ITMI950410A0 - Composti metallocenici bis-fluorenilici procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine - Google Patents

Composti metallocenici bis-fluorenilici procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Info

Publication number
ITMI950410A0
ITMI950410A0 ITMI950410A ITMI950410A ITMI950410A0 IT MI950410 A0 ITMI950410 A0 IT MI950410A0 IT MI950410 A ITMI950410 A IT MI950410A IT MI950410 A ITMI950410 A IT MI950410A IT MI950410 A0 ITMI950410 A0 IT MI950410A0
Authority
IT
Italy
Prior art keywords
fluorenil
olefins
catalysts
polymerization
preparation
Prior art date
Application number
ITMI950410A
Other languages
English (en)
Inventor
Luigi Resconi
Robert Lawrence Jones
Original Assignee
Spherilene Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Srl filed Critical Spherilene Srl
Publication of ITMI950410A0 publication Critical patent/ITMI950410A0/it
Priority to IT95MI000410A priority Critical patent/IT1275856B1/it
Priority to ES96103118T priority patent/ES2181816T3/es
Priority to EP96103118A priority patent/EP0729968B1/en
Priority to DE69623833T priority patent/DE69623833T2/de
Priority to US08/609,721 priority patent/US5786495A/en
Priority to KR1019960005498A priority patent/KR960034231A/ko
Priority to CN96105796A priority patent/CN1147522A/zh
Priority to JP8046358A priority patent/JPH08259583A/ja
Priority to CA002170928A priority patent/CA2170928A1/en
Publication of ITMI950410A1 publication Critical patent/ITMI950410A1/it
Application granted granted Critical
Publication of IT1275856B1 publication Critical patent/IT1275856B1/it
Priority to US09/086,807 priority patent/US6180733B1/en
Priority to US09/123,385 priority patent/US6054404A/en
Priority to US09/596,502 priority patent/US6365764B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
IT95MI000410A 1995-03-03 1995-03-03 Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione IT1275856B1 (it)

Priority Applications (12)

Application Number Priority Date Filing Date Title
IT95MI000410A IT1275856B1 (it) 1995-03-03 1995-03-03 Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
ES96103118T ES2181816T3 (es) 1995-03-03 1996-03-01 Metalocenos de bis-fluorenilo de puenteados, procedimiento para su preparacion y su empleo en catalizadores para la polimerizacion de olefinas.
EP96103118A EP0729968B1 (en) 1995-03-03 1996-03-01 Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
DE69623833T DE69623833T2 (de) 1995-03-03 1996-03-01 Verbrückte Bis-fluorenylmetallocene, Verfahren zu deren Herstellung, und deren Verwendung in Katalysatoren zur Polymerisation von Olefinen
US08/609,721 US5786495A (en) 1995-03-03 1996-03-01 Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
KR1019960005498A KR960034231A (ko) 1995-03-03 1996-03-02 다리걸친 형의 비스-플루오레닐 메탈로센, 그것의 제조 방법 및 올레핀 중합용 촉매로 사용되는 그것의 용도
CN96105796A CN1147522A (zh) 1995-03-03 1996-03-03 桥连双芴基金属茂，其制备方法和在烯烃聚合催化中的应用
JP8046358A JPH08259583A (ja) 1995-03-03 1996-03-04 橋状ビス−フルオレニルメタロセン、その製造法およびオレフィンの重合用触媒としての使用法
CA002170928A CA2170928A1 (en) 1995-03-03 1996-03-04 Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use theref in catalysts for the polymerization of olefins
US09/086,807 US6180733B1 (en) 1995-03-03 1998-05-29 Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
US09/123,385 US6054404A (en) 1995-03-03 1998-07-27 Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
US09/596,502 US6365764B1 (en) 1995-03-03 2000-06-19 Bridged bis-fluorenyl metallocenes process for the preparation thereof and use thereof in catalysts for the polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT95MI000410A IT1275856B1 (it) 1995-03-03 1995-03-03 Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione

Publications (3)

Publication Number Publication Date
ITMI950410A0 true ITMI950410A0 (it) 1995-03-03
ITMI950410A1 ITMI950410A1 (it) 1996-09-03
IT1275856B1 IT1275856B1 (it) 1997-10-24

Family

ID=11370763

Family Applications (1)

Application Number Title Priority Date Filing Date
IT95MI000410A IT1275856B1 (it) 1995-03-03 1995-03-03 Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione

Country Status (9)

Country Link
US (4) US5786495A (it)
EP (1) EP0729968B1 (it)
JP (1) JPH08259583A (it)
KR (1) KR960034231A (it)
CN (1) CN1147522A (it)
CA (1) CA2170928A1 (it)
DE (1) DE69623833T2 (it)
ES (1) ES2181816T3 (it)
IT (1) IT1275856B1 (it)

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US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
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US6608228B1 (en) * 1997-11-07 2003-08-19 California Institute Of Technology Two-photon or higher-order absorbing optical materials for generation of reactive species
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US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
FR2813079B1 (fr) * 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
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ATE503792T1 (de) * 2001-07-19 2011-04-15 Univation Tech Llc Polyethylenfilme mit verbesserten physikalischen eigenschaften
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Also Published As

Publication number Publication date
CN1147522A (zh) 1997-04-16
DE69623833D1 (de) 2002-10-31
JPH08259583A (ja) 1996-10-08
ITMI950410A1 (it) 1996-09-03
EP0729968B1 (en) 2002-09-25
IT1275856B1 (it) 1997-10-24
EP0729968A1 (en) 1996-09-04
KR960034231A (ko) 1996-10-22
US6054404A (en) 2000-04-25
CA2170928A1 (en) 1996-09-04
US5786495A (en) 1998-07-28
US6365764B1 (en) 2002-04-02
US6180733B1 (en) 2001-01-30
ES2181816T3 (es) 2003-03-01
DE69623833T2 (de) 2003-07-31

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