CN101980398A - 硫化锂的精制方法 - Google Patents

硫化锂的精制方法 Download PDF

Info

Publication number
CN101980398A
CN101980398A CN2010100021743A CN201010002174A CN101980398A CN 101980398 A CN101980398 A CN 101980398A CN 2010100021743 A CN2010100021743 A CN 2010100021743A CN 201010002174 A CN201010002174 A CN 201010002174A CN 101980398 A CN101980398 A CN 101980398A
Authority
CN
China
Prior art keywords
lithium
lithium sulfide
sulfide
organic solvent
solid electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010100021743A
Other languages
English (en)
Chinese (zh)
Inventor
清野美胜
千贺实
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Publication of CN101980398A publication Critical patent/CN101980398A/zh
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/36—Purification
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2010100021743A 2003-10-23 2004-10-15 硫化锂的精制方法 Pending CN101980398A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003363403 2003-10-23
JP2003-363403 2003-10-23

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN2004800309857A Division CN1871177B (zh) 2003-10-23 2004-10-15 硫化锂的精制方法

Publications (1)

Publication Number Publication Date
CN101980398A true CN101980398A (zh) 2011-02-23

Family

ID=34510038

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2010100021743A Pending CN101980398A (zh) 2003-10-23 2004-10-15 硫化锂的精制方法
CN2004800309857A Expired - Fee Related CN1871177B (zh) 2003-10-23 2004-10-15 硫化锂的精制方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2004800309857A Expired - Fee Related CN1871177B (zh) 2003-10-23 2004-10-15 硫化锂的精制方法

Country Status (8)

Country Link
US (1) US8084160B2 (cg-RX-API-DMAC7.html)
EP (1) EP1681263B1 (cg-RX-API-DMAC7.html)
JP (1) JP4896520B2 (cg-RX-API-DMAC7.html)
KR (1) KR101109821B1 (cg-RX-API-DMAC7.html)
CN (2) CN101980398A (cg-RX-API-DMAC7.html)
AT (1) ATE513788T1 (cg-RX-API-DMAC7.html)
TW (1) TW200530121A (cg-RX-API-DMAC7.html)
WO (1) WO2005040039A1 (cg-RX-API-DMAC7.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110255587A (zh) * 2012-11-15 2019-09-20 阿克马法国公司 用于制备碱金属硫化物的方法

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066539A1 (ja) 2005-12-09 2007-06-14 Idemitsu Kosan Co., Ltd. リチウムイオン伝導性硫化物系固体電解質及びそれを用いた全固体リチウム電池
EP2211415B1 (en) 2007-10-11 2013-11-06 Idemitsu Kosan Co., Ltd. Method for producing lithium ion conductive solid electrolyte
WO2010006366A1 (en) 2008-07-18 2010-01-21 Rincon Lithium Limited A process for recovering lithium from a brine
JP2010126422A (ja) * 2008-11-28 2010-06-10 Panasonic Corp リチウム含有複合酸化物の製造方法および非水系二次電池
JP5448038B2 (ja) 2009-02-27 2014-03-19 公立大学法人大阪府立大学 硫化物固体電解質材料
JP5287739B2 (ja) 2009-05-01 2013-09-11 トヨタ自動車株式会社 固体電解質材料
JP5590836B2 (ja) 2009-09-09 2014-09-17 公立大学法人大阪府立大学 硫化物固体電解質
JP5168269B2 (ja) 2009-11-25 2013-03-21 トヨタ自動車株式会社 Ｌｉイオン伝導性材料およびリチウム電池
JP5629198B2 (ja) * 2009-12-04 2014-11-19 出光興産株式会社 アルカリ金属硫化物及びその製造方法
JP5141675B2 (ja) 2009-12-16 2013-02-13 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池
CN103052995B (zh) 2010-08-05 2016-07-13 丰田自动车株式会社 硫化物固体电解质玻璃、锂固体电池和硫化物固体电解质玻璃的制造方法
JP5729940B2 (ja) * 2010-08-13 2015-06-03 出光興産株式会社 固体電解質ガラス及びその製造方法
JP5349427B2 (ja) 2010-08-26 2013-11-20 トヨタ自動車株式会社 硫化物固体電解質材料、正極体およびリチウム固体電池
JP5521899B2 (ja) 2010-08-26 2014-06-18 トヨタ自動車株式会社 硫化物固体電解質材料およびリチウム固体電池
JP5865268B2 (ja) * 2011-01-27 2016-02-17 出光興産株式会社 アルカリ金属硫化物と導電剤の複合材料
JP5708467B2 (ja) 2011-03-18 2015-04-30 トヨタ自動車株式会社 スラリー、固体電解質層の製造方法、電極活物質層の製造方法、および全固体電池の製造方法
JP5708233B2 (ja) 2011-05-18 2015-04-30 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法および硫化物固体電解質材料
CN103813980B (zh) * 2011-05-27 2016-05-18 罗克伍德锂有限责任公司 用于制备硫化锂的方法
DE102012209757A1 (de) * 2011-06-14 2012-12-20 Chemetall Gmbh Verfahren zur Herstellung eines kohlenstoffbeschichteten Lithiumsulfids und dessen Verwendung
JP5443445B2 (ja) 2011-07-06 2014-03-19 トヨタ自動車株式会社 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法
JP5445527B2 (ja) 2011-07-13 2014-03-19 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法
EP2759525B1 (en) 2011-09-22 2017-07-26 Idemitsu Kosan Co., Ltd Glass particles
JP6234665B2 (ja) 2011-11-07 2017-11-22 出光興産株式会社 固体電解質
JP6203474B2 (ja) 2011-11-24 2017-09-27 出光興産株式会社 電極材料、電極及びそれを用いたリチウムイオン電池
JP6243103B2 (ja) 2012-06-29 2017-12-06 出光興産株式会社 正極合材
WO2014073197A1 (ja) 2012-11-06 2014-05-15 出光興産株式会社 固体電解質
JP5757284B2 (ja) 2012-12-27 2015-07-29 トヨタ自動車株式会社 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法
JP6259617B2 (ja) 2013-04-24 2018-01-10 出光興産株式会社 固体電解質の製造方法
WO2014192309A1 (ja) 2013-05-31 2014-12-04 出光興産株式会社 固体電解質の製造方法
JP5673760B1 (ja) 2013-09-13 2015-02-18 トヨタ自動車株式会社 硫化物固体電解質の製造方法
CN103523806B (zh) * 2013-10-22 2014-11-12 瓮福（集团）有限责任公司 一种高纯度无水硫酸锂的制备方法
WO2016067631A1 (ja) 2014-10-31 2016-05-06 出光興産株式会社 硫化物ガラス及び結晶性固体電解質の製造方法、結晶性固体電解質、硫化物ガラス及び固体電池
JP6697398B2 (ja) 2014-12-16 2020-05-20 出光興産株式会社 硫化リチウム製造用装置及び硫化リチウムの製造方法
CN104609376A (zh) * 2015-01-30 2015-05-13 浙江工业大学 一种硫化锂粉体的制备方法
KR101684130B1 (ko) 2015-06-16 2016-12-07 현대자동차주식회사 리튬 이온 전도성 황화물의 제조방법, 이에 의하여 제조된 리튬 이온 전도성 황화물, 및 이를 포함하는 고체전해질, 전고체 배터리
CN105016310A (zh) * 2015-07-30 2015-11-04 广东先导稀材股份有限公司 一种高纯硫化锂的制备方法及装置
KR101930992B1 (ko) * 2016-02-15 2018-12-19 한양대학교 산학협력단 황화물계 고체 전해질의 제조방법, 이로부터 제조된 황화물계 고체 전해질 및 이를 포함하는 전고체 리튬 이차전지
KR101886036B1 (ko) 2016-08-22 2018-08-07 한국과학기술연구원 대기 안정성이 우수한 황화물계 고체전해질의 제조방법
JP6923173B2 (ja) 2016-12-14 2021-08-18 出光興産株式会社 硫黄含有複合体、その製造方法、及び固体電解質の製造方法
JP7294795B2 (ja) * 2017-11-17 2023-06-20 出光興産株式会社 硫化リチウム粉体、及びその製造方法
CN110790239B (zh) * 2019-08-26 2022-01-28 浙江工业大学 一种硫化锂粉体的机械球磨合成方法
CN112678781B (zh) * 2019-10-18 2022-04-15 天齐锂业（江苏）有限公司 硫化锂的制备方法
CN115135617B (zh) * 2020-02-17 2024-04-23 坚固力量营运公司 制备水反应性的硫化物材料的方法
CN112624060B (zh) * 2020-12-31 2022-09-20 江西赣锋锂业股份有限公司 一种利用工业级丁基锂制备高纯硫化锂的方法
JP7120424B1 (ja) * 2021-09-30 2022-08-17 Ａｇｃ株式会社 硫化水素の精製方法、硫化リチウムの製造方法、硫化水素精製装置および硫化リチウム製造装置
KR102707192B1 (ko) * 2022-02-28 2024-09-20 주식회사 레이크테크놀로지 황화리튬 제조 장치
JP2025512130A (ja) * 2022-03-31 2025-04-16 ソリヴィス インコーポレイテッド 高純度のアルカリ金属硫化物の製造方法
KR102666522B1 (ko) * 2022-11-10 2024-05-16 전북대학교산학협력단 황화 리튬의 제조방법
KR20240112592A (ko) * 2023-01-12 2024-07-19 주식회사 이수스페셜티케미컬 황화 리튬의 제조 방법
DE102023102404A1 (de) 2023-02-01 2024-08-01 Albemarle Germany Gmbh Verfahren zur Herstellung von an Kohlenstoffverunreinigung reduziertem/Kohlenstoffverunreinigung freiem Lithiumsulfid, das Kohlenstoffverunreinigung reduzierte/Kohlenstoffverunreinigung freie Lithiumsulfid sowie dessen Verwendung zur Herstellung von Festelektrolyten und Feststoffbatterien
DE102023114082A1 (de) 2023-05-30 2024-12-05 Albemarle Germany Gmbh Verfahren zur Herstellung von an Kohlenstoffverunreinigung reduziertem/Kohlenstoffverunreinigung freiem Lithiumsulfid, das an Kohlenstoffverunreinigung reduzierte/Kohlenstoffverunreinigung freie Lithiumsulfid sowie dessen Verwendung zur Synthese von Festkörperelektrolyten und Herstellung von Feststoffbatterien
CN117163922B (zh) 2023-09-20 2024-03-26 天齐锂业股份有限公司 Ev级硫化锂及其制备方法
KR20250094410A (ko) * 2023-12-18 2025-06-25 포스코홀딩스 주식회사 리튬 폴리설파이드를 이용한 황화 리튬의 제조 방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07330312A (ja) * 1994-06-03 1995-12-19 Idemitsu Petrochem Co Ltd 硫化リチウムの製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2677346B1 (fr) * 1991-06-10 1993-08-27 Atochem Procede de purification d'une solution aqueuse de chlorure de metal alcalin par enlevement de l'ammonium et de l'iode.
JPH09110404A (ja) * 1995-10-13 1997-04-28 Furukawa Co Ltd 硫化リチウムの製造方法
JP3816141B2 (ja) * 1996-04-16 2006-08-30 古河機械金属株式会社 硫化リチウムの製造方法
JP3510420B2 (ja) 1996-04-16 2004-03-29 松下電器産業株式会社 リチウムイオン伝導性固体電解質およびその製造方法
JPH09301706A (ja) * 1996-05-10 1997-11-25 Matsushita Electric Ind Co Ltd 固体電解質およびそれを用いた全固体リチウム電池
US6022640A (en) * 1996-09-13 2000-02-08 Matsushita Electric Industrial Co., Ltd. Solid state rechargeable lithium battery, stacking battery, and charging method of the same
JP3872846B2 (ja) * 1996-10-28 2007-01-24 出光興産株式会社 硫化リチウムの製造方法及びポリアリーレンスルフィドの製造方法
DE10008499A1 (de) * 1999-03-08 2000-09-28 Idemitsu Petrochemical Co Verfahren zur Abtrennung von festen Nicht-Lithiumhydroxid-Verbindungen
JP2000273175A (ja) 1999-03-19 2000-10-03 Idemitsu Petrochem Co Ltd ポリアリーレンスルフィド系樹脂の精製方法
JP3412616B2 (ja) 2000-07-19 2003-06-03 住友電気工業株式会社 リチウム二次電池用負極の製造方法
JP4953406B2 (ja) * 2001-08-23 2012-06-13 株式会社Ｇｓユアサ 全固体リチウム二次電池

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07330312A (ja) * 1994-06-03 1995-12-19 Idemitsu Petrochem Co Ltd 硫化リチウムの製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
AKITOSHI HAYASHI ET AL: "All-solid-state Li/S batteries with highly conductive glass–ceramic electrolytes", 《ELECTROCHEMISTRY COMMUNICATIONS》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110255587A (zh) * 2012-11-15 2019-09-20 阿克马法国公司 用于制备碱金属硫化物的方法

Also Published As

Publication number Publication date
US20070196739A1 (en) 2007-08-23
US8084160B2 (en) 2011-12-27
EP1681263B1 (en) 2011-06-22
EP1681263A1 (en) 2006-07-19
EP1681263A4 (en) 2008-06-25
TWI366554B (cg-RX-API-DMAC7.html) 2012-06-21
CN1871177A (zh) 2006-11-29
KR101109821B1 (ko) 2012-03-13
KR20060076316A (ko) 2006-07-04
TW200530121A (en) 2005-09-16
JPWO2005040039A1 (ja) 2007-03-01
JP4896520B2 (ja) 2012-03-14
WO2005040039A1 (ja) 2005-05-06
ATE513788T1 (de) 2011-07-15
EP1681263A8 (en) 2006-10-11
CN1871177B (zh) 2010-12-22

Similar Documents

Publication Publication Date Title
CN101980398A (zh) 硫化锂的精制方法
JP4128627B2 (ja) リチウムマンガン酸化物スピネルを製造する方法
US20070160911A1 (en) Lithium ion conducting sulfide based crystallized glass and method for production thereof
Zhu et al. Facile synthesis Zn-Ni bimetallic MOF with enhanced crystallinity for high power density supercapacitor applications
WO2005119706A1 (ja) 高性能全固体リチウム電池
KR20120044981A (ko) 비수 전해액 처리용 제올라이트 및 비수 전해액의 처리 방법
CN113336793B (zh) 一种二氟双草酸磷酸锂及其制备方法和应用
CN111483986A (zh) 一种双氟磺酰亚胺锂的制备方法及其双氟磺酰亚胺锂
KR20070099596A (ko) 리튬 이온 전도성 고체 전해질, 그 제조 방법 및 그 고체전해질을 이용한 리튬 2 차 전지용 고체 전해질, 그리고 그2 차 전지용 고체 전해질을 이용한 전고체 리튬 전지
CN118598869A (zh) 一种硫酸酯类化合物的合成方法及应用
US20240025744A1 (en) Method for preparing ultra cheap iron phosphate
CN106219503A (zh) 一种双（氟磺酰）亚胺及其碱金属盐的制备方法
JP2005187282A (ja) リチウム−ニッケル−マンガン複合酸化物及びその製造方法並びにその用途
CN117534089B (zh) 一种无添加剂制备高结晶Fe[Fe(CN)6]电极材料的方法及其应用
JPH11185810A (ja) リチウム電池用電解液及びその製造方法
Tanguy et al. Propagation of surface-assisted side reactions, a main cause for capacity fading of vanadium oxide nanograins
CN115385316B (zh) 一种磷酸铁锂的回收工艺
CN100355660C (zh) 一种(nh4)2v3o8的制备方法
CN110395750A (zh) 用作锂离子电池电解质的三氟甲基磺酸锂的制备方法
CN108448051A (zh) 水系钠离子电池Na0.58Mn2O4·1.38H2O材料及其制备方法与应用、电极
CN110085915B (zh) 一种高氯酸锂电解质溶液及其制备方法
CN107162949A (zh) 一种富马酸沃诺拉赞关键中间体及其制备方法
JP2025537446A (ja) ビス（フルオロスルホニル）イミドのアルカリ金属塩を含む組成物
CN115872871B (zh) 一种钙钛矿的合成方法及其应用
JP2025537445A (ja) ビス（フルオロスルホニル）イミドのアルカリ金属塩を含む組成物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20110223