DE69730718T2 - Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren - Google Patents
Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren Download PDFInfo
- Publication number
- DE69730718T2 DE69730718T2 DE69730718T DE69730718T DE69730718T2 DE 69730718 T2 DE69730718 T2 DE 69730718T2 DE 69730718 T DE69730718 T DE 69730718T DE 69730718 T DE69730718 T DE 69730718T DE 69730718 T2 DE69730718 T2 DE 69730718T2
- Authority
- DE
- Germany
- Prior art keywords
- dimethyl
- dimethylethyl
- silanaminato
- inden
- pyrrolidinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 0 **NC(CC1I)c2c1cccc2 Chemical compound **NC(CC1I)c2c1cccc2 0.000 description 2
- APTPTAJVOFVBJQ-UHFFFAOYSA-O CC(C1)=C(C=CC=C2)C2=C1[SH+]C Chemical compound CC(C1)=C(C=CC=C2)C2=C1[SH+]C APTPTAJVOFVBJQ-UHFFFAOYSA-O 0.000 description 1
- XUDKRHLNQZAEJR-GFDZPQBUSA-N CCCCNC(C1)=C(C=CC=C2)C2=C1[Si](C)(C)N(C(C)(C)C)[Tl+](C)(C)/C(/C=C/C)=C/C Chemical compound CCCCNC(C1)=C(C=CC=C2)C2=C1[Si](C)(C)N(C(C)(C)C)[Tl+](C)(C)/C(/C=C/C)=C/C XUDKRHLNQZAEJR-GFDZPQBUSA-N 0.000 description 1
- OPNXKKBXOFRPEJ-UHFFFAOYSA-N CN(C)C1=CCC2C=CC=CC12 Chemical compound CN(C)C1=CCC2C=CC=CC12 OPNXKKBXOFRPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2376896P | 1996-08-08 | 1996-08-08 | |
US23768P | 1996-08-08 | ||
US3481996P | 1996-12-19 | 1996-12-19 | |
US34819P | 1996-12-19 | ||
PCT/US1997/013170 WO1998006727A1 (en) | 1996-08-08 | 1997-07-28 | 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69730718D1 DE69730718D1 (de) | 2004-10-21 |
DE69730718T2 true DE69730718T2 (de) | 2005-09-22 |
Family
ID=26697575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69730718T Expired - Lifetime DE69730718T2 (de) | 1996-08-08 | 1997-07-28 | Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren |
Country Status (24)
Families Citing this family (141)
Publication number | Priority date | Publication date | Assignee | Title |
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US5968337A (en) * | 1996-04-18 | 1999-10-19 | Battelle Memorial Institute | Apparatus and method for constant flow oxidizing of organic materials |
JP2002519497A (ja) | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド |
ATE495205T1 (de) | 1998-11-02 | 2011-01-15 | Dow Global Technologies Inc | Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung |
US6326493B1 (en) * | 1999-01-25 | 2001-12-04 | Chisso Corporation | Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers |
EP1070072A4 (en) * | 1999-02-05 | 2002-09-25 | Boulder Scient Co | PRODUCTION OF SILYLATED AND N-SILYLATED COMPOUNDS |
JP2002542348A (ja) * | 1999-04-20 | 2002-12-10 | ビーピー ケミカルズ リミテッド | 遅延活性支持オレフィン重合触媒組成物、並びにその作成および使用方法 |
EP1177198B1 (en) | 1999-04-29 | 2002-11-20 | Dow Global Technologies Inc. | Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof |
DE60001557T2 (de) | 1999-05-13 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Metallkomplexe mit heteroatom-enthaltende brücke für olefinpolymerisationsverfahren |
AU3764600A (en) * | 1999-05-13 | 2000-12-05 | Dow Chemical Company, The | Di- and tri-heteroatom substituted indenyl metal complexes |
EP1102778B1 (en) | 1999-06-04 | 2003-04-02 | Basell Polyolefine GmbH | Process for the preparation of titanium complexes |
WO2000075146A1 (en) | 1999-06-04 | 2000-12-14 | The Dow Chemical Company | Boron-substituted cyclopentadienes and metal complexes thereof |
DE19927766A1 (de) * | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
EP1253158A1 (en) * | 1999-12-10 | 2002-10-30 | Dow Global Technologies Inc. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
EP1242471B1 (en) * | 1999-12-10 | 2012-02-29 | Dow Global Technologies LLC | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
JP2003520869A (ja) * | 2000-01-18 | 2003-07-08 | バセル テクノロジー カンパニー ビー.ブイ. | 実質的に非晶質のプロピレンベースのポリマーの製造方法 |
JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
US6906160B2 (en) * | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
US6943215B2 (en) * | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
JP2005508415A (ja) * | 2001-11-06 | 2005-03-31 | ダウ グローバル テクノロジーズ インコーポレイティド | アイソタクチックプロピレンコポリマー類、その製法および用途 |
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JP4062929B2 (ja) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
AU2003216477A1 (en) * | 2002-03-14 | 2003-09-29 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
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AU719500B2 (en) | 2000-05-11 |
TW455595B (en) | 2001-09-21 |
KR100528754B1 (ko) | 2006-01-09 |
SK15399A3 (en) | 2000-04-10 |
JP2000516228A (ja) | 2000-12-05 |
CA2262910C (en) | 2006-04-11 |
HUP9902581A2 (hu) | 1999-11-29 |
NO990545D0 (no) | 1999-02-05 |
BR9711124A (pt) | 1999-09-28 |
ES2224266T3 (es) | 2005-03-01 |
DE69730718D1 (de) | 2004-10-21 |
AR009035A1 (es) | 2000-03-08 |
JP3407074B2 (ja) | 2003-05-19 |
CO4870708A1 (es) | 1999-12-27 |
ATE276263T1 (de) | 2004-10-15 |
MY132554A (en) | 2007-10-31 |
HUP9902581A3 (en) | 2004-03-01 |
CZ42399A3 (cs) | 1999-07-14 |
KR20000029833A (ko) | 2000-05-25 |
ID18004A (id) | 1998-02-19 |
NZ333878A (en) | 2000-08-25 |
NO326005B1 (no) | 2008-09-01 |
CN1230190A (zh) | 1999-09-29 |
EP0923589A1 (en) | 1999-06-23 |
TR199900487T2 (xx) | 1999-06-21 |
CA2262910A1 (en) | 1998-02-19 |
CN1114609C (zh) | 2003-07-16 |
WO1998006727A1 (en) | 1998-02-19 |
NO990545L (no) | 1999-03-26 |
AU4145697A (en) | 1998-03-06 |
EG21365A (en) | 2001-09-30 |
US6268444B1 (en) | 2001-07-31 |
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