DE69617543T3 - Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung - Google Patents

Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung Download PDF

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Publication number
DE69617543T3
DE69617543T3 DE69617543T DE69617543T DE69617543T3 DE 69617543 T3 DE69617543 T3 DE 69617543T3 DE 69617543 T DE69617543 T DE 69617543T DE 69617543 T DE69617543 T DE 69617543T DE 69617543 T3 DE69617543 T3 DE 69617543T3
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Prior art keywords
substituents
atoms
metallocene compound
bis
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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DE69617543T
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German (de)
English (en)
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DE69617543T2 (de
DE69617543D1 (de
Inventor
Luigi Resconi
Fabrizio Piemontesi
Ilya E. Nifant'ev
Pavel V. Ivchenko
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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Publication of DE69617543D1 publication Critical patent/DE69617543D1/de
Publication of DE69617543T2 publication Critical patent/DE69617543T2/de
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Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69617543T 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung Expired - Lifetime DE69617543T3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ITMI950099 1995-01-23
PCT/EP1996/000171 WO1996022995A1 (en) 1995-01-23 1996-01-17 Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins

Publications (3)

Publication Number Publication Date
DE69617543D1 DE69617543D1 (de) 2002-01-17
DE69617543T2 DE69617543T2 (de) 2002-08-01
DE69617543T3 true DE69617543T3 (de) 2007-01-18

Family

ID=11370281

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DE69617543T Expired - Lifetime DE69617543T3 (de) 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung

Country Status (24)

Country Link
US (3) US6051728A (enExample)
EP (1) EP0751946B2 (enExample)
JP (1) JP3838662B2 (enExample)
KR (2) KR100414759B1 (enExample)
CN (2) CN1075076C (enExample)
AR (1) AR000776A1 (enExample)
AU (1) AU700256B2 (enExample)
BG (1) BG100904A (enExample)
BR (1) BR9606373A (enExample)
CA (1) CA2186232A1 (enExample)
CZ (1) CZ309596A3 (enExample)
DE (1) DE69617543T3 (enExample)
ES (1) ES2167539T5 (enExample)
FI (1) FI963759L (enExample)
HU (1) HUP9602907A3 (enExample)
IL (1) IL116853A (enExample)
IT (1) IT1272923B (enExample)
MX (1) MX9604229A (enExample)
PL (1) PL185055B1 (enExample)
RU (1) RU2177948C2 (enExample)
TR (1) TR199600720T1 (enExample)
TW (1) TW319777B (enExample)
WO (1) WO1996022995A1 (enExample)
ZA (1) ZA96485B (enExample)

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Publication number Publication date
PL185055B1 (pl) 2003-02-28
CA2186232A1 (en) 1996-08-01
EP0751946B1 (en) 2001-12-05
AU4536696A (en) 1996-08-14
TW319777B (enExample) 1997-11-11
FI963759A0 (fi) 1996-09-20
CN1150430A (zh) 1997-05-21
JP3838662B2 (ja) 2006-10-25
RU2177948C2 (ru) 2002-01-10
CN1075076C (zh) 2001-11-21
IT1272923B (it) 1997-07-01
ZA96485B (en) 1996-08-13
IL116853A (en) 2000-09-28
PL316387A1 (en) 1997-01-06
WO1996022995A1 (en) 1996-08-01
US20030120015A1 (en) 2003-06-26
FI963759A7 (fi) 1996-09-20
JPH09510994A (ja) 1997-11-04
ES2167539T5 (es) 2007-04-01
US6051728A (en) 2000-04-18
ES2167539T3 (es) 2002-05-16
ITMI950099A0 (it) 1995-01-23
CN1355256A (zh) 2002-06-26
KR970701723A (ko) 1997-04-12
IL116853A0 (en) 1996-07-23
DE69617543T2 (de) 2002-08-01
KR100414759B1 (ko) 2004-01-13
EP0751946A1 (en) 1997-01-08
ITMI950099A1 (it) 1996-07-23
HUP9602907A3 (en) 1997-12-29
BG100904A (bg) 1997-07-31
US6518386B1 (en) 2003-02-11
HUP9602907A2 (en) 1997-05-28
FI963759L (fi) 1996-09-20
AR000776A1 (es) 1997-08-06
CN1196721C (zh) 2005-04-13
AU700256B2 (en) 1998-12-24
CZ309596A3 (en) 1997-04-16
TR199600720T1 (tr) 1997-03-21
KR100418106B1 (ko) 2004-04-30
EP0751946B2 (en) 2006-08-09
DE69617543D1 (de) 2002-01-17
MX9604229A (es) 1997-12-31
BR9606373A (pt) 2004-06-29

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