BR112019006899A2 - processo para metilar hidrocarbonetos aromáticos - Google Patents
processo para metilar hidrocarbonetos aromáticosInfo
- Publication number
- BR112019006899A2 BR112019006899A2 BR112019006899A BR112019006899A BR112019006899A2 BR 112019006899 A2 BR112019006899 A2 BR 112019006899A2 BR 112019006899 A BR112019006899 A BR 112019006899A BR 112019006899 A BR112019006899 A BR 112019006899A BR 112019006899 A2 BR112019006899 A2 BR 112019006899A2
- Authority
- BR
- Brazil
- Prior art keywords
- paraxylene
- alkylation
- stream
- depleted
- contacted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/08—Xylenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00539—Pressure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
a presente invenção refere-se a um processo para produzir paraxileno uma matéria-prima de hidrocarboneto compreendendo benzeno e/ou tolueno é colocada em contato com um reagente de alquilação compreendendo metanol e/ou éter dimetílico em uma zona de reação de alquilação em condições de alquilação na presença de um catalisador de alquilação para produzir um produto alquilado compreendendo xilenos. o catalisador de alquilação compreende uma peneira molecular com um índice de restrição < 5 e as condições de alquilação compreendem uma temperatura menor que 500°c. pelo menos parte do produto alquilado é fornecido a uma unidade de recuperação de paraxileno para recuperar paraxileno e produzir uma corrente esgotada em paraxileno, que é então colocada em contato com um catalisador de isomerização de xileno em condições eficazes para isomerizar xilenos na corrente esgotada de paraxileno e produzir uma corrente isomerizada que possui uma maior concentração de paraxileno que a corrente esgotada em paraxileno. pelo menos parte da corrente isomerizada é então reciclada para a unidade de recuperação de paraxileno para recuperar o paraxileno nela.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662405036P | 2016-10-06 | 2016-10-06 | |
US201662405045P | 2016-10-06 | 2016-10-06 | |
PCT/US2017/051179 WO2018067281A1 (en) | 2016-10-06 | 2017-09-12 | Process for methylating aromatic hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112019006899A2 true BR112019006899A2 (pt) | 2019-07-02 |
Family
ID=61832196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019006899A BR112019006899A2 (pt) | 2016-10-06 | 2017-09-12 | processo para metilar hidrocarbonetos aromáticos |
Country Status (6)
Country | Link |
---|---|
US (1) | US10696608B2 (pt) |
JP (1) | JP6899430B2 (pt) |
KR (1) | KR102235872B1 (pt) |
CN (1) | CN109963828A (pt) |
BR (1) | BR112019006899A2 (pt) |
WO (1) | WO2018067281A1 (pt) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10246383B2 (en) | 2016-10-06 | 2019-04-02 | Exxonmobil Chemical Patents Inc. | Process for producing paraxylene by methylation of benzene and/or toluene |
CN110023271B (zh) | 2016-10-06 | 2022-08-19 | 埃克森美孚化学专利公司 | 用于通过苯和/或甲苯的甲基化制备对二甲苯的催化剂的选择性去活化方法 |
BR112019006899A2 (pt) | 2016-10-06 | 2019-07-02 | Exxonmobil Chemical Patents Inc | processo para metilar hidrocarbonetos aromáticos |
US11208365B2 (en) | 2016-12-20 | 2021-12-28 | Uop Llc | Processes and apparatuses for methylation of aromatics in an aromatics complex |
US11673849B2 (en) | 2016-12-21 | 2023-06-13 | Exxonmobil Chemical Patents Inc. | Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene |
US11130719B2 (en) * | 2017-12-05 | 2021-09-28 | Uop Llc | Processes and apparatuses for methylation of aromatics in an aromatics complex |
US11130720B2 (en) | 2018-03-23 | 2021-09-28 | Uop Llc | Processes for methylation of aromatics in an aromatics complex |
CN111954652B (zh) * | 2018-03-30 | 2022-11-08 | 埃克森美孚化学专利公司 | 混合二甲苯和高辛烷值c9+芳族化合物的共同制备方法 |
US11884615B2 (en) | 2021-01-27 | 2024-01-30 | Saudi Arabian Oil Company | Modified beta zeolitic (*BEA) catalyst for isomerization of alkylated aromatics, and method for isomerization of alkylated aromatics |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3755483A (en) | 1972-04-28 | 1973-08-28 | Mobil Oil | Vapor phase alkylation in presence of crystalline aluminosilicate catalyst |
US4002698A (en) | 1975-08-19 | 1977-01-11 | Mobil Oil Corporation | Methylation of toluene in the presence of a phosphorus-modified activated crystalline aluminosilicate catalyst |
US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
US5545788A (en) | 1991-06-19 | 1996-08-13 | Mobil Oil Corporation | Process for the alkylation of benzene-rich reformate using MCM-49 |
US5488194A (en) * | 1994-05-16 | 1996-01-30 | Mobil Oil Corp. | Selective production of para-dialkyl substituted benzenes and catalyst therefor |
US5939597A (en) | 1994-11-10 | 1999-08-17 | Mobil Oil Corporation | Fluid bed process for para-xylene production |
KR970707061A (ko) * | 1994-11-10 | 1997-12-01 | 맬컴 디. 킨 | 톨루엔 메틸화 반응에 의한 파라-크실렌의 선택적 제조 방법(selective paraxylene production by toluene methylation) |
ZA978671B (en) * | 1996-10-02 | 1999-03-26 | Mobil Oil Corp | Selective para-xylene production by toluene methylation |
US6423879B1 (en) | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
US6642426B1 (en) | 1998-10-05 | 2003-11-04 | David L. Johnson | Fluid-bed aromatics alkylation with staged injection of alkylating agents |
AU2003253666A1 (en) | 2002-06-19 | 2004-01-06 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes by reactive distillation of reformate |
WO2004000767A1 (en) | 2002-06-19 | 2003-12-31 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes from reformate |
EP1523535A1 (en) * | 2002-06-19 | 2005-04-20 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes from reformate |
JP4843501B2 (ja) | 2003-12-31 | 2011-12-21 | エクソンモービル・ケミカル・パテンツ・インク | 芳香族のアルキル化プロセス |
US20080058566A1 (en) | 2006-09-05 | 2008-03-06 | Fina Technology, Inc. | Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst |
US8115041B2 (en) | 2008-04-02 | 2012-02-14 | Saudi Basic Industries Corporation | Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process |
CN201433376Y (zh) | 2009-07-08 | 2010-03-31 | 高进雄 | 太阳能扫地吸尘环卫车 |
WO2012021256A2 (en) * | 2010-08-10 | 2012-02-16 | Exxonmobil Chemical Patents Inc. | Methane conversion process |
WO2012047401A2 (en) | 2010-09-30 | 2012-04-12 | Exxonmobil Chemical Patents Inc. | Regeneration of metal-containing catalysts |
CN103263946B (zh) * | 2013-06-08 | 2015-02-25 | 张宇 | 一种多孔状纳米二氧化硅/mcm-22分子筛催化剂的制备方法 |
IN2013MU02754A (pt) | 2013-08-23 | 2015-07-03 | Hindustan Petroleum Corp Ltd | |
US9598332B2 (en) * | 2013-12-20 | 2017-03-21 | Exxonmobil Chemical Patents Inc. | Production of para-xylene |
WO2015094500A2 (en) * | 2013-12-20 | 2015-06-25 | Exxonmobil Chemical Patents Inc. | Production of para-xylene |
JP6389284B2 (ja) * | 2014-06-30 | 2018-09-12 | エクソンモービル・ケミカル・パテンツ・インク | パラキシレンの製造方法 |
BR112019006899A2 (pt) | 2016-10-06 | 2019-07-02 | Exxonmobil Chemical Patents Inc | processo para metilar hidrocarbonetos aromáticos |
CN110023271B (zh) | 2016-10-06 | 2022-08-19 | 埃克森美孚化学专利公司 | 用于通过苯和/或甲苯的甲基化制备对二甲苯的催化剂的选择性去活化方法 |
US10246383B2 (en) | 2016-10-06 | 2019-04-02 | Exxonmobil Chemical Patents Inc. | Process for producing paraxylene by methylation of benzene and/or toluene |
US11208365B2 (en) | 2016-12-20 | 2021-12-28 | Uop Llc | Processes and apparatuses for methylation of aromatics in an aromatics complex |
-
2017
- 2017-09-12 BR BR112019006899A patent/BR112019006899A2/pt not_active Application Discontinuation
- 2017-09-12 WO PCT/US2017/051179 patent/WO2018067281A1/en active Application Filing
- 2017-09-12 CN CN201780070155.4A patent/CN109963828A/zh active Pending
- 2017-09-12 JP JP2019518466A patent/JP6899430B2/ja active Active
- 2017-09-12 US US16/336,034 patent/US10696608B2/en active Active
- 2017-09-12 KR KR1020197009880A patent/KR102235872B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN109963828A (zh) | 2019-07-02 |
JP2019537563A (ja) | 2019-12-26 |
US20190218159A1 (en) | 2019-07-18 |
KR102235872B1 (ko) | 2021-04-06 |
WO2018067281A1 (en) | 2018-04-12 |
KR20190045933A (ko) | 2019-05-03 |
US10696608B2 (en) | 2020-06-30 |
JP6899430B2 (ja) | 2021-07-07 |
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