JP4896520B2 - 硫化リチウムの精製方法 - Google Patents

硫化リチウムの精製方法 Download PDF

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Publication number
JP4896520B2
JP4896520B2 JP2005514938A JP2005514938A JP4896520B2 JP 4896520 B2 JP4896520 B2 JP 4896520B2 JP 2005514938 A JP2005514938 A JP 2005514938A JP 2005514938 A JP2005514938 A JP 2005514938A JP 4896520 B2 JP4896520 B2 JP 4896520B2
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Prior art keywords
lithium
lithium sulfide
sulfide
organic solvent
temperature
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Expired - Fee Related
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JP2005514938A
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Japanese (ja)
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JPWO2005040039A1 (ja
Inventor
美勝 清野
実 千賀
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Idemitsu Kosan Co Ltd
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Idemitsu Kosan Co Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/36—Purification
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2005514938A 2003-10-23 2004-10-15 硫化リチウムの精製方法 Expired - Fee Related JP4896520B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005514938A JP4896520B2 (ja) 2003-10-23 2004-10-15 硫化リチウムの精製方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2003363403 2003-10-23
JP2003363403 2003-10-23
JP2005514938A JP4896520B2 (ja) 2003-10-23 2004-10-15 硫化リチウムの精製方法
PCT/JP2004/015231 WO2005040039A1 (ja) 2003-10-23 2004-10-15 硫化リチウムの精製方法

Publications (2)

Publication Number Publication Date
JPWO2005040039A1 JPWO2005040039A1 (ja) 2007-03-01
JP4896520B2 true JP4896520B2 (ja) 2012-03-14

Family

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Family Applications (1)

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JP2005514938A Expired - Fee Related JP4896520B2 (ja) 2003-10-23 2004-10-15 硫化リチウムの精製方法

Country Status (8)

Country Link
US (1) US8084160B2 (cg-RX-API-DMAC7.html)
EP (1) EP1681263B1 (cg-RX-API-DMAC7.html)
JP (1) JP4896520B2 (cg-RX-API-DMAC7.html)
KR (1) KR101109821B1 (cg-RX-API-DMAC7.html)
CN (2) CN101980398A (cg-RX-API-DMAC7.html)
AT (1) ATE513788T1 (cg-RX-API-DMAC7.html)
TW (1) TW200530121A (cg-RX-API-DMAC7.html)
WO (1) WO2005040039A1 (cg-RX-API-DMAC7.html)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103523806A (zh) * 2013-10-22 2014-01-22 瓮福（集团）有限责任公司 一种高纯度无水硫酸锂的制备方法
WO2024151153A1 (ko) * 2023-01-12 2024-07-18 주식회사 이수스페셜티케미컬 황화 리튬의 제조 방법

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066539A1 (ja) 2005-12-09 2007-06-14 Idemitsu Kosan Co., Ltd. リチウムイオン伝導性硫化物系固体電解質及びそれを用いた全固体リチウム電池
EP2211415B1 (en) 2007-10-11 2013-11-06 Idemitsu Kosan Co., Ltd. Method for producing lithium ion conductive solid electrolyte
WO2010006366A1 (en) 2008-07-18 2010-01-21 Rincon Lithium Limited A process for recovering lithium from a brine
JP2010126422A (ja) * 2008-11-28 2010-06-10 Panasonic Corp リチウム含有複合酸化物の製造方法および非水系二次電池
JP5448038B2 (ja) 2009-02-27 2014-03-19 公立大学法人大阪府立大学 硫化物固体電解質材料
JP5287739B2 (ja) 2009-05-01 2013-09-11 トヨタ自動車株式会社 固体電解質材料
JP5590836B2 (ja) 2009-09-09 2014-09-17 公立大学法人大阪府立大学 硫化物固体電解質
JP5168269B2 (ja) 2009-11-25 2013-03-21 トヨタ自動車株式会社 Ｌｉイオン伝導性材料およびリチウム電池
JP5629198B2 (ja) * 2009-12-04 2014-11-19 出光興産株式会社 アルカリ金属硫化物及びその製造方法
JP5141675B2 (ja) 2009-12-16 2013-02-13 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池
CN103052995B (zh) 2010-08-05 2016-07-13 丰田自动车株式会社 硫化物固体电解质玻璃、锂固体电池和硫化物固体电解质玻璃的制造方法
JP5729940B2 (ja) * 2010-08-13 2015-06-03 出光興産株式会社 固体電解質ガラス及びその製造方法
JP5349427B2 (ja) 2010-08-26 2013-11-20 トヨタ自動車株式会社 硫化物固体電解質材料、正極体およびリチウム固体電池
JP5521899B2 (ja) 2010-08-26 2014-06-18 トヨタ自動車株式会社 硫化物固体電解質材料およびリチウム固体電池
JP5865268B2 (ja) * 2011-01-27 2016-02-17 出光興産株式会社 アルカリ金属硫化物と導電剤の複合材料
JP5708467B2 (ja) 2011-03-18 2015-04-30 トヨタ自動車株式会社 スラリー、固体電解質層の製造方法、電極活物質層の製造方法、および全固体電池の製造方法
JP5708233B2 (ja) 2011-05-18 2015-04-30 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法および硫化物固体電解質材料
CN103813980B (zh) * 2011-05-27 2016-05-18 罗克伍德锂有限责任公司 用于制备硫化锂的方法
DE102012209757A1 (de) * 2011-06-14 2012-12-20 Chemetall Gmbh Verfahren zur Herstellung eines kohlenstoffbeschichteten Lithiumsulfids und dessen Verwendung
JP5443445B2 (ja) 2011-07-06 2014-03-19 トヨタ自動車株式会社 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法
JP5445527B2 (ja) 2011-07-13 2014-03-19 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法
EP2759525B1 (en) 2011-09-22 2017-07-26 Idemitsu Kosan Co., Ltd Glass particles
JP6234665B2 (ja) 2011-11-07 2017-11-22 出光興産株式会社 固体電解質
JP6203474B2 (ja) 2011-11-24 2017-09-27 出光興産株式会社 電極材料、電極及びそれを用いたリチウムイオン電池
JP6243103B2 (ja) 2012-06-29 2017-12-06 出光興産株式会社 正極合材
WO2014073197A1 (ja) 2012-11-06 2014-05-15 出光興産株式会社 固体電解質
FR2997941B1 (fr) * 2012-11-15 2023-03-03 Arkema France Procede de preparation de sulfure de metal alcalin
JP5757284B2 (ja) 2012-12-27 2015-07-29 トヨタ自動車株式会社 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法
JP6259617B2 (ja) 2013-04-24 2018-01-10 出光興産株式会社 固体電解質の製造方法
WO2014192309A1 (ja) 2013-05-31 2014-12-04 出光興産株式会社 固体電解質の製造方法
JP5673760B1 (ja) 2013-09-13 2015-02-18 トヨタ自動車株式会社 硫化物固体電解質の製造方法
WO2016067631A1 (ja) 2014-10-31 2016-05-06 出光興産株式会社 硫化物ガラス及び結晶性固体電解質の製造方法、結晶性固体電解質、硫化物ガラス及び固体電池
JP6697398B2 (ja) 2014-12-16 2020-05-20 出光興産株式会社 硫化リチウム製造用装置及び硫化リチウムの製造方法
CN104609376A (zh) * 2015-01-30 2015-05-13 浙江工业大学 一种硫化锂粉体的制备方法
KR101684130B1 (ko) 2015-06-16 2016-12-07 현대자동차주식회사 리튬 이온 전도성 황화물의 제조방법, 이에 의하여 제조된 리튬 이온 전도성 황화물, 및 이를 포함하는 고체전해질, 전고체 배터리
CN105016310A (zh) * 2015-07-30 2015-11-04 广东先导稀材股份有限公司 一种高纯硫化锂的制备方法及装置
KR101930992B1 (ko) * 2016-02-15 2018-12-19 한양대학교 산학협력단 황화물계 고체 전해질의 제조방법, 이로부터 제조된 황화물계 고체 전해질 및 이를 포함하는 전고체 리튬 이차전지
KR101886036B1 (ko) 2016-08-22 2018-08-07 한국과학기술연구원 대기 안정성이 우수한 황화물계 고체전해질의 제조방법
JP6923173B2 (ja) 2016-12-14 2021-08-18 出光興産株式会社 硫黄含有複合体、その製造方法、及び固体電解質の製造方法
JP7294795B2 (ja) * 2017-11-17 2023-06-20 出光興産株式会社 硫化リチウム粉体、及びその製造方法
CN110790239B (zh) * 2019-08-26 2022-01-28 浙江工业大学 一种硫化锂粉体的机械球磨合成方法
CN112678781B (zh) * 2019-10-18 2022-04-15 天齐锂业（江苏）有限公司 硫化锂的制备方法
CN115135617B (zh) * 2020-02-17 2024-04-23 坚固力量营运公司 制备水反应性的硫化物材料的方法
CN112624060B (zh) * 2020-12-31 2022-09-20 江西赣锋锂业股份有限公司 一种利用工业级丁基锂制备高纯硫化锂的方法
JP7120424B1 (ja) * 2021-09-30 2022-08-17 Ａｇｃ株式会社 硫化水素の精製方法、硫化リチウムの製造方法、硫化水素精製装置および硫化リチウム製造装置
KR102707192B1 (ko) * 2022-02-28 2024-09-20 주식회사 레이크테크놀로지 황화리튬 제조 장치
JP2025512130A (ja) * 2022-03-31 2025-04-16 ソリヴィス インコーポレイテッド 高純度のアルカリ金属硫化物の製造方法
KR102666522B1 (ko) * 2022-11-10 2024-05-16 전북대학교산학협력단 황화 리튬의 제조방법
DE102023102404A1 (de) 2023-02-01 2024-08-01 Albemarle Germany Gmbh Verfahren zur Herstellung von an Kohlenstoffverunreinigung reduziertem/Kohlenstoffverunreinigung freiem Lithiumsulfid, das Kohlenstoffverunreinigung reduzierte/Kohlenstoffverunreinigung freie Lithiumsulfid sowie dessen Verwendung zur Herstellung von Festelektrolyten und Feststoffbatterien
DE102023114082A1 (de) 2023-05-30 2024-12-05 Albemarle Germany Gmbh Verfahren zur Herstellung von an Kohlenstoffverunreinigung reduziertem/Kohlenstoffverunreinigung freiem Lithiumsulfid, das an Kohlenstoffverunreinigung reduzierte/Kohlenstoffverunreinigung freie Lithiumsulfid sowie dessen Verwendung zur Synthese von Festkörperelektrolyten und Herstellung von Feststoffbatterien
CN117163922B (zh) 2023-09-20 2024-03-26 天齐锂业股份有限公司 Ev级硫化锂及其制备方法
KR20250094410A (ko) * 2023-12-18 2025-06-25 포스코홀딩스 주식회사 리튬 폴리설파이드를 이용한 황화 리튬의 제조 방법

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JPH09278423A (ja) * 1996-04-16 1997-10-28 Furukawa Co Ltd 硫化リチウムの製造方法
JPH09283156A (ja) * 1996-04-16 1997-10-31 Matsushita Electric Ind Co Ltd リチウムイオン伝導性固体電解質およびその製造方法
JPH09301706A (ja) * 1996-05-10 1997-11-25 Matsushita Electric Ind Co Ltd 固体電解質およびそれを用いた全固体リチウム電池
JPH10130005A (ja) * 1996-10-28 1998-05-19 Idemitsu Petrochem Co Ltd 硫化リチウムの製造方法及びポリアリーレンスルフィドの製造方法
JP2003068361A (ja) * 2001-08-23 2003-03-07 Japan Storage Battery Co Ltd 全固体リチウム二次電池

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JPH09283156A (ja) * 1996-04-16 1997-10-31 Matsushita Electric Ind Co Ltd リチウムイオン伝導性固体電解質およびその製造方法
JPH09301706A (ja) * 1996-05-10 1997-11-25 Matsushita Electric Ind Co Ltd 固体電解質およびそれを用いた全固体リチウム電池
JPH10130005A (ja) * 1996-10-28 1998-05-19 Idemitsu Petrochem Co Ltd 硫化リチウムの製造方法及びポリアリーレンスルフィドの製造方法
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103523806A (zh) * 2013-10-22 2014-01-22 瓮福（集团）有限责任公司 一种高纯度无水硫酸锂的制备方法
CN103523806B (zh) * 2013-10-22 2014-11-12 瓮福（集团）有限责任公司 一种高纯度无水硫酸锂的制备方法
WO2024151153A1 (ko) * 2023-01-12 2024-07-18 주식회사 이수스페셜티케미컬 황화 리튬의 제조 방법

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US20070196739A1 (en) 2007-08-23
US8084160B2 (en) 2011-12-27
EP1681263B1 (en) 2011-06-22
EP1681263A1 (en) 2006-07-19
EP1681263A4 (en) 2008-06-25
TWI366554B (cg-RX-API-DMAC7.html) 2012-06-21
CN1871177A (zh) 2006-11-29
KR101109821B1 (ko) 2012-03-13
KR20060076316A (ko) 2006-07-04
TW200530121A (en) 2005-09-16
JPWO2005040039A1 (ja) 2007-03-01
WO2005040039A1 (ja) 2005-05-06
CN101980398A (zh) 2011-02-23
ATE513788T1 (de) 2011-07-15
EP1681263A8 (en) 2006-10-11
CN1871177B (zh) 2010-12-22

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