DK2411443T4 - Fremgangsmåde til fremstilling af umættet polyester - Google Patents
Fremgangsmåde til fremstilling af umættet polyester Download PDFInfo
- Publication number
- DK2411443T4 DK2411443T4 DK10709858.4T DK10709858T DK2411443T4 DK 2411443 T4 DK2411443 T4 DK 2411443T4 DK 10709858 T DK10709858 T DK 10709858T DK 2411443 T4 DK2411443 T4 DK 2411443T4
- Authority
- DK
- Denmark
- Prior art keywords
- unsaturated polyester
- resin
- itaconate
- ester units
- polyester resin
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyesters Or Polycarbonates (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Developing Agents For Electrophotography (AREA)
Claims (25)
1. En fremgangsmåde til fremstilling af en umættet polyester harpiks omfattende itaconatholdige esterenheder som reaktive umættetheder ved omsætning af mindst itaconsyre og/eller itaconsyreanhydrid og mindst en diol, hvor fremgangsmåden udføres i nærvær af en 2-methyl-hydroquinon og hydroquinon.
2. Fremgangsmåden ifølge krav 1, hvor fremgangsmåden omfatter følgende trin: (i) påfyldning af reaktoren med itaconsyre og/eller itaconsyreanhydrid og den mindst ene diol og den 2-methyl-hydroquinon og den hydroquinon, (ii) opvarmning af reaktoren, indtil en temperatur på fra 180 til 200 °C, indtil syretallet af det dannede umættede polyester ligger under 60 mg KOH/g harpiks, (iii) afkøling af den dannede harpiks til fra 20 til 120 °C.
3. Fremgangsmåden ifølge ethvert af de foregående krav, hvor mængden af den 2-methyl-hydroquinon er mindst 25 ppm og højst 2.000 ppm, i forhold til mængden af råmaterialer, der er anvendt til fremstilling af den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder.
4. Fremgangsmåden ifølge ethvert af de foregående krav, hvor mængden af den 2-methyl-hydroquinon er mindst 25 ppm og højst 750 ppm, i forhold til mængden af råmaterialer, der er anvendt til fremstilling af den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder.
5. Fremgangsmåden ifølge ethvert af de foregående krav, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder er sammensat af: i) fra 33 til 66 mol-% glycol-monomerer, ii) fra 10 til 66 mol-% itaconsyre-monomerer, iii) fra 0 til 65 mol-% umættede disyremonomerer andre end itaconsyre- monomerer, og iv) fra O til 65 mol-% disyrer andre end umættede disyremonomerer.
6. Fremgangsmåden ifølge ethvert af de foregående krav, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder har et syretal, som er bestemt titrimetrisk ifølge ISO 2114-2400, i området fra 30 til 100 mg KOH/g harpiks.
7. Fremgangsmåden ifølge ethvert af de foregående krav, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder har en hydroxylværdi, som er bestemt titrimetrisk i henhold til ISO 4629-1996 højere end 25 mg KOH/g harpiks.
8. Fremgangsmåden ifølge ethvert af de foregående krav, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder har en Mn, som er bestemt i tetrahydrofuran ved GPC efter ISO 13885-1 ved at anvende polystyrenstandarder, på mindst 750 og højst 10000 Dalton.
9. Fremgangsmåden ifølge ethvert af de foregående krav, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder har en glasovergangstemperatur, bestemt ved hjælp af DSC ved en opvarmningshastighed på 5 °C/min, på mindst -70 og på højst 100 °C.
10. Fremgangsmåden ifølge ethvert af de foregående krav, hvor det molære forhold mellem mængden af hydroquinon og 2-hydroquinon er i området fra 0,2 til 5.
11. Fremgangsmåden ifølge ethvert af kravene 1-9, hvor det molære forhold mellem mængden af hydroquinon og 2-methyl-hydroquinon er i området fra 0,5 til 2.
12. Fremgangsmåden ifølge ethvert af de foregående krav, hvor mindst 25 vægt-% af de umættede dicarboxylsyre-byggesten af den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder, er itaconsyre-byggesten.
13. En harpikssammensætning omfattende en umættet polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder, 2-methyl-hydroquinon og hydroquinon hvor det molære forhold mellem mængden af hydroquinon og 2-methyl-hydroquinon er i området fra 0,2 til 2.
14. Harpikssammensætningen ifølge krav 13, hvor mængden af den 2-methyl-hydroquinon er mindst 25 ppm og højst 2.000 ppm, i forhold til den totale harpikssammensætning.
15. Harpikssammensætningen ifølge krav 13, hvor mængden af den 2-methyl-hydroquinon er mindst 25 ppm og højst 750 ppm, i forhold til den totale harpikssammensætning.
16. Harpikssammensætningen ifølge ethvert af kravene 13-15, yderligere omfattende en initiator.
17. Harpikssammensætningen ifølge krav 16, hvor initiatoren er et peroxid.
18. Harpikssammensætningen ifølge ethvert af kravene 13-17, hvor mindst 25 vægt-% af de umættede dicarboxylsyre-byggesten af den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder, er itaconsyre-byggesten.
19. Harpikssammensætningen ifølge ethvert af kravene 13-18 yderligere omfattende et reaktivt fortyndingsmiddel, som er i stand til at copolymerisere med den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder.
20. En hærdet genstand eller strukturel del opnået fra en harpikssammensætning ifølge ethvert af kravene 13-19 ved hærdning med en initiator.
21. Den hærdede genstand eller strukturel del ifølge krav 20, hvor initiatoren omfatter et peroxid.
22. Anvendelse af den hærdede genstand eller strukturel del ifølge krav 20 eller krav 21 i bildele, både, kemisk forankring, tagdækning, byggeri, containere, relining, rør, tanke, gulve eller vindmøllevinger.
23. En pulverovertrækssammensætning omfattende en harpikssammensætning ifølge ethvert af kravene 13-19.
24. Pulverovertrækssammensætningen ifølge krav 23, hvor den umættede polyesterharpiks omfattende itaconatholdige esterenheder som reaktive umættetheder har en glasovergangstemperatur, som er bestemt ved hjælp af DSC ved en opvarmningshastighed på 5 °C/min, på mindst 20 og højst 100 °C.
25. Fremgangsmåde til coating af et substrat med en pulverbelægnings-sammensætning ifølge ethvert af kravene 23-24, omfattende trinnene: 1) påføring af pulverovertrækssammensætningen på et substrat, således at substratet delvist eller helt er overtrukket med et overtræk, 2) opvarmning af den opnåede delvist eller helt overtrukket substrat for en sådan tid og til en sådan temperatur, at belægningen er mindst delvist hærdet.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09156142 | 2009-03-25 | ||
| EP09156130 | 2009-03-25 | ||
| EP09156131 | 2009-03-25 | ||
| EP09156137 | 2009-03-25 | ||
| EP09156139 | 2009-03-25 | ||
| PCT/EP2010/053851 WO2010108966A1 (en) | 2009-03-25 | 2010-03-24 | Process for preparing unsaturated polyester |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK2411443T3 DK2411443T3 (da) | 2016-04-11 |
| DK2411443T4 true DK2411443T4 (da) | 2018-11-19 |
Family
ID=42124624
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK10709858.4T DK2411443T4 (da) | 2009-03-25 | 2010-03-24 | Fremgangsmåde til fremstilling af umættet polyester |
| DK10710043.0T DK2411445T4 (da) | 2009-03-25 | 2010-03-24 | Umættet polyesterresin |
| DK10709857.6T DK2411442T4 (da) | 2009-03-25 | 2010-03-24 | Umættet polyesterresin |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK10710043.0T DK2411445T4 (da) | 2009-03-25 | 2010-03-24 | Umættet polyesterresin |
| DK10709857.6T DK2411442T4 (da) | 2009-03-25 | 2010-03-24 | Umættet polyesterresin |
Country Status (8)
| Country | Link |
|---|---|
| US (6) | US20120157618A1 (da) |
| EP (6) | EP2411444B1 (da) |
| JP (6) | JP2012521466A (da) |
| CN (6) | CN102361905B (da) |
| BR (6) | BRPI1011743B1 (da) |
| DK (3) | DK2411443T4 (da) |
| ES (6) | ES2477891T3 (da) |
| WO (6) | WO2010108968A1 (da) |
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