CZ309596A3 - Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization - Google Patents

Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization Download PDF

Info

Publication number
CZ309596A3
CZ309596A3 CZ963095A CZ309596A CZ309596A3 CZ 309596 A3 CZ309596 A3 CZ 309596A3 CZ 963095 A CZ963095 A CZ 963095A CZ 309596 A CZ309596 A CZ 309596A CZ 309596 A3 CZ309596 A3 CZ 309596A3
Authority
CZ
Czechia
Prior art keywords
substituents
metallocene compound
bis
formula
aryl
Prior art date
Application number
CZ963095A
Other languages
Czech (cs)
English (en)
Inventor
Luigi Resconi
Fabrizio Piemontesi
Ev Ilya E Nifant
Pavel V Ivchenko
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CZ309596(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Publication of CZ309596A3 publication Critical patent/CZ309596A3/cs

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CZ963095A 1995-01-23 1996-01-17 Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization CZ309596A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
CZ309596A3 true CZ309596A3 (en) 1997-04-16

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
CZ963095A CZ309596A3 (en) 1995-01-23 1996-01-17 Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization

Country Status (24)

Country Link
US (3) US6051728A (enExample)
EP (1) EP0751946B2 (enExample)
JP (1) JP3838662B2 (enExample)
KR (2) KR100414759B1 (enExample)
CN (2) CN1075076C (enExample)
AR (1) AR000776A1 (enExample)
AU (1) AU700256B2 (enExample)
BG (1) BG100904A (enExample)
BR (1) BR9606373A (enExample)
CA (1) CA2186232A1 (enExample)
CZ (1) CZ309596A3 (enExample)
DE (1) DE69617543T3 (enExample)
ES (1) ES2167539T5 (enExample)
FI (1) FI963759L (enExample)
HU (1) HUP9602907A3 (enExample)
IL (1) IL116853A (enExample)
IT (1) IT1272923B (enExample)
MX (1) MX9604229A (enExample)
PL (1) PL185055B1 (enExample)
RU (1) RU2177948C2 (enExample)
TR (1) TR199600720T1 (enExample)
TW (1) TW319777B (enExample)
WO (1) WO1996022995A1 (enExample)
ZA (1) ZA96485B (enExample)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
AU733813B2 (en) * 1996-11-15 2001-05-24 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
ES2203965T3 (es) * 1997-03-29 2004-04-16 Basell Polyolefine Gmbh Metalocenos y catalizadores para la polimerizacion de olefinas.
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
KR20010014072A (ko) 1998-04-21 2001-02-26 간디 지오프레이 에이치. 에틸렌과 알파-올레핀의 공중합체의 제조 방법
MXPA00002181A (es) * 1998-07-02 2003-04-22 Montell Technology Company Bv Procedimiento para la preparacion de polimeros de alfa-olefinas sustancialmente amorfos composiciones que los contienen, y procedimiento para la preparacion de ligandos puenteados.
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
CA2370799A1 (en) 2000-02-24 2001-08-30 Basell Technology Company Bv Organometallic compound useful as cocatalyst for polymerizing olefins
ES2223832T3 (es) 2000-03-22 2005-03-01 Basell Polyolefine Gmbh Procedimiento para la preparacion de composiciones termoplasticas de propileno isotactico y polipropileno flexible de isotacticidad inferior.
EP1222216B1 (en) * 2000-05-24 2004-12-29 Basell Polyolefine GmbH Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
JP2004516363A (ja) 2000-12-22 2004-06-03 バセル ポリオレフィン ジーエムビーエイチ オレフィンの重合用触媒成分
US7183332B2 (en) 2000-12-22 2007-02-27 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
WO2002102811A1 (en) 2001-05-21 2002-12-27 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
US7060765B2 (en) 2001-07-19 2006-06-13 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
ES2361734T3 (es) * 2001-07-19 2011-06-21 Univation Technologies Llc Películas de polietileno con propiedades físicas mejoradas.
JP4020862B2 (ja) * 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
WO2003046022A1 (en) 2001-11-27 2003-06-05 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
KR100921365B1 (ko) 2002-06-26 2009-10-15 바셀 폴리올레핀 이탈리아 에스.알.엘 내충격성 폴리올레핀 조성물
MXPA04012699A (es) * 2002-06-26 2005-03-23 Basell Poliolefine Spa Composiciones de poliolefina resistentes a impactos.
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
US7569647B2 (en) * 2002-10-10 2009-08-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
BR0315341B1 (pt) 2002-10-15 2014-02-18 Adesivos compreendendo poliolefina.
CN100362025C (zh) 2003-04-17 2008-01-16 巴塞尔聚烯烃意大利有限责任公司 气相烯烃聚合方法
US7122606B2 (en) 2003-07-04 2006-10-17 Basell Polyolefine Gmbh Olefin polymerization process
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
CN101001892A (zh) 2004-03-12 2007-07-18 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的催化剂体系
EP1723184A1 (en) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ 1−ヘキセンまたは高級α−オレフィンの重合方法
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
CN101061142B (zh) 2004-11-22 2012-04-18 巴塞尔聚烯烃股份有限公司 基于丙烯的三元共聚物
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
WO2009077185A1 (en) 2007-12-18 2009-06-25 Basell Polyolefine Gmbh Gas-phase process for the polymerization of alpha-olefins
CN101910225B (zh) * 2008-01-11 2014-06-04 三井化学株式会社 改性丙烯树脂
JP5263845B2 (ja) * 2008-02-29 2013-08-14 サンアロマー株式会社 ポリオレフィン組成物
US8637625B2 (en) 2008-11-18 2014-01-28 Borealis Ag Propylene-butene random copolymer produced in the presence of a metallocene catalyst
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN105555813B (zh) * 2013-09-30 2018-01-05 株式会社Lg化学 丙烯‑1‑丁烯共聚物的制备方法以及由此获得的丙烯‑1‑丁烯共聚物
US10450390B2 (en) 2014-12-15 2019-10-22 Lg Chem, Ltd. Metallocene compound, metallocene-supported catalyst, and method of preparing polyolefin using the same
KR101826253B1 (ko) * 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
BR112019011558B1 (pt) * 2016-12-05 2023-01-17 Exxonmobil Chemical Patents Inc Polietilenos de metaloceno que compreende unidades derivadas de etileno, seu processo de formação e películas
WO2019072695A1 (en) 2017-10-11 2019-04-18 Basell Polyolefine Gmbh CATALYST SUPPORTED SYSTEM

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
DE3751694T2 (de) * 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
ATE166890T1 (de) * 1988-12-26 1998-06-15 Mitsui Chemicals Inc Olefin-kopolymer und verfahren zur herstellung
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
ES2155492T3 (es) * 1991-05-27 2001-05-16 Basell Polyolefine Gmbh Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares.
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (enExample) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
TW272985B (enExample) * 1992-09-11 1996-03-21 Hoechst Ag
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Also Published As

Publication number Publication date
PL185055B1 (pl) 2003-02-28
CA2186232A1 (en) 1996-08-01
EP0751946B1 (en) 2001-12-05
AU4536696A (en) 1996-08-14
TW319777B (enExample) 1997-11-11
FI963759A0 (fi) 1996-09-20
CN1150430A (zh) 1997-05-21
JP3838662B2 (ja) 2006-10-25
RU2177948C2 (ru) 2002-01-10
CN1075076C (zh) 2001-11-21
IT1272923B (it) 1997-07-01
ZA96485B (en) 1996-08-13
IL116853A (en) 2000-09-28
PL316387A1 (en) 1997-01-06
WO1996022995A1 (en) 1996-08-01
US20030120015A1 (en) 2003-06-26
FI963759A7 (fi) 1996-09-20
JPH09510994A (ja) 1997-11-04
ES2167539T5 (es) 2007-04-01
US6051728A (en) 2000-04-18
ES2167539T3 (es) 2002-05-16
ITMI950099A0 (it) 1995-01-23
CN1355256A (zh) 2002-06-26
KR970701723A (ko) 1997-04-12
IL116853A0 (en) 1996-07-23
DE69617543T2 (de) 2002-08-01
KR100414759B1 (ko) 2004-01-13
EP0751946A1 (en) 1997-01-08
ITMI950099A1 (it) 1996-07-23
HUP9602907A3 (en) 1997-12-29
BG100904A (bg) 1997-07-31
US6518386B1 (en) 2003-02-11
HUP9602907A2 (en) 1997-05-28
FI963759L (fi) 1996-09-20
AR000776A1 (es) 1997-08-06
CN1196721C (zh) 2005-04-13
AU700256B2 (en) 1998-12-24
DE69617543T3 (de) 2007-01-18
TR199600720T1 (tr) 1997-03-21
KR100418106B1 (ko) 2004-04-30
EP0751946B2 (en) 2006-08-09
DE69617543D1 (de) 2002-01-17
MX9604229A (es) 1997-12-31
BR9606373A (pt) 2004-06-29

Similar Documents

Publication Publication Date Title
US6518386B1 (en) Metallocene compounds, process for their preparation thereof, and their use in catalysts for the polymerization of olefins
RU2362779C2 (ru) Металлоорганическое соединение переходного металла, бисциклопентадиенильная лигандная система, каталитическая система и получение полиолефинов
US5459117A (en) Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
JP3946282B2 (ja) プロピレンのエチレンとのアモルファスコポリマー
JP5584639B2 (ja) 1−ブテンの重合方法
CA2257177A1 (en) Metallocenes and catalysts for polymerization of olefins
JP2000511156A (ja) 開放ペンタジエニルメタロセン類、その前駆物質とそれからの重合触媒
EP1877453A1 (en) Process for the polymerization of alpha olefins
KR20100024433A (ko) 1-부텐 에틸렌 공중합체
EP0979247B1 (en) Process for producing isotactic polypropylenes in condensed phase using titanocenes
KR101139268B1 (ko) 유기금속 전이 금속 화합물, 비스시클로펜타디에닐 리간드계, 촉매 계 및 폴리올레핀 제조
KR101665076B1 (ko) 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법
JP2004534829A (ja) メタロセン、オレフィンポリマー製造用の触媒系における使用
JP3095754B2 (ja) プロピレン‐イソブロック共重合体、その製造方法およびそれに使用される触媒
JPH1180183A (ja) 重合用金属化合物及びそれを用いた芳香族ビニル化合物−オレフィン共重合体の製造方法
JP3154511B2 (ja) シンジオタクチックポリプロピレンの製造方法
WO2010077163A1 (en) Synthesis of substituted tetrahydroindenyl complexes, metallocenes produced therefrom and use of the metallocenes in polymerisation processes
JP2001288221A (ja) プロピレン重合体
KR20230072858A (ko) 폴리프로필렌 공중합체 제조방법
JP2002047313A (ja) プロピレン重合体
US20020032342A1 (en) Novel metallocene catalyst and process for preparing styrenic polymer using the same

Legal Events

Date Code Title Description
PD00 Pending as of 2000-06-30 in czech republic