DE2624097A1 - Verfahren zur alkylierung von aromatischen kohlenwasserstoffen - Google Patents

Verfahren zur alkylierung von aromatischen kohlenwasserstoffen

Info

Publication number
DE2624097A1
DE2624097A1 DE19762624097 DE2624097A DE2624097A1 DE 2624097 A1 DE2624097 A1 DE 2624097A1 DE 19762624097 DE19762624097 DE 19762624097 DE 2624097 A DE2624097 A DE 2624097A DE 2624097 A1 DE2624097 A1 DE 2624097A1
Authority
DE
Germany
Prior art keywords
zeolite
range
catalyst
alkylation
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19762624097
Other languages
German (de)
English (en)
Other versions
DE2624097C2 (OSRAM
Inventor
Werner Otto Haag
Did Harold Olson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Publication of DE2624097A1 publication Critical patent/DE2624097A1/de
Application granted granted Critical
Publication of DE2624097C2 publication Critical patent/DE2624097C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19762624097 1975-05-29 1976-05-28 Verfahren zur alkylierung von aromatischen kohlenwasserstoffen Granted DE2624097A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/582,025 US4016218A (en) 1975-05-29 1975-05-29 Alkylation in presence of thermally modified crystalline aluminosilicate catalyst

Publications (2)

Publication Number Publication Date
DE2624097A1 true DE2624097A1 (de) 1976-12-09
DE2624097C2 DE2624097C2 (OSRAM) 1988-06-09

Family

ID=24327535

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19762624097 Granted DE2624097A1 (de) 1975-05-29 1976-05-28 Verfahren zur alkylierung von aromatischen kohlenwasserstoffen

Country Status (11)

Country Link
US (1) US4016218A (OSRAM)
JP (1) JPS607603B2 (OSRAM)
BE (1) BE842040A (OSRAM)
CA (1) CA1070714A (OSRAM)
DE (1) DE2624097A1 (OSRAM)
FR (1) FR2312478A1 (OSRAM)
GB (1) GB1525323A (OSRAM)
IT (1) IT1060872B (OSRAM)
NL (1) NL7605626A (OSRAM)
NO (1) NO143498C (OSRAM)
ZA (1) ZA762844B (OSRAM)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2714239A1 (de) * 1976-03-31 1977-10-20 Mobil Oil Corp Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung
DE2756221A1 (de) * 1977-02-11 1978-08-17 Mobil Oil Corp Verfahren zur aethylierung von benzol
DE2826865A1 (de) * 1977-06-23 1979-01-18 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE3330912A1 (de) * 1982-08-27 1984-03-15 Toyo Soda Manufacturing Co., Ltd., Shinnanyo, Yamaguchi Verfahren zur herstellung von 1,2,4,5-tetraalkylbenzolen

Families Citing this family (357)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4176225A (en) 1975-06-10 1979-11-27 Clement Jean Claude Nylon polycondensate from diamino phosphonate
PL199748A1 (pl) * 1976-07-19 1978-04-24 Mobil Oil Corp Sposob selektywnego wytwarzania p-dwualkilobenzenow
US4117024A (en) * 1977-07-29 1978-09-26 Mobil Oil Corporation Ethylation of aromatic compounds
US4169111A (en) * 1978-02-02 1979-09-25 Union Oil Company Of California Manufacture of ethylbenzene
EP0005315B1 (en) 1978-05-08 1981-12-02 Imperial Chemical Industries Plc Production of xylene hydrocarbons
US4393262A (en) * 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
US4899007A (en) * 1979-01-31 1990-02-06 Mobil Oil Corporation Aromatic conversion reactions with zeolitic catalyst composition of improved shape selectivity
CA1142552A (en) * 1979-06-06 1983-03-08 Warren W. Kaeding Selective alkylation of xylenes with ethylene
US4869803A (en) * 1979-10-15 1989-09-26 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US4879019A (en) * 1979-10-15 1989-11-07 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US4301317A (en) * 1979-11-20 1981-11-17 Mobil Oil Corporation Preparation of 2-phenylalkanes
US4329509A (en) * 1979-11-30 1982-05-11 Mobil Oil Corporation Co-production of 2-alkanones and phenols
CA1148569A (en) * 1980-02-14 1983-06-21 Christine H. Kursewicz Aromatics processing
US4374296A (en) * 1980-02-14 1983-02-15 Mobil Oil Corporation Isomerization of paraffin hydrocarbons using zeolites with high steam-enhanced acidity
US4326994A (en) * 1980-02-14 1982-04-27 Mobil Oil Corporation Enhancement of zeolite catalytic activity
US4387260A (en) * 1981-04-20 1983-06-07 Cosden Technology, Inc. Alkylation of aromatic compounds with silicalite catalysts in the presence of steam
US4395554A (en) * 1981-12-01 1983-07-26 Mobil Oil Corporation Process for producing alpha-picoline
US4520220A (en) * 1982-02-22 1985-05-28 Cosden Technology, Inc. Alkylation of aromatics employing silicalite catalysts
US4480145A (en) * 1982-09-16 1984-10-30 Mobil Oil Corporation Catalysts for the conversion of methanol to ethylene plus gasoline
US4447664A (en) * 1982-09-23 1984-05-08 The Dow Chemical Company Integrated Fischer-Tropsch and aromatic alkylation process
US4490565A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4490566A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4758328A (en) * 1984-01-17 1988-07-19 Union Oil Company Of California Shock calcined aluminosilicate zeolites
EP0236602A1 (en) * 1986-03-04 1987-09-16 Union Oil Company Of California Shock calcined aluminosilicate zeolites
US4581214A (en) * 1984-01-17 1986-04-08 Union Oil Company Of California Shock calcined aluminosilicate zeolites
US4623633A (en) 1984-01-17 1986-11-18 Union Oil Company Of California Shock calcined aluminosilicate zeolites
US4552648A (en) * 1984-02-08 1985-11-12 Mobil Oil Corporation Fluidized catalytic cracking process
US4570027A (en) * 1984-04-27 1986-02-11 Exxon Research And Engineering Co. Alkylation of aromatic molecules using a silica-alumina catalyst derived from zeolite
US4582694A (en) * 1984-06-21 1986-04-15 Union Oil Company Of California Shock calcined crystalline silica catalysts
US4758327A (en) * 1984-06-21 1988-07-19 Union Oil Company Of California Shock calcined crystalline silica catalysts
US4623636A (en) 1984-06-21 1986-11-18 Union Oil Company Of California Shock calcined crystalline silica catalysts
US5047141A (en) * 1984-07-16 1991-09-10 Mobil Oil Corporation Larger pore molecular sieves of controlled activity
US4587371A (en) * 1984-08-27 1986-05-06 Cosden Technology, Inc. Hydrocarbon conversion of sulfur contaminated feed stock
IL73146A (en) * 1984-10-02 1988-11-15 Yeda Res & Dev Catalysts and process for the production of hydrocarbons and substitution of hydrocarbons
US4696732A (en) * 1984-10-29 1987-09-29 Mobil Oil Corporation Simultaneous hydrotreating and dewaxing of petroleum feedstocks
US4676887A (en) * 1985-06-03 1987-06-30 Mobil Oil Corporation Production of high octane gasoline
US4943366A (en) * 1985-06-03 1990-07-24 Mobil Oil Corporation Production of high octane gasoline
US4615997A (en) * 1985-06-03 1986-10-07 Mobil Oil Corporation Method for preparing hydroisomerization catalysts
US4740292A (en) * 1985-09-12 1988-04-26 Mobil Oil Corporation Catalytic cracking with a mixture of faujasite-type zeolite and zeolite beta
EP0315715B1 (en) * 1987-11-09 1992-06-03 Mobil Oil Corporation The use of dehydroxylated zeolites in the catalytic isomerisation of a xylene
US4724270A (en) * 1985-10-04 1988-02-09 Mobil Oil Corporation Catalytic conversion over dehydroxylated zeolite
US4913797A (en) * 1985-11-21 1990-04-03 Mobil Oil Corporation Catalyst hydrotreating and dewaxing process
US4790928A (en) * 1986-12-19 1988-12-13 Mobile Oil Corporation Catalytic conversion over dehydroxylated zeolite
US4783571A (en) * 1986-12-19 1988-11-08 Mobil Oil Corporation Catalytic conversion over dehydroxylated zeolite
US4828678A (en) * 1987-07-09 1989-05-09 Mobil Oil Corporation Catalytic cracking
EP0308099A1 (en) * 1987-09-02 1989-03-22 Mobil Oil Corporation Alkylation of aromatics
EP0308097B1 (en) 1987-09-02 1992-01-29 Mobil Oil Corporation Transalkylation of polyalkylaromatic hydrocarbons
US4885426A (en) * 1987-09-02 1989-12-05 Mobil Oil Corporation Transalkylation of polyaromatics
US4814543A (en) * 1987-12-28 1989-03-21 Mobil Oil Corporation Nitrogen resistant paraffin hydroisomerization catalysts
US4919790A (en) * 1988-01-19 1990-04-24 Mobil Oil Corporation Method for hydrocarbon dewaxing utilizing a reactivated spent MTG zeolite catalyst
US4827069A (en) * 1988-02-19 1989-05-02 Mobil Oil Corporation Upgrading light olefin fuel gas and catalytic reformate in a turbulent fluidized bed catalyst reactor
US4851602A (en) * 1988-04-11 1989-07-25 Mobil Oil Corporation Alkanes and alkenes conversion to high octane gasoline
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
US4935577A (en) * 1988-07-15 1990-06-19 Mobil Oil Corp. Hydrocarbon processes comprised of catalytic distillation using Lewis acid promoted inorganic oxide catalyst systems
US4877581A (en) * 1988-09-01 1989-10-31 Mobil Oil Corporation Catalyst for dewaxing hydrocarbon feedstock
US4997543A (en) * 1988-12-21 1991-03-05 Mobil Oil Corporation Reduction of benzene in gasoline
US5030783A (en) * 1989-01-17 1991-07-09 Mobil Oil Corporation Endothermic hydrocarbon upgrading process
US4950691A (en) * 1989-01-17 1990-08-21 Mobil Oil Corp. Endothermic hydrocarbon upgrading process
US4992607A (en) * 1989-03-20 1991-02-12 Mobil Oil Corporation Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate
US5262576A (en) * 1989-03-23 1993-11-16 Chemical Research & Licensing Company Method for the alkylation of organic aromatic compounds
US4970397A (en) * 1989-06-16 1990-11-13 Mobil Oil Corporation Method and apparatus for activating catalysts using electromagnetic radiation
US4950823A (en) * 1989-07-03 1990-08-21 Mobil Oil Corp. Benzene upgrading reformer integration
US5157185A (en) * 1989-09-01 1992-10-20 Mobil Oil Corporation Alkylation of aromatics
US5030787A (en) * 1990-01-24 1991-07-09 Mobil Oil Corp. Catalytic disproportionation/transalkylation utilizing a C9+ aromatics feed
US5334795A (en) * 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5106389A (en) * 1990-10-17 1992-04-21 Mobil Oil Corporation Process for conversion of light paraffins to alkylate in the production of tertiary alkyl ether rich gasoline
US5118896A (en) * 1990-10-31 1992-06-02 Amoco Corporation Aromatic alkylation process using large macropore, small particle size, zeolite catalyst
US5120890A (en) * 1990-12-31 1992-06-09 Uop Process for reducing benzene content in gasoline
US5077445A (en) * 1991-02-06 1991-12-31 Mobil Oil Corp. Liquid-phase alkylbenzene synthesis using hydrated catalyst
US5177284A (en) * 1991-05-28 1993-01-05 Mobil Oil Corporation Catalysts/process to synthesize alkylated naphthalene synthetic fluids with increased alpha/beta isomers for improving product qualities
US5118894A (en) * 1991-07-18 1992-06-02 Mobil Oil Corporation Production of ethylbenzene
US5391288A (en) * 1991-08-15 1995-02-21 Mobil Oil Corporation Gasoline upgrading process
CA2097090A1 (en) * 1992-06-02 1993-12-03 Quang N. Le Process for the production of tertiary alkyl ether rich fcc gasoline
US5308475A (en) * 1992-11-23 1994-05-03 Mobil Oil Corporation Use of ZSM-12 in catalytic cracking for gasoline octane improvement and co-production of light olefins
US5554274A (en) * 1992-12-11 1996-09-10 Mobil Oil Corporation Manufacture of improved catalyst
US5362378A (en) * 1992-12-17 1994-11-08 Mobil Oil Corporation Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value
US5599439A (en) * 1993-03-13 1997-02-04 Mobil Oil Corporation Gasoline and reformate upgrading process
US5349114A (en) * 1993-04-05 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
US5406015A (en) * 1993-05-28 1995-04-11 Mobil Oil Corp. Selective ethylbenzene disproportionation processes (SEBDP) with ex situ selectivated zeolite catalyst
US5403800A (en) * 1993-05-28 1995-04-04 Mobil Oil Corp. Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts
US5698756A (en) * 1993-05-28 1997-12-16 Mobil Oil Corporation Toluene alkylation with ethylene to produce para-ethyloluene
US6576582B1 (en) 1993-05-28 2003-06-10 Exxonmobil Oil Corporation Binderless ex situ selectivated zeolite catalyst
US5367099A (en) * 1993-05-28 1994-11-22 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalyst
US5659098A (en) * 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
US5530170A (en) * 1993-05-28 1996-06-25 Mobil Oil Corporation Ethylbenzene alkylation with ethylene to produce para-diethylbenzene
US5382737A (en) * 1993-05-28 1995-01-17 Mobil Oil Corp. Selective ethylbenzene disproportionation process (SEBDP) with ex situ selectivated zeolite catalysts
US5476823A (en) * 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5365004A (en) * 1993-05-28 1994-11-15 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalysts
JP3665069B2 (ja) * 1993-10-08 2005-06-29 アクゾ ノーベル ナムローゼ フェンノートシャップ 水素化分解及び水素化脱ロウ方法
US5726114A (en) * 1993-10-27 1998-03-10 Mobil Oil Corporation Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and methods to increase the activity thereof
US5625104A (en) * 1995-06-06 1997-04-29 Mobil Oil Corporation Alkali metal ion exchanged selectivated zeolite catalyst
DE4444709A1 (de) 1994-12-15 1996-06-20 Basf Ag Verfahren zur Herstellung von Glutardialdehyd
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
TW504501B (en) * 1995-02-10 2002-10-01 Mobil Oil Corp Process for converting feedstock comprising C9+ aromatic hydrocarbons to lighter aromatic products
JP3888703B2 (ja) * 1995-09-25 2007-03-07 ダイセル化学工業株式会社 ピリジン塩基類の製造方法、新規金属担持ゼオライトおよびその製法
US5849968A (en) * 1995-06-06 1998-12-15 Mobil Oil Corporation Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst
PT837849E (pt) * 1995-06-23 2002-06-28 Reilly Ind Inc Sintese de bases de piridina
DE69612529D1 (de) * 1995-09-25 2001-05-23 Daicel Chem Verfahren zur Herstellung von Pyridine
US5773679A (en) * 1995-12-26 1998-06-30 Mobil Oil Corporation Performance enhancement of zeolite catalysts with water cofeed
JP2002515823A (ja) * 1996-02-21 2002-05-28 エイエスイーシー・マニュファクチュアリング・カンパニー 高度に分散された組成物および／または均質な組成物、それから作られた材料および被覆物、およびその製造方法
US6538167B1 (en) 1996-10-02 2003-03-25 Exxonmobil Chemical Patents Inc. Process for producing light olefins
US5942651A (en) * 1997-06-13 1999-08-24 Mobile Oil Corporation Process for converting C9 + aromatic hydrocarbons to lighter aromatic products by transalkylation in the prescence of two zeolite-containing catalysts
CA2240612A1 (en) * 1997-07-29 1999-01-29 Vladimir Borisovich Kazansky Preparation of phenol and its derivatives
US6143940A (en) * 1998-12-30 2000-11-07 Chevron U.S.A. Inc. Method for making a heavy wax composition
US6150577A (en) * 1998-12-30 2000-11-21 Chevron U.S.A., Inc. Method for conversion of waste plastics to lube oil
US6984764B1 (en) 1999-05-04 2006-01-10 Exxonmobil Oil Corporation Alkylaromatics production
US6972347B1 (en) * 1999-06-16 2005-12-06 Toray Industries, Inc. Method for converting aromatic hydrocarbons
US6797155B1 (en) 1999-12-21 2004-09-28 Exxonmobil Research & Engineering Co. Catalytic cracking process using a modified mesoporous aluminophosphate material
US6703356B1 (en) * 2000-03-23 2004-03-09 Exxonmobil Research And Engineering Company Synthetic hydrocarbon fluids
US6747182B2 (en) 2000-03-24 2004-06-08 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
US6596662B2 (en) 2000-03-24 2003-07-22 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
JP2004500474A (ja) 2000-04-03 2004-01-08 シェブロン　ユー．エス．エー．　インコーポレイテッド 合成ガスを留出燃料に転化する改良された方法
US6506954B1 (en) 2000-04-11 2003-01-14 Exxon Mobil Chemical Patents, Inc. Process for producing chemicals from oxygenate
US6936744B1 (en) 2000-07-19 2005-08-30 Exxonmobil Chemical Patents, Inc. Alkylaromatics production
US6670517B1 (en) 2000-08-24 2003-12-30 Exxon Mobil Chemical Patents Inc. Process for alkylating aromatics
AU2002220152A1 (en) 2000-11-21 2002-06-03 Exxonmobil Chemical Patents Inc Process for producing light olefins
US6525234B1 (en) 2000-11-21 2003-02-25 Exxonmobil Oil Corporation Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
DE60224164T2 (de) * 2001-02-07 2008-12-04 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur herstellung von alkylaromatischen verbindungen
US6878654B2 (en) * 2001-07-11 2005-04-12 Exxonmobil Chemical Patents Inc. Reactivation of aromatics alkylation catalysts
US6781025B2 (en) 2001-07-11 2004-08-24 Exxonmobil Chemical Patents Inc. Reactivation of aromatics alkylation catalysts
AU2003217760A1 (en) * 2002-02-28 2003-09-16 Washington Group International, Inc. Production of alkyl aromatic compounds
US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US6768037B2 (en) * 2002-10-30 2004-07-27 Chevron U.S.A. Inc. Process to upgrade fischer-tropsch products and form light olefins
US7102043B2 (en) * 2002-11-04 2006-09-05 The Goodyear Tire + Rubber Company Process for synthesizing diisopropylbenzene
US7148391B1 (en) 2002-11-14 2006-12-12 Exxonmobil Chemical Patents Inc. Heavy aromatics processing
US7019185B2 (en) * 2002-12-06 2006-03-28 Exxonmobil Chemical Patents Inc. Aromatic alkylation process
US20040206666A1 (en) * 2003-03-10 2004-10-21 Adams Nicholas James Process for preparing a lubricating base oil and a gas oil
CN1761522A (zh) * 2003-03-21 2006-04-19 斯通&维布斯特公司 带有催化剂再活化的烷基芳香族化合物的生产
US20040188323A1 (en) * 2003-03-24 2004-09-30 Tzatzov Konstantin K. Active coating system for reducing or eliminating coke build-up during petrochemical processes
US7253330B2 (en) * 2003-04-29 2007-08-07 Exxonmobil Chemical Patents Inc. Oligomerization process
EP1479663A1 (en) * 2003-05-17 2004-11-24 Haldor Topsoe A/S Process for catalytic alkylation of monocyclic aromatic compounds and composition of use therein
US7589041B2 (en) 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
CA2467499C (en) * 2004-05-19 2012-07-17 Nova Chemicals Corporation Integrated process to convert heavy oils from oil sands to petrochemical feedstock
GB0412139D0 (en) 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
US7525002B2 (en) * 2005-02-28 2009-04-28 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization with aromatics alkylation
US20060194998A1 (en) * 2005-02-28 2006-08-31 Umansky Benjamin S Process for making high octane gasoline with reduced benzene content
JP2008535941A (ja) * 2005-02-28 2008-09-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー 気相芳香族アルキル化方法
US7498474B2 (en) * 2005-02-28 2009-03-03 Exxonmobil Research And Engineering Company Vapor phase aromatics alkylation process
WO2006094010A2 (en) * 2005-02-28 2006-09-08 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization with aromatics alkylation
US7476774B2 (en) * 2005-02-28 2009-01-13 Exxonmobil Research And Engineering Company Liquid phase aromatics alkylation process
JP5017252B2 (ja) 2005-03-31 2012-09-05 エクソンモービル・ケミカル・パテンツ・インク 希釈アルケンを用いたアルキル芳香族の生産
US8258360B2 (en) 2005-03-31 2012-09-04 Exxonmobil Chemical Patents Inc. Multiphase alkylaromatics production
US7456329B2 (en) * 2005-11-30 2008-11-25 Exxonmobil Chemical Patents Inc. Polyolefins from non-conventional feeds
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
CN101437783B (zh) * 2006-05-08 2012-12-12 埃克森美孚化学专利公司 有机化合物转化方法
EP2035140A1 (en) 2006-05-08 2009-03-18 ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware Improved catalyst composition
US8148592B2 (en) * 2006-05-08 2012-04-03 Cepsa Quimica, S.A. Catalytic transalkylation of dialkyl benzenes
US7501547B2 (en) * 2006-05-10 2009-03-10 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US20080033222A1 (en) * 2006-05-24 2008-02-07 Clark Michael C Process and apparatus for preparing ethylbenzene using vapor phase alkylation and liquid phase transalkylation
US8247629B2 (en) * 2006-05-24 2012-08-21 Exxonmobil Chemical Patents Inc. Monoalkylated aromatic compound production
FR2901804B1 (fr) * 2006-05-30 2012-08-31 Inst Francais Du Petrole Procede de transformation de l'ethanol en base pour carburant diesel
US7563358B2 (en) * 2006-08-24 2009-07-21 Exxonmobil Chemical Patents Inc. Process for the production of benzene, toluene, and xylenes
US7837861B2 (en) * 2006-10-18 2010-11-23 Exxonmobil Research & Engineering Co. Process for benzene reduction and sulfur removal from FCC naphthas
US8048295B2 (en) * 2006-12-05 2011-11-01 Exxonmobil Chemical Patents Inc. Process for decreasing bromine-reactive contaminants in hydrocarbon feeds
ES2319007B1 (es) * 2006-12-07 2010-02-16 Rive Technology, Inc. Metodos para fabricar materiales zeoliticos mesoestructurados.
US7645913B2 (en) 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts
JP5305465B2 (ja) * 2007-02-09 2013-10-02 エクソンモービル・ケミカル・パテンツ・インク 改良されたアルキル芳香族の生産プロセス
US7737314B2 (en) 2007-02-12 2010-06-15 Exxonmobil Chemical Patents Inc. Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein
US7790940B2 (en) * 2007-06-21 2010-09-07 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US7745676B2 (en) * 2007-07-30 2010-06-29 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US8206498B2 (en) * 2007-10-25 2012-06-26 Rive Technology, Inc. Methods of recovery of pore-forming agents for mesostructured materials
US8088961B2 (en) * 2007-12-27 2012-01-03 Chevron U.S.A. Inc. Process for preparing a pour point depressing lubricant base oil component from waste plastic and use thereof
CN101945703B (zh) 2008-02-21 2013-05-08 埃克森美孚化学专利公司 由甲烷生产芳烃的方法
EP2110368A1 (en) 2008-04-18 2009-10-21 Total Petrochemicals France Alkylation of aromatic substrates and transalkylation process
EP2321040A1 (en) * 2008-07-22 2011-05-18 ExxonMobil Chemical Patents Inc. Preparation of molecular sieve containing catalyst and its use in the production of alkylaromatic hydrocarbons
US8168061B2 (en) * 2008-07-25 2012-05-01 Exxonmobil Research And Engineering Company Process for flexible vacuum gas oil conversion using divided wall fractionation
US8163168B2 (en) 2008-07-25 2012-04-24 Exxonmobil Research And Engineering Company Process for flexible vacuum gas oil conversion
US8704025B2 (en) * 2008-07-28 2014-04-22 Exxonmobil Chemical Patents Inc. Molecular sieve composition EMM-12, a method of making and a process of using the same
WO2010014405A1 (en) 2008-07-28 2010-02-04 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using emm-12
WO2010014401A1 (en) 2008-07-28 2010-02-04 Exxonmobil Chemical Patents Inc. Hydroalkylation of aromatic compounds using emm-13
US8198496B2 (en) * 2008-07-28 2012-06-12 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using EMM-13
KR101254411B1 (ko) * 2008-07-28 2013-04-15 엑손모빌 케미칼 패턴츠 인코포레이티드 Ｅｍｍ-12를 이용하여 알킬방향족을 제조하는 방법
US8704023B2 (en) * 2008-07-28 2014-04-22 Exxonmobil Chemical Patents Inc. Molecular sieve composition EMM-13, a method of making and a process of using the same
BRPI0920691A2 (pt) * 2008-10-06 2015-12-29 Badger Licensing Llc processo para produção de cumeno
TWI458695B (zh) * 2008-10-06 2014-11-01 Badger Licensing Llc 異丙苯的製造方法
ES2573262T3 (es) * 2008-10-10 2016-06-06 Badger Licensing, Llc Procedimiento de producción de compuestos alquilaromáticos
US8524625B2 (en) * 2009-01-19 2013-09-03 Rive Technology, Inc. Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange
ES2875884T3 (es) 2009-01-19 2021-11-11 Grace W R & Co Introducción de mesoporosidad en zeolitas con bajo contenido en Si/A1
US8395006B2 (en) * 2009-03-13 2013-03-12 Exxonmobil Research And Engineering Company Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion
US20110056869A1 (en) * 2009-09-08 2011-03-10 Exxonmobil Research And Engineering Company Fuel production from feedstock containing lipidic material
EP2480638A4 (en) * 2009-09-25 2013-07-03 Exxonmobil Res & Eng Co FUEL MANUFACTURE FROM A RAW MATERIAL WITH A TRIGLYCERIDE AND / OR FATTY ACID ELECTRIC
US8685875B2 (en) * 2009-10-20 2014-04-01 Rive Technology, Inc. Methods for enhancing the mesoporosity of zeolite-containing materials
EP2496667A4 (en) * 2009-11-04 2015-01-07 Exxonmobil Res & Eng Co HYDROPOWERING A RAW MATERIAL WITH A LIPID MATERIAL FOR PRODUCING A TRANSPORT FUEL
EP2322972A1 (fr) * 2009-11-12 2011-05-18 Johnson Controls Technology Company Dispositif d'affichage, notamment pour véhicule automobile
US8546286B2 (en) 2009-12-15 2013-10-01 Exxonmobil Research And Engineering Company Preparation of hydrogenation and dehydrogenation catalysts
WO2011073431A2 (en) 2009-12-17 2011-06-23 Shell Internationale Research Maatschappij B.V. Process for producing hydrocarbons from microbial lipids
US20110171121A1 (en) * 2010-01-08 2011-07-14 Rive Technology, Inc. Compositions and methods for making stabilized mesoporous materials
US8629311B2 (en) * 2010-03-10 2014-01-14 Stone & Webster, Inc. Alkylated aromatics production
ES2672228T3 (es) 2010-05-20 2018-06-13 Exxonmobil Chemical Patents Inc. Procedimiento de alquilación mejorado
US20120022224A1 (en) 2010-07-22 2012-01-26 Geraldine Tosin Particles Including Zeolite Catalysts And Their Use In Oligomerization Processes
WO2012030440A1 (en) 2010-08-30 2012-03-08 Exxonmobil Chemical Patents Inc. Improved alkylation process
WO2012033562A1 (en) 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudates including zeolite catalysts and their use in oligomerization processes
CN103180042B (zh) 2010-10-15 2015-07-22 埃克森美孚化学专利公司 选择改进的催化剂组合物和使用所述催化剂组合物的烃转化方法
US20120152803A1 (en) 2010-12-20 2012-06-21 Exxonmobil Research And Engineering Company Increasing fuel smoke point
EP2694438A4 (en) 2011-04-08 2014-11-05 Rive Technology Inc MESOPOROUS ZEOLITE WITH MODIFIED FRAME
JP2014516769A (ja) 2011-04-13 2014-07-17 キオール，インク． バイオマスを液体燃料と化学品に熱触媒変換するための改良された触媒
CN103596683B (zh) 2011-05-09 2016-01-20 沙特基础工业公司 用于芳烃烷基化的催化剂
WO2013013887A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
US9428427B2 (en) 2011-07-25 2016-08-30 Exxonmobil Chemical Patents Inc. Process for nitrile removal from hydrocarbon feeds
WO2013013886A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013888A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
EP2736632B1 (en) 2011-07-25 2017-02-01 ExxonMobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
JP2014524509A (ja) 2011-08-19 2014-09-22 バジャー・ライセンシング・エルエルシー ガソリンのベンゼン含有量を低減する方法
CN103827033B (zh) 2011-09-16 2016-05-11 埃克森美孚化学专利公司 改进的mcm-56制造方法
WO2013039673A1 (en) 2011-09-16 2013-03-21 Exxonmobil Chemical Patents Inc. Improved liquid phase alkylation process
US20130096355A1 (en) 2011-10-17 2013-04-18 Exxonmobil Research And Engineering Company Selective dehydration of alcohols to dialkylethers and integrated alcohol-to-gasoline processes
US20130144097A1 (en) 2011-12-06 2013-06-06 Exxonmobil Chemical Patents Inc. Aromatics Production Process and Apparatus
CA2850979A1 (en) 2012-01-13 2013-07-18 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
WO2013119318A1 (en) 2012-02-08 2013-08-15 Exxonmobil Chemical Patents Inc. Production of monoalkyl aromatic compounds
ES2759938T3 (es) 2012-06-27 2020-05-12 Badger Licensing Llc Procedimiento de producción de cumeno
CN104428277B (zh) 2012-07-05 2017-03-15 巴杰许可有限责任公司 生产异丙苯的方法
MY170173A (en) 2012-07-13 2019-07-09 Badger Licensing Llc Process for producing phenol
PL2852565T3 (pl) 2012-07-26 2021-11-02 Badger Licensing, Llc Proces wytwarzania kumenu
KR101950063B1 (ko) 2012-08-14 2019-02-19 바져 라이센싱 엘엘씨 큐멘을 생성하고 아이소프로판올을 정제하는 통합된 방법
JP5736360B2 (ja) * 2012-10-26 2015-06-17 エクソンモービル・ケミカル・パテンツ・インク 有機化合物変換方法
US10138180B2 (en) 2012-11-27 2018-11-27 Badger Licensing Llc Production of styrene
SG11201502695TA (en) 2012-12-10 2015-05-28 Exxonmobil Res & Eng Co Synthesis and use of molecular sieve itq-32
WO2014109766A1 (en) 2013-01-14 2014-07-17 Badger Licensing Llc Process for balancing gasoline and distillate production in a refinery
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids
KR20150119091A (ko) 2013-03-14 2015-10-23 엑손모빌 케미칼 패턴츠 인코포레이티드 메틸 치환된 비페닐 화합물, 이의 제법 및 가소제의 제조에서의 이의 용도
EP2970050A4 (en) 2013-03-14 2016-04-06 Exxonmobil Chem Patents Inc METHYL-SUBSTITUTED BIPHENYL COMPOUNDS, THEIR PRODUCTION AND THEIR USE IN THE MANUFACTURE OF PLASTICIZERS
RU2640595C2 (ru) 2013-05-08 2018-01-10 БЭДЖЕР ЛАЙСЕНСИНГ ЭлЭлСи Способ алкилирования ароматических соединений
WO2014182434A1 (en) 2013-05-09 2014-11-13 Exxonmobil Chemical Patents Inc. Treatment of aromatic alkylation catalysts
WO2015031370A1 (en) 2013-08-30 2015-03-05 Exxonmobil Chemical Patents Inc. Catalytic alkane conversion and olefin separation
US9266744B2 (en) * 2013-10-10 2016-02-23 Chevron U.S.A. Inc. Synthesis of borosilicate ton-framework type molecular sieves
WO2015084576A2 (en) 2013-12-06 2015-06-11 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
CA2931610C (en) 2013-12-06 2019-04-09 Exxonmobil Upstream Research Company Methods and systems for producing liquid hydrocarbons
US9682899B2 (en) 2013-12-06 2017-06-20 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
US10167361B2 (en) 2014-03-25 2019-01-01 Exxonmobil Chemical Patents Inc. Production of aromatics and C2+olefins
US10131588B2 (en) 2013-12-06 2018-11-20 Exxonmobil Chemical Patents Inc. Production of C2+ olefins
WO2015084575A2 (en) 2013-12-06 2015-06-11 Exxonmobil Chemical Patents Inc. Production of c2+ olefins
US10099972B2 (en) 2013-12-06 2018-10-16 Exxonmobil Upstream Research Company Methods and systems for producing liquid hydrocarbons
WO2015089256A1 (en) 2013-12-13 2015-06-18 Exxonmobil Research And Engineering Company Enhanced methane formation in reforming catalysts
WO2015094696A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
CA2925996A1 (en) 2013-12-20 2015-06-25 Exxonmobil Research And Engineering Company Catalyst for conversion of oxygenates to aromatics
US9662640B2 (en) 2013-12-27 2017-05-30 Rive Technology, Inc. Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
CN111234862A (zh) 2014-02-07 2020-06-05 沙特基础工业公司 使用酸催化剂如酸性离子液体从烯烃流中去除芳香族杂质
WO2015118469A1 (en) 2014-02-07 2015-08-13 Saudi Basic Industries Corporation Removal of aromatic impurities from an alkene stream using an acid catalyst
WO2016003613A2 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
WO2016003612A1 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Processes for the production of para-xylene
US9950971B2 (en) 2014-07-23 2018-04-24 Exxonmobil Chemical Patents Inc. Process and catalyst for methane conversion to aromatics
US9809758B2 (en) 2014-07-24 2017-11-07 Exxonmobil Chemical Patents Inc. Production of xylenes from syngas
US9714386B2 (en) 2014-07-24 2017-07-25 Exxonmobil Chemical Patents Inc. Production of xylenes from syngas
JP6615888B2 (ja) 2014-08-15 2019-12-04 エクソンモービル・ケミカル・パテンツ・インク 芳香族の製造方法
US10173946B2 (en) 2014-10-10 2019-01-08 Exxonmobil Research And Engineering Company Apparatus and process for producing gasoline, olefins and aromatics from oxygenates
US10011538B2 (en) 2014-10-27 2018-07-03 Exxonmobil Chemical Patents Inc. Method of making aromatic hydrocarbons
WO2016081082A1 (en) 2014-11-20 2016-05-26 Exxonmobil Chemical Patents Inc. Conversion of lignin to fuels and aromatics
US10196329B2 (en) 2014-11-21 2019-02-05 Exxonmobil Chemical Patents Inc. Process for making para-xylene
CN107001946B (zh) 2014-11-25 2019-07-05 巴杰许可有限责任公司 降低汽油中苯含量的方法
EP3230208B1 (en) 2014-12-11 2022-05-18 W. R. Grace & Co.-Conn. Preparation of mesoporous zeolites with reduced processing
US10781149B2 (en) 2014-12-19 2020-09-22 Exxonmobil Chemical Patents Inc. Transalkylation process
WO2016099893A1 (en) 2014-12-19 2016-06-23 Exxonmobil Chemical Patents Inc. Production and use of dialkylbiphenyl isomer mixtures
US20160176776A1 (en) 2014-12-22 2016-06-23 Exxonmobil Research And Engineering Company Conversion of oxygenates to aromatics
US10626019B2 (en) 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
WO2016148755A1 (en) 2015-03-19 2016-09-22 Exxonmobil Chemical Patents Inc. Process and apparatus for the production of para-xylene
JP2018508557A (ja) 2015-03-20 2018-03-29 エクソンモービル ケミカル パテンツ インコーポレイテッド オレフィン含有炭化水素供給物をオリゴマー化生成物または水素化オリゴマー化生成物に変換する方法
US10017433B2 (en) 2015-03-31 2018-07-10 Exxonmobil Chemical Patents Inc. Transalkylated cyclohexylbenzyl and biphenyl compounds
US10059638B2 (en) 2015-03-31 2018-08-28 Exxonmobil Chemical Patents Inc. Oxygenated hydrocarbon conversion zoned method
KR101974770B1 (ko) 2015-04-30 2019-05-02 엑손모빌 케미칼 패턴츠 인코포레이티드 파라-자일렌의 제조를 위한 방법 및 장치
WO2017048378A1 (en) 2015-09-17 2017-03-23 Exxonmobil Chemical Patents Inc. Process for recovering para-xylene using a metal organic framework adsorbent in a simulated moving-bed process
US10265688B2 (en) 2015-09-22 2019-04-23 Exxonmobil Chemical Patents Inc. Method and catalyst system for improving benzene purity in a xylenes isomerization process
US11203557B2 (en) 2015-09-25 2021-12-21 Exxonmobil Chemical Patents Inc. Catalyst and its use in dehydrocyclization processes
US10071938B2 (en) 2015-09-25 2018-09-11 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US9845272B2 (en) 2015-09-25 2017-12-19 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
US10202318B2 (en) 2015-09-25 2019-02-12 Exxonmobil Chemical Patents Inc. Catalyst and its use in hydrocarbon conversion process
WO2017052858A1 (en) 2015-09-25 2017-03-30 Exxonmobile Chemical Patents Inc. Conversion of non-aromatic hydrocarbon
US9815749B2 (en) 2015-09-25 2017-11-14 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US10273196B2 (en) 2015-09-25 2019-04-30 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
WO2017065771A1 (en) 2015-10-15 2017-04-20 Badger Licensing Llc Production of alkylaromatic compounds
CA3004303C (en) 2015-11-04 2020-06-30 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein
EP3371142A4 (en) 2015-11-04 2018-10-24 ExxonMobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
CN108349844B (zh) 2015-11-04 2021-07-27 埃克森美孚化学专利公司 燃烧管转化系统和方法
WO2017078891A1 (en) 2015-11-04 2017-05-11 Exxonmoble Chemical Patents Inc. Integrated gas turbine and conversion system process
WO2017078892A1 (en) 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
EP3371139A4 (en) 2015-11-04 2018-09-19 ExxonMobil Chemical Patents Inc. Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein
CA3004330C (en) 2015-11-04 2020-05-12 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
JP6728351B2 (ja) 2015-11-04 2020-07-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 非環式ｃ５化合物の生成
CA3004316C (en) 2015-11-04 2019-12-31 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein
WO2017105617A1 (en) 2015-12-15 2017-06-22 Exxonmobil Chemical Patents Inc. Process for xylenes isomerization
US9809509B2 (en) 2015-12-15 2017-11-07 Exxonmobil Chemical Patents Inc. Process for xylenes isomerization
WO2017105869A1 (en) 2015-12-16 2017-06-22 Exxonmobil Research And Engineering Company Methods for upgrading olefin-containing feeds
WO2017127288A1 (en) 2016-01-19 2017-07-27 Exxonmobil Research And Engineering Company Naphtha production from refinery fuel gas
US10899683B2 (en) 2016-02-17 2021-01-26 Badger Licensing Llc Process for producing ethylbenzene
US10906851B2 (en) 2016-02-26 2021-02-02 Exxonmobil Chemical Patents Inc. Process for recovering para-xylene
US20200325096A1 (en) 2016-04-08 2020-10-15 Exxonmobil Chemical Patents Inc. Oxidation of Methyl-substituted Biphenyl Compounds
US10843981B2 (en) 2016-04-25 2020-11-24 Exxonmobil Chemical Patents Inc. Catalytic aromatization
WO2017188934A1 (en) 2016-04-26 2017-11-02 Badger Licensing Llc Process for reducing the benzene content of gasoline
WO2017213749A1 (en) 2016-06-09 2017-12-14 Exxonmobil Chemical Patents Inc. A process for producing mono-alkylated aromatic compound
US10821425B2 (en) 2016-06-09 2020-11-03 Exxonmobil Chemical Patents Inc. Treatment of aromatic alkylation catalysts
US10351489B2 (en) 2016-06-30 2019-07-16 Exxonmobil Chemical Patents Inc. Processes for recovering paraxylene
US10300404B2 (en) 2016-06-30 2019-05-28 Exxonmobil Chemical Patents Inc. Process for the recovering of paraxylene
WO2018057125A2 (en) 2016-09-22 2018-03-29 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and/or benzene
BR112019006899A2 (pt) 2016-10-06 2019-07-02 Exxonmobil Chemical Patents Inc processo para metilar hidrocarbonetos aromáticos
JP6982068B2 (ja) 2016-10-06 2021-12-17 エクソンモービル・ケミカル・パテンツ・インク ベンゼンおよび／またはトルエンのメチル化によるパラキシレン製造用の触媒に選択性付与するプロセス
KR20210088742A (ko) 2016-10-06 2021-07-14 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법
WO2018071184A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and catalyst compositions used
WO2018071185A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and dual bed catalyst systems used
US20180170823A1 (en) 2016-12-15 2018-06-21 Exxonmobil Research And Engineering Company Efficient process for converting methanol to gasoline
US20180171244A1 (en) 2016-12-15 2018-06-21 Exxonmobil Research And Engineering Company Process for improving gasoline quality from cracked naphtha
WO2018111540A1 (en) 2016-12-15 2018-06-21 Exxonmobil Research And Engineering Company Efficient process for upgrading paraffins to gasoline
US10646862B2 (en) 2016-12-15 2020-05-12 Exxonmobil Research And Engineering Company Upgrading fuel gas using stoichiometric air for catalyst regeneration
WO2018111538A1 (en) 2016-12-15 2018-06-21 Exxonmobil Research And Engineering Company Upgrading hydrocarbons using stoichiometric or below stoichiometric air for catalyst regeneration
WO2018111543A1 (en) 2016-12-15 2018-06-21 Exxonmobil Research And Engineering Company Efficient process for converting heavy oil to gasoline
EP3559159A1 (en) 2016-12-20 2019-10-30 ExxonMobil Research and Engineering Company Upgrading ethane-containing light paraffins streams
US10717069B2 (en) 2016-12-20 2020-07-21 Exxonmobil Research And Engineering Company Fuel upgrading by reforming and dehydrocracking
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
KR102524765B1 (ko) 2017-02-16 2023-04-25 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 경질 파라핀 전환을 위한 고정층 방사류 반응기
WO2018160327A1 (en) 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
US10323196B2 (en) 2017-03-17 2019-06-18 Exxonmobil Research And Engineering Company Methods and systems for producing gasoline from light paraffins
WO2018183009A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
WO2018183012A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
CN110461997A (zh) 2017-04-05 2019-11-15 埃克森美孚研究工程公司 集成式甲醇分离和甲醇制汽油转化工艺
WO2018217337A1 (en) 2017-05-22 2018-11-29 Exxonmobil Chemical Patents Inc. Integrated aromatics formation and methylation
US10676410B2 (en) 2017-06-22 2020-06-09 Exxonmobil Chemical Patents Inc. Systems and processes for alkane aromatization
WO2019099247A1 (en) 2017-11-14 2019-05-23 Exxonmobil Research And Engineering Company Gasification with enriched oxygen for production of synthesis gas
US10407631B2 (en) 2017-11-14 2019-09-10 Exxonmobil Research And Engineering Company Gasification with enriched oxygen for production of synthesis gas
US10400177B2 (en) 2017-11-14 2019-09-03 Exxonmobil Research And Engineering Company Fluidized coking with increased production of liquids
US10604458B2 (en) 2017-11-30 2020-03-31 Exxonmobil Chemical Patents Inc. Systems and methods for aromatic alkylation
CN111448178B (zh) 2017-12-05 2023-01-06 埃克森美孚化学专利公司 二甲苯生产方法和系统
WO2019118230A1 (en) 2017-12-14 2019-06-20 Exxonmobil Chemical Patents Inc. Processes for isomerizing alpha olefins
WO2019125840A1 (en) 2017-12-21 2019-06-27 Exxonmobil Research And Engineering Company Upgrading paraffins and olefins
EP3728170A1 (en) 2017-12-22 2020-10-28 ExxonMobil Chemical Patents Inc. Catalysts for producing paraxylene by methylation of benzene and/or toluene
WO2019143495A1 (en) 2018-01-22 2019-07-25 Exxonmobil Chemical Patents Inc. Production and use of 3,4' and 4,4'-dimethylbiphenyl isomers
US11254882B2 (en) 2018-02-21 2022-02-22 Exxonmobil Chemical Patents Inc. Conversion of C2 hydrocarbons in the presence of methane
WO2019190774A1 (en) 2018-03-30 2019-10-03 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane c9+ aromatics
WO2019212784A1 (en) 2018-05-03 2019-11-07 Exxonmobil Chemical Patents Inc Preparation of an hydroalkylation catalyst
WO2020014060A1 (en) 2018-07-12 2020-01-16 Exxonmobil Research And Engineering Company Vehicle powertrain with on-board catalytic reformer
CN110743605B (zh) 2018-07-23 2021-07-27 中国科学院大连化学物理研究所 一种用于乙醇和苯制备乙苯的催化剂及其制备和应用
CN112996597B (zh) * 2018-10-30 2024-03-15 埃克森美孚化学专利公司 微孔分子筛催化剂的煅烧
US12383891B2 (en) 2018-11-15 2025-08-12 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method for preparation of hierarchical TS-1 molecular sieve
KR102580277B1 (ko) 2018-11-15 2023-09-18 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 계층적 다공성 ts-1 분자체의 제조 방법
US11384289B2 (en) 2019-01-18 2022-07-12 ExxonMobil Technology and Engineering Company Conversion of methanol to gasoline with integrated paraffin conversion
US10919830B2 (en) 2019-01-18 2021-02-16 Exxonmobil Research And Engineering Company Layered catalyst loading for synthesis gas conversion
CN113646081B (zh) 2019-03-18 2024-01-09 埃克森美孚科技工程公司 中孔催化剂化合物及其用途
CN113574038B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
WO2020197890A1 (en) 2019-03-28 2020-10-01 Exxonmobil Chemical Patents Inc. Processes for converting benzene and/or toluene via methylation
WO2020197888A1 (en) 2019-03-28 2020-10-01 Exxonmobil Chemical Patents Inc. Processes and systems for converting benzene and/or toluene via methylation
US12239964B2 (en) 2019-03-29 2025-03-04 ExxonMobil Engineering & Technology Company Catalysts and processes for converting aromatics
TWI749489B (zh) 2019-03-29 2021-12-11 美商艾克頌美孚化學專利股份有限公司 用於轉化芳族化合物之觸媒及方法
WO2021076259A1 (en) 2019-10-17 2021-04-22 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
US11827593B2 (en) 2019-10-17 2023-11-28 Exxonmobil Chemicals Patents Inc. Production of alkylaromatic compounds
US11591527B2 (en) 2019-10-22 2023-02-28 ExxonMobil Technology and Engineering Company Processes for producing high octane reformate having high C5+ yield
WO2021080754A1 (en) 2019-10-25 2021-04-29 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
CN116457323A (zh) 2020-11-06 2023-07-18 埃克森美孚化学专利公司 烷基芳族化合物的生产
EP4247920A1 (en) 2020-11-17 2023-09-27 ExxonMobil Chemical Patents Inc. Concurrent isomerization/hydrogenation of unsaturated polyalphaolefin in the presence of a high activity catalyst
WO2023287579A1 (en) 2021-07-16 2023-01-19 ExxonMobil Technology and Engineering Company Integrated conversion and oligomerization of bio-derived alcohols
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
CN118159511A (zh) 2021-10-12 2024-06-07 埃克森美孚化学专利公司 生产二甲苯产物的分段烷基化
EP4504878A2 (en) 2022-04-06 2025-02-12 ExxonMobil Technology and Engineering Company Isoparaffinic and iso-olefinic distillate compositions
JP2025511814A (ja) 2022-04-06 2025-04-16 エクソンモービル テクノロジー アンド エンジニアリング カンパニー イソパラフィンケロシン組成物
US12012561B2 (en) 2022-04-06 2024-06-18 ExxonMobil Technology and Engineering Company Methods for converting C2+ olefins to higher carbon number olefins
WO2025072077A1 (en) 2023-09-25 2025-04-03 ExxonMobil Technology and Engineering Company Olefinic renewable naphtha as gasoline blend component
WO2025226576A1 (en) 2024-04-25 2025-10-30 ExxonMobil Technology and Engineering Company Processes for producing isobutylene and isobutylene-based polymers

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
DE2213109A1 (de) * 1971-03-18 1972-09-21 Mobil Oil Corp Kristalline Zeolithe und Verfahren zu ihrer Herstellung
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
DE2438252A1 (de) * 1973-08-09 1975-02-20 Mobil Oil Corp Verfahren zur herstellung von aromatischen verbindungen
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
DE2518097A1 (de) * 1974-04-24 1975-11-13 Mobil Oil Corp Verfahren zur herstellung von kohlenwasserstoffen
DE2321399C2 (de) * 1972-04-28 1982-09-16 Mobil Oil Corp., 10017 New York, N.Y. Verfahren zur Alkylierung von aromatischen Kohlenwasserstoffen

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751506A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
DE2213109A1 (de) * 1971-03-18 1972-09-21 Mobil Oil Corp Kristalline Zeolithe und Verfahren zu ihrer Herstellung
DE2321399C2 (de) * 1972-04-28 1982-09-16 Mobil Oil Corp., 10017 New York, N.Y. Verfahren zur Alkylierung von aromatischen Kohlenwasserstoffen
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
DE2438252A1 (de) * 1973-08-09 1975-02-20 Mobil Oil Corp Verfahren zur herstellung von aromatischen verbindungen
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
DE2518097A1 (de) * 1974-04-24 1975-11-13 Mobil Oil Corp Verfahren zur herstellung von kohlenwasserstoffen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J. Cat., Bd.6, 1966, S.278-287 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2714239A1 (de) * 1976-03-31 1977-10-20 Mobil Oil Corp Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung
DE2756221A1 (de) * 1977-02-11 1978-08-17 Mobil Oil Corp Verfahren zur aethylierung von benzol
DE2826865A1 (de) * 1977-06-23 1979-01-18 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE3330912A1 (de) * 1982-08-27 1984-03-15 Toyo Soda Manufacturing Co., Ltd., Shinnanyo, Yamaguchi Verfahren zur herstellung von 1,2,4,5-tetraalkylbenzolen

Also Published As

Publication number Publication date
FR2312478B1 (OSRAM) 1980-02-08
NO761790L (OSRAM) 1976-11-30
US4016218A (en) 1977-04-05
JPS51143625A (en) 1976-12-10
CA1070714A (en) 1980-01-29
FR2312478A1 (fr) 1976-12-24
NO143498C (no) 1981-02-25
JPS607603B2 (ja) 1985-02-26
NO143498B (no) 1980-11-17
IT1060872B (it) 1982-09-30
GB1525323A (en) 1978-09-20
DE2624097C2 (OSRAM) 1988-06-09
NL7605626A (nl) 1976-12-01
ZA762844B (en) 1977-12-28
BE842040A (fr) 1976-11-22
AU1427876A (en) 1977-12-01

Similar Documents

Publication Publication Date Title
DE2624097C2 (OSRAM)
DE2714239C2 (OSRAM)
DE2560441C2 (de) Verfahren zur Umwandlung von Paraffinen zu einem Olefine enthaltenden Produkt
DE2321471C2 (de) Verfahren zum Alkylieren von aromatischen Kohlenwasserstoffen
DE2756221C2 (OSRAM)
DE2912068C2 (de) Verfahren zur Herstellung von leichten olefinischen Kohlenwasserstoffen
DE2819267A1 (de) Verfahren zur gewinnung von p-xylol
DE2400946A1 (de) Aromatisierungsverfahren
DE2949169A1 (de) Waermeausgeglichenes cyclisches verfahren zur herstellung von leichten olefinen
DE2633881A1 (de) Katalysator fuer die umwandlung von organischen verbindungen sowie herstellung und verwendung des katalysators
DE2826865C2 (OSRAM)
DE2438251A1 (de) Verfahren zur umwandlung von synthesegas in benzin
DE2746380A1 (de) Verfahren zum entparaffinieren von petroloelen
DE2615150A1 (de) Verfahren zur umwandlung von alkoholen und/oder aethern in olefine und anwendung dieses verfahrens
DE3524890C2 (de) Verfahren zur Herstellung Ethylen und Propylen
DE2321399C2 (de) Verfahren zur Alkylierung von aromatischen Kohlenwasserstoffen
DE2753867C2 (OSRAM)
DE2749024C2 (de) Kristalline Aluminosilicat-Zeolithe, Verfahren zu ihrer Herstellung und ihre Verwendung
DE3874658T2 (de) Zweistufensynthese von einem zeolith.
DE2819304C2 (OSRAM)
DE3306091C2 (OSRAM)
DE3490097T1 (de) Bindemittelfreie Zeolithkatalysatoren, Verfahren zu ihrer Herstellung und katalytische Reaktion mit ihnen
DE3009497A1 (de) Verfahren zur herstellung von aromatischen kohlenwasserstoffen und wasserstoff
DE2935863A1 (de) Verfahren zur herstellung eines kohlenwasserstoffgemisches
DE2442241C3 (de) Verwendung bestimmter Zeolithe zur Xylolisomerisierung

Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8128 New person/name/address of the agent

Representative=s name: KADOR, U., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 800

D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee