IT1272923B - Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine - Google Patents
Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefineInfo
- Publication number
- IT1272923B IT1272923B ITMI950099A ITMI950099A IT1272923B IT 1272923 B IT1272923 B IT 1272923B IT MI950099 A ITMI950099 A IT MI950099A IT MI950099 A ITMI950099 A IT MI950099A IT 1272923 B IT1272923 B IT 1272923B
- Authority
- IT
- Italy
- Prior art keywords
- olefins
- catalysts
- polymerization
- procedure
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (30)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| CA002186232A CA2186232A1 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
| HU9602907A HUP9602907A3 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their preparation, their use in catalysts for the polymerization of olefins, process for polymerization of olefins and propylene (co)polymer |
| CZ963095A CZ309596A3 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization |
| EP96901285A EP0751946B2 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
| KR10-2003-7010028A KR100414759B1 (ko) | 1995-01-23 | 1996-01-17 | 메탈로센 화합물, 이것의 제조 방법, 및 이것의 올레핀중합용 촉매로서의 용도 |
| PCT/EP1996/000171 WO1996022995A1 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
| PL96316387A PL185055B1 (pl) | 1995-01-23 | 1996-01-17 | Związki matalocenowe oraz homopolimery i kopolimery propylenowe |
| BR9606373-4A BR9606373A (pt) | 1995-01-23 | 1996-01-17 | Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas |
| RU96121252/04A RU2177948C2 (ru) | 1995-01-23 | 1996-01-17 | Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена |
| DE69617543T DE69617543T3 (de) | 1995-01-23 | 1996-01-17 | Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung |
| TR96/00720T TR199600720T1 (tr) | 1995-01-23 | 1996-01-17 | Metalosen bilesikleri, bunlarin hazirlanmasi icin islemler ve olefinlerin polimerizasyonu icin katalizörde kullanimlari. |
| FI963759A FI963759A0 (fi) | 1995-01-23 | 1996-01-17 | Metalloseeniyhdisteitä, menetelmä niiden valmistamiseksi ja niiden käyttö olefiinien polymerointiin tarkoitetuissa katalyyteissä |
| AU45366/96A AU700256B2 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
| JP52259496A JP3838662B2 (ja) | 1995-01-23 | 1996-01-17 | メタロセン化合物、その製造法及びオレフィン重合用触媒におけるその使用 |
| CN96190226A CN1075076C (zh) | 1995-01-23 | 1996-01-17 | 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 |
| KR1019960705230A KR100418106B1 (ko) | 1995-01-23 | 1996-01-17 | 메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도 |
| ES96901285T ES2167539T5 (es) | 1995-01-23 | 1996-01-17 | Compuestos de metaloceno, procedimiento para su preparacion y su empleo en catalizadores para la polimerizacion de olefinas. |
| MX9604229A MX9604229A (es) | 1995-01-23 | 1996-01-17 | Compuesto de metaloceno, procedimiento para su preparacion y su uso en catalizadores para la polimerizacion de olefinas. |
| ZA96485A ZA96485B (en) | 1995-01-23 | 1996-01-22 | Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins |
| IL11685396A IL116853A (en) | 1995-01-23 | 1996-01-22 | Metallocene compounds their preparation and use |
| US08/599,483 US6051728A (en) | 1995-01-23 | 1996-01-23 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
| ARP960101110A AR000776A1 (es) | 1995-01-23 | 1996-01-23 | Un compuesto metalocénico, proceso para prepararlo, un catalizador para la polimerización de olefinas obtenido mediante el mismo y un proceso de polimerización de olefinas, en particular propileno, mediante dicho catalizador. |
| TW085102169A TW319777B (enExample) | 1995-01-23 | 1996-02-26 | |
| NO963954A NO963954D0 (no) | 1995-01-23 | 1996-09-20 | Metallocen-forbindelser, fremgangsmåter for fremstilling, og anvendelse av disse ved polymerisering av olefiner |
| BG100904A BG100904A (bg) | 1995-01-23 | 1996-10-11 | Металоцени, метод за тяхното получаване, приложението им в катализатори за полимеризация на олефини |
| IL13392100A IL133921A0 (en) | 1995-01-23 | 2000-01-07 | A process for polymerization of olefins in the presence of metallocenes |
| US09/481,047 US6518386B1 (en) | 1995-01-23 | 2000-01-11 | Metallocene compounds, process for their preparation thereof, and their use in catalysts for the polymerization of olefins |
| CNB011208953A CN1196721C (zh) | 1995-01-23 | 2001-06-07 | 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 |
| US10/269,699 US20030120015A1 (en) | 1995-01-23 | 2002-10-11 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI950099A0 ITMI950099A0 (it) | 1995-01-23 |
| ITMI950099A1 ITMI950099A1 (it) | 1996-07-23 |
| IT1272923B true IT1272923B (it) | 1997-07-01 |
Family
ID=11370281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Country Status (24)
| Country | Link |
|---|---|
| US (3) | US6051728A (enExample) |
| EP (1) | EP0751946B2 (enExample) |
| JP (1) | JP3838662B2 (enExample) |
| KR (2) | KR100414759B1 (enExample) |
| CN (2) | CN1075076C (enExample) |
| AR (1) | AR000776A1 (enExample) |
| AU (1) | AU700256B2 (enExample) |
| BG (1) | BG100904A (enExample) |
| BR (1) | BR9606373A (enExample) |
| CA (1) | CA2186232A1 (enExample) |
| CZ (1) | CZ309596A3 (enExample) |
| DE (1) | DE69617543T3 (enExample) |
| ES (1) | ES2167539T5 (enExample) |
| FI (1) | FI963759A0 (enExample) |
| HU (1) | HUP9602907A3 (enExample) |
| IL (1) | IL116853A (enExample) |
| IT (1) | IT1272923B (enExample) |
| MX (1) | MX9604229A (enExample) |
| PL (1) | PL185055B1 (enExample) |
| RU (1) | RU2177948C2 (enExample) |
| TR (1) | TR199600720T1 (enExample) |
| TW (1) | TW319777B (enExample) |
| WO (1) | WO1996022995A1 (enExample) |
| ZA (1) | ZA96485B (enExample) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
| DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
| JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
| DE19644039A1 (de) * | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocene |
| RU2194708C2 (ru) * | 1996-11-15 | 2002-12-20 | Монтелл Текнолоджи Компани Б.В. | Металлоцен, лиганд, каталитическая система, способ полимеризации |
| US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
| CA2257177A1 (en) | 1997-03-29 | 1998-10-08 | Montell Technology Company B.V. | Metallocenes and catalysts for polymerization of olefins |
| AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
| DE19748388A1 (de) * | 1997-11-03 | 1999-05-06 | Borealis Polymere Holding Gmbh | Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation |
| CN1272852A (zh) | 1998-04-21 | 2000-11-08 | 蒙特尔技术有限公司 | 乙烯与α-烯烃共聚物的制备方法 |
| AU4904099A (en) * | 1998-07-02 | 2000-01-24 | Montell Technology Company B.V. | Process for the preparation of substantially amorphous alpha-olefin polymers and compositions containing them and process for the preparation of bridged ligand |
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| RU2248980C2 (ru) | 2000-02-24 | 2005-03-27 | Базелль Текнолоджи Компани Б.В. | Металлоорганическое соединение, пригодное в качестве сокатализатора для полимеризации олефинов |
| TR200103338T1 (tr) | 2000-03-22 | 2002-07-22 | Basell Technology Company Bv | İsotaktik propilen polimerlerin termoplastik bileşimleri. |
| WO2001090205A1 (en) | 2000-05-24 | 2001-11-29 | Basell Technology Company B.V. | Propylene polymers and process for the preparation thereof |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| DE60135311D1 (de) | 2000-12-22 | 2008-09-25 | Basell Polyolefine Gmbh | Katalysatorkomponente fur die polymerisation von olefinen |
| JP2004516365A (ja) | 2000-12-22 | 2004-06-03 | バセル ポリオレフィン イタリア エス.ピー.エー. | 多孔性ポリマーの製造方法およびそれから得られるポリマー |
| DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| AU2002320633B2 (en) * | 2001-07-19 | 2005-08-25 | Univation Technologies, Llc | Polyethylene films with improved physical properties |
| KR100577139B1 (ko) * | 2001-07-19 | 2006-05-10 | 유니베이션 테크놀로지즈, 엘엘씨 | 불충분한 공단량체 혼입제 및 충분한 공단량체 혼입제를 함유하는 혼합 메탈로센 촉매계 |
| US6936675B2 (en) * | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| CA2454060A1 (en) | 2001-07-19 | 2003-01-30 | Univation Technologies, Llc | Low comonomer incorporating metallocene catalyst compounds |
| EP1448624A1 (en) | 2001-11-27 | 2004-08-25 | Basell Polyolefine GmbH | Process for the treatment of polymer compositions |
| RU2214415C1 (ru) * | 2002-05-13 | 2003-10-20 | Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" | Способ получения галогенидов металлоценов (варианты) |
| CN100343327C (zh) | 2002-06-26 | 2007-10-17 | 巴塞尔聚烯烃意大利有限公司 | 抗冲击聚烯烃组合物 |
| BR0305246B1 (pt) * | 2002-06-26 | 2012-12-11 | composições de poliolefinas resistentes ao impacto, seu processo de preparação, bem como artigos moldados por injeção compreendendo as mesmas. | |
| US7449246B2 (en) * | 2004-06-30 | 2008-11-11 | General Electric Company | Barrier coatings |
| AU2003273400A1 (en) * | 2002-10-10 | 2004-05-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7524910B2 (en) * | 2002-10-15 | 2009-04-28 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| CN100362025C (zh) | 2003-04-17 | 2008-01-16 | 巴塞尔聚烯烃意大利有限责任公司 | 气相烯烃聚合方法 |
| WO2005005495A2 (en) | 2003-07-04 | 2005-01-20 | Basell Polyolefine Gmbh | Olefin polymerization process |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
| EP1735355B1 (en) | 2004-03-12 | 2010-09-29 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
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| EP1655314A1 (en) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| WO2006053911A1 (en) | 2004-11-22 | 2006-05-26 | Basell Polyolefine Gmbh | Propylene based terpolymers |
| US7300994B2 (en) * | 2004-11-22 | 2007-11-27 | Cornell Research Foundation, Inc. | Isotactic polypropylene containing polymers |
| CN101076621A (zh) * | 2004-12-13 | 2007-11-21 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃组合物、纤维以及非织造织物 |
| ATE414804T1 (de) * | 2004-12-23 | 2008-12-15 | Basell Poliolefine Srl | Fasern mit elastischen eigenschaften |
| US7026494B1 (en) | 2005-01-10 | 2006-04-11 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high melt index polymers without the use of hydrogen |
| EP2231724B1 (en) | 2007-12-18 | 2011-08-10 | Basell Polyolefine GmbH | Gas-phase process for the polymerization of alpha-olefins |
| CN101910225B (zh) * | 2008-01-11 | 2014-06-04 | 三井化学株式会社 | 改性丙烯树脂 |
| KR101580849B1 (ko) * | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| EP2350147B1 (en) | 2008-11-18 | 2013-05-01 | Borealis AG | Propylene-butene random copolymer produced in the presence of a mettalocene catalyst |
| EP2341086A1 (en) † | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
| EP3022238B1 (en) | 2013-07-17 | 2017-09-20 | ExxonMobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| SG11201510461SA (en) | 2013-07-17 | 2016-01-28 | Exxonmobil Chem Patents Inc | Substituted metallocene catalysts |
| JP2016530360A (ja) | 2013-07-17 | 2016-09-29 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 置換メタロセン触媒を使用する方法およびそれに由来する生成物 |
| US9834628B2 (en) | 2013-07-17 | 2017-12-05 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| EP3022237B1 (en) | 2013-07-17 | 2018-10-03 | ExxonMobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9587053B2 (en) * | 2013-09-30 | 2017-03-07 | Lg Chem, Ltd. | Preparation method of a propylene-1-butene copolymer and a propylene-1-butene copolymer obtained therefrom |
| JP6440832B2 (ja) * | 2014-12-15 | 2018-12-19 | エルジー・ケム・リミテッド | メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 |
| KR101826253B1 (ko) * | 2015-07-15 | 2018-02-06 | 한화케미칼 주식회사 | 메탈로센 화합물 및 이의 제조방법 |
| JP7045377B2 (ja) * | 2016-12-05 | 2022-03-31 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 幅広い直交分布のフィルム用メタロセンポリエチレン |
| WO2019072695A1 (en) | 2017-10-11 | 2019-04-18 | Basell Polyolefine Gmbh | CATALYST SUPPORTED SYSTEM |
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| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
| EP0284708B1 (en) * | 1987-04-03 | 1996-01-31 | Fina Technology, Inc. | Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge. |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE68928696T2 (de) * | 1988-12-26 | 1998-12-03 | Mitsui Chemicals, Inc., Tokio/Tokyo | Olefin-kopolymer und verfahren zur herstellung |
| DE3929693A1 (de) * | 1989-09-07 | 1991-03-14 | Hoechst Ag | Verfahren zur herstellung eines polyolefinwachses |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| IT1249008B (it) * | 1990-06-27 | 1995-02-11 | Himont Inc | Copolimeri cristallini sindiotattici del propilene |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| AU9159191A (en) * | 1990-12-28 | 1992-08-17 | Exxon Chemical Patents Inc. | Syndiotactic polypropylene |
| DE59209897D1 (de) * | 1991-05-27 | 2001-04-26 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung |
| JPH04351638A (ja) * | 1991-05-29 | 1992-12-07 | Toray Dow Corning Silicone Co Ltd | ヘキセニル基含有シリコーンレジンおよびその製造方法 |
| TW300901B (enExample) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5330948A (en) * | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| EP0584609B1 (de) * | 1992-08-15 | 1999-03-10 | TARGOR GmbH | Verfahren zur Herstellung von Polyolefinen |
| TW272985B (enExample) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| EP0588208A3 (en) * | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
| JP3307704B2 (ja) * | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| DE69427999T3 (de) | 1993-06-07 | 2012-09-27 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens |
| DE69431222T2 (de) * | 1993-06-07 | 2003-04-17 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| US5504223A (en) * | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
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- 1996-01-17 CZ CZ963095A patent/CZ309596A3/cs unknown
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- 1996-01-17 RU RU96121252/04A patent/RU2177948C2/ru not_active IP Right Cessation
- 1996-01-17 TR TR96/00720T patent/TR199600720T1/xx unknown
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- 1996-01-17 DE DE69617543T patent/DE69617543T3/de not_active Expired - Lifetime
- 1996-01-17 CA CA002186232A patent/CA2186232A1/en not_active Abandoned
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