JP5508011B2 - Aba型トリブロック共重合体及びその製造方法 - Google Patents
Aba型トリブロック共重合体及びその製造方法 Download PDFInfo
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- JP5508011B2 JP5508011B2 JP2009522569A JP2009522569A JP5508011B2 JP 5508011 B2 JP5508011 B2 JP 5508011B2 JP 2009522569 A JP2009522569 A JP 2009522569A JP 2009522569 A JP2009522569 A JP 2009522569A JP 5508011 B2 JP5508011 B2 JP 5508011B2
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- vinyl ether
- carbon atoms
- general formula
- producing
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- 229920000428 triblock copolymer Polymers 0.000 title claims description 36
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 229920000642 polymer Polymers 0.000 claims description 56
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical group C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 47
- 239000000178 monomer Substances 0.000 claims description 45
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- -1 organometallic halide Chemical class 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 239000002841 Lewis acid Substances 0.000 claims description 21
- 150000007517 lewis acids Chemical class 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 239000003999 initiator Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- 238000010552 living cationic polymerization reaction Methods 0.000 claims description 11
- 230000001588 bifunctional effect Effects 0.000 claims description 10
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 238000005227 gel permeation chromatography Methods 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 229920001400 block copolymer Polymers 0.000 claims description 7
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 6
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910001507 metal halide Inorganic materials 0.000 claims description 4
- 150000005309 metal halides Chemical class 0.000 claims description 4
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 3
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 claims description 3
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
- 238000006243 chemical reaction Methods 0.000 description 44
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 40
- 229960000834 vinyl ether Drugs 0.000 description 35
- 229920001289 polyvinyl ether Polymers 0.000 description 20
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 239000011521 glass Substances 0.000 description 13
- FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
- JAMNSIXSLVPNLC-UHFFFAOYSA-N (4-ethenylphenyl) acetate Chemical compound CC(=O)OC1=CC=C(C=C)C=C1 JAMNSIXSLVPNLC-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- GRFNSWBVXHLTCI-UHFFFAOYSA-N 1-ethenyl-4-[(2-methylpropan-2-yl)oxy]benzene Chemical compound CC(C)(C)OC1=CC=C(C=C)C=C1 GRFNSWBVXHLTCI-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- JESXATFQYMPTNL-UHFFFAOYSA-N mono-hydroxyphenyl-ethylene Natural products OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- BCXWHEQGVHPGSH-UHFFFAOYSA-N 1-[4-(1-acetyloxyethoxy)butoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCOC(C)OC(C)=O BCXWHEQGVHPGSH-UHFFFAOYSA-N 0.000 description 7
- XLLXMBCBJGATSP-UHFFFAOYSA-N 2-phenylethenol Chemical compound OC=CC1=CC=CC=C1 XLLXMBCBJGATSP-UHFFFAOYSA-N 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000004817 gas chromatography Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- JAGRUUPXPPLSRX-UHFFFAOYSA-N 4-prop-1-en-2-ylphenol Chemical compound CC(=C)C1=CC=C(O)C=C1 JAGRUUPXPPLSRX-UHFFFAOYSA-N 0.000 description 5
- 101001074954 Homo sapiens Phosphatidylinositol 4,5-bisphosphate 5-phosphatase A Proteins 0.000 description 5
- 102100035985 Phosphatidylinositol 4,5-bisphosphate 5-phosphatase A Human genes 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
- 239000012300 argon atmosphere Substances 0.000 description 5
- 239000000706 filtrate Substances 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- PGYJSURPYAAOMM-UHFFFAOYSA-N 2-ethenoxy-2-methylpropane Chemical compound CC(C)(C)OC=C PGYJSURPYAAOMM-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 3
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 3
- PIUJWWBOMGMSAY-UHFFFAOYSA-N 2-ethenoxybutane Chemical compound CCC(C)OC=C PIUJWWBOMGMSAY-UHFFFAOYSA-N 0.000 description 3
- GNUGVECARVKIPH-UHFFFAOYSA-N 2-ethenoxypropane Chemical compound CC(C)OC=C GNUGVECARVKIPH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 125000003396 thiol group Chemical class [H]S* 0.000 description 3
- OWTJYMHZFCHOBI-UHFFFAOYSA-N (3-ethenylphenyl) acetate Chemical compound CC(=O)OC1=CC=CC(C=C)=C1 OWTJYMHZFCHOBI-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- ANGXXAFSDFORIA-UHFFFAOYSA-N 1-[4-(1-acetyloxyethoxy)cyclohexyl]oxyethyl acetate Chemical compound CC(=O)OC(C)OC1CCC(OC(C)OC(C)=O)CC1 ANGXXAFSDFORIA-UHFFFAOYSA-N 0.000 description 2
- UVMBRRGVNABPCP-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2,2-pentafluoroethane Chemical compound FC(F)(F)C(F)(F)OC=C UVMBRRGVNABPCP-UHFFFAOYSA-N 0.000 description 2
- HWCLMKDWXUGDKL-UHFFFAOYSA-N 1-ethenoxy-2-ethoxyethane Chemical compound CCOCCOC=C HWCLMKDWXUGDKL-UHFFFAOYSA-N 0.000 description 2
- GXZPMXGRNUXGHN-UHFFFAOYSA-N 1-ethenoxy-2-methoxyethane Chemical compound COCCOC=C GXZPMXGRNUXGHN-UHFFFAOYSA-N 0.000 description 2
- QIUCYKBVFAPWRR-UHFFFAOYSA-N 1-ethenoxy-3-methylbutane Chemical compound CC(C)CCOC=C QIUCYKBVFAPWRR-UHFFFAOYSA-N 0.000 description 2
- LTGJSMARDKHZOY-UHFFFAOYSA-N 1-ethenyl-3-[(2-methylpropan-2-yl)oxy]benzene Chemical compound CC(C)(C)OC1=CC=CC(C=C)=C1 LTGJSMARDKHZOY-UHFFFAOYSA-N 0.000 description 2
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- YNGIFMKMDRDNBQ-UHFFFAOYSA-N 3-ethenylphenol Chemical compound OC1=CC=CC(C=C)=C1 YNGIFMKMDRDNBQ-UHFFFAOYSA-N 0.000 description 2
- REWLXMVGEZMKSG-UHFFFAOYSA-N 3-prop-1-en-2-ylphenol Chemical compound CC(=C)C1=CC=CC(O)=C1 REWLXMVGEZMKSG-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000010511 deprotection reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- NDMXSCGMYOVVJE-UHFFFAOYSA-N ethoxymethyl acetate Chemical compound CCOCOC(C)=O NDMXSCGMYOVVJE-UHFFFAOYSA-N 0.000 description 2
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 2
- DLEGDLSLRSOURQ-UHFFFAOYSA-N fluroxene Chemical compound FC(F)(F)COC=C DLEGDLSLRSOURQ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- KJIFKLIQANRMOU-UHFFFAOYSA-N oxidanium;4-methylbenzenesulfonate Chemical compound O.CC1=CC=C(S(O)(=O)=O)C=C1 KJIFKLIQANRMOU-UHFFFAOYSA-N 0.000 description 2
- 125000006239 protecting group Chemical group 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- FPDZOFFZSWSOSL-UHFFFAOYSA-N trifluoromethoxyethene Chemical compound FC(F)(F)OC=C FPDZOFFZSWSOSL-UHFFFAOYSA-N 0.000 description 2
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- FPWPIVJXMURJKK-UHFFFAOYSA-N (3-ethenylphenoxy)-trimethylsilane Chemical compound C[Si](C)(C)OC1=CC=CC(C=C)=C1 FPWPIVJXMURJKK-UHFFFAOYSA-N 0.000 description 1
- QBKXNEUPNQWVFZ-UHFFFAOYSA-N (3-ethenylphenyl) 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC1=CC=CC(C=C)=C1 QBKXNEUPNQWVFZ-UHFFFAOYSA-N 0.000 description 1
- SOSNAIPTFXTNRU-UHFFFAOYSA-N (4-ethenylphenoxy)-trimethylsilane Chemical compound C[Si](C)(C)OC1=CC=C(C=C)C=C1 SOSNAIPTFXTNRU-UHFFFAOYSA-N 0.000 description 1
- ZRVLZJPJKUNCAC-UHFFFAOYSA-N (4-ethenylphenyl) 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC1=CC=C(C=C)C=C1 ZRVLZJPJKUNCAC-UHFFFAOYSA-N 0.000 description 1
- VHWMDPDYPIZKQS-UHFFFAOYSA-N (4-ethenylphenyl) methyl carbonate Chemical compound COC(=O)OC1=CC=C(C=C)C=C1 VHWMDPDYPIZKQS-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- MWZJGRDWJVHRDV-UHFFFAOYSA-N 1,4-bis(ethenoxy)butane Chemical compound C=COCCCCOC=C MWZJGRDWJVHRDV-UHFFFAOYSA-N 0.000 description 1
- CGHMMUAOPPRRMX-UHFFFAOYSA-N 1,4-bis(ethenoxy)cyclohexane Chemical compound C=COC1CCC(OC=C)CC1 CGHMMUAOPPRRMX-UHFFFAOYSA-N 0.000 description 1
- FVAPICVVXSIXDX-UHFFFAOYSA-N 1-(1-acetyloxyethoxymethoxy)ethyl acetate Chemical compound CC(=O)OC(C)OCOC(C)OC(C)=O FVAPICVVXSIXDX-UHFFFAOYSA-N 0.000 description 1
- BBMXNOISXHLMAT-UHFFFAOYSA-N 1-(ethenoxymethyl)-4-fluorobenzene Chemical compound FC1=CC=C(COC=C)C=C1 BBMXNOISXHLMAT-UHFFFAOYSA-N 0.000 description 1
- YFXKNGYUMOSNNY-UHFFFAOYSA-N 1-[10-(1-acetyloxyethoxy)decoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCCCCCCOC(C)OC(C)=O YFXKNGYUMOSNNY-UHFFFAOYSA-N 0.000 description 1
- QDYVJBZWCSCQNP-UHFFFAOYSA-N 1-[2-(1-acetyloxyethoxy)ethoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCOC(C)OC(C)=O QDYVJBZWCSCQNP-UHFFFAOYSA-N 0.000 description 1
- PUOMGNFPFMJHDY-UHFFFAOYSA-N 1-[3-(1-acetyloxyethoxy)propoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCOC(C)OC(C)=O PUOMGNFPFMJHDY-UHFFFAOYSA-N 0.000 description 1
- FLEPXCIQSDIFSP-UHFFFAOYSA-N 1-[5-(1-acetyloxyethoxy)pentoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCOC(C)OC(C)=O FLEPXCIQSDIFSP-UHFFFAOYSA-N 0.000 description 1
- QJQGSWDIJBJZDE-UHFFFAOYSA-N 1-[6-(1-acetyloxyethoxy)hexoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCCOC(C)OC(C)=O QJQGSWDIJBJZDE-UHFFFAOYSA-N 0.000 description 1
- UVWUTKXVORKWHB-UHFFFAOYSA-N 1-[7-(1-acetyloxyethoxy)heptoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCCCOC(C)OC(C)=O UVWUTKXVORKWHB-UHFFFAOYSA-N 0.000 description 1
- BRXKATXFXNGIDP-UHFFFAOYSA-N 1-[8-(1-acetyloxyethoxy)octoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCCCCOC(C)OC(C)=O BRXKATXFXNGIDP-UHFFFAOYSA-N 0.000 description 1
- WZYYKUPZXMPQGO-UHFFFAOYSA-N 1-[9-(1-acetyloxyethoxy)nonoxy]ethyl acetate Chemical compound CC(=O)OC(C)OCCCCCCCCCOC(C)OC(C)=O WZYYKUPZXMPQGO-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ZZAYVPYTPKHWOI-UHFFFAOYSA-N 1-ethenoxy-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(OC=C)C=C1 ZZAYVPYTPKHWOI-UHFFFAOYSA-N 0.000 description 1
- YXHRYLHTQVXZIK-UHFFFAOYSA-N 1-ethenoxy-4-methylbenzene Chemical compound CC1=CC=C(OC=C)C=C1 YXHRYLHTQVXZIK-UHFFFAOYSA-N 0.000 description 1
- MFKVIGSGQLMCIG-UHFFFAOYSA-N 1-ethenoxyadamantane Chemical compound C1C(C2)CC3CC2CC1(OC=C)C3 MFKVIGSGQLMCIG-UHFFFAOYSA-N 0.000 description 1
- IOSXLUZXMXORMX-UHFFFAOYSA-N 1-ethenoxypentane Chemical compound CCCCCOC=C IOSXLUZXMXORMX-UHFFFAOYSA-N 0.000 description 1
- BNKQWLUYZRSVOT-UHFFFAOYSA-N 1-ethenyl-3-(2-methylpropoxy)benzene Chemical compound CC(C)COC1=CC=CC(C=C)=C1 BNKQWLUYZRSVOT-UHFFFAOYSA-N 0.000 description 1
- LXOOIXRLEJSMKX-UHFFFAOYSA-N 1-ethenyl-3-ethoxybenzene Chemical compound CCOC1=CC=CC(C=C)=C1 LXOOIXRLEJSMKX-UHFFFAOYSA-N 0.000 description 1
- PECUPOXPPBBFLU-UHFFFAOYSA-N 1-ethenyl-3-methoxybenzene Chemical compound COC1=CC=CC(C=C)=C1 PECUPOXPPBBFLU-UHFFFAOYSA-N 0.000 description 1
- ZGHPIGRKLZFMBM-UHFFFAOYSA-N 1-ethenyl-3-propan-2-yloxybenzene Chemical compound CC(C)OC1=CC=CC(C=C)=C1 ZGHPIGRKLZFMBM-UHFFFAOYSA-N 0.000 description 1
- OFCRXVIOIFVHFG-UHFFFAOYSA-N 1-ethenyl-3-propoxybenzene Chemical compound CCCOC1=CC=CC(C=C)=C1 OFCRXVIOIFVHFG-UHFFFAOYSA-N 0.000 description 1
- DTNCNFLLRLHPNJ-UHFFFAOYSA-N 1-ethenyl-4-(1-ethoxyethoxy)benzene Chemical compound CCOC(C)OC1=CC=C(C=C)C=C1 DTNCNFLLRLHPNJ-UHFFFAOYSA-N 0.000 description 1
- SOXFPOYICGTMQC-UHFFFAOYSA-N 1-ethenyl-4-(2-methylpropoxy)benzene Chemical compound CC(C)COC1=CC=C(C=C)C=C1 SOXFPOYICGTMQC-UHFFFAOYSA-N 0.000 description 1
- CQUFSHRIMFCUBU-UHFFFAOYSA-N 1-ethenyl-4-(methoxymethoxy)benzene Chemical compound COCOC1=CC=C(C=C)C=C1 CQUFSHRIMFCUBU-UHFFFAOYSA-N 0.000 description 1
- OBRYRJYZWVLVLF-UHFFFAOYSA-N 1-ethenyl-4-ethoxybenzene Chemical compound CCOC1=CC=C(C=C)C=C1 OBRYRJYZWVLVLF-UHFFFAOYSA-N 0.000 description 1
- MEPWMZKEADGNEO-UHFFFAOYSA-N 1-ethenyl-4-propan-2-yloxybenzene Chemical compound CC(C)OC1=CC=C(C=C)C=C1 MEPWMZKEADGNEO-UHFFFAOYSA-N 0.000 description 1
- HYKOKFYURVJHKT-UHFFFAOYSA-N 1-ethenyl-4-propoxybenzene Chemical compound CCCOC1=CC=C(C=C)C=C1 HYKOKFYURVJHKT-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- WYKIFXZJDSEYBT-UHFFFAOYSA-N 10-(acetyloxymethoxy)decoxymethyl acetate Chemical compound CC(=O)OCOCCCCCCCCCCOCOC(C)=O WYKIFXZJDSEYBT-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- XIUHYXJWUMGXQC-UHFFFAOYSA-N 2-(3-ethenylphenoxy)oxane Chemical compound C=CC1=CC=CC(OC2OCCCC2)=C1 XIUHYXJWUMGXQC-UHFFFAOYSA-N 0.000 description 1
- OODGPKJPJBOZQL-UHFFFAOYSA-N 2-(4-ethenylphenoxy)oxane Chemical compound C1=CC(C=C)=CC=C1OC1OCCCC1 OODGPKJPJBOZQL-UHFFFAOYSA-N 0.000 description 1
- WYRCYTITXIBSDT-UHFFFAOYSA-N 2-(acetyloxymethoxy)butoxymethyl acetate Chemical compound CC(=O)OCOC(CC)COCOC(C)=O WYRCYTITXIBSDT-UHFFFAOYSA-N 0.000 description 1
- JCWJORVNWIULDI-UHFFFAOYSA-N 2-(acetyloxymethoxy)ethoxymethyl acetate Chemical compound CC(=O)OCOCCOCOC(C)=O JCWJORVNWIULDI-UHFFFAOYSA-N 0.000 description 1
- PYACMYDBPJYXIP-UHFFFAOYSA-N 2-(acetyloxymethoxy)pentoxymethyl acetate Chemical compound CC(=O)OCOC(CCC)COCOC(C)=O PYACMYDBPJYXIP-UHFFFAOYSA-N 0.000 description 1
- HXLLCROMVONRRO-UHFFFAOYSA-N 2-butoxyethenylbenzene Chemical compound CCCCOC=CC1=CC=CC=C1 HXLLCROMVONRRO-UHFFFAOYSA-N 0.000 description 1
- KJHFNHVFNLOTEH-UHFFFAOYSA-N 2-ethenoxyadamantane Chemical compound C1C(C2)CC3CC1C(OC=C)C2C3 KJHFNHVFNLOTEH-UHFFFAOYSA-N 0.000 description 1
- BYUNYALHUMSCSA-UHFFFAOYSA-N 2-ethenoxyoxane Chemical compound C=COC1CCCCO1 BYUNYALHUMSCSA-UHFFFAOYSA-N 0.000 description 1
- ZNYVTSYLHMCSSI-UHFFFAOYSA-N 2-ethenoxyoxolane Chemical compound C=COC1CCCO1 ZNYVTSYLHMCSSI-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- WHGXZPQWZJUGEP-UHFFFAOYSA-N 2-prop-1-enylphenol Chemical compound CC=CC1=CC=CC=C1O WHGXZPQWZJUGEP-UHFFFAOYSA-N 0.000 description 1
- CPTYTQXGQZYPBY-UHFFFAOYSA-N 3-(acetyloxymethoxy)propoxymethyl acetate Chemical compound CC(=O)OCOCCCOCOC(C)=O CPTYTQXGQZYPBY-UHFFFAOYSA-N 0.000 description 1
- QNBBNFVOYOKALV-UHFFFAOYSA-N 3-ethenoxybicyclo[2.2.1]heptane Chemical compound C1CC2C(OC=C)CC1C2 QNBBNFVOYOKALV-UHFFFAOYSA-N 0.000 description 1
- HHLGHULPTMLMBH-UHFFFAOYSA-N 3-ethenoxybicyclo[2.2.2]octane Chemical compound C1CC2C(OC=C)CC1CC2 HHLGHULPTMLMBH-UHFFFAOYSA-N 0.000 description 1
- XBTDDIJACWGUOF-UHFFFAOYSA-N 6-(acetyloxymethoxy)hexoxymethyl acetate Chemical compound CC(=O)OCOCCCCCCOCOC(C)=O XBTDDIJACWGUOF-UHFFFAOYSA-N 0.000 description 1
- PUJFGKWGQLAQCP-UHFFFAOYSA-N 7-(acetyloxymethoxy)heptoxymethyl acetate Chemical compound CC(=O)OCOCCCCCCCOCOC(C)=O PUJFGKWGQLAQCP-UHFFFAOYSA-N 0.000 description 1
- FCQIGFDVSLFDOX-UHFFFAOYSA-N 8-(acetyloxymethoxy)octoxymethyl acetate Chemical compound CC(=O)OCOCCCCCCCCOCOC(C)=O FCQIGFDVSLFDOX-UHFFFAOYSA-N 0.000 description 1
- DOKXMWSJBXIKDU-UHFFFAOYSA-N 9-(acetyloxymethoxy)nonoxymethyl acetate Chemical compound CC(=O)OCOCCCCCCCCCOCOC(C)=O DOKXMWSJBXIKDU-UHFFFAOYSA-N 0.000 description 1
- DJGNBFCOWZEIPU-UHFFFAOYSA-N C(C)(=O)OCOC1CCC(CC1)OCOC(C)=O Chemical compound C(C)(=O)OCOC1CCC(CC1)OCOC(C)=O DJGNBFCOWZEIPU-UHFFFAOYSA-N 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910018287 SbF 5 Inorganic materials 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- FVSBAKKVWXJPRA-UHFFFAOYSA-N acetyloxymethoxymethoxymethyl acetate Chemical compound CC(=O)OCOCOCOC(C)=O FVSBAKKVWXJPRA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- CBHOOMGKXCMKIR-UHFFFAOYSA-N azane;methanol Chemical compound N.OC CBHOOMGKXCMKIR-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- IHYWHVQKHIWVBX-UHFFFAOYSA-N ethenoxycycloheptane Chemical compound C=COC1CCCCCC1 IHYWHVQKHIWVBX-UHFFFAOYSA-N 0.000 description 1
- ORAFCUXGWRDXAC-UHFFFAOYSA-N ethenoxycyclooctane Chemical compound C=COC1CCCCCCC1 ORAFCUXGWRDXAC-UHFFFAOYSA-N 0.000 description 1
- HJVKTYVDOZVQPA-UHFFFAOYSA-N ethenoxycyclopentane Chemical compound C=COC1CCCC1 HJVKTYVDOZVQPA-UHFFFAOYSA-N 0.000 description 1
- AZDCYKCDXXPQIK-UHFFFAOYSA-N ethenoxymethylbenzene Chemical compound C=COCC1=CC=CC=C1 AZDCYKCDXXPQIK-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000004175 fluorobenzyl group Chemical group 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000006253 t-butylcarbonyl group Chemical group [H]C([H])([H])C(C(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- HGPXXOYPYCIJMU-UHFFFAOYSA-N tert-butyl (3-ethenylphenyl) carbonate Chemical compound CC(C)(C)OC(=O)OC1=CC=CC(C=C)=C1 HGPXXOYPYCIJMU-UHFFFAOYSA-N 0.000 description 1
- SODBJIZNBZJRCU-UHFFFAOYSA-N tert-butyl (3-ethenylphenyl)methyl carbonate Chemical compound CC(C)(C)OC(=O)OCC1=CC=CC(C=C)=C1 SODBJIZNBZJRCU-UHFFFAOYSA-N 0.000 description 1
- GJWMYLFHBXEWNZ-UHFFFAOYSA-N tert-butyl (4-ethenylphenyl) carbonate Chemical compound CC(C)(C)OC(=O)OC1=CC=C(C=C)C=C1 GJWMYLFHBXEWNZ-UHFFFAOYSA-N 0.000 description 1
- QVPBMCKCBQURHP-UHFFFAOYSA-N tert-butyl-(4-ethenylphenoxy)-dimethylsilane Chemical compound CC(C)(C)[Si](C)(C)OC1=CC=C(C=C)C=C1 QVPBMCKCBQURHP-UHFFFAOYSA-N 0.000 description 1
- 125000001981 tert-butyldimethylsilyl group Chemical group [H]C([H])([H])[Si]([H])(C([H])([H])[H])[*]C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000005931 tert-butyloxycarbonyl group Chemical group [H]C([H])([H])C(OC(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000006493 trifluoromethyl benzyl group Chemical group 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F16/14—Monomers containing only one unsaturated aliphatic radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
- C08F212/22—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
Description
で表されるオキシスチレン系繰り返し単位(a)を含むセグメントAと、
次の一般式(2)
−(CH2)m−X
(ここで、mは0、1、2または3であり、Xは未置換のフェニル基、或いは、一つ若しくはそれ以上の炭素数1〜4の直鎖若しくは分岐鎖アルキル基、アルキル基の全部若しくは一部の水素がフッ素に置換された炭素数1〜4の直鎖若しくは分岐鎖アルキル基であるフルオロアルキル基、炭素数1〜4のアルコキシ基、またはハロゲン原子によって置換されたフェニル基である)で表されるアリール基またはアリールアルキル基を表す]
で表されるビニルエーテル系繰り返し単位(b)を含むセグメントBとからなり、
セグメントAとセグメントBが単結合により結合していることを特徴とする。
で表されるビニルエーテル系単量体をリビングカチオン重合させ、次いで、次の一般式(4)
で表されるオキシスチレン系単量体を添加し、リビングカチオン重合させることにより製造することができる。
で表される構造を有するものを用いることができる。
平均共重合組成:13C−NMRの測定結果から求めた。
重量平均分子量Mw及び分子量分布Mw/Mn:
ゲルパーミエーションクロマトグラフィー(GPC)法により標準ポリスチレン検量
線から求めた[RI検出器;カラムはShodex社製KF−801+KF−805
L;溶離液はテトラヒドロフラン]。
p−tert−ブトキシスチレン/エチルビニルエーテル/p−tert−ブト
キシスチレン系トリブロックポリマーの製造:
p−ヒドロキシスチレン/エチルビニルエーテル/p−ヒドロキシスチレン系ト
リブロックポリマーの製造(PTBOS/EVE/PTBOS系トリブロックポ
リマーの脱保護:
p−tert−ブトキシスチレン/n−ブチルビニルエーテル/p−tert−
ブトキシスチレン系トリブロックポリマーの合成:
p−ヒドロキシスチレン/n−ブチルビニルエーテル/p−ヒドロキシスチレン
系トリブロックポリマーの製造(PTBOS/NBVE/PTBOS系トリブロ
ックポリマーの脱保護:
p−アセトキシスチレン/エチルビニルエーテル/p−アセトキシスチレン系ト
リブロックポリマーの合成:
p−イソプロペニルフェノール/エチルビニルエーテル/p−イソプロペニルフ
ェノール系トリブロックポリマーの合成:
p−tert−ブトキシスチレン/エチルビニルエーテル/p−tert−ブト
キシスチレン系トリブロックポリマーの合成:
Claims (6)
- 次の一般式(1)
で表されるオキシスチレン系繰り返し単位(a)を含むセグメントAと、
次の一般式(2)
[式中、R3は炭素数1〜6の直鎖または分岐鎖アルキル基、アルキル基の全部若しくは一部の水素がフッ素に置換された炭素数1〜6の直鎖若しくは分岐鎖アルキル基であるフルオロアルキル基、炭素数2〜6のアルコキシアルキル基、炭素数5〜10のシクロアルキル基、または
−(CH2)m−X
(ここで、mは0、1、2または3であり、Xは未置換のフェニル基、或いは、一つ若しくはそれ以上の炭素数1〜4の直鎖若しくは分岐鎖アルキル基、アルキル基の全部若しくは一部の水素がフッ素に置換された炭素数1〜4の直鎖若しくは分岐鎖アルキル基であるフルオロアルキル基、炭素数1〜4のアルコキシ基、またはハロゲン原子によって置換されたフェニル基である)で表されるアリール基またはアリールアルキル基を表す]
で表されるビニルエーテル系繰り返し単位(b)を含むセグメントBとからなり、
セグメントAとセグメントBが単結合により結合しているビニルエーテル系ABA型ブロック共重合体の製造方法であって、
二官能開始剤、ルイス酸及び溶媒の存在下に、次の一般式(3)
[式中、R 3 は前記式(2)における定義と同じである]
で表されるビニルエーテル系単量体をリビングカチオン重合させ、次いで、次の一般式(4)
[式中、R 1 及びR 2 は前記式(1)における定義と同じである]
で表されるオキシスチレン系単量体を添加し、リビングカチオン重合させ、かつ、
前記ルイス酸として2種類のルイス酸を併用し、2種類のルイス酸のうち一方のルイス酸を系中に導入し、同時にまたはその後に他方のルイス酸を系中に導入することを特徴とする前記ビニルエーテル系ABA型ブロック共重合体の製造方法。 - ポリマー鎖に含まれる全繰り返し単位に対する繰り返し単位(a)の割合が5〜80モル%であり、繰り返し単位(b)の割合が20〜95モル%であることを特徴とする請求項1に記載のビニルエーテル系ABA型トリブロック共重合体の製造方法。
- ゲルパーミエーションクロマトグラフィー(GPC)で測定されたポリスチレン換算重量平均分子量(Mw)が1000〜100000の範囲であり、重量平均分子量(Mw)と数平均分子量(Mn)の比で表される分散度(Mw/Mn)が2.0以下であることを特徴とする請求項1または2記載のビニルエーテル系ABA型トリブロック共重合体の製造方法。
- 上記一般式(3)で表されるビニルエーテル系単量体のリビングカチオン重合をルイス酸として有機金属ハロゲン化物の存在下で行い、上記一般式(4)で表されるオキシスチレン系単量体のリビングカチオン重合をルイス酸として金属ハロゲン化物の存在下で行うことを特徴とする請求項1に記載のビニルエーテル系ABA型ブロック共重合体の製造方法。
- 金属ハロゲン化物を分割添加または連続添加することを特徴とする請求項5に記載のビニルエーテル系ABA型ブロック共重合体の製造方法。
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