ES2269135T3 - Componentes y catalizadores para la polimerizacion de olefinas. - Google Patents
Componentes y catalizadores para la polimerizacion de olefinas. Download PDFInfo
- Publication number
- ES2269135T3 ES2269135T3 ES00926912T ES00926912T ES2269135T3 ES 2269135 T3 ES2269135 T3 ES 2269135T3 ES 00926912 T ES00926912 T ES 00926912T ES 00926912 T ES00926912 T ES 00926912T ES 2269135 T3 ES2269135 T3 ES 2269135T3
- Authority
- ES
- Spain
- Prior art keywords
- succinate
- hydrogen
- catalyst
- diethyl
- catalyst component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 61
- 239000003054 catalyst Substances 0.000 title claims description 72
- 150000001336 alkenes Chemical class 0.000 title claims description 17
- 239000011949 solid catalyst Substances 0.000 claims abstract description 50
- 239000001257 hydrogen Substances 0.000 claims abstract description 42
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 42
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 22
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 22
- 125000003118 aryl group Chemical group 0.000 claims abstract description 18
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 16
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 14
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 13
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 13
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 12
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000002367 halogens Chemical class 0.000 claims abstract description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 5
- 150000003890 succinate salts Chemical class 0.000 claims abstract 4
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 83
- -1 diisobutyl 2,2-dimethyl succinate Chemical compound 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 52
- 150000001875 compounds Chemical class 0.000 claims description 48
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 34
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 33
- 239000005977 Ethylene Substances 0.000 claims description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 25
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 23
- 239000010936 titanium Substances 0.000 claims description 21
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 19
- 239000001294 propane Substances 0.000 claims description 14
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 9
- 239000002253 acid Chemical class 0.000 claims description 8
- 125000004429 atom Chemical group 0.000 claims description 7
- 150000002430 hydrocarbons Chemical group 0.000 claims description 7
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 150000003377 silicon compounds Chemical class 0.000 claims description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- HSCLUIKEZDGKBP-UHFFFAOYSA-N 2,3-di(propan-2-yl)butanedioic acid Chemical compound CC(C)C(C(O)=O)C(C(C)C)C(O)=O HSCLUIKEZDGKBP-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 125000005498 phthalate group Chemical group 0.000 claims description 4
- 150000003609 titanium compounds Chemical class 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 150000001721 carbon Chemical group 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 claims 2
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 claims 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 35
- 229920000642 polymer Polymers 0.000 description 33
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 26
- 150000003900 succinic acid esters Chemical class 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000011777 magnesium Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 235000011147 magnesium chloride Nutrition 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 229910003074 TiCl4 Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- WXUAQHNMJWJLTG-VKHMYHEASA-N (S)-methylsuccinic acid Chemical compound OC(=O)[C@@H](C)CC(O)=O WXUAQHNMJWJLTG-VKHMYHEASA-N 0.000 description 3
- VQNGKYXWYAHFPF-UHFFFAOYSA-N 2-cyclohexyl-3-cyclopentylbutanedioic acid Chemical compound C1CCCC1C(C(=O)O)C(C(O)=O)C1CCCCC1 VQNGKYXWYAHFPF-UHFFFAOYSA-N 0.000 description 3
- KDNUUZCIPIPBKN-UHFFFAOYSA-N 4-oxo-4-(1,1,1-trifluoropropan-2-yloxy)butanoic acid Chemical compound FC(F)(F)C(C)OC(=O)CCC(O)=O KDNUUZCIPIPBKN-UHFFFAOYSA-N 0.000 description 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229940043279 diisopropylamine Drugs 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- AJLCTEPRECBBKT-UHFFFAOYSA-N 2,3-bis(3-methylbutyl)butanedioic acid Chemical compound CC(C)CCC(C(O)=O)C(C(O)=O)CCC(C)C AJLCTEPRECBBKT-UHFFFAOYSA-N 0.000 description 2
- FUFSLRDLUNRCHM-UHFFFAOYSA-N 2,3-diethyl-2,3-di(propan-2-yl)butanedioic acid Chemical compound CCC(C(C)C)(C(O)=O)C(CC)(C(C)C)C(O)=O FUFSLRDLUNRCHM-UHFFFAOYSA-N 0.000 description 2
- BEHQZIRZSPNOIT-UHFFFAOYSA-N 2,3-diethyl-2-propan-2-ylbutanedioic acid Chemical compound CCC(C(O)=O)C(CC)(C(C)C)C(O)=O BEHQZIRZSPNOIT-UHFFFAOYSA-N 0.000 description 2
- AVIFPSNRFRVXMI-UHFFFAOYSA-N 2-benzyl-2-propan-2-ylbutanedioic acid Chemical compound OC(=O)CC(C(C)C)(C(O)=O)CC1=CC=CC=C1 AVIFPSNRFRVXMI-UHFFFAOYSA-N 0.000 description 2
- UFSJLOVZESXSHD-UHFFFAOYSA-N 2-butyl-2-phenylbutanedioic acid Chemical compound CCCCC(CC(O)=O)(C(O)=O)C1=CC=CC=C1 UFSJLOVZESXSHD-UHFFFAOYSA-N 0.000 description 2
- VZWZBFDXXQFDHW-UHFFFAOYSA-N 2-cyclohexyl-3-(3-methylbutyl)butanedioic acid Chemical compound CC(C)CCC(C(O)=O)C(C(O)=O)C1CCCCC1 VZWZBFDXXQFDHW-UHFFFAOYSA-N 0.000 description 2
- LIJMAHQYXMQISA-UHFFFAOYSA-N 2-cyclohexyl-3-propan-2-ylbutanedioic acid Chemical compound CC(C)C(C(O)=O)C(C(O)=O)C1CCCCC1 LIJMAHQYXMQISA-UHFFFAOYSA-N 0.000 description 2
- GIPUHGMDLPLFGZ-UHFFFAOYSA-N 2-cyclopentyl-2-propylbutanedioic acid Chemical compound CCCC(CC(O)=O)(C(O)=O)C1CCCC1 GIPUHGMDLPLFGZ-UHFFFAOYSA-N 0.000 description 2
- ZTPFWDMGYSWDAI-UHFFFAOYSA-N 2-methyl-2-propan-2-ylbutanedioic acid Chemical compound CC(C)C(C)(C(O)=O)CC(O)=O ZTPFWDMGYSWDAI-UHFFFAOYSA-N 0.000 description 2
- RKAFKUROUOLPOL-UHFFFAOYSA-N 2-propan-2-ylbutanedioic acid Chemical compound CC(C)C(C(O)=O)CC(O)=O RKAFKUROUOLPOL-UHFFFAOYSA-N 0.000 description 2
- IFNUNBGGVMUJNV-UHFFFAOYSA-N 4-(1-cyclohexylethoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OC(C)C1CCCCC1 IFNUNBGGVMUJNV-UHFFFAOYSA-N 0.000 description 2
- RQPUMSMXKHBGMO-UHFFFAOYSA-N 4-(9H-fluoren-9-yloxy)-4-oxobutanoic acid Chemical compound C1=CC=C2C(OC(=O)CCC(=O)O)C3=CC=CC=C3C2=C1 RQPUMSMXKHBGMO-UHFFFAOYSA-N 0.000 description 2
- HZXMLBSUEZTYHZ-UHFFFAOYSA-N 4-(cyclohexylmethoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCC1CCCCC1 HZXMLBSUEZTYHZ-UHFFFAOYSA-N 0.000 description 2
- CQBVVSONJDUVEJ-UHFFFAOYSA-N 4-cyclohexyloxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OC1CCCCC1 CQBVVSONJDUVEJ-UHFFFAOYSA-N 0.000 description 2
- RQNNLQNFSREFER-UHFFFAOYSA-N CC(C)CC(C)OC(=O)CCC(=O)O Chemical compound CC(C)CC(C)OC(=O)CCC(=O)O RQNNLQNFSREFER-UHFFFAOYSA-N 0.000 description 2
- GFQUHXOKHFFPGI-UHFFFAOYSA-N CCC(CC)COC(=O)CCC(O)=O Chemical compound CCC(CC)COC(=O)CCC(O)=O GFQUHXOKHFFPGI-UHFFFAOYSA-N 0.000 description 2
- XHLXMRJWRKQMCP-UHFFFAOYSA-N Diethyl methylsuccinate Chemical compound CCOC(=O)CC(C)C(=O)OCC XHLXMRJWRKQMCP-UHFFFAOYSA-N 0.000 description 2
- 235000019502 Orange oil Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- RREHKLQGUDYKJV-UHFFFAOYSA-N bis(2-methylpropyl) 2,2,3-trimethylbutanedioate Chemical compound CC(C)COC(=O)C(C)C(C)(C)C(=O)OCC(C)C RREHKLQGUDYKJV-UHFFFAOYSA-N 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 150000001934 cyclohexanes Chemical class 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- JVQDNCKPHSZFSO-UHFFFAOYSA-N diethyl 2-phenylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=CC=C1 JVQDNCKPHSZFSO-UHFFFAOYSA-N 0.000 description 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- ZCSHNCUQKCANBX-UHFFFAOYSA-N lithium diisopropylamide Chemical compound [Li+].CC(C)[N-]C(C)C ZCSHNCUQKCANBX-UHFFFAOYSA-N 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229940078552 o-xylene Drugs 0.000 description 2
- 239000010502 orange oil Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RIFKADJTWUGDOV-UHFFFAOYSA-N 1-cyclohexylethanone Chemical compound CC(=O)C1CCCCC1 RIFKADJTWUGDOV-UHFFFAOYSA-N 0.000 description 1
- CQCFISPMNREOQX-UHFFFAOYSA-N 2,2,3,3-tetraethylbutanedioic acid Chemical compound CCC(CC)(C(O)=O)C(CC)(CC)C(O)=O CQCFISPMNREOQX-UHFFFAOYSA-N 0.000 description 1
- XDMIOWTZXSLEKJ-UHFFFAOYSA-N 2,2,3,3-tetrapropylbutanedioic acid Chemical compound CCCC(CCC)(C(O)=O)C(CCC)(CCC)C(O)=O XDMIOWTZXSLEKJ-UHFFFAOYSA-N 0.000 description 1
- GOHPTLYPQCTZSE-UHFFFAOYSA-N 2,2-dimethylsuccinic acid Chemical compound OC(=O)C(C)(C)CC(O)=O GOHPTLYPQCTZSE-UHFFFAOYSA-N 0.000 description 1
- NVSRLSRGXUGMCX-UHFFFAOYSA-N 2,3-bis(2,2-dimethylpropyl)butanedioic acid Chemical compound CC(C)(C)CC(C(O)=O)C(C(O)=O)CC(C)(C)C NVSRLSRGXUGMCX-UHFFFAOYSA-N 0.000 description 1
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- RQPNECGZAMRIRP-UHFFFAOYSA-N diethyl 2-cyclohexylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CCCCC1 RQPNECGZAMRIRP-UHFFFAOYSA-N 0.000 description 1
- XMVGCOWCTAZJNT-UHFFFAOYSA-N diethyl 2-cyclopropylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CC1 XMVGCOWCTAZJNT-UHFFFAOYSA-N 0.000 description 1
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- JYEMURZLFONTNE-UHFFFAOYSA-N ethyl 1-(2-ethoxyacetyl)-2,6-dimethylcyclohexane-1-carboxylate Chemical compound CCOCC(=O)C1(C(=O)OCC)C(C)CCCC1C JYEMURZLFONTNE-UHFFFAOYSA-N 0.000 description 1
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- IIDVGIFOWJJSIJ-UHFFFAOYSA-M lithium;2-methylpropanoate Chemical compound [Li+].CC(C)C([O-])=O IIDVGIFOWJJSIJ-UHFFFAOYSA-M 0.000 description 1
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- 238000005259 measurement Methods 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
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- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
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- 229920001897 terpolymer Polymers 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99201172 | 1999-04-15 | ||
| EP99201172 | 1999-04-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2269135T3 true ES2269135T3 (es) | 2007-04-01 |
Family
ID=8240100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00926912T Expired - Lifetime ES2269135T3 (es) | 1999-04-15 | 2000-04-12 | Componentes y catalizadores para la polimerizacion de olefinas. |
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|---|---|
| US (2) | US6818583B1 (https=) |
| EP (1) | EP1088009B1 (https=) |
| JP (2) | JP4717219B2 (https=) |
| KR (1) | KR100700957B1 (https=) |
| CN (2) | CN1240729C (https=) |
| AR (1) | AR043275A1 (https=) |
| AT (1) | ATE335014T1 (https=) |
| AU (1) | AU777683B2 (https=) |
| BR (1) | BR0006095B1 (https=) |
| CA (1) | CA2334743C (https=) |
| DE (1) | DE60029714T2 (https=) |
| ES (1) | ES2269135T3 (https=) |
| HU (1) | HUP0103083A3 (https=) |
| ID (1) | ID28200A (https=) |
| IL (1) | IL140154A (https=) |
| MY (1) | MY124016A (https=) |
| NO (1) | NO20006388L (https=) |
| PL (1) | PL345209A1 (https=) |
| RU (1) | RU2225415C2 (https=) |
| SA (1) | SA00210385B1 (https=) |
| TW (1) | TWI229086B (https=) |
| WO (1) | WO2000063261A1 (https=) |
Families Citing this family (279)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| CN1240729C (zh) * | 1999-04-15 | 2006-02-08 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的组分和催化剂 |
| WO2001057099A1 (en) * | 2000-02-02 | 2001-08-09 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| MXPA02005825A (es) * | 2000-10-13 | 2003-10-14 | Basell Poliolefine Spa | Componentes catalizadores para la polimerizacion de olefinas. |
| WO2003076480A1 (en) * | 2002-03-08 | 2003-09-18 | Basell Poliolefine Italia S.P.A. | Process for preparing a diether-based catalyst component |
| EP1507806B1 (en) | 2002-05-29 | 2006-10-11 | Basell Poliolefine Italia S.r.l. | Butene-1 (co)polymers and process for their preparation |
| ES2289295T3 (es) * | 2002-06-13 | 2008-02-01 | Basell Poliolefine Italia S.R.L. | Componentes cataliticos ziegler natta para la polimerizacion de olefinas. |
| US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| DE60317903T2 (de) * | 2002-07-02 | 2008-11-13 | Basell Poliolefine Italia S.R.L. | Katalysatorsystem für die polymerisation von olefinen |
| CN1218951C (zh) | 2002-07-17 | 2005-09-14 | 中国石油化工股份有限公司 | 一种硅醚化合物及其制备方法和应用 |
| PL374508A1 (en) * | 2002-08-01 | 2005-10-31 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| US7202314B2 (en) | 2002-09-16 | 2007-04-10 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| RU2318833C2 (ru) * | 2002-11-28 | 2008-03-10 | Базелль Полиолефин Италия С.П.А. | Сополимеры бутена-1 и способ их получения |
| EP1613670B1 (en) | 2003-03-26 | 2017-05-10 | Ineos Technologies USA LLC | Olefin polymerisation catalyst component containing a bicyclic cycloakane dicarboxylate as electron donor |
| TW200427763A (en) * | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| AU2004262661A1 (en) | 2003-08-05 | 2005-02-17 | Basell Poliolefine Italia S.R.L. | Polyolefin articles |
| WO2005047351A1 (en) * | 2003-10-28 | 2005-05-26 | Basell Poliolefine Italia S.R.L. | Components and catalysts for the polymerization of olefins |
| CA2567646A1 (en) * | 2004-05-21 | 2005-12-01 | Basell Poliolefine Italia S.R.L. | Impact resistant polyolefin compositions |
| CN101065437B (zh) | 2004-10-04 | 2010-12-08 | 巴塞尔聚烯烃意大利有限责任公司 | 弹性体聚烯烃组合物 |
| BRPI0517490B1 (pt) * | 2004-12-20 | 2016-10-04 | Basell Poliolefine Srl | Processo para preparar copolímeros heterofásicos de propileno |
| KR101240925B1 (ko) | 2004-12-21 | 2013-03-08 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 및 그의 투과성 필름 |
| ATE424435T1 (de) * | 2004-12-23 | 2009-03-15 | Basell Poliolefine Srl | Polyolefinische zusammensetzungen mit hoher bleichungsresistenz |
| JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| US7888438B2 (en) | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
| JP5530054B2 (ja) | 2005-01-19 | 2014-06-25 | 三井化学株式会社 | オレフィン重合体製造用固体状チタン触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| JP4632299B2 (ja) * | 2005-01-26 | 2011-02-16 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法および触媒 |
| EP1844100B1 (en) | 2005-02-03 | 2009-10-28 | Basell Poliolefine Italia S.r.l. | Propylene polymer composition for injection molding |
| CN101163738B (zh) * | 2005-04-21 | 2011-07-13 | 巴塞尔聚烯烃意大利有限责任公司 | 双轴取向丙烯聚合物膜 |
| EP1874530A2 (en) | 2005-04-28 | 2008-01-09 | Basell Poliolefine Italia S.r.l. | Reinforced polypropylene pipe |
| DE602006007572D1 (de) | 2005-05-12 | 2009-08-13 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| BRPI0613247A2 (pt) | 2005-05-27 | 2010-12-28 | Basell Poliolefine Srl | composições poliolefìnicas tendo boa resistência ao branqueamento |
| CA2613188A1 (en) | 2005-07-01 | 2007-01-11 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
| AU2006268772A1 (en) * | 2005-07-11 | 2007-01-18 | Basell Poliolefine Italia S.R.L. | Metallized propylene polymer film with good barrier retention properties |
| US20100160540A1 (en) * | 2005-08-08 | 2010-06-24 | Basell Poliolefine Italia S.R.L. | Process for the Nucleation of Polypropylene Resins |
| CN101309939B (zh) * | 2005-11-15 | 2011-01-12 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯-乙烯共聚物及其制备方法 |
| ATE499409T1 (de) | 2005-11-22 | 2011-03-15 | Basell Poliolefine Srl | Schlagzähe polyolefinzusammensetzungen |
| CN101341209B (zh) | 2005-12-20 | 2011-08-31 | 巴塞尔聚烯烃意大利有限责任公司 | 用于拉伸制品的聚丙烯组合物 |
| JP2009520090A (ja) * | 2005-12-20 | 2009-05-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 柔軟な不織布 |
| US8343602B2 (en) | 2006-02-23 | 2013-01-01 | Basell Poliolefine Italia, s.r.l. | Propylene polymers for injection molding applications |
| EP1849807A1 (en) * | 2006-04-24 | 2007-10-31 | Total Petrochemicals Research Feluy | Catalyst composition for the copolymerization of propylene |
| PL2029637T3 (pl) * | 2006-06-21 | 2010-08-31 | Total Res & Technology Feluy | Mieszanka katalizatorów (ko)polimeryzacji propylenu |
| EP2029634A1 (en) * | 2006-06-22 | 2009-03-04 | Basell Poliolefine Italia S.r.l. | Catalyst component for the polymerization of olefins based on 1,3-diethers |
| WO2007147740A1 (en) * | 2006-06-22 | 2007-12-27 | Basell Poliolefine Italia S.R.L. | Catalyst component for the polymerization of olefins |
| CN101490101B (zh) | 2006-07-18 | 2011-11-02 | 三井化学株式会社 | 固态钛催化剂成分、烯烃聚合用催化剂及烯烃聚合方法 |
| WO2008012144A1 (en) * | 2006-07-28 | 2008-01-31 | Basell Poliolefine Italia S.R.L. | Propylene polymers |
| KR101485811B1 (ko) | 2006-11-23 | 2015-01-26 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| CN101195666B (zh) * | 2006-12-06 | 2012-03-07 | 中国石油天然气股份有限公司 | 一种烯烃聚合用负载型催化剂及其制备方法 |
| DE602007005171D1 (de) | 2006-12-21 | 2010-04-15 | Basell Poliolefine Srl | Polypropylenfolien mit hohem schrumpf |
| US8455072B2 (en) * | 2006-12-22 | 2013-06-04 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for pipe system and sheets |
| WO2008082954A1 (en) * | 2006-12-29 | 2008-07-10 | Fina Technology, Inc. | Succinate-containing polymerization catalyst system using n-butylmethyldimethoxysilane for preparation of polypropylene film grade resins |
| RU2459836C2 (ru) | 2007-05-22 | 2012-08-27 | Базелль Полиолефин Италия С.Р.Л. | Способ получения мягких композиций пропиленовых полимеров |
| ATE485317T1 (de) | 2007-05-22 | 2010-11-15 | Basell Poliolefine Srl | Weiche propylenpolymerzusammensetzungen |
| PL2185600T3 (pl) * | 2007-08-24 | 2019-07-31 | W.R. Grace & Co. - Conn. | Samohamująca kompozycja katalityczna bez silanu |
| CN101848946B (zh) * | 2007-08-24 | 2013-06-12 | 陶氏环球技术有限责任公司 | 气相聚合方法 |
| BRPI0816051A2 (pt) * | 2007-08-29 | 2015-03-03 | Basell Poliolefine Srl | Catalisador para a polimerização de olefinas |
| FR2921368B1 (fr) | 2007-09-25 | 2012-10-12 | Pf Medicament | Nouveau procede de synthese de derives anticancereux de (poly) aminoalkylaminoacetamide d'epipodophyllotoxine. |
| CN101397246B (zh) * | 2007-09-28 | 2011-08-03 | 中国石油化工股份有限公司 | 一种2,3-二烃基琥珀酸及其酯类化合物的制备方法 |
| US8507628B2 (en) | 2007-10-02 | 2013-08-13 | Fina Technology, Inc. | Propylene based polymers for injection stretch blow molding |
| US20100249330A1 (en) * | 2007-10-15 | 2010-09-30 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high fluidity propylene polymers |
| CN101423572B (zh) * | 2007-11-01 | 2011-09-07 | 中国石油天然气股份有限公司 | 用于烯烃聚合的催化组分及其催化剂 |
| CN101423571B (zh) * | 2007-11-01 | 2010-09-01 | 中国石油天然气股份有限公司 | 烯烃聚合催化组分及其催化剂 |
| CN101423566B (zh) * | 2007-11-01 | 2010-11-03 | 中国石油天然气股份有限公司 | 一种固体催化组分及其催化剂 |
| SG194361A1 (en) | 2007-11-27 | 2013-11-29 | Mitsui Chemicals Inc | Solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process |
| EP2070954A1 (en) * | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content |
| EP2222730B2 (en) * | 2007-12-18 | 2019-12-25 | Basell Poliolefine Italia S.r.l. | Copolymers of propylene with hexene-1 and blown films obtained from them |
| US9988522B2 (en) | 2007-12-18 | 2018-06-05 | Basell Poliolefine Italia S.R.L. | Transparant polyolefin compositions |
| JP2011506718A (ja) * | 2007-12-20 | 2011-03-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 改良された特性を有する高立体規則性ポリプロピレン |
| JP5740159B2 (ja) * | 2007-12-21 | 2015-06-24 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 二座内部供与体を有する自己制限性触媒組成物 |
| WO2009083500A1 (en) * | 2007-12-28 | 2009-07-09 | Basell Poliolefine Italia S.R.L. | Plastic tanks made from random copolymers of propylene and hexene-1 |
| CN101735346B (zh) | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
| US8088872B2 (en) | 2008-11-25 | 2012-01-03 | Dow Global Technologies Llc | Procatalyst composition including silyl ester internal donor and method |
| ES2393976T3 (es) * | 2008-12-03 | 2013-01-03 | Süd-Chemie Ip Gmbh & Co. Kg | Composición donadora de electrones para un catalizador sólido, composición para catalizadores sólidos utilizada en la polimerización de alfa-olefinas, y proceso para la producción de un polímero consistente en unidades de alfa-olefinas que utilizan la composición para catalizadores sólidos. |
| BRPI0923586B1 (pt) | 2008-12-24 | 2019-09-10 | Basell Poliolefine Italia Srl | composição de poliolefina heterofásica |
| JP2012514087A (ja) | 2008-12-30 | 2012-06-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィンの蒸気処理 |
| CN101811982B (zh) * | 2009-02-19 | 2013-02-06 | 中国石油化工股份有限公司 | 2，3-二异丙基-2，3-二氰基丁二酸二酯类化合物及其制备方法和应用 |
| CN101811983B (zh) | 2009-02-19 | 2013-02-06 | 中国石油化工股份有限公司 | 2，3-二异丙基-2-氰基丁二酸二酯类化合物的制备方法 |
| CN101824107B (zh) * | 2009-03-04 | 2013-04-24 | 中国石油天然气股份有限公司 | 用于烯烃聚合的固体主催化剂 |
| CN101831016B (zh) * | 2009-03-10 | 2011-10-05 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化组分及其催化剂 |
| EP2411464B1 (en) | 2009-03-23 | 2013-05-08 | Basell Poliolefine Italia S.r.l. | Polyolefin masterbatch and composition suitable for injection molding |
| JP5689232B2 (ja) * | 2009-03-24 | 2015-03-25 | 三井化学株式会社 | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| US9090000B2 (en) * | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| SG175203A1 (en) * | 2009-04-17 | 2011-11-28 | China Petroleum & Chemical | Catalyst component used for olefin polymerization, process for preparing the same, and catalyst containing the same |
| EP2264099A1 (en) | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| US8975338B2 (en) | 2009-05-21 | 2015-03-10 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| CN102803310A (zh) * | 2009-06-19 | 2012-11-28 | 巴塞尔聚烯烃意大利有限责任公司 | 制备抗冲击性丙烯聚合物组合物的方法 |
| JP5852566B2 (ja) | 2009-06-26 | 2016-02-03 | サンアロマー株式会社 | ポリオレフィン組成物 |
| US8575272B2 (en) | 2009-07-31 | 2013-11-05 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions |
| BR112012002281B1 (pt) | 2009-07-31 | 2019-05-28 | Basell Poliolefine Italia S.R.L. | Composição polimérica e processo de polimerização para sua preparação |
| CN102146146B (zh) * | 2010-02-10 | 2013-08-14 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其催化剂 |
| US8541333B2 (en) | 2009-08-13 | 2013-09-24 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and a catalyst comprising the same |
| BR112012006343B1 (pt) | 2009-09-22 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | Composições de polímero de propileno |
| WO2011035994A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| BR112012006532B1 (pt) | 2009-09-22 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | Composições de polímero de propileno |
| WO2011036002A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| WO2011036016A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| EP2480597A1 (en) | 2009-09-24 | 2012-08-01 | Basell Poliolefine Italia S.r.l. | Heat-sealable polyolefin films |
| WO2011039314A1 (en) | 2009-09-29 | 2011-04-07 | Basell Poliolefine Italia Srl | Heat-sealable polyolefin films |
| CN102612538B (zh) | 2009-10-13 | 2015-11-25 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯聚合物组合物 |
| EP2501727B1 (en) | 2009-11-19 | 2014-05-14 | Basell Poliolefine Italia S.r.l. | Process for the preparation of impact resistant propylene polymer compositions |
| KR101114073B1 (ko) * | 2009-12-08 | 2012-02-22 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매의 제조 방법 |
| US8211819B2 (en) * | 2009-12-21 | 2012-07-03 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts |
| EP2516546B1 (en) | 2009-12-23 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Polyolefinic compositions for injection-moulded drainage systems |
| EP2519549A1 (en) | 2009-12-29 | 2012-11-07 | Basell Poliolefine Italia S.r.l. | Process for the production of polyolefin films |
| CN102666598B (zh) | 2009-12-31 | 2015-08-12 | 晓星株式会社 | 烯烃聚合用齐格勒-纳塔催化剂 |
| US20130012642A1 (en) | 2010-03-26 | 2013-01-10 | Basell Poliolefine Italia S.R.L. | Heterophasic Polyolefin Composition |
| CN102234337B (zh) * | 2010-04-22 | 2013-08-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| EP2566919B1 (en) | 2010-05-05 | 2016-05-11 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| CN102884123B (zh) | 2010-05-19 | 2015-03-25 | 巴塞尔聚烯烃意大利有限责任公司 | 用于洗涤机的聚丙烯桶 |
| WO2011144489A1 (en) | 2010-05-20 | 2011-11-24 | Basell Poliolefine Italia Srl | Propylene polymer compositions |
| JP5539789B2 (ja) * | 2010-06-09 | 2014-07-02 | 株式会社プライムポリマー | 微多孔膜形成用プロピレン重合体およびその用途 |
| RU2567546C2 (ru) | 2010-06-23 | 2015-11-10 | Базелль Полиолефин Италия Срл | Полиолефиновая композиция для систем труб и листов |
| ES2650670T3 (es) | 2010-06-23 | 2018-01-19 | Basell Poliolefine Italia S.R.L. | Caños y composición de poliolefina para la fabricación de los mismos |
| WO2011160953A1 (en) | 2010-06-23 | 2011-12-29 | Basell Poliolefine Italia Srl | Polyolefin composition for pipe systems and sheets |
| BR112012033011B1 (pt) * | 2010-06-24 | 2020-05-26 | Basell Poliolefine Italia S.R.L. | Sistema catalisador e processo para polimerizar olefinas utilizando tal sistema |
| CN102311513B (zh) * | 2010-06-29 | 2013-02-06 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及催化剂 |
| WO2012010678A1 (en) | 2010-07-23 | 2012-01-26 | Basell Poliolefine Italia Srl | Propylene polymer compositions |
| BR112013002158B1 (pt) | 2010-07-29 | 2020-07-28 | Basell Poliolefine Italia S.R.L | Copolímero aleatório de propileno, película ou folha mono-ou multicamada e artigos |
| CN102372651B (zh) * | 2010-08-12 | 2013-12-04 | 中国石油化工股份有限公司 | 2-环烷基-3-仲烷基-2-氰基丁二酸酯类化合物、制备方法及其应用 |
| CN102372797A (zh) * | 2010-08-12 | 2012-03-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| CN102432710A (zh) * | 2010-09-29 | 2012-05-02 | 中国石油化工股份有限公司 | 一种用于乙烯聚合催化剂载体的制备方法、催化剂组分及催化剂 |
| WO2012055742A2 (en) | 2010-10-26 | 2012-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing injection stretch blow molded polyolefin containers |
| EP2463413B1 (en) | 2010-12-07 | 2014-01-29 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
| WO2012076447A1 (en) | 2010-12-07 | 2012-06-14 | Basell Poliolefine Italia S.R.L. | Polyolefin based corrugated boards |
| EP2665772B1 (en) | 2011-01-18 | 2014-11-05 | Basell Poliolefine Italia S.r.l. | Polyolefin composition |
| CN103403088B (zh) | 2011-03-10 | 2016-02-10 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃基容器 |
| EP2505606B1 (en) | 2011-03-29 | 2017-03-01 | Basell Poliolefine Italia S.r.l. | Polyolefin composition for pipe systems |
| BR112013025014A2 (pt) | 2011-04-01 | 2017-01-17 | Basell Poliolefine Srl | componentes de catalisador para a polimerização de olefinas e catalisadores obtidos a partir destes |
| WO2012139897A1 (en) * | 2011-04-12 | 2012-10-18 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CN103649131B (zh) | 2011-07-06 | 2016-05-25 | 东邦钛株式会社 | 烯烃类聚合用固体催化剂成分、烯烃类聚合用催化剂及烯烃类聚合物的制造方法 |
| BR112014000017B1 (pt) | 2011-07-07 | 2020-04-07 | Basell Poliolefine Italia Srl | composição de polipropileno |
| JP5785809B2 (ja) * | 2011-07-28 | 2015-09-30 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
| JP5816481B2 (ja) * | 2011-07-28 | 2015-11-18 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
| US9862781B2 (en) * | 2011-08-08 | 2018-01-09 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom |
| EP2751059B1 (en) * | 2011-08-29 | 2015-09-16 | Saudi Basic Industries Corporation | Process for preparing di-substituted succinates |
| EP2583999A1 (en) | 2011-10-20 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| EP2594593A1 (en) * | 2011-11-17 | 2013-05-22 | Basell Poliolefine Italia S.r.l. | Process for the preparation of heterophasic propylene polymer compositions |
| WO2013083576A1 (en) | 2011-12-05 | 2013-06-13 | Basell Poliolefine Italia S.R.L. | Propylene terpolymers |
| EP2607384A1 (en) * | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| WO2013125504A1 (ja) * | 2012-02-20 | 2013-08-29 | サンアロマー株式会社 | シート成形用ポリプロピレン系樹脂組成物 |
| EP2666793A1 (en) | 2012-05-21 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymer |
| KR101677602B1 (ko) * | 2012-07-14 | 2016-11-18 | 인디언 오일 코퍼레이션 리미티드 | 1,2-페닐렌디오에이트를 내부 공여체로서 포함하는 지글러-나타 촉매계 및 그의 제조 방법 |
| EP2712874A1 (en) * | 2012-09-26 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN104736627B (zh) | 2012-10-03 | 2018-04-17 | 胜亚诺盟股份有限公司 | 蒸煮膜用丙烯树脂组合物 |
| EP2722348A1 (en) * | 2012-10-16 | 2014-04-23 | Basell Poliolefine Italia S.r.l. | Process for the preparation of propylene random copolymers |
| BR112015009509B1 (pt) | 2012-10-31 | 2021-09-21 | Exxonmobil Chemical Patents Inc | Artigos moldado compreendendo resinas de polipropileno de ampla distribuição de peso molecular e resina espumável |
| EP2914637B1 (en) | 2012-10-31 | 2017-12-13 | ExxonMobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| US9522968B2 (en) | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| EP2743073A1 (en) * | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Propylene-based terpolymers |
| EP2743307A1 (en) | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Polyolefin composition |
| JP6144045B2 (ja) * | 2012-12-28 | 2017-06-07 | サンアロマー株式会社 | ポリプロピレン樹脂組成物およびその製造方法ならびにポリプロピレンシートおよび二軸延伸ポリプロピレンフィルム |
| EP2757114A1 (en) * | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN103145553B (zh) * | 2013-03-06 | 2016-06-01 | 大连理工大学 | 2,3-烃基取代琥珀酸二酯的合成与应用 |
| EP2778265A1 (en) | 2013-03-11 | 2014-09-17 | Basell Polyolefine GmbH | Multilayer fibers |
| CN105899554B (zh) * | 2013-03-15 | 2018-07-27 | 巴塞尔聚烯烃意大利有限公司 | 用于制备丙烯三元共聚物的方法以及由此得到的三元共聚物 |
| JP6235805B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | 二軸延伸フィルム用ポリプロピレン樹脂組成物 |
| JP6235804B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | シート成形用ポリプロピレン樹脂組成物 |
| CN103304709B (zh) * | 2013-07-10 | 2016-03-30 | 河北工业大学 | 一种用于1-丁烯聚合的固体催化剂 |
| EP2829397A1 (en) | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Heat sealable polyolefin films and sheets |
| CN104418770B (zh) * | 2013-09-03 | 2016-03-30 | 中国石油化工股份有限公司 | 一种2,3-二非直链烷基-2-氰基丁二酸二酯化合物的制备方法 |
| CN104558287B (zh) * | 2013-10-24 | 2017-03-01 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂组分及催化剂 |
| US9567418B2 (en) | 2013-10-30 | 2017-02-14 | Basell Poliolefine Italia S.R.L. | Multimodal copolymers of propylene and 1-hexene |
| US9382348B2 (en) * | 2013-11-13 | 2016-07-05 | Chevron Phillips Chemical Company Lp | System and method for polymerization |
| CN114230931A (zh) | 2014-06-25 | 2022-03-25 | 埃克森美孚化学专利公司 | 高熔体强度聚丙烯以及用于保持熔体强度的挤出方法 |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| JP6598283B2 (ja) * | 2014-11-10 | 2019-10-30 | サンアロマー株式会社 | α−オレフィン類の重合方法 |
| CN107428872B (zh) | 2015-03-19 | 2020-08-04 | 巴塞尔聚烯烃意大利有限公司 | 基于丙烯的三元共聚物 |
| SG10202109529TA (en) * | 2015-06-19 | 2021-10-28 | Saudi Arabian Oil Co | Antifouling oligomerization catalyst systems |
| CN106608841B (zh) * | 2015-10-27 | 2018-06-12 | 中国石油化工股份有限公司 | 2-氰基-2,3-二烃基丁二酸二烷基酯类化合物的制备方法 |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| JP7178992B2 (ja) * | 2016-09-23 | 2022-11-28 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合用の触媒成分、触媒およびその応用 |
| FI3517555T3 (fi) * | 2016-09-23 | 2024-12-30 | China Petroleum & Chem Corp | Katalyyttikomponentti käytettäväksi olefiinipolymeroinnissa, katalyytti ja niiden käyttöjä |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| KR101853569B1 (ko) * | 2016-12-15 | 2018-04-30 | 한화토탈 주식회사 | 에틸렌 올리고머화 반응용 촉매계 및 이를 이용한 에틸렌 올리고머화 방법 |
| KR101963009B1 (ko) * | 2016-12-15 | 2019-03-27 | 한화토탈 주식회사 | 에틸렌 올리고머화 방법 |
| WO2018147944A1 (en) | 2017-02-07 | 2018-08-16 | Exxonmobil Chemical Patents Inc. | High melt strength polypropylenes with improved processability |
| FI3601383T3 (fi) | 2017-03-27 | 2024-05-30 | Basell Poliolefine Italia Srl | Propyleenietyleenisatunnaiskopolymeeri |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| WO2018222310A1 (en) | 2017-05-30 | 2018-12-06 | Exxonmobil Chemical Patents Inc. | High melt strength polypropylene with high stiffness and clarity |
| US10246530B2 (en) | 2017-06-27 | 2019-04-02 | Toho Titanium Co., Ltd. | Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization |
| US11505685B2 (en) | 2017-06-27 | 2022-11-22 | Exxonmobil Chemical Patents Inc. | High impact polypropylene impact copolymer |
| US11732067B2 (en) | 2017-06-27 | 2023-08-22 | Exxonmobil Chemical Patents Inc. | High stiffness polypropylene impact copolymer |
| US11186664B2 (en) | 2017-09-14 | 2021-11-30 | Basell Poliolefine Italia S.R.L. | Propylene ethylene random copolymer |
| JP7096681B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| JP7096682B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| JP7114361B2 (ja) | 2018-06-19 | 2022-08-08 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| WO2020057974A1 (en) | 2018-09-20 | 2020-03-26 | Basell Poliolefine Italia S.R.L. | Propylene terpolymer |
| US11905400B2 (en) | 2018-10-03 | 2024-02-20 | Basell Poliolefine Italia S.R.L. | Pipes and polypropylene composition for the manufacture thereof |
| JP7249126B2 (ja) | 2018-10-18 | 2023-03-30 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| WO2020114760A1 (en) | 2018-12-05 | 2020-06-11 | Basell Poliolefine Italia S.R.L. | Bopp multilayer film |
| WO2020231526A1 (en) | 2019-05-15 | 2020-11-19 | Exxonmobil Chemical Patents Inc. | Polypropylene-based compositions |
| EP3766652B1 (en) | 2019-07-16 | 2023-04-12 | Basell Poliolefine Italia S.r.l. | Use of injection molded container for microwave |
| US20230077569A1 (en) | 2020-02-17 | 2023-03-16 | Exxonmobil Chemical Patents Inc. | Propylene-based polymer compositions having a high molecular weight tail |
| ES3000738T3 (en) | 2020-06-30 | 2025-03-03 | Basell Poliolefine Italia Srl | Polyolefins compositions obtained from recycled polyolefins |
| US20230257562A1 (en) | 2020-06-30 | 2023-08-17 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| US20230265272A1 (en) | 2020-07-21 | 2023-08-24 | Basell Poliolefine Italia S.R.L. | High flow heterophasic polypropylene as appearance improver in polyolefin compositions |
| RU2752516C1 (ru) * | 2020-07-22 | 2021-07-28 | Федеральное государственное бюджетное учреждение науки Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) | Способ получения диалкил 2,3-диизобутилсукцината, компонента титан-магниевых катализаторов полимеризации олефинов |
| EP4185463B1 (en) | 2020-07-24 | 2024-10-02 | Basell Poliolefine Italia S.r.l. | Polyolefin composition for roofing applications |
| EP4192688B1 (en) | 2020-08-07 | 2024-08-21 | Basell Poliolefine Italia S.r.l. | Soft and flexible polyolefin composition |
| JP7575466B2 (ja) * | 2020-08-26 | 2024-10-29 | 三井化学株式会社 | エステル化合物 |
| MX2023005950A (es) | 2020-11-26 | 2023-06-06 | Basell Poliolefine Italia Srl | Composiciones de poliolefina obtenidas a partir de poliolefinas recicladas. |
| US20240059885A1 (en) | 2020-12-14 | 2024-02-22 | Basell Poliolefine Italia S.R.L. | Ultrasoft polyolefin composition |
| KR20230110317A (ko) | 2020-12-21 | 2023-07-21 | 미쓰이 가가쿠 가부시키가이샤 | 에스터 화합물 |
| WO2022167182A1 (en) | 2021-02-08 | 2022-08-11 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for functional films |
| BR112023015234A2 (pt) | 2021-02-26 | 2023-10-10 | Univ Freiburg Albert Ludwigs | Uso de um filme ou folha que compreende uma mescla de polímeros obtida por mesclagem em fusão de uma mistura, processo de fabricação de aditivo com base em extrusão, e, kit de impressão 3d |
| CN117715946A (zh) | 2021-08-24 | 2024-03-15 | 巴塞尔聚烯烃意大利有限公司 | 丙烯乙烯共聚物 |
| WO2023052083A1 (en) | 2021-09-28 | 2023-04-06 | Basell Poliolefine Italia S.R.L. | Soft polypropylene compositions |
| EP4422867B1 (en) | 2021-10-28 | 2025-11-19 | Basell Polyolefine GmbH | Reinforced polypropylene composition |
| CN116041577B (zh) | 2021-10-28 | 2024-12-06 | 中国石油化工股份有限公司 | 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法 |
| CN118284661B (zh) | 2021-12-22 | 2025-06-17 | 巴塞尔聚烯烃意大利有限公司 | 由再生聚烯烃获得的组合物 |
| US20250059362A1 (en) | 2021-12-23 | 2025-02-20 | Basell Poliolefine Italia S.R.L. | Soft polyolefin composition |
| WO2023124742A1 (zh) * | 2021-12-30 | 2023-07-06 | 中国石油天然气股份有限公司 | 聚丙烯树脂及其制备方法 |
| CN118574864B (zh) | 2022-02-17 | 2025-03-14 | 巴塞尔聚烯烃意大利有限公司 | 管道及其制造用聚丙烯组合物 |
| JP2023132923A (ja) * | 2022-03-11 | 2023-09-22 | 東邦チタニウム株式会社 | オレフィン類重合用触媒、オレフィン類重合体の製造方法及びプロピレン単独重合体 |
| JPWO2023171433A1 (https=) * | 2022-03-11 | 2023-09-14 | ||
| US20250304730A1 (en) | 2022-05-06 | 2025-10-02 | Basell Poliolefine Italia S.R.L. | Plastic material and shaped article obtained therefrom |
| WO2023247227A1 (en) | 2022-06-20 | 2023-12-28 | Basell Poliolefine Italia S.R.L. | Multilayer film |
| US20260015443A1 (en) | 2022-07-27 | 2026-01-15 | Exxonmobil Chemical Patents Inc. | Polyproplyene compositions with enhanced strain hardening and methods of producing the same |
| JP2025521958A (ja) | 2022-08-03 | 2025-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシールフィルム用ポリプロピレン組成物 |
| CN119546697B (zh) | 2022-08-04 | 2025-09-12 | 巴塞尔聚烯烃意大利有限公司 | 由再循环聚烯烃获得的聚烯烃组合物 |
| EP4565648A1 (en) | 2022-08-04 | 2025-06-11 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4317300A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4317299A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4565650A1 (en) | 2022-08-04 | 2025-06-11 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4565651A1 (en) | 2022-08-04 | 2025-06-11 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4317301A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4587515A1 (en) | 2022-09-14 | 2025-07-23 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339239A1 (en) | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339240A1 (en) | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| WO2024056322A1 (en) | 2022-09-14 | 2024-03-21 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| CN117924562A (zh) | 2022-10-24 | 2024-04-26 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用途 |
| EP4615889A1 (en) | 2022-11-07 | 2025-09-17 | Basell Poliolefine Italia S.r.l. | Molded article comprising propylene homopolymer |
| WO2024099626A1 (en) | 2022-11-07 | 2024-05-16 | Basell Poliolefine Italia S.R.L. | Propylene homopolymer |
| WO2024099643A1 (en) | 2022-11-07 | 2024-05-16 | Basell Poliolefine Italia S.R.L. | Molded article comprising a propylene homopolymer composition |
| EP4615887A1 (en) | 2022-11-07 | 2025-09-17 | Basell Poliolefine Italia S.r.l. | Propylene homopolymer |
| CN120051528A (zh) | 2022-11-07 | 2025-05-27 | 巴塞尔聚烯烃意大利有限公司 | 含有再生材料的聚烯烃组合物 |
| WO2024193834A1 (en) | 2022-11-07 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Polypropylene resin compositon |
| WO2024193835A1 (en) | 2022-11-07 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Polypropylene resin compositon |
| KR20250129692A (ko) | 2022-12-19 | 2025-08-29 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 착색 열가소성 조성물 |
| WO2024188683A1 (en) | 2023-03-14 | 2024-09-19 | Basell Poliolefine Italia S.R.L. | Soft polypropylene composition containing a recycled material |
| WO2024204847A1 (ja) | 2023-03-30 | 2024-10-03 | 三井化学株式会社 | アミド化合物 |
| WO2024204846A1 (ja) | 2023-03-31 | 2024-10-03 | 三井化学株式会社 | カルバメート化合物 |
| EP4698595A1 (en) | 2023-04-18 | 2026-02-25 | Basell Poliolefine Italia S.r.l. | Soft polypropylene composition containing a recycled material |
| WO2024223249A1 (en) | 2023-04-26 | 2024-10-31 | Basell Poliolefine Italia S.R.L. | Propylene-based copolymer compositon |
| EP4702093A1 (en) | 2023-04-26 | 2026-03-04 | Basell Poliolefine Italia S.r.l. | Propylene-based copolymer compositon |
| WO2025021459A1 (en) | 2023-07-27 | 2025-01-30 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
| CN121443683A (zh) | 2023-08-03 | 2026-01-30 | 巴塞尔聚烯烃意大利有限公司 | 含有再循环材料的软聚丙烯组合物 |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250066514A1 (en) | 2023-08-24 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| IT202300025932A1 (it) | 2023-12-05 | 2025-06-05 | Basell Poliolefine Italia Srl | Composizioni polipropileniche con proprietà meccaniche migliorate |
| WO2025125124A1 (en) | 2023-12-14 | 2025-06-19 | Basell Poliolefine Italia S.R.L. | Polypropylene composition for wire and cable applications |
| WO2025168499A1 (en) | 2024-02-07 | 2025-08-14 | Basell Poliolefine Italia S.R.L. | Translucent polypropylene-based material for additive manufacturing |
| EP4613810A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4613808A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4613809A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
| EP4636025A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4636026A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4636022A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4636027A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| WO2025228762A1 (en) | 2024-04-30 | 2025-11-06 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for painted articles |
| EP4660239A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefins |
| EP4660238A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefin |
| EP4660237A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions comprising recycled polyolefins and propylene homopolymer |
| EP4667525A1 (en) | 2024-06-19 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Transparent recycled polypropylene composition |
| EP4667524A1 (en) | 2024-06-20 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Recycled polyolefin composition having improved impact properties |
| EP4667218A1 (en) | 2024-06-20 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Recycled polyolefin composition having improoved impact properties |
| WO2026008347A1 (en) | 2024-07-01 | 2026-01-08 | Basell Poliolefine Italia S.R.L. | Process for improving melt flow rate of a polyolefin recyclate composition |
| EP4674874A1 (en) | 2024-07-05 | 2026-01-07 | Basell Poliolefine Italia S.r.l. | Random propylene copolymers for thermoforming applications |
| WO2026017674A1 (en) | 2024-07-17 | 2026-01-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer |
| EP4685164A1 (en) | 2024-07-24 | 2026-01-28 | Basell Poliolefine Italia S.r.l. | Propylene homopolymer composition |
| EP4685277A1 (en) | 2024-07-25 | 2026-01-28 | Basell Poliolefine Italia S.r.l. | Fiber comprising a propylene based polymers composition |
| WO2026041323A1 (en) | 2024-08-19 | 2026-02-26 | Basell Poliolefine Italia S.R.L. | Polypropylene composition having good thermal and optical properties |
| WO2026063967A1 (en) | 2024-09-19 | 2026-03-26 | Formosa Plastics Corporation, Usa | Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK133012C (da) | 1968-11-21 | 1976-08-09 | Montedison Spa | Katalysator til polymerisation af alkener |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| JPS58138209A (ja) * | 1982-02-08 | 1983-08-17 | Hitachi Ltd | 蒸気タ−ビン用ロ−タシヤフト |
| JPS58138709A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS59206415A (ja) * | 1983-05-11 | 1984-11-22 | Mitsui Petrochem Ind Ltd | １−ブテンの重合方法 |
| JPS59207904A (ja) | 1983-05-11 | 1984-11-26 | Mitsui Petrochem Ind Ltd | オレフイン重合体の製造方法 |
| JPS59206418A (ja) * | 1983-05-11 | 1984-11-22 | Mitsui Petrochem Ind Ltd | ４−メチル−１−ペンテン重合体の製法 |
| JPH0721018B2 (ja) * | 1985-07-05 | 1995-03-08 | 東燃料株式会社 | オレフイン重合用触媒成分の製造方法 |
| KR920000173B1 (ko) | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체 |
| JPH0739446B2 (ja) | 1988-04-04 | 1995-05-01 | チッソ株式会社 | 高剛性ポリプロピレンの製造法 |
| CA1334841C (en) * | 1988-09-13 | 1995-03-21 | Mamoru Kioka | Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalysts, and process for polymerizing olefins |
| KR920007040B1 (ko) | 1988-09-14 | 1992-08-24 | 미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀 중합용 촉매와 그 촉매의 성분 및 그 촉매에 의한 올레핀 중합법과 그 폴리올레핀에 의한 필름 및 사출성형품 |
| IT1227259B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Catalizzatori per la polimerizzazione di olefine. |
| JPH0733407B2 (ja) | 1988-12-26 | 1995-04-12 | 台湾塑膠工業股▲ひん▼有限公司 | ポリオレフィンの製造方法 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| DE69023575T2 (de) * | 1989-08-24 | 1996-08-08 | Mitsui Toatsu Chemicals | Neue extrudierte Filme und Folien aus Polypropylen. |
| US5504169A (en) * | 1989-09-13 | 1996-04-02 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| TW203083B (https=) * | 1990-05-11 | 1993-04-01 | Sumitomo Chemical Co | |
| JPH0488003A (ja) * | 1990-07-30 | 1992-03-19 | Mitsui Petrochem Ind Ltd | 分枝α‐オレフィンの重合方法 |
| IT1262935B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1256648B (it) | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| CA2128920C (en) * | 1993-07-28 | 1999-06-01 | Akihiko Yamamoto | Propylene polymer compositions |
| EP0702052A1 (en) | 1994-09-19 | 1996-03-20 | Unilever Plc | Conical wound polyolefin packaging |
| DE69518830T2 (de) * | 1994-12-20 | 2001-03-22 | Montell Technology Co. B.V., Hoofddorp | Polypropylenreaktionsmischung und verfahren zu ihrer herstellung |
| DE69821710T2 (de) | 1997-03-29 | 2005-01-13 | Basell Poliolefine Italia S.P.A. | Magnesiumdihalogenid/alkohol addukte, verfahren zu ihrer herstellung und damit hergestellte katalysatorbestandteile |
| DE69820399T2 (de) * | 1997-05-30 | 2004-10-07 | Mitsui Chemicals Inc | Polypropylenharz-Zusammensetzung und spritzgegossener Gegenstand |
| US6265512B1 (en) * | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
| CN1240729C (zh) * | 1999-04-15 | 2006-02-08 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的组分和催化剂 |
| WO2001057099A1 (en) * | 2000-02-02 | 2001-08-09 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| MXPA02005825A (es) * | 2000-10-13 | 2003-10-14 | Basell Poliolefine Spa | Componentes catalizadores para la polimerizacion de olefinas. |
-
2000
- 2000-04-12 CN CNB008011230A patent/CN1240729C/zh not_active Expired - Lifetime
- 2000-04-12 CA CA002334743A patent/CA2334743C/en not_active Expired - Lifetime
- 2000-04-12 DE DE60029714T patent/DE60029714T2/de not_active Expired - Lifetime
- 2000-04-12 KR KR1020007014289A patent/KR100700957B1/ko not_active Expired - Lifetime
- 2000-04-12 ID IDW20010114A patent/ID28200A/id unknown
- 2000-04-12 IL IL140154A patent/IL140154A/en active IP Right Grant
- 2000-04-12 RU RU2001101489/04A patent/RU2225415C2/ru active
- 2000-04-12 WO PCT/EP2000/003333 patent/WO2000063261A1/en not_active Ceased
- 2000-04-12 US US09/762,363 patent/US6818583B1/en not_active Expired - Lifetime
- 2000-04-12 EP EP00926912A patent/EP1088009B1/en not_active Expired - Lifetime
- 2000-04-12 HU HU0103083A patent/HUP0103083A3/hu unknown
- 2000-04-12 CN CNB2003101242368A patent/CN1294159C/zh not_active Expired - Lifetime
- 2000-04-12 ES ES00926912T patent/ES2269135T3/es not_active Expired - Lifetime
- 2000-04-12 BR BRPI0006095-0B1A patent/BR0006095B1/pt active IP Right Grant
- 2000-04-12 JP JP2000612346A patent/JP4717219B2/ja not_active Expired - Lifetime
- 2000-04-12 AT AT00926912T patent/ATE335014T1/de active
- 2000-04-12 AU AU45486/00A patent/AU777683B2/en not_active Ceased
- 2000-04-12 PL PL00345209A patent/PL345209A1/xx not_active IP Right Cessation
- 2000-04-13 TW TW089106866A patent/TWI229086B/zh not_active IP Right Cessation
- 2000-04-14 MY MYPI20001602A patent/MY124016A/en unknown
- 2000-04-17 AR ARP000101780A patent/AR043275A1/es active IP Right Grant
- 2000-09-24 SA SA00210385A patent/SA00210385B1/ar unknown
- 2000-12-14 NO NO20006388A patent/NO20006388L/no not_active Application Discontinuation
-
2004
- 2004-08-31 US US10/930,452 patent/US20050032633A1/en not_active Abandoned
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2011
- 2011-01-11 JP JP2011003209A patent/JP5372030B2/ja not_active Expired - Lifetime
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