JP2013150005A - 接着テープ及びそれを用いた太陽電池モジュール - Google Patents
接着テープ及びそれを用いた太陽電池モジュール Download PDFInfo
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- JP2013150005A JP2013150005A JP2013085057A JP2013085057A JP2013150005A JP 2013150005 A JP2013150005 A JP 2013150005A JP 2013085057 A JP2013085057 A JP 2013085057A JP 2013085057 A JP2013085057 A JP 2013085057A JP 2013150005 A JP2013150005 A JP 2013150005A
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- Prior art keywords
- solar cell
- cell module
- module according
- adhesive
- adhesive composition
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Abstract
【解決手段】
絶縁性接着剤組成物を含有する接着剤と金属箔とから形成された接続部材によって互いに電気的に接続された複数の太陽電池セルを有し、
前記絶縁性接着剤組成物が、熱硬化性樹脂、熱硬化性樹脂用硬化剤及びフィルム形成材を含有する、太陽電池モジュール。
【選択図】図1
Description
(1)接着テープの作製
フェノキシ樹脂(高分子量エポキシ樹脂)(ユニオンカーバイト社製、商品名「PKHC」)50gとエポキシ樹脂(ジャパンエポキシレジン社製、商品名「YL−980」)20g及びイミダゾール5gを酢酸エチル中に添加し、30質量%の酢酸エチル溶液を調製し、これに平均粒径2.5μmの毬栗状のNi粒子を、固形成分全体の体積に対して5体積%添加した。得られた混合液を厚み75μmの銅箔の片面にロールコーターを用いて塗布した。これを、110℃で5分間乾燥し、片面に厚み30μmの接着剤層が形成された金属箔を得た。これを幅2.0mmにスリットし、接着テープを得た。なお、接着剤層の厚みは、マイクロメータ(Mtutoyo Corp社製、ID−C112)を用いて測定した。
この接着テープを太陽電池セル(厚み150μm,15cm×15cm)上に形成されている電極配線(材質:銀ガラスペースト、2mm×15cm、Rz=10μm、Ry=14μm)の幅方向に合わせ、圧着ツール(装置名AC−S300、日化設備エンジニアリング社製)を用いて170℃,2MPaで,20秒間加熱加圧して、実施例1の接着テープ付き太陽電池セルを得た。
接着剤層の厚みを40μmとしたこと以外は実施例1と同様として、実施例2の接着テープ付き太陽電池セルを得た。
平均粒径2.5μmの毬栗状のNi粒子に代えて、平均粒子径5μmの金めっきNi粒子を用いたこと以外は実施例1と同様として、実施例3の接着テープ付き太陽電池セルを得た。
平均粒径2.5μmの毬栗状のNi粒子に代えて、平均粒子径が10μmの金/Niめっきプラスチック(スチレン−ブタジエン共重合体)粒子を、固形成分全体の体積に対して0.5体積%を用いたこと以外は実施例1と同様として、実施例4の接着テープ付き太陽電池セルを得た。
銅箔に代えてアルミニウム箔を用いたこと以外は実施例1と同様として、実施例5の接着テープ付き太陽電池セルを得た。
厚み75μmの銅箔に代えて、厚み175μmの銅箔を用いたこと以外は実施例1と同様として、実施例6の接着テープ付き太陽電池セルを得た。
Ni粒子を添加しなかったこと以外は実施例1と同様として、実施例7の接着テープ付き太陽電池セルを得た。
接着テープに代えてTAB線を用い、TAB線と電極配線とをはんだを用いて接続することにより、比較例1の接着テープ付き太陽電池セルを得た。
実施例1〜7及び比較例1で得られた接着テープ付き太陽電池セルについて太陽電池のF.F.(曲線因子)を測定した(初期値)。F.F.については、初期測定の終わったセルを85℃,85%RH下に暴露し、1500時間経過後の値も測定した(終値)。ワコム電創社製ソーラシミュレータ(WXS−155S−10,AM1.5G)を用いてIVカーブを測定し、初期値から終値を減じた値をDelta(F.F.)とした。なお、Delta(F.F.)が0.2以上の場合には、接続信頼性が十分でない。
Claims (16)
- 絶縁性接着剤組成物を含有する接着剤と金属箔とから形成された接続部材によって互いに電気的に接続された複数の太陽電池セルを有し、
前記絶縁性接着剤組成物が、熱硬化性樹脂、熱硬化性樹脂用硬化剤及びフィルム形成材を含有する、太陽電池モジュール。 - 前記フィルム形成材がフェノキシ樹脂である請求項1に記載の太陽電池モジュール。
- 前記フィルム形成材の重量平均分子量が10000〜10000000である、請求項1又は2に記載の太陽電池モジュール。
- 前記フィルム形成材の含有量が、前記絶縁性接着剤組成物の全量に対して2〜80質量%である、請求項1〜3のいずれか一項に記載の太陽電池モジュール。
- 前記熱硬化性樹脂がエポキシ樹脂である、請求項1〜4のいずれか一項に記載の太陽電池モジュール。
- 前記熱硬化性樹脂の含有量が、前記絶縁性接着剤組成物の全量に対して10〜80質量%である、請求項1〜5のいずれか一項に記載の太陽電池モジュール。
- 前記熱硬化性樹脂用硬化剤の含有量が、前記絶縁性接着剤組成物の全量に対して2〜10質量%である、請求項1〜6のいずれか一項に記載の太陽電池モジュール。
- 前記接着剤が導電性粒子を含有しない、請求項1〜7のいずれか一項に記載の太陽電池モジュール。
- 前記接着剤が導電性粒子をさらに含有する、請求項1〜7のいずれか一項に記載の太陽電池モジュール。
- 前記導電性粒子の含有量が、前記接着剤全体の体積に対して0.1〜20体積%である、請求項9に記載の太陽電池モジュール。
- 絶縁性接着剤組成物を含有する接着剤と金属箔とから形成された接続部材によって互いに電気的に接続された複数の太陽電池セルを有し、
前記絶縁性接着剤組成物が、熱可塑性樹脂、ラジカル重合性化合物及びラジカル重合開始剤を含有する、太陽電池モジュール。 - 前記熱可塑性樹脂がポリアミド類、フェノキシ樹脂類、ポリ(メタ)アクリレート類、ポリイミド類、ポリウレタン類、ポリエステル類又はポリビニルブチラール類である、請求項11に記載の太陽電池モジュール。
- 前記熱可塑性樹脂の重量平均分子量が5000〜150000である請求項11又は12に記載の太陽電池モジュール。
- 前記ラジカル重合性化合物が(メタ)アクリロイル基を有する、請求項11〜13のいずれか一項に記載の太陽電池モジュール。
- 請求項1〜14のいずれか一項に記載の太陽電池モジュールを製造する方法であって、
前記太陽電池セルと前記金属箔とを前記接着剤を用いて電気的に接続する工程を有する、太陽電池モジュールの製造方法。 - 請求項1〜14のいずれか一項に記載の太陽電池モジュールを製造するための前記接着剤の使用方法であって、
前記太陽電池セルと前記金属箔とを電気的に接続するために用いる、前記接着剤の使用方法。
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WO2015098872A1 (ja) * | 2013-12-26 | 2015-07-02 | 株式会社カネカ | 太陽電池のi‐v測定方法、太陽電池のi‐v測定装置、太陽電池の製造方法、太陽電池モジュールの製造方法、および太陽電池モジュール |
JPWO2015098872A1 (ja) * | 2013-12-26 | 2017-03-23 | 株式会社カネカ | 太陽電池のi‐v測定方法、太陽電池のi‐v測定装置、太陽電池の製造方法、太陽電池モジュールの製造方法、および太陽電池モジュール |
US10340848B2 (en) | 2013-12-26 | 2019-07-02 | Kaneka Corporation | I-V measurement device for solar cell, manufacturing method for solar cell, and solar cell module |
TWI667877B (zh) * | 2013-12-26 | 2019-08-01 | 日商鐘化股份有限公司 | Method for measuring solar cell IV, IV measuring device for solar cell, manufacturing method of solar cell, manufacturing method of solar cell module, and solar cell module |
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