SG11201510461SA - Substituted metallocene catalysts - Google Patents

Substituted metallocene catalysts

Info

Publication number
SG11201510461SA
SG11201510461SA SG11201510461SA SG11201510461SA SG11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA
Authority
SG
Singapore
Prior art keywords
metallocene catalysts
substituted metallocene
substituted
catalysts
metallocene
Prior art date
Application number
SG11201510461SA
Inventor
Jo Ann M Canich
Ilya S Borisov
Arkady K Golenishchev
Georgy P Goryunov
Dmitry V Uborsky
Pavel S Kulyabin
Dmitry S Kononovich
Vyatcheslav V Izmer
Alexander Z Voskoboynikov
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of SG11201510461SA publication Critical patent/SG11201510461SA/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/09Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
SG11201510461SA 2013-07-17 2014-07-08 Substituted metallocene catalysts SG11201510461SA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361847442P 2013-07-17 2013-07-17
PCT/US2014/045652 WO2015009479A1 (en) 2013-07-17 2014-07-08 Substituted metallocene catalysts

Publications (1)

Publication Number Publication Date
SG11201510461SA true SG11201510461SA (en) 2016-01-28

Family

ID=52344082

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201510461SA SG11201510461SA (en) 2013-07-17 2014-07-08 Substituted metallocene catalysts

Country Status (7)

Country Link
US (1) US9458254B2 (en)
EP (1) EP3022234B1 (en)
JP (1) JP2016531978A (en)
CN (2) CN110845546A (en)
ES (1) ES2715831T3 (en)
SG (1) SG11201510461SA (en)
WO (1) WO2015009479A1 (en)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
WO2015009480A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US20160122452A1 (en) 2013-07-17 2016-05-05 Exxonmobil Chemical Patents Inc. Ethylene-Propylene Copolymeric Compositions With Long Methylene Sequence Lengths
EP3022234B1 (en) 2013-07-17 2018-12-26 ExxonMobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358589B (en) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 Metallocene and by its derivative carbon monoxide-olefin polymeric
EP3204452A4 (en) 2014-10-06 2017-08-23 ExxonMobil Chemical Patents Inc. Thermoplastic polyolefin containing amorphous ethylene elastomer
CN110845801B (en) 2015-01-14 2023-01-03 埃克森美孚化学专利公司 Polymer composition and process for producing the same
US10815326B2 (en) 2016-01-19 2020-10-27 Exxonmobil Chemical Patents Inc. High molecular weight multimodal elastomer compositions with good processability
US20180362684A1 (en) 2016-01-22 2018-12-20 Exxonmobil Chemical Patents Inc. High Viscosity Metallocene Polymers with Low Volatiles Content
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US11352451B2 (en) 2016-07-13 2022-06-07 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
JP6936303B2 (en) 2016-07-14 2021-09-15 エクソンモービル・ケミカル・パテンツ・インク Bimodal copolymer composition polymerized with a binary metallocene catalyst
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018044395A1 (en) 2016-08-31 2018-03-08 Exxonmobil Chemical Patents Inc. Spiral heat exchanger as a preheater in polymer devolatilization processes
WO2018057124A1 (en) 2016-09-23 2018-03-29 Exxonmobil Chemical Patents Inc. Shrinkable thermoplastic vulcanizate and method and article
US10364308B2 (en) 2016-12-08 2019-07-30 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions
US10513601B2 (en) 2017-01-05 2019-12-24 Exxonmobil Chemical Patents Inc. Ethylene-propylene copolymers with amorphous and semi-crystalline components
US10822481B2 (en) 2017-01-05 2020-11-03 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions with ethylene-propylene copolymers
KR102271789B1 (en) * 2017-02-20 2021-06-30 엑손모빌 케미칼 패턴츠 인코포레이티드 Supported catalyst systems and methods of use thereof
US10508179B2 (en) 2017-02-28 2019-12-17 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM
JP6921563B2 (en) * 2017-03-07 2021-08-18 出光興産株式会社 Method for Producing Transition Metal Compounds and Olefin Polymers
EP3609934B1 (en) 2017-04-14 2023-04-05 ExxonMobil Chemical Patents Inc. Elastomeric compositions comprising epdm and epr
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
EP3647329B1 (en) * 2017-06-30 2024-05-29 Mitsui Chemicals, Inc. Propylene-based polymer, method for preparing same, propylene-based resin composition, and molded body
WO2019045878A1 (en) 2017-08-29 2019-03-07 Exxonmobil Chemical Patents Inc. Carbon dioxide as a catalyst quench agent in solution polymerization, and products made therefrom
CN111278872B (en) * 2017-10-23 2022-10-28 埃克森美孚化学专利公司 Polyethylene compositions and articles made therefrom
US11001657B2 (en) 2017-10-25 2021-05-11 Exxonmobil Chemical Patents Inc. Unbridged indacenyl metallocenes
US20200362263A1 (en) 2017-11-21 2020-11-19 Exxonmobil Chemical Patents Inc. Bimodal Copolymer Compositions Useful as Oil Modifiers
CN111417657B (en) * 2017-11-29 2022-11-25 埃克森美孚化学专利公司 Asymmetric ansa-metallocene catalyst compounds for the preparation of polyolefins having broad molecular weight distribution
CN111630102B (en) 2017-12-08 2023-04-21 埃克森美孚化学专利公司 Elastomeric terpolymer compositions for corner forming applications
JP7295112B2 (en) 2017-12-13 2023-06-20 シェブロン・オロナイト・カンパニー・エルエルシー Bimodal copolymer compositions useful as oil modifiers and lubricating oils containing the same
EP3752538A1 (en) 2018-02-12 2020-12-23 ExxonMobil Chemical Patents Inc. Metallocene catalyst feed system for solution polymerization process
CA3090994A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
US12006423B2 (en) 2018-08-29 2024-06-11 ExxonMobil Engineering & Technology Company Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes
EP3887414A4 (en) * 2018-11-29 2021-12-29 ExxonMobil Chemical Patents Inc. Poly(alpha-olefin)s and methods thereof
WO2021011911A1 (en) 2019-07-17 2021-01-21 Exxonmobil Chemical Patents Inc. Ethylene-based copolymer and propylene-alpha-olefin-diene compositions for use in layered articles
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US11325995B2 (en) * 2020-02-21 2022-05-10 Chevron Phillips Chemical Company Lp Metallocene catalysts for polyethylene
US11613593B2 (en) 2020-02-24 2023-03-28 Exxonmobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
US11766669B2 (en) 2020-06-26 2023-09-26 Exxonmobil Chemical Patents Inc. Hexahydrocyclopenta[e]-as-indacen-1-yl and octahydrobenzo[e]-as-indacen-1-yl based catalyst complexes and process for use thereof
EP4247825A1 (en) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
WO2022207551A1 (en) 2021-03-29 2022-10-06 Arlanxeo Netherlands B.V. Process for producing polymers
US20240100816A1 (en) * 2021-04-01 2024-03-28 Borealis Ag Biaxially oriented polypropylene-based multilayer film
WO2022240965A1 (en) 2021-05-14 2022-11-17 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers
WO2022240946A1 (en) 2021-05-14 2022-11-17 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers used as viscosity modifiers
CN117916277A (en) 2021-09-02 2024-04-19 埃克森美孚化学专利公司 Modification of C1 symmetric metallocene catalysts for the production of vinyl terminated polypropylene oligomers and macromers
WO2023217397A1 (en) 2022-05-09 2023-11-16 Arlanxeo Netherlands B.V. Process for producing polymers
CN114736099B (en) * 2022-05-18 2023-06-06 江苏南大光电材料股份有限公司 Preparation method of 1- (tertiary butyl) -3-chloronaphthalene

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5337644A (en) 1976-09-14 1978-04-06 Mitsubishi Chem Ind Ltd Transition metal complexes of 5,6-diaminocalicenes
FI59934C (en) 1978-07-05 1981-11-10 Suovaniemi Finnpipette FOERFLYTTNINGSANORDNING FOER ANALYSANLAEGGNINGAR
DE3772331D1 (en) 1986-11-13 1991-09-26 Idemitsu Kosan Co METHOD FOR OLIGOMERIZING PROPEN.
IT8919252A0 (en) 1989-01-31 1989-01-31 Ilano CATALYSTS FOR THE POLYMERIZATION OF OLEFINS.
EP0485821B1 (en) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocenes with 2-substituted indenyl-derivates as ligands, process for their preparation and their use as catalysts
TW300901B (en) 1991-08-26 1997-03-21 Hoechst Ag
TW294669B (en) 1992-06-27 1997-01-01 Hoechst Ag
DE59308494D1 (en) 1992-08-03 1998-06-10 Targor Gmbh Process for the preparation of an olefin polymer using metallocenes with specially substituted indenyl ligands
EP0629631B1 (en) 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Novel transition metal compound, and polymerization catalyst containing it
US5459117A (en) 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333128A1 (en) 1993-09-29 1995-03-30 Hoechst Ag Process for the preparation of polyolefins
DE4344689A1 (en) 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound
DE4344688A1 (en) 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound
DE4406963A1 (en) 1994-03-03 1995-09-07 Basf Ag Metallocene complexes with heterofunctional groups on the cyclopentadienyl system
IT1272923B (en) 1995-01-23 1997-07-01 Spherilene Srl METALLOCENIC COMPOUNDS, PROCEDURE FOR THEIR PREPARATION, AND THEIR USE IN CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
JPH08239416A (en) * 1995-03-02 1996-09-17 Mitsui Petrochem Ind Ltd New transition metal compound and olefin polymerization catalyst component comprising same
US6399533B2 (en) 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
WO1997038024A1 (en) * 1996-04-09 1997-10-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst, olefin polymerization method, olefin polymer compositions, and thermoformed articles
DE69710838T2 (en) 1996-04-22 2002-10-31 Japan Polyolefins Co Ltd POLYOLEFIN PRODUCTION CATALYST AND POLYOLEFIN PRODUCTION METHOD
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
FI971565A (en) 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
DE19917985A1 (en) 1999-04-21 2000-10-26 Targor Gmbh Metallocene catalyst system, useful for the production of polyolefins, comprises an organoboron or organoaluminum compound covalently bonded to a support.
RU2160276C1 (en) 1999-06-21 2000-12-10 Институт химической физики им. Н.Н. Семенова РАН Ansa-zirconocines with unsaturated cyclosilane bridge, and method of preparing thereof
US7141527B1 (en) 1999-09-22 2006-11-28 Basell Polyolefine Gmbh Catalyst system and process for the polymerization of olefins
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
EP1548022A3 (en) 1999-12-23 2007-06-13 Basell Polyolefine GmbH Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins
DE19962814A1 (en) 1999-12-23 2001-06-28 Targor Gmbh Catalyst system, useful for the production of polyolefins, comprises a metallocene, a Lewis base, a support and a compound containing at least one Group 3 element
US6492465B1 (en) 2000-02-08 2002-12-10 Exxonmobil Chemical Patents, Inc. Propylene impact copolymers
BR0105430A (en) 2000-02-24 2002-06-04 Basell Technology Co Bv Organometallic cocatalyst compounds, catalytic system and process for polymerization of olefins
DE10025412A1 (en) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Chemical products suitable as cocatalysts, processes for their preparation and their use in catalyst systems for the production of polyolefins
EP1294733B1 (en) 2000-06-30 2004-02-25 ExxonMobil Chemical Patents Inc. Bridged bis(indenyl)metallocene compounds
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP1632506A1 (en) 2000-06-30 2006-03-08 ExxonMobil Chemical Patents Inc. Propylene polymer
US6538082B2 (en) 2000-12-05 2003-03-25 Solvay Polyolefins Europe-Belgium Asymmetric silicon-bridged metallocenes useful as catalysts in the polymerization of α-olefins, process for their preparation and use of said metallocenes for the polymerization of α-olefins
EP1421090B1 (en) 2001-06-29 2014-03-26 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
DE10158656A1 (en) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organo transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for making polyolefins
WO2004005360A2 (en) 2002-07-09 2004-01-15 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
EP1539843B1 (en) 2002-09-06 2009-10-14 Basell Polyolefine GmbH Process for the copolymerization of ethylene
JP4972284B2 (en) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク Multiple catalyst systems for olefin polymerization and polymers produced therefrom
US20040132935A1 (en) 2002-10-24 2004-07-08 Palanisamy Arjunan Branched crystalline polypropylene
EP1567560B1 (en) 2002-12-06 2011-01-19 Basell Polyolefine GmbH Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
DE10358082A1 (en) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organometallic transition metal compound used in catalyst system for preparation of polyolefins, uses biscyclopentadienyl ligand systems in its preparation
US7220695B2 (en) 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2005105864A1 (en) * 2004-04-16 2005-11-10 Exxonmobil Chemical Patents Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
DE102004020524A1 (en) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylene for film, e.g. stretch film, used in carrier bags, contains ethylene homopolymers and/or copolymers of ethylene with 1-alkenes
WO2006044058A1 (en) 2004-10-12 2006-04-27 Exxonmobil Chemical Patents Inc. Trialkylaluminum treated supports
EP1861435B1 (en) 2005-03-23 2016-01-13 Basell Polyolefine GmbH Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
US7985799B2 (en) 2005-05-11 2011-07-26 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefin blends
CN101074276B (en) 2006-05-18 2011-06-22 中国石油天然气股份有限公司 Long-chain branching polypropylene and its production
WO2009050037A1 (en) 2007-10-19 2009-04-23 Basell Polyolefine Gmbh Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands
BRPI0722162A2 (en) 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh METALOCENE COMPOUNDS, CATALYZERS UNDERSTANDING THE SAME, PROCESS FOR PRODUCING AN OLEPHIN POLYMER BY THE USE OF CATALYZERS, AND OLEFINE HOMO-AND COPOLYMERS.
GB0918736D0 (en) 2009-10-26 2009-12-09 Isis Innovation Catalysts
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
WO2012134715A2 (en) 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8969482B2 (en) * 2011-09-30 2015-03-03 Exxonmobil Chemical Patents Inc. Dynamic modulation of metallocene catalysts
EP3022234B1 (en) 2013-07-17 2018-12-26 ExxonMobil Chemical Patents Inc. Substituted metallocene catalysts

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