ES2192408T3 - Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos. - Google Patents

Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.

Info

Publication number
ES2192408T3
ES2192408T3 ES99960984T ES99960984T ES2192408T3 ES 2192408 T3 ES2192408 T3 ES 2192408T3 ES 99960984 T ES99960984 T ES 99960984T ES 99960984 T ES99960984 T ES 99960984T ES 2192408 T3 ES2192408 T3 ES 2192408T3
Authority
ES
Spain
Prior art keywords
manufacture
metallocenes
ansa
polymerization
monoariloxi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99960984T
Other languages
English (en)
Inventor
Carsten Bingel
Hans-Herbert Brintzinger
Hans-Robert-Hellmuth Damrau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1999112576 external-priority patent/DE19912576A1/de
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2192408T3 publication Critical patent/ES2192408T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

Procedimiento para la fabricación de monoariloxi-ansa-metalocenos. La presente invención hace referencia a un procedimiento de síntesis para la fabricación de monoariloxiansa-metalocenos así como a su utilización en la polimerización de olefinas. Los metalocenos pueden, si se diera el caso en combinación con uno o varios cocatalizadores, ser empleados como componentes del catalizador para la polimerización y copolimerización de las olefinas. En especial, se emplean los metalocenos que contienen halógenos como etapas previas del catalizador, ya que por ejemplo, pueden transformarse en un complejo del metaloceno catiónico activo en la polimerización a través de un aluminoxano.
ES99960984T 1998-11-25 1999-11-18 Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos. Expired - Lifetime ES2192408T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19854350 1998-11-25
DE1999112576 DE19912576A1 (de) 1999-03-19 1999-03-19 Verfahren zur Herstellung von Monoaryloxy-Ansa-Metallocenen

Publications (1)

Publication Number Publication Date
ES2192408T3 true ES2192408T3 (es) 2003-10-01

Family

ID=26050368

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99960984T Expired - Lifetime ES2192408T3 (es) 1998-11-25 1999-11-18 Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.

Country Status (7)

Country Link
US (1) US6620953B1 (es)
EP (1) EP1133504B1 (es)
JP (1) JP2002530416A (es)
BR (1) BR9915708B1 (es)
DE (1) DE59904565D1 (es)
ES (1) ES2192408T3 (es)
WO (1) WO2000031091A1 (es)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000031089A1 (de) 1998-11-25 2000-06-02 Basell Polyolefine Gmbh Verfahren zur aufreinigung von metallocenen
DE59914158D1 (de) * 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
WO2001053201A1 (en) 2000-01-21 2001-07-26 U.S. Borax Inc. Nonaborate compositions and their preparation
US7122498B2 (en) * 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6376412B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
DE10200422A1 (de) * 2002-01-08 2003-07-17 Basell Polyolefine Gmbh Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen
WO2004037840A1 (en) * 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl) zirconium componds
DE10250025A1 (de) * 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe
AU2003293887A1 (en) * 2002-12-16 2004-07-09 Basell Polyolefine Gmbh Preparation of supported catalyst systems containing reduced amounts of aluminoxanes
WO2004056481A1 (en) * 2002-12-20 2004-07-08 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
DE10360060A1 (de) * 2003-12-19 2005-07-21 Basell Polyolefine Gmbh Verfahren zur meso-selektiven Synthese von anso-Metallocen
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004022861A1 (de) * 2004-05-06 2005-12-01 Basell Polyolefine Gmbh Verfahren zur racemo-selectiven Herstellung von ansa-Metallocenen
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
CN101652178B (zh) 2007-03-06 2014-08-27 巴塞尔聚烯烃股份有限公司 铁络合物及其在聚合方法中的用途
DE102007017903A1 (de) * 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
US20100093953A1 (en) * 2007-05-04 2010-04-15 Basell Polyolefine Gmbh Polyethylene, process and catalyst composition for the preparation thereof
WO2009015804A1 (en) * 2007-07-27 2009-02-05 Basell Polyolefine Gmbh Catalyst system for polymerization of olefinic monomers, process for preparing polymers and polymers prepared by the process
WO2009050037A1 (en) * 2007-10-19 2009-04-23 Basell Polyolefine Gmbh Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands
US8207281B2 (en) * 2007-12-18 2012-06-26 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefins polymerization
EP2222720B1 (en) 2007-12-19 2016-02-10 Basell Polyolefine GmbH Mono-hydroindacenyl complexes
CN101903418A (zh) * 2007-12-21 2010-12-01 巴塞尔聚烯烃股份有限公司 包含菲咯啉的络合物
US8435911B2 (en) * 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
EP2536735B1 (en) * 2010-02-19 2018-08-01 Dow Global Technologies LLC Metal-ligand complexes and catalysts
EP3039026A4 (en) * 2013-08-28 2016-08-24 Exxonmobil Chem Patents Inc RACEMIC SELECTIVITY METALLIZATION METHOD
US9376518B2 (en) 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
ES2093166T3 (es) 1991-11-30 1996-12-16 Hoechst Ag Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.
US5245623A (en) 1991-12-02 1993-09-14 Hughes Aircraft Company Infrared-to-visible upconversion display system and method operable at room temperature
TW294669B (es) 1992-06-27 1997-01-01 Hoechst Ag
DE4406109A1 (de) 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
US5597935A (en) 1994-06-01 1997-01-28 University Of Iowa Research Foundation Synthesis of ansa-metallocene catalysts
JP3143347B2 (ja) 1994-12-30 2001-03-07 ワイケイケイ株式会社 スナップボタン
DE19547147A1 (de) 1995-01-14 1996-07-18 Volkswagen Ag Vorrichtung zur Lagerung einer Abtriebswelle in einem Getriebegehäuse eines Kraftfahrzeuges
US5556997A (en) 1995-04-24 1996-09-17 Albemarle Corporation Enhanced synthesis of racemic metallocenes
EP0780396B1 (de) 1995-12-18 2002-10-02 Basell Polyolefine GmbH Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen
BR9808827B1 (pt) 1997-03-07 2009-12-01 processo para a preparação de indanonas, e, uso de uma indanona.
DE59914158D1 (de) * 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
WO2000031089A1 (de) * 1998-11-25 2000-06-02 Basell Polyolefine Gmbh Verfahren zur aufreinigung von metallocenen

Also Published As

Publication number Publication date
WO2000031091A1 (de) 2000-06-02
DE59904565D1 (de) 2003-04-17
EP1133504B1 (de) 2003-03-12
JP2002530416A (ja) 2002-09-17
BR9915708B1 (pt) 2010-07-13
BR9915708A (pt) 2001-08-14
EP1133504A1 (de) 2001-09-19
US6620953B1 (en) 2003-09-16

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