EP3371139A4 - Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein - Google Patents
Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein Download PDFInfo
- Publication number
- EP3371139A4 EP3371139A4 EP16862667.9A EP16862667A EP3371139A4 EP 3371139 A4 EP3371139 A4 EP 3371139A4 EP 16862667 A EP16862667 A EP 16862667A EP 3371139 A4 EP3371139 A4 EP 3371139A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- compounds
- acyclic
- cyclic
- conversion
- catalyst composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001875 compounds Chemical class 0.000 title 2
- 125000002015 acyclic group Chemical group 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
- 125000004122 cyclic group Chemical group 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
- B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
- B01J29/62—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
- B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
- B01J29/63—Iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7215—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L
- C07C2529/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L containing iron group metals, noble metals or copper
- C07C2529/62—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562250681P | 2015-11-04 | 2015-11-04 | |
| EP16153721 | 2016-02-02 | ||
| PCT/US2016/056023 WO2017078897A2 (en) | 2015-11-04 | 2016-10-07 | Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3371139A2 EP3371139A2 (en) | 2018-09-12 |
| EP3371139A4 true EP3371139A4 (en) | 2018-09-19 |
Family
ID=55304862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16862667.9A Withdrawn EP3371139A4 (en) | 2015-11-04 | 2016-10-07 | Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP3371139A4 (en) |
| JP (1) | JP6824265B2 (en) |
| CN (1) | CN108349843A (en) |
| CA (1) | CA3004308C (en) |
| WO (1) | WO2017078897A2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017078896A2 (en) * | 2015-11-04 | 2017-05-11 | Exxonmobil Chemical Patents Inc. | Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein |
| WO2022138746A1 (en) * | 2020-12-24 | 2022-06-30 | Ｅｎｅｏｓ株式会社 | Method for producing cyclopentadiene |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2438400A (en) * | 1945-11-24 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438404A (en) * | 1948-01-20 | 1948-03-23 | Sun Oil Co | Treatment of hydrocarbons |
| DE2535809A1 (en) * | 1974-08-13 | 1976-03-04 | Shell Int Research | Cyclic 5C hydrocarbons from n-pentane feeds - by contact with hydrogen on a platinum-silica catalyst |
| WO1989004818A1 (en) * | 1987-11-17 | 1989-06-01 | Mobil Oil Corporation | A dehydrogenation and dehydrocyclization catalyst, its synthesis and use |
| US4886926A (en) * | 1988-06-24 | 1989-12-12 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials |
| US20090062446A1 (en) * | 2007-09-04 | 2009-03-05 | General Electric Company | Composition and associated method |
| US20130153456A1 (en) * | 2011-12-15 | 2013-06-20 | General Electric Company | Containment case and method of manufacture |
| WO2013176712A1 (en) * | 2012-05-25 | 2013-11-28 | Exxonmobil Chemical Patents Inc. | Dicyclopentadiene based resin compositions and articles manufactured therefrom |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US28341A (en) | 1860-05-22 | Improvement in apparatus for condensing coal-oil | ||
| US2438399A (en) | 1945-11-24 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438401A (en) | 1946-02-26 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438398A (en) | 1947-08-19 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438403A (en) | 1947-08-19 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438402A (en) | 1947-08-19 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| NL238183A (en) | 1962-08-03 | |||
| NL6503410A (en) | 1963-02-21 | 1965-09-20 | ||
| US3442795A (en) | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
| US3308069A (en) | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| US3293192A (en) | 1965-08-23 | 1966-12-20 | Grace W R & Co | Zeolite z-14us and method of preparation thereof |
| US3524820A (en) | 1968-08-19 | 1970-08-18 | Universal Oil Prod Co | Preparation of rare earth metal exchanged crystalline alumino silicates |
| US3631209A (en) * | 1970-06-22 | 1971-12-28 | Goodyear Tire & Rubber | Preparation of cycloolefins |
| US3766093A (en) | 1972-01-07 | 1973-10-16 | Mobil Oil Corp | Treatment of organic cationcontaining zeolites |
| US3894104A (en) | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Aromatization of hetero-atom substituted hydrocarbons |
| US3972832A (en) | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| US4246202A (en) * | 1979-05-23 | 1981-01-20 | El Paso Products Company | Production of cyclic hydrocarbons from normal octenes |
| US4401556A (en) | 1979-11-13 | 1983-08-30 | Union Carbide Corporation | Midbarrel hydrocracking |
| JPH03501942A (en) * | 1987-11-17 | 1991-05-09 | モービル オイル コーポレーシヨン | Dehydrogenation and dehydrocyclization catalysts, their synthesis and applications |
| US5192728A (en) | 1988-06-24 | 1993-03-09 | Mobil Oil Corporation | Tin-colating microporous crystalline materials and their use as dehydrogenation, dehydrocyclization reforming catalysts |
| US5491119A (en) | 1989-10-30 | 1996-02-13 | Exxon Chemical Patents Inc. | Zeolite L |
| CN1030329C (en) * | 1991-12-12 | 1995-11-22 | 中国石油化工总公司石油化工科学研究院 | Catalyst for dehydroaromatization of alkane and its preparing process |
| US5254787A (en) | 1992-09-08 | 1993-10-19 | Mobil Oil Corp. | Dehydrogenation and dehydrocyclization using a non-acidic NU-87 catalyst |
| US9034287B2 (en) * | 2013-03-13 | 2015-05-19 | Basf Corporation | Catalyst compositions, articles, methods and systems |
| WO2017078896A2 (en) * | 2015-11-04 | 2017-05-11 | Exxonmobil Chemical Patents Inc. | Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein |
-
2016
- 2016-10-07 EP EP16862667.9A patent/EP3371139A4/en not_active Withdrawn
- 2016-10-07 CA CA3004308A patent/CA3004308C/en active Active
- 2016-10-07 JP JP2018522785A patent/JP6824265B2/en active Active
- 2016-10-07 CN CN201680064428.XA patent/CN108349843A/en active Pending
- 2016-10-07 WO PCT/US2016/056023 patent/WO2017078897A2/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2438400A (en) * | 1945-11-24 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
| US2438404A (en) * | 1948-01-20 | 1948-03-23 | Sun Oil Co | Treatment of hydrocarbons |
| DE2535809A1 (en) * | 1974-08-13 | 1976-03-04 | Shell Int Research | Cyclic 5C hydrocarbons from n-pentane feeds - by contact with hydrogen on a platinum-silica catalyst |
| WO1989004818A1 (en) * | 1987-11-17 | 1989-06-01 | Mobil Oil Corporation | A dehydrogenation and dehydrocyclization catalyst, its synthesis and use |
| US4886926A (en) * | 1988-06-24 | 1989-12-12 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials |
| US20090062446A1 (en) * | 2007-09-04 | 2009-03-05 | General Electric Company | Composition and associated method |
| US20130153456A1 (en) * | 2011-12-15 | 2013-06-20 | General Electric Company | Containment case and method of manufacture |
| WO2013176712A1 (en) * | 2012-05-25 | 2013-11-28 | Exxonmobil Chemical Patents Inc. | Dicyclopentadiene based resin compositions and articles manufactured therefrom |
Non-Patent Citations (2)
| Title |
|---|
| See also references of WO2017078897A2 * |
| V. SH. FEL'DBLYUM ET AL: "Cyclization and dehydrocyclization of C5 hydrocarbons over platinum nanocatalysts and in the presence of hydrogen sulfide", DOKLADY. CHEMISTRY, vol. 424, no. 2, February 2009 (2009-02-01), RU, pages 27 - 30, XP055267350, ISSN: 0012-5008, DOI: 10.1134/S0012500809020025 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA3004308A1 (en) | 2017-05-11 |
| CN108349843A (en) | 2018-07-31 |
| JP6824265B2 (en) | 2021-02-03 |
| CA3004308C (en) | 2020-05-12 |
| WO2017078897A3 (en) | 2018-03-01 |
| EP3371139A2 (en) | 2018-09-12 |
| JP2019500321A (en) | 2019-01-10 |
| WO2017078897A2 (en) | 2017-05-11 |
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| A4 | Supplementary search report drawn up and despatched |
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