HU213044B - Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme with additives improving detergent effect - Google Patents
Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme with additives improving detergent effect Download PDFInfo
- Publication number
- HU213044B HU213044B HU9303085A HU9303085A HU213044B HU 213044 B HU213044 B HU 213044B HU 9303085 A HU9303085 A HU 9303085A HU 9303085 A HU9303085 A HU 9303085A HU 213044 B HU213044 B HU 213044B
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- HU
- Hungary
- Prior art keywords
- alkyl
- detergent composition
- liquid detergent
- composition according
- weight
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 113
- 239000007788 liquid Substances 0.000 title claims abstract description 57
- 229920005862 polyol Polymers 0.000 title claims abstract description 50
- 108091005804 Peptidases Proteins 0.000 title claims abstract description 48
- 102000035195 Peptidases Human genes 0.000 title claims abstract description 47
- 239000000654 additive Substances 0.000 title claims description 44
- 230000001236 detergent effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 138
- 150000003077 polyols Chemical group 0.000 claims abstract description 47
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical group OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 43
- 102000004190 Enzymes Human genes 0.000 claims abstract description 39
- 108090000790 Enzymes Proteins 0.000 claims abstract description 39
- 239000004327 boric acid Chemical group 0.000 claims abstract description 36
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 19
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 16
- 125000000129 anionic group Chemical group 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- -1 amino aldehyde Chemical class 0.000 claims description 65
- 125000000217 alkyl group Chemical group 0.000 claims description 62
- 239000004367 Lipase Substances 0.000 claims description 38
- 102000004882 Lipase Human genes 0.000 claims description 38
- 108090001060 Lipase Proteins 0.000 claims description 38
- 229940088598 enzyme Drugs 0.000 claims description 38
- 235000019421 lipase Nutrition 0.000 claims description 38
- 239000004094 surface-active agent Substances 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 29
- 150000001412 amines Chemical class 0.000 claims description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 22
- 230000000996 additive effect Effects 0.000 claims description 22
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 150000004665 fatty acids Chemical class 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 20
- 125000002887 hydroxy group Chemical class [H]O* 0.000 claims description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Chemical class 0.000 claims description 16
- 239000004365 Protease Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 150000002431 hydrogen Chemical class 0.000 claims description 13
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 12
- 125000003107 substituted aryl group Chemical group 0.000 claims description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 10
- 108010059892 Cellulase Proteins 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 10
- 239000007859 condensation product Substances 0.000 claims description 10
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- 150000002148 esters Chemical class 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 9
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- 230000001580 bacterial effect Effects 0.000 claims description 8
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- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 7
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 6
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical class [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 6
- 108010065511 Amylases Proteins 0.000 claims description 5
- 102000013142 Amylases Human genes 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical class [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 4
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004382 Amylase Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 4
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- PWMWNFMRSKOCEY-UHFFFAOYSA-N 1-Phenyl-1,2-ethanediol Chemical compound OCC(O)C1=CC=CC=C1 PWMWNFMRSKOCEY-UHFFFAOYSA-N 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 125000001475 halogen functional group Chemical group 0.000 claims description 3
- 239000000473 propyl gallate Substances 0.000 claims description 3
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- 235000010388 propyl gallate Nutrition 0.000 claims description 3
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 3
- LOSWWGJGSSQDKH-UHFFFAOYSA-N 3-ethoxypropane-1,2-diol Chemical compound CCOCC(O)CO LOSWWGJGSSQDKH-UHFFFAOYSA-N 0.000 claims description 2
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- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 238000010367 cloning Methods 0.000 claims description 2
- 229940074391 gallic acid Drugs 0.000 claims description 2
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- 241000194108 Bacillus licheniformis Species 0.000 claims 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
- 229940061720 alpha hydroxy acid Drugs 0.000 abstract description 12
- 150000001280 alpha hydroxy acids Chemical class 0.000 abstract description 12
- 235000010338 boric acid Nutrition 0.000 description 33
- 150000003839 salts Chemical class 0.000 description 29
- 238000009472 formulation Methods 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 20
- 239000000463 material Substances 0.000 description 17
- 239000011734 sodium Substances 0.000 description 17
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- 229910052708 sodium Inorganic materials 0.000 description 16
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- 238000005406 washing Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 7
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- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 239000008121 dextrose Substances 0.000 description 1
- RUYJNKYXOHIGPH-UHFFFAOYSA-N dialuminum;trioxido(trioxidosilyloxy)silane Chemical compound [Al+3].[Al+3].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] RUYJNKYXOHIGPH-UHFFFAOYSA-N 0.000 description 1
- IKJFYINYNJYDTA-UHFFFAOYSA-N dibenzothiophene sulfone Chemical compound C1=CC=C2S(=O)(=O)C3=CC=CC=C3C2=C1 IKJFYINYNJYDTA-UHFFFAOYSA-N 0.000 description 1
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- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
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- NNCAWEWCFVZOGF-UHFFFAOYSA-N mepiquat Chemical compound C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
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- 125000005341 metaphosphate group Chemical group 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
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- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- QEALYLRSRQDCRA-UHFFFAOYSA-N myristamide Chemical compound CCCCCCCCCCCCCC(N)=O QEALYLRSRQDCRA-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
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- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
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- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
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- 235000019351 sodium silicates Nutrition 0.000 description 1
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- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical group 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical class [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000000954 titration curve Methods 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 108010036927 trypsin-like serine protease Proteins 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Steroid Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69351591A | 1991-04-30 | 1991-04-30 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HU9303085D0 HU9303085D0 (en) | 1994-03-28 |
| HUT67139A HUT67139A (en) | 1995-02-28 |
| HU213044B true HU213044B (en) | 1997-01-28 |
Family
ID=24784989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9303085A HU213044B (en) | 1991-04-30 | 1992-04-24 | Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme with additives improving detergent effect |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US5468414A (enExample) |
| EP (1) | EP0583420B1 (enExample) |
| JP (1) | JP3219765B2 (enExample) |
| CN (1) | CN1034021C (enExample) |
| AT (1) | ATE136055T1 (enExample) |
| AU (1) | AU666660B2 (enExample) |
| BR (1) | BR9205959A (enExample) |
| CA (1) | CA2108908C (enExample) |
| CZ (1) | CZ285148B6 (enExample) |
| DE (1) | DE69209500T2 (enExample) |
| DK (1) | DK0583420T3 (enExample) |
| ES (1) | ES2085024T3 (enExample) |
| GR (1) | GR3019462T3 (enExample) |
| HU (1) | HU213044B (enExample) |
| IE (1) | IE921388A1 (enExample) |
| MX (1) | MX9202070A (enExample) |
| MY (1) | MY109321A (enExample) |
| NZ (1) | NZ242536A (enExample) |
| PH (1) | PH31244A (enExample) |
| PL (1) | PL170474B1 (enExample) |
| PT (1) | PT100445A (enExample) |
| SK (1) | SK120893A3 (enExample) |
| TR (1) | TR28516A (enExample) |
| TW (1) | TW221827B (enExample) |
| WO (1) | WO1992019709A1 (enExample) |
Families Citing this family (487)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU666660B2 (en) * | 1991-04-30 | 1996-02-22 | Procter & Gamble Company, The | Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme |
| ES2076794T3 (es) * | 1991-12-04 | 1995-11-01 | Procter & Gamble | Composiciones detergentes liquidas para lavar la ropa con acido citrico, celulasa, y complejo acido borico-diol para inhibir enzima proteolitica. |
| EP0583536B1 (en) * | 1992-08-14 | 1997-03-05 | The Procter & Gamble Company | Liquid detergents containing an alpha-amino boronic acid |
| US5866525A (en) * | 1993-09-07 | 1999-02-02 | Colgate-Palmolive Company | Laundry detergent compositions containing lipase and soil release polymer |
| DE69434635D1 (en) | 1993-10-08 | 2006-04-27 | Novo Nordisk As | Amylasevarianten |
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| GB8311314D0 (en) * | 1983-04-26 | 1983-06-02 | Unilever Plc | Aqueous enzyme-containing compositions |
| NZ208157A (en) * | 1983-05-31 | 1986-11-12 | Colgate Palmolive Co | Built single-phase liquid detergent compositions containing stabilised enzymes |
| NZ208156A (en) * | 1983-05-31 | 1986-11-12 | Colgate Palmolive Co | Built single-phase liquid detergent compositions containing stabilised enzymes |
| US4537707A (en) * | 1984-05-14 | 1985-08-27 | The Procter & Gamble Company | Liquid detergents containing boric acid and formate to stabilize enzymes |
| US4747977A (en) * | 1984-11-09 | 1988-05-31 | The Procter & Gamble Company | Ethanol-free liquid laundry detergent compositions |
| US4900475A (en) | 1985-07-26 | 1990-02-13 | Colgate-Palmolive Co. | Stabilized built liquid detergent composition containing enzyme |
| US4842758A (en) | 1986-10-31 | 1989-06-27 | Colgate-Palmolive Company | Stabilized enzyme system for use in aqueous liquid built detergent compositions |
| US5039446A (en) * | 1988-07-01 | 1991-08-13 | Genencor International, Inc. | Liquid detergent with stabilized enzyme |
| US4959179A (en) * | 1989-01-30 | 1990-09-25 | Lever Brothers Company | Stabilized enzymes liquid detergent composition containing lipase and protease |
| EP0385526A3 (en) * | 1989-02-27 | 1991-09-11 | Unilever N.V. | Enzymatic liquid detergent composition |
| DE3921839A1 (de) * | 1989-07-03 | 1991-01-17 | Henkel Kgaa | Enzymatischer reiniger |
| HUT62312A (en) * | 1990-03-05 | 1993-04-28 | Cephalon Inc | Process for producing chymotrypsin-like proteases and their inhibitors |
| EP0450702A3 (en) * | 1990-04-06 | 1993-06-02 | Unilever N.V. | Process for preparing liquid enzymatic detergent compositions |
| NZ237570A (en) * | 1990-04-13 | 1993-09-27 | Colgate Palmolive Co | Enzyme stabilising composition and stabilised enzyme-containing built detergent compositions |
| US5221495A (en) * | 1990-04-13 | 1993-06-22 | Colgate-Palmolive Company | Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions |
| DK204290D0 (da) * | 1990-08-24 | 1990-08-24 | Novo Nordisk As | Enzymatisk detergentkomposition og fremgangsmaade til enzymstabilisering |
| AU666660B2 (en) * | 1991-04-30 | 1996-02-22 | Procter & Gamble Company, The | Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme |
-
1992
- 1992-04-24 AU AU22340/92A patent/AU666660B2/en not_active Ceased
- 1992-04-24 DK DK92914376.6T patent/DK0583420T3/da active
- 1992-04-24 WO PCT/US1992/003371 patent/WO1992019709A1/en not_active Ceased
- 1992-04-24 PL PL92301146A patent/PL170474B1/pl unknown
- 1992-04-24 EP EP92914376A patent/EP0583420B1/en not_active Expired - Lifetime
- 1992-04-24 HU HU9303085A patent/HU213044B/hu not_active IP Right Cessation
- 1992-04-24 CA CA002108908A patent/CA2108908C/en not_active Expired - Lifetime
- 1992-04-24 CZ CZ932304A patent/CZ285148B6/cs not_active IP Right Cessation
- 1992-04-24 BR BR9205959A patent/BR9205959A/pt not_active IP Right Cessation
- 1992-04-24 ES ES92914376T patent/ES2085024T3/es not_active Expired - Lifetime
- 1992-04-24 AT AT92914376T patent/ATE136055T1/de not_active IP Right Cessation
- 1992-04-24 JP JP51191892A patent/JP3219765B2/ja not_active Expired - Lifetime
- 1992-04-24 DE DE69209500T patent/DE69209500T2/de not_active Expired - Lifetime
- 1992-04-24 SK SK1208-93A patent/SK120893A3/sk unknown
- 1992-04-28 PH PH44278A patent/PH31244A/en unknown
- 1992-04-29 NZ NZ242536A patent/NZ242536A/en unknown
- 1992-04-30 TR TR00420/92A patent/TR28516A/xx unknown
- 1992-04-30 MX MX9202070A patent/MX9202070A/es not_active IP Right Cessation
- 1992-04-30 MY MYPI92000754A patent/MY109321A/en unknown
- 1992-04-30 CN CN92104214.0A patent/CN1034021C/zh not_active Expired - Fee Related
- 1992-04-30 PT PT100445A patent/PT100445A/pt not_active Application Discontinuation
- 1992-06-30 TW TW081105186A patent/TW221827B/zh active
- 1992-07-01 IE IE138892A patent/IE921388A1/en not_active Application Discontinuation
-
1994
- 1994-12-21 US US08/361,023 patent/US5468414A/en not_active Expired - Lifetime
-
1996
- 1996-03-29 GR GR960400837T patent/GR3019462T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IE921388A1 (en) | 1992-11-04 |
| EP0583420B1 (en) | 1996-03-27 |
| JP3219765B2 (ja) | 2001-10-15 |
| JPH07501349A (ja) | 1995-02-09 |
| PT100445A (pt) | 1993-08-31 |
| CA2108908C (en) | 1998-06-30 |
| ATE136055T1 (de) | 1996-04-15 |
| ES2085024T3 (es) | 1996-05-16 |
| CZ230493A3 (en) | 1994-04-13 |
| TR28516A (tr) | 1996-09-02 |
| SK120893A3 (en) | 1994-08-10 |
| CN1034021C (zh) | 1997-02-12 |
| EP0583420A1 (en) | 1994-02-23 |
| CN1067449A (zh) | 1992-12-30 |
| US5468414A (en) | 1995-11-21 |
| CZ285148B6 (cs) | 1999-05-12 |
| AU2234092A (en) | 1992-12-21 |
| WO1992019709A1 (en) | 1992-11-12 |
| CA2108908A1 (en) | 1992-10-31 |
| BR9205959A (pt) | 1994-07-26 |
| PH31244A (en) | 1998-06-18 |
| TW221827B (enExample) | 1994-03-21 |
| GR3019462T3 (en) | 1996-06-30 |
| DE69209500D1 (de) | 1996-05-02 |
| HU9303085D0 (en) | 1994-03-28 |
| MY109321A (en) | 1997-01-31 |
| DE69209500T2 (de) | 1996-10-31 |
| MX9202070A (es) | 1992-11-01 |
| AU666660B2 (en) | 1996-02-22 |
| HUT67139A (en) | 1995-02-28 |
| PL170474B1 (pl) | 1996-12-31 |
| NZ242536A (en) | 1995-06-27 |
| DK0583420T3 (da) | 1996-07-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HMM4 | Cancellation of final prot. due to non-payment of fee |