TW319777B - - Google Patents
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- Publication number
- TW319777B TW319777B TW085102169A TW85102169A TW319777B TW 319777 B TW319777 B TW 319777B TW 085102169 A TW085102169 A TW 085102169A TW 85102169 A TW85102169 A TW 85102169A TW 319777 B TW319777 B TW 319777B
- Authority
- TW
- Taiwan
- Prior art keywords
- patent application
- compound
- item
- substituent
- group
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW319777B true TW319777B (enExample) | 1997-11-11 |
Family
ID=11370281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW085102169A TW319777B (enExample) | 1995-01-23 | 1996-02-26 |
Country Status (24)
| Country | Link |
|---|---|
| US (3) | US6051728A (enExample) |
| EP (1) | EP0751946B2 (enExample) |
| JP (1) | JP3838662B2 (enExample) |
| KR (2) | KR100418106B1 (enExample) |
| CN (2) | CN1075076C (enExample) |
| AR (1) | AR000776A1 (enExample) |
| AU (1) | AU700256B2 (enExample) |
| BG (1) | BG100904A (enExample) |
| BR (1) | BR9606373A (enExample) |
| CA (1) | CA2186232A1 (enExample) |
| CZ (1) | CZ309596A3 (enExample) |
| DE (1) | DE69617543T3 (enExample) |
| ES (1) | ES2167539T5 (enExample) |
| FI (1) | FI963759L (enExample) |
| HU (1) | HUP9602907A3 (enExample) |
| IL (1) | IL116853A (enExample) |
| IT (1) | IT1272923B (enExample) |
| MX (1) | MX9604229A (enExample) |
| PL (1) | PL185055B1 (enExample) |
| RU (1) | RU2177948C2 (enExample) |
| TR (1) | TR199600720T1 (enExample) |
| TW (1) | TW319777B (enExample) |
| WO (1) | WO1996022995A1 (enExample) |
| ZA (1) | ZA96485B (enExample) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
| DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
| JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
| DE19644039A1 (de) * | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocene |
| HUP9904527A2 (hu) * | 1996-11-15 | 2000-05-28 | Montell Technology Company B.V. | Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok |
| US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
| IL127229A0 (en) * | 1997-03-29 | 1999-09-22 | Montell Technology Company Bv | Metallocenes and catalysts for polymerization of olefins |
| AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
| DE19748388A1 (de) * | 1997-11-03 | 1999-05-06 | Borealis Polymere Holding Gmbh | Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation |
| KR20010014072A (ko) | 1998-04-21 | 2001-02-26 | 간디 지오프레이 에이치. | 에틸렌과 알파-올레핀의 공중합체의 제조 방법 |
| MXPA00002181A (es) | 1998-07-02 | 2003-04-22 | Montell Technology Company Bv | Procedimiento para la preparacion de polimeros de alfa-olefinas sustancialmente amorfos composiciones que los contienen, y procedimiento para la preparacion de ligandos puenteados. |
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| RU2248980C2 (ru) | 2000-02-24 | 2005-03-27 | Базелль Текнолоджи Компани Б.В. | Металлоорганическое соединение, пригодное в качестве сокатализатора для полимеризации олефинов |
| TR200103338T1 (tr) | 2000-03-22 | 2002-07-22 | Basell Technology Company Bv | İsotaktik propilen polimerlerin termoplastik bileşimleri. |
| DE60108062T2 (de) * | 2000-05-24 | 2005-06-02 | Basell Polyolefine Gmbh | Propylenpolymere und verfahren zur ihrer herstellung |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| US6703458B2 (en) | 2000-12-22 | 2004-03-09 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
| EP1355958A2 (en) | 2000-12-22 | 2003-10-29 | Basell Poliolefine Italia S.p.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
| JP4173803B2 (ja) | 2001-05-21 | 2008-10-29 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合用触媒系 |
| US7060765B2 (en) | 2001-07-19 | 2006-06-13 | Univation Technologies, Llc | Low comonomer incorporating metallocene catalyst compounds |
| EP1412420B1 (en) | 2001-07-19 | 2011-03-30 | Univation Technologies LLC | Polyethylene films with improved physical properties |
| US6936675B2 (en) | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| CZ2004246A3 (cs) | 2001-07-19 | 2004-11-10 | Univation Technologies, Llc A Delaware Company | Směsné metalocenové katalytické systémy obsahující složku slabě začleňující komonomer a složku dobře začleňující komonomer |
| JP2005510590A (ja) | 2001-11-27 | 2005-04-21 | バセル ポリオレフィン ジーエムビーエイチ | ポリマー組成物の処理の方法 |
| RU2214415C1 (ru) * | 2002-05-13 | 2003-10-20 | Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" | Способ получения галогенидов металлоценов (варианты) |
| US7572859B2 (en) | 2002-06-26 | 2009-08-11 | Basell Polyolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
| CN100354356C (zh) * | 2002-06-26 | 2007-12-12 | 巴塞尔聚烯烃意大利有限公司 | 抗冲击聚烯烃组合物 |
| US7449246B2 (en) * | 2004-06-30 | 2008-11-11 | General Electric Company | Barrier coatings |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| AU2003304716A1 (en) * | 2002-10-15 | 2005-11-25 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| BRPI0409738B1 (pt) | 2003-04-17 | 2014-01-21 | Processo contínuo para a polimerização de olefinas em um reator de leito fluidizado | |
| KR101167877B1 (ko) | 2003-07-04 | 2012-07-23 | 바젤 폴리올레핀 게엠베하 | 올레핀 중합 방법 |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
| EP1723184A1 (en) | 2004-03-12 | 2006-11-22 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1735355B1 (en) | 2004-03-12 | 2010-09-29 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| CN101001892A (zh) | 2004-03-12 | 2007-07-18 | 巴塞尔聚烯烃股份有限公司 | 用于烯烃聚合的催化剂体系 |
| EP1655314A1 (en) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| US7300994B2 (en) * | 2004-11-22 | 2007-11-27 | Cornell Research Foundation, Inc. | Isotactic polypropylene containing polymers |
| CN101061142B (zh) | 2004-11-22 | 2012-04-18 | 巴塞尔聚烯烃股份有限公司 | 基于丙烯的三元共聚物 |
| US20080160862A1 (en) * | 2004-12-13 | 2008-07-03 | Basell Poliolefine Italia S.R.L. | Polyolefin Composition, Fibres and Nonwoven Fabrics |
| CN101087905B (zh) * | 2004-12-23 | 2010-12-15 | 巴塞尔聚烯烃意大利有限责任公司 | 具有弹性的纤维 |
| US7026494B1 (en) | 2005-01-10 | 2006-04-11 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high melt index polymers without the use of hydrogen |
| US8084557B2 (en) | 2007-12-18 | 2011-12-27 | Basell Polyolefine Gmbh | Gas-phase process for the polymerization of alpha-olefins |
| US20100280153A1 (en) * | 2008-01-11 | 2010-11-04 | Keita Itakura | Modified propylene resin |
| BRPI0908411B1 (pt) * | 2008-02-29 | 2018-10-30 | Basell Poliolefine Italia Srl | composições de poliolefinas |
| WO2010057841A1 (en) * | 2008-11-18 | 2010-05-27 | Borealis Ag | Propylene-butene random copolymer produced in the presence of a mettalocene catalyst |
| EP2341086A1 (en) † | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
| EP3539993A1 (en) | 2013-07-17 | 2019-09-18 | ExxonMobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| CN105377904B (zh) | 2013-07-17 | 2018-07-10 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
| JP2016531978A (ja) | 2013-07-17 | 2016-10-13 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 置換メタロセン触媒 |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| EP3022236B1 (en) | 2013-07-17 | 2017-11-15 | ExxonMobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| CN105555813B (zh) * | 2013-09-30 | 2018-01-05 | 株式会社Lg化学 | 丙烯‑1‑丁烯共聚物的制备方法以及由此获得的丙烯‑1‑丁烯共聚物 |
| WO2016099117A1 (ko) | 2014-12-15 | 2016-06-23 | 주식회사 엘지화학 | 메탈로센 화합물, 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법 |
| KR101826253B1 (ko) * | 2015-07-15 | 2018-02-06 | 한화케미칼 주식회사 | 메탈로센 화합물 및 이의 제조방법 |
| JP7045377B2 (ja) * | 2016-12-05 | 2022-03-31 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 幅広い直交分布のフィルム用メタロセンポリエチレン |
| EP3694811B1 (en) | 2017-10-11 | 2024-04-03 | Basell Polyolefine GmbH | Supported catalyst system |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
| DE3751694T2 (de) * | 1987-04-03 | 1996-08-01 | Fina Technology | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE68929210T2 (de) * | 1988-12-26 | 2001-01-04 | Mitsui Chemicals, Inc. | Olefincopolymere und Verfahren zur Herstellung davon |
| DE3929693A1 (de) * | 1989-09-07 | 1991-03-14 | Hoechst Ag | Verfahren zur herstellung eines polyolefinwachses |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| IT1249008B (it) * | 1990-06-27 | 1995-02-11 | Himont Inc | Copolimeri cristallini sindiotattici del propilene |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| AU9159191A (en) * | 1990-12-28 | 1992-08-17 | Exxon Chemical Patents Inc. | Syndiotactic polypropylene |
| ES2087339T3 (es) * | 1991-05-27 | 1996-07-16 | Hoechst Ag | Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares. |
| JPH04351638A (ja) * | 1991-05-29 | 1992-12-07 | Toray Dow Corning Silicone Co Ltd | ヘキセニル基含有シリコーンレジンおよびその製造方法 |
| TW300901B (enExample) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5330948A (en) * | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| ATE177436T1 (de) * | 1992-08-15 | 1999-03-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen |
| TW272985B (enExample) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| EP0588208A3 (en) * | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
| JP3307704B2 (ja) * | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| CA2125246C (en) * | 1993-06-07 | 2001-07-03 | Junichi Imuta | Transition metal compound and olefin polymerization catalyst using the same |
| DE69427999T3 (de) * | 1993-06-07 | 2012-09-27 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| US5504223A (en) * | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
-
1995
- 1995-01-23 IT ITMI950099A patent/IT1272923B/it active IP Right Grant
-
1996
- 1996-01-17 KR KR1019960705230A patent/KR100418106B1/ko not_active Expired - Fee Related
- 1996-01-17 BR BR9606373-4A patent/BR9606373A/pt not_active IP Right Cessation
- 1996-01-17 MX MX9604229A patent/MX9604229A/es unknown
- 1996-01-17 PL PL96316387A patent/PL185055B1/pl not_active IP Right Cessation
- 1996-01-17 CZ CZ963095A patent/CZ309596A3/cs unknown
- 1996-01-17 KR KR10-2003-7010028A patent/KR100414759B1/ko not_active Expired - Fee Related
- 1996-01-17 ES ES96901285T patent/ES2167539T5/es not_active Expired - Lifetime
- 1996-01-17 RU RU96121252/04A patent/RU2177948C2/ru not_active IP Right Cessation
- 1996-01-17 DE DE69617543T patent/DE69617543T3/de not_active Expired - Lifetime
- 1996-01-17 CA CA002186232A patent/CA2186232A1/en not_active Abandoned
- 1996-01-17 CN CN96190226A patent/CN1075076C/zh not_active Expired - Fee Related
- 1996-01-17 WO PCT/EP1996/000171 patent/WO1996022995A1/en not_active Ceased
- 1996-01-17 JP JP52259496A patent/JP3838662B2/ja not_active Expired - Lifetime
- 1996-01-17 TR TR96/00720T patent/TR199600720T1/xx unknown
- 1996-01-17 AU AU45366/96A patent/AU700256B2/en not_active Ceased
- 1996-01-17 EP EP96901285A patent/EP0751946B2/en not_active Expired - Lifetime
- 1996-01-17 HU HU9602907A patent/HUP9602907A3/hu unknown
- 1996-01-17 FI FI963759A patent/FI963759L/fi unknown
- 1996-01-22 IL IL11685396A patent/IL116853A/xx not_active IP Right Cessation
- 1996-01-22 ZA ZA96485A patent/ZA96485B/xx unknown
- 1996-01-23 AR ARP960101110A patent/AR000776A1/es active IP Right Grant
- 1996-01-23 US US08/599,483 patent/US6051728A/en not_active Expired - Lifetime
- 1996-02-26 TW TW085102169A patent/TW319777B/zh active
- 1996-10-11 BG BG100904A patent/BG100904A/xx unknown
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2000
- 2000-01-11 US US09/481,047 patent/US6518386B1/en not_active Expired - Lifetime
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2001
- 2001-06-07 CN CNB011208953A patent/CN1196721C/zh not_active Expired - Fee Related
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2002
- 2002-10-11 US US10/269,699 patent/US20030120015A1/en not_active Abandoned
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