TWI254989B - An apparatus for process of a substrate - Google Patents
An apparatus for process of a substrate Download PDFInfo
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- TWI254989B TWI254989B TW094105522A TW94105522A TWI254989B TW I254989 B TWI254989 B TW I254989B TW 094105522 A TW094105522 A TW 094105522A TW 94105522 A TW94105522 A TW 94105522A TW I254989 B TWI254989 B TW I254989B
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- electrode
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- 239000000758 substrate Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title abstract description 20
- 238000012545 processing Methods 0.000 claims abstract description 110
- 230000001681 protective effect Effects 0.000 claims description 17
- 238000007599 discharging Methods 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 238000009941 weaving Methods 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 83
- 235000012431 wafers Nutrition 0.000 description 49
- 238000006243 chemical reaction Methods 0.000 description 26
- 238000012546 transfer Methods 0.000 description 26
- 238000003860 storage Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000000231 atomic layer deposition Methods 0.000 description 8
- 238000007789 sealing Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000006557 surface reaction Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45563—Gas nozzles
- C23C16/45578—Elongated nozzles, tubes with holes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
- C23C16/345—Silicon nitride
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/448—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials
- C23C16/452—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials by activating reactive gas streams before their introduction into the reaction chamber, e.g. by ionisation or addition of reactive species
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
- C23C16/45542—Plasma being used non-continuously during the ALD reactions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67109—Apparatus for thermal treatment mainly by convection
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Electromagnetism (AREA)
- Plasma & Fusion (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical Vapour Deposition (AREA)
Description
1254989 九、發明說明: 【發明所屬之技術領域】 本發明係關於基板處理裝置,尤其是,關於利用由電漿 所激發的處理氣體而於半導體晶圓上進行成膜的基板處理 裝置。 【先前技術】 在利用由電漿所激發的處理氣體而於半導體晶圓上進 行成膜的基板處理裝置,爲防止與處理氣體的反應,具有將 • 產生電漿的電極收容於保護管內的構造(參照日本國特開 2002-280378 號公報)° 【發明內容】 本發明者等發現了最好在此種構造的基板處理裝置 中,可均勻產生電漿,同時,容易安裝於裝置上之構造的電 極。 因此,本發明之目的在於,提供一種具備可均勻產生電 漿,同時,容易安裝於裝置上之構造的電極的基板處理裝置。 ^ 根據本發明之一態樣,提供一種基板處理裝置,其特徵 爲具有收容至少一片基板的處理室;將處理氣體供應給處理 室內的氣體供給系統;排出處理室內的環境氣體的排氣系 統;及爲將處理氣體設爲活性狀態而可插拔地收容於保護管 內的至少一對電極; 上述電極係以至少一處被彎曲的狀態收容於保護管 內,更且,上述電極係由可撓性構件所構成。 【實施方式】 1254989 根據本發明之較佳實施形態,提供一種基板處理裝置’ 其特徵爲具有收容至少一片基板的處理室;將處理氣體供應 給處理室內的氣體供給系統;排出處理室內的環境氣體的排 氣系統;及爲將處理氣體設爲活性狀態而可插拔地收容於保 護管內的至少一對電極; 上述電極係以至少一處被彎曲的狀態收容於保護管 內,更且,上述電極係由可撓性構件所構成。 最好電極係利用編結線狀之導電構件所構成。又,最好 • 於電極設置芯。 又,最好電極係將利用編結線狀之導電構件所構成的構 件設爲中空的圓筒形狀。 又,最好電極係由將線狀之導電構件形成束狀構成的構 件所構成。 又,最好一對電極的各電極分別可插拔地收容於另外的 保護管內。 又,最好一對電極的各電極的外徑,係較另外的保護管 •的各內徑小1至2 m m。 另外,最好基板處理裝置係在將以指定間隔疊層多片基 板而保持的基板保持構件收容於處理室內的狀態執行基板 處理的裝置, 上述一對電極係沿基板的疊層方向所配置,更且,電極 的端部係設置爲較保持於基板保持構件的電極端部側的最 端部的基板位置,至少還要超過在基板保持構件的基板彼此 的間隔量的長度。 1254989 在該情況,最好電極的端部設置在超過基板保持構件的 頂板位置的位置。 又,根據本發明之較佳實施形態,提供一種具備處理基 板之步驟的半導體裝置的製造方法,其使用特徵爲具有:收 容至少一片基板的處理室;將處理氣體供應給處理室內的氣 體供給系統;排出處理室內的環境氣體的排氣系統;及爲將 處理氣體成爲活性狀態而可插拔地收容於保護管內的至少 一對電極;上述電極係以至少一處被彎曲的狀態收容於保護 φ 管內,更且,上述電極係由可撓性構件,所構成的基板處理 裝置。 以下,說明本發明之較佳實施例。 在本發明之較佳實施例中,產生電漿的電極係以至少一 處被彎曲的狀態收容於保護管內,同時,由可撓性構件所構 成。 藉由將電極設爲可撓性,可在插入保護管內時保持柔軟 性,同時可抑制熱膨脹。另外,爲從反應室的下方至上方進 • 行均勻放電,即使在使用細長形狀的電極的情況,仍可容易 地於保護管拆裝。 另外,利用編結線狀之導電構件來構成產生電漿的電 極,可增大電極插入時的自由度,可使熱膨脹引起的變形少 者。又,可確保表面積,且高頻具有流動於物體表面的特性, 因此可有效產生電漿。尤其是,將電極加工爲圓筒形狀,可 獲得更好的效果。 藉由在產生電漿的電極設置芯,可不致縮短具有可撓性 1254989 的電極進行使用,可對多片晶圓供給更爲均勻的電漿。 又,最好由線狀之導電構件形成束狀構成的構件來構成 產生電漿的電極,利用此種構成,可容易實現剖面圓形的具 有彎曲性的細長形狀的電極。 又,作爲導電構件的一例,最好使用鐵、鎳、碳、金等 或包含此等的化合物。其中,若考慮耐熱性、金屬污染、價 格等因素,以使用鎳爲最佳。 另外,尤其在500°C以上的高溫環境內使用的情況,以 # 使用鎢、鉬等的高熔點金屬或碳纖維等爲較佳。 (實施例1) 以下,參照圖式進一步詳細說明本發明之實施例。 本實施例係針對作爲對晶圓等的基板進行製程處理例 而使用ALD(Atomic Layer Deposition)法的成膜處理,簡單 地說明之。 ALD法係在某成膜條件(溫度、時間等)下,將用於成膜 之2種類(或此以上)的原料組成的氣體,各一種類交錯地供 ® 給基板上,以1原子層單位進行吸附,利用表面反應進行成 膜的方法。 亦即,利用之化學反應,例如,在形成SiN(氮化矽)膜 的情況之ALD法,使用DCS(SiH2Cl2)與NH3(氫),以300 至600 °C的低溫進行高品質的成膜。另外,成膜所需要的原 料氣體係各一種類交錯地供給多種類的反應性氣體。另外, 膜厚控制係由供給反應性氣體的週期數所控制。(例如,當 成膜速度爲lA/週期時,在形成20A的膜的情況,進行2〇 1254989 週期的處理) 第1圖爲說明本實施例的基板處理裝置的縱型基板處理 爐用的槪要縱剖面圖,第2圖爲說明本實施例的基板處理裝 置的縱型基板處理爐用的槪要橫剖面圖。 在加熱手段的加熱器207的內側,設有作爲處理基板的 晶圓200的反應容器的反應管203,該反應管203的下端開 口由屬蓋體的密封帽蓋2 1 9,藉由氣密構件的〇形環(未圖 示)而氣密性封閉。在反應管203及加熱器207的外側設有 # 隔熱構件208。隔熱構件208係設置爲還覆蓋反應管203的 上方。至少由加熱器207、隔熱構件208、反應管203及密 封帽蓋219形成處理爐202。另外,由反應管203、密封帽 蓋219及後述之形成於反應管203內的緩衝室237形成處理 室201。在密封帽蓋219藉由載具台218及旋轉軸220立設 有屬基板保持手段的載具2 1 7,載具台2 1 8係形成爲保持載 具217的保持體。載具217係插入處理爐202內。在載具217 內,被分批處理的多片晶圓200呈水平姿勢沿管軸方向以多 ® 段疊載於垂直方向。加熱器207係將插入處理爐202內的晶 圓200加熱爲指定溫度。 在反應管203內的中央部設有將多片晶圓2〇〇以多段且 以相同間隔載置於垂直方向的載具2 1 7,該載具2 1 7係藉由 圖中省略的載具升降機機構而可出入於反應管203。另外, 爲提高處理的均勻性,設有旋轉載具2 1 7用的屬旋轉手段的 載具旋轉機構267,藉由旋轉載具旋轉機構267,可使保持 於載具台2 1 8的載具2 1 7旋轉。 1254989 另外,設有對處理爐202供給複數種類(在此爲2種類) 的氣體的作爲供給管的2根氣體供給管232a、23 2b。在此, 從氣體供給管232a藉由屬流量控制手段的流量控制器241a 及屬開閉閥的閥243a,更藉由後述之形成於反應管203內的 緩衝室237,將反應氣體供給處理室201,從氣體供給管23 2b 藉由屬流量控制手段的流量控制器24 1 b、屬開閉閥的閥 24 3b、儲氣部247及屬開閉閥的閥243c,並藉由氣體供給部 (未圖示),將反應氣體供給處理室201。 Φ 處理室201係藉由排放氣體的排氣管的氣體排氣管231 並藉由閥243d連接於排氣手段的真空泵246,用以進行真空 排氣。又,該閥243d係利用開閉閥而可進行處理室201的 真空排氣、停止真空排氣,並利用調節閥開啓度而可進行壓 力調整的開閉閥。 在構成處理室201之反應管203內壁及晶圓200之間的 圓弧狀空間,從反應管203的下部至上部的內壁沿著晶圓 200的疊置方向,設有屬氣體分散空間之緩衝室237,在與 ® 該緩衝室237的晶圓200相鄰的內側的壁端部近旁設有供給 氣體的屬供給孔的氣體供給孔248a。該氣體供給孔248a朝 反應管203的中心方向開口。該氣體供給孔248a沿著晶圓 2 00的疊置方向從下部至上部以指定長度分別具有相同的開 口面積,且以相同開口間距而設。 在與設有緩衝室2 3 7之氣體供給孔2 4 8 a側的相反側的 反應管203的側壁,連接有氣體供給管232a。 又,在緩衝室237配設有具有細長構造的電極269及電 -10- 1254989 I 極270,分別被從上部至下部保護電極的屬保護管的電極保 護管27 5所保護,該電極269或電極270的任一端藉由整合 器27 2連接於高頻電源27 3,而另一端連接於屬基準電位的 地線。該結果在電極2 6 9及電極2 7 0間的電漿生成區域2 2 4 生成電漿。 該電極保護管275形成爲在將電極269及電極270之各 者與緩衝室237的環境隔離的狀態下可插入緩衝室237的構 造。 • 在此,電極保護管275的內部,當爲與外部空氣(大氣) 相同的環境時,分別插入電極保護管275的電極269及電極 270,因加熱器207的加熱而被氧化。在此,電極保護管275 的內部設有充塡或鈍化氮氣等的惰性氣體,抑制氧氣濃度爲 充分低,用以防止電極269及電極270用的惰性氣體鈍化機 構(未圖示)。 本實施例中係將電極保護管2 7 5設爲在途中彎曲的構 造,緩衝室237內由從較最下端的晶圓2〇0更下側延伸至較 • 載具頂部2 1 6更上部的垂直部與其下的傾斜部所構成。傾斜 部的下端係從反應管203的側壁突出於外部。 電極2 6 9及電極2 7 0係藉由使用具有可撓性的構件,而 可從電極保護管275的傾斜部下端將電極269、270插入電 極保護管275內,同時,可使電極269、270到達電極保護 管275的上端部。 作爲電極2 6 9及電極2 7 0的一例,第3圖顯示將導電構 件加工爲薄板狀的構造。這爲使用一個具有可撓性的導電構 -11- 1254989 件的電極269及電極270的一例。該電極269、270係將導 電構件加工爲薄板狀者,在薄板的主面沿垂直方向可具備彎 曲性。因此即使爲電極269、270的插入口位於反應管203 的側面的構造,仍可將電極269、270插入電極保護管275。 另外,當將高頻電力施加於該電極269、270時,可產生電 漿2 24。但是也有薄板電極269、270在電極保護管275中產 生歪斜,以使電極269、270間的間隔在垂直方向上不成爲 一定,而使得電漿224變得不均勻的情況。 ϋ 接著,參照第4、5圖說明使用多個具有可彎曲性的導 電構件的電極269、270的例子。 首先,第4圖顯示將加工爲線狀的導電構件形成束狀的 電極269、270的構造。該電極269、270係使用將導電構件 加工爲線狀者,因此具有可撓性、彎曲性。 另外,第5圖顯示織入加工爲線狀的導電構件的構造的 例子。該電極269、270係形成爲織入多根導電構件,且於 其中心穿通芯271的構造。在織入型電極269、270內不具 Φ 備芯271的情況,電極269、270當於產生電漿224時進行 加熱,則有變軟且網眼堵塞,而向下方收縮的情況。另外’ 在將維護時暫時拔出的電極269、270再度插入電極保護管 275時,有變軟的電極269、270因與電極保護管275的摩擦 而收縮,而無法使電極269、270到達最上部的晶圓200的 情況。電極269、270到達最上部的晶圓200,則意味著在存 在有多個晶圓200的區域會出現無電漿224產生的部分或不 均勻的部分,從而有影響及成膜的懸念。在此,藉由將芯27 1 1254989 放入電極269、270的中心,即可成爲防止收縮的構造。 另外,作爲在上部晶圓200區域出現無電漿224產生的 部分的其他對策,如第1圖所示,以即使在電極269、270 收縮的情況仍可將電漿224供給最上面的晶圓200的方式, 朝上部方向增長電極269、270,以使來到較載具頂部216 更上部的位置。藉此,可將電極269、270插入較最上面的 晶圓200更高的位置,以便即使在由熱產生收縮的情況,仍 不會在存在有晶圓2Ό0的區域產生無電漿224產生的區域。 • 又,電極269、270的上部端的設置位置,係在至少較 最上面的晶圓200還要高出保持於載具217的晶圓200的保 持間隔以上的上側。如本實施形態般,以設置於超過載具頂 部2 1 6位置的位置爲較佳。 第4、5圖所示情況,當以成爲較電極保護管275的內 徑小1〜2mm的外形的方式製成電極269、270時,可殘留 插入電極269、270用的間隙,同時,可在電極269、270與 電極保護管27 5之間使沿橫方向歪斜的間隙消除,因此電極 ® 269、270保持筆直的形狀,可更爲均勻地產生電漿。 利用此種電極構造,可在反應管203內使用性良好且可 拆裝及安全運用生成均勻電漿用的細長形狀的電極269、 270 ° 在從氣體供給孔248a的位置旋轉120度的反應管203 的內側設有噴嘴2 3 3。該噴嘴2 3 3係在依ALD法的成膜中, 在將多種類的氣體,各一種類交錯供給晶圓200時,作爲分 擔緩衝室237與氣體供給種子的供給部。 Ί254989 該噴嘴2 3 3也與緩衝室2 3 7相同在與晶圓鄰接之位置具 有以相同間距供給氣體的屬供給孔的氣體供給孔248c,下部 連接有氣體供給管232b。 氣體供給孔248c的開口面積,在噴嘴23 3內與處理室 20 1的差壓小的情況,從上游側至下游側以相同的開口面積 且設爲相同的開口間距即可,但在差壓大的情況,可從上游 側朝向下游側增大開口面積或減小開口間距。 屬控制手段的控制器321係連接於流量控制器241a、 φ 241b、閥 243a、243b、243c、24 3d、加熱器 207、真空泵 24 6、 載具旋轉機構267、同中省略的載具升降機構、高頻電源 273、整合器272,用以進行流量控制器241a、241b的流量 調整、閥243a、243b、243c的開閉動作、閥243d的開閉及 壓力調整動作、加熱器207的溫度調節、真空泵246的啓動、 停止、載具旋轉機構267的旋轉速度調節、載具升降機構的 升降動作控制、高頻電源273的電力供給控制、依整合器272 的阻抗控制。 ^ 以下,針對依ALD法的成膜例,以使用DCS及NH3氣 體進行SiN膜的成膜爲例作說明。 首先,將欲成膜之晶圓200裝塡於載具217,搬入處理 爐202內。搬入後順序執行以下的4個步驟。 [步驟1 ] 在步驟1中,混合流動電漿激勵所必要的NH3氣體與電 漿激勵所不需的DC S氣體。首先,同時打開設於氣體供給 管23 2a的閥24 3a及設於氣體排氣管231的閥243d,從氣體 -14- 1254989 供給管23 2a將由流量控制器241a所進行流量調整的NH3氣 體噴出於緩衝室237內,在電極269及電極270之間,從高 頻電源273藉由整合器272施加0.1〜(K6Kw的高頻電力, 電漿激發NH3,作爲活性種子邊供給處理室20 1邊從氣體排 氣管排氣。在藉由電漿激發NH3氣體而作爲活性種子流動 時,適當調整閥243d而將處理室201內壓力設爲10〜 lOOPa。由流量控制器241a所控制的NH3的供給量,係1000 〜10000 seem。對藉由電漿激發NH3而獲得的活性種子曝露 • 晶圓200的時間爲1〜120秒。此時之加熱器207的溫度係 設定爲使晶圓成爲300〜600 °C。藉由以電漿活化NH3氣體 之方法,可以低溫處理晶圓表面。 在藉由電漿激發NH3而作爲活性種子予以供給時,打開 氣體供給管2 32b上游側的閥243b,關閉下游側的閥243c, 以使DCS也流動。藉此在設於閥243b、243c間的儲氣部247 蓄積DCS。此時,流動於處理室201內的氣體係爲藉由電漿 激發NH3而獲得的活性種子,不存在DCS。因此NH3不引 ® 起氣相反應,由電漿激發而成爲活性種子的NH3與晶圓200 上的襯底膜進行表面反應。 [步驟2 ] 在步驟2中,在關閉氣體供給管2 3 2a的閥243a而停止 NH3的供給後,雖由n2的惰性氣體鈍化反應管203內,但 其間還是繼續供給儲氣部247。當在儲氣部247蓄積有指定 壓力、指定量的DCS後,還關閉上游側的閥243b,將DCS 封入儲氣部247內。另外,氣體排氣管231的閥243 d在保 1254989 持爲打開的狀態下,藉由真空泵246充分對處理室201進行 排氣,以便從處理室201內排除殘留NH3。 [步驟3] 在步驟3中,在處理室201的排氣結束後,關閉氣體排 氣管231的閥243d以停止排氣。打開氣體供給管232b下游 側的閥243c。藉此,蓄積於儲氣部247內的DCS —氣被供 給處理室201。此時,因爲關閉氣體供給管232b的閥243d, 因此處理室 201 內的壓力急遽上升而升壓至約 φ 93 lPa(7Torr)。供給DCS用的時間係設定爲2〜4秒,且將 曝露在其後上升的壓力環境中的時間設定爲2〜4秒,合計 爲6秒。此時之晶圓溫度與NH3的供給時相同,爲300〜 600 °C。藉由DCS的供給,DCS進行表面反應,將N-H耦合 的Η取代爲Si,在晶圓200上成膜SiN膜。 [步驟4] 在步驟3中,在成膜後關閉閥243c,且打開閥243d, 對處理室201進行真空排氣,排除貢獻給殘留之DSC的成 • 膜後的氣體。另外,此時當將N2等的惰性氣體供給處理室 201時,可進一步提高從處理室201排除貢獻給殘留之DSC 的成膜後的氣體的效果。另外,打開閥243b而開始將DCS 供給儲氣部2 4 7。 將上述步驟1〜4作爲一個週期,利用多次重複該週期 而於晶圓上成膜指定膜厚的SiN膜。 又,在ALD裝置中,氣體吸附於襯底膜表面。該氣體 的吸附量與氣體的壓力及氣體的曝露時間成比例。因此爲了 -16- 1254989 在短時間內吸附希望的一定量的氣體,有必要在短時間內增 大氣體壓力。在該點上,本實施例中,係在關閉閥243d的 基礎上瞬間供給蓄積於儲氣部247內的DCS,因此可急遽提 高處理室201內的DCS的壓力,可瞬間吸附希望的一定量 的氣體。 另外,本實施例中,在蓄積DCS於儲氣部247內的期 間,藉由電漿激發屬在ALD法中需要的步驟的NH3氣體作 爲活性種子予以供給,及進行處理室20 1的排氣,因此無須 # 蓄積DCS用的特別步驟。另外,將處理室201內排氣以除 去NH3氣體後流動DCS,因此兩者在朝向晶圓200的途中不 發生反應。供給之DCS可僅在晶圓200的表面有效進行反 應。 其次,參照第6圖,作爲比較例,針對使用無可撓性的 電極27 6、277的情況的反應管構造進行說明。 如第6圖所示,在從下側插入電極276的情況,只能從 下部插入電極276,電漿只生成於緩衝室237的下方,因此 ^ 晶圓200的處理在載具217的上下均成爲不均勻。 其次,參照第7、8圖,說明本發明之能良好適用之基 板處理裝置的一例的半導體製造裝置的槪要。 在框體1 〇 1內部的前面側,設有在與未圖示的外部裝置 間進行作爲基板收容容器之匣盒1 〇〇的授受的屬保持具授受 構件的匣盒台1 05,在匣盒台1 05的後側設有作爲升降手段 的匣盒升降機115,在匣盒升降機115安裝有作爲搬運手段 的匣盒移載機1 1 4。又,在匣盒升降機1 1 5的後側設有作爲 1254989 匣盒100的載置手段的匣盒櫃109,同時在匣盒台105的上 方還設有預備匣盒櫃110。在預備匣盒櫃110的上方設有無 塵單元1 1 8,且以使無塵空氣流通於框體1 〇 1內部的方式所 構成。 在框體101後部上方設有處理爐202,在處理爐202的 下方設有作爲升降手段的載具升降機121,該載具升降機121 用以使呈水平姿勢多段保持作爲基板之晶圓200的屬基板保 持手段的載具217升降於處理爐202,在安裝於載具升降機 • 121的升降構件122的前端部安裝有作爲蓋體的密封帽 219,用以垂直支持載具217。在載具升降機121與匣盒櫃 109之間設有作爲升降手段的移載升降機113,在移載升降 機1 1 3設有作爲搬送手段的晶圓移載機1 1 2。又,在載具升 降機1 2 1的旁邊設有作爲遮蔽構件的爐口閘門1 1 6,該爐口 閘門1 1 6具有開閉機構且用以堵塞處理爐202的下面。 裝塡有晶圓200的匣盒1〇〇,係由未圖示的外部搬送裝 置以使晶圓200朝向上方的姿勢搬入匣盒台105,以晶圓200 ® 成爲水平姿勢的方式在匣盒台105旋轉90度。更且,匣盒 1 00係藉由匣盒升降機1 1 5的升降動作、橫行動作及匣盒移 載機1 1 4的進退動作、旋轉動作的協動,從匣盒台1 〇 5被搬 送至匣盒櫃109或預備匣盒櫃110。 在匣盒櫃109具有收容成爲晶圓移載機112的搬送對象 的匣盒1〇〇的移載櫃123,供晶圓200移載之匣盒1〇〇係藉 由匣盒升降機115、匣盒移載機114移載於移載櫃123。 當匣盒100移載於移載櫃123時,藉由晶圓移載機1 12 -18- 1254989 的進退動作、旋轉動作及移載升降機1 1 3的升降動作的協 動,從移載櫃123將晶圓200移載至降下狀態的載具217。 當將指定片數的晶圓200移載於載具217時,藉由載具 升降機121將載具217插入處理爐202內,藉由密封帽219 氣密性封閉處理爐202。在被氣密性封閉之處理爐202內加 熱晶圓200,同時將處理氣體供給處理爐202內,用以對晶 圓200進行處理。 當完成對晶圓200的處理時,晶圓200通過上述動作的 # 反向步驟,被從載具217移載於移載櫃123的匣盒100內, 匣盒1〇〇藉由匣盒移載機114而從移載櫃123移載於匣盒台 105,並藉由未圖示的外部搬送裝置搬出至框體1〇1的外部。 又,爐口閘門1 16在載具217降下狀態時處理爐202的下面, 以防止外部空氣進入處理爐202內。 匣盒移載機1 1 4等的搬送動作係由搬送控制手段1 24所 控制。 以上圖示且說明了種種典型之實施形態,但本發明並不 ® 限於此等實施形態。因此本發明之範圍係由以下的專利申請 範圍所限定。 綜上所述,根據本發明之較佳實施形態,提供一種具備 可均勻產生電漿,同時,容易安裝於裝置上之構造的電極的 基板處理裝置。 【圖式簡單說明】 第1圖爲說明本發明之實施例1的基板處理裝置的縱型 基板處理爐用的槪要縱剖面圖。 -19- 1254989 第2圖爲說明本發明之實施例1的基板處理裝置的縱型 基板處理爐用的槪要橫剖面圖。 第3圖爲說明本發明之實施例1的基板處理裝置的縱型 基板處理爐所使用的電漿產生用電極用的槪要圖。 第4圖爲說明本發明之實施例1的基板處理裝置的縱型 基板處理爐所使用的電漿產生用電極用的槪要圖。 第5圖爲說明本發明之實施例1的基板處理裝置的縱型 基板處理爐所使用的電漿產生用電極用的槪要圖。 B 第6圖爲說明比較用的縱型基板處理爐用的槪要縱音丨』_ 圖。 第7圖爲說明本發明之實施例1的基板處理裝釐用% _ 要立體圖。 第8圖爲說明本發明之實施例1的基板處理裝釐用@ _ 要縱剖面圖。 【元件符號說明】 100 匣 盒 101 框 體 105 匣 盒 台 109 匣 盒 櫃 1 10 預 備 匣 盒 櫃 112 晶 圓 移 載 機 113 移 載 升 降 機 114 匣 盒 移 載 機 115 匣 盒 升 降 機 -20- 1254989
116 118 12 1 122 123 124 200 201 202 203 207 208 2 16 217 2 18 2 19 220 224 23 1 232a 、 232b 233 237 241a、 241b 爐口閘門 無塵單元 載具升降機 升降構件 移載櫃 搬送控制手段 晶圓 處理室 處理爐 反應管 加熱器 隔熱構件 載具頂部 載具 載具台 密封帽蓋 旋轉軸 電漿生成區域 氣體排氣管 氣體供給管 噴嘴 緩衝室 流量控制器 243a 、 243b 、 243c 、 243d 1254989 246 真空泵 247 儲氣部 248a、248c 氣體供給孔 267 載具旋轉機構 269 、 270 電極 27 1 272 273 275 276
心 整合器 高頻電源 電極保護管 電極 321 控制器
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Claims (1)
1254989 十、申請專利範圍: 1. 一種基板處理裝置, 具有:收容至少一片基板的處理室;將處理氣體供應給 處理室內的氣體供給系統;排出處理室內的環境氣體的排 氣系統;及爲將處理氣體設爲活性狀態而可插拔地收容於 保護管內的至少一對電極,其特徵爲 上述電極係以至少一處被彎曲的狀態收容於保護管 內,更且,上述電極係由可撓性構件所構成。 # 2 .如申請專利範圍第1項之基板處理裝置,其中電極係利用 織入線狀導電構件所構成。 3 .如申請專利範圍第1項之基板處理裝置,其中電極係將利 用織入線狀導電構件所構成的構件形成中空的圓筒形狀 者。 4.如申請專利範圍第1項之基板處理裝置,其中電極係由將 線狀導電構件形成束狀構成的構件所構成。 5 .如申請專利範圍第1項之基板處理裝置,其中基板處理裝 ^ 置係在將以指定間隔疊層多片基板而保持的基板保持構 件收容於處理室內的狀態,執行基板處理的裝置, 上述一對電極係沿基板的疊層方向所配置,更且,電極的端 部,係設置爲較保持於基板保持構件的電極端部側的最端 部的基板位置,至少還要超過基板保持構件的基板彼此的 間隔量的長度。 6 ·如申請專利範圍第1項之基板處理裝置,其中一對電極的 各電極分別可插拔地收容於另外的保護管內。 -23 - 1254989 7 ·如申請專利範圍第6項之基板處理裝置,其中一對電極的 各電極的外徑,係較另外的保護管的各內徑小1至2mm。 8.如申請專利範圍第2項之基板處理裝置,其中於電極設置 心 0 9 ·如申請專利範圍第5項之基板處理裝置,其中電極的端部 設置在超過基板保持構件的頂板位置的位置。
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JP5137903B2 (ja) | 2013-02-06 |
KR100817644B1 (ko) | 2008-03-27 |
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US20110209664A1 (en) | 2011-09-01 |
TW200601455A (en) | 2006-01-01 |
US20080153308A1 (en) | 2008-06-26 |
JPWO2005083766A1 (ja) | 2007-11-29 |
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WO2005083766A1 (ja) | 2005-09-09 |
JP2009212528A (ja) | 2009-09-17 |
US7958842B2 (en) | 2011-06-14 |
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