CN1075076C - 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 - Google Patents

金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Info

Publication number
CN1075076C
CN1075076C CN96190226A CN96190226A CN1075076C CN 1075076 C CN1075076 C CN 1075076C CN 96190226 A CN96190226 A CN 96190226A CN 96190226 A CN96190226 A CN 96190226A CN 1075076 C CN1075076 C CN 1075076C
Authority
CN
China
Prior art keywords
substituting group
hydrogen atom
formula
compound
metallocenic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN96190226A
Other languages
English (en)
Chinese (zh)
Other versions
CN1150430A (zh
Inventor
L·雷斯康尼
F·皮蒙特西
I·E·尼芬特夫
P·V·伊夫陈科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1075076(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of CN1150430A publication Critical patent/CN1150430A/zh
Application granted granted Critical
Publication of CN1075076C publication Critical patent/CN1075076C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN96190226A 1995-01-23 1996-01-17 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 Expired - Fee Related CN1075076C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ITMI95A000099 1995-01-23

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNB011208953A Division CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Publications (2)

Publication Number Publication Date
CN1150430A CN1150430A (zh) 1997-05-21
CN1075076C true CN1075076C (zh) 2001-11-21

Family

ID=11370281

Family Applications (2)

Application Number Title Priority Date Filing Date
CN96190226A Expired - Fee Related CN1075076C (zh) 1995-01-23 1996-01-17 金属茂化合物及其制法和在烯烃聚合催化剂中的应用
CNB011208953A Expired - Fee Related CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB011208953A Expired - Fee Related CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Country Status (24)

Country Link
US (3) US6051728A (enExample)
EP (1) EP0751946B2 (enExample)
JP (1) JP3838662B2 (enExample)
KR (2) KR100414759B1 (enExample)
CN (2) CN1075076C (enExample)
AR (1) AR000776A1 (enExample)
AU (1) AU700256B2 (enExample)
BG (1) BG100904A (enExample)
BR (1) BR9606373A (enExample)
CA (1) CA2186232A1 (enExample)
CZ (1) CZ309596A3 (enExample)
DE (1) DE69617543T3 (enExample)
ES (1) ES2167539T5 (enExample)
FI (1) FI963759A0 (enExample)
HU (1) HUP9602907A3 (enExample)
IL (1) IL116853A (enExample)
IT (1) IT1272923B (enExample)
MX (1) MX9604229A (enExample)
PL (1) PL185055B1 (enExample)
RU (1) RU2177948C2 (enExample)
TR (1) TR199600720T1 (enExample)
TW (1) TW319777B (enExample)
WO (1) WO1996022995A1 (enExample)
ZA (1) ZA96485B (enExample)

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US20030120015A1 (en) 2003-06-26
EP0751946B1 (en) 2001-12-05
ES2167539T3 (es) 2002-05-16
AR000776A1 (es) 1997-08-06
ZA96485B (en) 1996-08-13
CN1150430A (zh) 1997-05-21
DE69617543T2 (de) 2002-08-01
KR970701723A (ko) 1997-04-12
ITMI950099A1 (it) 1996-07-23
CN1196721C (zh) 2005-04-13
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TR199600720T1 (tr) 1997-03-21
EP0751946A1 (en) 1997-01-08
CN1355256A (zh) 2002-06-26
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