JP4354987B2 - 基板処理装置 - Google Patents
基板処理装置 Download PDFInfo
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- JP4354987B2 JP4354987B2 JP2006510398A JP2006510398A JP4354987B2 JP 4354987 B2 JP4354987 B2 JP 4354987B2 JP 2006510398 A JP2006510398 A JP 2006510398A JP 2006510398 A JP2006510398 A JP 2006510398A JP 4354987 B2 JP4354987 B2 JP 4354987B2
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
- C23C16/345—Silicon nitride
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/448—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials
- C23C16/452—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials by activating reactive gas streams before their introduction into the reaction chamber, e.g. by ionisation or addition of reactive species
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
- C23C16/45542—Plasma being used non-continuously during the ALD reactions
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67109—Apparatus for thermal treatment mainly by convection
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- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical Vapour Deposition (AREA)
Description
少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成したことを特徴とする基板処理装置が提供される。
少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成したことを特徴とする基板処理装置が提供される。
前記一対の電極が基板の積層方向に亘って配置され、更に、前記電極の端部が、前記基板保持部材に保持される前記電極端部側の最端の基板位置よりも、少なくとも基板保持部材での基板同士の間隔分の長さを超えて設置されている。
この場合に、より好ましくは、前記電極の端部が、前記基板保持部材の天板の位置を超えた位置に設置されている。
少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成したことを特徴とする基板処理装置を使用して、基板を処理する工程を備える半導体装置の製造方法が提供される。
本発明の好ましい実施例においては、プラズマを発生させる電極は、少なくとも一箇所が屈曲した状態で保護管内に収容されると共に、可撓性の部材で構成されている。
電極を可撓性とすることにより、保護管内に挿入時に柔軟性を持たせることができると共に、熱膨張を抑制することができるためである。また、反応室の下から上まで均一な放電を行うために細長形状の電極を用いる場合でも、保護管に容易に着脱することができる。
また、特に500℃以上の高温雰囲気で用いる場合は、タングステン、モリブデンなどの高融点金属や炭素繊維なども好ましく用いられる。
ステップ1では、プラズマ励起の必要なNH3ガスと、プラズマ励起の必要のないDCSガスとを併行して流す。まずガス供給管232aに設けたバルブ243a、及びガス排気管231に設けたバルブ243dを共に開けて、ガス供給管232aからマスフローコントローラ241aにより流量調整されたNH3ガスをバッファ室237へ噴出し、電極269及び電極270間に高周波電源273から整合器272を介して高周波電力を0.1〜0.6kW印加してNH3をプラズマ励起し、活性種として処理室201に供給しつつガス排気管231から排気する。NH3ガスをプラズマ励起することにより活性種として流すときは、バルブ243dを適正に調整して処理室201内圧力を10〜100Paとする。マスフローコントローラ241aで制御するNH3の供給流量は1000〜10000sccmである。NH3をプラズマ励起することにより得られた活性種にウエハ200を晒す時間は1〜120秒間である。このときのヒータ207温度はウエハが300〜600℃になるよう設定してある。NH3ガスをプラズマで活性化する事によりウエハ表面を低温で処理することができる。
ステップ2では、ガス供給管232aのバルブ243aを閉めて、NH3の供給を止めた後、N2の不活性ガスで反応管203内をパージするが、その間も引続きガス溜め247へ供給を継続する。ガス溜め247に所定圧、所定量のDCSが溜まったら上流側のバルブ243bも閉めて、ガス溜め247にDCSを閉じ込めておく。また、ガス排気管231のバルブ243dは開いたままにし真空ポンプ246により、処理室201を十分に排気し、残留NH3を処理室201から排除する。
ステップ3では、処理室201の排気が終わったらガス排気管231のバルブ243dを閉じて排気を止める。ガス供給管232bの下流側のバルブ243cを開く。これによりガス溜め247に溜められたDCSが処理室201に一気に供給される。このときガス排気管231のバルブ243dが閉じられているので、処理室201内の圧力は急激に上昇して約931Pa(7Torr)まで昇圧される。DCSを供給するための時間は2〜4秒に設定し、その後上昇した圧力雰囲気中に晒す時間を2〜4秒に設定し、合計6秒とした。このときのウエハ温度はNH3の供給時と同じく、300〜600℃である。DCSの供給により、DCSが表面反応しN−H結合のHがSiと置換されて、ウエハ200上にSiN膜が成膜される。
ステップ3では、成膜後、バルブ243cを閉じ、バルブ243dを開けて処理室201を真空排気し、残留するDCSの成膜に寄与した後のガスを排除する。また、この時にはN2等の不活性ガスを処理室201に供給すると、更に残留するDCSの成膜に寄与した後のガスを処理室201から排除する効果が高まる。またバルブ243bを開いてガス溜め247へのDCSの供給を開始する。
その結果、本発明は、プラズマにより励起された処理ガスを利用して半導体ウエハに成膜を行う基板処理装置に特に好適に利用できる。
Claims (3)
- 少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成し、
前記電極は、線状の導電部材を編み込んで構成した部材を中空の円筒形状としたものであることを特徴とする基板処理装置。 - 少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成し、
前記電極は、線状の導電部材を束ねて構成した部材からなることを特徴とする基板処理装置。 - 少なくとも一つの基板を収容する処理室と、
前記処理室内に処理ガスを供給するガス供給系と、
前記処理室内の雰囲気を排気する排気系と、
前記処理ガスを活性な状態とするため、保護管内に挿抜可能に収容された、少なくとも一対の電極と、を有し、
前記電極は、少なくとも一箇所が屈曲した状態で前記保護管内に収容され、更に、前記電極は可撓性の部材で構成し、
前記電極は、線状の導電部材を編み込んで構成されており、
前記電極に芯を設けたことを特徴とする基板処理装置。
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JP2004055446 | 2004-02-27 | ||
JP2004055446 | 2004-02-27 | ||
PCT/JP2005/002306 WO2005083766A1 (ja) | 2004-02-27 | 2005-02-16 | 基板処理装置 |
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JP2009141686A Division JP5137903B2 (ja) | 2004-02-27 | 2009-06-12 | 基板処理装置、半導体装置の製造方法及び電極 |
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JPWO2005083766A1 JPWO2005083766A1 (ja) | 2007-11-29 |
JP4354987B2 true JP4354987B2 (ja) | 2009-10-28 |
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JP2009141686A Active JP5137903B2 (ja) | 2004-02-27 | 2009-06-12 | 基板処理装置、半導体装置の製造方法及び電極 |
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Country Status (5)
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US (2) | US7958842B2 (ja) |
JP (2) | JP4354987B2 (ja) |
KR (1) | KR100817644B1 (ja) |
TW (1) | TWI254989B (ja) |
WO (1) | WO2005083766A1 (ja) |
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