DE69617543D1 - Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung - Google Patents

Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung

Info

Publication number
DE69617543D1
DE69617543D1 DE69617543T DE69617543T DE69617543D1 DE 69617543 D1 DE69617543 D1 DE 69617543D1 DE 69617543 T DE69617543 T DE 69617543T DE 69617543 T DE69617543 T DE 69617543T DE 69617543 D1 DE69617543 D1 DE 69617543D1
Authority
DE
Germany
Prior art keywords
catalysts
production
olefin polymerization
metallocene compounds
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69617543T
Other languages
English (en)
Other versions
DE69617543T2 (de
DE69617543T3 (de
Inventor
Luigi Resconi
Fabrizio Piemontesi
Ev Ilya E Nifant
Pavel V Ivchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69617543(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Publication of DE69617543D1 publication Critical patent/DE69617543D1/de
Publication of DE69617543T2 publication Critical patent/DE69617543T2/de
Application granted granted Critical
Publication of DE69617543T3 publication Critical patent/DE69617543T3/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69617543T 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung Expired - Lifetime DE69617543T3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI950099 1995-01-23
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
PCT/EP1996/000171 WO1996022995A1 (en) 1995-01-23 1996-01-17 Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins

Publications (3)

Publication Number Publication Date
DE69617543D1 true DE69617543D1 (de) 2002-01-17
DE69617543T2 DE69617543T2 (de) 2002-08-01
DE69617543T3 DE69617543T3 (de) 2007-01-18

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69617543T Expired - Lifetime DE69617543T3 (de) 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung

Country Status (24)

Country Link
US (3) US6051728A (de)
EP (1) EP0751946B2 (de)
JP (1) JP3838662B2 (de)
KR (2) KR100418106B1 (de)
CN (2) CN1075076C (de)
AR (1) AR000776A1 (de)
AU (1) AU700256B2 (de)
BG (1) BG100904A (de)
BR (1) BR9606373A (de)
CA (1) CA2186232A1 (de)
CZ (1) CZ309596A3 (de)
DE (1) DE69617543T3 (de)
ES (1) ES2167539T5 (de)
FI (1) FI963759L (de)
HU (1) HUP9602907A3 (de)
IL (1) IL116853A (de)
IT (1) IT1272923B (de)
MX (1) MX9604229A (de)
PL (1) PL185055B1 (de)
RU (1) RU2177948C2 (de)
TR (1) TR199600720T1 (de)
TW (1) TW319777B (de)
WO (1) WO1996022995A1 (de)
ZA (1) ZA96485B (de)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
TR199901635T2 (xx) * 1996-11-15 2000-02-21 Montell Technology Company Bv Heterosiklik metalosenler ve polimerizasyon kataliz�rleri.
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
JP4169791B2 (ja) * 1997-03-29 2008-10-22 バセル テクノロジー カンパニー ベスローテン フェンノートシャップ オレフィン重合用メタロセンと触媒
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
US6448350B1 (en) 1998-04-21 2002-09-10 Basell Technology Company Bv Process for the preparation of copolymers of ethylene with alpha-olefins
KR20010023577A (ko) * 1998-07-02 2001-03-26 간디 지오프레이 에이치. 실질적으로 무정형인 알파-올레핀 중합체의 제조 방법 및이를 함유하는 조성물 및 가교된 리간드의 제조방법
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP1173445B1 (de) 2000-02-24 2004-06-09 Basell Polyolefine GmbH Organometallische verbindung die als cokatalysator bei der polymerisation von olefinen verwendbar ist
CN1162454C (zh) 2000-03-22 2004-08-18 巴塞尔技术有限公司 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法
WO2001090205A1 (en) 2000-05-24 2001-11-29 Basell Technology Company B.V. Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
WO2002051887A2 (en) 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
DE60202524T2 (de) 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
AR034829A1 (es) * 2001-07-19 2004-03-17 Univation Tech Llc Sistemas catalizadores de metaloceno mezclados que contienen un incorporador pobre de comonomeros y un buen incorporador de comonomeros
JP4221363B2 (ja) 2001-07-19 2009-02-12 ユニベーション・テクノロジーズ・エルエルシー 物性が向上したポリエチレンフィルム
BR0211290A (pt) 2001-07-19 2004-09-14 Univation Tech Llc Compostos de catalisador de metaloceno de baixa incorporação de comonÈmero
WO2003046022A1 (en) 2001-11-27 2003-06-05 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
MXPA04012699A (es) * 2002-06-26 2005-03-23 Basell Poliolefine Spa Composiciones de poliolefina resistentes a impactos.
RU2308470C2 (ru) 2002-06-26 2007-10-20 Базелль Полиолефин Италия С.П.А. Ударопрочные полиолефиновые композиции
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
EP1549688A2 (de) * 2002-10-10 2005-07-06 Basell Polyolefine GmbH Verfahren zur copolymerisation von ethylen
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ES2394304T3 (es) * 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
WO2004092228A1 (en) 2003-04-17 2004-10-28 Basell Poliolefine Italia S.R.L. Gas-phase olefin polymerization process
JP4709748B2 (ja) 2003-07-04 2011-06-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合方法
EP1564226A1 (de) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Katalysatorsystem auf Basis von Titanocene
KR20070004712A (ko) 2004-03-12 2007-01-09 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매 시스템
EP1723184A1 (de) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
EP1735355B1 (de) 2004-03-12 2010-09-29 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
EP1655314A1 (de) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Polymerisationsverfahren von 1-buten mit propen
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
US8101695B2 (en) 2004-11-22 2012-01-24 Basell Polyolefine Gmbh Propylene based terpolymers
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
US8084557B2 (en) 2007-12-18 2011-12-27 Basell Polyolefine Gmbh Gas-phase process for the polymerization of alpha-olefins
CN101910225B (zh) * 2008-01-11 2014-06-04 三井化学株式会社 改性丙烯树脂
EP2247424B1 (de) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefinzusammensetzungen
US8637625B2 (en) 2008-11-18 2014-01-28 Borealis Ag Propylene-butene random copolymer produced in the presence of a metallocene catalyst
EP2341086A1 (de) † 2009-12-30 2011-07-06 Borealis AG BOPP-Folie
SG10201802959WA (en) * 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
EP3022238B1 (de) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN105555813B (zh) * 2013-09-30 2018-01-05 株式会社Lg化学 丙烯‑1‑丁烯共聚物的制备方法以及由此获得的丙烯‑1‑丁烯共聚物
WO2016099117A1 (ko) 2014-12-15 2016-06-23 주식회사 엘지화학 메탈로센 화합물, 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR101826253B1 (ko) 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
BR112019011558B1 (pt) * 2016-12-05 2023-01-17 Exxonmobil Chemical Patents Inc Polietilenos de metaloceno que compreende unidades derivadas de etileno, seu processo de formação e películas
US11518824B2 (en) 2017-10-11 2022-12-06 Basell Polyolefine Gmbh Supported catalyst system

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
DE3751694T2 (de) * 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
ATE166890T1 (de) * 1988-12-26 1998-06-15 Mitsui Chemicals Inc Olefin-kopolymer und verfahren zur herstellung
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
ES2090209T3 (es) * 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
AU9159191A (en) * 1990-12-28 1992-08-17 Exxon Chemical Patents Inc. Syndiotactic polypropylene
ES2087339T3 (es) * 1991-05-27 1996-07-16 Hoechst Ag Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares.
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
DE59309424D1 (de) * 1992-08-15 1999-04-15 Targor Gmbh Verfahren zur Herstellung von Polyolefinen
TW272985B (de) * 1992-09-11 1996-03-21 Hoechst Ag
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
EP0629631B1 (de) * 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Also Published As

Publication number Publication date
ITMI950099A0 (it) 1995-01-23
ZA96485B (en) 1996-08-13
FI963759A0 (fi) 1996-09-20
AR000776A1 (es) 1997-08-06
ITMI950099A1 (it) 1996-07-23
KR100418106B1 (ko) 2004-04-30
HUP9602907A3 (en) 1997-12-29
JPH09510994A (ja) 1997-11-04
FI963759A7 (fi) 1996-09-20
EP0751946B2 (de) 2006-08-09
MX9604229A (es) 1997-12-31
HUP9602907A2 (en) 1997-05-28
KR100414759B1 (ko) 2004-01-13
CN1355256A (zh) 2002-06-26
ES2167539T5 (es) 2007-04-01
AU4536696A (en) 1996-08-14
ES2167539T3 (es) 2002-05-16
IT1272923B (it) 1997-07-01
US6051728A (en) 2000-04-18
TR199600720T1 (tr) 1997-03-21
BG100904A (bg) 1997-07-31
DE69617543T2 (de) 2002-08-01
EP0751946B1 (de) 2001-12-05
RU2177948C2 (ru) 2002-01-10
US20030120015A1 (en) 2003-06-26
PL316387A1 (en) 1997-01-06
BR9606373A (pt) 2004-06-29
CN1075076C (zh) 2001-11-21
IL116853A (en) 2000-09-28
FI963759L (fi) 1996-09-20
IL116853A0 (en) 1996-07-23
AU700256B2 (en) 1998-12-24
DE69617543T3 (de) 2007-01-18
CZ309596A3 (en) 1997-04-16
KR970701723A (ko) 1997-04-12
JP3838662B2 (ja) 2006-10-25
PL185055B1 (pl) 2003-02-28
CN1196721C (zh) 2005-04-13
TW319777B (de) 1997-11-11
CA2186232A1 (en) 1996-08-01
US6518386B1 (en) 2003-02-11
CN1150430A (zh) 1997-05-21
EP0751946A1 (de) 1997-01-08
WO1996022995A1 (en) 1996-08-01

Similar Documents

Publication Publication Date Title
DE69617543D1 (de) Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung
ATE291030T1 (de) Substituierte metallocenverbindungen für olefinpolymerisationkatalysatorsystemen, deren zwischenverbindungen und verfahren zu ihrer herstellung
DE69617530D1 (de) Ziegler-Natta Katalysatoren mit Metallocenen für die Olefinpolymerisation
DE59104869D1 (de) 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
ATE206131T1 (de) Phosphonomonoesternnukleinsäuren, verfahren zu ihrer herstellung und ihre verwendung
DE69726841D1 (de) Heteroatomsubstituierte metallocene für olefipolymerisationkatalysatore un verfahren zu deren herstellung
DE69704356D1 (de) Syndiotaktische/isotaktische blockpolyolefinen, katalysatore und verfahren zu ihrer herstellung
DE59610595D1 (de) OLIGO-p-PHENYLEN-EINHEITEN ENTHALTENDE POLYMERE, VERFAHREN ZU IHRER HERSTELLUNG SOWIE IHRE VERWENDUNG
DE69321203D1 (de) Kohlenwasserstoffhydrobehandlungskatalysatoren und Verfahren zu ihrer Herstellung
DE69827617D1 (de) Verfahren zur herstellung von hochaktiven katalysatoren;die katalysatoren und ihre verwendung
DE59303987D1 (de) Katalysierte kationische lackbindemittel, verfahren zu ihrer herstellung und ihre verwendung
ATE161528T1 (de) Ceramidverbindungen, verfahren zu ihrer herstellung und ihre verwendung in der kosmetik oder der dermatologie
DE69524333D1 (de) Metallocen verbindungen und ihre verwendung in katalysatoren für die polymerisation von olefinen
DE59603491D1 (de) Wasserlösliche copolymerisate, die vernetzer einpolymerisiert enthalten, verfahren zu ihrer herstellung und ihre verwendung
DE59610224D1 (de) Katalysatoren auf Kupferbasis, Verfahren zu ihrer Herstellung sowie ihre Verwendung und ein Verfahren zur Herstellung von alkylhalogensilanen
DE69609186D1 (de) Verbrückte metallocenverbindungen, verfahren zu deren herstellung und deren verwendung als olefinpolymerisationskatalysator
DE69610302D1 (de) Einlagerungsverbindungen, verfahren zu ihrer herstellung und ihre verwendung insbesondere in der pyrotechnik
ATE210638T1 (de) Biphenylsulfonylcyanamide, verfahren zu ihrer herstellung und ihre verwendung als medikament
ATE172196T1 (de) 2- (2-alkoxy-6-trifluormethylpyrimidin-4-yl)- oxymethylen>-phenylessigsäurederivate, verfahren und zwischenprodukte zu ihrer herstellung und ihre verwendung
DE59600966D1 (de) Agglomerierte, feinteilige, vernetzte vinylimidazol-copolymerisate, verfahren zu ihrer herstellung und ihre verwendung
ATE262377T1 (de) Katalysatoren zur oxychlorierung von ethylen, verfahren zu ihrer herstellung, und oxychlorierungsverfahren
ATE200075T1 (de) Hydroximsäurederivate, verfahren zu ihrer herstellung und ihre verwendung als schädlingsbekämpfungsmittel und fungizide
DE60009582D1 (de) Hochwirksame und selektive Katalysatoren für die Herstellung von ungesättigten Nitrilen, Verfahren zu ihrer Verwendung
DE59610666D1 (de) Mehrlagenfolie, verfahren zu ihrer herstellung und ihre verwendung
DE69617713D1 (de) Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren

Legal Events

Date Code Title Description
8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings
8328 Change in the person/name/address of the agent

Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8327 Change in the person/name/address of the patent owner

Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE