KR101668974B1 - 활물질 입자 및 그 이용 - Google Patents
활물질 입자 및 그 이용 Download PDFInfo
- Publication number
- KR101668974B1 KR101668974B1 KR1020157020743A KR20157020743A KR101668974B1 KR 101668974 B1 KR101668974 B1 KR 101668974B1 KR 1020157020743 A KR1020157020743 A KR 1020157020743A KR 20157020743 A KR20157020743 A KR 20157020743A KR 101668974 B1 KR101668974 B1 KR 101668974B1
- Authority
- KR
- South Korea
- Prior art keywords
- active material
- particles
- lithium
- material particles
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
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- B60L11/18—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L50/00—Electric propulsion with power supplied within the vehicle
- B60L50/50—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y02E60/122—
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Power Engineering (AREA)
- Transportation (AREA)
- Mechanical Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009274381A JP5175826B2 (ja) | 2009-12-02 | 2009-12-02 | 活物質粒子およびその利用 |
| JPJP-P-2009-274381 | 2009-12-02 | ||
| PCT/JP2010/067691 WO2011067982A1 (ja) | 2009-12-02 | 2010-10-07 | 活物質粒子およびその利用 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127017038A Division KR101563775B1 (ko) | 2009-12-02 | 2010-10-07 | 활물질 입자 및 그 이용 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150093252A KR20150093252A (ko) | 2015-08-17 |
| KR101668974B1 true KR101668974B1 (ko) | 2016-10-24 |
Family
ID=44114841
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127017038A Active KR101563775B1 (ko) | 2009-12-02 | 2010-10-07 | 활물질 입자 및 그 이용 |
| KR1020157020743A Active KR101668974B1 (ko) | 2009-12-02 | 2010-10-07 | 활물질 입자 및 그 이용 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127017038A Active KR101563775B1 (ko) | 2009-12-02 | 2010-10-07 | 활물질 입자 및 그 이용 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US20120282525A1 (enExample) |
| EP (2) | EP2509142B1 (enExample) |
| JP (1) | JP5175826B2 (enExample) |
| KR (2) | KR101563775B1 (enExample) |
| CN (1) | CN102612772B (enExample) |
| CA (1) | CA2781658C (enExample) |
| WO (1) | WO2011067982A1 (enExample) |
Families Citing this family (95)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5464348B2 (ja) * | 2010-02-26 | 2014-04-09 | 住友金属鉱山株式会社 | 非水系電解質二次電池正極活物質用ニッケル−コバルト複合水酸化物およびその製造方法、ならびに該ニッケル−コバルト複合水酸化物を用いた非水系電解質二次電池正極活物質の製造方法 |
| JP5141791B2 (ja) | 2010-08-30 | 2013-02-13 | 株式会社デンソー | 温度センサ |
| KR101500250B1 (ko) * | 2010-10-15 | 2015-03-06 | 도요타지도샤가부시키가이샤 | 이차 전지 |
| WO2012049777A1 (ja) | 2010-10-15 | 2012-04-19 | トヨタ自動車株式会社 | 二次電池 |
| CA2817494C (en) | 2010-11-12 | 2016-01-12 | Toyota Jidosha Kabushiki Kaisha | Secondary battery |
| WO2012063369A1 (ja) | 2010-11-12 | 2012-05-18 | トヨタ自動車株式会社 | 二次電池 |
| JP5354480B2 (ja) * | 2010-12-09 | 2013-11-27 | 横河電機株式会社 | 燃料電池評価装置 |
| WO2012117557A1 (ja) * | 2011-03-03 | 2012-09-07 | トヨタ自動車株式会社 | 非水電解液二次電池 |
| JP5551195B2 (ja) * | 2011-03-16 | 2014-07-16 | 日本化学工業株式会社 | リチウムニッケルマンガンコバルト複合酸化物の製造方法 |
| JP5650247B2 (ja) * | 2011-05-06 | 2015-01-07 | トヨタ自動車株式会社 | リチウムイオン二次電池 |
| WO2012164752A1 (ja) * | 2011-05-30 | 2012-12-06 | 住友金属鉱山株式会社 | 非水系二次電池用正極活物質とその製造方法、ならびに該正極活物質を用いた非水系電解質二次電池 |
| KR101584880B1 (ko) * | 2011-05-31 | 2016-01-13 | 도요타지도샤가부시키가이샤 | 리튬 이차 전지 |
| JP5316726B2 (ja) * | 2011-06-07 | 2013-10-16 | 住友金属鉱山株式会社 | ニッケル複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および、非水系電解質二次電池 |
| GB2492167C (en) | 2011-06-24 | 2018-12-05 | Nexeon Ltd | Structured particles |
| JP5651547B2 (ja) * | 2011-06-29 | 2015-01-14 | 日立オートモティブシステムズ株式会社 | リチウムイオン二次電池 |
| JP5839221B2 (ja) * | 2011-08-26 | 2016-01-06 | トヨタ自動車株式会社 | リチウム二次電池 |
| JP6011838B2 (ja) * | 2011-08-31 | 2016-10-19 | トヨタ自動車株式会社 | リチウム二次電池 |
| JP5725358B2 (ja) * | 2011-09-15 | 2015-05-27 | トヨタ自動車株式会社 | リチウム二次電池 |
| JP5920872B2 (ja) * | 2011-11-25 | 2016-05-18 | 株式会社田中化学研究所 | リチウム金属複合酸化物及びその製造方法 |
| JP5858279B2 (ja) | 2011-12-05 | 2016-02-10 | トヨタ自動車株式会社 | リチウムイオン二次電池 |
| JP5971109B2 (ja) * | 2011-12-20 | 2016-08-17 | 住友金属鉱山株式会社 | ニッケル複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| JP5709010B2 (ja) * | 2011-12-20 | 2015-04-30 | トヨタ自動車株式会社 | 非水電解液二次電池 |
| JP5641362B2 (ja) * | 2011-12-26 | 2014-12-17 | トヨタ自動車株式会社 | 正極活物質の製造方法 |
| JP5682796B2 (ja) * | 2012-01-12 | 2015-03-11 | トヨタ自動車株式会社 | リチウム二次電池 |
| WO2013114095A1 (en) | 2012-01-30 | 2013-08-08 | Nexeon Limited | Composition of si/c electro active material |
| GB2499984B (en) | 2012-02-28 | 2014-08-06 | Nexeon Ltd | Composite particles comprising a removable filler |
| KR101361118B1 (ko) * | 2012-03-08 | 2014-02-13 | 주식회사 라미나 | 기-액 반응기를 이용한 리튬이차전지용 양극 활물질 제조 방법 |
| DE112012006167B4 (de) | 2012-03-30 | 2024-03-28 | Toyota Jidosha Kabushiki Kaisha | Lithium-Ionen-Sekundärbatterie |
| JP6055967B2 (ja) * | 2012-05-10 | 2017-01-11 | 株式会社田中化学研究所 | 正極活物質及びその製造方法、正極活物質前駆体、リチウム二次電池用正極、並びにリチウム二次電池 |
| GB2502625B (en) | 2012-06-06 | 2015-07-29 | Nexeon Ltd | Method of forming silicon |
| JP5630593B2 (ja) | 2012-06-06 | 2014-11-26 | 住友金属鉱山株式会社 | ニッケル複合水酸化物、非水系電解質二次電池用正極活物質、非水系電解質二次電池、およびこれらの製造方法 |
| JP5664930B2 (ja) | 2012-06-29 | 2015-02-04 | トヨタ自動車株式会社 | 非水電解質二次電池 |
| JP5630669B2 (ja) | 2012-06-29 | 2014-11-26 | トヨタ自動車株式会社 | リチウム二次電池 |
| WO2014061399A1 (ja) * | 2012-10-15 | 2014-04-24 | 日本碍子株式会社 | リチウム二次電池用正極活物質及びそれを用いた正極 |
| JP5664932B2 (ja) | 2012-10-17 | 2015-02-04 | トヨタ自動車株式会社 | 二次電池 |
| GB2507535B (en) | 2012-11-02 | 2015-07-15 | Nexeon Ltd | Multilayer electrode |
| WO2014077231A1 (ja) * | 2012-11-13 | 2014-05-22 | 戸田工業株式会社 | 非水電解質二次電池用マンガン酸リチウム粒子粉末及びその製造方法、並びに非水電解質二次電池 |
| JP6361955B2 (ja) * | 2013-01-11 | 2018-07-25 | 株式会社Gsユアサ | 蓄電素子及びその製造方法 |
| JP6369739B2 (ja) * | 2013-01-11 | 2018-08-08 | 株式会社Gsユアサ | 蓄電素子及びその製造方法 |
| JP5847352B2 (ja) * | 2013-03-04 | 2016-01-20 | 三井金属鉱業株式会社 | リチウム金属複合酸化物粉体 |
| CN105122514B (zh) * | 2013-03-26 | 2017-12-19 | 三洋电机株式会社 | 非水电解质二次电池用正极活性物质及使用其的非水电解质二次电池 |
| JP6159395B2 (ja) | 2013-05-10 | 2017-07-05 | 住友金属鉱山株式会社 | 遷移金属複合水酸化物粒子とその製造方法、非水電解質二次電池用正極活物質とその製造方法および非水電解質二次電池 |
| CN105264708A (zh) * | 2013-06-05 | 2016-01-20 | 丰田自动车株式会社 | 锂离子二次电池 |
| JP6186919B2 (ja) | 2013-06-17 | 2017-08-30 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6044463B2 (ja) * | 2013-06-19 | 2016-12-14 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| US10629903B2 (en) * | 2013-07-31 | 2020-04-21 | Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) | Method for preparing transition metal composite oxide, transition metal composite oxide prepared thereby, and lithium composite oxide prepared using same |
| GB2516895C (en) * | 2013-08-05 | 2019-05-15 | Nexeon Ltd | Structured particles |
| JP6467352B2 (ja) * | 2014-01-20 | 2019-02-13 | 住友化学株式会社 | 正極活物質およびその製造方法 |
| JP6167943B2 (ja) * | 2014-03-07 | 2017-07-26 | トヨタ自動車株式会社 | 非水電解質二次電池 |
| KR101567203B1 (ko) | 2014-04-09 | 2015-11-09 | (주)오렌지파워 | 이차 전지용 음극 활물질 및 이의 방법 |
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| CA2781658A1 (en) | 2011-06-09 |
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| EP2533329A2 (en) | 2012-12-12 |
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| EP2509142B1 (en) | 2015-12-16 |
| US20130011331A1 (en) | 2013-01-10 |
| CN102612772B (zh) | 2015-05-06 |
| CA2781658C (en) | 2015-02-17 |
| EP2509142A1 (en) | 2012-10-10 |
| US20130302687A1 (en) | 2013-11-14 |
| KR20150093252A (ko) | 2015-08-17 |
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