RU2016136183A - Способ получения этиленовых сополимеров - Google Patents

Способ получения этиленовых сополимеров Download PDF

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RU2016136183A
RU2016136183A RU2016136183A RU2016136183A RU2016136183A RU 2016136183 A RU2016136183 A RU 2016136183A RU 2016136183 A RU2016136183 A RU 2016136183A RU 2016136183 A RU2016136183 A RU 2016136183A RU 2016136183 A RU2016136183 A RU 2016136183A
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group
hydrocarbon group
catalyst
ratio
compound
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RU2016136183A
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RU2016136183A3 (ru
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Франсис С. РИКС
Чин-Тай ЛЮЕ
Джефф ХАРЛАН С.
Лафлин Дж. МакКАЛАФ
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ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи
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Publication of RU2016136183A3 publication Critical patent/RU2016136183A3/ru

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Claims (17)

1. Способ полимеризации олефинов с получением полиолефинового полимера с мультимодальным распределением по составу, включающий в себя приведение этилена и сомономера в контакт с каталитической системой, где каталитическая система включает в себя первое каталитическое соединение и второе каталитическое соединение, которые совместно нанесены на носитель с формированием совместно нанесенной каталитической системы, где первое каталитическое соединение включает в себя соединение со следующей формулой:
(C5HaR1 b)(C5HcR2 d)HfX2,
в которой каждый R1 независимо представляет собой H, углеводородную группу, замещенную углеводородную группу или гетероатомную группу; каждый R2 независимо представляет собой H, углеводородную группу, замещенную углеводородную группу или гетероатомную группу; a и c имеют значение ≥ 3; a+b=c+d=5; по меньшей мере один R1 и по меньшей мере один R2 представляют собой углеводородную или замещенную углеводородную группу; смежные группы R1 и группы R2 могут быть соединены с образованием кольца; и каждый X независимо представляет собой уходящую группу, выбираемую из лабильной углеводородной, замещенной углеводородной или гетероатомной группы, или двухвалентный радикал, который связан с группой R1 или R2; и второе каталитическое соединение включает в себя по меньшей мере одно соединение с нижеследующими формулами:
Figure 00000001
,
в которых каждый R3 независимо представляет собой H, углеводородную группу, замещенную углеводородную группу или гетероатомную группу; R4 представляет собой углеводородную группу, замещенную углеводородную группу или гетероатомную группу; каждый R5 независимо представляет собой H, углеводородную группу, замещенную углеводородную группу или гетероатомную группу; где R3, R4 и R5 могут быть одинаковыми или различными; и каждый X независимо представляет собой уходящую группу, выбираемую из лабильной углеводородной, замещенной углеводородной, гетероатомной группы, или двухвалентный радикал, который связан с группой R3, R4 или R5.
2. Способ по п.1, где значение соотношения включения сомономера/этилена для второго катализатора составляет менее примерно 0,8 от значения соотношения включения сомономера/этилена для первого катализатора.
3. Способ по п.1, включающий в себя непрерывное объединение суспензии каталитического компонента с раствором каталитического компонента с формированием совместно нанесенной каталитической системы.
4. Способ по п.3, где суспензия каталитического компонента содержит первое каталитическое соединение, а раствор каталитического компонента содержит второе каталитическое соединение.
5. Способ по п.1, включающий в себя:
проведение измерений на образце полиолефинового полимера, чтобы получить первоначальное свойство продукта; и
изменение технологического параметра, чтобы получить второе свойство продукта, основываясь, по меньшей мере частично, на первоначальном свойстве продукта.
6. Способ по п.5, где проведение измерений на образце полиолефинового полимера включает в себя измерение включения сомономера как функции молекулярной массы.
7. Способ по п.5, где проведение измерений на образце включает в себя определение индекса текучести, индекса расплава, отношения двух индексов расплава, плотности, молекулярно-массового распределения, содержания сомономера или любых сочетаний названных показателей.
8. Способ по п.5, где изменение технологического параметра
включает в себя регулировку молярного количества каталитического компонента, который объединяют с суспензией каталитического компонента.
9. Способ по п.1, включающий в себя регулировку отношения количеств сомономера к этилену в реакторе полимеризации для того, чтобы контролировать распределение по составу, молекулярно-массовое распределение, индекс расплава (I2) или отношение двух индексов расплава, либо любых сочетаний названных показателей полиолефинового полимера.
10. Способ по п.1, включающий в себя регулировку отношения количеств водорода к этилену в реакторе полимеризации для того, чтобы контролировать распределение по составу, молекулярно-массовое распределение, индекс расплава (I2) или отношение двух индексов расплава, либо любых сочетаний названных показателей полиолефинового полимера.
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Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106029710B (zh) * 2014-02-11 2019-08-30 尤尼威蒂恩技术有限责任公司 制造聚烯烃产物
CN106574014B (zh) * 2014-06-16 2021-04-16 尤尼威蒂恩技术有限责任公司 修改聚乙烯树脂的熔体流动比率和/或溶胀的方法
CA2983284C (en) 2015-04-23 2023-09-26 Univation Technologies, Llc Polyethylene copolymers having a particular comonomer distribution
FR3043687B1 (fr) * 2015-11-13 2020-07-03 Universite Blaise Pascal Clermont Ii Procede sol-gel de synthese d'un materiau luminescent de formulation generale axbyfz:mn
KR101711788B1 (ko) * 2016-03-09 2017-03-14 한화케미칼 주식회사 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
SG11201808179SA (en) * 2016-03-31 2018-10-30 Dow Global Technologies Llc An olefin polymerization catalyst
CN109071844A (zh) * 2016-04-22 2018-12-21 埃克森美孚化学专利公司 聚乙烯片材
US10302621B2 (en) 2016-06-15 2019-05-28 Exxonmobil Chemical Patents Inc. Methods for characterizing branching distribution in polymers
PT3293210T (pt) * 2016-09-12 2019-06-12 Scg Chemicals Co Ltd Película de polietileno multimodal
MY193008A (en) * 2016-09-29 2022-09-21 Dow Global Technologies Llc Multilayer stretch films having a high cling force and methods thereof
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
EP3523337A4 (en) * 2016-10-05 2020-08-05 ExxonMobil Chemical Patents Inc. STERICALLY HUMP METALLOCENE, SYNTHESIS AND USE
US20190284310A1 (en) * 2016-11-03 2019-09-19 Exxonmobil Chemical Patents Inc. Catalyst Supply System and Process for Producing Polymers
EP3538571B1 (en) * 2016-11-08 2022-06-01 Univation Technologies, LLC Bimodal polyethylene
CA3045440C (en) * 2016-12-05 2021-07-06 Exxonmobil Chemical Patents Inc. Broad orthogonal distribution metallocene polyethylenes for films
WO2018106388A1 (en) 2016-12-05 2018-06-14 Exxonmobil Chemical Patents Inc. Broad orthogonal distribution metallocene polyethylenes for films
CA3046800A1 (en) 2016-12-15 2018-06-21 Univation Technologies, Llc Rating polymerization processes
CN110050026B (zh) * 2016-12-19 2022-05-31 陶氏环球技术有限责任公司 导体护套和用于制造其的方法
EP3580245B1 (en) * 2017-02-13 2020-11-25 Univation Technologies, LLC Bimodal polyethylene resins
US10723819B2 (en) 2017-02-20 2020-07-28 Exxonmobil Chemical Patents, Inc. Supported catalyst systems and processes for use thereof
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
SG11201907497PA (en) * 2017-02-20 2019-09-27 Exxonmobil Chemical Patents Inc Supported catalyst systems and processes for use thereof
US10947329B2 (en) * 2017-05-10 2021-03-16 Univation Technologies, Llc Catalyst systems and processes for using the same
WO2018213395A1 (en) 2017-05-17 2018-11-22 Univation Technologies, Llc A hafnium complex; a supported hafnium complex; methods of forming a polymer using such complexes
EP3631440B1 (en) 2017-06-02 2023-02-22 Univation Technologies, LLC Method of determining a relative decrease in catalytic efficacy of a catalyst in a catalyst solution
BR112019025923B1 (pt) * 2017-06-08 2024-02-06 Univation Technologies, Llc Método de manutenção de um valor alvo de um índice de fluxo de fusão de um produto de polímero de polietileno
WO2019027587A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. POLYETHYLENE COMPOSITIONS AND FILMS PREPARED THEREFROM
US10844150B2 (en) 2017-08-04 2020-11-24 Exxonmobil Chemical Patents Inc. Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes
CN111108130B (zh) * 2017-08-04 2022-06-28 埃克森美孚化学专利公司 具有含-CH2-SiMe3部分的非桥连二茂铪的混合催化剂
US11302459B2 (en) 2017-10-06 2022-04-12 Exxonmobil Chemical Patents Inc. Polyethylene extrudates and methods of making the same
JP6986163B2 (ja) * 2017-10-23 2021-12-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 触媒系およびそれを使用する重合方法
US11161924B2 (en) * 2017-10-27 2021-11-02 Univation Technologies, Llc Polyethylene copolymer resins and films
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
WO2019089153A1 (en) * 2017-10-31 2019-05-09 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US10927203B2 (en) 2017-11-13 2021-02-23 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US10927202B2 (en) 2017-11-13 2021-02-23 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
EP3710502A1 (en) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerization processes
WO2019099577A1 (en) * 2017-11-15 2019-05-23 Exxonmobil Chemical Patents Inc. Polymerization processes
EP3710501A2 (en) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerization processes
US20190161559A1 (en) * 2017-11-28 2019-05-30 Exxonmobil Chemical Patents Inc. Catalyst Systems and Polymerization Processes for Using the Same
WO2019108977A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
US10926250B2 (en) 2017-12-01 2021-02-23 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
CN108129729A (zh) * 2017-12-20 2018-06-08 宁波市鄞州智伴信息科技有限公司 一种基于永磁材料的新型可塑型磁控管的制备工艺
KR102459861B1 (ko) 2017-12-21 2022-10-27 주식회사 엘지화학 가공성이 우수한 에틸렌/1-부텐 공중합체
KR102323807B1 (ko) * 2018-01-12 2021-11-09 주식회사 엘지화학 촉매 조성물 내 브롬 화합물의 제거 방법
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
CA3090994A1 (en) * 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
CN112055720B (zh) * 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
US11447587B2 (en) * 2018-05-02 2022-09-20 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019246069A1 (en) 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2020046406A1 (en) * 2018-08-30 2020-03-05 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
US10927205B2 (en) 2018-08-30 2021-02-23 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
US10899860B2 (en) 2018-08-30 2021-01-26 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
KR102258230B1 (ko) * 2018-10-19 2021-05-28 한화솔루션 주식회사 올레핀계 중합체
EP3873949A1 (en) * 2018-11-01 2021-09-08 ExxonMobil Chemical Patents Inc. Slurry trim catalyst feeder modifications
EP3873947A1 (en) * 2018-11-01 2021-09-08 ExxonMobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio by trim and olefin polymerization with the same
WO2020092597A1 (en) * 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of catalysts by trim and olefin polymerization
EP3873946A1 (en) * 2018-11-01 2021-09-08 ExxonMobil Chemical Patents Inc. Mixed catalyst systems with properties tunable by condensing agent
CN113039212B (zh) * 2018-11-01 2023-04-14 埃克森美孚化学专利公司 干燥催化剂进料的管线内修整
WO2020092606A1 (en) * 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio and olefin polymerization
CN112823163B (zh) 2018-11-06 2024-04-19 陶氏环球技术有限责任公司 烷烃可溶的非茂金属预催化剂
WO2020096735A1 (en) 2018-11-06 2020-05-14 Dow Global Technologies Llc Method of olefin polymerization using alkane-soluble non-metallocene precatalyst
BR112021006521B1 (pt) 2018-11-06 2024-03-05 Dow Global Technologies Llc Composto, método para sintetizar um composto, solução de um composto, sistema de catalisador e método para produzir um polímero de poliolefina
US20220017730A1 (en) * 2018-11-16 2022-01-20 Exxonmobil Chemical Patents Inc. Polyolefin Compositions Suitable for Films
KR102116476B1 (ko) 2019-01-18 2020-05-28 대림산업 주식회사 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지
JP7237407B2 (ja) 2019-02-20 2023-03-13 エルジー・ケム・リミテッド 触媒組成物およびこれを用いたポリオレフィンの製造方法
KR102372974B1 (ko) * 2019-04-05 2022-03-10 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법
CN113748140A (zh) * 2019-04-30 2021-12-03 陶氏环球技术有限责任公司 金属-配体络合物
US11014997B2 (en) 2019-05-16 2021-05-25 Chevron Phillips Chemical Company Lp Dual catalyst system for producing high density polyethylenes with long chain branching
KR102203007B1 (ko) 2019-06-05 2021-01-14 대림산업 주식회사 다단계 연속 중합 방법을 이용한 멀티모달 폴리올레핀 제조방법
WO2021040760A1 (en) 2019-08-28 2021-03-04 Exxonmobil Chemical Patents Inc. Polyolefin compositions for films
KR102595112B1 (ko) * 2019-09-30 2023-10-30 주식회사 엘지화학 올레핀계 중합체
CN113795524B (zh) * 2019-09-30 2023-10-03 株式会社Lg化学 聚丙烯基复合材料
JP7412845B2 (ja) * 2019-09-30 2024-01-15 エルジー・ケム・リミテッド オレフィン系重合体
KR102547232B1 (ko) * 2019-10-24 2023-06-26 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
KR102605269B1 (ko) * 2019-12-09 2023-11-23 한화솔루션 주식회사 기상 중합에 의한 올레핀계 중합체의 제조방법
WO2021126448A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Broad orthogonal distribution polyethylenes for films
WO2021222280A2 (en) 2020-05-01 2021-11-04 Exxonmobil Chemical Patents Inc. Linear low density polyethylene for film applications
WO2021222016A2 (en) 2020-05-01 2021-11-04 Exxonmobil Chemical Patents Inc. Linear low density polyethylene for film applications
JP2023528187A (ja) * 2020-05-29 2023-07-04 ダウ グローバル テクノロジーズ エルエルシー 触媒系及びそれを使用してポリエチレンを生産するためのプロセス
CN114466873B (zh) * 2020-07-03 2024-02-06 株式会社Lg化学 烯烃类聚合物
CA3193394A1 (en) 2020-09-22 2022-03-31 Bo Liu Bimodal polyethylene copolymer and film thereof
US11578156B2 (en) 2020-10-20 2023-02-14 Chevron Phillips Chemical Company Lp Dual metallocene polyethylene with improved processability for lightweight blow molded products
KR102608612B1 (ko) * 2020-11-23 2023-12-04 한화솔루션 주식회사 올레핀계 중합체 및 그 제조방법
KR102608616B1 (ko) * 2020-11-23 2023-12-04 한화솔루션 주식회사 올레핀계 중합체, 그로부터 제조된 필름 및 그 제조방법
EP4255942A1 (en) 2020-12-02 2023-10-11 ExxonMobil Chemical Patents Inc. Medium density polyethylene compositions with broad orthogonal composition distribution
WO2022124692A1 (ko) * 2020-12-08 2022-06-16 한화솔루션 주식회사 올레핀계 중합체 및 그 제조방법
CN116601187A (zh) * 2020-12-08 2023-08-15 韩华思路信株式会社 烯烃系聚合物、由其制造的膜及其制造方法
US20240084057A1 (en) * 2020-12-08 2024-03-14 Hanwha Solutions Corporation Olefin polymer and preparation method therefor
CA3206442A1 (en) * 2021-02-09 2022-08-18 Rhett A. BAILLIE Hafnium metallocenes having nonidentical ligands
US20240026046A1 (en) * 2021-03-23 2024-01-25 Lg Chem, Ltd. Olefin-Based Polymer
WO2022210844A1 (ja) * 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム
CN113089152B (zh) * 2021-04-06 2022-11-22 军事科学院系统工程研究院军需工程技术研究所 一种原位聚合阻燃锦纶66全牵伸丝的高质高效生产方法
CN115490733A (zh) * 2021-06-17 2022-12-20 广东阿格蕾雅光电材料有限公司 含oncn四齿配体的杂环修饰的铂配合物
KR20230036257A (ko) * 2021-09-07 2023-03-14 한화솔루션 주식회사 올레핀계 중합체의 제조방법 및 이를 이용하여 제조된 올레핀계 중합체
CN117980354A (zh) 2021-10-26 2024-05-03 埃克森美孚化学专利公司 具有卓越加工性和机械性质的高度取向线性低密度聚乙烯膜
WO2023154769A1 (en) 2022-02-11 2023-08-17 Dow Global Technologies Llc Bimodal medium density polyethylene compositions suitable for use as microirrigation drip tapes
WO2023215694A1 (en) 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis(phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2023215693A1 (en) 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis(phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2023215695A1 (en) 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis (phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2023215696A1 (en) 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Modified pyridine-2,6-bis(phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2024030624A1 (en) * 2022-08-05 2024-02-08 Dow Global Technologies Llc Asymmettrical zirconium metallocenes having an isobutyl cyclopentadienyl ligand
WO2024044423A1 (en) 2022-08-22 2024-02-29 Exxonmobil Chemical Patents, Inc. Polyethylene compositions and films made therefrom

Family Cites Families (133)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067518A (en) 1958-04-02 1962-12-11 Martin A Herman Master type squaring fixture
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
FR2618786B1 (fr) 1987-07-31 1989-12-01 Bp Chimie Sa Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
DE68928100T2 (de) * 1988-09-30 1997-11-06 Exxon Chemical Patents Inc Lineare ethylen-copolymermischungen von copolymeren mit engen molekulargewichts- und kompositionsverteilungen
US5041584A (en) 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
TW300901B (ru) * 1991-08-26 1997-03-21 Hoechst Ag
KR100253826B1 (ko) * 1991-12-30 2000-04-15 그레이스 스티븐 에스. 에틸렌 공중합체의 중합방법
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
JP3365661B2 (ja) * 1992-11-19 2003-01-14 三井化学株式会社 エチレン系共重合体組成物
GB9224876D0 (en) * 1992-11-27 1993-01-13 Exxon Chemical Patents Inc Improved processing polyolefin blends
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
CA2168883C (en) * 1993-08-06 2000-07-04 Moses Olukayode Jejelowo Polymerization catalysts, their production and use
WO1995009172A1 (fr) * 1993-09-30 1995-04-06 Idemitsu Kosan Co., Ltd. Compose d'un metal de transition, catalyseur de polymerisation d'olefine, et procede de production d'un polymere olefinique a l'aide du catalyseur
AT401520B (de) * 1994-03-22 1996-09-25 Danubia Petrochem Polymere Metallocene und deren einsatz für die olefinpolymerisation
AU679355B2 (en) * 1994-03-25 1997-06-26 Mobil Oil Corporation Linear low density polyethylene
US5525678A (en) 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
ATE223929T1 (de) * 1995-05-16 2002-09-15 Univation Tech Llc Herstellung von polyethylen unter verwendung eines stereoisomeren metallocens
CN1067689C (zh) * 1995-10-20 2001-06-27 中国科学院化学研究所 一种用于合成高分子量聚乙烯的金属茂催化剂及其制备方法
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
US6255426B1 (en) * 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
AU8066498A (en) * 1997-06-14 1999-01-04 Board Of Trustees Of The Leland Stanford Junior University Ethylene enhancement of processes for synthesis of high melting thermoplast ic elastomeric alpha-olefin polymers (pre/epe effects)
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
FI973050A (fi) 1997-07-18 1999-01-19 Borealis As Menetelmä sellaisten olefiinipolymeerien valmistamiseksi joilla on haluttu molekyylipainojakauma
ES2191962T3 (es) 1997-07-28 2003-09-16 Basell Polyolefine Gmbh Procedimiento para la obtencion de metalocenos.
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
EP0953582A1 (en) 1998-04-27 1999-11-03 Fina Research S.A. Polyolefin production
US6207606B1 (en) * 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
ES2572756T3 (es) 1998-05-18 2016-06-02 Chevron Phillips Chemical Company Lp Proceso para la polimerización de un monómero con una composición de catalizador que contiene un compuesto organometálico, un compuesto de organoaluminio y un compuesto de óxido sólido tratado
FI990003A (fi) * 1999-01-04 2000-07-05 Borealis Polymers Oy Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot
WO2000050466A1 (en) * 1999-02-22 2000-08-31 Borealis Technology Oy Olefin polymerisation process
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
GB9917851D0 (en) * 1999-07-29 1999-09-29 Borealis As Process
US6380328B1 (en) * 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6372868B1 (en) * 1999-12-07 2002-04-16 Univation Technologies, Llc Start up methods for multiple catalyst systems
SK5492002A3 (en) * 1999-10-22 2002-12-03 Univation Tech Llc Start up methods for multiple catalyst systems
CN100484969C (zh) * 1999-10-22 2009-05-06 尤尼威蒂恩技术有限责任公司 聚合方法
IL149174A0 (en) 1999-10-22 2002-11-10 Univation Tech Llc Catalyst systems and their use in a polymerization process
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
JP2001320296A (ja) 2000-05-12 2001-11-16 Temuko Japan:Kk トランシーバ
US6897273B2 (en) 2000-12-04 2005-05-24 Univation Technologies, Llc Catalyst composition, method of polymerization and polymer therefrom
CZ20031553A3 (cs) * 2000-12-04 2003-11-12 Univation Technologies, Llc Způsob polymerace
US6605675B2 (en) * 2000-12-04 2003-08-12 Univation Technologies, Llc Polymerization process
US6608149B2 (en) 2000-12-04 2003-08-19 Univation Technologies, Llc Polymerization process
US20030008988A1 (en) * 2001-01-29 2003-01-09 Sasol Technology (Proprietary) Limited Polymerization
EP1416001A4 (en) * 2001-06-29 2005-03-09 Japan Polypropylene Corp CATALYST FOR POLYMERIZATION OF OLEFINS AND CORRESPONDING METHOD
JP3660623B2 (ja) * 2001-07-05 2005-06-15 株式会社東芝 アンテナ装置
JP4020862B2 (ja) * 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
JP4221363B2 (ja) * 2001-07-19 2009-02-12 ユニベーション・テクノロジーズ・エルエルシー 物性が向上したポリエチレンフィルム
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
US7060765B2 (en) * 2001-07-19 2006-06-13 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
JP2003105029A (ja) 2001-07-25 2003-04-09 Japan Polychem Corp オレフィン重合体及びその製造方法
US6642400B2 (en) * 2001-09-26 2003-11-04 Univation Technologies, Llc Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same
SG96700A1 (en) * 2001-09-27 2003-06-16 Sumitomo Chemical Co Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer
JP2003096124A (ja) * 2001-09-27 2003-04-03 Sumitomo Chem Co Ltd 付加重合用触媒成分、付加重合用触媒および付加重合体の製造方法、並びにメタロセン系遷移金属化合物の用途
JP2003096125A (ja) * 2001-09-27 2003-04-03 Sumitomo Chem Co Ltd 付加重合用触媒成分、付加重合用触媒および付加重合体の製造方法、並びにメタロセン系遷移金属化合物の用途
CN101037488B (zh) * 2001-11-15 2010-08-25 尤尼威蒂恩技术有限责任公司 利用先行指标的聚合监测和控制
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
RU2329272C2 (ru) * 2002-10-25 2008-07-20 Базелль Полиолефине Гмбх Рацемоселективное получение поддающихся выделению анса-металлоценовых бифеноксидных комплексов, имеющих относительно короткое время изомеризации
US6869903B2 (en) * 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
JP4343231B2 (ja) * 2003-10-15 2009-10-14 ユニベーション・テクノロジーズ・エルエルシー 重合方法及びポリマー組成物特性の調節
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
BRPI0508789A (pt) * 2004-04-07 2007-09-04 Union Carbide Chem Plastic método para preparar poliolefinas com um ìndice de fluxo de fundido e uma taxa de fluxo de fundido alvos
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
BRPI0513057A (pt) * 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US7193017B2 (en) 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US7432328B2 (en) * 2005-06-14 2008-10-07 Univation Technologies, Llc Enhanced ESCR bimodal HDPE for blow molding applications
GB0420396D0 (en) 2004-09-14 2004-10-13 Bp Chem Int Ltd Polyolefins
US7064096B1 (en) 2004-12-07 2006-06-20 Nova Chemicals (International) Sa Dual catalyst on a single support
MX2008000842A (es) * 2005-07-19 2008-04-04 Exxonmobil Chem Patents Inc Composiciones de polialfa-olefinas y procesos para producirlas.
WO2007011462A1 (en) * 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US7625982B2 (en) * 2005-08-22 2009-12-01 Chevron Phillips Chemical Company Lp Multimodal polyethylene compositions and pipe made from same
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US8247065B2 (en) * 2006-05-31 2012-08-21 Exxonmobil Chemical Patents Inc. Linear polymers, polymer blends, and articles made therefrom
ATE501185T1 (de) * 2006-06-27 2011-03-15 Univation Tech Llc Ethylen-alpha-olefin-copolymere und polymerisierungsverfahren für deren herstellung
RU2446179C2 (ru) * 2006-06-27 2012-03-27 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Усовершенствованные способы полимеризации с использованием металлоценовых катализаторов, полимерные продукты и их применение
CN101516931B (zh) 2006-06-27 2015-08-26 尤尼威蒂恩技术有限责任公司 用于滚塑和注塑制品的以茂金属催化剂制备的聚合物
US7569784B2 (en) * 2006-10-13 2009-08-04 Eaton Corporation Electrical switching apparatus, and housing and integral pole shaft bearing assembly therefor
WO2008060512A1 (en) * 2006-11-14 2008-05-22 Univation Technologies, Llc. Catalyst systems and polymerization processes
US7662894B2 (en) * 2006-12-19 2010-02-16 Saudi Bosic Industries Corporation Polymer supported metallocene catalyst composition for polymerizing olefins
TWI404730B (zh) * 2007-02-05 2013-08-11 Univation Tech Llc 控制聚合物性質之方法
WO2008105546A1 (en) * 2007-02-26 2008-09-04 Sumitomo Chemical Company, Limited Production process of olefin polymer
CN101679540B (zh) * 2007-05-02 2012-09-05 Lg化学株式会社 聚烯烃及其制备方法
TW200932762A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
TW200936619A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
RU2476446C2 (ru) * 2007-11-20 2013-02-27 Юнивейшн Текнолоджиз, Ллк Способ получения полиолефинов
JP5311805B2 (ja) 2007-11-21 2013-10-09 日本ポリエチレン株式会社 オレフィン重合用触媒及びそれを用いたオレフィンの重合方法
US8436114B2 (en) * 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
CN101939343B (zh) * 2007-12-18 2013-10-02 尤尼威蒂恩技术有限责任公司 聚合期间控制双峰催化剂活性的方法
BRPI0819552A2 (pt) 2007-12-31 2015-05-19 Dow Global Technologies Inc Processo para produzir um polímero a base de olefina
US20090240010A1 (en) 2008-03-20 2009-09-24 Mcdaniel Max P Alumina-silica activator-supports for metallocene catalyst compositions
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
ATE545664T1 (de) * 2008-04-28 2012-03-15 Univation Tech Llc Verfahren zur herstellung von katalysatorsystemen
CN102066441B (zh) * 2008-06-20 2014-03-12 埃克森美孚化学专利公司 高乙烯基封端的基于丙烯的低聚物
US8372930B2 (en) 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8580902B2 (en) * 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
EP2344551B1 (en) * 2008-09-25 2014-05-28 Basell Polyolefine GmbH Impact resistant lldpe composition and films made thereof
JP5752043B2 (ja) 2008-12-17 2015-07-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合用の触媒系、その製造、及び使用
BRPI1010927A2 (pt) * 2009-05-14 2016-04-05 Univation Tech Llc sistemas catalisadores de metal misturados que têm uma resposta de hidrogênio sob medida.
MX362816B (es) 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
MY158186A (en) 2009-07-28 2016-09-15 Univation Tech Llc Polymerization process using a supported constrained geometry catalyst
WO2011072851A1 (en) 2009-12-18 2011-06-23 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
SG182320A1 (en) * 2010-01-22 2012-08-30 Exxonmobil Chem Patents Inc Ethylene copolymers, methods for their production, and use
ES2693720T3 (es) * 2010-02-22 2018-12-13 Univation Technologies, Llc Sistemas catalíticos y métodos para usar los mismos para producir productos poliolefínicos
US8999875B2 (en) 2010-05-28 2015-04-07 Basell Polyolefine Gmbh Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
US8288487B2 (en) 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
US8932975B2 (en) 2010-09-07 2015-01-13 Chevron Phillips Chemical Company Lp Catalyst systems and methods of making and using same
CA2734167C (en) * 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
JP2013053308A (ja) * 2011-08-11 2013-03-21 Sumitomo Chemical Co Ltd オレフィン重合体の製造方法、エチレン系重合体および成形体
WO2013028283A1 (en) * 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
CN102382217B (zh) * 2011-08-30 2013-05-08 浙江大学 分子量可调的双峰或宽峰分布聚乙烯的制备方法
US9580533B2 (en) * 2011-09-23 2017-02-28 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
US9181371B2 (en) 2011-11-08 2015-11-10 Univation Technologies, Llc Methods for producing polyolefins with catalyst systems
CA2798855C (en) * 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2780508A1 (en) * 2012-06-21 2013-12-21 Nova Chemicals Corporation Polyethylene composition, film and polymerization process
ES2606684T3 (es) * 2012-11-07 2017-03-27 Chevron Phillips Chemical Company Lp Resinas de poliolefina de baja densidad y películas preparadas a partir de éstas
BR112015014121B1 (pt) * 2012-12-14 2021-04-06 Nova Chemicals (International) S.A. Copolímero de etileno, processo de polimerização de olefina para produzir um copolímero de etileno e camada de película
CN104822716B (zh) * 2012-12-21 2017-11-14 埃克森美孚化学专利公司 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜
WO2014123598A1 (en) * 2013-02-07 2014-08-14 Univation Technologies, Llc Preparation of polyolefin
CN105073794B (zh) * 2013-03-15 2018-04-20 尤尼威蒂恩技术有限责任公司 用于烯烃聚合的包含金属茂和基于三齿氮的配体络合物的多催化剂系统
US9156970B2 (en) * 2013-09-05 2015-10-13 Chevron Phillips Chemical Company Lp Higher density polyolefins with improved stress crack resistance
US9181370B2 (en) * 2013-11-06 2015-11-10 Chevron Phillips Chemical Company Lp Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom
CN106029710B (zh) * 2014-02-11 2019-08-30 尤尼威蒂恩技术有限责任公司 制造聚烯烃产物

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