh) * 2021-12-14 2023-05-02 安徽元琛环保科技股份有限公司 一种环保型三维粒子电极的制备方法及制备的电极
CN114198988B (zh) * 2021-12-29 2022-10-25 双胞胎(集团)股份有限公司 一种用于家畜饲料原料的脱水系统
WO2023139421A1 (en) * 2022-01-24 2023-07-27 Ariunbat Tserendash Complex device and method for pyrolysis of organic raw materials and organic wastes
CN114650708B (zh) * 2022-03-01 2023-08-15 深圳市凌心科技有限公司 一种工业自动控制系统装置制造用高效降温设备
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CN115385476B (zh) * 2022-08-22 2024-01-26 湖南仁和环境股份有限公司 一种餐厨垃圾发酵沼液除臭装置及方法
CN115608744B (zh) * 2022-09-29 2023-06-02 广州市晶科电器有限公司 一种餐厨垃圾转化饲料设备
CN115414833B (zh) * 2022-11-07 2023-03-21 中科微针(北京)科技有限公司 一种用于粘性溶液的制备以及消泡装置
US11939878B1 (en) 2022-12-15 2024-03-26 Ge Infrastructure Technology Llc Turbomachine component having self-breaking supports
US11920794B1 (en) 2022-12-15 2024-03-05 Ge Infrastructure Technology Llc Combustor having thermally compliant bundled tube fuel nozzle
CN116274259A (zh) * 2023-05-16 2023-06-23 国家电投集团科学技术研究院有限公司 微型厨余垃圾处理系统和方法
CN117282516A (zh) * 2023-11-24 2023-12-26 福建美天环保科技有限公司 一种餐厨垃圾破碎分离装置

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003164831A (ja) * 2001-12-03 2003-06-10 Hayakawa Kankyo Kenkyusho:Kk 超臨界水によるゴミ・廃棄物処理システムおよび発電システム
JP2004168589A (ja) * 2002-11-20 2004-06-17 Kenjiro Tsuyuri ゴミの焼却、焼却後の廃ガスの集塵・中和・触媒の反応装置及び触媒後の肥料化プラント並びにその構造
CN1631559A (zh) * 2004-12-27 2005-06-29 徐晓军 生活垃圾湿式强化氧化消解的处理方法
US20090288938A1 (en) * 2006-12-20 2009-11-26 Jesus Eduardo Rodriguez Hernandez System and method for obtaining hydrocarbons from organic and inorganic solid waste
CN101130194B (zh) * 2007-09-14 2010-04-14 苏州市洁净废植物油回收有限公司 餐余垃圾综合处理回收再利用的方法
CN101612630B (zh) * 2009-06-24 2010-09-08 北京国宗元投资有限公司 生活垃圾无害化资源化实时处理方法和系统
CN101837366A (zh) * 2010-05-17 2010-09-22 北京昊业怡生科技有限公司 餐厨垃圾集中处理的方法

Family Cites Families (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5312902B2 (zh) * 1972-03-27 1978-05-06
CH588052A5 (zh) * 1975-04-01 1977-05-31 Kunz W Ag Maschinen Und Appara
US5104047A (en) * 1990-08-21 1992-04-14 Simmons Leonard E Wet process recovery system for solid waste
CN2176820Y (zh) * 1993-11-30 1994-09-14 天津市大港区振东玻璃钢厂 酸雾吸收器
JP2560202B2 (ja) * 1994-03-17 1996-12-04 三井鉱山株式会社 開袋機
CN2224719Y (zh) * 1995-03-03 1996-04-17 南通通德工程有限公司 复式固液分离机
SE506488C2 (sv) * 1995-03-30 1997-12-22 Liss Ola Lindkvist Metod och apparat för sönderdelning av material som ska komposteras
CN1146482A (zh) * 1995-09-29 1997-04-02 上海赢得实业总公司 微乳化生物合成柴油
JPH09174098A (ja) * 1995-12-28 1997-07-08 Ebara Corp 有機性汚泥の減量化法
CN1155452A (zh) * 1996-06-03 1997-07-30 北京绿色环境工程技术研究所 一种垃圾发酵前分选回收装置
JPH1066951A (ja) * 1996-08-28 1998-03-10 Keihanna Kankyo Kk 有機質廃棄物の炭化方法及び装置
JP3411482B2 (ja) * 1997-10-01 2003-06-03 住友重機械工業株式会社 ゴミ焼却炉における排ガス処理装置の運転方法
JPH11169628A (ja) * 1997-12-15 1999-06-29 Kyoei Sangyo Kk 燃焼炉の排ガス処理方法及びその装置
JP2000015233A (ja) * 1998-06-30 2000-01-18 Toto Ltd 厨芥処理装置および厨芥処理装置の運転方法
CN2358998Y (zh) * 1998-11-06 2000-01-19 赵石林 生活垃圾湿式分选处理机
JP2001187375A (ja) * 1999-10-22 2001-07-10 Aichi Electric Co Ltd 有機廃棄物の処理方法および処理装置
JP2002143896A (ja) * 2000-11-15 2002-05-21 Kiyomoto Iron & Machinery Works Co Ltd 有機系廃棄物並びに下水汚泥若しくは畜糞又は下水汚泥及び畜糞の処理方法
CN2455257Y (zh) * 2000-12-28 2001-10-24 西安交通大学 放电等离子体空气灭菌净化机
CN2483387Y (zh) * 2001-06-13 2002-03-27 天诚环保生化科技股份有限公司 厨余有机废弃物的处理机
BE1014261A3 (nl) * 2001-06-20 2003-07-01 Organic Waste Systems Naamloze Werkwijze en inrichting voor het anaeroob vergisten van organisch materiaal.
CN2527567Y (zh) * 2002-01-17 2002-12-25 谢照仁 热风双重加热厨余发酵机
KR100453932B1 (ko) * 2002-02-07 2004-10-26 구경신 건설폐기물의 수조식 골재선별 처리장치
US6979426B2 (en) * 2002-03-15 2005-12-27 Biodiesel Industries Biodiesel production unit
CN2574791Y (zh) * 2002-09-25 2003-09-24 天津百利珀金斯环保设备有限公司 垃圾破袋处理装置
JP2004136169A (ja) * 2002-10-16 2004-05-13 Aizawa Seisakusho:Kk 複動式連続生ごみ処理装置
CN1206189C (zh) * 2003-01-23 2005-06-15 湖南大学 厌氧好氧一体式堆肥反应装置
CN2618688Y (zh) * 2003-04-17 2004-06-02 四川省环能科技实业有限公司 多功能垃圾分选机
CN1212494C (zh) * 2003-05-15 2005-07-27 南海市华星光电实业有限公司 一种室内空气的净化方法及装置
CN2644943Y (zh) * 2003-09-05 2004-09-29 宋勇 一种可通新鲜空气的空调器
CN2659549Y (zh) * 2003-09-28 2004-12-01 赵石林 生活垃圾有机物湿式分离机
CN2655913Y (zh) * 2003-10-31 2004-11-17 罗炳灿 等离子体空气灭菌净化器
JP4398270B2 (ja) * 2004-02-03 2010-01-13 新日鉄エンジニアリング株式会社 植物繊維を含む有機土の処理方法及び有機土処理装置
JP2006044956A (ja) * 2004-07-30 2006-02-16 Yuasa Sangyo:Kk 有機肥料の製造方法
CN2731377Y (zh) * 2004-09-22 2005-10-05 陈奇森 气流式干燥机
CN100435959C (zh) * 2004-09-24 2008-11-26 邓连松 风扫环磨机
CN100441966C (zh) * 2004-10-14 2008-12-10 北京工业大学 立式光催化空气净化器
US7171762B2 (en) * 2004-10-19 2007-02-06 Gala Industries, Inc. Self-cleaning centrifugal pellet dryer and method thereof
KR20060117617A (ko) * 2005-05-13 2006-11-17 차순용 폐기물 건조장치
CN2844810Y (zh) * 2005-09-02 2006-12-06 上海山水路桥机械设备有限公司 三筒烘干机
JP4771257B2 (ja) * 2005-11-28 2011-09-14 株式会社松尾工業所 廃食用油精製装置
JP3892893B1 (ja) * 2006-03-24 2007-03-14 寺尾 義典 廃食用油の処理装置
CN2911573Y (zh) * 2006-04-25 2007-06-13 岳邦富 单级干燥滚筒和多级干燥滚筒及其新型高湿物料烘干机
CN101134610A (zh) * 2006-08-28 2008-03-05 上海科林环保工程技术有限公司 餐厅含油废水净化处理装置
US20100284854A1 (en) * 2007-01-03 2010-11-11 John Lee Edwards Radicals on eradication surfaces
CN101011593A (zh) * 2007-02-02 2007-08-08 上海福缘电子有限公司 具有高浓度负离子辐射的空气净化器
CN201037141Y (zh) * 2007-03-20 2008-03-19 赵山山 全天候高效沼气发生器
CN201055804Y (zh) * 2007-04-27 2008-05-07 广州德润环保科技发展有限公司 立式可腐有机垃圾的破碎与脱水装置
CN201044896Y (zh) * 2007-05-22 2008-04-09 宁波大学 一种油柜式全自动柴油动态乳化装置
CN101219331B (zh) * 2007-09-28 2010-12-08 泉州市天龙环境工程有限公司 燃煤锅炉烟气脱硫除尘净化系统
CN101219824A (zh) * 2007-11-20 2008-07-16 无锡林信环保工程有限公司 曝气流化床微电解装置
CN201176436Y (zh) * 2008-02-01 2009-01-07 李尚云 沼气发酵罐
CN101284280A (zh) * 2008-04-30 2008-10-15 北京恒业村科技有限公司 小型垃圾物料分选装置
CN101722172A (zh) * 2008-10-16 2010-06-09 王志成 生活垃圾综合分选机
CN101429480A (zh) * 2008-12-18 2009-05-13 新疆西域牧歌农业科技有限公司 一种秸秆混合原料发酵产沼气的方法及装置
CN201366110Y (zh) * 2009-01-09 2009-12-23 镇江同盛环保设备工程有限公司 气固两相臭气净化装置
US20100267102A1 (en) * 2009-04-16 2010-10-21 Feed Resource Recovery, Inc. Waste distribution, conversion, and utilization
CN101920041A (zh) * 2009-06-11 2010-12-22 张俊杰 垃圾站综合性消毒、除臭及污水净化循环利用系统
CN201439395U (zh) * 2009-06-22 2010-04-21 北京昊业怡生科技有限公司 破袋机
CN101618391A (zh) * 2009-07-15 2010-01-06 无锡汉神电气有限公司 一种催化氧化式有机垃圾的处理系统
CN101717716B (zh) * 2009-09-28 2012-07-25 浙江科峰生物技术有限公司 自动链带式固态发酵反应装置及其自动固态发酵的方法
CN201618489U (zh) * 2009-11-04 2010-11-03 煤炭科学研究总院杭州环境保护研究所 一种化工废气喷淋旋流组合净化装置
CN102060577B (zh) * 2009-11-18 2013-08-14 余福华 一种将泔水处理成有机肥料的设备
CN201596564U (zh) * 2010-02-03 2010-10-06 天津德为环保工程设备有限公司 城市生活垃圾资源化分选装置
CN201653092U (zh) * 2010-03-24 2010-11-24 楼生友 静音式节能干燥机
CN101816874B (zh) * 2010-05-12 2011-11-23 华南再生资源(中山)有限公司 燃料裂解炉尾气处理系统
CN101962599A (zh) * 2010-05-28 2011-02-02 王金华 利用地沟油提炼工业油脂的成套设备及方法
CN201728222U (zh) * 2010-07-16 2011-02-02 林敏� 餐厨垃圾综合处理机
CN101955382B (zh) * 2010-08-16 2012-09-19 广州农冠生物科技有限公司 一种餐厨垃圾处理方法及其处理系统
CN101906355B (zh) * 2010-08-30 2012-02-01 北京昊业怡生科技有限公司 一种利用餐厨垃圾回收油制取生物柴油的方法
CN101921049B (zh) * 2010-09-21 2012-01-25 同济大学 一种城市污泥及有机质干法厌氧发酵产沼气的方法及装置
CN102151683A (zh) * 2010-12-02 2011-08-17 北京工商大学 餐厨垃圾湿热—发酵综合无害化和资源化处理系统
CN201880472U (zh) * 2010-12-06 2011-06-29 张步芳 一种工业燃煤锅炉烟气脱硫除尘装置
CN102093949A (zh) * 2010-12-08 2011-06-15 江南大学 一种多功能生物固体发酵罐
CN102072628A (zh) * 2010-12-29 2011-05-25 东莞市英豪机械有限公司 立式脱水设备
CN102125925A (zh) * 2010-12-30 2011-07-20 东莞市东力环保设备有限公司 一种餐厨垃圾处理装置
CN102151687A (zh) * 2010-12-31 2011-08-17 东莞市东力环保设备有限公司 一种零排放的餐厨垃圾处理装置
WO2012117145A1 (en) * 2011-02-28 2012-09-07 Kumera Oy Method and apparatus for drying moist material
CN102690134B (zh) * 2011-03-21 2014-12-24 焦社杰 餐厨垃圾资源化处理方法及其处理系统
CN102211107B (zh) * 2011-03-24 2013-02-27 天津农学院 餐厨废弃物无害化资源化处理设备
CN102728600A (zh) * 2011-04-11 2012-10-17 张希曾 一种餐厨垃圾综合处理方法
CN202081098U (zh) * 2011-05-05 2011-12-21 郑州蓝德环保科技有限公司 干法湿法联合发酵秸秆的加工装置
CN102218441B (zh) * 2011-05-11 2013-08-21 中山市泰帝科技有限公司 一种餐厨垃圾的固液分离装置及方法
CN102295997B (zh) * 2011-07-07 2013-09-04 严正华 一种厨余废弃油脂处理方法及系统
CN102441557B (zh) * 2011-10-21 2013-11-06 中国科学院过程工程研究所 一种好氧-厌氧联合固态发酵装置及发酵方法
CN102357517A (zh) * 2011-11-16 2012-02-22 上海野马环保设备工程有限公司 生活垃圾破碎、压实一体化处理系统
CN202322431U (zh) * 2011-11-29 2012-07-11 四川深蓝环保科技股份有限公司 一种餐厨废物的油脂分离回收装置
CN202465702U (zh) * 2011-12-16 2012-10-03 成都德通环境工程有限公司 一种用于餐厨垃圾处理的两步厌氧发酵装置
CN102631982A (zh) * 2012-04-24 2012-08-15 张伟铭 一种生活垃圾新型水分选系统
CN102671924A (zh) * 2012-05-29 2012-09-19 陈文才 餐饮垃圾综合回收利用的方法
WO2014079171A1 (zh) * 2012-11-23 2014-05-30 华南再生资源(中山)有限公司 富氧微乳化混合生物柴油的制作方法及装置
CN203295470U (zh) * 2013-01-31 2013-11-20 华南再生资源(中山)有限公司 富氧微乳化混合生物柴油的制作装置
CN203183865U (zh) * 2013-01-31 2013-09-11 华南再生资源(中山)有限公司 尾气处理系统
CN203228968U (zh) * 2013-01-31 2013-10-09 华南再生资源(中山)有限公司 一种餐厨垃圾承装塑料袋分瓣割破装置

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003164831A (ja) * 2001-12-03 2003-06-10 Hayakawa Kankyo Kenkyusho:Kk 超臨界水によるゴミ・廃棄物処理システムおよび発電システム
JP2004168589A (ja) * 2002-11-20 2004-06-17 Kenjiro Tsuyuri ゴミの焼却、焼却後の廃ガスの集塵・中和・触媒の反応装置及び触媒後の肥料化プラント並びにその構造
CN1631559A (zh) * 2004-12-27 2005-06-29 徐晓军 生活垃圾湿式强化氧化消解的处理方法
US20090288938A1 (en) * 2006-12-20 2009-11-26 Jesus Eduardo Rodriguez Hernandez System and method for obtaining hydrocarbons from organic and inorganic solid waste
CN101130194B (zh) * 2007-09-14 2010-04-14 苏州市洁净废植物油回收有限公司 餐余垃圾综合处理回收再利用的方法
CN101612630B (zh) * 2009-06-24 2010-09-08 北京国宗元投资有限公司 生活垃圾无害化资源化实时处理方法和系统
CN101837366A (zh) * 2010-05-17 2010-09-22 北京昊业怡生科技有限公司 餐厨垃圾集中处理的方法

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10823404B1 (en) 2016-03-11 2020-11-03 Pyrodyne Thermal, LLC Materials handling system for feed injection to thermal kiln retorts
CN105712756A (zh) * 2016-04-20 2016-06-29 常州市苏风机械有限公司 一种超高温有机肥发酵设备
CN110813997A (zh) * 2019-11-26 2020-02-21 浙江任我行教育科技有限公司 一种纺织废料处理装置
CN111875664A (zh) * 2020-07-31 2020-11-03 程红梅 一种小分子肽分离装置
CN112676298A (zh) * 2020-11-13 2021-04-20 广东省建筑设计研究院有限公司 一种厨余垃圾与市政污泥、粪便的协同处理系统及方法
US20230142466A1 (en) * 2021-11-05 2023-05-11 Shenzhen Guanke Technologies Co., Ltd Grating structure and uv light
WO2024063256A1 (ko) * 2022-09-20 2024-03-28 삼성전자주식회사 음식물 쓰레기 처리기
RU217262U1 (ru) * 2022-12-21 2023-03-24 Татьяна Сергеевна Макарова Устройство для переработки пластиковых отходов 3D-печати в пластиковый филамент

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