CN112867478A - 用于处理毛发的毛发处理组合物、方法和套件 - Google Patents
用于处理毛发的毛发处理组合物、方法和套件 Download PDFInfo
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- CN112867478A CN112867478A CN201980067548.9A CN201980067548A CN112867478A CN 112867478 A CN112867478 A CN 112867478A CN 201980067548 A CN201980067548 A CN 201980067548A CN 112867478 A CN112867478 A CN 112867478A
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- acid
- hair
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- hair treatment
- salt
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Abstract
本发明涉及头发处理组合物,其包括功能为赋予头发期望的美容特性的组分的独特组合。所述头发处理组合物通常包括:至少0.5重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐;一种或多种选自二胺、多胺、烷基胺、链烷醇胺及其混合物的胺;一种或多种果聚糖多糖;一种或多种前溶剂;和水。
Description
技术领域
本公开涉及对改善毛发质量特别有用的毛发处理组合物。还公开了包括毛发处理组合物的套件和使用该毛发处理组合物的方法。
背景技术
许多消费者期望使用通过如下方式来改善角质基质(如,毛发)外观的美容和护理组合物:其例如通过改变毛发颜色、样式和/或形状,和/或通过赋予毛发各种美容特性(如,光泽)和调理。许多已知的用于改善毛发外观的组合物和方法都涉及对头发的化学处理。
举例来说,改变毛发颜色的过程可能涉及在毛发上附着一种人造色素,从而为毛发提供不同的色度或颜色,和/或提升(lift)发色,例如将深发色淡化至较浅的色度。提升发色的过程(也称为淡化(或脱色))通常需要使用氧化剂。通常通过将毛发改色组合物施加到头发上之前和之后的色调高度的变化来评估头发的淡化。该变化对应于淡化或提升的程度或水平。“色调”的概念基于自然色度的分类,一种色调将每种色度与紧邻其后或紧靠其前的色度分开,这是发型设计专业人员众所周知的。色调高度或水平的范围可以是从1(黑色)到10(浅金色),一个单位对应一种色调;因此,数字越大,色度越浅或提升程度越大。
另外,有许多用于造型或改变毛发形状的技术和组合物。例如,被称为“毛发松弛剂”或“直发剂”的护发产品可以松弛或拉直包括烫卷发在内的卷曲或卷缩发。拉直或松弛非常卷曲的毛发的卷可以增加这种毛发的可管理性和造型的容易度。相反,用于永久性烫卷头发的组合物将赋予直发卷曲或波浪感。可以将不同类型的组合物施加到头发上,以改变其形状并使其更易于管理,例如碱性和酸性组合物。毛发松弛剂、直发剂、烫发剂(perm)和/或卷发剂(wave)可以由专业人员在美发沙龙施用或由个人消费者在家中施用。
虽然染色或提色组合物可以有效地改变发色,而松弛、拉直、烫发和卷发组合物可以有效地改变头发的形状,但是这些化学处理剂会损坏毛发纤维和/或刺激头皮。因此,为了减少或避免对毛发的损害,以及改善组合物的美容性能,人们一直在寻求使用新的和另外的组分以及各成分的新组合。
但是,组分或成分组合的选择可能会带来困难——它们不能损害其他化妆品特质,如组合物的施用的简便性和均匀性、流变学或粘度特性和稳定性、颜色沉积和目标色度的形成,和/或导致更多不利因素,如增加毛发损伤或使毛发看起来更不健康。因此,期望向消费者提供可以化学处理毛发同时对毛发提供其他美容优点(如光泽、调理、纤维强度和/或健康外观),但避免或最小化毛发损伤的组合物和方法。
此外,天然的和敏化的或化学处理过的毛发都可以包含几种带负电荷的部分,例如,羧酸盐(由氨基酸和硫酯键的水解而产生)和/或磺酸盐(由二硫键的氧化而产生)。这些带负电的部分会降低毛发的美容性能。而且,当毛发被化学处理或被损伤时,毛发中的二硫键(两个半胱氨酸单元之间的二硫键)可被还原或断裂,从而导致巯基和/或半胱氨酸的形成。因此,不断需要有助于改善毛发特性的毛发处理组合物。
发明内容
本发明的一个方面涉及一种毛发处理组合物,其包括:
-至少0.5重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐;
-一种或多种胺,其选自二胺、多胺、烷基胺、链烷醇胺及其混合物;
-一种或多种果聚糖多糖;
-一种或多种前溶剂(prosolvent);和
-水。
在一个或多个实施方案中,该最少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐是二羧酸和/或其盐。在一些实施方案中,其中所述组合物包括至少一种二羧酸和/或其盐,并且该至少一种二羧酸和/或其盐选自:草酸、丙二酸、苹果酸、戊二酸、柠康酸、琥珀酸、己二酸、酒石酸、富马酸、马来酸、癸二酸、壬二酸、十二烷二酸、邻苯二甲酸、间苯二甲酸、对苯二甲酸、2,6-萘二酸及其盐。在一个或多个实施方案中,该至少一种二羧酸和/或其盐是马来酸、丙二酸和/或其盐。在一些实施方案中,组合物包括至少一种三羧酸和/或其盐,并且该至少一种三羧酸和/或其盐选自:柠檬酸、异柠檬酸、乌头酸、丙烷-1,2,3-三羧酸、苯-1,3,5-三羧酸及其盐。在一个或多个实施方案中,该至少一种三羧酸和/或其盐是柠檬酸和/或其盐。在一些实施方案中,所述组合物包括至少0.5至约20重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐,基于毛发处理组合物的总重量计。在一个或多个实施方案中,所述组合物包括一种或多种选自式(II)的化合物的烷基胺和/或链烷醇胺:
NR3R4R5
(II)
其中,R3、R4和R5独立地是H、C1-C40烷基、C1-C40单羟基烷基或C2-C40多羟基烷基,条件是R3、R4和R5中的至少一个是烷基或单羟基烷基或多羟基烷基。在一些实施方案中,所述组合物包括一种或多种链烷醇胺,其选自单乙醇胺、二乙醇胺、三乙醇胺、单异丙醇胺、二异丙醇胺、N-二甲氨基-乙醇胺、2-氨基-2-甲基-1-丙醇、三异丙醇胺、2-氨基-2-甲基-1,3-丙二醇、3-氨基-1,2-丙二醇、3-二甲氨基-1,2-丙二醇、三(羟基甲基氨基)甲烷及其混合物。在一个或多个实施方案中,所述组合物包括单乙醇胺。在一些实施方案中,一种或多种胺的总量是约1至约20重量%,基于毛发处理组合物的总重量计。在一个或多个实施方案中,一种或多种果聚糖多糖是菊粉多糖和/或左聚糖(levan)多糖。
在一些实施方案中,一种或多种果聚糖多糖包括菊粉。在一些实施方案中,一种或多种果聚糖多糖以约1至约5重量%的量存在,基于毛发处理组合物的总重量计。在一个或多个实施方案中,一种或多种前溶剂选自己二醇、丁二醇、丙二醇,及其组合。
任何上述实施方案均可组合。举例来说,在一些实施方案中,毛发处理组合物包括:
-约2至约4重量%的马来酸和/或其盐;
-约1至约3重量%的乙醇胺;
-约1至约5重量%的菊粉;
-约2至约4重量%的己二醇和丁二醇的混合物,和
-水。
本发明的另一方面涉及处理毛发的方法。在一些实施方案中,该方法包括将本文所述的任何组合物施用于毛发。在一个或多个实施方案中,将该组合物作为洗发剂或调理程序的一部分施用于毛发。在一些实施方案中,将化学松弛剂施加至毛发之后,施加所述组合物。
具体实施方式
术语“毛发处理组合物”涵盖用于毛发的各种类型的组合物,例如化学松弛剂组合物、洗发剂、调理剂、洗发水、发用洗剂、发用凝胶、摩丝类(mouse-type)产品、喷雾剂等。毛发处理组合物以其为毛发提供美容益处的能力为特征。众所周知,洗发剂为毛发提供清洁益处,调理剂为毛发提供调理益处,而凝胶可以为毛发提供造型益处。可以赋予毛发的其他益处的非限制性实例包括强度、光滑度、柔软度和柔顺度。
本公开的毛发处理组合物通常包括:
-至少0.5重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐;
-一种或多种选自二胺、多胺、烷基胺、链烷醇胺及其混合物的胺;
-一种或多种果聚糖多糖;
-一种或多种前溶剂;和
-水。
以成分的独特组合为特征的上述组合物,同时有利地提供毛发强化的益处和造型益处。
本文所述的毛发处理组合物可以是任何合适的物理形式。合适的形式包括但不限于低至中等粘度的液体、洗剂、乳、摩丝、喷雾剂、凝胶、霜剂、糊剂、粘土状物、棒状物、调理剂等。例如,喷雾制剂可以由包括气雾剂分配器或泵式喷雾分配器的容器分配。这样的分配器在本领域中是已知的,并且可以从各种制造商处商购获得。当从加压的气雾剂容器中分配喷雾制剂时,可以使用推进剂将组合物从容器中推出。合适的推进剂包括但不限于可液化气体或卤化推进剂。合适的推进剂的例子包括二甲基醚和烃类推进剂如丙烷、正丁烷、异丁烷、CFCs和CFC替代物推进剂。推进剂可以单独使用或混合使用。此外,免洗型(leave-on)毛发造型组合物可以为乳液形式(例如油包水型或水包油型乳液)。在一些情况下,免洗型(leave-in)毛发造型组合物为糊状形式,其可以是可用手指涂在整个头发上的半固体产品。
毛发处理组合物可以包装在各种不同的容器中,例如,即用型容器。有用包装的非限制性实例包括管、广口瓶、盖式包装(cap)、单位剂量包装和瓶,包括可挤压的管和瓶。
非聚合的单羧酸、二羧酸或三羧酸
非聚合的单羧酸、二羧酸或三羧酸是具有一个(单)、两个(二)或三个(三)羧基(-COOH)的有机化合物。非聚合的单羧酸、二羧酸和三羧酸和/或其盐通常具有小于约500g/mol,小于约400g/mol或小于约300g/mol的分子量。
单羧酸或其盐的非限制性实例包括甲酸、乙酸、丙酸、丁酸、戊酸、己酸、庚酸、辛酸、壬酸、癸酸、十一酸、月桂酸、十三酸、月桂酸、十三酸、肉豆蔻酸、十五酸、棕榈酸、十七酸、硬脂酸、十九酸、花生酸、乳酸、其盐、及其混合物。在一些情况下,所述毛发处理组合物至少包括乳酸和/或其盐。
二羧酸和/或其盐的非限制性实例包括草酸、丙二酸、苹果酸、戊二酸、柠康酸、琥珀酸、己二酸、酒石酸、富马酸、马来酸、癸二酸、壬二酸、十二烷二酸、邻苯二甲酸、间苯二甲酸、对苯二甲酸、2,6-萘二酸、其盐,及其混合物。在一些情况下,毛发处理组合物包括草酸、丙二酸、苹果酸、马来酸、其盐或其混合物。
三羧酸及其盐的非限制性实例包括至少一种选自柠檬酸、异柠檬酸,乌头酸,丙烷-1,2,3-三羧酸,苯-1,3,5-三羧酸、其盐及其混合物的三羧酸和/或其盐。在一些例子中,毛发处理组合物至少包括柠檬酸和/或其盐。
在一些情况下,毛发处理组合物包括至少一种或多种二羧酸和/或其盐,特别是草酸、丙二酸、苹果酸、马来酸、其盐或其混合物。特别有用的二羧酸是丙二酸和/或其盐。
至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐的总量为至少0.5重量%,基于毛发处理组合物的总重量计。在一些情况下,至少一种非聚合的单羧酸、二羧酸或三羧酸和/或盐的总量为至少0.6、0.7、0.8、0.9或1重量%,最高至约15、20、25或30重量%。此外,至少一种非聚合的单羧酸、二羧酸或三羧酸,和/或其盐的总量可以为至少0.5重量%至约50重量%,至少0.5重量%至约40重量%,至少0.5重量%至约30重量%,至少0.5重量%至约20重量%,至少0.5重量%至约10重量%,至少0.5重量%至约5重量%,至少0.8重量%至约50重量%,至少0.8重量%至约40重量%,至少0.8重量%至约30重量%,约0.8至约20重量%,约0.8至约10重量%,约0.8重量%至约5重量%,约1重量%至约50重量%,约重量%至约40重量%,约1重量%至约30重量%,约1重量%至约20重量%,约1重量%至约10重量%,约1重量%至约5重量%,约2重量%至约50重量%,约2重量%至约40重量%,约2重量%至约30重量%,约2重量%至约20重量%,约2重量%至约10重量%,或约2重量%至约5重量%。
胺
可以在毛发处理组合物中使用的胺类型的非限制性实例众多,但是可以包括二胺、多胺、烷基胺、链烷醇胺及其混合物。所述一种或多种胺可以是伯、仲、叔胺及其混合物。
二胺
可能有用的二胺的非限制性实例是伯胺和仲胺。二胺可包括伯胺基和仲胺基两者。任选的二胺可包括至少一个环氧乙烷基团。举例来说,二胺中可存在1至4个环氧乙烷基团。二胺可任选地包括环氧丙烷基团。例如,二胺中可存在1至4个环氧丙烷基团。二胺的非限制性实例包括4,9-二氧杂十二烷-二胺;4,7,10-三氧杂-1,13-十三烷二胺;乙二胺;聚氧丙二胺;聚乙二醇二胺;三乙二醇二胺(2OE);n-(2-羟基乙基)-乙二胺;1,3-二氨基丙烷;1,7-二氨基庚烷;1,4-二氨基丁烷;1,2-二氨基丙烷;1,6-二氨基己烷;1,11-二氨基-3,6,9-三氧杂十一烷;1,5-二氨基戊烷;聚氧乙二胺;2,2-二甲基-1,3-丙二胺;2,2-双(氨基乙氧基)丙烷;4,7,10-三氧杂-1,13-十三烷二胺;1,3-二氨基戊烷;4,7,10-三氧杂-1,13;1,5-二氨基-2-甲基戊烷;(3s,4s)-(-)-3,4-己二胺二盐酸盐;1,9-二氨基壬烷及其混合物。
在一些情况下,二胺可以选自:4,9-二氧杂十二烷-二胺、4,7,10-三氧杂-1,13-十三烷二胺、乙二胺、聚氧丙二胺、聚乙二醇二胺、三乙二醇二胺(2OE);n-(2-羟基乙基)-亚乙基二胺;1,3-二氨基丙烷、1,7-二氨基庚烷、1,4-二氨基丁烷、1,2-二氨基丙烷、1,6-二氨基己烷、1,11-二氨基-3,6,9-三氧杂十一烷、1,5-二氨基戊烷、聚氧乙二胺、2,2-二甲基-1,3-丙二胺、2,2-双(氨基乙氧基)丙烷、4,7,10-三氧杂-1,13-十三烷二胺、1,3-氨基戊烷、4,7,10-三氧杂-1,13;1,5-二氨基-2-甲基戊烷、(3s,4s)-(-)-3,4-己二胺二盐酸盐、1,9-二氨基壬烷及其混合物。
多胺
多胺具有两个以上的氨基。在一些情况下,本公开的组合物可以包含一种或多种多胺,但是在一些情况下,述组合物不含或基本上不含多胺。多胺可以是例如包含多个氨基的氨基化多糖,例如,氨基化多糖的的水解物。
多胺也可以是包含多个氨基的聚合物,其包括均聚物、共聚合物和三元聚合物。
在一些情况下,多胺选自聚乙烯亚胺。聚乙烯亚胺可任选地被取代。可用的聚乙烯亚胺的非限制性实例包括商购自BASF的Lupasol产品。Lupasol聚乙烯亚胺的合适的实例包括Lupasol PS、Lupasol PL、Lupasol PR8515、Lupasol G20、Lupasol G35以及Lupasol SC聚乙烯亚胺反应产品(如,Lupasol SC-61B、Lupasol SC-62J和Lupasol SC-86X)。可用于本发明的组合物中的聚乙烯亚胺的其他非限制性实例是商购自Aceto的Epomin产品。Epomin聚乙烯亚胺的合适的实例包括Epomin SP-006、Epomin SP-012、Epomin SP-018和EpominP-1000。合适多胺还选自聚乙烯胺。其实例包括BASF的Lupamines 9095、9030、9010、5095、1595。
多胺化合物还可被取代。这样的化合物的实例是Cognis的PEG-15Cocopolyamine。
在一些情况下,多胺选自蛋白质和蛋白质衍生物。合适的蛋白质和蛋白质衍生物的非限制性实例包括C.T.F.A国际化妆品成分词典和手册(International CosmeticIngredient Dictionary and Handbook),第8版,第2卷,(2000)的第1701至1703页中列出的那些,其通过引用整体并入本文。在一些情况下,至少一种多胺选自小麦蛋白、大豆蛋白、燕麦蛋白、胶原蛋白和角蛋白。
多胺可以是烷氧基化的多胺。烷氧基化的多胺可选自具有至少两个氨基和至少一个烷氧基化度的胺化合物。烷氧基化作用由可以选自环氧乙烷和环氧丙烷的环氧烷烃基团提供。合适的烷氧基化多胺的非限制性实例包括对应于下式的化合物:
NH2R(R'CHCH2O)x(R'CHCH2O)y(R'CHCH2O)z-RNH2
其中R表示-CH2-、-CH2CH2-、-CHCH3-或-C(CH3)2-基团,或直链或支链的、非环状或环状的、饱和或不饱和的、脂族或芳香族的、取代的或未取代的含有至少3个碳原子的烃基;x、y和z彼此独立地表示0至约100的数字;R'表示氢,或烷基,优选甲基;并且x+y+z之和至少是1。在一些情况下,R是支链或支链的、非环烷基或烯基或烷基苯基;x、y和z彼此独立,优选表示2至100的数字。
烷氧基化多胺的非限制性实例包括,例如,十四烷基氧丙基-1,3-二氨基丙烷;C12-14烷基氧丙基-1,3-二氨基丙烷;C12-15烷基氧丙基胺和可从Tomah以TOMAH DA-17的商品名购得的其他类似材料。烷氧基化多胺的其他实例是属于Jeffamine系列的二胺化合物,例如可从犹他州盐湖城的Huntsman Corporation获得的JEFFAMINE D和JEFFAMINE ED系列。这些JEFFAMINE化合物的实例是JEFFAMINE D230、JEFFAMINE D400、JEFFAMINE D2000、JEFFAMINE D4000、JEFFAMINE HK-511、JEFFAMINE ED600、JEFFAMINE ED900和JEFFAMINEED2003。JEFFAMINE D系列化合物是胺封端的PPG(聚丙二醇),而JEFFAMINE ED系列化合物基于聚醚二胺,主要具有PEG(聚乙二醇)骨架。
合适的二胺形式的烷氧基化多胺的其他非限制性实例包括对应于下式的化合物:
NH2(CH2)xOCH2CH2O(CH2)xNH2
其中x是2或3。
烷氧基化多胺的实例是可从犹他州盐湖城的Huntsman Corporation获得的属于JEFFAMINE系列的二胺化合物,例如JEFFAMINE EDR148和JEFFAMINE EDR176。
三胺形式的烷氧基化多胺的其他非限制性实例包括对应于下式的化合物:
其中R是氢、-CH2或-C2H5,n=0或1,并且x、y和z彼此独立地表示0至100的数字且其和x+y+z至少是1。
烷氧基化多胺的实例是属于Jeffamine系列的三胺化合物,例如可从犹他州盐湖城的Huntsman Corporation获得的Jeffamine T系列。Jeffamine T系列化合物的实例是JEFFAMINE T403、JEFFAMINE T3000和JEFF胺T5000。Jeffamine T系列化合物是通过使PO与三元醇引发剂反应,然后使末端羟基胺化而制得的三胺。
烷基胺和链烷醇胺
组合物可包括的一种或多种烷基胺和/或一种或多种链烷醇胺包括式(II)的化合物:
NR3R4R5
(II)
其中R3、R4和R5独立地是H、C1-C40烷基、C1-C40单羟基烷基或C2-C40多羟基烷基,条件是R3、R4和R5中的至少一个是烷基或单羟基烷基或多羟基烷基。在一些情况下,R3、R4和R5独立地是H、C1-C2烷基、C1-C20单羟基烷基或C2-C20多羟基烷基,条件是R3、R4和R5中的至少一个是烷基或单羟基烷基或多羟基烷基。最后,R3、R4和R5可独立地是H、C1-C10烷基、C1-C10单羟基烷基或C2-C10多羟基烷基,条件是R3、R4和R5中的至少一个是烷基或单羟基烷基或多羟基烷基。
链烷醇胺的非限制性实例包括单乙醇胺、二乙醇胺、三乙醇胺、单异丙醇胺、二异丙醇胺、N-二甲氨基-乙醇胺、2-氨基-2-甲基-1-丙醇、三异丙醇胺、2-氨基-2-甲基-1,3-丙二醇、3-氨基-1,2-丙二醇、3-二甲氨基-1,2-丙二醇、三(羟基甲基氨基)甲烷及其混合物。在一些情况下,组合物至少包括单乙醇胺。在一些情况下,组合物至少包括单乙醇胺。
烷基胺的其他非限制性实例包括对应于下式的脂族胺化合物及其盐:
RN(R')2
其中R是包含至少6个碳原子的烃基。另外,R可以是直链或支链、非环或环状、饱和或不饱和、脂族或芳族、取代或未取代的。通常,R为直链或支链的非环烷基或烯基,或烷基苯基;并且基团R'(其可以相同或不同)表示H或包含少于6个碳原子的烃基。另外,基团R'(其可以相同或不同)是直链或支链、非环或环状、饱和或不饱和、取代或未取代的。在一些情况下,基团R'(其可以相同或不同)为H或甲基。
在一些情况下,烷基胺包括但不限于以下例子:二甲基月桂胺、二甲基山嵛胺(behenamine)、二甲基椰油胺、二甲基肉豆蔻胺、二甲基棕榈胺、二甲基硬脂胺、二甲基牛脂胺、二甲基大豆胺、硬脂胺、大豆胺、椰油胺、月桂胺、棕榈胺、油胺,牛脂胺及其混合物。
烷基单胺的其他非限制性实例包括对应于下式的酰胺基胺化合物及其盐:
RCONHR'N(R”)2
其中:R是含有至少6个碳原子的烃基。另外,R可以是直链或支链、非环或环状、饱和或不饱和、脂族或芳族、取代或未取代的。通常,R为直链或支链的非环烷基或烯基或烷基苯基;且R'是包含少于6个碳原子数,或2或3个碳原子的二价烃基基团,且R”是H或包含少于6个碳原子的烃基。另外,R”是直链或支链、非环或环状、饱和或不饱和、取代或未取代的。通常,R”是直链或支链的非环烷基或烯基。在一些情况下,R”是H或甲基。
可用于本公开的组合物中的氨基酰胺的实例包括但不限于以下:油酰胺丙基二甲胺(oleamidopropyl dimethylamine)、硬脂酰胺丙基二甲胺(stearamidopropyldimethylamine)、异硬脂酰胺丙基二甲胺(isostearamidopropyl dimethylamine)、硬脂酰胺乙基二甲胺(stearamidoethyl dimethylamine)、月桂酰胺丙基二甲胺(lauramidopropyl dimethylamine)、肉豆蔻酰胺丙基二甲胺(myristamidopropyldimethylamine)、山嵛酰胺丙基二甲胺(behenamidopropyl dimethylamine)、二亚油酰胺丙基二甲胺(dilinoleamidopropyl dimethylamine)、棕榈酰胺丙基二甲胺(palmitamidopropyl dimethylamine)、蓖麻油酰胺丙基二甲胺(ricinoleamindopropyldimethylamine)、大豆酰氨丙基二甲胺(soyamidopropyl dimethylamine)、小麦胚芽酰胺丙基二甲胺(wheat germamidopropyl dimethylamine)、向日葵籽酰胺丙基二甲基胺(sunflowerseedamidopropyl dimethylamine)、扁桃仁酰胺丙基二甲胺(almondamidopropyl dimethylamine)、鳄梨酰胺丙基二甲胺(avocadoamidopropyldimethylamine)、巴磺酰胺丙基二甲胺(babassuamidopropyl dimethylamine)、椰油酰胺丙基二甲胺(cocamidopropyl dimethylamine)、貂油酰胺丙基二甲胺(minkamidopropyldimethylamine)、燕麦油酰胺丙基二甲胺(oatamidopropyl dimethylamine)、芝麻酰胺丙基二甲胺(sesamidopropyl dimethylamine)、妥尔油酰胺丙基二甲胺(tallamidopropyldimethylamine)、芥子酰胺丙基二甲胺(brassicaamidopropyl dimethylamine)、橄榄油酰胺丙基二甲胺(olivamidopropyl dimethylamine)、棕榈酰胺丙基二甲胺(palmitamidopropyl dimethylamine)、硬脂酰胺乙基二乙胺(stearamidoethyldiethylamine)及其混合物。
其他的胺
可能有用的其他的胺包括烷氧基化的单胺。烷氧基化单胺是具有氨基和至少一个烷氧基化度的化合物。烷氧基化作用由通常选自环氧乙烷和环氧丙烷的环氧烷基提供。
合适的烷氧基化单胺的非限制性实例包括对应于下式的化合物:
RN[(R'CHCH2O)xH][(R'CHCH2O)yH]
其中R是包含至少6个碳原子的烃基。R可以是直链或支链、非环或环状、饱和或不饱和、脂族或芳族、取代或未取代的;x和y彼此独立地表示0至100的数字,条件是x+y之和>0;基团R'(其可相同或不同)表示氢或烷基(如甲基)。通常,R为直链或支链的非环烷基或烯基或烷基苯基;x和y彼此独立,通常各自为0至30。通常,一个R'基团为氢,且另一个R'基团为甲基。
烷氧基化单胺的非限制性实例包括:PEG-2 Cocamine、PEG-3 Cocamine、PEG-5Cocamine、PEG-10 Cocamine、PEG-15 Cocamine、PEG-20 Cocamine、PEG-2 Lauramine、PEG-12 Palmitamine、PEG-2 Rapeseedamine、PEG-2 Oleamine、PEG-5 Oleamine、PEG-6Oleamine、PEG-10 Oleamine、PEG-15 Oleamine、PEG-20 Oleamine、PEG-25 Oleamine和PEG-30 Oleamine。其他实例是大豆胺、硬脂胺和牛脂胺的烷氧基化衍生物。
合适的烷氧基化单胺的其他非限制性实例包括对应于下式的化合物:
RNR”[(R'CHCH2O)xH]
其中R是包含至少6个碳原子的烃基。R可以是直链或支链、非环或环状、饱和或不饱和、脂族或芳族、取代或未取代的;x表示1到100的数字;R'表示氢或烷基(例如特别是甲基);并且R”是氢或烃基。通常,R为直链或支链、非环烷基或烯基或烷基苯基;x通常是1至30的数字。当R”是烃基时,该基团可为直链或支链、饱和或不饱和、取代或未取代的。由R”表示的烃基还可包含烷氧基化部分(如由[(R'CHCH2O)yH]所定义),和/或杂原子(如氮)。当R”包含至少一个烷氧基化部分时,式中的烷氧基化总数可以为1至120。烷氧基化单胺的实例包括PEG-3牛脂氨基丙胺、PEG-10牛脂氨基丙胺、PEG-15牛脂氨基丙胺和PEG-105山嵛基丙二胺。
烷氧基化单胺的其他非限制性实例包括对应于下式的化合物:
R(R'CHCH2O)x(R'CHCH2O)yNHy
其中R是包含至少6个碳原子的烃基。R可以是直链或支链、非环或环状、饱和或不饱和、脂族或芳族、取代或未取代的;x和y彼此独立地表示0至100的数字,条件是x+y之和>0;基团R'(可相同或不同)表示氢或烷基(特别是甲基)。通常,R为直链或支链的非环烷基或烯基或烷基苯基;x和y彼此独立,通常各自为0至30。烷氧基化单胺的实例包括包含单胺基的聚醚胺。这些聚醚胺是以商品名Jeffamine(M系列,如M-600,M-1000,M-2005和M-2070)和Surfonamine系列(B-60,B-100,B-200,L-100,L-200,L-207,L-300)自Hunstman商购可得。
该一种或多种胺的总量可有所不同,但在一些情况下,该一种或多种胺的总量是约0.1至约50重量%,基于毛发处理组合物的总重量计。在一些情况下,该一种或多种胺的总量是约0.1至约50重量%,约0.1至约30重量%,约0.1至约25重量%,约0.1至约20重量%,约0.1至约15重量%,约0.1至约10重量%,约0.5至约35重量%,约0.5至约30重量%,约0.5至约25重量%,约0.5至约20重量%,约0.5至约15重量%,约0.5至约10重量%,约1至约35重量%,约1至约30重量%,约1至约25重量%,约1至约20重量%,约1至约15重量%,约1至约10重量%,或约1至约5重量%。
果聚糖多糖
果聚糖多糖(也称为“果聚糖”)是果糖分子的聚合物。果聚糖多糖包括菊粉多糖(也称为“菊粉”)和左聚糖多糖(也称为“左聚糖”)。在一些情况下,免洗型毛发造型组合物包括菊粉多糖;在一些情况下,免洗型毛发造型组合物包括左聚糖多糖;但是在一些情况下,免洗型毛发造型组合物可同时包含菊粉和左聚糖多糖。
一种或多种果聚糖多糖的总量可有所不同,但通常为约0.1至约40重量%,基于免洗型毛发造型组合物的总重量。一种或多种果聚糖多糖的总量可为约0.1至约30重量%,约0.1至约20重量%,约0.1至约15重量%,约0.1至约10重量%,约0.1至约5重量%,约1至约40重量%,约1至约30重量%,约1至约20重量%,约1至约15重量%,约1至约10重量%,或约1至约5重量%。
菊粉是指由多种植物产生的一类多糖,并且是果聚糖多糖(也成为了“果聚糖”)的一个例子,是果糖分子的聚合物。菊粉通常从菊苣根中提取,并可含有(2→1)连接的β-d-果糖基残基(n=2–60),通常具有一个α-d-葡萄糖端基。菊粉可以约0.1、0.2、0.3、0.4、0.5、0.6、0.7、0.8、0.9、1、1.1、1.2、1.3、1.4或1.5至约1.5、2、2.5、3、3.5、4、4.5、5、6、7、8、9或10重量%的量存在,以组合物总重量计。在其他实施方案中,菊粉以约0.1至约10重量%,或约0.5至约2.5重量%的量存在。
前溶剂
如本文所用,“前溶剂”是指通过增强活性成分向毛发中的渗透而增强组合物性能的溶剂系统。在一个或多个实施方案中,前溶剂包括一种或多种二醇化合物。在其他实施方案中,二醇化合物选自己二醇、丁二醇、丙二醇及其组合。
在一个或多个实施方案中,前溶剂包括两种成分的混合物,其比例为约1:2至约2:1,或更特别是1:1。在一些实施方案中,前溶剂包括己二醇和丁二醇。在一个或多个实施方案中,前溶剂在己二醇和丁二醇之外还包含丙二醇。
尽管不希望受任何特定理论的束缚,但认为前溶剂的存在增加了渗透活性物如马来酸的功效。前溶剂还可以充当表面活性剂,并有助于稳定乳液。当存在低pH成分(例如马来酸)时,乳液稳定性是特别重要的效果,因为这样的低pH成分可能对乳液稳定性具有负面影响。因此,认为前溶剂起到抵消低pH成分对乳液稳定性的负面作用以及辅助活性物渗透至皮层的作用。
其他组分
在一个或多个实施方案中,其中所述的毛发处理组合物可包含一种或多种其他成分。实例包括但不限于表面活性剂、阳离子调理剂、硅酮、成膜剂、其他聚合物、香料和防腐剂。以下是有关此类其他成分的其他详细信息。
表面活性剂
阳离子表面活性剂
术语“阳离子表面活性剂”意为当其包含在本公开的组合物中时带正电的表面活性剂。该表面活性剂可以带有一个或多个正永久电荷,或者可包含在本公开的组合物中可阳离子化的一个或多个官能团。
阳离子表面活性剂的非限制性实例包括:山嵛基苄基二甲基氯化铵(behenalkonium chloride)、苄索氯铵(benzethonium chloride)、西吡氯铵(cetylpyridinium chloride)、山嵛基三甲基氯化铵(behentrimonium chloride)、劳拉氯铵(lauralkonium chloride)、西他氯铵(cetalkonium chloride)、西曲溴铵(cetrimoniumbromide)、西曲氯铵(cetrimonium chloride)、十六烷基胺氢氟化物(cethylaminehydrofluoride)、氯化氯烯丙基六亚甲基四胺(chlorallylmethenamine chloride)(季铵盐(Quaternium)-15)、二硬脂基二甲基氯化铵(季铵盐-5)、十二烷基二甲基乙基苄基氯化铵(季铵盐-14)、季铵盐-22、季铵盐-26、季铵盐-18水辉石、二甲氨基氯乙烷盐酸盐、半胱氨酸盐酸盐、二乙醇铵POE(10)油酸基(oletyl)乙醚磷酸盐、二乙醇胺POE(3)油酸基乙醚磷酸盐、牛脂烷基氯化铵(tallow alkonium chloride)、二甲基双二十八烷基溴化铵(dimethyldioctadecylammoniumbentonite)、司拉氯铵(stearalkonium chloride)、溴化度米芬(domiphen bromide)、苯甲地那铵(denatonium benzoate)、肉豆蔻基二甲基苄基氯化铵(myristalkonium chloride)、月桂基三甲基氯化铵(laurtrimonium chloride)、乙二胺二盐酸盐、胍盐酸盐、吡哆醇HCl、碘非他胺(iofetamine)盐酸盐、葡甲胺(meglumine)盐酸盐、甲基氯化苯乙胺(methylbenzethonium chloride)、肉豆蔻基三甲基溴化铵(myrtrimoniumbromide)、油酸基三甲基氯化铵(oleyltrimonium chloride)、聚季铵盐-1(Polyquaternium-1)、盐酸普鲁卡因、椰油基甜菜碱(cocobetaine)、司拉氯铵膨润土(stearalkonium bentonite)、硬脂酰三甲铵锂蒙脱石(stearalkoniumhectonite)、硬脂酰三羟乙基丙二胺二氢氟酸盐、牛脂基苄基三甲基氯化铵(tallowtrimonium chloride)和十六烷基三甲基溴化铵。
阴离子表面活性剂
术语“阴离子表面活性剂”意为仅包括作为离子或可离子化基团的阴离子的表面活性剂。这些阴离子基团优选选自CO2H、CO2 -、SO3H、SO3 -、OSO3H、OSO3 -O2PO2H、O2PO2H和O2PO2 2-。
可用的阴离子表面活性剂可为烷基硫酸盐、烷基醚硫酸盐、烷基氨基醚硫酸盐、烷基芳基聚醚硫酸盐、单甘油酯硫酸盐、烷基磺酸盐,烷基酰胺磺酸盐、烷基芳基磺酸盐、α-烯烃磺酸盐、链烷烃磺酸盐、烷基磺基琥珀酸盐、烷基醚磺基琥珀酸盐、烷基酰胺磺基琥珀酸盐、烷基磺基乙酸盐、酰基肌氨酸盐、酰基谷氨酸盐、烷基磺化琥珀酰胺酸盐、酰基羟乙基磺酸盐(acylisethionate)和N-酰基牛磺酸盐、烷基单酯和多糖苷-多羧酸的盐、酰基乳酸盐、D-半乳糖苷糖醛酸的盐、烷基醚羧酸的盐、烷基芳基醚羧酸的盐和烷基氨基醚羧酸的盐;或所有这些化合物的非盐化形式,所有这些化合物的烷基和酰基都包含6至24个碳原子,而芳基意为苯基。这些化合物中的一些可为氧乙烯化的,然后优选包括1至50个环氧乙烷单元。
多糖苷-多羧酸的C6-C24烷基单酯的盐可选自C6-C24烷基多糖苷-柠檬酸盐、C6-C24烷基多糖苷-酒石酸盐和C6-C24烷基多糖苷-磺基琥珀酸盐。
当阴离子表面活性剂为盐形式时,其尤其可选自碱金属盐(如钠或钾盐,优选钠盐)、铵盐、胺盐,并且特别是氨基醇盐或碱土金属盐(如镁盐)。
尤其可提及的氨基醇盐的实例包括单乙醇胺、二乙醇胺和三乙醇胺盐,单异丙醇胺、二异丙醇胺或三异丙醇胺盐,2-氨基-2-甲基-1-丙醇盐,2-氨基-2-甲基-1,3-丙二醇盐和三(羟甲基)氨基甲烷盐。可以使用碱金属或碱土金属盐,特别是钠盐或镁盐。
还要提到任选地被乙氧基化的、包括2至50个环氧乙烷单元的(C6-C24)烷基硫酸盐、(C6-C24)烷基醚硫酸盐,以及其混合物,特别是形式为碱金属盐或碱土金属盐、铵盐或氨基醇盐。在一些情况下,阴离子表面活性剂选自(C10-C20)烷基醚硫酸盐,且特别是包含2.2摩尔环氧乙烷的月桂基醚硫酸钠。
两性表面活性剂
可用于本发明的化妆品组合物中的两性表面活性剂可以选自甜菜碱,磺基甜菜碱(sultaine)、两性乙酸盐、两性丙酸盐及其混合物。更通常地,使用甜菜碱和两性丙酸盐,并且最通常使用甜菜碱。可用于当前组合物中的甜菜碱包括具有下式的那些甜菜碱:
其中
R10是具有8-18个碳原子的烷基;且
n为1至3的整数。
特别有用的甜菜碱包括例如椰油基甜菜碱(coco betaine)、椰油基酰胺丙基甜菜碱、月桂基甜菜碱、月桂基羟基磺基甜菜碱、月桂基二甲基甜菜碱、椰油基酰胺丙基羟基磺基甜菜碱(cocoamidopropyl hydrosultaine)、山嵛基甜菜碱、辛酰/癸酰胺丙基甜菜碱(capryl/capramidopropyl betaine)、月桂基硫磺基甜菜碱、硬脂基甜菜碱及其混合物。通常,至少一种甜菜碱化合物选自椰油基甜菜碱、椰油酰胺丙基甜菜碱、山嵛基甜菜碱、辛基/癸酰胺丙基甜菜碱、月桂基甜菜碱及其混合物,并且更通常为椰油基甜菜碱。
可用于本发明组合物的羟基磺基甜菜碱包括以下
其中
R是具有8-18个碳原子的烷基。
有用的烷基两性乙酸盐包括具有下式的那些
其中
R是具有8-18个碳原子的烷基。
有用的烷基两性二乙酸盐包括具有下式的那些
其中
R是具有8-18个碳原子的烷基。
本公开的两性表面活性剂可以是任选地季铵化的仲或叔脂族胺衍生物,其中脂族基团是包括8至22个碳原子的直链或支链,所述胺衍生物包含至少一个阴离子基团,例如羧基、磺酸基、硫酸基、磷酸基或膦酸基。
非离子表面活性剂
非离子表面活性剂使本身就众所周知的化合物(对此,例如,参见“表面活性剂手册(Handbook of Surfactants)”,M.R.Porter,Blackie&Son出版社(Glasgow和London),1991,第116-178页),其通过引用全文而并入本文。
非离子表面活性剂可以例如选自醇、α-二醇、烷基酚和脂肪酸酯,这些化合物是乙氧基化的、丙氧基化的或甘油酯化的,并具有至少一个包括例如8至18个碳原子的脂肪链,环氧乙烷或环氧丙烷基团的数量可以在2至50的范围内,而甘油基团的数目可以在1至30的范围内。也可提及麦芽糖衍生物。还可非限制性地提及环氧乙烷和/或环氧丙烷的共聚物;环氧乙烷和/或环氧丙烷与脂肪醇的缩合物;多乙氧基化脂肪酰胺,其包括例如2至30mol环氧乙烷;包括例如1.5至5个(例如1.5至4个)甘油基的聚甘油化脂肪酰胺;脱水山梨醇的乙氧基化脂肪酸酯,其包括2至30mol环氧乙烷;植物来源的乙氧基化油;蔗糖的脂肪酸酯;聚乙二醇的脂肪酸酯;甘油(C6-C24)烷基多糖苷的多乙氧基化脂肪酸单酯或二酯、N-(C6-C24)烷基葡萄糖胺衍生物、胺氧化物如(C10-C14)烷基胺氧化物或N-(C10-C14)酰氨基丙基吗啉氧化物;及其混合物。
非离子表面活性剂可优选选自聚氧亚烷基化或聚甘油酯化的非离子表面活性剂。氧化烯单元更特别是氧化乙烯或氧化丙烯单元,或其组合,并且优选是氧化乙烯单元。
在一些情况下,非离子表面活性剂可选自多元醇与具有包含例如8至24个碳原子,优选12至22个碳原子的饱和或不饱和链的脂肪酸的酯,及其烷氧基化衍生物,优选环氧烷数为10至200,且更优选10至100,诸如:一种或多种C8-C24,优选C12-C22脂肪酸的甘油酯及其烷氧基化衍生物,优选环氧烷数为10至200,且更优选10至100;一种或多种C8-C24,优选C12-C22脂肪酸的聚乙二醇酯及其烷氧基化衍生物,优选环氧烷数为10至200,且更优选10至100;一种或多种C8-C24,优选C12-C22脂肪酸的山梨醇酯及其烷氧基化衍生物,优选环氧烷数为10至200,且更优选10至100;一种或多种C8-C24,优选C12-C22脂肪酸的糖(蔗糖、葡萄糖、烷基葡萄糖)酯及其烷氧基化衍生物,优选环氧烷数为10至200,且更优选10至100;脂肪醇的醚;糖与一种或多种C8-C24,优选C12-C22脂肪醇的醚;及其混合物。
可提及的乙氧基化的脂肪酯的实例包括:环氧乙烷与月桂酸、棕榈酸、硬脂酸或山嵛酸的酯的加合物及其混合物,尤其是包含9至100个氧乙烯基团的那些,诸如,PEG-9至PEG-50月桂酸酯(如CTFA名称:PEG-9月桂酸酯至PEG-50月桂酸酯);PEG-9至PEG-50棕榈酸酯(如CTFA名称:PEG-9棕榈酸酯至PEG-50棕榈酸酯);PEG-9至PEG-50硬脂酸酯(如CTFA名称:PEG-9硬脂酸酯至PEG-50硬脂酸酯);PEG-9至PEG-50棕榈酸硬脂酸酯;PEG-9至PEG-50山嵛酸酯(如CTFA名称:PEG-9山嵛酸酯至PEG-50山嵛酸酯);聚乙二醇100EO单硬脂酸酯(CTFA名称:PEG-100硬脂酸酯);及其混合物。
尤其可以列举脂肪酸的甘油酯、硬脂酸甘油酯(单、二和/或三硬脂酸甘油酯)(CTFA名称:硬脂酸甘油酯)或蓖麻酸甘油酯及其混合物。
例如可以列举C8-C24烷氧基化脂肪酸的甘油酯、多乙氧基化硬脂酸甘油酯(单、二和/或三硬脂酸甘油酯)如PEG-20硬脂酸甘油酯。
也可使用这些表面活性剂的混合物:例如,由Uniqema以名称ARLACEL 165销售的包含硬脂酸甘油酯和PEG-100硬脂酸酯的产品和由Goldschmidt以名称TEG1N销售的包含硬脂酸甘油酯(单和二硬脂酸甘油酯)和硬脂酸钾的产品(CTFA名称:硬脂酸甘油酯SE)。
阳离子调理剂
可以在本公开的组合物中使用的阳离子调理剂可以是单烷基季胺,如硬脂基三甲基氯化铵(stearyl trimonium chloride)、大豆三甲基氯化铵(soyatrimonium chloride)或椰油基乙基二甲基乙基硫酸铵(coco-ethyldimonium ethosulfate)。其他合适的阳离子调理剂包括但不限于山嵛基三甲基氯化铵、二烷基季胺(如,二鲸蜡基二甲基氯化铵(dicetyldimonium chloride)、二椰油基二甲基氯化铵(dicocodimethyl ammoniumchloride)或二硬脂基二甲基氯化铵(distearyldimethyl ammonium chloride))和聚季铵盐化合物如聚季铵盐-6、聚季铵盐-22或聚季铵盐-5。
举例来说,阳离子调理剂可选自聚季铵盐-10(也称为季铵化多羟乙基纤维素)、西曲氯铵(也称为鲸蜡基三甲基氯化铵,CTAC)、山嵛基三甲基氯化铵(也称为二十二烷基三甲基氯化铵)、山嵛基三甲基甲硫酸铵(behentrimonium methosulfate)、硬脂基三甲基氯化铵、硬脂酸氯铵(stearalkonium chloride)、二鲸蜡基二甲基氯化铵、羟丙基三甲基氯化铵、椰油基三甲基甲硫酸铵、油基二甲基苄基氯化铵(olealkonium chloride)、硬脂基三甲基氯化铵、巴巴苏油酰胺丙基苄基二甲基氯化铵(babassuamidopropalkonium chloride)、油菜油酰胺丙基二甲胺(brassicamidopropyl dimethylamine)、季铵盐-91、Salcare/PQ-37、季铵盐-22、季铵盐-87、聚季铵盐-4、聚季铵盐-6、聚季铵盐-11、聚季铵盐-44、聚季铵盐-67、氨基封端二甲基聚硅氧烷(amodimethicone)、月桂基甜菜碱(lauryl betaine)、Polyacrylate-1Crosspolymer、羟丙基水解小麦蛋白硬脂基二甲基铵(steardimoniumhydroxypropyl hydrolyzed wheat protein)、山嵛酰胺丙基PG-二甲基氯化铵(behenamidopropyl PG-dimonium chloride)、羟丙基水解大豆蛋白月桂基二甲基铵(lauryldimonium hydroxypropyl hydrolyzed soy protein)、氨丙基聚二甲硅氧烷(aminopropyl dimethicone)、Quaterium-8和二聚亚油酰胺丙基二甲胺聚二甲硅氧烷PEG-7磷酸酯(dilinoleamidopropyl dimethylamine dimethicone PEG-7phosphate)。
在一些情况下,阳离子调理剂是阳离子聚合物。术语“阳离子聚合物”意为包括至少一个阳离子基团和/或至少一个能被离子化为阳离子基团的基团的任何聚合物。
本发明中特别有用的阳离子聚合物包括,但不限于,聚季铵盐4、聚季铵盐6、聚季铵盐7、聚季铵盐10、聚季铵盐11、聚季铵盐16、聚季铵盐22、聚季铵盐28、聚季铵盐32、聚季铵盐-46、聚季铵盐-51、聚季铵盐-52、聚季铵盐-53、聚季铵盐-54、聚季铵盐-55、聚季铵盐-56、聚季铵盐-57、聚季铵盐-58、聚季铵盐-59、聚季铵盐-60、聚季铵盐-63、聚季铵盐-64、聚季铵盐-65、聚季铵盐-66、聚季铵盐-67、聚季铵盐-70、聚季铵盐-73、聚季铵盐-74、聚季铵盐-75、聚季铵盐-76、聚季铵盐-77、聚季铵盐-78、聚季铵盐-79、聚季铵盐-80、聚季铵盐-81、聚季铵盐-82、聚季铵盐-84、聚季铵盐-85、聚季铵盐-86、聚季铵盐-87、聚季铵盐-90、聚季铵盐-91、聚季铵盐-92、聚季铵盐-94,和瓜尔胶羟丙基三甲基氯化铵(guarhydroxypropyltrimonium chloride)。
本发明特别优选的阳离子聚合物包括从AMERCHOL可获得的POLYMER JR-125、POLYMER JR-400、POLYMER JR-30M羟乙基纤维素聚合物(聚季铵盐10);从Rhodia可获得的JAGUAR C.RTM.13-S、瓜尔胶羟丙基三甲基氯化铵;和从Nalco可获得的MERQUAT.RTM.100和280——一种二甲基二烷基氯化铵(聚季铵盐6)。
阳离子聚合物通常以大于0重量%至约15重量%,优选约0.5重量%至约10重量%,更优选约1重量%至约5重量%的量存在,基于组合物的总重量计。
本文中有用的阳离子聚合物包括聚季铵盐4、聚季铵盐6、聚季铵盐7、聚季铵盐10、聚季铵盐11、聚季铵盐16、聚季铵盐22和聚季铵盐32。本发明中有用的阳离子聚合物包括但不限于聚季铵盐4、聚季铵盐6、聚季铵盐7、聚季铵盐10、聚季铵盐11、聚季铵盐16、聚季铵盐22、聚季铵盐28、聚季铵盐32和瓜尔胶羟丙基三甲基氯化铵。优选的阳离子聚合物包括从AMERCHOL可获得的POLYMER JR-125,POLYMER JR-400、POLYMER JR-30M羟乙基纤维素聚合物(聚季铵盐10);从Rhodia可获得的JAGUAR C13-S、瓜尔胶羟丙基三甲基氯化铵;和从Nalco可获得的MERQUAT 100和280——一种二甲基二烷基氯化铵(聚季铵盐6)。
油
毛发造型组合物可包含一种或多种油,例如硅油、氟油(fluoro oils)、烃基油(hydrocarbon-based oil)等。术语“油”意为在室温(20-25℃)和大气压(760mmHg)下呈液体形式的任何脂肪物质。通常,化妆品组合物中的至少一种油是油相的一部分。“油相”是包括至少一种可包括其他脂溶性及亲脂成分的油和脂肪物质的相。可以将油相与水相在乳液中合并。适用于本文用途的油可以是挥发性的或非挥发性的。术语“挥发性油”涉及在室温和大气压下,与皮肤或角蛋白纤维接触后能够在不到一小时内蒸发的油。挥发性油在室温下为液体,并且在室温和大气压下具有非零蒸气压,特别是在0.13Pa至40000Pa(10-3至300mmHg)的范围内。术语“非挥发性油”是指在室温和大气压下在皮肤或角蛋白纤维上保留至少几小时的油,尤其是蒸气压小于10-3mmHg(0.13Pa)的油。
术语“硅油”是指包括至少一个硅原子,尤其是至少一个Si-O基团的油。术语“氟油”是指包括至少一个氟原子的油。术语“烃基油”是指主要包括氢和碳原子的油。烃基油可以是动物烃基油、植物烃基油、矿物烃基油或合成烃基油。此外,合适的油可以是矿物烃基油、植物烃基油或合成烃基油。
硅油
本文所述的化妆品组合物可包括一种或多种硅油。硅油的非限制性实例包括二甲基硅油、环甲硅油、聚硅酮-11、苯基三甲基硅氧烷(phenyl trimethicone)、三甲基甲硅烷氧基氨端聚二甲基硅氧烷(trimethylsilylamodimethicone)和硬脂氧基三甲基硅烷。在一些情况下,化妆品组合物包括二甲基硅油和任选地其他油,包括其他硅油。通常,一种或多种硅油是非挥发性硅油。在一些实施方案中,硅油是聚二甲基硅氧烷(PDMS)、包括侧链的和/或在硅酮链末端的烷基或烷氧基(这些基团各自包含2至24个碳原子)的聚二甲基硅氧烷或苯基硅酮如苯基三甲基硅氧烷、苯基二甲聚硅氧烷、苯基(三甲基硅氧基)二苯基硅氧烷、二苯基二甲聚硅氧烷、二苯基(甲基二苯基)三硅氧烷或(2-苯基乙基)三甲基硅氧基硅酸酯。
可提及的硅油的其他实例包括挥发性直链或环状硅油,尤其是粘度为8厘沲(8x106m2/s)且尤其包含2至7个硅原子的那些,这些硅酮任选地包括含1至10个碳原子的烷基或烷氧基。对于可用于本发明的挥发性硅油,尤其可提及八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷、七甲基己基三硅氧烷、七甲基辛基三硅氧烷、六甲基二硅氧烷、八甲基三硅氧烷、十甲基四硅氧烷和十二甲基五硅氧烷及其混合物。
氟油
本文所述的化妆品组合物可包括一种或多种氟油。例如,该一种或多种氟油可以选自全氟甲基环戊烷、全氟-1,3-二甲基环己烷、十二氟戊烷、十四氟己烷、溴代全氟辛基、九氟甲氧基丁烷、九氟乙氧基异丁烷和4-三氟甲基全氟吗啉。也可以使用挥发性氟油,如,九氟甲氧基丁烷、十氟戊烷、十四氟己烷、十二氟戊烷。
烃基油
本文所述的化妆品组合物可包括一种或多种烃基油。例如,烃基油可以是饱和烃、不饱和烃、脂质、甘油三酯、天然油和/或合成油。在一些实施方案中,组合物包括选自氢化聚异丁烯和氢化聚癸烯的合成油。
烃基油可以是非挥发性烃基油,如:
(i)植物来源的烃基油,如甘油三酯,其通常是脂肪酸和甘油的三酯,该脂肪酸的链长从C4到C24不等,这些链可能是饱和的或不饱和的和直链或支链的;这些油特别是小麦胚芽油、向日葵油、葡萄籽油、芝麻油、玉米油、杏仁油、蓖麻油、乳木果油、鳄梨油、橄榄油、大豆油、甜扁桃仁油、棕榈油、菜籽油、棉籽油、榛子油、夏威夷果油、荷荷巴油、苜蓿油、罂粟油、南瓜籽油、葫芦油(marrow oil)、黑加仑油、月见草油、粟米油、大麦油、奎奴亚藜油、黑麦油、红花油、烛果油、西番莲油和麝香玫瑰油。
(ii)包含10至40个碳原子的合成醚;
(iii)矿物或合成来源的直链或支链烃,如凡士林,聚癸烯,氢化聚异丁烯,如Parleam和4 0角鲨烷;
(iv)合成酯,例如,式RCOOR'的油,其中R表示包含1至40个碳原子的直链或支链的脂肪酸残基,而R'表示尤其是支链的、包含1至40个碳原子的烃基链,条件是R+R'是≥10,例如Purcellin oil(鲸蜡硬脂醇辛酸酯)、肉豆蔻酸异丙酯、棕榈酸异丙酯、苯甲酸C12-C15烷基酯(如,由Witco以商品名Finsolv或Witconol销售的产品或由EvonikGoldschmidt以商品名Tegosoft销售的产品)、苯甲酸2-乙基苯基酯(如,由ISP以名称X-Tend 226销售的商业产品)、羊毛酸异丙酯,月桂酸己酯,己二酸二异丙酯,异壬酸异壬酯,芥酸油醇酯,棕榈酸2-乙基己基酯,异硬脂酸异硬脂基酯,癸二酸二异丙酯(如,由Stearinerie Dubois以名称“Dub Dis”销售的产品)、醇或多元醇的辛酸酯、癸酸酯或蓖麻酸酯,如二辛酸丙二醇酯;羟基化的酯,如乳酸异硬脂基酯或苹果酸二异硬脂基酯;和季戊四醇酯;柠檬酸酯或酒石酸酯,如二(直链C12-C13烷基)酒石酸酯(如,由Enichem AugustaIndustriale以名称Cosmacol销售的那些)以及二(直链C14-C15烷基)酒石酸酯(如,由相同公司以名称Cosmacol销售的那些);或乙酸酯;
(v)在室温下为液态的脂肪醇,其包括含12至26个碳原子的支链和/或不饱和碳基链,例如辛基十二烷醇、异硬脂基醇、油醇、2-己基癸醇、2-丁基辛醇或2-十一烷基十五烷醇;
(vi)高级脂肪酸,例如油酸、亚油酸或亚麻酸;
(ix)精油,选自向日葵油、芝麻油、薄荷油、澳洲坚果油、茶树油、月见草油、鼠尾草油、迷迭香油、芫荽油、百里香油、多香果油(pimento berries oil)、玫瑰油、茴香油、香脂油、佛手柑油、玫瑰木油、雪松油、洋甘菊油、鼠尾草油、香紫苏油、丁香油、柏树油、桉树油、茴香油、海茴香油、乳香油、天竺葵油、姜油、葡萄柚油、茉莉油、杜松油、薰衣草油、柠檬油、柠檬草油、酸橙油、柑橘油、马郁兰油、没药油、橙花油、橙油、广藿香油、胡椒油、黑胡椒油、橙叶油(petitgrain oil)、松树油、玫瑰精油、迷迭香油、檀木油、留兰香油、甘松香油、香根草油、冬青油和依兰。
在某些情况下,非挥发性烃基油是甘油三酯,特别是辛酸/癸酸甘油三酸酯、合成酯,尤其是异壬酸异壬酯、芥酸油醇酯、苯甲酸C12-C15烷基酯、苯甲酸2-乙基苯基酯和脂肪醇如辛基十二烷醇。
作为挥发性烃基油,提及包含8至16个碳原子的烃基油,尤其是支链的C8-C16链烷烃,如石油来源的C8-C16异烷烃(也称为异链烷烃),如异十二烷(也称为2,2,4,4,6-五甲基庚烷)、异癸烷或异十六烷,以商品名Isopar或Permethyl出售的油,支链C8-C16酯和新戊酸异己基酯。
防腐剂
在本文所述的用于处理毛发的组合物中可以包含一种或多种防腐剂。合适的防腐剂包括但不限于含甘油的化合物(例如,甘油或乙基己基甘油或苯氧基乙醇)、苯甲醇、对羟基苯甲酸酯(对羟基苯甲酸甲酯、对羟基苯甲酸乙酯、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯、对羟基苯甲酸异丁酯等)、苯甲酸钠、乙二胺四乙酸(EDTA)、山梨酸钾和/或葡萄柚种籽提取物或其组合。所述组合物中可包含一种以上的防腐剂。其他防腐剂在化妆品行业中是已知的,包括水杨酸、DMDM乙内酰脲、甲醛、氯苯甘醚(Chlorphenism)、三氯生、咪唑烷基脲、重氮烷基脲、山梨酸、甲基异噻唑啉酮、脱氢乙酸钠、脱氢乙酸、季铵盐-15、硬脂酸氯铵、吡啶硫酮锌(Zinc Pyrithione)、焦亚硫酸钠、2-溴-2-硝基丙烷、葡萄糖酸氯己定(Chlorhexidine Digluconate)、聚氨丙基双胍、苯扎氯铵、亚硫酸钠、水杨酸钠、柠檬酸、印度楝树油(Neem Oil)、精油(各种)、乳酸和维生素E(生育酚)。
一种或多种防腐剂(当存在时)的总量可有所不同。在一些情况下,基于组合物的总重量计,一种或多种防腐剂的总量为约0.01至约5重量%,约0.01至约4重量%,约0.15至约1重量%或约1至约3重量%。
取决于其他组分的具体组合、组合物的形式和/或制剂的用途(例如,发用喷雾、霜剂、糊剂、调理剂等),可以在毛发造型组合物中包括或从中排除合适的组分,如在本公开中列出的那些(包括上文列出的那些)。
方法
本发明的另一方面涉及使用本文所述的毛发处理组合物的方法。该方法大体上包括将所述任何毛发处理组合物施加于毛发。毛发处理组合物可能在多种场合下都有用,无论是经处理的毛发还是未经处理的毛发。在经处理的毛发上的用途可包括化学松弛型毛发。可以在松弛剂之后但在中和洗发剂之前、中和洗涤发剂之后、在调理剂中或作为调理剂,或在松弛程序后将其作为免洗处理,来施用毛发处理组合物。在未经处理的头发上的使用可包括作为洗发剂的一部分、作为调理剂的一部分、作为预处理或者在洗发后作为免洗处理。
本公开的毛发处理方法可包括将本公开的毛发处理组合物施用于毛发(湿的、潮的或干的毛发),使毛发处理剂在毛发上保留足够的时间,以及从毛发上冲洗掉毛发处理组合物。可以在其他毛发处理组合物(例如,化学松弛剂组合物、洗发剂、调理剂、洗剂、凝胶等)之前、期间或之后将毛发处理组合物施加于毛发。
如前所述,毛发处理组合物特别用于处理经化学处理的毛发。在一些情况下,在从毛发上冲洗掉化学处理组合物后不久(例如,从冲洗掉化学处理组合物时起大约5、10、15、20或30分钟内),而头发尚湿或潮时,将毛发处理组合物施用于毛发。可使毛发处理组合物在毛发上保留一段时间,例如从大约几秒钟(1、3、5或10秒)到大约10、20或30分钟或更长的时间。在一些情况下,在从毛发上洗掉化学处理组合物后不久,将毛发处理组合物施用于经化学处理的毛发;在施用毛发处理组合物后,随后用洗发剂和/或调理剂或调理洗发剂(多合一洗发剂/调理剂)对毛发进行处理。可以在施用洗发剂和/或调理剂或调理洗发剂之前将毛发处理组合物从毛发上冲洗掉,或者可以使其在洗发和/或调理过程中将其留在毛发上并与洗发剂或调理剂或调理洗发剂一起从毛发上冲洗掉。例如,可以将毛发处理组合物施加于毛发,而无需从毛发冲洗掉毛发处理剂,随后将洗发剂(或调理剂或调理洗发剂)施用于毛发(层叠于已施用于毛发的毛发处理组合物上)。将两种组合物(毛发处理组合物和洗发剂、调理剂或调理洗发剂)一起从毛发上冲洗掉。
而且,在将所述毛发处理组合物施用于毛发之前,可以将其与洗发剂和/或调理剂或调理洗发剂组合。将所述毛发处理组合物与一种或多种其他毛发处理组合物(例如,洗发剂、调理剂、调理洗发剂、漂洗液等)组合。例如,所述毛发处理组合物可以在施用于毛发之前与洗发剂(或调理剂或调理洗发剂)混合。在这种情况下,洗发剂(或调理剂或调理洗发剂)与毛发处理组合物的混合物在清洁和/或调理过程中同时施加于毛发,并同时从毛发上冲洗掉。或者,所述毛发处理组合物可以层叠在已施加了洗发剂(或调理剂或调理洗发剂)的毛发上(或涂泡于毛发中),反之亦然。在这种情况下,可以先将毛发处理组合物施加于毛发,而不用将其从毛发上冲洗掉,然后再将洗发剂(或调理剂或调理洗发剂)施加到毛发上。或者,可以先将洗发剂(或调理剂或调理洗发剂)施用于毛发,而无需从毛发冲洗掉洗发剂(或调理剂或调理洗发剂),再将毛发处理组合物也施加于毛发。然后,将所述多种组合物同时从毛发上冲洗掉。
上面描述的是施用毛发处理组合物或将毛发处理组合物与另一种组合物(例如洗发剂、调理剂或调理洗发剂等)组合或层叠施用。在一些情况下,将毛发处理组合物单独施用于毛发,并与也被施用于毛发的另一种组合物(例如洗发剂、调理剂、调理洗发剂等)组合或层叠。例如,可以将毛发处理组合物施加于该头发。随后,在将毛发处理组合物从毛发上冲洗掉或不冲洗掉的情况下,可以将其中已经混合有毛发处理组合物的另一组合物(例如洗发剂、调理剂、调理洗发剂等)施加到毛发上。
当与另一组合物(例如洗发剂、调理剂、调理洗发剂等)组合时,毛发处理组合物可以以约1:10至约10:1,约1:5至约5:1,约1:3至约3:1,约1:2至约2:1,约1:1至约4:1,约1:1至约3:1,或约1:1至约2:1(本公开的毛发处理组合物:另一种组合物)的比例混合或使用。
在将毛发处理组合物从毛发上冲洗掉之前,可以使其在毛发上保留一段的时间最小化,但是不需要使毛发处理组合物在毛发上保留较长的时间。有利地,可以施加毛发处理组合物并将其在毛发上保留对于常规洗发和/或调理而言典型的一段时间。例如,可以将毛发处理组合物(在与另一毛发处理组合物(例如洗发剂或调理剂)组合的情况下)施用于毛发并使其在毛发上保留几秒钟(1、2、3、5或10秒),最高至约1、2、5、10、20或30分钟或更长时间。
在不将毛发处理组合物与另一组合物(例如洗发剂、调理剂、调理洗发剂等)同时施用于毛发时,可以在用另一组合物(例如洗发剂、调理剂、调理洗发剂等)处理毛发之后或之前立即将毛发处理组合物施用于毛发。例如,可以在将另一组合物施用于毛发之前或之后约1、2、5、10或20分钟内将毛发处理组合物施用于毛发。
套件
本公开的毛发处理组合物可被并入套件中。例如,套件可包括至少一种本公开的毛发处理组合物和一种或多种其他毛发处理组合物(例如,毛发松弛组合物、洗发剂、调理剂等)。各种毛发处理组合物被分别容纳在套件中。在一些情况下,套件包括一种或多种(本公开的)毛发处理组合物、洗发剂和/或调理剂,所有这些都被单独容纳。套件还可包括一种或多种(本公开的)毛发处理组合物、化学松弛剂组合物和任选的洗发剂和/或调理剂。套件中还可包括说明书、混合组件、刷子、手套、量具等。
通过以下实施例给出本公开的实施方式。实施例用于阐明技术,而无本质上的限制。
实施例1
(毛发处理组合物)
实施例2
(成分的协同作用)
进行测试来确定几种成分的影响。将含有如下表所示的成分的组合物的几个制剂施加至中度脱色的毛发样板。该样板由几个化学工作者用1-5等级评定系统针对表中所示的每种属性特征进行评估。在比较实验中,使用了相同量的每种成分。
+指示标识(signal)可见
++指示标识明显
+++指示标识非常显著
当在所有头发属性中同时存在菊粉、马来酸和前溶剂三者时,结果表明具有协同作用。
前述说明阐明并描述了本公开。另外,本公开仅示出和描述了优选实施例,但是,如上所述,应当理解,其能够以各种其他组合、变型和在各种其他环境中使用,并能够在本文所表述的发明构思的范围内进行改变或修饰,与上述教导和/或相关领域的技术或知识相称。本文上述实施方案还旨在解释申请人已知的最佳模式,并使本领域的其他技术人员能够以这样或其他的实施方案并用其特定的应用或用途所要求的各种变型来利用本公开。因此,本说明无意将本发明限制为本文公开的形式。同样,旨在将所附权利要求书解释为包括替代实施例。
如本文所使用的,术语“包括(comprising)”、“具有(having)”和“包括(including)”(或“包括(comprise)”,“具有(have)”和“包括(include)”)以其开放的、非限制性含义使用。
术语“一(a)”,“一(an)”和“该(the)”应理解为涵盖复数以及单数。
因此,术语“其混合物”也涉及“其多种混合物”。在整个公开中,在以下例子中(其中字母A-F表示元素)所示的一列元素之后使用术语“其混合物”:“一个或多个选自A、B、C、D、E、F及其混合物的元素”。术语“其混合物”不要求该混合物包括全部A、B、C、D、E和F(尽管可以包括全部A、B、C、D、E和F)。相反,其表示可以包括A、B、C、D、E和F中的任意两者或多者的混合物。换言之,它等同于短语“选自A、B、C、D、E、F,以及A、B、C、D、E和F中任意两者或多者的混合物的一个或多个元素”。
同样,术语“其盐”也涉及“其多种盐”。因此,在本公开内容提及“选自A、B、C、D、E、F、其盐及其混合物的元素”时,其表示:可包括A、B、C、D、和F中的一者或多者,可包括A的盐、B的盐、C的盐、D的盐、E的盐和F的盐中的一者或多者,或可以包括A、B、C、D、E、F、A的盐、B的盐、C的盐、D的盐、E的盐和F的盐中任意两者的混合物。
本公开通篇所提及的盐,例如,非聚合的单羧酸、二羧酸和/或三羧酸盐,可包括具有抗衡离子(如碱金属、碱土金属或铵抗衡离子)的盐。然而,所列抗衡离子是非限制性的。
措辞“一种或多种”意为“至少一种”,因此包括单独的组分以及混合物/组合。
除操作实施例中或另有说明外,所有表示成分的量和/或反应条件的数字在任何情况下均应理解为被术语“约”修饰,意为在所指数字的+/-5%之内。
针对本文所述的各种组合物(包括毛发处理组合物)所确定的各种类别的组分中的一些,可能会重叠。在这种两个或多个组分之间可能存在重叠的情况下,单个发生重叠的化合物不代表一种以上的组分。例如,甲基季铵化的甲基丙烯酸二甲氨基乙基酯的均聚物可以被表征为阳离子聚合物组分和增稠剂组分。如果将特定组合物描述为既包括阳离子聚合物又包括增稠剂,则单独的甲基季铵化的甲基丙烯酸二甲氨基乙基酯的均聚物将仅充当阳离子聚合物或仅充当增稠剂(该化合物不在同一组合物中同时充当阳离子聚合物和增稠剂)。
除非另有说明,本文所有百分比、份数和比例均基于本发明组合物的总重量。
如本文所用,“角蛋白基质”包括但不限于诸如人头上的头发和/或头皮的角蛋白纤维。
如本文所用,“调理”意为赋予一种或多种毛发纤维至少一种选自可梳理性、保湿性、光亮(luster)、光泽和柔软性的性质。调理状态可以通过本领域已知的任何方式来评估,如,根据梳理功(combing work)(gm-in),测量和比较经处理的头发和未经处理的头发的易梳理性,和消费者感受。
如本文所用,术语“处理”(及其语法变体)是指将本公开的组合物施用于角质基质如毛发的表面。术语“处理”及其语法变体涉及使毛发与本公开的毛发处理组合物接触。
如本文所用,术语“稳定的”意为该组合物在例如至少1天(24小时)、一周、一个月或一年的一段时间内不表现出相分离和/或结晶。
如本文所用,“挥发性”意为具有小于约100℃的闪点。
如本文所用,“非挥发性”意为具有大于约100℃的闪点。
本文公开的所有范围和值都是包括和可组合的。例如,落入本文所述范围内的本文所述任何值或点均可用作最小值或最大值,以得出子范围等。此外,所提供的所有范围意在包括该给定范围内的每个特定范围,以及给定范围的子范围之间的组合。因此,1-5的范围具体包括1、2、3、4和5,以及诸如2-5、3-5、2-3、2-4、1-4等子范围。
如本文所用,术语“基本上不含”(“substantially free”或“essentially free”)意为基于组合物的总重量计,有小于约5重量%的特定材料被添加到组合物中。然而,组合物可包括小于约3重量%,小于约2重量%,小于约1重量%,小于约0.5重量%,小于约0.1重量%的特定材料或不包括特定材料。
在本说明书中引用的所有出版物和专利申请都通过引用并入本文,并且出于任何和所有目的,就如同每个单独的出版物或专利申请都被具体地和单独地指出,以通过引用而并入。在本公开与通过引用并入本文的任何出版物或专利申请之间不一致的情况下,以本公开为准。
Claims (20)
1.一种毛发处理组合物,包括:
-至少0.5重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐;
-一种或多种胺,其选自二胺、多胺、烷基胺、链烷醇胺及其混合物;
-一种或多种果聚糖多糖;
-一种或多种前溶剂;和
-水。
2.根据权利要求1所述的毛发处理组合物,其中所述至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐是二羧酸和/或其盐。
3.根据权利要求2所述的毛发处理组合物,其包括至少一种二羧酸和/或其盐,其中所述至少一种二羧酸和/或其盐选自:草酸、丙二酸、苹果酸、戊二酸、柠康酸、琥珀酸、己二酸、酒石酸、富马酸、马来酸、癸二酸、壬二酸、十二烷二酸、邻苯二甲酸、间苯二甲酸、对苯二甲酸、2,6-萘二酸及其盐。
4.根据权利要求3所述的毛发处理组合物,其中所述至少一种二羧酸和/或其盐是马来酸、丙二酸和/或其盐。
5.根据权利要求2所述的毛发处理组合物,其包括至少一种三羧酸和/或其盐,其中所述至少一种三羧酸和/或其盐选自:柠檬酸、异柠檬酸、乌头酸、丙烷-1,2,3-三羧酸、苯-1,3,5-三羧酸及其盐。
6.根据权利要求5所述的毛发处理组合物,其中所述至少一种三羧酸和/或其盐是柠檬酸和/或其盐。
7.根据权利要求1-6中任一项所述的毛发处理组合物,其包括至少0.5至约20重量%的至少一种非聚合的单羧酸、二羧酸或三羧酸和/或其盐,基于毛发处理组合物的总重量计。
8.根据权利要求1-6中任一项所述的毛发处理组合物,其包括一种或多种选自式(II)的化合物的烷基胺和/或链烷醇胺:
NR3R4R5
(II)
其中,R3、R4和R5独立地是H、C1-C40烷基、C1-C40单羟基烷基或C2-C40多羟基烷基,条件是R3、R4和R5中的至少一个是烷基或单羟基烷基或多羟基烷基。
9.根据权利要求8所述的毛发处理组合物,其包括一种或多种选自以下的链烷醇胺:单乙醇胺、二乙醇胺、三乙醇胺、单异丙醇胺、二异丙醇胺、N-二甲氨基乙醇胺、2-氨基-2-甲基-1-丙醇、三异丙醇胺、2-氨基-2-甲基-1,3-丙二醇、3-氨基-1,2-丙二醇、3-二甲氨基-1,2-丙二醇、三(羟基甲基氨基)甲烷,及其混合物。
10.根据权利要求9所述的毛发处理组合物,其包括单乙醇胺。
11.根据权利要求1-6中任一项所述的毛发处理组合物,其中所述一种或多种胺的总量是约1至约20重量%,基于毛发处理组合物的总重量计。
12.根据权利要求1-6中任一项所述的毛发处理组合物,其中所述一种或多种果聚糖多糖是菊粉多糖和/或左聚糖多糖。
13.根据权利要求12所述的毛发处理组合物,其中所述一种或多种果聚糖多糖包括菊粉。
14.根据权利要求1-6中任一项所述的毛发处理组合物,其中所述一种或多种果聚糖多糖以约1至约5重量%的量存在,基于毛发处理组合物的总重量计。
15.根据权利要求1-6中任一项所述的毛发处理组合物,其中所述一种或多种前溶剂选自己二醇、丁二醇、丙二醇及其组合。
16.一种毛发处理组合物,包括:
-约2至约4重量%的马来酸和/或其盐;
-约1至约3重量%的乙醇胺;
-约1至约5重量%菊粉;
-约2至约4重量%的己二醇和丁二醇的混合物;和
-水。
17.一种处理毛发的方法,所述方法包括:
-将根据权利要求1-16中任一项所述的组合物施加至毛发。
18.根据权利要求17所述的方法,其中所述组合物作为洗发剂或调理程序的一部分被施加至毛发。
19.根据权利要求18所述的方法,其中将化学松弛剂施加至毛发之后,施加所述组合物。
20.一种处理毛发的方法,所述方法包括:
-将权利要求16所述的组合物施加至毛发。
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