JP2003528420A - 複合固体ポリマー電解質膜 - Google Patents

複合固体ポリマー電解質膜

Info

Publication number
JP2003528420A
JP2003528420A JP2000576501A JP2000576501A JP2003528420A JP 2003528420 A JP2003528420 A JP 2003528420A JP 2000576501 A JP2000576501 A JP 2000576501A JP 2000576501 A JP2000576501 A JP 2000576501A JP 2003528420 A JP2003528420 A JP 2003528420A
Authority
JP
Japan
Prior art keywords
polymer
spem
ion
sulfonated
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000576501A
Other languages
English (en)
Japanese (ja)
Other versions
JP2003528420A5 (https=
Inventor
フオーマト，リチヤード・エム
コバー，ロバート・エフ
オースナー，ポール
ランドロー，ネルソン
ルービン，レスリー・エス
Original Assignee
フオスター・ミラー・インコーポレイテツド
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US1998/017898 external-priority patent/WO1999010165A1/en
Application filed by フオスター・ミラー・インコーポレイテツド filed Critical フオスター・ミラー・インコーポレイテツド
Publication of JP2003528420A publication Critical patent/JP2003528420A/ja
Publication of JP2003528420A5 publication Critical patent/JP2003528420A5/ja
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5223—Polyphenylene oxide, phenyl ether polymers or polyphenylethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/56—Polyamides, e.g. polyester-amides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • B01D71/643—Polyether-imides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275—Heterogeneous membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/497—Ionic conductivity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/1062—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/06—Polyhydrazides; Polytriazoles; Polyamino-triazoles; Polyoxadiazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/491—Porosity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Cell Separators (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Moulding By Coating Moulds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2000576501A 1998-08-28 1999-08-26 複合固体ポリマー電解質膜 Pending JP2003528420A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US9817898 1998-08-28
PCT/US1998/017898 WO1999010165A1 (en) 1997-08-29 1998-08-28 Composite solid polymer electrolyte membranes
US09/261,349 US6248469B1 (en) 1997-08-29 1999-03-03 Composite solid polymer electrolyte membranes
US09/261,349 1999-03-03
PCT/US1999/019476 WO2000022684A2 (en) 1998-08-28 1999-08-26 Composite solid polymer electrolyte membranes

Publications (2)

Publication Number Publication Date
JP2003528420A true JP2003528420A (ja) 2003-09-24
JP2003528420A5 JP2003528420A5 (https=) 2006-10-19

Family

ID=26736230

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000576501A Pending JP2003528420A (ja) 1998-08-28 1999-08-26 複合固体ポリマー電解質膜

Country Status (5)

Country Link
US (2) US6248469B1 (https=)
JP (1) JP2003528420A (https=)
AU (1) AU2341500A (https=)
CA (1) CA2342237A1 (https=)
WO (1) WO2000022684A2 (https=)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002008680A (ja) * 2000-06-21 2002-01-11 Toyota Central Res & Dev Lab Inc 複合化架橋電解質
JP2003022823A (ja) * 2001-07-09 2003-01-24 Nitto Denko Corp プロトン伝導性膜又はフィルムとそれらを用いてなる燃料電池
JP2005048022A (ja) * 2003-07-31 2005-02-24 Toyobo Co Ltd 複合イオン交換膜およびその製造方法
JP2006120368A (ja) * 2004-10-19 2006-05-11 Asahi Glass Co Ltd 固体高分子電解質膜、固体高分子型燃料電池用膜電極接合体及び固体高分子電解質膜の製造方法
KR100750290B1 (ko) * 2006-07-11 2007-08-20 한국화학연구원 상호침투 고분자 그물구조를 갖는 연료전지용 동시가교-이미드 고분자 전해질막과 이의 제조방법
US7862921B2 (en) 2003-03-28 2011-01-04 Sumitomo Chemical Company, Limited Process for continuously producing polymer electrolyte membrane and producing apparatus therefor
JP2012506945A (ja) * 2009-12-04 2012-03-22 ベイジン プルーデント センチュリー テクノロジー．コー．エルティーディー ポリマーブレンドプロトン交換膜及びこれを製造する方法
JP2013503436A (ja) * 2009-08-25 2013-01-31 コーロン インダストリーズ インク 燃料電池用の高分子電解質膜及びその製造方法
JP2016532259A (ja) * 2013-08-06 2016-10-13 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 内部での架橋結合を用いて電解質膜を製造する方法
JP2017532716A (ja) * 2014-08-04 2017-11-02 ジョンソン、マッセイ、フュエル、セルズ、リミテッドＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｆｕｅｌ Ｃｅｌｌｓ Ｌｉｍｉｔｅｄ 膜
US9893373B2 (en) 2010-05-25 2018-02-13 3M Innovative Properties Company Reinforced electrolyte membrane
JP2018506149A (ja) * 2015-01-09 2018-03-01 アプライド マテリアルズ インコーポレイテッドＡｐｐｌｉｅｄ Ｍａｔｅｒｉａｌｓ，Ｉｎｃｏｒｐｏｒａｔｅｄ バッテリセパレータ上へのリチウム金属コーティング
CN109999664A (zh) * 2019-04-17 2019-07-12 北京碧水源膜科技有限公司 窄孔径分布大通量纳滤膜的制备方法
US11705569B2 (en) 2017-04-03 2023-07-18 Asahi Kasei Kabushiki Kaisha Composite polymer electrolyte membrane
WO2024101800A1 (ko) * 2022-11-08 2024-05-16 코오롱인더스트리 주식회사 연료 전지용 막-전극 어셈블리, 및 이의 제조 방법

Families Citing this family (241)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2748485B1 (fr) * 1996-05-07 1998-08-07 Commissariat Energie Atomique Polyimides sulfones, membranes preparees avec ceux-ci, et dispositif de pile a combustible comprenant ces membranes
WO1998029916A1 (en) * 1996-12-27 1998-07-09 Japan Storage Battery Co., Ltd. Gas diffusion electrode, solid polymer electrolyte membrane, method of producing them, and solid polymer electrolyte type fuel cell using them
JP4150867B2 (ja) * 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
AU2831000A (en) * 1999-03-08 2000-09-28 Center For Advanced Science And Technology Incubation, Ltd. Electrolytic membrane for fuel cell and its manufacturing method, and fuel cell and its manufacturing method
US6759157B1 (en) * 1999-06-11 2004-07-06 The Penn State Research Foundation Proton conducting polymer membranes
DE19952850A1 (de) * 1999-11-03 2001-05-10 Bayer Ag Polycarbonat-Substrate
JP3656244B2 (ja) * 1999-11-29 2005-06-08 株式会社豊田中央研究所 高耐久性固体高分子電解質及びその高耐久性固体高分子電解質を用いた電極−電解質接合体並びにその電極−電解質接合体を用いた電気化学デバイス
JP4042285B2 (ja) * 2000-02-23 2008-02-06 トヨタ自動車株式会社 固体高分子電解質膜およびその製造方法
US6709387B1 (en) 2000-05-15 2004-03-23 Given Imaging Ltd. System and method for controlling in vivo camera capture and display rate
WO2001094450A2 (en) 2000-06-02 2001-12-13 Sri International Polymer membrane composition
US7361729B2 (en) * 2000-09-20 2008-04-22 Virginia Tech Intellectual Properties, Inc. Ion-conducting sulfonated polymeric materials
JP3607862B2 (ja) * 2000-09-29 2005-01-05 株式会社日立製作所 燃料電池
US20020127474A1 (en) * 2001-01-09 2002-09-12 E.C.R.-Electro-Chemical Research Ltd. Proton-selective conducting membranes
DE10201691A1 (de) * 2001-01-19 2002-09-05 Honda Motor Co Ltd Polymerelektrolytmembran, Verfahren zu deren Herstellung und Membranelektrodenanordnung und Polymerelektrolytbrennstoffzelle, die diese umfasst
DE10201886B4 (de) * 2001-01-19 2014-01-23 Honda Giken Kogyo K.K. Polymerelektrolytmembran sowie Verfahren zur Herstellung dieser und Festpolymerelektrolytbrennstoffzelle, welche diese verwendet
WO2002059996A1 (fr) * 2001-01-26 2002-08-01 Toray Industries, Inc. Film electrolytique de polymere et procede de fabrication dudit film et pile a combustible de polymere solide utilisant ledit film
NL1017412C2 (nl) * 2001-02-21 2002-08-22 Tno Werkwijze voor het tegen biologische aangroei beschermen van oppervlakken.
US6632553B2 (en) * 2001-03-27 2003-10-14 Mti Microfuel Cells, Inc. Methods and apparatuses for managing effluent products in a fuel cell system
WO2002093676A2 (en) * 2001-05-15 2002-11-21 Ballard Power Systems Inc. Ion-exchange materials with improved ion conductivity
US7316855B2 (en) 2001-06-01 2008-01-08 Polyfuel, Inc. Fuel cell assembly for portable electronic device and interface, control, and regulator circuit for fuel cell powered electronic device
ATE400904T1 (de) 2001-06-01 2008-07-15 Polyfuel Inc Austauschbare brennstoffpatrone, brennstoffzellenaggregat mit besagter brennstoffpatrone für tragbare elektronische geräte und entsprechendes gerät
TW588076B (en) * 2001-07-03 2004-05-21 Sumitomo Chemical Co Polymer electrolyte membrane and fuel cell
TW589760B (en) * 2001-08-09 2004-06-01 Sumitomo Chemical Co Polymer electrolyte composition and fuel cell
US7318972B2 (en) * 2001-09-07 2008-01-15 Itm Power Ltd. Hydrophilic polymers and their use in electrochemical cells
JP3561250B2 (ja) * 2001-09-21 2004-09-02 株式会社日立製作所 燃料電池
KR100437267B1 (ko) * 2001-10-17 2004-06-23 학교법인 서강대학교 연료전지용 고분자 전해질 막 및 이의 제조방법
KR100453680B1 (ko) * 2001-11-10 2004-10-20 한국과학기술연구원 가교된 이온 교환 막 및 그 제조방법
US6861489B2 (en) * 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US6986963B2 (en) 2001-12-14 2006-01-17 Ut-Battelle Llc Metallization of bacterial cellulose for electrical and electronic device manufacture
JP2006508493A (ja) * 2002-01-23 2006-03-09 ポリフューエル・インコーポレイテッド 酸−塩基プロトン伝導性ポリマーブレンド膜
DK1477515T3 (da) 2002-02-15 2013-01-28 Toyo Boseki klyngeionbyttermembran og elektrolytmembran-elektrodeforbindelseslegeme
US6981877B2 (en) * 2002-02-19 2006-01-03 Mti Microfuel Cells Inc. Simplified direct oxidation fuel cell system
DE10209419A1 (de) * 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10213540A1 (de) * 2002-03-06 2004-02-19 Celanese Ventures Gmbh Lösung aus Vinylphosphonsäure, Verfahren zur Herstellung einer Polymerelektrolytmembran aus Polyvinylphosphaonsäure und deren Anwendung in Brennstoffzellen
US20050118478A1 (en) * 2002-03-06 2005-06-02 Joachim Kiefer Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells
ES2292993T3 (es) * 2002-03-06 2008-03-16 Basf Fuel Cell Gmbh Membrana electrolitica conductora de protones con permeabilidad reducida de metanol y su aplicacion en pilas de combustible.
CN100355133C (zh) * 2002-03-07 2007-12-12 宇部兴产株式会社 电解质膜和使用它的固体高分子型燃料电池
US20050053818A1 (en) * 2002-03-28 2005-03-10 Marc St-Arnaud Ion exchange composite material based on proton conductive functionalized inorganic support compounds in a polymer matrix
US20030196893A1 (en) * 2002-04-23 2003-10-23 Mcelroy James Frederick High-temperature low-hydration ion exchange membrane electrochemical cell
CA2483015A1 (en) * 2002-04-25 2003-11-06 Pemeas Gmbh Multilayer electrolyte membrane
DE10220818A1 (de) * 2002-05-10 2003-11-20 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10220817A1 (de) * 2002-05-10 2003-11-27 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
US7354679B2 (en) * 2002-05-13 2008-04-08 Polyfuel, Inc. Ion conductive random copolymers
EP1518290A4 (en) 2002-05-13 2009-12-02 Polyfuel Inc ION-LEADING BLOCK COPOLYMERS
WO2003095509A1 (en) 2002-05-13 2003-11-20 Polyfuel, Inc. Sulfonated copolymer
US7402351B2 (en) * 2002-06-10 2008-07-22 E.I. Du Pont De Nemours And Company Carboxylic acid-based ionomer fuel cells
US20030235737A1 (en) * 2002-06-19 2003-12-25 Yoocharn Jeon Metal-coated polymer electrolyte and method of manufacturing thereof
DE10230477A1 (de) * 2002-07-06 2004-01-15 Celanese Ventures Gmbh Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung
GB0216834D0 (en) * 2002-07-19 2002-08-28 Accentus Plc Porous polymeric membrane
DE10235358A1 (de) * 2002-08-02 2004-02-12 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polymere und deren Anwendung in Brennstoffzellen
EP1527494B1 (de) * 2002-08-02 2005-12-28 Pemeas GmbH Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen
DE10235357A1 (de) * 2002-08-02 2004-02-12 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäure- und Sulfonsäuregruppen enthaltende Polymere und deren Anwendung in Brennstoffzellen
FR2843399B1 (fr) * 2002-08-06 2004-09-03 Commissariat Energie Atomique Polymeres de type polyphenylenes, leur procede de preparation, membranes et dispositif de pile a combustible comprenant ces membranes
US6977009B2 (en) * 2002-08-07 2005-12-20 Hewlett-Packard Development Company, L.P. Metal coated polymer electrolyte membrane having a reinforcement structure
US6630265B1 (en) * 2002-08-13 2003-10-07 Hoku Scientific, Inc. Composite electrolyte for fuel cells
DE10239701A1 (de) * 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
US6787007B2 (en) 2002-09-23 2004-09-07 Bechtel Bwxt Idaho, Llc Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion
DE10246461A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran enthaltend Polyazolblends und deren Anwendung in Brennstoffzellen
DE10246373A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246459A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
WO2004034676A1 (en) * 2002-10-08 2004-04-22 Koninklijke Philips Electronics N.V. Integrated circuit and method for establishing transactions
US7649025B2 (en) * 2002-10-17 2010-01-19 Toyo Boseki Kabushiki Kaisha Composite ion-exchange membrane
US6841283B2 (en) * 2002-10-21 2005-01-11 Utc Fuel Cells, Llc High water permeability proton exchange membrane
US20060138042A1 (en) * 2002-10-24 2006-06-29 Kazutake Okamoto Heat-resistant film and composite ion-exchange membrane
DE10262009A1 (de) * 2002-10-29 2004-05-19 Daimlerchrysler Ag Polymerelektrolytmembran-Brennstoffzelle mit einer verstärkten Polymerelektrolytmembran
US20040086774A1 (en) * 2002-11-05 2004-05-06 Munoz Beth C. Gas diffusion electrodes
JP2006508516A (ja) * 2002-12-02 2006-03-09 ポリフューエル・インコーポレイテッド 携帯電子装置用燃料電池カートリッジ
US20040175598A1 (en) * 2002-12-02 2004-09-09 Bliven David C. Fuel cell power supply for portable computing device and method for fuel cell power control
US20040157101A1 (en) * 2003-02-11 2004-08-12 Smedley Stuart I. Fuel cell electrode assembly
WO2004072141A2 (en) * 2003-02-13 2004-08-26 The Penn State Research Foundation Synthesis of polyphosphazenes with sulfonimide side groups
EP1619735A4 (en) * 2003-03-06 2010-05-12 Toray Industries POLYMERIC ELECTROLYTE, POLYMERIC ELECTROLYTE ELEMENT, MEMBRANE ELECTRODE COMPOSITE, AND POLYMERIC ELECTROLYTE FUEL CELL
DE10312029A1 (de) * 2003-03-18 2004-10-07 Daimlerchrysler Ag Selbstheilende Membran für eine Brennstoffzelle
JP4493287B2 (ja) * 2003-03-28 2010-06-30 住友化学株式会社 高分子電解質複合膜の連続的製造方法及び装置
US7282293B2 (en) 2003-04-15 2007-10-16 Mti Microfuel Cells Inc. Passive water management techniques in direct methanol fuel cells
US7407721B2 (en) * 2003-04-15 2008-08-05 Mti Microfuel Cells, Inc. Direct oxidation fuel cell operating with direct feed of concentrated fuel under passive water management
WO2004102714A1 (ja) * 2003-05-13 2004-11-25 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質ポリマー、その製造方法及び膜・電極接合体
US7556660B2 (en) 2003-06-11 2009-07-07 James Kevin Shurtleff Apparatus and system for promoting a substantially complete reaction of an anhydrous hydride reactant
CN100446312C (zh) * 2003-06-25 2008-12-24 东丽株式会社 高分子电解质、以及使用了该高分子电解质的高分子电解质膜、膜电极复合体和高分子电解质型燃料电池
DE112004001057B4 (de) * 2003-06-27 2014-06-05 Asahi Kasei Chemicals Corp. Polymerelektrolytmembran mit hoher Festigkeit, Verfahren zur Herstellung davon und Verwendung
US20050042489A1 (en) * 2003-07-11 2005-02-24 Kenji Fukuta Laminate useful as a membrane-electrode assembly for fuel cells, production process therefor and a fuel cell provided with the laminate
JP4875489B2 (ja) * 2003-07-27 2012-02-15 ベーアーエスエフ フューエル セル ゲーエムベーハー プロトン伝導性膜およびその使用
US6962959B2 (en) * 2003-08-28 2005-11-08 Hoku Scientific, Inc. Composite electrolyte with crosslinking agents
US7132191B2 (en) * 2003-09-17 2006-11-07 General Motors Corporation Addressing one MEA failure mode by controlling MEA catalyst layer overlap
ATE550368T1 (de) * 2003-09-30 2012-04-15 Sumitomo Chemical Co Blockcopolymer und seine verwendung
DE602004030358D1 (de) * 2003-10-02 2011-01-13 Univ Yamanashi Sulfonierte aromatische polyether, herstellungsverfahren dafür und elektrolytmembranen
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US20070099051A1 (en) * 2003-11-06 2007-05-03 Renault S.A.S. Ion-conducting composite membranes
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7537857B2 (en) * 2003-12-17 2009-05-26 Bdf Ip Holdings Ltd. Reduced degradation of ion-exchange membranes in electrochemical fuel cells
JP4109623B2 (ja) * 2003-12-25 2008-07-02 本田技研工業株式会社 プロトン伝導体及びその製造方法
US7255924B2 (en) * 2004-01-13 2007-08-14 The United States Of America As Represented By The Secretary Of The Navy Carbon nanoarchitectures with ultrathin, conformal polymer coatings for electrochemical capacitors
WO2005086264A1 (ja) * 2004-03-04 2005-09-15 Matsushita Electric Industrial Co., Otd. 複合電解質膜、触媒層膜接合体、膜電極接合体および高分子電解質型燃料電池
CN100477355C (zh) * 2004-03-19 2009-04-08 东亚合成株式会社 电解质膜及燃料电池
US7375176B2 (en) * 2004-03-31 2008-05-20 Litt Morton H Liquid crystal poly(phenylene sulfonic acids)
ITMI20040789A1 (it) * 2004-04-22 2004-07-22 Solvay Solexis Spa Membrane fluorurate
US7662498B2 (en) * 2004-04-23 2010-02-16 Asahi Kasei Chemicals Corporation Polymer electrolyte composition containing aromatic hydrocarbon-based resin
GB2426763B (en) 2004-04-23 2009-11-04 Asahi Kasei Chemicals Corp Polymer electrolyte composition containing aromatic hydrocarbon-based resign
US7811693B2 (en) * 2004-05-13 2010-10-12 Toyota Motor Engineering & Manfacturing North America, Inc. Proton exchange membranes (PEM) based on hybrid inorganic-organic copolymers with grafted phosphoric acid groups and implanted metal cations
JP2007537317A (ja) * 2004-05-14 2007-12-20 ペミアス ゲーエムベーハー 異方性造形体、異方性造形体の製造方法および使用
KR100536257B1 (ko) * 2004-06-29 2005-12-12 삼성에스디아이 주식회사 연료 전지용 막/전극 접합체 및 그를 포함하는 연료 전지
KR100542228B1 (ko) * 2004-06-30 2006-01-10 삼성에스디아이 주식회사 연료전지용 고분자 막/전극 접합체 및 이를 포함하는연료전지
KR100696680B1 (ko) * 2004-06-30 2007-03-19 삼성에스디아이 주식회사 연료전지용 고분자 전해질막 및 그 제조방법
KR100637486B1 (ko) * 2004-06-30 2006-10-20 삼성에스디아이 주식회사 연료전지용 전해질막 및 이를 포함하는 연료전지
KR100658739B1 (ko) * 2004-06-30 2006-12-15 삼성에스디아이 주식회사 연료전지용 고분자 전해질막 및 그 제조방법
KR100599799B1 (ko) * 2004-06-30 2006-07-12 삼성에스디아이 주식회사 연료전지용 고분자 전해질막, 막-전극 접합체, 연료전지및 막-전극 접합체의 제조방법
KR100598159B1 (ko) * 2004-08-05 2006-07-07 한양대학교 산학협력단 폴리스티렌 술폰산이 그라프트된 폴리술폰 공중합물및 그제조방법, 이를 이용한 연료전지용 고분자 전해질막
US8642228B2 (en) * 2004-08-31 2014-02-04 Samsung Sdi Co., Ltd. Polymer electrolyte membrane and fuel cell using the polymer electrolyte membrane
KR100723389B1 (ko) * 2005-12-21 2007-05-30 삼성에스디아이 주식회사 폴리머 전해질막 및 이를 채용한 연료전지
KR100647287B1 (ko) * 2004-08-31 2006-11-23 삼성에스디아이 주식회사 폴리머 전해질막 및 이를 채용한 연료전지
CN100541888C (zh) * 2004-09-03 2009-09-16 东丽株式会社 高分子电解质材料、高分子电解质部件、膜电极复合体和高分子电解质型燃料电池
WO2006028190A1 (ja) 2004-09-09 2006-03-16 Asahi Kasei Chemicals Corporation 固体高分子電解質膜およびその製造方法
CN100539271C (zh) * 2004-09-09 2009-09-09 旭化成电子材料株式会社 固体高分子电解质膜及其制造方法
US20060275637A1 (en) * 2004-09-30 2006-12-07 The University Of Tokyo Electrolyte membrane and preparing method thereof
US20060083852A1 (en) * 2004-10-18 2006-04-20 Yoocham Jeon Fuel cell apparatus and method of manufacture thereof
US7910260B2 (en) * 2004-11-01 2011-03-22 GM Global Technology Operations LLC Method for stabilizing polyelectrolyte membrane films used in fuel cells
US8475971B2 (en) * 2004-11-24 2013-07-02 GM Global Technology Operations LLC Membrane treatment method
KR20070086373A (ko) * 2004-12-03 2007-08-27 니토 덴코 가부시키가이샤 전해질막의 제조 방법, 전해질막 및 그의 전해질막을이용한 고체 고분자형 연료 전지
KR100657918B1 (ko) * 2004-12-11 2006-12-14 삼성에스디아이 주식회사 고분자 전해질 및 이를 채용한 연료전지
KR101135479B1 (ko) * 2005-01-26 2012-04-13 삼성에스디아이 주식회사 연료전지용 고분자 전해질막, 이의 제조방법, 및 이를포함하는 연료전지 시스템
US7601449B2 (en) * 2005-02-08 2009-10-13 Gm Global Technology Operations, Inc. Sulfonated poly(phenylene sulfide) films as polyelectrolyte membranes
US8178224B2 (en) * 2005-02-08 2012-05-15 GM Global Technology Operations LLC Sulfonated polyelectrolyte membranes containing perfluorosulfonate ionomers
US7419732B2 (en) 2005-02-11 2008-09-02 Gore Enterprise Holdings, Inc. Method for reducing degradation in a fuel cell
KR101201816B1 (ko) * 2005-03-07 2012-11-15 삼성에스디아이 주식회사 막-전극 어셈블리, 그 제조방법, 및 이를 포함하는 연료전지 시스템
US7635062B2 (en) * 2005-03-11 2009-12-22 Bha Group, Inc. Composite membrane
KR100714362B1 (ko) 2005-03-23 2007-05-02 삼성에스디아이 주식회사 연료전지용 전해질, 막전극 접합체 및 연료전지용 전해질의제조방법
KR100684787B1 (ko) * 2005-03-31 2007-02-20 삼성에스디아이 주식회사 연료전지용 고분자 전해질막, 이의 제조 방법 및 이를포함하는 연료전지용 스택 및 연료전지 시스템
US20060228608A1 (en) * 2005-04-11 2006-10-12 Tze-Chiang Chung High temperature and low relative humidity polymer/inorganic composite membranes for proton exchange membrane fuel cells
KR100624470B1 (ko) * 2005-06-14 2006-09-15 삼성에스디아이 주식회사 연료전지용 고분자 전해질막 및 그의 제조방법
JP2007023183A (ja) * 2005-07-19 2007-02-01 Toyota Motor Corp 多孔質膜、多孔質膜の製造方法、固体高分子電解質膜、及び燃料電池
US8993193B2 (en) * 2005-08-05 2015-03-31 GM Global Technology Operations LLC Sulfonated perfluorosulfonic acid polyelectrolyte membranes
US7838138B2 (en) * 2005-09-19 2010-11-23 3M Innovative Properties Company Fuel cell electrolyte membrane with basic polymer
US7517604B2 (en) * 2005-09-19 2009-04-14 3M Innovative Properties Company Fuel cell electrolyte membrane with acidic polymer
KR100707163B1 (ko) * 2005-10-12 2007-04-13 삼성에스디아이 주식회사 고체산, 이를 포함하는 고분자 전해질막 및 이를 채용한연료전지
TW200719507A (en) * 2005-11-08 2007-05-16 Univ Chang Gung Making method for separator with high ionic conductivity
US20080020260A1 (en) * 2005-11-12 2008-01-24 Brydon Chris A Apparatus, system, and method for manifolded integration of a humidification chamber for input gas for a proton exchange membrane fuel cell
US7833645B2 (en) 2005-11-21 2010-11-16 Relion, Inc. Proton exchange membrane fuel cell and method of forming a fuel cell
KR100717800B1 (ko) * 2005-11-22 2007-05-11 삼성에스디아이 주식회사 연료 전지용 고분자 전해질 막, 이의 제조 방법 및 이를포함하는 연료 전지용 막-전극 어셈블리
JP2009518264A (ja) * 2005-12-01 2009-05-07 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア イオン伝導用の機能化された無機薄膜
US20070128425A1 (en) * 2005-12-07 2007-06-07 3M Innovative Properties Company Reinforced ion-conductive membranes
KR100846072B1 (ko) * 2006-01-04 2008-07-14 주식회사 엘지화학 촉매 트래핑 층을 포함하고 있는 막-전극 접합체 및그것으로 구성된 연료전지
KR101202331B1 (ko) * 2006-02-20 2012-11-16 삼성에스디아이 주식회사 다중 블럭 공중합체, 그 제조방법, 상기 다중 블럭공중합체로부터 제조된 고분자 전해질막, 그 제조방법 및상기 고분자 전해질막을 포함하는 연료전지
KR101312262B1 (ko) * 2006-02-23 2013-09-25 삼성에스디아이 주식회사 고분자막, 그 제조방법 및 이를 채용한 연료전지
KR101264331B1 (ko) * 2006-02-25 2013-05-14 삼성에스디아이 주식회사 고분자 전해질막, 이의 제조 방법 및 이를 구비한 연료전지
US20070218371A1 (en) * 2006-03-14 2007-09-20 Tda Research, Inc. Nanoporous polymer electrolyte
KR101234232B1 (ko) * 2006-03-16 2013-02-22 삼성에스디아이 주식회사 다중 블럭 공중합체, 그 제조방법, 상기 다중 블럭공중합체로부터 제조된 고분자 전해질막, 그 제조방법 및상기 고분자 전해질막을 포함하는 연료전지
WO2007135689A2 (en) 2006-05-24 2007-11-29 Ben Gurion University Of The Negev R&D Authority Membranes, coatings and films and methods for their preparation
GB0611600D0 (en) * 2006-06-13 2006-07-19 Itm Fuel Cells Ltd Improvements to membranes
US7851557B2 (en) * 2006-06-20 2010-12-14 Lg Chem, Ltd. Organic/inorganic composite electrolyte membranes using zeolite and fuel cell comprising the same
KR100752072B1 (ko) * 2006-07-25 2007-08-27 한국에너지기술연구원 연료전지용 유기-무기 복합체 고분자 전해질막 및 이의제조방법
US7651542B2 (en) 2006-07-27 2010-01-26 Thulite, Inc System for generating hydrogen from a chemical hydride
US7648786B2 (en) 2006-07-27 2010-01-19 Trulite, Inc System for generating electricity from a chemical hydride
TW200810197A (en) * 2006-08-15 2008-02-16 Univ Chang Gung Method for producing composite solid polymer electrolyte (SPE)
US7846610B2 (en) * 2006-10-23 2010-12-07 Canon Kabushiki Kaisha Electrolyte membrane, production method thereof, and fuel cell
US7964651B2 (en) * 2006-12-21 2011-06-21 Toyota Motor Engineering & Manufacturing North America, Inc. Sulfonyl grafted heterocycle materials for proton conducting electrolytes
KR100773322B1 (ko) 2006-12-26 2007-11-05 한국과학기술연구원 크로스링크된 ｐｂｉ를 포함하는 연료전지용 고분자전해질막 및 그 제조방법
US7915351B2 (en) 2007-02-05 2011-03-29 Pbi Performance Products, Inc. Polybenzimidazole-polyetherketoneketone blends and miscible blends
KR100853713B1 (ko) * 2007-03-29 2008-08-25 한국과학기술원 연료전지용 고분자 복합막 및 이를 포함하는 연료전지
US8357214B2 (en) 2007-04-26 2013-01-22 Trulite, Inc. Apparatus, system, and method for generating a gas from solid reactant pouches
US8026020B2 (en) 2007-05-08 2011-09-27 Relion, Inc. Proton exchange membrane fuel cell stack and fuel cell stack module
US9293778B2 (en) 2007-06-11 2016-03-22 Emergent Power Inc. Proton exchange membrane fuel cell
US20090029227A1 (en) * 2007-07-25 2009-01-29 John Patton Apparatus, system, and method for securing a cartridge
CA2732060A1 (en) 2007-07-25 2009-01-29 Trulite, Inc. Apparatus, system, and method to manage the generation and use of hybrid electric power
US20090045544A1 (en) * 2007-08-14 2009-02-19 General Electric Company Method for manufacturing ultra-thin polymeric films
JP2010536980A (ja) * 2007-08-20 2010-12-02 テクニオン リサーチ アンド ディベロップメント ファウンデーション リミテッド ポリスルホンポリマー並びに逆浸透、ナノ濾過及び限外濾過のための膜
US9023553B2 (en) * 2007-09-04 2015-05-05 Chemsultants International, Inc. Multilayered composite proton exchange membrane and a process for manufacturing the same
US8003274B2 (en) 2007-10-25 2011-08-23 Relion, Inc. Direct liquid fuel cell
KR100967627B1 (ko) * 2007-12-26 2010-07-05 한국에너지기술연구원 연료전지용 고분자전해질 복합막의 제조 방법
KR101063215B1 (ko) * 2008-02-20 2011-09-07 한국과학기술원 고분자 전해질 연료전지용 강화 복합막
US8147735B2 (en) * 2008-07-09 2012-04-03 Eltron Research & Development, Inc. Semipermeable polymers and method for producing same
US8349174B2 (en) * 2008-07-23 2013-01-08 Baxter International Inc. Portable power dialysis machine
US8536299B2 (en) * 2008-12-08 2013-09-17 University Of Dayton Rigid-rod copolymer compositions and the polymeric fibers fabricated from those compositions for enhanced flame resistance
US20100167100A1 (en) * 2008-12-26 2010-07-01 David Roger Moore Composite membrane and method for making
EP2398578A1 (en) * 2009-02-19 2011-12-28 Ben-Gurion University Of The Negev Research And Development Authority Chemically resistant membranes, coatings and films and methods for their preparation
US8561812B2 (en) * 2009-03-27 2013-10-22 Uop Llc Blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups
US8132678B2 (en) * 2009-03-27 2012-03-13 Uop Llc Polybenzoxazole polymer-based mixed matrix membranes
US8132677B2 (en) 2009-03-27 2012-03-13 Uop Llc Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking
US8127937B2 (en) * 2009-03-27 2012-03-06 Uop Llc High performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes
US8127936B2 (en) * 2009-03-27 2012-03-06 Uop Llc High performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes
US8613362B2 (en) * 2009-03-27 2013-12-24 Uop Llc Polymer membranes derived from aromatic polyimide membranes
US20100326913A1 (en) * 2009-06-25 2010-12-30 Uop Llc Polybenzoxazole membranes prepared from aromatic polyamide membranes
US8459469B2 (en) * 2009-06-25 2013-06-11 Uop Llc Polybenzoxazole membranes prepared from aromatic polyamide membranes
US7867019B1 (en) * 2009-07-17 2011-01-11 Fluke Corporation Thermal imaging device with a battery pack with a shock absorber
CN102576855B (zh) 2009-08-24 2015-11-25 赛昂能源有限公司 用于电化学电池的剥离系统
SG169305A1 (en) * 2009-08-26 2011-03-30 Siemens Pte Ltd Ion exchange membranes
JP5649657B2 (ja) 2009-11-20 2015-01-07 ギブン イメージング リミテッドＧｉｖｅｎ Ｉｍａｇｉｎｇ Ｌｔｄ． 生体内デバイスの電力消費を制御するシステムおよび方法
KR101376362B1 (ko) 2010-04-28 2014-03-26 코오롱패션머티리얼 (주) 연료전지용 고분자 전해질막 및 그 제조방법
WO2011146670A1 (en) * 2010-05-19 2011-11-24 Seeo, Inc High temperature lithium cells with solid polymer electrolytes
EP2609647B1 (en) 2010-08-24 2017-03-15 Sion Power Corporation Electrolyte materials for use in electrochemical cells
CN103237600B (zh) 2010-10-15 2016-07-13 伊沃夸水处理技术有限责任公司 阴离子交换膜及制造方法
JP5889907B2 (ja) 2010-10-15 2016-03-22 エヴォクア ウォーター テクノロジーズ エルエルシーＥｖｏｑｕａ Ｗａｔｅｒ Ｔｅｃｈｎｏｌｏｇｉｅｓｌｌｃ カチオン交換膜を製造するためのモノマー溶液の製造方法
US9457318B2 (en) 2010-12-12 2016-10-04 Ben-Gurion University Of The Negev Research And Development Authority Anion exchange membranes, methods of preparation and uses
US9490488B2 (en) * 2011-03-29 2016-11-08 Council Of Scientific & Industrial Research Process for the preparation of membrane electrode assemblies (MEAs)
KR101433133B1 (ko) * 2011-03-31 2014-08-25 코오롱인더스트리 주식회사 고분자 전해질 및 이의 제조 방법
US9240257B2 (en) * 2011-07-06 2016-01-19 Johnson IP Holding, Inc. Solid, lithium-salt-doped, thermoset polyimide polymer electrolyte and electrochemical cell employing same
KR101767370B1 (ko) 2011-07-29 2017-08-24 코오롱인더스트리 주식회사 연료전지용 고분자 전해질막 및 그 제조방법
KR101890747B1 (ko) 2011-11-03 2018-10-01 삼성전자주식회사 이온 교환막 충전용 조성물, 이온 교환막의 제조방법, 이온 교환막 및 레독스 플로우 전지
CN102658645B (zh) * 2012-05-14 2014-06-25 华北电力大学 一种具有特定取向结构的全氟磺酸质子交换膜的制备方法
US9283523B2 (en) * 2012-05-25 2016-03-15 Pbi Performance Products, Inc. Acid resistant PBI membrane for pervaporation dehydration of acidic solvents
US20150214526A1 (en) * 2012-09-03 2015-07-30 Basf Se Electrochemical cells comprising reaction products of polyimides
WO2014055123A1 (en) 2012-10-04 2014-04-10 Evoqua Water Technologies Llc High-performance anion exchange membranes and methods of making same
CA2887132C (en) 2012-10-11 2020-07-21 Evoqua Water Technologies Llc Coated ion exchange membranes
US20150159010A1 (en) * 2012-12-06 2015-06-11 Sergei Rudenja Conducting interpenetrating polymer networks, related methods, compositions and systems
KR20140074099A (ko) 2012-12-07 2014-06-17 삼성전자주식회사 연료 전지용 전극 촉매, 이의 제조 방법, 및 이를 포함한 막 전극 접합체 및 연료 전지
US9543607B2 (en) 2013-02-22 2017-01-10 National Research Council Of Canada Process for producing ion exchange membranes by melt-processing of acidic PFSA ionomers
CN103165841B (zh) * 2013-03-06 2016-04-13 珠海市赛纬电子材料有限公司 一种锂离子电池用隔膜的生产方法
CN103178229A (zh) * 2013-03-06 2013-06-26 珠海市赛纬电子材料有限公司 锂离子电池用隔膜的生产方法
JP2016510829A (ja) * 2013-03-11 2016-04-11 エオニックス・アドバンスト・マテリアルズ・コーポレイションＡｏｎｉｘ Ａｄｖａｎｃｅｄ Ｍａｔｅｒｉａｌｓ Ｃｏｒｐ． 熱可塑性複合材を製造するための組成物および方法
US20140272595A1 (en) * 2013-03-15 2014-09-18 Basf Se Compositions for use as protective layers and other components in electrochemical cells
JP2016511517A (ja) 2013-03-15 2016-04-14 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ 保護電極構造
US9728768B2 (en) 2013-03-15 2017-08-08 Sion Power Corporation Protected electrode structures and methods
US9099711B2 (en) 2013-09-11 2015-08-04 King Fahd University Of Petroleum And Minerals Fuel cell membrane
WO2015116959A1 (en) * 2014-01-31 2015-08-06 Paragon Space Development Corporation Ionomer-membrane water processing apparatus
US9695066B2 (en) 2014-01-31 2017-07-04 Paragon Space Development Corporation Ionomer-membrane water processing apparatus
CN106062995B (zh) 2014-02-19 2020-02-04 巴斯夫欧洲公司 使用包含抑制电解质的离子导体的复合物的电极保护
US10490796B2 (en) 2014-02-19 2019-11-26 Sion Power Corporation Electrode protection using electrolyte-inhibiting ion conductor
US10150085B2 (en) * 2014-10-30 2018-12-11 Nok Corporation Membrane-forming dope for carbon membranes and a method for producing a carbon hollow fiber membrane using the same
US10150086B2 (en) * 2014-12-12 2018-12-11 Nok Corporation Method for producing a carbon hollow fiber membrane
CN107532314A (zh) 2015-03-16 2018-01-02 卡勒拉公司 离子交换膜、电化学系统和方法
CN104960127B (zh) 2015-07-03 2017-02-01 淮安科润膜材料有限公司 增强型全氟离子膜流延机
CN108028396B (zh) 2015-09-24 2021-04-30 阿莫绿色技术有限公司 燃料电池用分离膜、其制备方法及燃料电池电极组件
US10266954B2 (en) 2015-10-28 2019-04-23 Calera Corporation Electrochemical, halogenation, and oxyhalogenation systems and methods
FR3049605B1 (fr) * 2016-04-05 2018-03-23 Arkema France Procede d'obtention de films fins et articles filmogenes
US11826748B2 (en) * 2016-08-10 2023-11-28 Ffi Ionix Ip, Inc. Ion exchange polymers and ion exchange membranes incorporating same
US11168013B2 (en) 2016-09-16 2021-11-09 Paragon Space Development Corporation In-situ resource utilization-derived water purification and hydrogen and oxygen production
US10752523B2 (en) 2016-09-16 2020-08-25 Paragon Space Development Corporation Systems and methods for recovery of purified water and concentrated brine
US10584201B2 (en) 2017-01-10 2020-03-10 The Texas A&M University System Methanesulfonic acid mediated solvent free synthesis of conjugated porous polymer networks
JP7404349B2 (ja) 2018-09-25 2023-12-25 エヴォクア ウォーター テクノロジーズ エルエルシー 一価選択性カチオン交換膜
CN109294228A (zh) * 2018-10-31 2019-02-01 中国久远高新技术装备公司 一种高强度高伸长率聚芳酰胺薄膜及其制备方法
CN110064312B (zh) * 2019-04-29 2022-03-08 袁书珊 一种高通量耐溶剂界面聚合复合膜及其制备方法
EP4032137A4 (en) * 2019-09-20 2024-08-14 LI-S Energy Limited FLEXIBLE LITHIUM-SULFUR BATTERIES
CN111170422B (zh) * 2020-01-07 2022-04-19 浙江工业大学 一种耐有机溶剂阴离子交换膜的制备方法
CN112717727B (zh) * 2020-12-03 2022-05-13 北京理工大学 一类具有氢气分离性质的玻璃态mof膜材料及其制备方法
CN114259886A (zh) * 2021-12-28 2022-04-01 北京林业大学 一种基于微米结构基底的电致亲疏水性可逆调控复合膜制备方法
CN116203772B (zh) * 2023-02-16 2024-02-13 安徽精一门科技发展有限公司 基于质子传递的快速响应电致变色器件及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63248490A (ja) * 1987-04-06 1988-10-14 Mitsubishi Heavy Ind Ltd 多重効用造水装置の運転法
JPH05326037A (ja) * 1992-05-14 1993-12-10 Nitto Denko Corp 電 池
JPH0629032A (ja) * 1992-07-08 1994-02-04 Sumitomo Electric Ind Ltd 高分子電解質膜及びその製造法
JPH06242474A (ja) * 1993-02-17 1994-09-02 Tonen Corp エレクトロクロミック素子及び高分子電解質薄膜の製造方法
WO1996013872A1 (en) * 1994-11-01 1996-05-09 Case Western Reserve University Proton conducting polymers
WO1996018216A1 (de) * 1994-12-09 1996-06-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Polymerelektrolyt-membran-brennstoffzelle
WO1996029360A1 (de) * 1995-03-20 1996-09-26 Hoechst Aktiengesellschaft Sulfonierte polyetherketone, verfahren zu ihrer herstellung und verwendung zur herstellung von membranen
JP2001514431A (ja) * 1997-08-29 2001-09-11 フオスター・ミラー・インコーポレイテツド 複合固体ポリマー電解質膜

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3284238A (en) 1960-08-26 1966-11-08 American Cyanamid Co Novel gel compositions and methods for preparation thereof
US3226361A (en) 1961-11-29 1965-12-28 Gen Electric Functional aromatic substituents in polyphenylene oxides
US3528954A (en) 1967-10-30 1970-09-15 Du Pont Process for homopolymerization of tetrafluoroethylene and copolymerization of same with fluoro co-monomers in the solvent 1,1,2 - trichloro - 1,2,2 - trifluoroethane
US3528858A (en) 1968-12-04 1970-09-15 Gen Electric Sulfonated aryl-substituted polyphenylene ether ion exchange membranes
JPS5349090A (en) 1976-10-15 1978-05-04 Asahi Glass Co Ltd Preparation of fluorinated plymer containing ion exchange group
GB1550874A (en) 1976-10-28 1979-08-22 Asahi Glass Co Ltd Process for producing fluorinated copolymer having ion-exchange groups
US4110265A (en) 1977-03-01 1978-08-29 Ionics Inc. Ion exchange membranes based upon polyphenylene sulfide
US4191811A (en) 1977-03-01 1980-03-04 Ionics, Incorported Ion exchange membranes based upon polyphenylene sulfide and fluorocarbon polymeric binder
US4131740A (en) 1977-04-20 1978-12-26 E. I. Du Pont De Nemours And Company Alkyl perfluoro-ω-fluoroformyl esters and their preparation
EP0008894B1 (en) 1978-09-05 1983-02-23 Imperial Chemical Industries Plc Sulphonated polyarylethersulphone copolymers and process for the manufacture thereof
US4358412A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Preparation of vinyl ethers
US4330654A (en) 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
DE3271691D1 (en) * 1981-12-21 1986-07-17 Aligena Ag Semipermeable membranes of modified polystyrene, process for their manufacture and their use
US4413106A (en) 1982-12-27 1983-11-01 Albany International Corp. Heterogeneous sulfonation process for difficultly sulfonatable poly(ether sulfone)
US4939235A (en) 1985-09-26 1990-07-03 Foster-Miller, Inc. Biaxially oriented ordered polybenzothiazole film
US5501831A (en) 1985-09-26 1996-03-26 Foster-Miller, Inc. Method for preparing interpenetrated polymer films
US5168011A (en) 1985-09-26 1992-12-01 Foster Miller Inc. Interpenetrated polymer fibers
US4973442A (en) 1985-09-26 1990-11-27 Foster Miller Inc. Forming biaxially oriented ordered polymer films
US4845150A (en) 1985-09-26 1989-07-04 Foster-Miller Inc. Interpenetrated polymer films
EP0227299A3 (en) 1985-12-20 1987-10-07 The Standard Oil Company Polymer/liquid crystal composite semipermeable membranes and process for the use thereof
US4714663A (en) * 1986-10-14 1987-12-22 The United States Of America As Represented By The United States Department Of Energy Sulfonated polysulfone battery membrane for use in corrosive environments
JP2694341B2 (ja) 1987-02-04 1997-12-24 ハイドロノーティクス 改良された耐酸化性膜およびその製造方法
US4814399A (en) 1987-07-24 1989-03-21 Hoechst Celanese Corporation Sulfoalkylation of polybenzimidazole
DE58909860D1 (de) 1988-04-30 1999-11-11 Akzo Nobel Nv Verfahren zur Sulfonierung von aromatischen Polyäthersulfonen
US4865930A (en) * 1988-10-27 1989-09-12 Hughes Aircraft Company Method for forming a gas-permeable and ion-permeable membrane
US5288529A (en) 1989-06-16 1994-02-22 Foster-Miller Inc. Liquid crystal polymer film
US5202165A (en) 1989-08-18 1993-04-13 Foster-Miller, Inc. Vessel construction
WO1991014499A1 (fr) 1990-03-27 1991-10-03 Toray Industries, Inc. Membrane composite
CA2085549A1 (en) 1991-12-25 1993-06-26 Noboru Nakano Fuel cell and electrolyte membrane therefor
DE69305878T2 (de) 1992-01-20 1997-05-22 Nippon Telegraph & Telephone Fester Polymerelektrolyt und Verfahren zu seiner Herstellung
SG73410A1 (en) 1992-06-13 2000-06-20 Hoechst Ag Polymer electrolyte membrane and process for the production thereof
US5300206A (en) 1992-08-03 1994-04-05 Metallgesellschaft Ag Antipercolation gas-diffusion electrode and method of making same
DE4241150C1 (de) 1992-12-07 1994-06-01 Fraunhofer Ges Forschung Elektrodenmembran-Verbund, Verfahren zu dessen Herstellung sowie dessen Verwendung
US5271813A (en) 1993-03-29 1993-12-21 University Of Central Florida Apparatus and method for the electrolysis of water employing a sulfonated solid polymer electrolyte
US5403675A (en) 1993-04-09 1995-04-04 Maxdem, Incorporated Sulfonated polymers for solid polymer electrolytes
US5348569A (en) 1993-06-30 1994-09-20 Praxair Technology, Inc. Modified poly(phenylene oxide) based membranes for enhanced fluid separation
US5422411A (en) 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5773162A (en) 1993-10-12 1998-06-30 California Institute Of Technology Direct methanol feed fuel cell and system
US5599638A (en) 1993-10-12 1997-02-04 California Institute Of Technology Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane
DE4415678A1 (de) 1994-05-04 1995-11-09 Hoechst Ag Elektrochemische Zelle
US5599614A (en) 1995-03-15 1997-02-04 W. L. Gore & Associates, Inc. Integral composite membrane
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
AU5889296A (en) 1995-06-07 1996-12-30 Ballard Power Systems Inc. Copolymeric compositions of trifluorostyrene, substituted tr ifluorostyrene and substituted ethylene, and ion-exchange me mbranes formed therefrom
US5599639A (en) 1995-08-31 1997-02-04 Hoechst Celanese Corporation Acid-modified polybenzimidazole fuel cell elements
DE69608702T2 (de) 1995-12-28 2001-02-01 The Research Foundation Of State University Of New York, Albany Membranen aus sulfoniertem polyphenylenoxid (s-ppo) und polymerblends mit polyvinylidenfluorid (pvdf) zum einsatz als polymerelektrolyt in elektrochemischen zellen
FR2748485B1 (fr) 1996-05-07 1998-08-07 Commissariat Energie Atomique Polyimides sulfones, membranes preparees avec ceux-ci, et dispositif de pile a combustible comprenant ces membranes
US6187231B1 (en) 1996-10-01 2001-02-13 Celanese Ventures Gmbh Process for producing polymeric films for use as fuel cells
US6444343B1 (en) 1996-11-18 2002-09-03 University Of Southern California Polymer electrolyte membranes for use in fuel cells

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63248490A (ja) * 1987-04-06 1988-10-14 Mitsubishi Heavy Ind Ltd 多重効用造水装置の運転法
JPH05326037A (ja) * 1992-05-14 1993-12-10 Nitto Denko Corp 電 池
JPH0629032A (ja) * 1992-07-08 1994-02-04 Sumitomo Electric Ind Ltd 高分子電解質膜及びその製造法
JPH06242474A (ja) * 1993-02-17 1994-09-02 Tonen Corp エレクトロクロミック素子及び高分子電解質薄膜の製造方法
WO1996013872A1 (en) * 1994-11-01 1996-05-09 Case Western Reserve University Proton conducting polymers
WO1996018216A1 (de) * 1994-12-09 1996-06-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Polymerelektrolyt-membran-brennstoffzelle
WO1996029360A1 (de) * 1995-03-20 1996-09-26 Hoechst Aktiengesellschaft Sulfonierte polyetherketone, verfahren zu ihrer herstellung und verwendung zur herstellung von membranen
JP2001514431A (ja) * 1997-08-29 2001-09-11 フオスター・ミラー・インコーポレイテツド 複合固体ポリマー電解質膜

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002008680A (ja) * 2000-06-21 2002-01-11 Toyota Central Res & Dev Lab Inc 複合化架橋電解質
JP2003022823A (ja) * 2001-07-09 2003-01-24 Nitto Denko Corp プロトン伝導性膜又はフィルムとそれらを用いてなる燃料電池
US7862921B2 (en) 2003-03-28 2011-01-04 Sumitomo Chemical Company, Limited Process for continuously producing polymer electrolyte membrane and producing apparatus therefor
JP2005048022A (ja) * 2003-07-31 2005-02-24 Toyobo Co Ltd 複合イオン交換膜およびその製造方法
JP2006120368A (ja) * 2004-10-19 2006-05-11 Asahi Glass Co Ltd 固体高分子電解質膜、固体高分子型燃料電池用膜電極接合体及び固体高分子電解質膜の製造方法
KR100750290B1 (ko) * 2006-07-11 2007-08-20 한국화학연구원 상호침투 고분자 그물구조를 갖는 연료전지용 동시가교-이미드 고분자 전해질막과 이의 제조방법
JP2013503436A (ja) * 2009-08-25 2013-01-31 コーロン インダストリーズ インク 燃料電池用の高分子電解質膜及びその製造方法
US8486579B2 (en) 2009-12-04 2013-07-16 Prudent Energy Inc. Polymer blend proton exchange membrane and method for manufacturing the same
JP2012506945A (ja) * 2009-12-04 2012-03-22 ベイジン プルーデント センチュリー テクノロジー．コー．エルティーディー ポリマーブレンドプロトン交換膜及びこれを製造する方法
US9893373B2 (en) 2010-05-25 2018-02-13 3M Innovative Properties Company Reinforced electrolyte membrane
JP2016532259A (ja) * 2013-08-06 2016-10-13 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 内部での架橋結合を用いて電解質膜を製造する方法
JP2017532716A (ja) * 2014-08-04 2017-11-02 ジョンソン、マッセイ、フュエル、セルズ、リミテッドＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｆｕｅｌ Ｃｅｌｌｓ Ｌｉｍｉｔｅｄ 膜
US10777833B2 (en) 2014-08-04 2020-09-15 Johnson Matthey Fuel Cells Limited Membrane
JP2018506149A (ja) * 2015-01-09 2018-03-01 アプライド マテリアルズ インコーポレイテッドＡｐｐｌｉｅｄ Ｍａｔｅｒｉａｌｓ，Ｉｎｃｏｒｐｏｒａｔｅｄ バッテリセパレータ上へのリチウム金属コーティング
US11705569B2 (en) 2017-04-03 2023-07-18 Asahi Kasei Kabushiki Kaisha Composite polymer electrolyte membrane
CN109999664A (zh) * 2019-04-17 2019-07-12 北京碧水源膜科技有限公司 窄孔径分布大通量纳滤膜的制备方法
WO2024101800A1 (ko) * 2022-11-08 2024-05-16 코오롱인더스트리 주식회사 연료 전지용 막-전극 어셈블리, 및 이의 제조 방법

Also Published As

Publication number Publication date
WO2000022684A3 (en) 2000-07-20
CA2342237A1 (en) 2000-04-20
US20020045085A1 (en) 2002-04-18
AU2341500A (en) 2000-05-01
US6248469B1 (en) 2001-06-19
US7052793B2 (en) 2006-05-30
WO2000022684A2 (en) 2000-04-20
WO2000022684A9 (en) 2000-12-14

Similar Documents

Publication Publication Date Title
US6248469B1 (en) Composite solid polymer electrolyte membranes
US7550216B2 (en) Composite solid polymer electrolyte membranes
CA2300934C (en) Composite solid polymer electrolyte membranes
Ding et al. Enhancing proton conductivity of polybenzimidazole membranes by introducing sulfonate for vanadium redox flow batteries applications
CA2402840C (en) Composite ion exchange material
CA2679594C (en) Polymer electrolyte composition, polymer electrolyte membrane, membrane electrode assembly and solid polymer electrolyte-based fuel cell
JP2003503510A (ja) 電気化学的用途での使用に好適な新規なイオン伝導性材料およびそれに関連する方法
KR102295383B1 (ko) 고분자 전해질 막, 막 전극 접합체 및 고체 고분자형 연료 전지
JP2011103295A (ja) 高分子電解質膜、膜−電極接合体、及び固体高分子形燃料電池
CA2382144C (en) Composite ion-exchange membranes
JP4337175B2 (ja) 高分子電解質およびイオン交換体
JP2003528212A (ja) イオン交換材料
JP2008500701A (ja) 固体ポリマー電解質膜
CN100539271C (zh) 固体高分子电解质膜及其制造方法
JP2009217950A (ja) イオン伝導性高分子電解質膜およびその製造方法
Liu et al. Sulfonated poly (aryl ether)-type polymers as proton exchange membranes: synthesis and performance
EP1116292A2 (en) Composite solid polymer electrolyte membranes
KR20110090051A (ko) 퍼플루오로사이클로부탄기를 포함하는 브랜치된 술폰화 공중합체, 이의 제조방법 및 이를 이용한 전해질막
TWI645609B (zh) 高分子電解質膜、膜電極接合體及固體高分子型燃料電池
CA3013067C (en) Bipolar ionomer membrane

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060825

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060825

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20091013

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20091228

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20100108

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100412

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20100518