US3874870A - Microbiocidal polymeric quarternary ammonium compounds - Google Patents

Microbiocidal polymeric quarternary ammonium compounds Download PDF

Info

Publication number
US3874870A
US3874870A US42593173A US3874870A US 3874870 A US3874870 A US 3874870A US 42593173 A US42593173 A US 42593173A US 3874870 A US3874870 A US 3874870A
Authority
US
Grant status
Grant
Patent type
Prior art keywords
butene
composition
product
reaction
grams
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
Harold A Green
John J Merianos
Alfonso N Petrocci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MILLMASTER ONYX GROUP LP
Original Assignee
MILL MASTER ONYX CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Grant date

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/0206Polyalkylene(poly)amines
    • C08G73/0213Preparatory process
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/0206Polyalkylene(poly)amines
    • C08G73/0213Preparatory process
    • C08G73/0226Quaternisation of polyalkylene(poly)amines

Abstract

The use of polymeric quaternary ammonium compounds prepared by the condensation of 1,4-dihalo-2-butene and 1,4-bisdimethylamino-2-butene as microbiocidal agents in aqueous systems.

Description

United States Patent [11] 3,874,870 Green et al. Apr. 1, 1975 MICROBIOCIDAL POLYMERIC [56] References Cited QUARTERNARY AMMONIUM UNITED STATES PATENTS COMPOUNDS 3,140,976 7/1964 Berenschot et a1. 424/329 [75] Inventors; Harold A, Green, Havertown P3; 3,539,684 11/1970 Hoover 424/78 J Mel-ianos Jersey Ci 3,771,989 11/1973 Pera et al 424/329 Alfonso N. Petrocci, Glen Rock7 3,778,283 12/1973 Freyhold 106/84 both of FOREIGN PATENTS OR APPLICATIONS [73] Assignee: Mill Master Onyx Corporation, New 69-8949 7/1970 South rica York, N.Y.

Primary Examiner-Albert T. Meyers [22] Flled' 1973 Assistant Examiner-Douglas W. Robinson [21] App]. No.: 425,931 Attorney, Agent, or FirmArthur A. Jacobs, Esq.

52 U.S. Cl 71/67, 260/875 R, 424/78, ABSTRACT 424/329 The use of polymeric quaternary ammonium com- 1 AOIN AOlN A61K 0 pounds prepared by the condensation of 1,4-diha1o-2- A61K 17/00 butene and l,4-bis-dimethylamino-Z-butene as micro- Fleld of Search biocidal agents in aqueQuS Systems,

8 Claims, N0 Drawings MlCROBIOClDAL POLYMERIC QUARTERNARY AMMONIUM COMPOUNDS This invention relates to microbiocidal agents, and it particularly relates to microbiocidal agents comprising polymeric quaternary ammonium compounds.

It is known that many quaternary ammonium compounds have biocidal or inhibitory effects on microorganisms. However, few such compounds, or indeed few biocidal compounds of any type, have been found to have all the necessary characteristics required for the biocidal treatment of aqueous systems of the recirculated type such as industrial or process waters of the type used in paper manufacturing, cooling towers, air conditioners, humidifiers and the like. Even relatively standing waters such as swimming pools have been problems insofar as maintaining them substantially free of bacteria, fungi and algae,

The control of microorganisms in aqueous systems of the aforesaid type has long been recognized as a particularly burdensome problem since the environment of the aqueous medium itselfis often extremely conducive to rapid multiplication and growth of these undesirable organisms. Only through the rise of carefully tailored microbiocidal agents can this growth and reproduction be reliably controlled without detriment to the process in which the water is used. For example, many times a n X-CH biocidal compound is rendered completely inactive by the particular surrounding media containing the undesirable microorganisms. A particular problem in recirculated waters is that the recirculation causes many difficult problems, among which is the gradual build-up and accumulation of undesirable microorganisms in the aqueous fluid. Various bacteria, fungi and algae are favorably produced in such recirculated waters.

Another common feature of quaternary ammonium biocides is that their biocidal effectiveness is diminished in the presence of non-ionic emulsifiers, often to the point where they no longer function as acceptable biocides. This has significantly reduced their possible use in cosmetics and similar preparations that require the inclusion of non-ionic emulsifiers.

An additional problem in the use of most microbiocidal agents in aqueous systems is the formation of large amounts of foam. This foam is generally highly undesirable and the formation thereof by these agents often makes them useless for particular applications.

In accordance with the present invention, it has now been discovered that certain polymeric quaternary ammonium compounds and, particularly, the product made by the condensation of 1,4-dihalo-2-butene and l,4-bis-dimethylamino-2-butene is not only a highly effective microbiocidal agent in aqueous systems, including recirculating waters, industrial waters, cosmetics and other emulsions containing non-ionic emulsifiers, as well as in general usage, but also effects such purpose without causing undue foaming.

It is to be noted that a particular aspect of the present invention is that the quaternary ammonium moieties of -CH=CH-CH X n (CH the present compounds are part of a long chain rather than being on branches that are bonded to the long chain.

The aforesaid compounds are active against Pseudomonas aeruginosa at a concentration relative to the total composition as low as 25 ppm, although the preferred concentration is about 150 ppm. Against Aerohacter acrogenes, they are active at a concentration as low as ppm, although the preferred concentration is about 100 ppm. Against algae, such as Chlorella pyrenoidosa, they are active at a concentration at least as low as 1 ppm and probably even much below that concentration according to present indications.

Insofar as concerns upper limits, the concentration may apparently be increased indefinitely without deleteriously affecting the biocidal activity.

More specifically with regard to cosmetic compositions. the products of this invention are effective at a concentration at least as low as about 500 ppm relative to the total composition, and probably at even lower concentrations, according to present indications. The preferred range, however, is about I ,000 to 2,000 ppm.

There is no absolute certainty of the actual structure of the product of the condensation reaction because isomerizations are possible. However, ideally, the reaction would appear to be as follows:

wherein X is a halogen such as chlorine or bromine and n is an integer from about 2 to 30.

The following examples illustrate the present invention with no intent to be limited thereby, however, except as claimed:

EXAMPLE 1 14.2 grams of l,4-bis-dimethylamino-Z-butene (0.1 mole) was dissolved in grams of water, and to it was added 12.5 grams (0.] mole) of l,4-dicholoro-2- butene over a period of 15 to minutes while maintaining constant stirring. The reaction was exothermic so that the temperature rose to about 7()C. The reaction mixture was then warmed on a steam bath at a temperature of about C. for about 1 hour, after which the reaction was considered complete. Titration of ionized chlorine was used as a measure of the extent of the reaction and indicated between 98 and 10071 completeness. The reaction product was a viscous material containing about 50% active material.

It was found that when a significant excess of the dichlorobutene was used, a second phase separated out of the final reaction product. Analysis indicated this second phase to contain primarily unreacted dichlorobutene.

Quite surprisingly, the compounds of this invention may be obtained directly as crystalline-like solids when the reaction is carried out in certain organic solvents such isopropanol, acetone and inert halogenated solvents. This is illustrated as follows:

EXAMPLEZ 14.2 grams of l,4-bis-dimethylamino-2-butene were mixed with 25 grams of isopropanol, and to it was added, with stirring. 12.5 grams of 1.4-dichloro-2- butene over a period of about minutes (or at a rate which keeps the solvent gently refluxing). After the exothermic reaction subsided, the mixture was warmed on a ateam bath to reflux temperature and maintained at such temperature for about 1 hour. It was then cooled, to room temperature, whereby a precipitate was formed. The precipitate was then separated out by filtration as the final product. The precipitate weighed 18.7 grams. This product is substantially free from impurities caused by side reactions or due to absorption of unreactcd starting materials, thereby making it easier to purify for use in cosmetics or cosmetic emulsions.

Solid products of the above type have the commercial advantage over aqueous solutions or dispersions because they have less bulk on a pound for pound active ingredient basis.

EXAMPLE 3 The same reactants and procedures were used as in Example 2.except that instead of the isopropanol,

grams of acetone was used. It yielded 21.4 grams of a solid product.

The same procedures may be used except that 1,4- dibromo-2-butene is substituted for the 1,4-dichloro-2- butene, with equivalent mol ratios. The product is substantially similar in all essential characteristics.

EXAMPLE 4 142 grams of l,4'bis-dimethylamino-2-butcne were dissolved in 300 ml. of 1,1 ,l-trichloroethane and to it was added slowly, with constant stirring, 125 grams of l ,4-dichloro-2-butenc at a rate which kept the reaction mixture at a temperature between 45 and 60C., and stirring was continued at 45 to 60C. for 1 hour after an almost-white precipitate was first deposited. After cooling, the precipitate wascollected by filtration and dried in a vacuum desiccator. ltwcighed 245 grams.

Various changes in relative proportions were made to determine whether any significant variations occurred. These as illustrated as follows:

EXAMPLE 5 14.2 grams of l,4-bis-dimethylamino-2-butenc (0.1

mole) was dissolved in grams of water, and to it was added 25.0 grams of 1,4-dichloro-2-butene (0.2 moles) over a period of 15-30 minutes, maintaining constant stirring. The reaction was exothermic. After 1 hour analysis for ionic chloride showed that the reaction was about 98% complete.

EXAMPLE 6 The same reactants and procedures were used as in Example 5, but the solvent was 35 grams of isopropyl alcohol instead of water. After about 1 hour, the solid polymeric product was filtered off. It weighed about 18.7 grams. I

EXAMPLE 7 The same reactants and procedures as used in Example 5, but using 35 grams of acetone as a solvent instead of water, gave a solid product which weighed 21.4 grams after filtration.

EXAMPLE 8 14.2 grams of 1,4-bis-dimethylamino-2-butene (0. 1 mole) was dissolved in grams of water, and wit was added 37.5 grams of 1,4-dichloro-2-butene over a period of 1530 minutes, maintaining constant stirring.

The reaction was exothermic. After one hour, analysis for ionic chloride showed that the reaction was about 9894 complete.

EXAMPLE 9 EXAMPLE 10 The same reactants and procedures as used in Example 8, but using 45 grams of aceton'einstead of water gave a solid product which weighed 21.4 grams after filtration.

EXAMPLE 1 1 14.2 grams of bis-dimethylamino-Z-butene (0.1 mole) was dissolved in 20 grams of water and to it was added 6.3 grams of 1,4-dichloro-2-butene (0.05 mole) over a period of 15-30 minutes. The reaction was exothermic. After 1 hour, analysis for ionic chloride,

showed that the reaction was about 98% complete' EXAMPLE 12 The same reactants and procedures used in Example 1 1 were used with 20 grams of isopropyl alcohol as sol vent instead of water. After about 1 hour, the. solid f polymeric product was filtered off. It weighed. 9.4

grams.

EXAMPLE 13 The same reactants and procedures as used in Exam ple 1 1 were used, except that 20 grams of acetone replaced water as solvent. After about 1 hour, the product weighed about 10.7 grams.

EXAMPLE 14 21.3 grams of 1,4-bis-dimethylamino-2-butene was (0.15 moles) dissolved in 25 grams of water, and to it was added 6.3 grams of 1,4-dichloro-2-butene (0.05 moles) over a period of 15-30 minutes, maintaining constant stirring. After 1 hour, analysis for ionic ch1o-- ride showed about 9871 completion.

EXAMPLE 15 The same reactants used in Example l4,but with 25 grams of isopropyl alcohol replacing water as solvent,

produced 9.4 grams of solid polymeric product after filtration.

EXAMPLE 16 The same reactants used in Example 14, but with 25 1 grams of acetone replacing water as solvent, produced about 10.7 grams of solid polymeric product.

EXAMPLE '17 In order to determine the microbiocidal effectiveness of the present compound, the following test procedures were used:

Bactericidal Tests l. ml. volume of the product of Example 1 (here? inafter referred to as product A) was diluted in distilled water to the test concentration, and was added asceptically to previously sterilized cotton-stoppered 125 ml. Erlenmeyer flasks. For comparative purposes, the same test concentration was prepared using another known microbiocidal polymeric quaternary ammonium compound, namely a product produced by the reaction of bis(2-chlorocthyl) ether and tetramethyl ethylenediamine (hereinafter referred to as Product B").

2. One set of test flasks were each inoculated with 0.5 ml. of a 1/10 nutrient broth dilution of a 24-hour nutrient broth culture of Aerobactcr aerogenes and another set of test flasks were each inoculated with 0.5 ml. of a one-tenth nutrient broth dilution of a 24-hour nutri ent broth culture of Pseudomonas aeruginosa.

3. At 30 and 60, minutes following inoculation, a 1 ml. aliquot of each product was removed rrom each flask and added to 9 ml. of sterile azolectin/Tween 80" neutralizer from which additional fold serial dilutions were prepared in the sterile neutralizer solution.

4. Agar plate counts were prepared from 10 and 10 dilutions.

5. A control of sterile distilled water was similarly inoculated and aliquots were made at the same intervals and plates at 10*, 10", and 10 dilutions.

6. A comparison of the surviving organisms for various concentrations of test materials, at the different time periods was made. The results were as follows:

Table l AGAINST PSI-IUDUMONAS AEROGINOSA Cone. No. of Bacteria Surviving After Sample in ppm. 30 min. 60 min.

Product A 75 29,600 18,500

Product B" 150 26.000 6,800

-Untretlted 8,500,000 12,500,000

(Control) Table 2 AGAlNST AEROBACI'IJR AERUGl-INLZS Cone. No. of Bacteria Surviving After Sample in ppm. 30 min. 60 min.

Product A" 20 5,600 4,300 50 3,000 1 ,1 100 "Product 13" 100 30,000 30,000

Untreated (Control) 10,500,000 1 1,000,000

Table 3 The following 'l'ahlc comprises a comparison of Product A" and "Product B" at identical concentrations:

AGAINST AI-[ROIMCI'l-JR AEROGENl-IS' Algaestatie Tests 1. 24 ml. volumes of Product A and Product B were prepared in sterile Erlenmeyer flasks at various test concentrations.

2. 1 ml. of 5-7 days Allen's liquid medium growth of Chlorella pyrenoidosa (Wise. strain) was added to each flask (Allens liquid medium is a standard test composition comprising mg. NH,C1, 1000 mg. NaNo 250 mg. K HPO 3 mg. FcCl 513 mg. MgSO 50 mg. CaCl and 1000 mil. distilled water).

3. The inoculated flasks. plus untreated inoculated control flasks, were incubated at room temperature (about 25C.) under continuous artificial illumination.

4. Following 5 to 7 days incubation, observation was made for macroscopic growth to determine the minimum inhibitory level for each test material.

The results were as follows:

Table 4 Sample Minimum effective concentration in ppm.

Product A" 1.0 "Product 13" 1.5

A graduated blender cylinder is rinsed with distilled water. ml, of aqueous test solution is added downthe walls of the blender so as to cause no foam. the blender is turned to high speed for exactly 5 seconds, and upon turning the blades off, timing is started with a stop watch, and at the same time the foam height read in mm. from the 100 ml. mark. The foam half-life is defined as the time it takes for liquid to drain out of the foam and reach the 50 ml. mark.

A further test was made using the Cylinder Shake Test procedure which is as follows:

CYLINDER SHAKE TEST I ml. of test solution is gently poured down the walls of a 250 ml. graduated cylinder that has a glass stopper. The cylinder is stoppered and inverted times in 15 seconds, finally resting it in an upright position. The foam height is read in cc. from the base of the foam.

Table 6 Foam Height in cc. Sample ppm. Initial l min. 5 min.

B'I'C 77(1" 50 45 34 Product A" St) (I (l "BTC 2l25" 5U 50 (i 4 Another test used was .the standard Ross-Miles Test using the procedure reported in "ASTM Standards, Designation 1175-53, Part X, 1958, page 878," which is the ASTM test for foaming properties of surface active material. The results were as follows;

Table 7 Foam Height in cc. Sample ppm. Initial I min. 5 min.

BTC 776' 50 30 20 Product A" 50 0 t) I) BTC 2l25" 5O 35 I5 I() The above results clearly show not only that the product of this invention is highly biocidal but that it is non-foaming, whcreasother quaternary ammonium bi ocides cause a relatively large amount of foaming in aqueous composition.

The following examples illustrate various cosmetic compositions using the product of the present invention:

Example I8 Components 71 by Wt. I by by Wt. "/r by Wt.

Mineral oil (65/75 VisC.) 35.0 35.0 35.0 35.0

Lanolin (Cosmetic Grade) l.() 1.0 1.0 l.()

Celyl alcohol I.() l.() l.() 1.!)

'IWEEN 8t)" (Atlas Powder Co.) (non-ionic "SPAN Rt) (Atlas Powder Co.) (non-ionic emulsifier) "Product A Water (Distilled) 55.0

In the case of the first formulation, without Product A A, the mineral oil, lanolin, cetyl alcohol, Tween 80, and Span 80 were combined and heated to about (157()C. The water was heated to about 7()C. and added slowly to the hot non-aqucousphase while stirring the mixture until it emulsified completely. The emulsion was cooled to room temperatureusing con-. tinued agitation.

In each formulation when Product A was incorporated. the mineral oil, lanolin, cetyl alcohol,Twee n.8(), and Span were combined and heated to about 657()C. The water and Product A were combined and heated to about 6570C. Then the hot aqueous solution was added slowly to the hot non-aqueous phase while stirring, and agitation was maintained until emulsification was effected. Then the emulsion was cooled with continued stirring to room temperature. The resultant product was an oil-in-water emulsion.

These compositions are utilizable as hand creams and baby lotions.

These compositions were tested in thefollowing manner:

50 gm. samples from each composition were aseptieally transferred to sterile 8 02. wide mouth jars. Two replicate jars were prepared in everyinstance, includ; ing an untreated control. Each jar was inoculated with 2.5 ml. of a one-ten sterile nutrient heated dilution of pooled 24 hour broth cultures of Staphylococcus aureus. Pseudomonas aeruginosa, Escherichia coli, Enterobacteraerogenes, proteus species and Bacillus spe cies. In this manner a bacterial challenge load of l-l OX 1 O bacteria/nil. ofjar content was obtained. All. the inoculated jars were stored at 2527C. At weekly intervals following inoculation, 1 ml. aliquots of jar content were removed from each jar and tenfold serial dilutions were prepared therefrom in stcrile A zalectin/- Tween 80 neutralizer solution which wereplated into TGE a jar. In this manner the number of surviving viable bacteria in each jar was determined. In those instances where no viable surviving bacteria lO bac.teria) were observed at four weeks following inoculation,

the jar contents were reinoculated exactly as previously and IOXIO bacteria/ml. The. variation around the mean of the inoculum concentration is of little importance when a reduction to less than lO/ml. ofviable l bacteria is observed.

Table 8 INOCULATION at 6 X It) organisms/nth ol'jar content for each of the four formulations of Example 18.

From a statistical point of view, there is no significant difference between an initial inoculum load of IX I 0 Week Count Count Count Count I (19 X H)" l5.()(l() II) 10' 2 71 X [0" 74,000 H) l() 3 54 X It) 1.400 l(). [0 4 XI II) II) 10 In order to double'check the validity of this test showing less than 10 organisms/ml. after four weeks,

the samples were rcinoculat cd and the weekly counts Table 10 after reinoculation were:

INOCULATION at 3.8X10 organisms/ml. of jar content for each o1- the four formulations o1- Example 20:

Week Count Count Count Count 5 Count Count Count Count eek 5 10K X10" 10 10 10 6 169 X 10" 10 10 10 I [8x100 ISXIOIF RXXIUH 7 180x10" 10 10 10 2 23x1 :lxloli IZXIU ()IZXHW 8 209 X 10' 10 10 10 3 87x10 7 84x10" sfixloli 4 l()(t l0' 50x10" 70x10" 80x10" 10 5 109x10" 114x10" 50x10" 20x10" UZXIU 7'JXI1)" 45Xl0" 36 l0' The followmg example were prepared in the same 4X10 89x10" 67x10 750x10" manner as Example 18, but substnutmg other well- 8 fi mzxmfi xlxm" known, highly active biocidal quaternary ammonium compounds for Product A. They were then similarly evaluated.

Ex'tm 1e 19 p Example 21 I" F I/ I" Componuns h W1. 1 h Wt. by Wt. h Wt. Comlmmms (/1 by wt. by wt WL Mimml *1" Mineral 011 55.0 55.0 55.0 55.0 105/75 VISC.) 35.0 35.0 35.0 55.0 (65/75 visa) Lanolin Lanolin (Cosmetic Grade) 1.0 1.0 (Cosmetic Cetyl Alcohol 1.0 1.0 1.0 1 0 Grade) 1.0 1.0 1.0 1.0 TWEEN 150" 5.4 .1 5.4 Cetyl alcohol 1.0 1.0 1.0 1.0 SPAN 110 2.0 2.0 2.0 2.0 E 80' 5.4 .4 5.4 5.4 BTC snr SPAN 80 2.6 .0 2.6 2.6 (On\'x (711001.01) 0 0.1 0.2 04 HYAMINE 1633 Water (507') (131511110111 55.0 54.0 54.1: 54.0

Table 9 lNOCULATlON at 4.7 X 1()orgnnisn1s/ml. o1 jar content for each of the lour formulations of Example 19.

. Table 1 1 Count Count Count Count cck INOCULATION at 3.1"1 l0 organisms/ml. ot' jar content for each i 40 of the four formulations of Example 21: 1 10x10- 10x10" 10x10" 4x10" 3 98x10" 13x10" 1 1X10" 5X10" Count Count Count Count 1 07x10" 40x10 24x10 10x10" COR 4 142x10" lt)2 84x10" 01x10" 5 167Xl0" l19 l0 X4Xl0" (17 l0 l ZZXIU 19X 10 l7 l0"' l5 l0 6 180x10" l 14 10 32x11)" 44x11)" 2 P.4Xl0 21x11)" 19 l0 l -l l0 7 140x10" 95x10 82x10" 70x10" 3 80x10" 71x10" 94x10" 111x10" 8 4 0" 2 1 0 54 4 94x10 80x10 72Xl0 92X10" 5 106 l0 74 10" 67 l0 x10" 6 l loXlt) 91x10 84x10 X10 7 '-)Z l() 74 l0' 4ZX10 ZXXH)" 8 94X10" 82x10" 56 10' 43Xl0" 50 Example 20 Components "/1 by Wt. 71 hy Wt. 71 by Wt. by Wt.

Mineral oil gs (65/75 \-1se.) 35.0 35.0 35.0 35.0 Example 22 Lanolin (Cosmetic (irade) 1.0 1.0 1.0 1.0 Components "/1 by Wt. '/r by Wt. by Wt. 71 by Wt.

Cetyl alcohol 1.0 1.0 1.0 1.0 Mineral oil 0 (65/75 Vise.) 35.0 35.0 35.0 35.0 TWEEN 110" 5.4 5.4 5.4 0 5.4 Lwmlin (Cosmetic (irade) 1.0 1.0 1.0 1.0

. Z. 2. 2. 2X 51 AN 6 Cetyl 111001101 1.0 1.0 1.0 1.0 TWEEN 5.4 5.4 5.4 5.4 i 3135M "SPAN 2.0 2.0 2.0 2.0 HYAMINE 23110" (Onyx henLC o.) 0 0.1 0.2 0.4 1

(Robin & Haas) 0 0.1 0.2 0.4 Water Water (Distilled) 5540 54.) 54.1 5 (Distilled) 55.0 54.9 54.8 54.6

Table 12 INOCULATION at 4.l'l l() organisms/ml. of jar content for each of the four fornnilations of Example 22:

Although oil-in-water emulsions have been described above, it is within the scope of the present invention to use water-in-oil emulsions for the same purposes.

The invention claimed is:

l. A method of controlling the proliferation of deleterious microorganisms selected from the group consisting of bacteria and algae in an aqueous system, which comprises applying to said microorganisms a hacteriacidally or algaecidally effective amount of a condensation product formed'by mixing l,4-bisdimethylamino-Z-butene dissolved in a solvent with 1,4- dihalo-Z-butene at room temperature whereby an exothermic reaction is obtained causing the temperature of the mixture to rise, then maintaining the mixture at no higher than reflux temperature until the reaction is LII complete, wherein these reactants arepresent ina molar proportion of between about 1:3 and about 321 relative to each other.

2. The method of claim 1 wherein the dihalo is dichloro.

3. The method of claim 1 wherein the dihalo. is dibromo.

4. The method of claim 1 wherein the aqueousmedia is recirculated water.

5. An aqueous composition containing, as a biocidal agent, the condensation product formed by mixing] ,4- a

bis-dimethylamino-Z-butene dissolved in a solvent with l,4-dihalo-2-butene at room temperature whereby an .exothcrmicreaction is obtained causing the temperature of the mixture to rise, then maintaining the mixture at no higher than reflux temperature until the reaction is complete, wherein these reactants are in a molar proportion of between about about 1:3 and about 3:]

relative to each other, said agent being present in a bacteriacidally or algaecidally effective amount.

6. The composition of claim 5 wherein said aqueous media comprises recirculating water.

Claims (8)

1. A METHOD OF CONTROLLING THE PROLIFERATION OF DELETERIOUS MICROORGANISMS SELECTED FROM THE GROUP CONSISTING OF BACTERIA AND ALGAE IN AN AQUEOUS SYSTEM, WHICH COMPRISES APPLYING TO SAID MICROOGANISMS A BACTERIACIDALLY OR ALAECIDALLY EFFECTIVE AMOUNT OF A CONDENSATION PRODUCT FORMED BY MIXING 1,4BISIDIMETHYLAMINO-2-BUTENE DISSOLVED IN A SOLVENT WITH 1,4DIHALO-2-BUTENE AT ROOM TEMPERATURE WHEREBY AN EXOTHERMIC REACTION IS OBTAINED CAUSING THE TEMPERATURE OF THE MIXTURE TO RISE, THEN MAINTAINING THE MIXTURE AT NO HIGHER THAN REFLUX TEMPERATURE UNTIL THE REACTION COMPLETE,
2. The method of claim 1 wherein the dihalo is dichloro.
3. The method of claim 1 wherein the dihalo is dibromo.
4. The method of claim 1 wherein the aqueous media is recirculated water.
5. An aqueous composition containing, as a biocidal agent, the condensation product formed by mixing 1,4-bis-dimethylamino-2-butene dissolved in a solvent with 1,4-dihalo-2-butene at room temperature whereby an exothermic reaction is Obtained causing the temperature of the mixture to rise, then maintaining the mixture at no higher than reflux temperature until the reaction is complete, wherein these reactants are in a molar proportion of between about about 1:3 and about 3:1 relative to each other, said agent being present in a bacteriacidally or algaecidally effective amount.
6. The composition of claim 5 wherein said aqueous media comprises recirculating water.
7. The composition of claim 5 wherein said composition is an aqueous emulsion containing non-ionic emulsifiers.
8. The composition of claim 5 wherein said composition is a hand cream or baby lotion.
US3874870A 1973-12-18 1973-12-18 Microbiocidal polymeric quarternary ammonium compounds Expired - Lifetime US3874870A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US3874870A US3874870A (en) 1973-12-18 1973-12-18 Microbiocidal polymeric quarternary ammonium compounds

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US3874870A US3874870A (en) 1973-12-18 1973-12-18 Microbiocidal polymeric quarternary ammonium compounds
US3929990A US3929990A (en) 1973-12-18 1974-08-07 Microbiocidal polymeric quaternary ammonium compounds
US3923973A US3923973A (en) 1973-12-18 1974-09-30 Fungicidal polymeric quaternary ammonium compounds
US3928323A US3928323A (en) 1973-12-18 1974-10-03 Anti-microbial quaternary ammonium co-polymers
US05565839 US4025627A (en) 1973-12-18 1975-04-07 Microbiocidal polymeric quaternary ammonium compounds

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US47852474 Continuation-In-Part 1974-06-12 1974-06-12
US48696074 Continuation-In-Part 1974-07-10 1974-07-10
US3929990A Continuation-In-Part US3929990A (en) 1973-12-18 1974-08-07 Microbiocidal polymeric quaternary ammonium compounds
US3928323A Continuation-In-Part US3928323A (en) 1973-12-18 1974-10-03 Anti-microbial quaternary ammonium co-polymers

Publications (1)

Publication Number Publication Date
US3874870A true US3874870A (en) 1975-04-01

Family

ID=23688625

Family Applications (1)

Application Number Title Priority Date Filing Date
US3874870A Expired - Lifetime US3874870A (en) 1973-12-18 1973-12-18 Microbiocidal polymeric quarternary ammonium compounds

Country Status (1)

Country Link
US (1) US3874870A (en)

Cited By (312)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2307856A1 (en) * 1975-04-14 1976-11-12 British Petroleum Co polymer composition forming a film and used as a paint preventing fouling by marine organisms
US4025617A (en) * 1974-10-03 1977-05-24 Millmaster Onyx Corporation Anti-microbial quaternary ammonium co-polymers
US4155994A (en) * 1977-01-21 1979-05-22 Kewanee Industries, Inc. Hair conditioning agents
US4157388A (en) * 1977-06-23 1979-06-05 The Miranol Chemical Company, Inc. Hair and fabric conditioning compositions containing polymeric ionenes
US4197865A (en) * 1975-07-04 1980-04-15 L'oreal Treating hair with quaternized polymers
US4209397A (en) * 1979-01-31 1980-06-24 Kewanee Industries Flocculants for aqueous systems
US4240450A (en) * 1977-03-15 1980-12-23 L'oreal Composition and process for the treatment of keratin materials with polymers
US4379137A (en) * 1979-06-30 1983-04-05 Sterling Drug Inc. Disinfecting and preserving composition comprising a synergistic combination of a polymeric quaternary ammonium compound and a 3-isothiazolone compound
US4381919A (en) * 1975-07-04 1983-05-03 Societe Anonyme Dite: L'oreal Hair dye composition containing quaternized polymers
US4418054A (en) * 1976-11-24 1983-11-29 Millmaster Onyx Group, Inc. Polymeric quaternary ammonium compounds for skin care
US4488564A (en) * 1980-12-19 1984-12-18 L'oreal Oily composition intended for the treatment of keratin substances and the skin
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
EP0382562A1 (en) * 1989-02-10 1990-08-16 Buckman Laboratories International, Inc. Polymeric quaternary ammonium trihalides useful as microbicides, sanitizers and disinfectants
WO1991009522A1 (en) * 1990-01-05 1991-07-11 Allergan, Inc. Ophthalmic compositions and methods for preserving and using same
US5277901A (en) * 1990-01-05 1994-01-11 Allergan, Inc. Ophthalmic compositions and methods for preserving and using same
US5326841A (en) * 1989-01-25 1994-07-05 Epitope, Inc. Germicidal barriers
US5371083A (en) * 1989-09-27 1994-12-06 Buckman Laboratories International, Inc. Synergistic combinations of ionenes with hexahydro-1,3,5-tris-(2-hydroxyethyl)-s-triazine in controlling fungal and bacterial growth in synthetic metalworking fluids
US5387717A (en) * 1992-08-12 1995-02-07 Buckman Laboratories International, Inc. Method for the detoxification of mustard gas, sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US5401881A (en) * 1992-08-12 1995-03-28 Buckman Laboratories International, Inc. Sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US5419897A (en) * 1993-04-09 1995-05-30 Buckman Laboratories International, Inc. Ionene polymers as anthelmintics in animals
US5451398A (en) * 1990-01-05 1995-09-19 Allergan, Inc. Ophthalmic and disinfecting compositions and methods for preserving and using same
US5489569A (en) * 1992-12-14 1996-02-06 Buckman Laboratories International, Inc. Composition and method for increasing the effectiveness of pesticides
US5512597A (en) * 1991-11-08 1996-04-30 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobials
US5536494A (en) * 1994-10-04 1996-07-16 Alcon Laboratories, Inc. Polyethylene oxide-containing quaternary ammunium polymers and pharmaceutical compositions containing an antimicrobial amount of same
EP0723772A1 (en) 1995-01-30 1996-07-31 L'oreal Reducing composition bared on a basic amino acid and a cationic polymer
US5575993A (en) * 1994-08-31 1996-11-19 Buckman Laboratories International, Inc. Ionene polymers containing biologically-active anions
US5637308A (en) * 1995-07-10 1997-06-10 Buckman Laboratories International, Inc. Tabletized ionene polymers
WO1997029741A1 (en) * 1996-02-14 1997-08-21 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobials
US5661118A (en) * 1994-04-22 1997-08-26 L'oreal Hair and skin washing and treatment compositions based on ceramide and/or glycoceramide and on polymers containing cationic groups
US5681862A (en) * 1993-03-05 1997-10-28 Buckman Laboratories International, Inc. Ionene polymers as microbicides
WO1997045473A1 (en) * 1991-11-08 1997-12-04 Alcon Laboratories, Inc. Absolute molecular weight polymers and methods for their use
WO1997046210A1 (en) 1996-06-07 1997-12-11 L'oreal Detergent cosmetic compositions for hair care and utilisation thereof
US5700456A (en) * 1994-04-21 1997-12-23 L'oreal Compositions for the treatment and protection of hair, based on ceramide and/or glycoceramide and on polymers containing cationic groups
US5707534A (en) * 1995-07-10 1998-01-13 Buckman Laboratories International, Inc. Use of tabletized ionene polymers in water treatment
US5709880A (en) * 1995-07-10 1998-01-20 Buckman Laboratories International, Inc. Method of making tabletized ionene polymers
WO1998013444A1 (en) * 1996-09-24 1998-04-02 Cincinnati Milacron Inc. Machining fluid composition and method of machining
DE19646726A1 (en) * 1996-11-13 1998-05-14 Widulle Herbert Dipl Chem Dr Topical composition containing polymeric quaternary ammonium salt
US5776960A (en) * 1996-10-16 1998-07-07 Buckman Laboratories International, Inc. Synergistic antimicrobial compositions containing an ionene polymer and a pyrithione salt and methods of using the same
US5843865A (en) * 1996-02-07 1998-12-01 Buckman Laboratories International, Inc. Synergistic antimicrobial compositions containing an ionene polymer and a salt of dodecylamine and methods of using the same
US5866016A (en) * 1997-07-01 1999-02-02 Buckman Laboratories International, Inc. Methods and compositions for controlling biofouling using combinations of an ionene polymer and a salt of dodecylamine
US5962555A (en) * 1996-06-25 1999-10-05 Buckman Laboratories International, Inc. ASA sizing emulsions containing low and high molecular weight cationic polymers
US6051611A (en) * 1991-11-08 2000-04-18 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobias
US6114484A (en) * 1998-11-16 2000-09-05 Nalco Chemical Company Polymers for chemical treatment and precipitation of soluble metal cyanide and oxoanion compounds from waste water
US6153570A (en) * 1996-06-07 2000-11-28 L'oreal S.A. Detergent cosmetic compositions and use
US6162423A (en) * 1996-07-23 2000-12-19 L'oreal S.A. Washing and conditioning compositions containing silicone and dialkyl ether
US6203451B1 (en) 1999-01-13 2001-03-20 Acushnet Company Zwitter-ion and ionene golf ball forming compositions and methods
US6260556B1 (en) 1999-01-29 2001-07-17 L'oreal Anhydrous composition for bleaching keratin fibers
WO2001068043A2 (en) 2000-03-14 2001-09-20 L'oreal Dyeing compositions for keratinous fibres containing paraphenylenediamine derivatives with pyrrolidinyl group
US6338842B1 (en) 1999-02-03 2002-01-15 L'oreal S.A. Cosmetic composition comprising an anionic surfactant, an amphoteric surfactant, a polyolefin, a cationic polymer and a salt or an alcohol which is water-soluble, use and process
US6379401B1 (en) 1999-01-29 2002-04-30 L'oreal, S.A. Anhydrous composition for bleaching keratin fibers comprising a combination of a water-soluble thickening polymer and a nonionic amphiphilic polymer comprising at least one fatty chain
US6410493B1 (en) 1998-11-12 2002-06-25 L'oreal S.A. Conditioning and detergent composition comprising an anionic surfactant, a silicone, and a cationic polymer
US6423305B1 (en) 1997-12-29 2002-07-23 L'oreal S.A. Cosmetic composition comprising at least an amidoethercarboxylic acid surfactant and at least a cationic polymer/anionic polymer combination
US6436151B2 (en) 1999-12-30 2002-08-20 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain, and at least one fatty alcohol comprising more than twenty carbon atoms and uses thereof
US6444197B2 (en) 1999-12-13 2002-09-03 L'oreal S.A. Bleaching composition for keratin fibers, comprising a combination of two polyurethane polyethers
US6451298B1 (en) 1999-10-20 2002-09-17 L'oreal, S.A. Cosmetic compositions comprising at least one silicone copolymer and at least one cationic polymer, and uses thereof
US6471953B1 (en) 1999-06-28 2002-10-29 L'oreal S.A. Permanent-waving process comprising the preliminary application of a composition comprising at least one anionic polymer
US20020157193A1 (en) * 2001-02-02 2002-10-31 Frederic Legrand Pulverulent composition for bleaching human keratin fibers
US6482400B1 (en) 1999-06-30 2002-11-19 L'Oréal S.R. Mascara containing film-forming polymers
US20020177828A1 (en) * 1998-12-08 2002-11-28 Batich Christopher D. Absorbent materials with covalently-bonded, nonleachable, polymeric antimicrobial surfaces, and methods for preparation
US20020193265A1 (en) * 2001-03-30 2002-12-19 Beatrice Perron Detergent cosmetic compositions containing an anionic surfactant derived from amino acids and salts thereof and a soluble conditioning agent and uses thereof
US6506372B1 (en) 1999-06-25 2003-01-14 L'oreal S.A. Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses
US20030023782A1 (en) * 2001-07-26 2003-01-30 International Business Machines Corp. Microprocessor system bus protocol providing a fully pipelined input/output DMA write mechanism
US20030019597A1 (en) * 2001-06-05 2003-01-30 Hill Walter B. Polymeric creping adhesives and creping methods using same
US6514488B1 (en) 1999-02-03 2003-02-04 L'oreal S.A. Detergent cosmetic compositions and uses thereof
US20030031644A1 (en) * 2001-01-18 2003-02-13 Geltex Pharmaceuticals, Inc. Ionene polymers and their use as antimicrobial agents
US6534047B1 (en) 1999-06-30 2003-03-18 L'oreal S.A. Mascara containing film-forming polymers
US20030074747A1 (en) * 2001-07-27 2003-04-24 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US20030103929A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20030103926A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20030108503A1 (en) * 2001-09-11 2003-06-12 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20030118537A1 (en) * 2001-11-08 2003-06-26 Priscille Devin-Baudoin Process for permanently reshaping the hair using particular aminosilicones
US6589519B1 (en) 1997-08-25 2003-07-08 L'oreal S.A. Cosmetic compositions containing a polyoxyalkylenated aminosilicone block copolymer and a conditioner, and uses thereof
US20030126692A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-treatment of processes for coloring keratin fibers with direct dyes or with oxidation dyes
US20030129155A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US20030140429A1 (en) * 2001-11-08 2003-07-31 Frederic Legrand Keratin fibre dyeing composition comprising a particular aminosilicone
US20030147827A1 (en) * 2001-11-08 2003-08-07 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030147841A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147840A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147842A1 (en) * 2001-11-08 2003-08-07 Serge Restle Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20030152541A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030152542A1 (en) * 2001-11-08 2003-08-14 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030152543A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030157049A1 (en) * 2001-11-08 2003-08-21 Jonathan Gawtrey Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US6635262B2 (en) 2000-03-14 2003-10-21 L'oreal S.A. Roll-on applicator comprising a hair composition
US20030223948A1 (en) * 2002-03-28 2003-12-04 Mireille Maubru Cosmetic composition comprising at least one anionic surfactant, at least one cationic polymer and at least one amphiphilic, branched block acrylic copolymer and method for treating hair using such a composition
US6663902B1 (en) 2000-09-19 2003-12-16 Ecolab Inc. Method and composition for the generation of chlorine dioxide using Iodo-Compounds, and methods of use
US20040019981A1 (en) * 2000-11-08 2004-02-05 Francois Cottard Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US20040025266A1 (en) * 2000-11-08 2004-02-12 Francois Cottard Oxidation dyeing composition for karatinous fibres comprising a cationic associative polyurethane
US6695887B2 (en) 1999-12-30 2004-02-24 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one fatty alcohol having more than twenty carbon atoms and at least one oxyalkylenated nonionic surfactant with an hlb greater than 5
US20040037796A1 (en) * 2000-11-20 2004-02-26 Francois Cottard Composition for treating keratinous materials comprising a cationic associative polyurethane polymer and a protecting or conditioning agent
US20040034944A1 (en) * 2000-08-21 2004-02-26 Frederic Legrand Bleaching composition for dyed keratinous fibers
US20040039101A1 (en) * 2002-05-31 2004-02-26 Claude Dubief Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer
US20040034946A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US20040034947A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Bleachng composition for keratinous fibres comprising an associate polyurethane
US20040049861A1 (en) * 2000-12-04 2004-03-18 Francois Cottard Oxidation dyeing composition for keratinous fibres comprising an associative polymer and a pearling agent
US20040060126A1 (en) * 2000-12-04 2004-04-01 Francois Cottard Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US20040064902A1 (en) * 2000-12-06 2004-04-08 Stephane Sabelle Oxidatiton dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in position 2 and 5
US20040077510A1 (en) * 2002-07-08 2004-04-22 Pascale Lazzeri Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US20040077852A1 (en) * 2002-07-05 2004-04-22 Stephane Sabelle Para-phenylenediamine derivatives containing a pyrrolidyl group, and use of these derivatives for coloring keratin fibers
US20040074013A1 (en) * 2000-12-06 2004-04-22 Eric Terranova Oxidation dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in positions 3 and 4, and dyeing method using same
US20040083559A1 (en) * 2000-12-06 2004-05-06 Stephane Sabelle Dyeing composition based on 1-(4-aminophenyl)pyrrolidines substituted at least in positions 2 and 3
US20040088799A1 (en) * 2000-12-06 2004-05-13 Stephane Sabelle Oxidation dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in position 2
US20040093675A1 (en) * 2001-04-02 2004-05-20 Laurent Vidal Dyeing composition for dyeing kerationou fibres comprising a cationic azo-dye
US20040105832A1 (en) * 2001-01-12 2004-06-03 Geraldine Fack Cosmetic compositions containing fructan and a cationic polymer and their uses
US20040105833A1 (en) * 2001-03-30 2004-06-03 Geraldine Fack Cosmetic compositions containing a starch phosphate and a cationic polymer and uses thereof
US20040122807A1 (en) * 2002-12-24 2004-06-24 Hamilton Darin E. Methods and systems for performing search interpretation
US20040123401A1 (en) * 2002-09-09 2004-07-01 Stephane Sabelle Bis-para-phenylenediamine derivatives comprising a pyrrolidyl group and use of these derivatives for dyeing keratin fibres
US20040133994A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
US20040133995A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US20040163186A1 (en) * 2002-12-06 2004-08-26 Frederic Simonet Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US20040175352A1 (en) * 2003-03-06 2004-09-09 David Oppong Microbicidal compositions including an ionene polymer and 2,4,4-trichloro-2-hydroxydiphenyl ether, and methods of using the same
US20040180030A1 (en) * 2002-12-19 2004-09-16 Mireille Maubru Cosmetic compositions comprising at least one alkylamphohydroxyalkylsulphonate amphoteric surfactant and at least one nacreous agent and/or opacifier, and uses thereof
US6800098B1 (en) 1999-12-08 2004-10-05 L'oreal, S.A. Oxidation dye composition for keratinic fibres containing a thickening polymer with an ether plastic skeleton
US6800096B1 (en) 1999-12-08 2004-10-05 L'oreal S.A. Composition, process and kit for bleaching keratin fibers comprising at least one thickening polymer with an aminoplast-ether skeleton
US20040208843A1 (en) * 2002-09-24 2004-10-21 Gabin Vic Cosmetic composition comprising an exogenous ligand-receptor system adsorbed or covalently attached to keratin materials, and hair treatment using this composition or constituent elements thereof
US20040205902A1 (en) * 2002-12-06 2004-10-21 Francois Cottard Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
US20040221401A1 (en) * 2003-03-25 2004-11-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20040226110A1 (en) * 2003-01-16 2004-11-18 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20040235700A1 (en) * 2003-01-16 2004-11-25 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20040234485A1 (en) * 2003-03-11 2004-11-25 Mireille Maubru Cosmetic compositions comprising at least one crosslinked copolymer, at least one insoluble mineral particle and at least one polymer, and uses thereof
US20040237213A1 (en) * 2001-06-12 2004-12-02 Gregory Plos Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US20040237217A1 (en) * 2003-03-25 2004-12-02 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20040256598A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US20040258641A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US20050005371A1 (en) * 2003-04-01 2005-01-13 Chrystel Pourille-Grethen Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US20050005368A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US20050008593A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US20050008594A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Composiiton for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US20050011017A1 (en) * 2003-03-25 2005-01-20 L'oreal S.A. Oxidizing composition comprising hydroxycarboxylic acids and salts thereof as complexing agents for dyeing, bleaching or permanently reshaping keratin fibres
US20050033251A1 (en) * 1998-12-08 2005-02-10 Quick-Med Technologies, Inc. Controlled release of biologically active substances from select substrates
US20050028301A1 (en) * 2001-09-28 2005-02-10 Florent Pastore Dyeing composition with a brightening effect for human kerationous fibres
US20050031562A1 (en) * 2003-04-01 2005-02-10 Luc Gourlaouen Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US20050036970A1 (en) * 2003-03-25 2005-02-17 L'oreal S.A. Reducing compositions for bleaching or permanently reshaping keratin fibres comprising polycarboxylic acids and salts thereof as complexing agents
US20050039270A1 (en) * 2003-03-25 2005-02-24 L'oreal S.A. Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres
US20050076457A1 (en) * 2003-04-01 2005-04-14 Gregory Plos Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof
US20050098763A1 (en) * 2003-04-01 2005-05-12 Gregory Plos Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
US20050125912A1 (en) * 2001-12-21 2005-06-16 Patricia Desenne Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US6916344B1 (en) 1999-12-08 2005-07-12 L'oreal S.A. Direct dyeing composition for keratinic fibers containing a thickening polymer with an ether plastic skeleton
US6919073B2 (en) 2001-05-16 2005-07-19 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US20050158262A1 (en) * 2003-12-19 2005-07-21 Eric Parris Cosmetic composition comprising a cationic agent, a polymer comprising a hetero atom and an oil, and cosmetic treatment process
US20050175569A1 (en) * 2004-01-07 2005-08-11 Geraldine Fack Cosmetic compositions comprising a cation, a drawing polymer and a thickener, and cosmetic treatment processes
US20050186151A1 (en) * 2003-08-11 2005-08-25 Franck Giroud Cosmetic composition comprising stabilized and optionally coated metal particles
US20050188475A1 (en) * 2004-01-07 2005-09-01 Alain Lagrange Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US6946005B2 (en) 2002-03-27 2005-09-20 L'oreal S.A. Pyrrolidinyl-substituted para-phenylenediamine derivatives substituted with a cationic radical, and use of these derivatives for dyeing keratin fibers
US20050208005A1 (en) * 2003-08-11 2005-09-22 Franck Giroud Cosmetic composition comprising particles having a core-shell structure
US20050232883A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US20050232884A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US20050232885A1 (en) * 2004-01-07 2005-10-20 L'oreal Detergent cosmetic compositions comprising at least one surfactant, at least one drawing polymer and at least one nonsilicone conditioner, and use thereof
US20050238599A1 (en) * 2001-11-08 2005-10-27 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US20060002887A1 (en) * 2002-11-19 2006-01-05 Genzyme Corporation Ionene oligomers and polymers
US6984250B1 (en) 1999-12-08 2006-01-10 L'oreal Composition, method, and kit for the bleaching or permanent reshaping of keratin fibers, comprising at least one thickening polymer with an aminoplast-ether skeleton
US20060010617A1 (en) * 2002-12-24 2006-01-19 Luc Gourlaouen Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20060025318A1 (en) * 2004-04-22 2006-02-02 Mireille Maubru Composition for washing and conditioning keratin materials, comprising a carboxyalkyl starch, and process for the use thereof
EP1634569A1 (en) 2004-09-08 2006-03-15 L'oreal Cosmetic composition based on a cationic surfactant, a fatty alcohol, a cationic non-silicone polymer and a diol
US20060057096A1 (en) * 2004-09-08 2006-03-16 Pascale Lazzeri Cosmetic composition comprising at least one cationic surfactant, at least one aminated silicone, at least one fatty alcohol, and at least one diol
US7045673B1 (en) 1998-12-08 2006-05-16 Quick-Med Technologies, Inc. Intrinsically bactericidal absorbent dressing and method of fabrication
US20060156479A1 (en) * 2004-12-23 2006-07-20 Leila Hercouet Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
EP1688127A1 (en) 2005-01-18 2006-08-09 L'oreal Hair treatment composition containing an aromatic alcohol, an aromatic carboxylic acid a protecting agent
US20060182697A1 (en) * 2005-01-18 2006-08-17 Boris Lalleman Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
EP1698326A2 (en) 2005-02-11 2006-09-06 L'oreal Cosmetic composition comprising a cationic surfactant, a cationic polymer, a solid compound and a starch, and cosmetic treatment process
EP1707190A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a hydrophobically modified nonionic cellulose and method for dyeing keratin fibres using it
EP1707182A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a fatty acid ester and process for dyeing keratin fibres using the same
EP1707183A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a non-ionic associative polymer, process for dyeing keratin fibres using same
EP1707181A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, and process for dyeing keratin fibres using the same
EP1707184A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibres using the same and device therefor
EP1716841A1 (en) 2002-12-06 2006-11-02 L'Oréal Composition for the oxidative dyeing of keratinic fibers
EP1716840A1 (en) 2005-03-31 2006-11-02 L'oreal Hair-dye composition containing a glycerol ester and the corresponding hair-dyeing process
US20060248662A1 (en) * 2005-03-31 2006-11-09 Frederic Legrand Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US20060257339A1 (en) * 2005-05-13 2006-11-16 L'oreal Use of conductive polymer nanofibers for treating keratinous surfaces
US20060260071A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US20060260070A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US20060260069A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
US20060269493A1 (en) * 2004-02-05 2006-11-30 Quick-Med Technologies, Inc. Silicate and other oxide powders with bonded anitmicrobial polymers
US20060265817A1 (en) * 2005-03-31 2006-11-30 Frederic Legrand Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
US7147673B2 (en) 2003-04-01 2006-12-12 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof
US20070074356A1 (en) * 2005-09-29 2007-04-05 Boris Lalleman Process for the photoprotective treatment of artificially dyed keratin fibers by application of a liquid water/steam mixture
US7211268B2 (en) 2001-11-15 2007-05-01 L'oreal S.A. Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US20070104668A1 (en) * 2005-10-28 2007-05-10 Virginie Masse Composition for the care of keratin material and cosmetic treatment process using said composition
US20070104747A1 (en) * 2005-10-28 2007-05-10 Virginie Masse Cosmetic composition comprising at least one anti-dandruff agent and also oxyethylenated sorbitan monolaurate, and cosmetic treatment process using said composition
US20070105734A1 (en) * 2005-10-28 2007-05-10 Sandrine Decoster Composition for washing keratin materials and cosmetic treatment process using said composition
US20070106061A1 (en) * 2005-09-27 2007-05-10 Zollinger Mark L Methods to reduce organic impurity levels in polymers and products made therefrom
US20070141006A1 (en) * 2004-03-17 2007-06-21 Aude Livoreil Cosmetic compositions containing modified polyamines and the uses thereof
US20070174974A1 (en) * 2003-05-09 2007-08-02 De La Mettrie Roland Process for treating keratin fibres by applying heat
US20070191255A1 (en) * 2006-02-16 2007-08-16 Buckman Laboratories International, Inc. Method and composition to control the growth of microorganisms in aqueous systems
US20070190008A1 (en) * 2005-12-20 2007-08-16 Catherine Campain Process for permanently reshaping the hair, comprising applying to the hair at least one precipitated fixing polymer, and multi-compartment device
US7258852B2 (en) 2001-09-11 2007-08-21 L'oreal S.A. Cosmetic compositions containing a methacrylic acid copolymer and an oil, and uses thereof
US20070197388A1 (en) * 2006-02-22 2007-08-23 Buckman Laboratories International, Inc. Haloperoxidase treatment to control algae
US20070237733A1 (en) * 2004-01-05 2007-10-11 Frederic Simonet Cosmetic Composition of Water-in-Water Emulsion type Based on Surfactants and Cationic Polymers
US20070251026A1 (en) * 2006-04-12 2007-11-01 Boris Lalleman Unsaturated fatty substances for protecting the color of artificially dyed keratin fibers with respect to washing; and dyeing processes
US7303589B2 (en) 2003-04-01 2007-12-04 L'oreal S.A. Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same
EP1920755A1 (en) 2006-11-10 2008-05-14 L'Oréal Method for permanently deforming keratinous fibres comprising a step of applying an intermediate rinsing component comprising a monovalent metal cation salt or an ammonia salt and an organic acid
US20080119554A1 (en) * 2004-11-26 2008-05-22 Rajiv Jalan Compositions Comprising Ornithine And Phenylacetate Or Phenylbutyrate For Treating Hepatic Encephalopathy
US20080127429A1 (en) * 2006-10-25 2008-06-05 Gaelle Brun Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
EP1935396A1 (en) 2006-12-22 2008-06-25 L'Oreal Method for permanently deforming keratinous fibres including a step of applying a reducing composition with a low concentration and an intermediate drying step
EP1944011A1 (en) 2007-01-12 2008-07-16 L'Oréal Reductive composition designed to be used in a method for permanently deforming keratinous fibres containing cysteine and thiolactic acid or one of their salts
US20080241247A1 (en) * 2007-03-27 2008-10-02 Buckman Laboratories International, Inc. Compositions and Methods To Control the Growth Of Microorganisms In Aqueous Systems
US20080262194A1 (en) * 2007-04-17 2008-10-23 Advanced Medical Optics, Inc. Polyquaternium-1 synthesis methods
EP1997473A2 (en) 2007-04-30 2008-12-03 L'Oreal Use of a multi-carbosite, multi-group coupling agent for protecting the colour of artificially dyed keratin fibres with respect to washing; dyeing processes
EP2011473A1 (en) 2007-06-29 2009-01-07 L'Oreal Anhydrous composition in paste form for bleaching keratinous fibres.
DE102007030642A1 (en) 2007-07-02 2009-01-08 Momentive Performance Materials Gmbh A process for the preparation of polyorganosiloxanes having (C6-C60) -Alkylmethylsiloxygruppen and dimethylsiloxy
EP2039345A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic compositions containing a cationic copolymer and a particular triglyceride and uses thereof
EP2039346A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic composition comprising a cationic copolymer and a starch and cosmetic treatment process
EP2039344A2 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic composition comprising a cationic copolymer and an anionic associative polymer and cosmetic treatment process
US20090081148A1 (en) * 2000-08-25 2009-03-26 L'oreal S.A. Protection of keratinous fibers using ceramides and/or glycoceramides
EP2065074A2 (en) 2007-11-09 2009-06-03 L'Oréal Composition for the oxidation dyeing of keratin fibres comprising a cellulose with hydrophobic substituent(s), an oxidation dye and a cationic polymer
EP2065024A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising (meth)acrylic copolymers and at least one oil
EP2065028A2 (en) 2007-11-30 2009-06-03 L'Oreal Repositionable hairstyling composition comprising at least one (meth)acrylic copolymer and at least one silicone.
EP2065023A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising at least one (meth)acrylic copolymer and at least one pearlescent agent
EP2070511A2 (en) 2007-09-14 2009-06-17 L'Oreal Cosmetic composition comprising at least one specific cationic polymer, at least one surface-active agent, at least one cationic or amphoteric polymer and at least one mineral particle, and cosmetic treatment method using said composition
EP2072084A2 (en) 2007-09-14 2009-06-24 L'Oréal Cosmetic compositions containing a cationic copolymer, an amino silicone and a cationic polymer, and uses thereof
EP2072033A2 (en) 2007-09-14 2009-06-24 L'Oreal Cosmetic composition comprising at least one specific cationic polymer and at least one fatty acid ester in C8-C24 and oxyethylenated sorbitan comprising 2 to 10 oxyethylene patterns, and cosmetic treatment method using said composition
US20090203795A1 (en) * 2007-04-17 2009-08-13 Abbott Medical Optics Inc. Polyquaternium-1 synthesis methods and associated formulations
US20090209716A1 (en) * 2007-04-17 2009-08-20 Abbott Medical Optics Inc. Polyquarternium-1 synthesis methods
EP2092961A1 (en) 2008-02-22 2009-08-26 L'Oréal Use of particular cationic polymers as anti-oxidant or anti-radical agents
EP2092933A1 (en) 2008-02-22 2009-08-26 L'Oréal Use of particular cationic polymers in a dye composition and associated with a chelating agent as antioxidants or free-radical scavengers
EP2111842A1 (en) 2008-03-28 2009-10-28 L'Oréal Dyeing composition comprising ammonium chloride, method of colouring keratin fibres, and device
EP2113240A1 (en) 2008-04-28 2009-11-04 L'Oréal Cosmetic composition comprising an emulsion obtained by a PIT method
EP2116220A1 (en) 2008-04-28 2009-11-11 L'Oreal Cosmetic composition comprising an emulsion obtained by a PIT method
US20090288674A1 (en) * 2003-04-01 2009-11-26 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20090311200A1 (en) * 2008-06-13 2009-12-17 Colgate-Palmolive Oral Compositions and Uses Thereof
US7651533B2 (en) 2005-03-31 2010-01-26 Oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor
EP2198850A1 (en) 2008-12-22 2010-06-23 L'oreal Cosmetic composition containing four types of surfactants and one non-silicone fatty derivative
EP2198837A1 (en) 2008-12-22 2010-06-23 L'oreal Cosmetic composition containing four surfactants, a cationic polymer and a zinc salt
EP2198929A1 (en) 2008-12-19 2010-06-23 L'oreal Hair dye or lightening composition comprising a fatty substance and a cationic polymer, and use thereof
WO2010070140A1 (en) 2008-12-19 2010-06-24 L'oreal Antiperspirant composition containing at least one complex formed by combining at least one anionic species and at least one cationic species, and process for treating human perspiration
US7771492B2 (en) 1999-12-30 2010-08-10 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated fatty alcohols and polyglycerolated fatty alcohols
EP2236053A1 (en) 2009-04-03 2010-10-06 L'Oréal Method for the steam treatment of hair
EP2246039A1 (en) 2009-04-30 2010-11-03 L'Oréal Method for dyeing hair comprising the step of treating the hair with an organic silicon compound
EP2246040A2 (en) 2009-04-15 2010-11-03 L'Oréal Method for the shaping of hair including a step of applying a reducing composition and a heating step
EP2266528A1 (en) 2009-04-30 2010-12-29 L'Oréal Process for colouring and/or bleaching human hair using a composition comprising an amino trialkoxysilane or amino trialcenyloxysilane
EP2275082A1 (en) 2002-12-06 2011-01-19 L'Oréal Composition for oxidation dyeing keratin fibers comprising a nonionic associative polymer, a specific cellulosic compound and a specific cationic polymer.
EP2301630A2 (en) 2008-12-19 2011-03-30 L'Oréal Oxidizing composition for the treatment of keratin fibres comprising a cationic polymer, a fatty amide and an anti-oxygen agent
WO2011074140A1 (en) 2009-12-18 2011-06-23 L'oreal Process for treating keratin fibers
WO2011073564A2 (en) 2009-12-17 2011-06-23 L'oreal Cosmetic composition comprising a surfactant, a liquid fatty alcohol and a non-ionic associative polymer and cosmetic treatment method
WO2011073563A2 (en) 2009-12-17 2011-06-23 L'oreal Cosmetic composition comprising a surfactant, a liquid fatty alcohol and an oxyethylenated fatty alcohol ether and cosmetic treatment method
FR2954139A1 (en) * 2009-12-23 2011-06-24 Oreal cosmetic composition comprising at least one volatile linear alkane and at least one non-protein cationic polymer
EP2338469A1 (en) 2009-12-23 2011-06-29 L'Oréal Use of a cosmetic composition containing a linear volatile alcane and an associative non-ionic polymer for conditioning the hair
US20110155163A1 (en) * 2009-12-23 2011-06-30 Viravau Valerie Cosmetic composition comprising at least one organosilicon compound, at least one anionic surfactant and at least one nonionic thickener, and process using the composition
US20110158927A1 (en) * 2009-12-23 2011-06-30 Viravau Valerie Cosmetic composition comprising at least one organosilicon compound, at least one anionic surfactant and at least one cationic polymer
EP2343040A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least one anionic surface-active agent and at least one amine silicone as well as a method implementing said composition
EP2343039A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least two anionic surface-active agents and at least one amphoteric surface-active agent
EP2363110A1 (en) 2009-09-15 2011-09-07 L'Oréal Use of drying oils for protecting the color of artificially colored keratin fibers against washing; method for coloring hair
WO2011107432A2 (en) 2010-03-01 2011-09-09 L'oreal Composition comprising ellagic acid and a particular cationic surfactant, and cosmetic use thereof
WO2011107469A1 (en) 2010-03-01 2011-09-09 L'oreal Use of ellagic acid as an anti-dandruff agent
WO2011107433A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic composition based on ellagic acid or a derivative thereof and a bacterial extract
WO2011107468A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic antidandruff composition based on ellagic acid or a derivative thereof and a second, different active compound in a specific weight ratio
WO2011107467A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic composition based on ellagic acid or a derivative thereof and on a particular mixture of surfactants
WO2011138450A2 (en) 2010-05-07 2011-11-10 L'oreal Foaming cosmetic composition containing ellagic acid or one of the salts thereof and an essential oil
WO2012032055A1 (en) 2010-09-06 2012-03-15 L'oreal Cosmetic composition comprising at least one cationic polymer and at least two cationic surfactants
WO2012032673A1 (en) 2010-09-08 2012-03-15 L'oreal Cosmetic composition for keratin fibers
WO2012038536A2 (en) 2010-09-24 2012-03-29 L'oreal Cosmetic composition comprising at least one hygroscopic salt, at least one aromatic polyol ether and at least one diol, and cosmetic treatment process
WO2012042019A2 (en) 2010-10-01 2012-04-05 L'oreal Process for treating keratin fibres using at least one sulfureous reducing agent, at least one cationic polymer and at least one mercaptosiloxane.
WO2012049145A1 (en) 2010-10-12 2012-04-19 L'oreal Cosmetic composition comprising a particular silicon derivative and one or more acrylic thickening polymers
WO2012055812A1 (en) 2010-10-26 2012-05-03 L'oreal Cosmetic composition comprising a fatty-chain alkoxysilane and an antidandruff agent.
WO2012055807A1 (en) 2010-10-26 2012-05-03 L'oreal Cosmetic composition comprising a fatty-chain alkoxysilane and a cationic polymer
WO2012059410A1 (en) 2010-11-02 2012-05-10 L'oreal Dye composition having a low content of ammonia
WO2012072765A1 (en) 2010-12-03 2012-06-07 L'oreal Cosmetic composition containing a non-amino silicone, a liquid fatty ester and an amino silicone, process and use
WO2012076559A1 (en) 2010-12-07 2012-06-14 L'oreal COMPOSITION COMPRISING AN OXIDATION DYE PRECURSOR, A POLYCONDENSATE OF ETHYLENE OXIDE AND PROPYLENE OXIDE AND A CATIONIC POLYMER WITH A CHARGE DENSITY OF GREATER THAN OR EQUAL TO 4 meq./g
WO2012084863A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt and 1,2-octanediol
WO2012084901A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt and a solid fatty ester
WO2012084904A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a particular zinc salt and a starch
WO2012084866A1 (en) 2010-12-21 2012-06-28 L'oreal Composition comprising a non-nitrogenous zinc salt and a particular cationic surfactant
WO2012084867A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt, a cationic polymer and a propellant
WO2012084903A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a particular zinc salt and an amino silicone
WO2012110608A2 (en) 2011-02-17 2012-08-23 L'oreal Process for treating keratin fibres using a silicone elastomer in combination with heat
WO2012137165A2 (en) 2011-04-08 2012-10-11 L'oreal A hair treatment method
WO2012149617A1 (en) 2011-05-04 2012-11-08 L'oreal S.A. Detergent cosmetic compositions comprising four surfactants, a cationic polymer and a silicone, and use thereof
WO2012163869A2 (en) 2011-05-27 2012-12-06 L'oreal Composition comprising an alkoxysilane and a modified starch, and cosmetic use thereof
WO2012164065A2 (en) 2011-06-01 2012-12-06 L'oreal Process for treating straightened keratin fibres
WO2012163868A2 (en) 2011-05-27 2012-12-06 L'oreal Composition comprising an alkoxysilane, a fatty ester and a silicone, and cosmetic use thereof
WO2012171850A2 (en) 2011-06-17 2012-12-20 L'oreal Cosmetic composition comprising an anionic surfactant, a nonionic or amphoteric surfactant and a solid fatty alcohol, and cosmetic treatment process
WO2013004784A2 (en) 2011-07-05 2013-01-10 L'oreal Dye composition using a long-chain ether of an alkoxylated fatty alcohol and a cationic polymer, processes and devices using the same
WO2013004773A2 (en) 2011-07-05 2013-01-10 L'oreal Cosmetic composition rich in fatty substances comprising a polyoxyalkylenated fatty alcohol ether and a direct dye and/or an oxidation dye, the dyeing method and the device
WO2013042274A1 (en) 2011-09-22 2013-03-28 L'oreal Cosmetic cleansing composition
WO2013045630A1 (en) 2011-09-30 2013-04-04 L'oreal Foam dye composition comprising at least one liquid fatty alcohol and a particular cationic polymer
WO2013092608A2 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising a hydrophobically modified cellulose, a sulfated or sulfonated anionic surfactant and a branched fatty alcohol
WO2013092722A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising a hydrophobically modified cellulose and an anionic surfactant comprising one or more carboxylate group(s)
WO2013093332A2 (en) 2011-12-20 2013-06-27 L'oreal Cosmetic composition comprising an anionic surfactant, a solid fatty alcohol and a solid fatty ester, and cosmetic treatment process
WO2013110653A1 (en) 2012-01-23 2013-08-01 L'oreal Composition comprising at least one specific alkoxysilane polymer
WO2013183021A1 (en) 2012-06-07 2013-12-12 L'oreal Method of shaping hair using fatty bodies, non-silicone polymers or surfactants
DE102012012263A1 (en) * 2012-06-22 2013-12-24 Alfred E. Tiefenbacher (Gmbh & Co. Kg) A process for the preparation of Polyquaternium-1
WO2014002290A1 (en) 2012-06-29 2014-01-03 L'oreal Cosmetic composition for keratin fibers
WO2014020146A2 (en) 2012-08-02 2014-02-06 L'oreal Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant
WO2014020147A2 (en) 2012-08-02 2014-02-06 L'oreal Dyeing composition comprising a fatty substance, a non-ionic guar gum, an amphoteric surfactant and a non-ionic or anionic surfactant, and an oxidizing agent, dyeing process and suitable device
DE202013011676U1 (en) 2012-11-09 2014-02-14 L'oreal Composition containing a dicarbonyl compound
WO2014056962A2 (en) 2012-10-11 2014-04-17 L'oreal Cosmetic composition comprising a bacterial lysate, a thickener and a particular surfactant system, and cosmetic treatment process
WO2014068795A1 (en) 2012-10-31 2014-05-08 L'oreal Use of triazine derivatives for permanent deformation of keratin fibers
WO2014072645A1 (en) 2012-11-09 2014-05-15 L'oreal Method for straightening the hair using a composition containing glyoxylic acid and/or a derivative thereof
WO2014091125A2 (en) 2012-12-11 2014-06-19 L'oreal Cosmetic composition comprising a nonionic surfactant, a cationic surfactant, a liquid fatty ester and a particular silicone, and cosmetic treatment method
WO2014091111A2 (en) 2012-12-11 2014-06-19 L'oreal Cosmetic composition comprising the association of nonionic and cationic surfactants, and cosmetic treatment method
WO2014111668A2 (en) 2013-01-18 2014-07-24 L'oreal Flexible solid cosmetic composition comprising anionic surfactants and polyols, and cosmetic treatment method
WO2014111579A2 (en) 2013-01-18 2014-07-24 L'oreal Hair shaping process in which is applied a particular styling composition, which is rinsed out
WO2014111669A2 (en) 2013-01-18 2014-07-24 L'oreal Flexible solid cosmetic composition comprising anionic surfactants and solid particles, and cosmetic treatment process
WO2015044057A1 (en) 2013-09-24 2015-04-02 L'oreal Cosmetic composition comprising a combination of surfactants of carboxylate, acylisethionate and alkyl(poly)glycoside type
WO2015063122A1 (en) 2013-10-30 2015-05-07 L'oreal Expanded dyeing composition comprising an inert gas, an oxidation dye and an oxyalkylenated nonionic surfactant
WO2015091334A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing composition comprising at least 75% of fatty substances and a mixture of oxyethylenated surfactants
WO2015091336A1 (en) 2013-12-19 2015-06-25 L'oreal Composition rich in fatty substances comprising hydrogen peroxide, a persalt and oxyethylenated surfactants
WO2015091338A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing process using compositions rich in fatty substances
WO2015091337A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing composition rich in fatty substances comprising a mixture of oxyethylenated surfactants
US9066890B2 (en) 2011-07-05 2015-06-30 L'oreal Dye composition comprising an alkoxylated fatty alcohol ether and a fatty alcohol
US9226879B2 (en) 2011-09-30 2016-01-05 L'oreal Foam dye composition comprising at least one particular oxyethylenated nonionic surfactant
WO2016096654A1 (en) 2014-12-17 2016-06-23 L'oreal Dye composition comprising a para-phenylenediamine oxidation base and an amphoteric or cationic polymer in a medium rich in fatty substances
WO2016156486A1 (en) 2015-04-02 2016-10-06 L'oreal Cosmetic composition comprising non-amino polyalkylsiloxanes, oxyethylenated polymers and fatty alcohols
US9463148B2 (en) 2011-09-30 2016-10-11 L'oreal Foam dye composition comprising a polycondensate of ethylene oxide and propylene oxide
WO2017018498A1 (en) 2015-07-28 2017-02-02 L'oreal Composition, process, method and use for keratin fibers
WO2017104221A1 (en) 2015-12-15 2017-06-22 L'oreal Combination of polyion complex particle and non-polymeric acid having two or more acid dissociation constants
WO2017102650A1 (en) 2015-12-14 2017-06-22 L'oreal Device for dispensing a product for dyeing and/or lightening keratin fibres comprising an associative polymer
WO2017104585A1 (en) 2015-12-15 2017-06-22 L'oreal Combination of polyion complex particle and hydrophilic or water-soluble uv filter
WO2018007352A1 (en) 2016-07-07 2018-01-11 L'oreal Cosmetic composition comprising a particular combination of surfactants, a silicone, a cationic polymer, a fatty alcohol and a clay
WO2018056235A1 (en) 2016-09-20 2018-03-29 L'oreal Composition for keratin fibers
WO2018081399A1 (en) 2016-10-31 2018-05-03 L'oreal Compositions for chemically treated hair
US9974725B1 (en) 2017-05-24 2018-05-22 L'oreal Methods for treating chemically relaxed hair

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140976A (en) * 1960-12-16 1964-07-14 Armour Pharma Quaternary ammonium germicide
US3539684A (en) * 1968-11-21 1970-11-10 Calgon C0Rp Bactericidal polymers
US3771989A (en) * 1971-11-26 1973-11-13 Buckman Labor Inc Method of controlling the growth of algae
US3778283A (en) * 1971-03-03 1973-12-11 Henkel & Cie Gmbh Binders based on alkali metal silicates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140976A (en) * 1960-12-16 1964-07-14 Armour Pharma Quaternary ammonium germicide
US3539684A (en) * 1968-11-21 1970-11-10 Calgon C0Rp Bactericidal polymers
US3778283A (en) * 1971-03-03 1973-12-11 Henkel & Cie Gmbh Binders based on alkali metal silicates
US3771989A (en) * 1971-11-26 1973-11-13 Buckman Labor Inc Method of controlling the growth of algae

Cited By (430)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4025617A (en) * 1974-10-03 1977-05-24 Millmaster Onyx Corporation Anti-microbial quaternary ammonium co-polymers
FR2307856A1 (en) * 1975-04-14 1976-11-12 British Petroleum Co polymer composition forming a film and used as a paint preventing fouling by marine organisms
US4197865A (en) * 1975-07-04 1980-04-15 L'oreal Treating hair with quaternized polymers
US4381919A (en) * 1975-07-04 1983-05-03 Societe Anonyme Dite: L'oreal Hair dye composition containing quaternized polymers
US4418054A (en) * 1976-11-24 1983-11-29 Millmaster Onyx Group, Inc. Polymeric quaternary ammonium compounds for skin care
US4155994A (en) * 1977-01-21 1979-05-22 Kewanee Industries, Inc. Hair conditioning agents
US4719099A (en) * 1977-03-15 1988-01-12 L'oreal Composition and process for the treatment of keratin materials with polymers
US4240450A (en) * 1977-03-15 1980-12-23 L'oreal Composition and process for the treatment of keratin materials with polymers
US4157388A (en) * 1977-06-23 1979-06-05 The Miranol Chemical Company, Inc. Hair and fabric conditioning compositions containing polymeric ionenes
US4209397A (en) * 1979-01-31 1980-06-24 Kewanee Industries Flocculants for aqueous systems
US4379137A (en) * 1979-06-30 1983-04-05 Sterling Drug Inc. Disinfecting and preserving composition comprising a synergistic combination of a polymeric quaternary ammonium compound and a 3-isothiazolone compound
US4488564A (en) * 1980-12-19 1984-12-18 L'oreal Oily composition intended for the treatment of keratin substances and the skin
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
US5326841A (en) * 1989-01-25 1994-07-05 Epitope, Inc. Germicidal barriers
EP0382562A1 (en) * 1989-02-10 1990-08-16 Buckman Laboratories International, Inc. Polymeric quaternary ammonium trihalides useful as microbicides, sanitizers and disinfectants
US4960590A (en) * 1989-02-10 1990-10-02 Buckman Laboratories International, Inc. Novel polymeric quaternary ammonium trihalides
US5371083A (en) * 1989-09-27 1994-12-06 Buckman Laboratories International, Inc. Synergistic combinations of ionenes with hexahydro-1,3,5-tris-(2-hydroxyethyl)-s-triazine in controlling fungal and bacterial growth in synthetic metalworking fluids
US5451398A (en) * 1990-01-05 1995-09-19 Allergan, Inc. Ophthalmic and disinfecting compositions and methods for preserving and using same
US5277901A (en) * 1990-01-05 1994-01-11 Allergan, Inc. Ophthalmic compositions and methods for preserving and using same
WO1991009522A1 (en) * 1990-01-05 1991-07-11 Allergan, Inc. Ophthalmic compositions and methods for preserving and using same
US5171526A (en) * 1990-01-05 1992-12-15 Allergan, Inc. Ophthalmic compositions and methods for preserving and using same
US6051611A (en) * 1991-11-08 2000-04-18 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobias
US5512597A (en) * 1991-11-08 1996-04-30 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobials
WO1997045473A1 (en) * 1991-11-08 1997-12-04 Alcon Laboratories, Inc. Absolute molecular weight polymers and methods for their use
US5387717A (en) * 1992-08-12 1995-02-07 Buckman Laboratories International, Inc. Method for the detoxification of mustard gas, sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US5401881A (en) * 1992-08-12 1995-03-28 Buckman Laboratories International, Inc. Sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US5489569A (en) * 1992-12-14 1996-02-06 Buckman Laboratories International, Inc. Composition and method for increasing the effectiveness of pesticides
US5681862A (en) * 1993-03-05 1997-10-28 Buckman Laboratories International, Inc. Ionene polymers as microbicides
US5419897A (en) * 1993-04-09 1995-05-30 Buckman Laboratories International, Inc. Ionene polymers as anthelmintics in animals
US5700456A (en) * 1994-04-21 1997-12-23 L'oreal Compositions for the treatment and protection of hair, based on ceramide and/or glycoceramide and on polymers containing cationic groups
US5661118A (en) * 1994-04-22 1997-08-26 L'oreal Hair and skin washing and treatment compositions based on ceramide and/or glycoceramide and on polymers containing cationic groups
US5575993A (en) * 1994-08-31 1996-11-19 Buckman Laboratories International, Inc. Ionene polymers containing biologically-active anions
US5536494A (en) * 1994-10-04 1996-07-16 Alcon Laboratories, Inc. Polyethylene oxide-containing quaternary ammunium polymers and pharmaceutical compositions containing an antimicrobial amount of same
EP0723772A1 (en) 1995-01-30 1996-07-31 L'oreal Reducing composition bared on a basic amino acid and a cationic polymer
US5707534A (en) * 1995-07-10 1998-01-13 Buckman Laboratories International, Inc. Use of tabletized ionene polymers in water treatment
US5709880A (en) * 1995-07-10 1998-01-20 Buckman Laboratories International, Inc. Method of making tabletized ionene polymers
US5637308A (en) * 1995-07-10 1997-06-10 Buckman Laboratories International, Inc. Tabletized ionene polymers
US5843865A (en) * 1996-02-07 1998-12-01 Buckman Laboratories International, Inc. Synergistic antimicrobial compositions containing an ionene polymer and a salt of dodecylamine and methods of using the same
WO1997029741A1 (en) * 1996-02-14 1997-08-21 Alcon Laboratories, Inc. Polymeric quaternary ammonium compounds and their use as ophthalmic antimicrobials
WO1997046210A1 (en) 1996-06-07 1997-12-11 L'oreal Detergent cosmetic compositions for hair care and utilisation thereof
US6451747B1 (en) 1996-06-07 2002-09-17 L'oreal S.A. Detergent cosmetic compositions for hair care and utilisation thereof
US6153570A (en) * 1996-06-07 2000-11-28 L'oreal S.A. Detergent cosmetic compositions and use
US5962555A (en) * 1996-06-25 1999-10-05 Buckman Laboratories International, Inc. ASA sizing emulsions containing low and high molecular weight cationic polymers
US6162423A (en) * 1996-07-23 2000-12-19 L'oreal S.A. Washing and conditioning compositions containing silicone and dialkyl ether
WO1998013444A1 (en) * 1996-09-24 1998-04-02 Cincinnati Milacron Inc. Machining fluid composition and method of machining
US6008236A (en) * 1996-10-16 1999-12-28 Buckman Laboratories International, Inc. Synergistic antimicrobial compositions containing an ionene polymer and a pyrithione salt and methods of using the same
US5776960A (en) * 1996-10-16 1998-07-07 Buckman Laboratories International, Inc. Synergistic antimicrobial compositions containing an ionene polymer and a pyrithione salt and methods of using the same
DE19646726A1 (en) * 1996-11-13 1998-05-14 Widulle Herbert Dipl Chem Dr Topical composition containing polymeric quaternary ammonium salt
US5866016A (en) * 1997-07-01 1999-02-02 Buckman Laboratories International, Inc. Methods and compositions for controlling biofouling using combinations of an ionene polymer and a salt of dodecylamine
US6589519B1 (en) 1997-08-25 2003-07-08 L'oreal S.A. Cosmetic compositions containing a polyoxyalkylenated aminosilicone block copolymer and a conditioner, and uses thereof
US6423305B1 (en) 1997-12-29 2002-07-23 L'oreal S.A. Cosmetic composition comprising at least an amidoethercarboxylic acid surfactant and at least a cationic polymer/anionic polymer combination
US6410493B1 (en) 1998-11-12 2002-06-25 L'oreal S.A. Conditioning and detergent composition comprising an anionic surfactant, a silicone, and a cationic polymer
US6114484A (en) * 1998-11-16 2000-09-05 Nalco Chemical Company Polymers for chemical treatment and precipitation of soluble metal cyanide and oxoanion compounds from waste water
US6177017B1 (en) * 1998-11-16 2001-01-23 Nalco Chemical Company Polymers for chemical treatment and precipitation of soluble metal cyanide and oxoanion compounds from waste water
US20050033251A1 (en) * 1998-12-08 2005-02-10 Quick-Med Technologies, Inc. Controlled release of biologically active substances from select substrates
US7709694B2 (en) 1998-12-08 2010-05-04 Quick-Med Technologies, Inc. Materials with covalently-bonded, nonleachable, polymeric antimicrobial surfaces
US20020177828A1 (en) * 1998-12-08 2002-11-28 Batich Christopher D. Absorbent materials with covalently-bonded, nonleachable, polymeric antimicrobial surfaces, and methods for preparation
US7045673B1 (en) 1998-12-08 2006-05-16 Quick-Med Technologies, Inc. Intrinsically bactericidal absorbent dressing and method of fabrication
US6203451B1 (en) 1999-01-13 2001-03-20 Acushnet Company Zwitter-ion and ionene golf ball forming compositions and methods
US6379401B1 (en) 1999-01-29 2002-04-30 L'oreal, S.A. Anhydrous composition for bleaching keratin fibers comprising a combination of a water-soluble thickening polymer and a nonionic amphiphilic polymer comprising at least one fatty chain
US6260556B1 (en) 1999-01-29 2001-07-17 L'oreal Anhydrous composition for bleaching keratin fibers
US6514488B1 (en) 1999-02-03 2003-02-04 L'oreal S.A. Detergent cosmetic compositions and uses thereof
US6338842B1 (en) 1999-02-03 2002-01-15 L'oreal S.A. Cosmetic composition comprising an anionic surfactant, an amphoteric surfactant, a polyolefin, a cationic polymer and a salt or an alcohol which is water-soluble, use and process
US6506372B1 (en) 1999-06-25 2003-01-14 L'oreal S.A. Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses
US6471953B1 (en) 1999-06-28 2002-10-29 L'oreal S.A. Permanent-waving process comprising the preliminary application of a composition comprising at least one anionic polymer
US6482400B1 (en) 1999-06-30 2002-11-19 L'Oréal S.R. Mascara containing film-forming polymers
US6534047B1 (en) 1999-06-30 2003-03-18 L'oreal S.A. Mascara containing film-forming polymers
US6451298B1 (en) 1999-10-20 2002-09-17 L'oreal, S.A. Cosmetic compositions comprising at least one silicone copolymer and at least one cationic polymer, and uses thereof
US6916344B1 (en) 1999-12-08 2005-07-12 L'oreal S.A. Direct dyeing composition for keratinic fibers containing a thickening polymer with an ether plastic skeleton
US6984250B1 (en) 1999-12-08 2006-01-10 L'oreal Composition, method, and kit for the bleaching or permanent reshaping of keratin fibers, comprising at least one thickening polymer with an aminoplast-ether skeleton
US6800096B1 (en) 1999-12-08 2004-10-05 L'oreal S.A. Composition, process and kit for bleaching keratin fibers comprising at least one thickening polymer with an aminoplast-ether skeleton
US6800098B1 (en) 1999-12-08 2004-10-05 L'oreal, S.A. Oxidation dye composition for keratinic fibres containing a thickening polymer with an ether plastic skeleton
US6444197B2 (en) 1999-12-13 2002-09-03 L'oreal S.A. Bleaching composition for keratin fibers, comprising a combination of two polyurethane polyethers
US7771492B2 (en) 1999-12-30 2010-08-10 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated fatty alcohols and polyglycerolated fatty alcohols
US6695887B2 (en) 1999-12-30 2004-02-24 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one fatty alcohol having more than twenty carbon atoms and at least one oxyalkylenated nonionic surfactant with an hlb greater than 5
US6436151B2 (en) 1999-12-30 2002-08-20 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain, and at least one fatty alcohol comprising more than twenty carbon atoms and uses thereof
WO2001068043A2 (en) 2000-03-14 2001-09-20 L'oreal Dyeing compositions for keratinous fibres containing paraphenylenediamine derivatives with pyrrolidinyl group
US7179301B2 (en) 2000-03-14 2007-02-20 L'oreal S.A. Dyeing compositions for keratinous fibers containing paraphenylenediamine derivatives with pyrrolidinyl group
US20030093866A1 (en) * 2000-03-14 2003-05-22 Laurent Vidal Dyeing compositions for keratinous fibres containing paraphenylenediamine derivatives with pyrrolidinyl group
US6635262B2 (en) 2000-03-14 2003-10-21 L'oreal S.A. Roll-on applicator comprising a hair composition
US20050132505A9 (en) * 2000-08-21 2005-06-23 Frederic Legrand Bleaching composition for dyed keratinous fibers
US20040034944A1 (en) * 2000-08-21 2004-02-26 Frederic Legrand Bleaching composition for dyed keratinous fibers
US20090081148A1 (en) * 2000-08-25 2009-03-26 L'oreal S.A. Protection of keratinous fibers using ceramides and/or glycoceramides
US8703109B2 (en) 2000-08-25 2014-04-22 L'oreal Protection of keratinous fibers using ceramides and/or glycoceramides
US6663902B1 (en) 2000-09-19 2003-12-16 Ecolab Inc. Method and composition for the generation of chlorine dioxide using Iodo-Compounds, and methods of use
US7108726B2 (en) 2000-11-08 2006-09-19 L'oreal S.A. Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US20040019981A1 (en) * 2000-11-08 2004-02-05 Francois Cottard Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US7077869B2 (en) 2000-11-08 2006-07-18 L'oreal S.A. Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US20040025266A1 (en) * 2000-11-08 2004-02-12 Francois Cottard Oxidation dyeing composition for karatinous fibres comprising a cationic associative polyurethane
US7066965B2 (en) 2000-11-08 2006-06-27 L'oreal S.A. Bleaching composition for keratinous fibers comprising an associate polyurethane
US20040034947A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Bleachng composition for keratinous fibres comprising an associate polyurethane
US20040034946A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US7101405B2 (en) 2000-11-08 2006-09-05 L'oreal S.A. Oxidation dyeing composition for karatinous fibers comprising a cationic associative polyurethane
US7914775B2 (en) 2000-11-20 2011-03-29 L'oreal S.A. Composition for treating keratinous materials comprising a cationic associative polyurethane polymer and a protecting or conditioning agent
US20040037796A1 (en) * 2000-11-20 2004-02-26 Francois Cottard Composition for treating keratinous materials comprising a cationic associative polyurethane polymer and a protecting or conditioning agent
US20040049861A1 (en) * 2000-12-04 2004-03-18 Francois Cottard Oxidation dyeing composition for keratinous fibres comprising an associative polymer and a pearling agent
US20040060126A1 (en) * 2000-12-04 2004-04-01 Francois Cottard Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US7364594B2 (en) 2000-12-04 2008-04-29 L'oreal S.A. Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US7431740B2 (en) 2000-12-04 2008-10-07 L'oreal, S.A. Oxidation dyeing composition for keratinous fibers comprising an associative polymer and a pearling agent
US20040074013A1 (en) * 2000-12-06 2004-04-22 Eric Terranova Oxidation dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in positions 3 and 4, and dyeing method using same
US20040088799A1 (en) * 2000-12-06 2004-05-13 Stephane Sabelle Oxidation dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in position 2
US20040083559A1 (en) * 2000-12-06 2004-05-06 Stephane Sabelle Dyeing composition based on 1-(4-aminophenyl)pyrrolidines substituted at least in positions 2 and 3
US20040064902A1 (en) * 2000-12-06 2004-04-08 Stephane Sabelle Oxidatiton dyeing composition based on 1-(4-aminophenyl) pyrrolidines substituted in position 2 and 5
US7928087B2 (en) 2001-01-12 2011-04-19 L'oreal Cosmetic compositions containing fructan and a cationic polymer and their uses
US20040105832A1 (en) * 2001-01-12 2004-06-03 Geraldine Fack Cosmetic compositions containing fructan and a cationic polymer and their uses
US20030031644A1 (en) * 2001-01-18 2003-02-13 Geltex Pharmaceuticals, Inc. Ionene polymers and their use as antimicrobial agents
US6955806B2 (en) 2001-01-18 2005-10-18 Genzyme Corporation Ionene polymers and their use as antimicrobial agents
US20070025954A1 (en) * 2001-01-18 2007-02-01 Fitzpatrick Richard J Ionene polymers and their use as antimicrobial agents
US20020157193A1 (en) * 2001-02-02 2002-10-31 Frederic Legrand Pulverulent composition for bleaching human keratin fibers
US7220285B2 (en) 2001-02-02 2007-05-22 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US20060191081A1 (en) * 2001-02-02 2006-08-31 L'oreal, S.A. Pulverulent composition for bleaching human keratin fibers
US20040105833A1 (en) * 2001-03-30 2004-06-03 Geraldine Fack Cosmetic compositions containing a starch phosphate and a cationic polymer and uses thereof
US20020193265A1 (en) * 2001-03-30 2002-12-19 Beatrice Perron Detergent cosmetic compositions containing an anionic surfactant derived from amino acids and salts thereof and a soluble conditioning agent and uses thereof
US20040093675A1 (en) * 2001-04-02 2004-05-20 Laurent Vidal Dyeing composition for dyeing kerationou fibres comprising a cationic azo-dye
US20050201960A1 (en) * 2001-05-16 2005-09-15 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US6919073B2 (en) 2001-05-16 2005-07-19 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US6991707B2 (en) 2001-06-05 2006-01-31 Buckman Laboratories International, Inc. Polymeric creping adhesives and creping methods using same
US20030019597A1 (en) * 2001-06-05 2003-01-30 Hill Walter B. Polymeric creping adhesives and creping methods using same
US20040237213A1 (en) * 2001-06-12 2004-12-02 Gregory Plos Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US7189266B2 (en) 2001-06-12 2007-03-13 L'oreal, S.A. Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US20030023782A1 (en) * 2001-07-26 2003-01-30 International Business Machines Corp. Microprocessor system bus protocol providing a fully pipelined input/output DMA write mechanism
US20030074747A1 (en) * 2001-07-27 2003-04-24 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US20060248664A1 (en) * 2001-07-27 2006-11-09 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US20030103926A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20040001796A9 (en) * 2001-09-11 2004-01-01 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20030108503A1 (en) * 2001-09-11 2003-06-12 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20030103929A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US7258852B2 (en) 2001-09-11 2007-08-21 L'oreal S.A. Cosmetic compositions containing a methacrylic acid copolymer and an oil, and uses thereof
US7217296B2 (en) 2001-09-28 2007-05-15 L'oreal S.A. Dyeing composition with a lightening effect for human keratin materials comprising at least one fluorescent dye
US20050028301A1 (en) * 2001-09-28 2005-02-10 Florent Pastore Dyeing composition with a brightening effect for human kerationous fibres
US6846333B2 (en) 2001-11-08 2005-01-25 L'oreal, S.A. Keratin fiber dyeing composition comprising a particular aminosilicone
US7220408B2 (en) 2001-11-08 2007-05-22 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030157049A1 (en) * 2001-11-08 2003-08-21 Jonathan Gawtrey Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7138109B2 (en) 2001-11-08 2006-11-21 L'oreal, Sa Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US20030152543A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030152542A1 (en) * 2001-11-08 2003-08-14 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030152541A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030126692A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-treatment of processes for coloring keratin fibers with direct dyes or with oxidation dyes
US20030147842A1 (en) * 2001-11-08 2003-08-07 Serge Restle Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7223385B2 (en) 2001-11-08 2007-05-29 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7135167B2 (en) 2001-11-08 2006-11-14 L'oreal, Sa Oxidizing composition for treating keratin fibers, comprising a particular aminosilicone
US20070154441A1 (en) * 2001-11-08 2007-07-05 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7128902B2 (en) 2001-11-08 2006-10-31 L'oreal, Sa Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147840A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147841A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147827A1 (en) * 2001-11-08 2003-08-07 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030140429A1 (en) * 2001-11-08 2003-07-31 Frederic Legrand Keratin fibre dyeing composition comprising a particular aminosilicone
US20030129155A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US20030118537A1 (en) * 2001-11-08 2003-06-26 Priscille Devin-Baudoin Process for permanently reshaping the hair using particular aminosilicones
US20070154434A1 (en) * 2001-11-08 2007-07-05 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20050238599A1 (en) * 2001-11-08 2005-10-27 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US20070202065A1 (en) * 2001-11-08 2007-08-30 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US7510705B2 (en) 2001-11-08 2009-03-31 L'oreal, S.A. Process for permanently reshaping the hair using particular aminosilicones
US7504094B2 (en) 2001-11-08 2009-03-17 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US7485289B2 (en) 2001-11-08 2009-02-03 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20070160557A1 (en) * 2001-11-15 2007-07-12 L'oreal S.A. Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US7211268B2 (en) 2001-11-15 2007-05-01 L'oreal S.A. Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US20050125912A1 (en) * 2001-12-21 2005-06-16 Patricia Desenne Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US7153331B2 (en) 2001-12-21 2006-12-26 L'oreal S.A. Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US6946005B2 (en) 2002-03-27 2005-09-20 L'oreal S.A. Pyrrolidinyl-substituted para-phenylenediamine derivatives substituted with a cationic radical, and use of these derivatives for dyeing keratin fibers
US20030223948A1 (en) * 2002-03-28 2003-12-04 Mireille Maubru Cosmetic composition comprising at least one anionic surfactant, at least one cationic polymer and at least one amphiphilic, branched block acrylic copolymer and method for treating hair using such a composition
US7498022B2 (en) 2002-03-28 2009-03-03 L'oreal S.A. Cosmetic composition comprising at least one anionic surfactant, at least one cationic polymer and at least one amphiphilic, branched block acrylic copolymer and method for treating hair using such a composition
US20040039101A1 (en) * 2002-05-31 2004-02-26 Claude Dubief Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer
US7232561B2 (en) 2002-05-31 2007-06-19 L'oreal S.A. Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer
US7132534B2 (en) 2002-07-05 2006-11-07 L'oreal Para-phenylenediamine derivatives containing a pyrrolidyl group, and use of these derivatives for coloring keratin fibers
US20040077852A1 (en) * 2002-07-05 2004-04-22 Stephane Sabelle Para-phenylenediamine derivatives containing a pyrrolidyl group, and use of these derivatives for coloring keratin fibers
US20040077510A1 (en) * 2002-07-08 2004-04-22 Pascale Lazzeri Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US7157413B2 (en) 2002-07-08 2007-01-02 L'oreal Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US20050101499A9 (en) * 2002-07-08 2005-05-12 Pascale Lazzeri Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US20040123401A1 (en) * 2002-09-09 2004-07-01 Stephane Sabelle Bis-para-phenylenediamine derivatives comprising a pyrrolidyl group and use of these derivatives for dyeing keratin fibres
US6923835B2 (en) 2002-09-09 2005-08-02 L'oreal S.A. Bis-para-phenylenediamine derivatives comprising a pyrrolidyl group and use of these derivatives for dyeing keratin fibres
US20040208843A1 (en) * 2002-09-24 2004-10-21 Gabin Vic Cosmetic composition comprising an exogenous ligand-receptor system adsorbed or covalently attached to keratin materials, and hair treatment using this composition or constituent elements thereof
US20040133994A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
US20040133995A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US7147672B2 (en) 2002-10-21 2006-12-12 L'oreal S.A. Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US7323015B2 (en) 2002-10-21 2008-01-29 L'oreal S.A. Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
US20060002887A1 (en) * 2002-11-19 2006-01-05 Genzyme Corporation Ionene oligomers and polymers
US20080104775A1 (en) * 2002-12-06 2008-05-08 L,Oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 MEQ/G and not comprising a C8-C30 fatty chain
US7771491B2 (en) 2002-12-06 2010-08-10 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US20040163186A1 (en) * 2002-12-06 2004-08-26 Frederic Simonet Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US20040205902A1 (en) * 2002-12-06 2004-10-21 Francois Cottard Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
US7329287B2 (en) 2002-12-06 2008-02-12 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US7326256B2 (en) 2002-12-06 2008-02-05 L'ORéAL S.A. Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
EP1716841A1 (en) 2002-12-06 2006-11-02 L'Oréal Composition for the oxidative dyeing of keratinic fibers
EP2275082A1 (en) 2002-12-06 2011-01-19 L'Oréal Composition for oxidation dyeing keratin fibers comprising a nonionic associative polymer, a specific cellulosic compound and a specific cationic polymer.
US20040180030A1 (en) * 2002-12-19 2004-09-16 Mireille Maubru Cosmetic compositions comprising at least one alkylamphohydroxyalkylsulphonate amphoteric surfactant and at least one nacreous agent and/or opacifier, and uses thereof
US7261744B2 (en) 2002-12-24 2007-08-28 L'oreal S.A. Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20060010617A1 (en) * 2002-12-24 2006-01-19 Luc Gourlaouen Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20040122807A1 (en) * 2002-12-24 2004-06-24 Hamilton Darin E. Methods and systems for performing search interpretation
US7217298B2 (en) 2003-01-16 2007-05-15 L'oreal S.A. Ready-to-use bleaching compositions, preparation process and bleaching process
US20040235700A1 (en) * 2003-01-16 2004-11-25 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20040226110A1 (en) * 2003-01-16 2004-11-18 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US7226486B2 (en) 2003-01-16 2007-06-05 L'oreal S.A Ready-to-use bleaching compositions, preparation process and bleaching process
US20040175352A1 (en) * 2003-03-06 2004-09-09 David Oppong Microbicidal compositions including an ionene polymer and 2,4,4-trichloro-2-hydroxydiphenyl ether, and methods of using the same
US7708981B2 (en) 2003-03-11 2010-05-04 L'oreal S.A. Cosmetic compositions comprising at least one crosslinked copolymer, at least one insoluble mineral particle and at least one polymer, and uses thereof
US20040234485A1 (en) * 2003-03-11 2004-11-25 Mireille Maubru Cosmetic compositions comprising at least one crosslinked copolymer, at least one insoluble mineral particle and at least one polymer, and uses thereof
US20050011017A1 (en) * 2003-03-25 2005-01-20 L'oreal S.A. Oxidizing composition comprising hydroxycarboxylic acids and salts thereof as complexing agents for dyeing, bleaching or permanently reshaping keratin fibres
US20050039270A1 (en) * 2003-03-25 2005-02-24 L'oreal S.A. Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres
US20040221401A1 (en) * 2003-03-25 2004-11-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US7267696B2 (en) 2003-03-25 2007-09-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US7303588B2 (en) 2003-03-25 2007-12-04 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20040237217A1 (en) * 2003-03-25 2004-12-02 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20050036970A1 (en) * 2003-03-25 2005-02-17 L'oreal S.A. Reducing compositions for bleaching or permanently reshaping keratin fibres comprising polycarboxylic acids and salts thereof as complexing agents
US7150764B2 (en) 2003-04-01 2006-12-19 L'oreal S.A. Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof
US20050008594A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Composiiton for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US20050008593A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US7186278B2 (en) 2003-04-01 2007-03-06 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US20050005368A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US7192454B2 (en) 2003-04-01 2007-03-20 L'oreal S.A. Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
US7195651B2 (en) 2003-04-01 2007-03-27 L'oreal S.A. Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US7195650B2 (en) 2003-04-01 2007-03-27 L'oreal S.A. Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US7198650B2 (en) 2003-04-01 2007-04-03 L'oreal S.A. Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US7208018B2 (en) 2003-04-01 2007-04-24 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US7204860B2 (en) 2003-04-01 2007-04-17 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US7250064B2 (en) 2003-04-01 2007-07-31 L'oreal S.A. Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US7303589B2 (en) 2003-04-01 2007-12-04 L'oreal S.A. Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same
US20050076457A1 (en) * 2003-04-01 2005-04-14 Gregory Plos Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof
US7736631B2 (en) 2003-04-01 2010-06-15 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20050098763A1 (en) * 2003-04-01 2005-05-12 Gregory Plos Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
US20050031562A1 (en) * 2003-04-01 2005-02-10 Luc Gourlaouen Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US20090288674A1 (en) * 2003-04-01 2009-11-26 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20040258641A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US20040256598A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US20050005371A1 (en) * 2003-04-01 2005-01-13 Chrystel Pourille-Grethen Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US7147673B2 (en) 2003-04-01 2006-12-12 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof
US20070174974A1 (en) * 2003-05-09 2007-08-02 De La Mettrie Roland Process for treating keratin fibres by applying heat
US7608115B2 (en) 2003-05-09 2009-10-27 L'oreal S.A. Process for treating keratin fibres by applying heat
US20100005600A1 (en) * 2003-05-09 2010-01-14 L'oreal S.A. Process for treating keratin fibres by applying heat
US20050186151A1 (en) * 2003-08-11 2005-08-25 Franck Giroud Cosmetic composition comprising stabilized and optionally coated metal particles
US20050208005A1 (en) * 2003-08-11 2005-09-22 Franck Giroud Cosmetic composition comprising particles having a core-shell structure
US20050158262A1 (en) * 2003-12-19 2005-07-21 Eric Parris Cosmetic composition comprising a cationic agent, a polymer comprising a hetero atom and an oil, and cosmetic treatment process
US20070237733A1 (en) * 2004-01-05 2007-10-11 Frederic Simonet Cosmetic Composition of Water-in-Water Emulsion type Based on Surfactants and Cationic Polymers
US20050232885A1 (en) * 2004-01-07 2005-10-20 L'oreal Detergent cosmetic compositions comprising at least one surfactant, at least one drawing polymer and at least one nonsilicone conditioner, and use thereof
US20050188475A1 (en) * 2004-01-07 2005-09-01 Alain Lagrange Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US7294152B2 (en) 2004-01-07 2007-11-13 L'oreal S.A. Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US20050175569A1 (en) * 2004-01-07 2005-08-11 Geraldine Fack Cosmetic compositions comprising a cation, a drawing polymer and a thickener, and cosmetic treatment processes
US20060269493A1 (en) * 2004-02-05 2006-11-30 Quick-Med Technologies, Inc. Silicate and other oxide powders with bonded anitmicrobial polymers
US20070141006A1 (en) * 2004-03-17 2007-06-21 Aude Livoreil Cosmetic compositions containing modified polyamines and the uses thereof
US20050232884A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US20050232883A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US7976831B2 (en) 2004-04-02 2011-07-12 L'oreal S.A. Method for treating hair fibers
US9675822B2 (en) 2004-04-02 2017-06-13 L'oreal Method for treating hair fibers
US20060025318A1 (en) * 2004-04-22 2006-02-02 Mireille Maubru Composition for washing and conditioning keratin materials, comprising a carboxyalkyl starch, and process for the use thereof
US20060057096A1 (en) * 2004-09-08 2006-03-16 Pascale Lazzeri Cosmetic composition comprising at least one cationic surfactant, at least one aminated silicone, at least one fatty alcohol, and at least one diol
EP1634569A1 (en) 2004-09-08 2006-03-15 L'oreal Cosmetic composition based on a cationic surfactant, a fatty alcohol, a cationic non-silicone polymer and a diol
US20080119554A1 (en) * 2004-11-26 2008-05-22 Rajiv Jalan Compositions Comprising Ornithine And Phenylacetate Or Phenylbutyrate For Treating Hepatic Encephalopathy
US20060156479A1 (en) * 2004-12-23 2006-07-20 Leila Hercouet Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
US7429275B2 (en) 2004-12-23 2008-09-30 L'oreal S.A. Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
US8790623B2 (en) 2005-01-18 2014-07-29 Il'Oreal Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
US20060182697A1 (en) * 2005-01-18 2006-08-17 Boris Lalleman Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
EP1688127A1 (en) 2005-01-18 2006-08-09 L'oreal Hair treatment composition containing an aromatic alcohol, an aromatic carboxylic acid a protecting agent
EP1698326A2 (en) 2005-02-11 2006-09-06 L'oreal Cosmetic composition comprising a cationic surfactant, a cationic polymer, a solid compound and a starch, and cosmetic treatment process
US20060260069A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
EP1707184A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibres using the same and device therefor
EP1707182A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a fatty acid ester and process for dyeing keratin fibres using the same
US7651533B2 (en) 2005-03-31 2010-01-26 Oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor
EP1707183A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a non-ionic associative polymer, process for dyeing keratin fibres using same
EP1707181A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition with a reduced content of starting materials, and process for dyeing keratin fibres using the same
EP1716840A1 (en) 2005-03-31 2006-11-02 L'oreal Hair-dye composition containing a glycerol ester and the corresponding hair-dyeing process
US20060248662A1 (en) * 2005-03-31 2006-11-09 Frederic Legrand Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US7442214B2 (en) 2005-03-31 2008-10-28 L'oreal S.A. Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
EP1707190A1 (en) 2005-03-31 2006-10-04 L'oreal Dye composition comprising a hydrophobically modified nonionic cellulose and method for dyeing keratin fibres using it
US20060260071A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US7578854B2 (en) 2005-03-31 2009-08-25 L'oreal S.A. Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
US7575605B2 (en) 2005-03-31 2009-08-18 L'oreal S.A. Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US20060260070A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US20060265817A1 (en) * 2005-03-31 2006-11-30 Frederic Legrand Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
US7550015B2 (en) 2005-03-31 2009-06-23 L'oreal S.A. Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US7569078B2 (en) 2005-03-31 2009-08-04 L'oreal S.A. Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US20060257339A1 (en) * 2005-05-13 2006-11-16 L'oreal Use of conductive polymer nanofibers for treating keratinous surfaces
US7803899B2 (en) 2005-09-27 2010-09-28 Buckman Laboratories International, Inc. Methods to reduce organic impurity levels in polymers and products made therefrom
US20070106061A1 (en) * 2005-09-27 2007-05-10 Zollinger Mark L Methods to reduce organic impurity levels in polymers and products made therefrom
US7998464B2 (en) 2005-09-29 2011-08-16 L'oreal S.A. Process for the photoprotective treatment of artificially dyed keratin fibers by application of a liquid water/steam mixture
US20070074356A1 (en) * 2005-09-29 2007-04-05 Boris Lalleman Process for the photoprotective treatment of artificially dyed keratin fibers by application of a liquid water/steam mixture
US20070104747A1 (en) * 2005-10-28 2007-05-10 Virginie Masse Cosmetic composition comprising at least one anti-dandruff agent and also oxyethylenated sorbitan monolaurate, and cosmetic treatment process using said composition
US20070105734A1 (en) * 2005-10-28 2007-05-10 Sandrine Decoster Composition for washing keratin materials and cosmetic treatment process using said composition
US20070104668A1 (en) * 2005-10-28 2007-05-10 Virginie Masse Composition for the care of keratin material and cosmetic treatment process using said composition
US8586014B2 (en) 2005-10-28 2013-11-19 L'oreal Composition for the care of keratin material and cosmetic treatment process using said composition
US7867969B2 (en) 2005-10-28 2011-01-11 L'oreal S.A. Composition for washing keratin materials comprising a magnesium salt anionic surfactant
US20070190008A1 (en) * 2005-12-20 2007-08-16 Catherine Campain Process for permanently reshaping the hair, comprising applying to the hair at least one precipitated fixing polymer, and multi-compartment device
EP2181596A1 (en) 2006-02-16 2010-05-05 Buckman Laboratories International, Inc Method of inhibiting the growth of microorganism in aqueous systems using a composition comprising lysozyme
US20070191255A1 (en) * 2006-02-16 2007-08-16 Buckman Laboratories International, Inc. Method and composition to control the growth of microorganisms in aqueous systems
US7348301B2 (en) 2006-02-16 2008-03-25 Buckman Laboratories International, Inc. Lysozyme-based method and composition to control the growth of microorganisms in aqueous systems
US20070197388A1 (en) * 2006-02-22 2007-08-23 Buckman Laboratories International, Inc. Haloperoxidase treatment to control algae
US20070251026A1 (en) * 2006-04-12 2007-11-01 Boris Lalleman Unsaturated fatty substances for protecting the color of artificially dyed keratin fibers with respect to washing; and dyeing processes
US20100047201A1 (en) * 2006-04-12 2010-02-25 L'oreal, S.A. Unsaturated fatty substances for protecting the color of artificially dyed keratin fibers with respect to washing; and dyeing processes
US20080127429A1 (en) * 2006-10-25 2008-06-05 Gaelle Brun Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
US7799093B2 (en) 2006-10-25 2010-09-21 L'ORéAL S.A. Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
EP1920755A1 (en) 2006-11-10 2008-05-14 L'Oréal Method for permanently deforming keratinous fibres comprising a step of applying an intermediate rinsing component comprising a monovalent metal cation salt or an ammonia salt and an organic acid
EP1935396A1 (en) 2006-12-22 2008-06-25 L'Oreal Method for permanently deforming keratinous fibres including a step of applying a reducing composition with a low concentration and an intermediate drying step
EP1944011A1 (en) 2007-01-12 2008-07-16 L'Oréal Reductive composition designed to be used in a method for permanently deforming keratinous fibres containing cysteine and thiolactic acid or one of their salts
US20080241247A1 (en) * 2007-03-27 2008-10-02 Buckman Laboratories International, Inc. Compositions and Methods To Control the Growth Of Microorganisms In Aqueous Systems
US20090209716A1 (en) * 2007-04-17 2009-08-20 Abbott Medical Optics Inc. Polyquarternium-1 synthesis methods
US20080262194A1 (en) * 2007-04-17 2008-10-23 Advanced Medical Optics, Inc. Polyquaternium-1 synthesis methods
WO2008131013A1 (en) * 2007-04-17 2008-10-30 Advanced Medical Optics, Inc. Polyquaternium-1 synthesis methods
US20110027214A1 (en) * 2007-04-17 2011-02-03 Abbott Medical Optics Inc. Polyquaternium- 1 synthesis methods
US7999063B2 (en) 2007-04-17 2011-08-16 Abbott Medical Optics Inc. Polyquaternium-1 synthesis methods and associated formulations
US7705112B2 (en) 2007-04-17 2010-04-27 Abbott Medical Optics Inc. Polyquaternium-1 synthesis methods
US7795374B2 (en) 2007-04-17 2010-09-14 Abbott Medical Optics Inc. Polyquarternium-1 synthesis methods
US8309679B2 (en) 2007-04-17 2012-11-13 Abbott Medical Optics Inc. Polyquaternium-1 synthesis methods
US8106151B2 (en) 2007-04-17 2012-01-31 Abbot Medical Optics Inc. Polyquaternium-1 synthesis methods
US20090203795A1 (en) * 2007-04-17 2009-08-13 Abbott Medical Optics Inc. Polyquaternium-1 synthesis methods and associated formulations
EP1997473A2 (en) 2007-04-30 2008-12-03 L'Oreal Use of a multi-carbosite, multi-group coupling agent for protecting the colour of artificially dyed keratin fibres with respect to washing; dyeing processes
EP2011473A1 (en) 2007-06-29 2009-01-07 L'Oreal Anhydrous composition in paste form for bleaching keratinous fibres.
DE102007030642A1 (en) 2007-07-02 2009-01-08 Momentive Performance Materials Gmbh A process for the preparation of polyorganosiloxanes having (C6-C60) -Alkylmethylsiloxygruppen and dimethylsiloxy
EP2072084A2 (en) 2007-09-14 2009-06-24 L'Oréal Cosmetic compositions containing a cationic copolymer, an amino silicone and a cationic polymer, and uses thereof
EP2039345A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic compositions containing a cationic copolymer and a particular triglyceride and uses thereof
EP2070511A2 (en) 2007-09-14 2009-06-17 L'Oreal Cosmetic composition comprising at least one specific cationic polymer, at least one surface-active agent, at least one cationic or amphoteric polymer and at least one mineral particle, and cosmetic treatment method using said composition
EP2039344A2 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic composition comprising a cationic copolymer and an anionic associative polymer and cosmetic treatment process
EP2072033A2 (en) 2007-09-14 2009-06-24 L'Oreal Cosmetic composition comprising at least one specific cationic polymer and at least one fatty acid ester in C8-C24 and oxyethylenated sorbitan comprising 2 to 10 oxyethylene patterns, and cosmetic treatment method using said composition
EP2039346A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic composition comprising a cationic copolymer and a starch and cosmetic treatment process
EP2065074A2 (en) 2007-11-09 2009-06-03 L'Oréal Composition for the oxidation dyeing of keratin fibres comprising a cellulose with hydrophobic substituent(s), an oxidation dye and a cationic polymer
EP2065028A2 (en) 2007-11-30 2009-06-03 L'Oreal Repositionable hairstyling composition comprising at least one (meth)acrylic copolymer and at least one silicone.
EP2065024A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising (meth)acrylic copolymers and at least one oil
EP2065023A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising at least one (meth)acrylic copolymer and at least one pearlescent agent
EP2092933A1 (en) 2008-02-22 2009-08-26 L'Oréal Use of particular cationic polymers in a dye composition and associated with a chelating agent as antioxidants or free-radical scavengers
EP2092961A1 (en) 2008-02-22 2009-08-26 L'Oréal Use of particular cationic polymers as anti-oxidant or anti-radical agents
EP2111842A1 (en) 2008-03-28 2009-10-28 L'Oréal Dyeing composition comprising ammonium chloride, method of colouring keratin fibres, and device
EP2116220A1 (en) 2008-04-28 2009-11-11 L'Oreal Cosmetic composition comprising an emulsion obtained by a PIT method
EP2113240A1 (en) 2008-04-28 2009-11-04 L'Oréal Cosmetic composition comprising an emulsion obtained by a PIT method
US9724278B2 (en) 2008-06-13 2017-08-08 Colgate-Palmolive Company Oral compositions and uses thereof
US20090311200A1 (en) * 2008-06-13 2009-12-17 Colgate-Palmolive Oral Compositions and Uses Thereof
EP2301630A2 (en) 2008-12-19 2011-03-30 L'Oréal Oxidizing composition for the treatment of keratin fibres comprising a cationic polymer, a fatty amide and an anti-oxygen agent
WO2010070140A1 (en) 2008-12-19 2010-06-24 L'oreal Antiperspirant composition containing at least one complex formed by combining at least one anionic species and at least one cationic species, and process for treating human perspiration
EP2198929A1 (en) 2008-12-19 2010-06-23 L'oreal Hair dye or lightening composition comprising a fatty substance and a cationic polymer, and use thereof
EP2198850A1 (en) 2008-12-22 2010-06-23 L'oreal Cosmetic composition containing four types of surfactants and one non-silicone fatty derivative
EP2198837A1 (en) 2008-12-22 2010-06-23 L'oreal Cosmetic composition containing four surfactants, a cationic polymer and a zinc salt
EP2236053A1 (en) 2009-04-03 2010-10-06 L'Oréal Method for the steam treatment of hair
EP2246040A2 (en) 2009-04-15 2010-11-03 L'Oréal Method for the shaping of hair including a step of applying a reducing composition and a heating step
EP2246039A1 (en) 2009-04-30 2010-11-03 L'Oréal Method for dyeing hair comprising the step of treating the hair with an organic silicon compound
EP2266528A1 (en) 2009-04-30 2010-12-29 L'Oréal Process for colouring and/or bleaching human hair using a composition comprising an amino trialkoxysilane or amino trialcenyloxysilane
EP2363110A1 (en) 2009-09-15 2011-09-07 L'Oréal Use of drying oils for protecting the color of artificially colored keratin fibers against washing; method for coloring hair
WO2011073564A2 (en) 2009-12-17 2011-06-23 L'oreal Cosmetic composition comprising a surfactant, a liquid fatty alcohol and a non-ionic associative polymer and cosmetic treatment method
WO2011073563A2 (en) 2009-12-17 2011-06-23 L'oreal Cosmetic composition comprising a surfactant, a liquid fatty alcohol and an oxyethylenated fatty alcohol ether and cosmetic treatment method
WO2011074140A1 (en) 2009-12-18 2011-06-23 L'oreal Process for treating keratin fibers
EP2343042A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least one anionic surface-active agent and at least one cationic polymer
US20110182842A1 (en) * 2009-12-23 2011-07-28 Carine Aires Cosmetic composition comprising at least one organosilicon compound, at least two anionic surfactants and at least one amphoteric surfactant
EP2356975A1 (en) 2009-12-23 2011-08-17 L'Oréal Cosmetic composition comprising at least two volatile linear alkanes and at least one cationic, non-protein polymer
EP2343039A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least two anionic surface-active agents and at least one amphoteric surface-active agent
EP2343041A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least one anionic surface-active agent and at least one non-ionic thickener, as well as a method implementing the composition
US9248083B2 (en) 2009-12-23 2016-02-02 L'oreal Cosmetic composition comprising at least one organosilicon compound, at least two anionic surfactants and at least one amphoteric surfactant
US9095528B2 (en) 2009-12-23 2015-08-04 L'oreal Cosmetic composition comprising at least two volatile linear alkanes and at least one nonprotein cationic polymer
US20110155163A1 (en) * 2009-12-23 2011-06-30 Viravau Valerie Cosmetic composition comprising at least one organosilicon compound, at least one anionic surfactant and at least one nonionic thickener, and process using the composition
EP2338469A1 (en) 2009-12-23 2011-06-29 L'Oréal Use of a cosmetic composition containing a linear volatile alcane and an associative non-ionic polymer for conditioning the hair
FR2954139A1 (en) * 2009-12-23 2011-06-24 Oreal cosmetic composition comprising at least one volatile linear alkane and at least one non-protein cationic polymer
EP2343040A2 (en) 2009-12-23 2011-07-13 L'Oréal Cosmetic composition containing at least one organic silicon compound, at least one anionic surface-active agent and at least one amine silicone as well as a method implementing said composition
US20110158927A1 (en) * 2009-12-23 2011-06-30 Viravau Valerie Cosmetic composition comprising at least one organosilicon compound, at least one anionic surfactant and at least one cationic polymer
WO2011107468A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic antidandruff composition based on ellagic acid or a derivative thereof and a second, different active compound in a specific weight ratio
WO2011107433A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic composition based on ellagic acid or a derivative thereof and a bacterial extract
WO2011107432A2 (en) 2010-03-01 2011-09-09 L'oreal Composition comprising ellagic acid and a particular cationic surfactant, and cosmetic use thereof
WO2011107469A1 (en) 2010-03-01 2011-09-09 L'oreal Use of ellagic acid as an anti-dandruff agent
WO2011107467A2 (en) 2010-03-01 2011-09-09 L'oreal Cosmetic composition based on ellagic acid or a derivative thereof and on a particular mixture of surfactants
WO2011138450A2 (en) 2010-05-07 2011-11-10 L'oreal Foaming cosmetic composition containing ellagic acid or one of the salts thereof and an essential oil
WO2012032055A1 (en) 2010-09-06 2012-03-15 L'oreal Cosmetic composition comprising at least one cationic polymer and at least two cationic surfactants
WO2012032673A1 (en) 2010-09-08 2012-03-15 L'oreal Cosmetic composition for keratin fibers
WO2012038536A2 (en) 2010-09-24 2012-03-29 L'oreal Cosmetic composition comprising at least one hygroscopic salt, at least one aromatic polyol ether and at least one diol, and cosmetic treatment process
WO2012042019A2 (en) 2010-10-01 2012-04-05 L'oreal Process for treating keratin fibres using at least one sulfureous reducing agent, at least one cationic polymer and at least one mercaptosiloxane.
WO2012049145A1 (en) 2010-10-12 2012-04-19 L'oreal Cosmetic composition comprising a particular silicon derivative and one or more acrylic thickening polymers
WO2012055812A1 (en) 2010-10-26 2012-05-03 L'oreal Cosmetic composition comprising a fatty-chain alkoxysilane and an antidandruff agent.
WO2012055807A1 (en) 2010-10-26 2012-05-03 L'oreal Cosmetic composition comprising a fatty-chain alkoxysilane and a cationic polymer
US8784506B2 (en) 2010-11-02 2014-07-22 L'oreal Dye composition having a low content of ammonia
WO2012059410A1 (en) 2010-11-02 2012-05-10 L'oreal Dye composition having a low content of ammonia
WO2012072765A1 (en) 2010-12-03 2012-06-07 L'oreal Cosmetic composition containing a non-amino silicone, a liquid fatty ester and an amino silicone, process and use
US8628586B2 (en) 2010-12-07 2014-01-14 L'oreal Composition comprising an oxidation dye precursor, a polycondensate of ethylene oxide and propylene oxide and a cationic polymer with a charge density of greater than or equal to 4 meq./g
WO2012076559A1 (en) 2010-12-07 2012-06-14 L'oreal COMPOSITION COMPRISING AN OXIDATION DYE PRECURSOR, A POLYCONDENSATE OF ETHYLENE OXIDE AND PROPYLENE OXIDE AND A CATIONIC POLYMER WITH A CHARGE DENSITY OF GREATER THAN OR EQUAL TO 4 meq./g
WO2012084866A1 (en) 2010-12-21 2012-06-28 L'oreal Composition comprising a non-nitrogenous zinc salt and a particular cationic surfactant
US9375393B2 (en) 2010-12-21 2016-06-28 L'oreal Composition comprising a non-nitrogenous zinc salt and a particular cationic surfactant
WO2012084901A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt and a solid fatty ester
US8828368B2 (en) 2010-12-21 2014-09-09 L'oreal Cosmetic composition comprising a particular zinc salt and a starch
US8802066B2 (en) 2010-12-21 2014-08-12 L'oreal Cosmetic composition comprising a particular zinc salt and an amino silicone
WO2012084904A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a particular zinc salt and a starch
WO2012084903A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a particular zinc salt and an amino silicone
WO2012084867A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt, a cationic polymer and a propellant
WO2012084863A1 (en) 2010-12-21 2012-06-28 L'oreal Cosmetic composition comprising a zinc salt and 1,2-octanediol
WO2012110608A2 (en) 2011-02-17 2012-08-23 L'oreal Process for treating keratin fibres using a silicone elastomer in combination with heat
WO2012137165A2 (en) 2011-04-08 2012-10-11 L'oreal A hair treatment method
WO2012149617A1 (en) 2011-05-04 2012-11-08 L'oreal S.A. Detergent cosmetic compositions comprising four surfactants, a cationic polymer and a silicone, and use thereof
WO2012163869A2 (en) 2011-05-27 2012-12-06 L'oreal Composition comprising an alkoxysilane and a modified starch, and cosmetic use thereof
WO2012163868A2 (en) 2011-05-27 2012-12-06 L'oreal Composition comprising an alkoxysilane, a fatty ester and a silicone, and cosmetic use thereof
US9776020B2 (en) 2011-05-27 2017-10-03 L'oreal Composition comprising an alkoxysilane and a modified starch, and cosmetic use thereof
US9610241B2 (en) 2011-06-01 2017-04-04 L'oreal Process for treating straightened keratin fibres
WO2012164065A2 (en) 2011-06-01 2012-12-06 L'oreal Process for treating straightened keratin fibres
US9180086B2 (en) 2011-06-01 2015-11-10 L'oreal Process for treating straightened keratin fibres
WO2012171850A2 (en) 2011-06-17 2012-12-20 L'oreal Cosmetic composition comprising an anionic surfactant, a nonionic or amphoteric surfactant and a solid fatty alcohol, and cosmetic treatment process
WO2013004773A2 (en) 2011-07-05 2013-01-10 L'oreal Cosmetic composition rich in fatty substances comprising a polyoxyalkylenated fatty alcohol ether and a direct dye and/or an oxidation dye, the dyeing method and the device
US9060944B2 (en) 2011-07-05 2015-06-23 L'oreal Cosmetic composition rich in fatty substances comprising a polyoxyalkylenated fatty alcohol ether and a direct dye and/or an oxidation dye, the dyeing method and the device
US9044412B2 (en) 2011-07-05 2015-06-02 L'oreal Dye composition using a long-chain ether of an alkoxylated fatty alcohol and a cationic polymer, processes and devices using the same
US9066890B2 (en) 2011-07-05 2015-06-30 L'oreal Dye composition comprising an alkoxylated fatty alcohol ether and a fatty alcohol
WO2013004784A2 (en) 2011-07-05 2013-01-10 L'oreal Dye composition using a long-chain ether of an alkoxylated fatty alcohol and a cationic polymer, processes and devices using the same
WO2013042274A1 (en) 2011-09-22 2013-03-28 L'oreal Cosmetic cleansing composition
US9463148B2 (en) 2011-09-30 2016-10-11 L'oreal Foam dye composition comprising a polycondensate of ethylene oxide and propylene oxide
WO2013045630A1 (en) 2011-09-30 2013-04-04 L'oreal Foam dye composition comprising at least one liquid fatty alcohol and a particular cationic polymer
US9226879B2 (en) 2011-09-30 2016-01-05 L'oreal Foam dye composition comprising at least one particular oxyethylenated nonionic surfactant
WO2013092608A2 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising a hydrophobically modified cellulose, a sulfated or sulfonated anionic surfactant and a branched fatty alcohol
WO2013092722A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising a hydrophobically modified cellulose and an anionic surfactant comprising one or more carboxylate group(s)
WO2013093332A2 (en) 2011-12-20 2013-06-27 L'oreal Cosmetic composition comprising an anionic surfactant, a solid fatty alcohol and a solid fatty ester, and cosmetic treatment process
WO2013110653A1 (en) 2012-01-23 2013-08-01 L'oreal Composition comprising at least one specific alkoxysilane polymer
WO2013183021A1 (en) 2012-06-07 2013-12-12 L'oreal Method of shaping hair using fatty bodies, non-silicone polymers or surfactants
US9475907B2 (en) 2012-06-22 2016-10-25 Alfred E. Tiefenbacher GmbH & Co., KG Process for the preparation of polyquarternium-I
WO2013189596A1 (en) * 2012-06-22 2013-12-27 Alfred E. Tiefenbacher (Gmbh & Co. Kg) Process for the preparation of polyquaternium-1
DE102012012263A1 (en) * 2012-06-22 2013-12-24 Alfred E. Tiefenbacher (Gmbh & Co. Kg) A process for the preparation of Polyquaternium-1
WO2014002290A1 (en) 2012-06-29 2014-01-03 L'oreal Cosmetic composition for keratin fibers
US9827185B2 (en) 2012-08-02 2017-11-28 L'oreal Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant
WO2014020147A2 (en) 2012-08-02 2014-02-06 L'oreal Dyeing composition comprising a fatty substance, a non-ionic guar gum, an amphoteric surfactant and a non-ionic or anionic surfactant, and an oxidizing agent, dyeing process and suitable device
WO2014020146A2 (en) 2012-08-02 2014-02-06 L'oreal Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant
WO2014056962A2 (en) 2012-10-11 2014-04-17 L'oreal Cosmetic composition comprising a bacterial lysate, a thickener and a particular surfactant system, and cosmetic treatment process
WO2014068795A1 (en) 2012-10-31 2014-05-08 L'oreal Use of triazine derivatives for permanent deformation of keratin fibers
WO2014072645A1 (en) 2012-11-09 2014-05-15 L'oreal Method for straightening the hair using a composition containing glyoxylic acid and/or a derivative thereof
DE202013011676U1 (en) 2012-11-09 2014-02-14 L'oreal Composition containing a dicarbonyl compound
WO2014091111A2 (en) 2012-12-11 2014-06-19 L'oreal Cosmetic composition comprising the association of nonionic and cationic surfactants, and cosmetic treatment method
WO2014091125A2 (en) 2012-12-11 2014-06-19 L'oreal Cosmetic composition comprising a nonionic surfactant, a cationic surfactant, a liquid fatty ester and a particular silicone, and cosmetic treatment method
WO2014111668A2 (en) 2013-01-18 2014-07-24 L'oreal Flexible solid cosmetic composition comprising anionic surfactants and polyols, and cosmetic treatment method
WO2014111579A2 (en) 2013-01-18 2014-07-24 L'oreal Hair shaping process in which is applied a particular styling composition, which is rinsed out
WO2014111669A2 (en) 2013-01-18 2014-07-24 L'oreal Flexible solid cosmetic composition comprising anionic surfactants and solid particles, and cosmetic treatment process
WO2015044057A1 (en) 2013-09-24 2015-04-02 L'oreal Cosmetic composition comprising a combination of surfactants of carboxylate, acylisethionate and alkyl(poly)glycoside type
WO2015063122A1 (en) 2013-10-30 2015-05-07 L'oreal Expanded dyeing composition comprising an inert gas, an oxidation dye and an oxyalkylenated nonionic surfactant
WO2015091336A1 (en) 2013-12-19 2015-06-25 L'oreal Composition rich in fatty substances comprising hydrogen peroxide, a persalt and oxyethylenated surfactants
WO2015091338A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing process using compositions rich in fatty substances
WO2015091337A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing composition rich in fatty substances comprising a mixture of oxyethylenated surfactants
WO2015091334A1 (en) 2013-12-19 2015-06-25 L'oreal Dyeing composition comprising at least 75% of fatty substances and a mixture of oxyethylenated surfactants
WO2016096654A1 (en) 2014-12-17 2016-06-23 L'oreal Dye composition comprising a para-phenylenediamine oxidation base and an amphoteric or cationic polymer in a medium rich in fatty substances
WO2016156486A1 (en) 2015-04-02 2016-10-06 L'oreal Cosmetic composition comprising non-amino polyalkylsiloxanes, oxyethylenated polymers and fatty alcohols
WO2017018498A1 (en) 2015-07-28 2017-02-02 L'oreal Composition, process, method and use for keratin fibers
WO2017102650A1 (en) 2015-12-14 2017-06-22 L'oreal Device for dispensing a product for dyeing and/or lightening keratin fibres comprising an associative polymer
WO2017104585A1 (en) 2015-12-15 2017-06-22 L'oreal Combination of polyion complex particle and hydrophilic or water-soluble uv filter
WO2017104221A1 (en) 2015-12-15 2017-06-22 L'oreal Combination of polyion complex particle and non-polymeric acid having two or more acid dissociation constants
WO2018007352A1 (en) 2016-07-07 2018-01-11 L'oreal Cosmetic composition comprising a particular combination of surfactants, a silicone, a cationic polymer, a fatty alcohol and a clay
WO2018056235A1 (en) 2016-09-20 2018-03-29 L'oreal Composition for keratin fibers
WO2018081399A1 (en) 2016-10-31 2018-05-03 L'oreal Compositions for chemically treated hair
US9974725B1 (en) 2017-05-24 2018-05-22 L'oreal Methods for treating chemically relaxed hair

Similar Documents

Publication Publication Date Title
US5624634A (en) Peracid compositions for medical disinfection
US4581351A (en) Composition of matter containing imidazolidinyl urea and pyrithione and its derivatives
US6534075B1 (en) Antimicrobial and antiviral compositions and treatments for food surfaces
US5709880A (en) Method of making tabletized ionene polymers
Hough-Troutman et al. Ionic liquids with dual biological function: sweet and anti-microbial, hydrophobic quaternary ammonium-based salts
US5776960A (en) Synergistic antimicrobial compositions containing an ionene polymer and a pyrithione salt and methods of using the same
US6436445B1 (en) Antimicrobial and antiviral compositions containing an oxidizing species
US4767542A (en) Method for disinfecting aqueous medium with N,N'-dihalo-2-imidazolidinones
US6242009B1 (en) Microbicidal formulations and methods to control microorganisms
US5093078A (en) Novel polymeric quaternary ammonium trihalides and use of polymeric quaternary ammonium trihalides as microbicides, sanitizers and disinfectants
US5064613A (en) Solid antimicrobial
US5403587A (en) Disinfectant and sanitizing compositions based on essential oils
US4499077A (en) Anti-microbial compositions and associated methods for preparing the same and for the disinfecting of various objects
US5720983A (en) Two pack peracid disinfection system, method of preparation of disinfectant composition therefrom, and use thereof in disinfecting a surface
US5707534A (en) Use of tabletized ionene polymers in water treatment
US2917429A (en) Method of destroying nematodes employing dimethyl polysulfides
US5286719A (en) Phospholipid virucidal compositions
US4829129A (en) Reaction product of polymer with chlorine dioxide
US6630172B2 (en) Microbicidal composition containing potassium sodium tartrate
US4337269A (en) Preservative compositions
GB2090605A (en) Polymer of diallyl ammonium monomers pharmaceutical compositions thereof
US4976874A (en) Control of biofouling in aqueous systems by non-polymeric quaternary ammonium polyhalides
US4073927A (en) Di-quaternary ammonium salts of hydantoin and compositions thereof
US4089977A (en) Polymeric anti-microbial agent
US4025627A (en) Microbiocidal polymeric quaternary ammonium compounds

Legal Events

Date Code Title Description
AS Assignment

Owner name: BARCLAYS AMERICAN, 1 BUSINESS CREDIT, INC. 111 FOU

Free format text: SECURITY INTEREST;ASSIGNOR:MILLMASTER ONYX GROUP, INC., A DE CORP.;REEL/FRAME:004139/0941

Effective date: 19821222

Owner name: MILLMASTER ONYX GROUP, INC., A DE CORP.

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:KEWANEE INDUSTRIES, INC.;REEL/FRAME:004139/0909

Effective date: 19830407

AS Assignment

Owner name: BANKERS TRUST COMPANY, A CORP. OF NY, NEW YORK

Free format text: SECURITY INTEREST;ASSIGNOR:MILLMASTER ONYX GROUP, INC., A CORP. OF DE;REEL/FRAME:005002/0735

Effective date: 19881019

AS Assignment

Owner name: MILLMASTER ONYX GROUP, INC.

Free format text: RE-ASSIGNMENT AND RELEASE.;ASSIGNOR:BANKERS TRUST COMPANY;REEL/FRAME:006273/0869

Effective date: 19920630

AS Assignment

Owner name: CIT GROUP/BUSINESS CREDIT, INC., NEW YORK

Free format text: SECURITY INTEREST;ASSIGNOR:MILLMASTER ONYX GROUP, INC.;REEL/FRAME:006319/0109

Effective date: 19920630

AS Assignment

Owner name: MILLMASTER ONYX GROUP, INC., CONNECTICUT

Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:BANKERS TRUST COMPANY;REEL/FRAME:006388/0575

Effective date: 19920630

AS Assignment

Owner name: MILLMASTER ONYX GROUP, L.P.

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MOG ACQUISITION CORPORATION;REEL/FRAME:006587/0526

Effective date: 19930122

Owner name: MOG ACQUISITION CORPORATION

Free format text: MERGER;ASSIGNOR:MILLMASTER ONYX GROUP, INC.;REEL/FRAME:006589/0218

Effective date: 19930121