CA2099214C - Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts - Google Patents

Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts Download PDF

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Publication number
CA2099214C
CA2099214C CA002099214A CA2099214A CA2099214C CA 2099214 C CA2099214 C CA 2099214C CA 002099214 A CA002099214 A CA 002099214A CA 2099214 A CA2099214 A CA 2099214A CA 2099214 C CA2099214 C CA 2099214C
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Prior art keywords
formula
group
compound
catalyst
polymerization
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CA002099214A
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French (fr)
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CA2099214A1 (en
Inventor
Frank Kuber
Bernd Bachmann
Walter Spaleck
Andreas Winter
Jurgen Rohrmann
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Basell Polyolefine GmbH
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Hoechst AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/14—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the side-chain of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/67—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having two rings, e.g. tetralones
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    • C07F17/00—Metallocenes
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    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
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    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA002099214A 1992-06-27 1993-06-25 Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts Expired - Fee Related CA2099214C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4221244.8 1992-06-27
DE4221244 1992-06-27

Publications (2)

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CA2099214A1 CA2099214A1 (en) 1993-12-28
CA2099214C true CA2099214C (en) 2005-08-30

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CA002099214A Expired - Fee Related CA2099214C (en) 1992-06-27 1993-06-25 Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts

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US (7) US5770753A (member.php)
EP (2) EP0576970B1 (member.php)
JP (2) JP3737134B2 (member.php)
KR (1) KR100283824B1 (member.php)
AT (2) ATE162194T1 (member.php)
AU (1) AU661587B2 (member.php)
CA (1) CA2099214C (member.php)
DE (2) DE59307969D1 (member.php)
ES (2) ES2169288T3 (member.php)
FI (1) FI107449B (member.php)
RU (1) RU2118961C1 (member.php)
TW (1) TW294669B (member.php)
ZA (1) ZA934577B (member.php)

Families Citing this family (331)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
TW294669B (member.php) * 1992-06-27 1997-01-01 Hoechst Ag
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
EP0584609B1 (de) * 1992-08-15 1999-03-10 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen
DE69412954T2 (de) 1993-01-11 1999-03-11 Mitsui Chemicals, Inc., Tokio/Tokyo Propylenpolymer zusammensetzung
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
KR100314971B1 (ko) * 1993-05-25 2002-07-03 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀중합을위한지지된메탈로센촉매시스템,그의제조방법및용도
DE69426043T3 (de) * 1993-06-07 2015-06-18 Mitsui Chemicals, Inc. Polypropylen
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
ATE198893T1 (de) * 1993-11-24 2001-02-15 Targor Gmbh Metallocene, verfahren zu ihrer herstellung und ihrer verwendung als katalysatoren
EP0668157B1 (de) 1994-02-21 2003-05-21 Basell Polyolefine GmbH Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung
AT401520B (de) * 1994-03-22 1996-09-25 Danubia Petrochem Polymere Metallocene und deren einsatz für die olefinpolymerisation
CN1104444C (zh) * 1994-04-11 2003-04-02 三井化学株式会社 丙烯聚合物组合物的制备方法
DE4416894A1 (de) * 1994-05-13 1995-11-16 Witco Gmbh Verfahren zur Synthese von Mono- und Dimethylmetallocenen und deren Lösungen speziell für den Einsatz zur Polymerisation von Olefinen
KR100378973B1 (ko) * 1994-06-24 2003-08-19 엑손모빌 케미칼 패턴츠 인코포레이티드 중합촉매시스템, 이의 제조방법 및 용도
JPH0848835A (ja) * 1994-08-08 1996-02-20 Mitsui Toatsu Chem Inc 耐劣化性熱可塑性樹脂組成物
DE4434640C1 (de) * 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
KR100368194B1 (ko) * 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
EP0785956B1 (en) * 1994-10-13 1999-04-28 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
TW383314B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
IT1272922B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti metallocenici
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
EP0739897A1 (de) 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
DE19516801A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
EP0745638A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit verbessertem Weiterreisswiderstand
EP0745477A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit verbessertem Migrationswiderstand
ES2150616T3 (es) * 1995-05-31 2000-12-01 Hoechst Ag Lamina de polipropileno biaxialmente orientada con una estabilidad dimensional mejorada.
JPH08325327A (ja) * 1995-06-02 1996-12-10 Chisso Corp 高立体規則性ポリプロピレン
DE19525178A1 (de) * 1995-07-11 1997-01-16 Basf Ag Verfahren zur Umwandlung der achiralen meso-Form eines ansa-Metallkomplexes in die chirale rac.-Form
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
DE59609748D1 (de) * 1995-12-18 2002-11-07 Basell Polyolefine Gmbh Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen
DE19548788A1 (de) 1995-12-27 1997-07-03 Hoechst Ag Folien und Schichten
US5908903A (en) 1995-12-27 1999-06-01 Basf Aktiengesellschaft Metallocene catalyst systems containing lewis bases
IT1282666B1 (it) 1996-02-22 1998-03-31 Enichem Spa Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
DE69710838T2 (de) * 1996-04-22 2002-10-31 Japan Polyolefins Co. Ltd., Tokio/Tokyo Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren
DE19617230A1 (de) 1996-04-30 1997-11-06 Basf Ag Oxidierte Metallocen-Polyolefin-Wachse
SG67392A1 (en) * 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same
DE19622481A1 (de) 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
AR009520A1 (es) * 1996-09-04 2000-04-26 Dow Chemical Co Interpolimeros de monomeros de alfa-olefinas/vinilideno aromaticas y/o monomeros alifaticos o de vinilidenocicloalifaticos y proceso para obtenerlos.
US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
PT835886E (pt) * 1996-10-09 2004-05-31 Atofina Res Processo para a preparacao e utilizacao de compostos de dicloreto de (bis(indenil)etano)zirconio meso/racemico
PT839836E (pt) * 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
ID21507A (id) * 1996-12-19 1999-06-17 Dow Chemical Co Kompleks logam yang mengandung indenil tersubstitusi pada 3-aril dan proses polimerisasinya
US5968864A (en) * 1996-12-20 1999-10-19 Fina Technology, Inc. Catalyst efficiency for supported metallocene catalyst
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
EP0856524A1 (en) * 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
US5789634A (en) * 1997-02-05 1998-08-04 Boulder Scientific Company Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst intermediates
US6465700B1 (en) * 1997-02-05 2002-10-15 Boulder Scientific Company Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst ligands
DE19707236A1 (de) 1997-02-24 1998-08-27 Targor Gmbh Katalysatorzusammensetzung
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR100624632B1 (ko) * 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US5789502A (en) * 1997-04-22 1998-08-04 Fina Technology, Inc. Process for co-polymerization of propylene and ethylene
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6252019B1 (en) * 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
JP2008121030A (ja) * 1997-08-15 2008-05-29 Chisso Corp 多分散性プロピレン重合体およびその製造方法
JP4119607B2 (ja) * 1997-08-15 2008-07-16 チッソ株式会社 多分散性プロピレン重合体およびその製造方法
DE19738051A1 (de) 1997-09-01 1999-03-04 Targor Gmbh Spritzgieß-Artikel aus Metallocen-Polypropylen
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
KR100458047B1 (ko) * 1997-12-29 2005-04-13 고려화학 주식회사 탈취효과를갖는황토가첨가된비닐바닥재의제조방법
DE19806918A1 (de) 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE19813657A1 (de) * 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE19813656A1 (de) 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Übergangsmetallverbindung
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
DE69918100T2 (de) 1998-05-13 2005-07-07 Exxonmobil Chemical Patents Inc., Baytown Propylenhomopolymere und herstellungsverfahren
WO1999061487A1 (de) * 1998-05-23 1999-12-02 Targor Gmbh Katalysatorsystem und seine verwendung zur polymerisation von propylen
KR100457722B1 (ko) * 1998-06-10 2005-02-23 고려화학 주식회사 게르마늄함유광물질이첨가된바닥재
US6037417A (en) † 1998-08-18 2000-03-14 Montell Technology Company Bv Polypropylene composition useful for making solid state oriented film
JP2000191862A (ja) * 1998-10-20 2000-07-11 Mitsui Chemicals Inc 軟質ポリプロピレン系重合体組成物およびその成形体
CN100340568C (zh) 1998-11-25 2007-10-03 塔戈尔股份有限公司 茂金属一卤化物
ES2192408T3 (es) 1998-11-25 2003-10-01 Basell Polyolefine Gmbh Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.
EP1361226A3 (de) 1998-11-25 2004-01-02 Basell Polyolefine GmbH Verfahren zur Aufreinigung von Metallocenen
DE19857292A1 (de) 1998-12-11 2000-06-15 Targor Gmbh Talkumverstärkte Polypropylen-Formmasse mit hoher Schlagzähigkeit
JP4446132B2 (ja) * 1999-02-09 2010-04-07 チッソ株式会社 押出ラミネートフィルムの製造方法
JP2000248015A (ja) * 1999-02-26 2000-09-12 Idemitsu Petrochem Co Ltd オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
EP1505181B1 (en) 1999-05-13 2008-10-29 ExxonMobil Chemical Patents Inc. Elastic fibers and articles made therefrom, including crystalline and crystallizable polymers of propylene
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
RU2160277C1 (ru) * 1999-06-21 2000-12-10 Институт химической физики РАН им. Н.Н. Семенова Анса-цирконоцены, функционализированные по циклосилановому мостику, и способ их получения
RU2160276C1 (ru) * 1999-06-21 2000-12-10 Институт химической физики им. Н.Н. Семенова РАН Анса-цирконоцены с непредельным циклосилановым мостиком и способ их получения
US6291699B1 (en) * 1999-08-24 2001-09-18 Boulder Scientific Company 2-alkyl-4-(2,6-dialkylphenyl) indenes
KR100448099B1 (ko) * 1999-10-12 2004-09-13 고려화학 주식회사 천연옥이 함유된 바닥재
EP1226206B1 (en) 1999-11-04 2003-10-22 ExxonMobil Chemical Patents Inc. Propylene copolymer foams and their use
US6420580B1 (en) * 1999-11-05 2002-07-16 Univation Technologies, Llc Catalyst compositions and method of polymerization therewith
US6809168B2 (en) 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6977287B2 (en) 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
EP1242483B1 (en) 1999-12-10 2005-04-20 ExxonMobil Chemical Patents Inc. Propylene diene copolymerized polymers
MXPA02006199A (es) 1999-12-22 2003-10-15 Exxon Chemical Patents Inc Composiciones adhesivas a base de polipropileno.
JP4901043B2 (ja) 1999-12-23 2012-03-21 バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 遷移金属化合物、配位子組成物、触媒組成物及びこれをオレフィンの重合及び共重合に使用する方法
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
RU2171814C1 (ru) * 1999-12-31 2001-08-10 Институт проблем химической физики РАН Иммобилизованный катализатор гомо- и сополимеризации олефинов, способ его получения и способ получения гомо- и сополимеров олефинов
ES2215879T3 (es) 2000-02-08 2004-10-16 Exxonmobil Chemical Patents Inc. Metodo de preparacion de ligandos de bisciclo-pentadienilo del grupo 14 con puente.
US6384142B1 (en) 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers
US6248833B1 (en) 2000-02-29 2001-06-19 Exxon Mobil Chemical Patents Inc. Fibers and fabrics prepared with propylene impact copolymers
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
DE10025412A1 (de) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
GB0015395D0 (en) * 2000-06-26 2000-08-16 Ciba Spec Chem Water Treat Ltd Stabilisation of light sensitive substances
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) * 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) * 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
ES2211808T3 (es) * 2000-06-30 2004-07-16 Exxonmobil Chemical Patents Inc. Compuestos puenteados de bis(indenil)metaloceno.
US6380123B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6414095B1 (en) * 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
DE10047461A1 (de) 2000-09-21 2002-04-11 Basf Ag Aminosäurekomplexe und ihre Verwendung zur Herstellung von Olefinpolymerisaten
CN1478122A (zh) * 2000-11-30 2004-02-25 埃克森美孚化学专利公司 用于精密注射成型应用的聚丙烯
DE60234067D1 (de) 2001-04-05 2009-12-03 Japan Polypropylene Corp Katalysator für Olefinpolymerisation und Verfahren zur Olefinpolymerisation
US6987196B2 (en) 2001-04-10 2006-01-17 Basell Polyolefine Gmbh Process for the production of monohalide or dihalide metallocene compounds
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
ATE519789T1 (de) 2001-06-12 2011-08-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von buten-1
WO2002100909A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP2005522406A (ja) * 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
JP2003128720A (ja) 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
JP4291693B2 (ja) * 2001-11-12 2009-07-08 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンを重合する方法および１−ブテンポリマー
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US7157591B2 (en) * 2001-12-10 2007-01-02 Exxonmobie Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
DE10200422A1 (de) * 2002-01-08 2003-07-17 Basell Polyolefine Gmbh Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen
JP4417719B2 (ja) 2002-01-08 2010-02-17 バーゼル・ポリオレフィン・ゲーエムベーハー シリコン橋状メタロセン化合物の製造
KR100450478B1 (ko) * 2002-03-11 2004-10-01 권혁성 송이 분말을 포함하는 장판
US7074865B2 (en) * 2002-04-12 2006-07-11 Dow Global Technologies Inc. Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
US20050182266A1 (en) * 2002-06-12 2005-08-18 Schulte Jorg L. Transition metal componds their preparation and their use in catalyst systems for the polymerization and copolymerization of olefins
WO2003106470A1 (en) * 2002-06-12 2003-12-24 Basell Polyolefine Gmbh Transition metal compounds their preparation and their use in catalyst systems for the polymerization and copolymerization of olefins
CN100343327C (zh) 2002-06-26 2007-10-17 巴塞尔聚烯烃意大利有限公司 抗冲击聚烯烃组合物
KR100921364B1 (ko) 2002-06-26 2009-10-14 바셀 폴리올레핀 이탈리아 에스.알.엘 내충격성 폴리올레핀 조성물
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
KR20100119802A (ko) 2002-08-16 2010-11-10 존슨 앤드 존슨 비젼 케어, 인코포레이티드 콘택트 렌즈 제조용 금형
EP1539843B1 (en) * 2002-09-06 2009-10-14 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7319125B2 (en) * 2002-09-20 2008-01-15 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7569647B2 (en) * 2002-10-10 2009-08-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
EP1554233A1 (en) * 2002-10-22 2005-07-20 Basell Polyolefine GmbH Preparation of substituted indenes
FR2846807A1 (fr) * 2002-10-31 2004-05-07 St Microelectronics Sa Circuit de commande de deux interrupteurs unidirectionnels en courant
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
JP2006512410A (ja) 2002-12-06 2006-04-13 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 有機金属遷移金属化合物、ビスシクロペンタジエニル配位子を有する化合物、触媒組成物、及びこれらを用いたポリオレフィンの製造法
KR200306360Y1 (ko) * 2002-12-14 2003-03-07 주식회사 신영데코 음이온 방출 장식용 시트
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
JP4742221B2 (ja) 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
US20070060727A1 (en) * 2003-09-11 2007-03-15 Basel Polyolefine Gmbh Multistep process for preparing heterophasic propylene copolymers
CN1878806A (zh) * 2003-09-11 2006-12-13 巴塞尔聚烯烃股份有限公司 制备多相丙烯共聚物的多步法
JP4590037B2 (ja) * 2003-09-30 2010-12-01 日本ポリプロ株式会社 オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
US7189790B2 (en) 2003-09-30 2007-03-13 Japan Polypropylene Corporation Catalyst component for olefin polymerization, catalyst for α-olefin polymerization and process for the production of α-olefin polymer
WO2005044911A1 (en) 2003-11-06 2005-05-19 Basell Poliolefine Italia S.R.L. Polypropylene composition
EP1735354A1 (en) * 2004-04-16 2006-12-27 Exxonmobil Chemical Company Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
US7285608B2 (en) * 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
EP1753792B1 (en) 2004-05-04 2009-10-14 Basell Polyolefine GmbH Process for the preparation of atactic 1-butene polymers
US8039540B2 (en) 2004-06-08 2011-10-18 Basell Poliolefine Italia S.R.L. Polyolefin composition having a high balance of stiffness, impact strength and elongation at break and low thermal shrinkage
JP4381898B2 (ja) * 2004-06-18 2009-12-09 三井化学株式会社 プロピレン系重合体、プロピレン系重合体の製造方法、及び塗装性材料
JP2008505198A (ja) * 2004-07-05 2008-02-21 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 重合触媒、主族配位化合物、ポリオレフィンの製造方法及びポリオレフィン
BRPI0513057A (pt) * 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
WO2006065844A2 (en) 2004-12-16 2006-06-22 Exxonmobil Chemical Patents Inc. Process for producing substituted metallocene compounds for olefin polymerization
JP5198872B2 (ja) 2004-12-17 2013-05-15 ダウ グローバル テクノロジーズ エルエルシー レオロジー改変相対的高溶融強度ポリエチレン組成物並びにパイプ、フィルム、シート、およびブロー成型品の製造方法
JP2008536813A (ja) 2005-03-18 2008-09-11 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
PL1858907T3 (pl) 2005-03-18 2009-04-30 Basell Polyolefine Gmbh Metalocenowe związki
BRPI0612170B1 (pt) 2005-03-23 2017-02-21 Basell Polyolefine Gmbh processo para a polimerização de olefinas
EP1861435B1 (en) 2005-03-23 2016-01-13 Basell Polyolefine GmbH Process for the polymerization of olefins
US20060247394A1 (en) * 2005-04-29 2006-11-02 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
EP1879959B1 (en) 2005-05-11 2011-07-06 Basell Poliolefine Italia S.r.l. Polymerization process for preparing polyolefin blends
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
RU2008101445A (ru) * 2005-06-13 2009-07-20 Базелль Полиолефине Гмбх (De) Способ сополимеризации пропилена
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
JP2007161876A (ja) * 2005-12-14 2007-06-28 Mitsui Chemicals Inc オレフィン系重合体およびその製造方法
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7763562B2 (en) * 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
ATE529431T1 (de) 2005-12-14 2011-11-15 Exxonmobil Chem Patents Inc Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
EP1996600B1 (en) * 2006-03-17 2011-09-28 Basell Polyolefine GmbH Metallocene compounds
WO2007116034A1 (en) 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
US20070255028A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US8110518B2 (en) * 2006-04-28 2012-02-07 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
RU2008122073A (ru) * 2006-05-02 2009-12-10 Дау Глобал Текнолоджиз Инк. (Us) Композиции полиэтилена высокой плотности, способ их получения, оболочки проводов и кабелей, изготовленные из них, и способ получения таких оболочек проводов и кабелей
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
WO2008077530A2 (en) * 2006-12-22 2008-07-03 Basell Polyolefine Gmbh Multimodal polyethylene composition, mixed catalyst and process for preparing the composition
US7256240B1 (en) 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
WO2008107135A1 (en) 2007-03-06 2008-09-12 Basell Polyolefine Gmbh Iron complexes and their use in polymerization processes
ES2383471T3 (es) 2007-04-09 2012-06-21 Exxonmobil Chemical Patents Inc. Composiciones heterogéneas y blandas de polipropileno isotáctico
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
ATE450569T1 (de) * 2007-05-02 2009-12-15 Dow Global Technologies Inc Hochdichte polyethylenzusammensetzungen, verfahren zu deren herstellung, daraus hergestellte einspritzgeformte artikel und verfahren zur herstellung derartiger artikel
EP2160419B1 (en) 2007-06-04 2013-11-13 ExxonMobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8133832B2 (en) * 2007-07-27 2012-03-13 Basell Polyolefine Gmbh Catalyst system for polymerization of olefinic monomers, process for preparing polymers, and polymers prepared by the process
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
EP2201042B1 (en) * 2007-09-13 2012-06-27 ExxonMobil Research and Engineering Company In-line blending of plasticizers with a base polymer
EP2195349B1 (en) * 2007-09-13 2012-07-11 ExxonMobil Research and Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
MX2010004470A (es) * 2007-10-25 2010-07-28 Lummus Novolen Technology Gmbh Sintesis racemoselectiva de compuestos de ansa-metaloceno, compuestos de ansa-metaloceno catalizadores que los comprenden, procesos para producir un polimero de olefina mediante el uso de los catalizadores y homo- y co-polimeros de olefina.
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
US8207281B2 (en) * 2007-12-18 2012-06-26 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefins polymerization
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN103254497B (zh) * 2007-12-20 2015-11-18 埃克森美孚研究工程公司 生产聚丙烯和乙烯-丙烯共聚物的共混物的在线共混方法
CN101945942B (zh) * 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
EP2236577A3 (en) 2008-02-18 2011-05-04 Basell Polyolefine GmbH Polyethylene article
RU2010139855A (ru) 2008-02-29 2012-04-10 Базелль Полиолефин Италия С.Р.Л. (It) Полиолефиновые композиции
EP2103634A1 (en) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Production of propylene-based polymers
JP5315773B2 (ja) 2008-04-24 2013-10-16 住友化学株式会社 プロピレン系樹脂組成物
BRPI0916813A2 (pt) 2008-07-23 2020-08-11 Basell Polyolefine Gmbh método para transição de sistemas incompatíveis de catalisador de polimerização de olefina
WO2010022941A1 (en) 2008-08-29 2010-03-04 Basell Polyolefine Gmbh Polyethylene for injection moldings
KR20110061584A (ko) 2008-09-25 2011-06-09 바젤 폴리올레핀 게엠베하 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름
RU2509782C2 (ru) 2008-09-25 2014-03-20 Базелль Полиолефине Гмбх Ударопрочная композиция лпэнп и полученные из нее пленки
JP5181104B2 (ja) * 2008-12-10 2013-04-10 株式会社プライムポリマー プロピレン系ブロック共重合体
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
CN102264773B (zh) 2008-12-23 2013-12-04 巴塞尔聚烯烃股份有限公司 不相容的烯烃聚合催化剂体系之间转变的方法
RU2011135979A (ru) 2009-01-30 2013-03-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиции полиэтилена высокой плотности, способ их получения, изготовленные из них укупоривающие изделия и способ изготовления таких укупоривающих изделий
CN102356100B (zh) 2009-03-30 2014-01-08 三井化学株式会社 烯烃与共轭二烯的共聚物及其制备方法
DE102009020090A1 (de) 2009-05-06 2010-11-11 Lanxess Deutschland Gmbh Reduktion des Einflusses der Wasseraufnahme auf die elektrische Leitfähigkeit von elektrisch leitfähigen Polyamid-Formmassen
WO2011041696A1 (en) 2009-10-02 2011-04-07 Dow Global Technologies Inc. Block composites and impact modified compositions
US8859451B2 (en) 2009-12-18 2014-10-14 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
PL2563957T3 (pl) 2010-04-30 2018-09-28 Basell Polyolefine Gmbh Polimerowy filament lub włókno
US20130137331A1 (en) 2010-06-15 2013-05-30 Galen C. Richeson Nonwoven Fabrics Made From Polymer Blends And Methods For Making Same
US9029478B2 (en) 2011-02-07 2015-05-12 Equistar Chemicals, Lp High clarity polyethylene films
US9469791B2 (en) 2011-04-28 2016-10-18 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
US8445620B2 (en) 2011-08-04 2013-05-21 Exxonmobil Research And Engineering Company Elastic propylene-alpha-olefin copolymer compositions and processes to produce them
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
US9321945B2 (en) 2011-09-30 2016-04-26 Equistar Chemicals, Lp Systems, methods and compositions for production of tie-layer adhesives
US10059081B2 (en) 2011-12-22 2018-08-28 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
WO2013125670A1 (ja) 2012-02-24 2013-08-29 日本ポリプロ株式会社 プロピレン－エチレン共重合体樹脂組成物並びにその成形体、フィルム及びシート
JP5883322B2 (ja) * 2012-03-26 2016-03-15 住友理工株式会社 樹脂製フューエルチューブ
EP2824107B1 (en) 2012-05-08 2017-01-18 Lg Chem, Ltd. Ansa-metallocene compound and method for preparing supported catalyst using same
EP2746320A1 (en) 2012-12-20 2014-06-25 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
ES2823768T3 (es) 2012-12-28 2021-05-10 Univation Tech Llc Métodos para integrar la producción de aluminoxano en la producción de catalizador
JP6015443B2 (ja) * 2012-12-30 2016-10-26 日本ポリプロ株式会社 架橋インデニル化合物の精製方法
CN103086834B (zh) * 2013-01-08 2015-05-27 上海化工研究院 一种联芳基茚类化合物的制备方法
KR102214265B1 (ko) 2013-01-14 2021-02-10 유니베이션 테크놀로지즈, 엘엘씨 증가된 생산성을 갖는 촉매 시스템의 제조 방법
JP5695687B2 (ja) * 2013-03-05 2015-04-08 日本ポリエチレン株式会社 エチレン／α−オレフィン共重合体の製造方法
WO2014204780A1 (en) 2013-06-18 2014-12-24 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
US11214036B2 (en) 2013-06-18 2022-01-04 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
SG11201510461SA (en) 2013-07-17 2016-01-28 Exxonmobil Chem Patents Inc Substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
JP2016530360A (ja) 2013-07-17 2016-09-29 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒を使用する方法およびそれに由来する生成物
CN105593249B (zh) 2013-10-14 2018-10-09 巴塞尔聚烯烃股份有限公司 耐热性提高的聚乙烯
MX2016012458A (es) 2014-03-28 2017-01-06 Mitsui Chemicals Inc Resina basada en olefina, metodo para producirla y composicion de resina basada en propileno.
WO2015161241A1 (en) 2014-04-18 2015-10-22 IFS Industries Inc. Low density and high performance packaging hot melt
JP5899269B2 (ja) * 2014-06-11 2016-04-06 ヤフー株式会社 生成装置、生成方法および生成プログラム
JP5901697B2 (ja) * 2014-06-11 2016-04-13 ヤフー株式会社 配信装置、配信方法および配信プログラム
JP2016050189A (ja) * 2014-08-31 2016-04-11 日本ポリエチレン株式会社 メタロセン化合物、それを用いるオレフィン重合触媒及びオレフィン重合体の製造方法
US10766981B2 (en) 2014-09-30 2020-09-08 Exxonmobil Chemical Patents Inc. Bimodal polypropylenes and method of making same
EP3204452A4 (en) 2014-10-06 2017-08-23 ExxonMobil Chemical Patents Inc. Thermoplastic polyolefin containing amorphous ethylene elastomer
KR102006096B1 (ko) 2015-05-08 2019-07-31 엑손모빌 케미칼 패턴츠 인코포레이티드 중합 방법
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
EP3375849A4 (en) 2015-11-09 2019-06-26 Mitsui Chemicals, Inc. VISCOSITY MODIFIER FOR LUBRICATING OILS, ADDITIVE COMPOSITION FOR LUBRICATING OILS, AND LUBRICATING OIL COMPOSITIONS
US10883197B2 (en) 2016-01-12 2021-01-05 Chevron Phillips Chemical Company Lp High melt flow polypropylene homopolymers for fiber applications
CN109312013A (zh) 2016-05-27 2019-02-05 埃克森美孚化学专利公司 茂金属催化剂组合物和使用其的聚合方法
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US10822481B2 (en) 2017-01-05 2020-11-03 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions with ethylene-propylene copolymers
JP2019172946A (ja) * 2017-05-26 2019-10-10 三井化学株式会社 プロピレン系重合体の製造方法
JP7223540B2 (ja) * 2017-09-27 2023-02-16 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
KR102001965B1 (ko) * 2017-10-12 2019-07-19 롯데케미칼 주식회사 폴리올레핀 촉매 및 이를 이용한 폴리올레핀 제조방법
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
KR102412130B1 (ko) 2017-12-26 2022-06-23 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법 및 이로부터 제조된 촉매를 이용하는 폴리프로필렌의 제조방법
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
CN112292406B (zh) * 2018-03-19 2023-04-04 博里利斯股份公司 烯烃聚合催化剂
EP3788081B1 (en) 2018-05-02 2025-07-02 ExxonMobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
US11383483B2 (en) 2018-07-26 2022-07-12 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
US11649331B2 (en) 2018-11-13 2023-05-16 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
US20220025135A1 (en) 2018-11-13 2022-01-27 Exxonmobil Chemical Patents Inc. Polyethylene Films
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
JP7572961B2 (ja) 2019-02-20 2024-10-24 フイナ・テクノロジー・インコーポレーテツド 低い反りを有するポリマー組成物
WO2020184421A1 (ja) 2019-03-12 2020-09-17 三井化学株式会社 オレフィン系樹脂、その架橋物およびそれらの製造方法
US11186665B2 (en) 2019-10-04 2021-11-30 Chevron Phillips Chemical Company Lp Catalyst composition and method for preparing polyethylene
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2021080803A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Impact copolymer compositions
EP4048729A1 (en) 2019-10-22 2022-08-31 Celanese International Corporation Thermoplastic vulcanizate compositions and processes for the production thereof
CN112745413B (zh) * 2019-10-30 2023-06-13 中国石油化工股份有限公司 一种茂金属聚丙烯的制备方法及装置
JP2023501982A (ja) 2019-10-30 2023-01-20 中国石油化工股▲ふん▼有限公司 メタロセン化合物及びその製造方法並びに適用
US12415911B2 (en) 2019-12-03 2025-09-16 Basell Polyolefine Gmbh Polyethylene composition for filaments or fibers
PT4069774T (pt) 2019-12-03 2024-02-05 Basell Polyolefine Gmbh Composição de polietileno para filamentos ou fibras
US20230018505A1 (en) 2019-12-17 2023-01-19 Exxonmobil Chemical Patents Inc. Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
WO2021195070A1 (en) 2020-03-26 2021-09-30 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers
CN115667392A (zh) 2020-06-15 2023-01-31 埃克森美孚化学专利公司 包含两种丙烯基聚合物的组合以及含有该组合的组合物
KR102733546B1 (ko) * 2020-08-04 2024-11-21 주식회사 엘지화학 전이 금속 화합물, 이의 제조방법, 및 이를 포함하는 촉매 조성물
WO2022203463A1 (ko) * 2021-03-26 2022-09-29 주식회사 엘지화학 폴리프로필렌 수지 조성물 및 이로부터 제조된 부직포
WO2022203461A1 (ko) * 2021-03-26 2022-09-29 주식회사 엘지화학 폴리프로필렌 수지 조성물 및 그의 제조방법
KR20240001127A (ko) 2021-04-26 2024-01-03 피나 테크놀러지, 인코포레이티드 얇은 단일-부위 촉매화된 중합체 시트
US20240209124A1 (en) 2021-04-30 2024-06-27 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
CN113667042B (zh) * 2021-08-28 2022-02-11 潍坊驼王实业有限公司 一种熔喷无纺布的制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
ES2091273T3 (es) * 1990-11-12 1996-11-01 Hoechst Ag Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
ES2090209T3 (es) 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒
TW300901B (member.php) * 1991-08-26 1997-03-21 Hoechst Ag
ATE286918T1 (de) * 1991-10-15 2005-01-15 Basell Polyolefine Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
CA2081432A1 (en) * 1991-10-28 1993-04-29 Eric Johannes Maria De Boer Catalyst composition
TW309523B (member.php) * 1991-11-30 1997-07-01 Hoechst Ag
TW318184B (member.php) * 1991-11-30 1997-10-21 Hoechst Ag
TW294669B (member.php) * 1992-06-27 1997-01-01 Hoechst Ag
EP0584609B1 (de) * 1992-08-15 1999-03-10 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen
DE69426043T3 (de) * 1993-06-07 2015-06-18 Mitsui Chemicals, Inc. Polypropylen
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
US5847176A (en) * 1997-06-30 1998-12-08 Boulder Scientific Company Preparation of chiral titanocenes

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DE59310245D1 (de) 2002-01-17
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AU661587B2 (en) 1995-07-27
EP0576970B1 (de) 1998-01-14
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