DE69617543D1 - Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung - Google Patents
Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierungInfo
- Publication number
- DE69617543D1 DE69617543D1 DE69617543T DE69617543T DE69617543D1 DE 69617543 D1 DE69617543 D1 DE 69617543D1 DE 69617543 T DE69617543 T DE 69617543T DE 69617543 T DE69617543 T DE 69617543T DE 69617543 D1 DE69617543 D1 DE 69617543D1
- Authority
- DE
- Germany
- Prior art keywords
- catalysts
- production
- olefin polymerization
- metallocene compounds
- metallocene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950099 | 1995-01-23 | ||
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| PCT/EP1996/000171 WO1996022995A1 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE69617543D1 true DE69617543D1 (de) | 2002-01-17 |
| DE69617543T2 DE69617543T2 (de) | 2002-08-01 |
| DE69617543T3 DE69617543T3 (de) | 2007-01-18 |
Family
ID=11370281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69617543T Expired - Lifetime DE69617543T3 (de) | 1995-01-23 | 1996-01-17 | Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung |
Country Status (24)
| Country | Link |
|---|---|
| US (3) | US6051728A (de) |
| EP (1) | EP0751946B2 (de) |
| JP (1) | JP3838662B2 (de) |
| KR (2) | KR100414759B1 (de) |
| CN (2) | CN1075076C (de) |
| AR (1) | AR000776A1 (de) |
| AU (1) | AU700256B2 (de) |
| BG (1) | BG100904A (de) |
| BR (1) | BR9606373A (de) |
| CA (1) | CA2186232A1 (de) |
| CZ (1) | CZ309596A3 (de) |
| DE (1) | DE69617543T3 (de) |
| ES (1) | ES2167539T5 (de) |
| FI (1) | FI963759A0 (de) |
| HU (1) | HUP9602907A3 (de) |
| IL (1) | IL116853A (de) |
| IT (1) | IT1272923B (de) |
| MX (1) | MX9604229A (de) |
| PL (1) | PL185055B1 (de) |
| RU (1) | RU2177948C2 (de) |
| TR (1) | TR199600720T1 (de) |
| TW (1) | TW319777B (de) |
| WO (1) | WO1996022995A1 (de) |
| ZA (1) | ZA96485B (de) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
| DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
| JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
| DE19644039A1 (de) * | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocene |
| RU2194708C2 (ru) * | 1996-11-15 | 2002-12-20 | Монтелл Текнолоджи Компани Б.В. | Металлоцен, лиганд, каталитическая система, способ полимеризации |
| US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
| BR9804807A (pt) * | 1997-03-29 | 1999-08-17 | Montell Technology Company Bv | Compostos metalocenos e catalisadores para a polimeraza-Æo de olefinas |
| AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
| DE19748388A1 (de) * | 1997-11-03 | 1999-05-06 | Borealis Polymere Holding Gmbh | Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation |
| US6448350B1 (en) | 1998-04-21 | 2002-09-10 | Basell Technology Company Bv | Process for the preparation of copolymers of ethylene with alpha-olefins |
| JP2002519484A (ja) | 1998-07-02 | 2002-07-02 | モンテル テクノロジー カンパニー ビーブイ | 実質的非晶質α−オレフィンポリマーの製造法とそれを含有する組成物および橋状リガンドの製造法 |
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| AU783058B2 (en) | 2000-02-24 | 2005-09-22 | Basell Technology Company B.V. | Organometallic compound useful as cocatalyst for polymerizing olefins |
| CA2374007A1 (en) | 2000-03-22 | 2001-09-27 | Luigi Resconi | Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof |
| US6703457B2 (en) | 2000-05-24 | 2004-03-09 | Basell Polyolefine Gmbh | Propylene polymers and process for the preparation thereof |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| WO2002051887A2 (en) | 2000-12-22 | 2002-07-04 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
| WO2002051877A2 (en) | 2000-12-22 | 2002-07-04 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
| DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| EP1412400A2 (de) * | 2001-07-19 | 2004-04-28 | Univation Technologies LLC | Gemischte metallocenkatalysatorsysteme mit schnellem und langsamen komonomereinbau |
| US6936675B2 (en) | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| ATE503792T1 (de) * | 2001-07-19 | 2011-04-15 | Univation Tech Llc | Polyethylenfilme mit verbesserten physikalischen eigenschaften |
| JP2004536183A (ja) | 2001-07-19 | 2004-12-02 | ユニベーション・テクノロジーズ・エルエルシー | コモノマー低結合性メタロセン触媒化合物 |
| EP1448624A1 (de) | 2001-11-27 | 2004-08-25 | Basell Polyolefine GmbH | Verfahren zur herstellung von polymerzusammensetzungen |
| RU2214415C1 (ru) * | 2002-05-13 | 2003-10-20 | Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" | Способ получения галогенидов металлоценов (варианты) |
| US7700690B2 (en) * | 2002-06-26 | 2010-04-20 | Basell Poliolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
| PL372195A1 (en) | 2002-06-26 | 2005-07-11 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| US7449246B2 (en) * | 2004-06-30 | 2008-11-11 | General Electric Company | Barrier coatings |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| BRPI0409738B1 (pt) | 2003-04-17 | 2014-01-21 | Processo contínuo para a polimerização de olefinas em um reator de leito fluidizado | |
| US7122606B2 (en) | 2003-07-04 | 2006-10-17 | Basell Polyolefine Gmbh | Olefin polymerization process |
| EP1564226A1 (de) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Katalysatorsystem auf Basis von Titanocene |
| CN101001892A (zh) | 2004-03-12 | 2007-07-18 | 巴塞尔聚烯烃股份有限公司 | 用于烯烃聚合的催化剂体系 |
| ATE482983T1 (de) | 2004-03-12 | 2010-10-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen |
| US7943716B2 (en) | 2004-03-12 | 2011-05-17 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1655314A1 (de) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Polymerisationsverfahren von 1-buten mit propen |
| US7300994B2 (en) * | 2004-11-22 | 2007-11-27 | Cornell Research Foundation, Inc. | Isotactic polypropylene containing polymers |
| EP1814922A1 (de) | 2004-11-22 | 2007-08-08 | Basell Polyolefine GmbH | Propylenbasierte terpolymere |
| EP1825036A1 (de) * | 2004-12-13 | 2007-08-29 | Basell Poliolefine Italia S.r.l. | Polyolefinzusammensetzung, fasern und vliesstoffe |
| ATE414804T1 (de) * | 2004-12-23 | 2008-12-15 | Basell Poliolefine Srl | Fasern mit elastischen eigenschaften |
| US7026494B1 (en) | 2005-01-10 | 2006-04-11 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high melt index polymers without the use of hydrogen |
| ATE519788T1 (de) | 2007-12-18 | 2011-08-15 | Basell Polyolefine Gmbh | Gasphasenverfahren zur polymerisation von alpha- olefinen |
| CN101910225B (zh) * | 2008-01-11 | 2014-06-04 | 三井化学株式会社 | 改性丙烯树脂 |
| KR101580849B1 (ko) * | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| US8637625B2 (en) | 2008-11-18 | 2014-01-28 | Borealis Ag | Propylene-butene random copolymer produced in the presence of a metallocene catalyst |
| EP2341086A1 (de) † | 2009-12-30 | 2011-07-06 | Borealis AG | BOPP-Folie |
| US9834628B2 (en) | 2013-07-17 | 2017-12-05 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| CN110845546A (zh) | 2013-07-17 | 2020-02-28 | 埃克森美孚化学专利公司 | 取代的茂金属催化剂 |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| EP3022238B1 (de) | 2013-07-17 | 2017-09-20 | ExxonMobil Chemical Patents Inc. | Metallocene und katalysatorzusammensetzungen daraus |
| WO2015009480A1 (en) * | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| US9587053B2 (en) * | 2013-09-30 | 2017-03-07 | Lg Chem, Ltd. | Preparation method of a propylene-1-butene copolymer and a propylene-1-butene copolymer obtained therefrom |
| JP6440832B2 (ja) * | 2014-12-15 | 2018-12-19 | エルジー・ケム・リミテッド | メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 |
| KR101826253B1 (ko) * | 2015-07-15 | 2018-02-06 | 한화케미칼 주식회사 | 메탈로센 화합물 및 이의 제조방법 |
| CN110167974B (zh) * | 2016-12-05 | 2021-12-10 | 埃克森美孚化学专利公司 | 用于膜的宽正交分布茂金属聚乙烯 |
| US11518824B2 (en) | 2017-10-11 | 2022-12-06 | Basell Polyolefine Gmbh | Supported catalyst system |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
| ATE133690T1 (de) * | 1987-04-03 | 1996-02-15 | Fina Technology | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE68929006T2 (de) * | 1988-12-26 | 1999-10-07 | Mitsui Chemicals, Inc. | Olefincopolymere und Verfahren zur Herstellung davon |
| DE3929693A1 (de) * | 1989-09-07 | 1991-03-14 | Hoechst Ag | Verfahren zur herstellung eines polyolefinwachses |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| IT1249008B (it) * | 1990-06-27 | 1995-02-11 | Himont Inc | Copolimeri cristallini sindiotattici del propilene |
| DE59104869D1 (de) * | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
| EP0485821B1 (de) * | 1990-11-12 | 1996-06-12 | Hoechst Aktiengesellschaft | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| AU9159191A (en) * | 1990-12-28 | 1992-08-17 | Exxon Chemical Patents Inc. | Syndiotactic polypropylene |
| DE59209897D1 (de) * | 1991-05-27 | 2001-04-26 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung |
| JPH04351638A (ja) * | 1991-05-29 | 1992-12-07 | Toray Dow Corning Silicone Co Ltd | ヘキセニル基含有シリコーンレジンおよびその製造方法 |
| TW300901B (de) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5330948A (en) * | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| DE59309424D1 (de) * | 1992-08-15 | 1999-04-15 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen |
| TW272985B (de) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| EP0588208A3 (en) * | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
| JP3307704B2 (ja) * | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| EP1209165B1 (de) * | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylenelastomere |
| DE69426043T3 (de) * | 1993-06-07 | 2015-06-18 | Mitsui Chemicals, Inc. | Polypropylen |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| US5504223A (en) * | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
-
1995
- 1995-01-23 IT ITMI950099A patent/IT1272923B/it active IP Right Grant
-
1996
- 1996-01-17 WO PCT/EP1996/000171 patent/WO1996022995A1/en not_active Ceased
- 1996-01-17 FI FI963759A patent/FI963759A0/fi unknown
- 1996-01-17 CZ CZ963095A patent/CZ309596A3/cs unknown
- 1996-01-17 HU HU9602907A patent/HUP9602907A3/hu unknown
- 1996-01-17 PL PL96316387A patent/PL185055B1/pl not_active IP Right Cessation
- 1996-01-17 MX MX9604229A patent/MX9604229A/es unknown
- 1996-01-17 EP EP96901285A patent/EP0751946B2/de not_active Expired - Lifetime
- 1996-01-17 AU AU45366/96A patent/AU700256B2/en not_active Ceased
- 1996-01-17 RU RU96121252/04A patent/RU2177948C2/ru not_active IP Right Cessation
- 1996-01-17 JP JP52259496A patent/JP3838662B2/ja not_active Expired - Lifetime
- 1996-01-17 KR KR10-2003-7010028A patent/KR100414759B1/ko not_active Expired - Fee Related
- 1996-01-17 ES ES96901285T patent/ES2167539T5/es not_active Expired - Lifetime
- 1996-01-17 BR BR9606373-4A patent/BR9606373A/pt not_active IP Right Cessation
- 1996-01-17 TR TR96/00720T patent/TR199600720T1/xx unknown
- 1996-01-17 CN CN96190226A patent/CN1075076C/zh not_active Expired - Fee Related
- 1996-01-17 KR KR1019960705230A patent/KR100418106B1/ko not_active Expired - Fee Related
- 1996-01-17 DE DE69617543T patent/DE69617543T3/de not_active Expired - Lifetime
- 1996-01-17 CA CA002186232A patent/CA2186232A1/en not_active Abandoned
- 1996-01-22 ZA ZA96485A patent/ZA96485B/xx unknown
- 1996-01-22 IL IL11685396A patent/IL116853A/xx not_active IP Right Cessation
- 1996-01-23 US US08/599,483 patent/US6051728A/en not_active Expired - Lifetime
- 1996-01-23 AR ARP960101110A patent/AR000776A1/es active IP Right Grant
- 1996-02-26 TW TW085102169A patent/TW319777B/zh active
- 1996-10-11 BG BG100904A patent/BG100904A/xx unknown
-
2000
- 2000-01-11 US US09/481,047 patent/US6518386B1/en not_active Expired - Lifetime
-
2001
- 2001-06-07 CN CNB011208953A patent/CN1196721C/zh not_active Expired - Fee Related
-
2002
- 2002-10-11 US US10/269,699 patent/US20030120015A1/en not_active Abandoned
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69617543D1 (de) | Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung | |
| ATE291030T1 (de) | Substituierte metallocenverbindungen für olefinpolymerisationkatalysatorsystemen, deren zwischenverbindungen und verfahren zu ihrer herstellung | |
| DE69617530D1 (de) | Ziegler-Natta Katalysatoren mit Metallocenen für die Olefinpolymerisation | |
| DE59104869D1 (de) | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. | |
| ATE206131T1 (de) | Phosphonomonoesternnukleinsäuren, verfahren zu ihrer herstellung und ihre verwendung | |
| DE69726841D1 (de) | Heteroatomsubstituierte metallocene für olefipolymerisationkatalysatore un verfahren zu deren herstellung | |
| DE69704356D1 (de) | Syndiotaktische/isotaktische blockpolyolefinen, katalysatore und verfahren zu ihrer herstellung | |
| DE59610595D1 (de) | OLIGO-p-PHENYLEN-EINHEITEN ENTHALTENDE POLYMERE, VERFAHREN ZU IHRER HERSTELLUNG SOWIE IHRE VERWENDUNG | |
| DE69321203D1 (de) | Kohlenwasserstoffhydrobehandlungskatalysatoren und Verfahren zu ihrer Herstellung | |
| DE69827617D1 (de) | Verfahren zur herstellung von hochaktiven katalysatoren;die katalysatoren und ihre verwendung | |
| DE59303987D1 (de) | Katalysierte kationische lackbindemittel, verfahren zu ihrer herstellung und ihre verwendung | |
| DE59812458D1 (de) | Polymerstabilisierte metallkolloid-enhaltende katalysatoren, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren für brennstoffzellen | |
| ATE161528T1 (de) | Ceramidverbindungen, verfahren zu ihrer herstellung und ihre verwendung in der kosmetik oder der dermatologie | |
| DE69524333D1 (de) | Metallocen verbindungen und ihre verwendung in katalysatoren für die polymerisation von olefinen | |
| DE59603491D1 (de) | Wasserlösliche copolymerisate, die vernetzer einpolymerisiert enthalten, verfahren zu ihrer herstellung und ihre verwendung | |
| DE59610224D1 (de) | Katalysatoren auf Kupferbasis, Verfahren zu ihrer Herstellung sowie ihre Verwendung und ein Verfahren zur Herstellung von alkylhalogensilanen | |
| DE69609186D1 (de) | Verbrückte metallocenverbindungen, verfahren zu deren herstellung und deren verwendung als olefinpolymerisationskatalysator | |
| DE69610302D1 (de) | Einlagerungsverbindungen, verfahren zu ihrer herstellung und ihre verwendung insbesondere in der pyrotechnik | |
| ATE210638T1 (de) | Biphenylsulfonylcyanamide, verfahren zu ihrer herstellung und ihre verwendung als medikament | |
| ATE172196T1 (de) | 2- (2-alkoxy-6-trifluormethylpyrimidin-4-yl)- oxymethylen>-phenylessigsäurederivate, verfahren und zwischenprodukte zu ihrer herstellung und ihre verwendung | |
| DE59600966D1 (de) | Agglomerierte, feinteilige, vernetzte vinylimidazol-copolymerisate, verfahren zu ihrer herstellung und ihre verwendung | |
| ATE262377T1 (de) | Katalysatoren zur oxychlorierung von ethylen, verfahren zu ihrer herstellung, und oxychlorierungsverfahren | |
| ATE200075T1 (de) | Hydroximsäurederivate, verfahren zu ihrer herstellung und ihre verwendung als schädlingsbekämpfungsmittel und fungizide | |
| DE60009582D1 (de) | Hochwirksame und selektive Katalysatoren für die Herstellung von ungesättigten Nitrilen, Verfahren zu ihrer Verwendung | |
| DE59610666D1 (de) | Mehrlagenfolie, verfahren zu ihrer herstellung und ihre verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8366 | Restricted maintained after opposition proceedings | ||
| 8328 | Change in the person/name/address of the agent |
Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN |
|
| 8327 | Change in the person/name/address of the patent owner |
Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE |