CN1208294C - 将乙烯转化成氯乙烯的生产方法和在该方法中使用的新催化剂组合物 - Google Patents

将乙烯转化成氯乙烯的生产方法和在该方法中使用的新催化剂组合物 Download PDF

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Publication number
CN1208294C
CN1208294C CNB008159696A CN00815969A CN1208294C CN 1208294 C CN1208294 C CN 1208294C CN B008159696 A CNB008159696 A CN B008159696A CN 00815969 A CN00815969 A CN 00815969A CN 1208294 C CN1208294 C CN 1208294C
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China
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catalyst
rare earth
ethylene
reactor
chlorine
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Expired - Fee Related
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CNB008159696A
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Chinese (zh)
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CN1391546A (zh
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M·E·琼斯
M·M·奥尔肯
D·A·希克曼
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Lanco Intellectual Property Co ltd
Dow Global Technologies LLC
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Dow Chemical Co
Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB008159696A 1999-11-22 2000-10-03 将乙烯转化成氯乙烯的生产方法和在该方法中使用的新催化剂组合物 Expired - Fee Related CN1208294C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16689799P 1999-11-22 1999-11-22
US60/166,897 1999-11-22

Related Child Applications (2)

Application Number Title Priority Date Filing Date
CN2004100885764A Division CN1623659B (zh) 1999-11-22 2000-10-03 将乙烯转化成氯乙烯的生产方法中使用的新催化剂组合物
CNA2007101281197A Division CN101104147A (zh) 1999-11-22 2000-10-03 一种具催化作用的组合物

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CN1391546A CN1391546A (zh) 2003-01-15
CN1208294C true CN1208294C (zh) 2005-06-29

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Family Applications (8)

Application Number Title Priority Date Filing Date
CN2004100885764A Expired - Fee Related CN1623659B (zh) 1999-11-22 2000-10-03 将乙烯转化成氯乙烯的生产方法中使用的新催化剂组合物
CNB008159696A Expired - Fee Related CN1208294C (zh) 1999-11-22 2000-10-03 将乙烯转化成氯乙烯的生产方法和在该方法中使用的新催化剂组合物
CNA2007101281197A Pending CN101104147A (zh) 1999-11-22 2000-10-03 一种具催化作用的组合物
CN00815970A Pending CN1391547A (zh) 1999-11-22 2000-10-06 由乙烷和乙烯制造氯乙烯并从反应器流出物中部分回收hci的方法
CN00815909A Pending CN1391544A (zh) 1999-11-22 2000-10-06 由乙烷乙烯制造氯乙烯次反应消耗反应器流出物流中氯化氢的方法
CN00816026A Pending CN1391545A (zh) 1999-11-22 2000-10-06 从反应器流出物直接回收hci的由乙烷和乙烯制造氯乙烯的方法
CNB008160244A Expired - Fee Related CN1206196C (zh) 1999-11-22 2000-11-16 采用多孔稀土卤化物载体的催化剂的氧卤化方法
CN00816025A Pending CN1391548A (zh) 1999-11-22 2000-11-16 使用稀土卤化物或卤氧化物催化剂进行卤代烷烃的脱氢卤化作用

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN2004100885764A Expired - Fee Related CN1623659B (zh) 1999-11-22 2000-10-03 将乙烯转化成氯乙烯的生产方法中使用的新催化剂组合物

Family Applications After (6)

Application Number Title Priority Date Filing Date
CNA2007101281197A Pending CN101104147A (zh) 1999-11-22 2000-10-03 一种具催化作用的组合物
CN00815970A Pending CN1391547A (zh) 1999-11-22 2000-10-06 由乙烷和乙烯制造氯乙烯并从反应器流出物中部分回收hci的方法
CN00815909A Pending CN1391544A (zh) 1999-11-22 2000-10-06 由乙烷乙烯制造氯乙烯次反应消耗反应器流出物流中氯化氢的方法
CN00816026A Pending CN1391545A (zh) 1999-11-22 2000-10-06 从反应器流出物直接回收hci的由乙烷和乙烯制造氯乙烯的方法
CNB008160244A Expired - Fee Related CN1206196C (zh) 1999-11-22 2000-11-16 采用多孔稀土卤化物载体的催化剂的氧卤化方法
CN00816025A Pending CN1391548A (zh) 1999-11-22 2000-11-16 使用稀土卤化物或卤氧化物催化剂进行卤代烷烃的脱氢卤化作用

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EP (4) EP1235772B1 (enExample)
JP (3) JP5053493B2 (enExample)
KR (3) KR100780562B1 (enExample)
CN (8) CN1623659B (enExample)
AR (6) AR026559A1 (enExample)
AT (4) ATE287386T1 (enExample)
AU (3) AU779286B2 (enExample)
BG (3) BG106725A (enExample)
BR (3) BR0015921B1 (enExample)
CA (3) CA2391582C (enExample)
DE (2) DE60017590T2 (enExample)
DK (2) DK1235772T3 (enExample)
GC (2) GC0000145A (enExample)
HU (3) HUP0204181A2 (enExample)
IL (6) IL149742A0 (enExample)
MA (6) MA25692A1 (enExample)
MX (3) MXPA02005142A (enExample)
MY (1) MY125504A (enExample)
NO (6) NO20022402L (enExample)
PL (6) PL354730A1 (enExample)
RU (4) RU2265006C2 (enExample)
TW (2) TW581752B (enExample)
WO (4) WO2001038273A1 (enExample)

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